BASF Greater China TPU 特性及应用 26/09/2003 VTC HongKongThermoplastic Polyurethane2 TPU...

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BASF Greater China

TPU 特性及应用

26/09/2003 VTC HongKong Thermoplastic Polyurethane 2

TPU 的特性

Very good flexibility and impact strenght Operate at low temperature at low temperatures 低温柔韧 抗冲击

High tear strength 撕裂强度 Long life

Good resitance against oil and fuel 耐油 Use in this application

Processing with standard machines 通用加工性 No additional investment

Very good damping behaviour 耐湿气 耐水解 Improved comfort; long life

Property BenefitBenefit

High tensile strength 拉伸强度 Reduction of wall thickness

Abrasion resistance 耐磨 Low wear

Elastollan properties

Elastollan 的优点

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TPU 的特性 Elastollan properties

##99 SHORE A D硬度 与 的转换关系

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Hardness Shore D

Har

dnes

s S

hore

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Series1

•一般来讲 , A 适合于较软材料 , D 适合于较硬材料 . A 与 D 的指标有一定交迭(overlap):

1180A 1185A 1190A 1195A 1154D 1160DShore A 80 87 92 96Shore D 36 42 48 53 60

•硬度随温度的升高而降低 . 标准测试硬度的条件是 23°C 50% 相对湿度 (DIN 53505)

硬度

硬度是 TPU 选型的基本指标

TPU 一般采用邵氏 (Shore) 硬度 A 和 D.

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TPU 的特性 Comparison Modulus of elasticity 弹性模量

106

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10-1

E-

Mo

du

l弹性

模量

(M

Pa)

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Rubber

Co-poly

esther

Steel

Aluminium

TPR

TPE

PVC

ABS

PE

Polycarbonate

TP

U

R-TPU

Polyester

Elastollan properties

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0 500 1000 1500 2000 2500 3000 3500

Elastollan 11

Elastollan C

Elastollan B

Elastollan S

Elastollan R

Modulus of elasticity( 弹性模量 )

[ MPa ]

Elastollan propertiesTPU 的特性

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0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75

Elastollan 11

Elastollan C

Elastollan B

Elastollan S

Elastollan R

Tensile strength 拉伸强度

[ MPa ]

Elastollan properties

[ MPa ]

TPU 的特性

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TPU 的特性 Elastollan properties

Compression Set ( 压缩形变率 )(%)

•以百分比表示 , 指 TPU 经过一定条件的压缩后 , 形成永久变形的 部分的多少 .

•标准测试方法 : DIN 53517.

•在测试前进行热处理 (Post cure) 有可能得到最好的指标 .

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TPU 的特性 Elastollan properties

Impact Strength 耐冲击Impact strength Notched impact strength

Elastollan C 85A down to -60C no fracture Fracture from -50CElastollan C 95A down to -60C no fracture Fracture from -40CElastollan C 60D down to -60C no fracture Fracture from -20CElastollan 1185A down to -60C no fracture Fracture from -60CElastollan 1195A down to -60C no fracture Fracture from -50CElastollan 1160D down to -60C no fracture Fracture from -30C

Elastollan grade have outstanding low-temperature impact strengthElastollan 拥有卓越的低温耐冲击性 , 即使是在有缺口存在时 .

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TPU 的特性 Elastollan properties

Temperatur [° C]

Thermal expansion coefficient( 热膨胀系数 ) [1/K] •ELASTOLLAN 的热膨胀系数受温度和硬度的影响

•RTPU 的热膨胀系数接近于铝和钢铁 .

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TPU 的特性 Elastollan properties

Thermal Deformation; Vicat softening temperature (ISO 306, Tv50/50) 热变形特性 : 维卡软化点

Materials

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PA66 PA6 POM-H R 3000 C74D PP-H ABS C64D 1164D

蓝色为 ELASTOLLAN 材料

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TPU 的特性 Elastollan properties

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Elastollan C 85 A

Elastollan 1185 A

Temperature [°C]

End criterion( 判断标准 ): tensile strength: 20 MPa

Long term air ageing( 空气热老化 )E

xpo

sure

tim

e(暴

露时

间)

[h]

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TPU 的特性 Elastollan properties

1185A (Ether-Type)

C85A (Ester-Type)

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Ten

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str

eng

th [

MP

a]

Time [days]

Air ageing at 100°C 摄氏 100 °C 空气老化

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TPU 的特性 Elastollan properties

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10000

100000

50 60 70 80 90 100

End criterion( 判断标准 ): tensile strength: 20 MPa

Long term hydrolysis resistance 长期耐水解性能

Elastollan 1185 A

Elastollan C 85 A

Imm

ersi

on

tim

e [h

]

Temperature [°C]

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TPU 的特性 Elastollan properties

0 50 100 150 200 250

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th [

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1185 A( 聚醚型 , 长期耐水解 )

C 85 A( 聚酯型 )

Time [d]

Effect of Water Immersion at 80°C 浸泡在摄氏 80 度的水中

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TPU 的特性 Elastollan properties

Swelling ASTM-Oil

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Elastollan C85A TPE-V TPE-V

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ASTM 1

ASTM 2

ASTM 3

166h100°C

168h100°C

504h100°C

耐油性 ( 浸泡在油中的膨胀 )

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良好的耐磨性 低磨擦损耗

TPU 的特性

Surface of a TPU test pieceafter abrasion 经过耐磨测试后的试片表面

High tensile strength高拉伸强度

+High elasticity

高弹性

= High abrasion resistance耐磨

Elastollan properties

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TPU 的应用 Elastollan applicationsExtursion 挤出类

CABLE 电缆

Elastollan sheathing and connectors meets the most stringent criteria for the protection of valuable and sensitive power and control cables. ELASTOLLAN 制做的护套和连接器可以满足各种供电电缆和控制电缆的严格要求 .

•abrasion-resistant 耐磨•flexible from -40°C to +125°C 均衡的高低温耐受性•resistant to cutting, tearing and tear propagation 耐切割 , 撕裂•good electrical properties 良好的电性能•resistant to hydrolysis 耐水解•resistant to oils and greases 耐油 , 脂

Special Elastollan grades are also 特殊级别 ELASTOLLAN 可提供 :

flame-retardant without halogen 无卤素阻燃级suitable for matt surfaces 不反光表面crosslinkable. 可交联级

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TPU 的应用 Elastollan applicationsExtursion 挤出类

CABLE 电缆

电缆护套和连接器 : 柔韧 , 水密性 , 耐冲击 .(C-grade; 1100-grade; B-grade;S-grade)

汽车的 ABS 制动系统必须100% 的可靠 . 用 ELASTOLLAN 材料制做的 ABS 电缆可以信赖.同样可用于 ESP;BBK;ASR;DSC;TC 系统.(1100-grade) 工业机器人拖弋电缆,气压喉管,保护套管:

柔韧;阻燃;长期耐机械磨损.( C -grade;1100-grade)  

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TPU 的应用 Elastollan applicationsExtursion 挤出类CABLE 电缆

Cable for television camera: 电视摄像用电缆Camera and headphone cables must not be reflective. A special matt Elastollan provides an optimum surface finish for this application. 摄像和耳机线要求不反射光线 . 用特殊暗面的 ELASTOLLAN可满足此要求 . (ELASTOLLAN 1185A M)

Cables of halogen free flame retardant Elastollan for high reliability, mainly in applications such as cables for robots and automatic equipment无卤阻燃 ELASTOLLAN 电缆护套 , 可靠性高 , 主要用于自动化设备 .(ELASTOLLAN 1185A FHF)

多功能电缆需要 ELASTOLLAN 护套

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TPU 的应用 Elastollan applicationsExtursion 挤出类FIBER 弹性纤维

Solvent free production 无溶剂high elasticity 高弹性colour brilliance 高光泽度high extension 高伸长abrasion resistant 耐磨elastic and kink resistant 防绞结washable 可冲洗resistant to perspiration, alkali, UV-light, Chlorine and sea water耐 汗 ; 碱 ; 紫外线 ; 氯化物 ; 海水temperature resistant 耐温 Processing Technique:Modified melt spinning equipment 需要用熔融纺设备生产 Typical applications:典型用途textiles for clothing衣物orthopaedic items塑型产品elastic ribbon 弹性丝带

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TPU 的应用 Elastollan applicationsExtursion 挤出类

HOSE 喉管

Properties: 特性 :abrasion-resistant耐磨flexible from -40°C to +100°C均衡的高低温耐受性resistant to cutting, tearing and tear propagation耐切割 , 撕裂 , 裂缝延伸resistant to hydrolysis, microorganism耐水解 ,微生物resistant to oils and greases耐油 , 脂resistant to ozone.耐臭氧

Special Elastollan grades are also特殊级别 ELASTOLLAN 可提供 :halogen free无卤素阻燃级 suitable for matt surfaces暗面

Typical applications for hoses:典型用途 :pneumatic hoses 气压管spiral hoses螺旋线conveying hoses传送管hydraulic hoses (outer layers) 水龙

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TPU 的应用 Elastollan applicationsExtursion 挤出类HOSE 喉管

Pneumatic hoses made of Elastollan show an optimal burst pressure and resilience behaviour and allow for tight bend radii

TPU coiled cables have a long lasting excellent memory

High pressure hoses: protection againstphysical climatic abuse

Extraction&conveying hoses:flexible&durable for use with themost abrasive substance

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TPU 的应用 Elastollan applicationsExtursion 挤出类

FILM 薄膜

Properties: 特性 :abrasion-resistant耐磨flexible from -40°C to +125°C均衡的高低温耐受性resistant to cutting, tearing and tear propagation耐切割 , 撕裂 , 裂缝延伸resistant to hydrolysis, microorganism耐水解 ,微生物resistant to oils and greases耐油 , 脂resistant to ozone and high-energy radiation.耐臭氧 , 高能射线 

Special Elastollan grades are also特殊级别 ELASTOLLAN 可提供 :halogen free无卤素级 suitable for matt surfaces暗面highly elastic and stretchable高弹性 , 高伸长率scratchproof防擦 (刮 )伤 Processing加工方式 :Conventional processing equipment. Blowm film and flat-die extrusion. Also calendering Extrusion and calender melt coating.适合通常的薄膜加工方式

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TPU 的应用 Elastollan applicationsExtursion 挤出类FILM 薄膜

blow film: extremely pin penetration and tear resistant耐穿孔 , 耐撕裂

Protective sheeting for mattresses are impermeable to water but breathable作为床垫的保护层 , 防止水渗入 , 可透气

Typical applications for films:典型用途:interior trim and engine enclosure (automotive) 汽车内饰 , 发动机围栏medical films医用薄膜 (手术用 ) protective film for mattresses床垫膜packaging film包装膜ski and snowboard film滑雪板薄膜air cushions for shoe inserts鞋用气囊clothing 衣物

Low temperature flexibility and surface protection for snowboards为滑雪板提供表面保护和低温柔韧

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TPU 的应用 Elastollan applicationsExtursion 挤出类

PROFILE 异形材

Properties: 特性 :abrasion-resistant耐磨flexible from -40°C to +100°C均衡的高低温耐受性resistant to cutting, tearing and tear propagation耐切割 , 撕裂 , 裂缝延伸resistant to hydrolysis, microorganism耐水解 ,微生物resistant to oils and greases耐油 , 脂resistant to ozone.耐臭氧 

Special Elastollan grades are also特殊级别 ELASTOLLAN 可提供 :halogen free无卤素阻燃级 suitable for matt surfaces暗面

Typical applications for hoses:典型用途 :round-section belts圆截面带 drive belts 传送带sealing strips 密封条 scraper blades刮刃hinges 绞链

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TPU 的应用 Elastollan applicationsExtursion 挤出类PROFILE 异形材

Elastollan profiles: flexible and chemical resistent for an excellent seal足够的柔韧和耐化学性 , 以达优良的密封效果 .

Round section and V-belts:Creep&abrision resistance, flexible and ease of weldingELASTOLLAN 制作的圆形及 V 形皮带的特点 : 耐磨 , 耐蠕变 , 柔韧 , 易焊接 .

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TPU 的应用 Elastollan applicationsExtursion 挤出类

COMPOUND 与其它塑料共混

Properties: 特性 :low temperature flexibility 低温柔韧impact and flexcrack resistant 抗冲击 abrasion resistant 耐磨 sound absorbant吸声 weathering resistant 耐侯 resistant to oils, greases and ozone 耐油脂 ,臭氧 elastic and crease resistant 高弹 , 防折皱 tear resistant 耐撕裂

Hardness: 55 Shore A to 74 D

Processing: 加工On conventional processing machines 采用通常加工设备

extrusion for films and fibrescompounding for polymer blends

Typical applications for compounds:典型用途 :fastening elements紧扣件safety elements安全件multi-component articles 多组份物件

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TPU 的应用 Elastollan applicationsExtursion 挤出类COMPOUND 与其它塑料共混

POM/ Elastollan -compound for cable fixing clips in automotive applications. To improve impact strength.用 ELASTOLLAN 和 POM共混的汽车用线缆固定夹 , 其冲击强度得到增强 .

Anthracite-coloured handle in a rubber compounds has an agreeably soft feelModification with Elastollan increases durability用 ELSATOLLAN共混后的手柄手敢柔软舒适 , 更耐用 .

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TPU 的应用 Elastollan applicationsInjection 注射类SHOE 鞋类

Elastollan shoe soles are comfortable, lightweight, fashionable, ergonomic, durable and can be anti-static. In short perfect for safety footwear. Typical applications in the footwear sector are: soles for safety footwear, hiking boots and shoes, sports shoes, heel taps, reinforcements trimmings. Hardness: 55 Shore A to 74 Shore D.ELASTOLLAN 可以用来制做安全鞋 ; 运动鞋 ; 休闲鞋 . 具有耐磨 , 舒适 , 寿命长 , 性价比高的特点 .

Safety shoe安全鞋 Sports shoe运动鞋

Sports shoe sole: in various hardness grade and color combinations

多种硬度 , 适合多种配色

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TPU 的应用 Elastollan applicationsInjection 注射类SPORTS AND LEISURE 运动与休闲品

Typical applications in the footwear sector are: performance-enhancing, ergonomic, trendy.Elastollan Ski tips protect against mechanical damage from snow and ice. Intelligent design also enhances the degree of the protection. Typical applications for leisure activities:典型休闲用途 :skateboard rollers滑冰鞋轮子inline roller skate shells 线形滑冰鞋golf trolley covers 高尔夫推车罩mast sleeves旗杆护套

Typical wintersport applications:冬季运动用途 :ski boot shells冰鞋外壳件shells for snowboard boots雪靴film for snowboards滑雪板薄膜ski tips雪翘尖端binder elements紧固件

Hardness: 55 Shore A to 74 Shore D

Properties:特性 :abrasion-resistant 耐磨notched impact strength 缺口冲击强度rigid坚韧flexible at low temperature 低温柔韧good resilience 弹性flexural strength曲折强度durable 耐用

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TPU 的应用 Elastollan applicationsInjection 注射类

SPORTS AND LEISURE 运动与休闲品

Low temperature flexibility and surface protection for snowboardsELASTOLLAN 薄膜 : 为滑雪板提供表面保护和低温柔韧

Ski tips protect against mechanical damage from snow and ice保护滑雪板免受冰雪中的机械创伤 . 成熟的设计更加能提升保护功能 .

Elastollan as materials:your product ideas soonbecome reality滑雪护目镜

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TPU 的应用 Elastollan applicationsInjection 注射类AUTOMOBILE 汽车

Elastollan provides this branch of industry with a material which fulfils the requirements for quality and consistency and an outstanding combination of material properties such as low temperature flexibility, good appearance and damping, resistance to oils, abrasion resistance and durability. 出色的综合性能全面满足汽车工业的严格要求 .

Typical automotive applications: 用途 :gear knobs排挡头selector fingersbushings衬套stop damperscover stripsaerials天线seals 密封条cable runschassis spring seatings 弹簧座套non-slip linings止滑衬套trim装饰件door/seat stops.

Properties: 性能 :resistant to oils, grease and ozone 耐油脂 ,臭氧 abrasion-resistant 耐磨notched impact strength 缺口冲击强度rigid坚韧flexible at low temperature 低温柔韧good resilience 弹性flexural strength曲折强度durable 耐用elastic modulus up to 10,000 N/mm2弹性模量高达 10,000 N/mm2

Hardness: 55 Shore A to 74 Shore D.

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TPU 的应用 Elastollan applicationsInjection 注射类AUTOMOBILE 汽车

The slush-moulded skin of this instrument panel requires a high quality surface finish, which.is provided by this plasticiser-free, Elastollan development product. Advantages include : outstanding UV resistance, low emissions and fogging, low density and good low temperature properties.仪表板 : 抗 UV, 不含增塑剂 , 良好的低温性 .

This gear lever is equipped with Elastollan damping elements to neutralise vibration and noise变速杆套 :

中和振动和噪音 .

The flexible sealing lip on this Elastollan door sill closes against the door post and seals against ingress of dirt and moisture. 门窗弹性密封条 :保护车门窗 ,免受尘埃和水份影响 .

The selection of Elastollan for gear lever knobs allow very high reproduction of mould detail. The parts have a good feel, are scratchproof and resistant to dirt.排档头 : 手感好 , 防刮擦 , 防污 .

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TPU 的应用 Elastollan applicationsInjection 注射类AGRICULTURE 农业用品

High-tech and practicleHigh-tech products in the food-producing sector have become essential to enable rationalisation, enhanced efficiency and competitiveness.They are also vital aids to targeted and careful use of natural resources.

Typical agriculture applications:典型用途 :grass collecting fingers集草隔条rollers轮conveyor belts传送带seals/cages for roller bearings滚珠轴承密封栏ear tags 耳标collars and chainspicking fingers收割隔条transponders

Properties: 性能 :resistant to oils, grease and ozone 耐油脂 ,臭氧 abrasion-resistant 耐磨notched impact strength 缺口冲击强度rigid坚韧flexible at low temperature 低温柔韧good resilience 弹性flexural strength曲折强度durable 耐用

Hardness: 55 Shore A to 74 Shore D.

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TPU 的应用 Elastollan applicationsInjection 注射类AGRICULTURE 农业用品

Ear TagsElastollan ear tags for the identification of livestock last a lifetime. Weather resistant, flexible and with high tear resistance, they are also suitable for bar coding and attachment of electronic

chips. 动物耳标 :长寿命 , 耐侯 , 弹性抗撕裂 , 还可印刷条形码或安装电子芯片 .

SortingDuring harvesting crops are cleaned of adhering soil and carefully graded using flexible Elastollan sorting components.收割机用筛选器 :柔韧耐磨的 ELASTOLLAN意味着更长的使用寿命 .

Elastollan spacersSelective fishing is a much better alternative to maintain world fish stocks than the use of nets. Elastollan spacers along the lines hold the cords with the fishing hooks reliably in position, making selective fishing a practical proposition for both deep sea and inshore fisheries.鱼钩定位器 :令不同深度选择性捕捞成为现实 .

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TPU 的应用 Elastollan applicationsInjection 注射类INDUSTRY AND ENGINEERING 工业工程用品

Properties: 性能 :

resistant to oils, grease and ozone 耐油脂 ,臭氧 abrasion-resistant 耐磨notched impact strength 缺口冲击强度rigid坚韧flexible at low temperature 低温柔韧good resilience 弹性flexural strength曲折强度durable 耐用can be combined with other materials.可与其他材料混合 .

Hardness: 55 Shore A to 74 Shore D.

Swimming pool cleaner. The flexible, serrated Elastollan cleaning disc faithfully follows all contours of the pool, is resistant to abrasion and chlorinated water.泳池清洗器 : 耐磨 , 耐含氯水 .

用于铁轨和混凝土枕木之间的减振垫 :减低振动和共振 , 同时降低噪音 .

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TPU 的应用 Elastollan applicationsInjection 注射类INDUSTRY AND ENGINEERING 工业工程用品

Able to take continuous loading, abrasion-resistant and sound-damping: Elastollan roller tyres for conveyor systems and shopping trolleys. 用于传送系统 (扶梯 ,手推车 ) 的轮子 :持续负重 , 耐磨 , 消音 .

Elastollan sieve elements provide long term wear and resistance to abrasion for screening of abrasive sharp-edged bulk materials.矿筛 :承受各种坚硬 , 锋利物料的长期磨损 .

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TPU 的应用 Elastollan applicationsInjection 注射类OVERMOULDING 多次注射

More functional through Elastollan: multi-component partsMore economic production. Elastollan can be combined with engineering plastics to optimises the performance of the finished product. Over-moulded products enable more efficient production by reducing and simplifying production processes.ELASTOLLAN 能够与多种工程塑料共混 , 达到优化产品性能 , 简化加工过程的目的 .Handles, for example for power tools, are given a better feel and become less easily soiled, with soft, scratchproof coverings of Elastollan. 例如工具手柄 , ELASTOLLAN 能够提供舒适手感 , 防污 , 防刮擦的特性 .

handle forpower tools withElastollan® handle sheet(53 Shore A)

Cover of a Laptop withElastollan® 1185

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TPU 的应用 Elastollan applicationsInjection 注射类OVERMOULDING 多次注射

Controller 控制器 :Housing: PCSoft elements:Elastollan 1180 A10

Sealing for air filter空气过滤器密封件 :Elastollan C60 A 10WHousing: PA6

手机天线 , 触摸部位 .

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TPU 的应用 Elastollan applicationsInjection 注射类OVERMOULDING 多次注射

Potential Applications for power tools

Black & Decker

Contact to following Power Tool manufacturers:

MetaboHiltiKressBlack & DeckerFeinFesto TooltechnikBosch

Important for Soft material:1. Good adhesion to PA or ABS/PC与 PC, ABS, PC粘合性良好 .(关于 ELASTOLLAN与其它材料的粘合性能 ,请参考下一页 )

2. Fast cycle time短成型周期 .

1. Grips2. Sealings

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TPU 的应用 Elastollan applicationsInjection 注射类OVERMOULDING 多次注射

Soft componentHard component 1180A-10 1185A-10 C 78A-10 C 85A-50 S 85A-50 685 A-10 C 60 A-10 W

Luran 388 S SAN + + + + + + k.H.Luran S 778 T ASA + + + + + + k.H.Luran SKR 2863 ASA / PC + + + + + + k.H.Ultradur S 4090 G4 PBT / ASA k.H. k.H. k.H. k.H. k.H. k.H. k.H.Ultradur B 4520 PBT k.H. k.H. k.H. k.H. k.H. k.H. k.H.Terluran 996 S ABS + + + + + + k.H.Novodur P2H - AT ABS + % ++ % % % %Bayblend T 65 PC / ABS + + ++ ++ + k.H. k.H.Makrolon 2605 PC + ++ ++ ++ ++ ++ k.H.Ultramid A3K PA 66 - + - k.H. + - -Ultramid B3K PA 6 - + + + + + -Ultramid B3S PA 6 + + + + + + -Ultramid B3 PA 6 % % ++ % % % %Rilsan AMN PA 12 k.H. k.H. k.H. k.H. k.H. k.H. k.H.Pebax 5533SN01 PEBA ++ ++ + + + + +Pebax 7033 SN 01 PEBA + + + + + k.H. k.H.Lomod LX 1243 TEEE + + - + + + k.H.Lucryl G 88 UV 1 Q 13 PMMA - + + + + + k.H.Ultraform S 2320 POM k.H. k.H. k.H. k.H. k.H. k.H. k.H.Hostaform C 9021 POM k.H. k.H. k.H. k.H. k.H. k.H. k.H.Hostaform S 9064 POM k.H. k.H. k.H. k.H. k.H. k.H. k.H.Elastollan R 2002 R - TPU ++ ++ ++ ++ + ++ -Elastollan LP 9202 R - TPU % % + % % % %Elastollan LP 9062 HM - TPU % % ++ % % % %Elastollan C 78 A 10 TPU % % ++ % % % %Polystyrol 168 N PS k.H. k.H. k.H. k.H. k.H. k.H. k.H.Polystyrol 475 K PS k.H. k.H. k.H. k.H. k.H. k.H. k.H.Hart - PVC G 6441 PVC + ++ ++ ++ ++ ++ +

Bonding of Hard-Soft combination

++ very good bonding; + good bonding; k.H. without bonding; % not tested

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