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Kohei Fuchibe Publication List
June 10, 2011
1) K. Fuchibe, H. Jyono, M. Fujiwara, T. Kudo, M. Yokota, J. Ichikawa, ‘Domino Friedel–Crafts-Type Cyclizations of Difluoroalkenes Utilizing the α-Cation-Stabilizing Effect of Fluorine: An Efficient Method for Synthesizing Angular PAHs,’ Chem. Eur. J. in press.
2) K. Oh, K. Fuchibe, J. Ichikawa, ‘Synthesis of 1,1-Difluoroallenes from Commercially Available 1,1,1-Trifluoro-2-iodoethane,’ Synthesis 2011, 881-886.
3) R. Nadano, K. Fuchibe, M. Ikeda, H. Takahashi, J. Ichikawa, ‘Rapid and Slow Generation of 1-Trifluoromethylvinyllithium: Syntheses and Applications of CF3-Containing Allylic Alcohols, Allylic Amines, and Vinyl Ketones,’ Chem. Asian J. 2010, 5, 1875-1883.
4) M. Yokota, K. Fuchibe, M. Ueda, Y. Mayumi, J. Ichikawa, ‘Facile Synthesis of 1,1-Difluoroallenes via the Difluorovinylidenation of Aldehydes and Ketones,’ Org. Lett. 2009, 11, 3994-3997.
5) K. Fuchibe, T. Kaneko, K. Mori, T. Akiyama, ‘Expedient Synthesis of N-Fused Indoles: A C–F Activation and C–H Insertion Approach,’ Angew. Chem. Int. Ed. 2009, 48, 8070-8073 (Selected to the Cover Picture).
Hilight Article; T. G. Driver, ‘Niobium-Catalyzed Activation of Aryl Trifluoromethyl Groups and Functionalization of C–H Bonds: an Efficient and Convergent Approach to the Synthesis of N-Heterocycles,’ Angew. Chem. Int. Ed. 2009, 48, 7974-7976.
6) K. Fuchibe, T. Akiyama, ‘Catalytic Activation of Carbon-fluorine Bonds by Low-valent Niobium Species,’ J. Synth. Org. Chem., Jpn. 2009, 67, 208-218.
7) J. Itoh, K. Fuchibe, T. Akiyama, ‘Chiral Phosphoric Acid Catalyzed Enantioselective Friedel-Crafts Alkylation of Indoles with Nitroalkenes: Cooperative Effect of 3A Molecular Sieves,’ Angew. Chem. Int. Ed. 2008, 47, 4016-4018.
8) J. Itoh, K. Fuchibe, T. Akiyama, ‘Preparation of β-Amino Esters by a Chiral Brønsted Acid-catalyzed Mannich-type Reaction,’ Synthesis 2008, 1319-1322.
9) K. Fuchibe, K. Mitomi, R. Suzuki, T. Akiyama, ‘C–C coupling Reactions of Superstrong CF3 Groups with C(sp2)–H Bonds: Reactivity and Synthetic Utility of Zero-valent Niobium Catalyst,’ Chem. Asian J. 2008, 3, 261-271.
10) T. Akiyama, Y. Honma, J. Itoh, K. Fuchibe, ‘Vinylogous Mannich-type Reaction Catalyzed by an Iodine-substituted Chiral Phosphoric Acid,’ Adv. Synth. Catal. 2008, 350, 399-402.
11) K. Fuchibe, Y. Ohshima, K. Mitomi, T. Akiyama,’Hydrodefluorinations by Low-valent Niobium Catalyst,’ J. Fluorine Chem. 2007, 128, 1158-1167.
12) M. Yamanaka, J. Itoh, K. Fuchibe, T. Akiyama, ‘Chiral Brønsted Acid Catalyzed Enantioselective Mannich-Type Reaction,’ J. Am. Chem. Soc. 2007, 129, 6756-6764.
13) K. Fuchibe, Y. Ohshima, K. Mitomi, T. Akiyama, ‘Low-Valent Niobium-Catalyzed Reduction of α,α,α-Trifluorotoluenes,’ Org. Lett. 2007, 9, 1497-1499.
14) H. Kagoshima, K. Fuchibe, T. Akiyama, ‘Synthesis of Nitrogen-containing Compounds Using Chromium Fischer Carbene Complexes,’ Chem. Rec. 2007, 7, 104-114.
15) K. Fuchibe, K. Mitomi, T. Akiyama, ‘Low-valent Niobium-mediated Synthesis of Indenes: Intramolecular Coupling Reaction of CF3 Group with Alkene C–H Bond,’ Chem. Lett. 2007, 36, 24-25.
16) T. Akiyama, J. Itoh, K. Fuchibe, ‘Recent Progress in Chiral Brønsted Acid Catalysis,’ Adv. Synth. Catal. 2006, 348, 999-1010.
17) J. Itoh, K. Fuchibe, T. Akiyama, ‘Mannich-type Reaction in Water in the Presence of a Surfactant,’ Synthesis 2006, 4075-4080.
18) K. Fuchibe, R. Hatemata, T. Akiyama, ‘One-Pot Synthesis of Chiral Dehydroproline Esters: [3+2]-Type Cycloaddition Reaction of Allenylstannane and α-Imino Ester,’ Tetrahedron 2006, 62,11304-11310.
19) J. Itoh, K. Fuchibe, T. Akiyama, ‘Chiral Brønsted Acid-Catalyzed Enantioselective Aza-Diels-Alder Reaction of Brassard’s Diene with Imines,’ Angew. Chem. Int. Ed. 2006, 45, 4796-4798.
20) T. Akiyama, H. Morita, K. Fuchibe, ‘Chiral Brønsted Acid-Catalyzed Inverse Electron-Demand Aza Diels-Alder Reaction,’ J. Am. Chem. Soc. 2006, 128, 13070-13071.
21) K. Fuchibe, D. Ono, T. Akiyama, ‘Synthesis of Pyrroles: Reaction of Chromium N-Alkylaminocarbene Complexes with α,β-Unsaturated Aldehydes,’ Chem. Commun. 2006, 2271-2273.
22) T. Akiyama, T. Tamura, J. Itoh, H. Morita, K. Fuchibe, ‘Enantioselective Aza-Diels-Alder Reaction Catalyzed by a Chiral Brønsted Acid: Effect of the Additive on the Enantioselectivity,’ Synlett 2006, 141-143.
23) K. Fuchibe, T. Akiyama, ‘Low-Valent Niobium-Mediated Double Activation of C–F/C–H Bonds: Fluorene Synthesis from o-Arylated α,α,α-Trifluorotoluene Derivatives,’ J. Am. Chem. Soc. 2006, 128, 1434-1435.
24) T. Akiyama, S. Funaki, K. Fuchibe, ‘Stereoselective Synthesis of Tetrahydrofuran by Diastereoselective [3+2] Cycloaddition Reaction of Chiral Allylsilane with α-Keto Ester,’ Heterocycles, 2006, 369-374.
25) T. Akiyama, K. Fuchibe, J. Itoh, ‘Brønsted Acid-Catalyzed Addition and Cyclization Reaction with Imine: From Aqueous Reaction to Enantioselective Reactions,’ J. Synth. Org. Chem., Jpn., 2005, 63, 1062-1068.
26) K. Fuchibe, R. Hatemata, T. Akiyama, ‘Enantioselective Three-Component Synthesis of 4-Arylated Dehydroprolines: [3+2] Annulation of Allenylstannane and α-Imino Ester,’ Tetrahedron Lett. 2005, 46, 8563-8566.
27) T. Akiyama, Y. Saitoh, H. Morita, K. Fuchibe, ‘Enantioselective Mannich-type Reaction Catalyzed by a Brønsted Acid Derived from TADDOL,’ Adv. Synth. Catal. 2005, 347, 1523-1526.
28) T. Akiyama, K. Matsuda, K. Fuchibe, ‘HCl-catalyzed Stereoselective Mannich Reaction in H2O-SDS System’, Synlett, 2005, 322-324.
29) K. Daidouji, K. Fuchibe, T. Akiyama, ‘Cu(I)-Catalyzed Enantioselective [3+2] Cycloaddition Reaction of 1-Alkylallenylsilanewith α-Imino Ester: Chiral Synthesis of Pyrroline Derivatives,’ Org. Lett. 2005, 7, 1051-1053.
30) T. Akiyama, A. Suzuki, K. Fuchibe, ‘Mannich-type Reaction Promoted by an Ionic Liquid,’ Synlett, 2005, 1024-1026.
31) T. Akiyama, H. Morita, J. Itoh, K. Fuchibe, ‘Chiral Brønsted Acid-catalyzed Enantioselective Hydrophosphonylation of Imines: Asymmetric Synthesis of α-Amino Phosphonates,’ Org. Lett. 2005, 7, 2583-2585.
32) T. Akiyama, K. Matsuda, K. Fuchibe, ‘Montmorillonite K10-Catalyzed Nucleophilic Addition Reaction to Aldimines in Water (Special Topic: Aqueous Chemistry: Invited),’ Synthesis, 2005, 2606-2608.
33) K. Fuchibe, Yuji Aoki, T. Akiyama, ‘[3+2] Cycloaddition Reactions of Cyclopropylmethylsilanes and α-Keto Aldehydes: Trans- and Cis-selective Formation of 2-Silylmethyltetrahydrofurans,’ Chem. Lett. 2005, 34, 538-539.
34) K. Fuchibe, T. Akiyama, ‘Niobium-catalyzed Reduction of Monofluoroarenes with LiAlH4,’ Synlett 2004, 1282-1284.
35) T. Akiyama, J. Itoh, K. Yokota, K. Fuchibe, ‘Enantioselective Mannich-type Reaction Catalyzed by a Chiral Brønsted Acid,’ Angew. Chem. Int. Ed. 2004, 43, 1566-1568.
36) T. Akiyama, S. Nakashima, K. Yokota, K. Fuchibe, ‘Synthesis of Aryl-substituted Quinoline Derivatives via Bronsted Acid-Catalyzed [4+2] Aza Diels-Alder Reaction,’ Chem. Lett. 2004, 33, 922-923.
37) K. Sangu, K. Fuchibe, T. Akiyama, ‘A Novel Approach to 2-Arylated Quinolines: Electrocyclization of Alkynyl Imines via Vinylidene Complexes,’ Org. Lett. 2004, 6, 353-355.
38) T. Akiyama, K. Daidouji, K. Fuchibe, ‘Cu(I)-Catalyzed Enantioselective [2 + 2] Cycloaddition of 1-Methoxyallenylsilane with α-Imino Ester: Chiral Synthesis of α,β-Unsaturated Acylsilanes,’ Org. Lett. 2003, 5, 3691-3693.
39) T. Akiyama, M. Sanada, K. Fuchibe, ‘Brønsted Acid-mediated Synthesis of α-Amino Phosphonates under Solvent-free Conditions’, Synlett 2003, 1463-1464.
40) T. Akiyama, M. Hara, K. Fuchibe, S. Sakamoto, K. Yamaguchi, ‘Synthesis of a Novel Crown Ether Derived from Chiro-inositol and Its Catalytic Activity on the Asymmetric Michael Addition,’ Chem. Commun. 2003, 1734-1735.
41) T. Akiyama, S. Ogi, K. Fuchibe, ‘Stereoselective Synthesis of CF3-substituted Aziridines by Lewis Acid-mediated Aziridination of Aldimines with Diazoacetates,’ Tetrahedron Lett. 2003, 44, 4011-4013.
42) K. Fuchibe, N. Iwasawa, ’Generation of Reactive Species by One-electron Reduction of Fischer-type Carbene Complexes of Group 6 Metals and Their Use for Carbon-carbon Bond Formation,’ Chem. Eur. J. 2003, 9, 905-914.
43) T. Akiyama, K. Matsuda, K. Fuchibe, ‘Montmorillonite K10-catalyzed Aza-Diels-Alder Reaction of Danishefsky's Diene with Aldimines, Generated in situ from Aliphatic Aand an Amine, in Aqueous Media,’ Synlett 2002, 1898-1900.
44) K. Sangu, H. Kagoshima, K. Fuchibe, T. Akiyama, ‘Novel Thermal Reaction of Fischer Carbene Complexes with Imines: Synthesis of β-Methoxy Allylic Amine Derivatives,’ Org. Lett. 2002, 4, 3967-3969.
45) T. Akiyama, J. Itoh, K. Fuchibe, ‘Mannich-type Reaction Catalyzed by HBF4 in Water: Effect of the Loading of Surfactant,’ Synlett 2002, 1269-1272.
46) K. Fuchibe, N. Iwasawa, ‘Reactions of Novel Reactive Species Generated by Samarium(II)-mediated One-electron Reduction of Fischer-type Carbene Complexes,’ Org. Lett. 2000, 2, 3297-3299.
47) K. Fuchibe, N. Iwasawa, ‘A Novel Use of the Anions of Fischer-type Carbene Complexes as Alkenyl Metallic Species,’ Tetrahedron 2000, 56, 4907-4915.
48) N. Iwasawa, K. Fuchibe, ‘Synthesis of α-Methoxy-α,β-Unsaturated Esters by Iodine-oxidation of the Anions of Fischer-type Carbene Complexes,’ Chem. Lett. 1998, 1149-1150.
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