ChemInform Abstract: The Pauson—Khand Reaction in Synthesis of Bicyclic Rigid α-Amino Acids

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2001 amino acids, peptides

amino acids, peptidesU 0400

43 - 210The Pauson–Khand Reaction in Synthesis of Bicyclic Rigid α-AminoAcids. — The Pauson–Khand reaction is shown to be compatible withthe Schllkopf bislactim ether auxiliary and can be used in stereoselectiveconstructions of bicyclic α-amino acids [cf. (V)], where the ring carbon ofthe amino acid is imbedded in the pentalene ring system. — (WANG,JING; FALCK-PEDERSEN, METTE LENE; ROEMMING, CHRISTIAN;UNDHEIM, KJELL; Synth. Commun. 31 (2001) 8, 1141-1148; Dep. Chem.,Univ. Oslo, N-0315 Oslo, Norway; EN)

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