. . . .?

PVC/ | | chjin@lgchem.com

2

Phthalate

01

Phthalate. Phthalate

Phthalic Anhydride

. Phthalate Adipate,

Trimellitate, tere-Phthalate

Phthalate

.

Phthalate DEHP 1930

, , , ,

, , .

,

DINP

DBP

BBP .

DEHP DBP

Phthalate

. Phthalate

.

,

(EU) REACH, RoHS

.

Phthalate

.

Phthalate

.

02

1)

18 20

.

,

.

1960

, , ,

.

3LG POLYMER JOURNAL | 2016 SUMMER.

21

(Sustainable Development)

.

1987

(World Commission on Environment &

Development) Brundtland

.

, ,

.

(Quality of life),

(Integrated decision-making),

(Equity) .

,

.

, ,

,

. EU

REACH(Registration, Evaluation,

Authorization and Restriction of Chemicals),

WEEE(Waste Electrical and Electronic Equipment),

RoHS(Directive on the restriction of the use of

hazardous substances in electrical and electronic

equipment) . WTO

(Technical Barrier

to Trade)

.

1 | :

Protection

Dev

elop

men

t

Protection

Dev

elop

men

t

SustainableDevelopment

. . . .?4

2) REACH

?

- (Substance),

, , EU

?

- EU , 1

.

-(Substance, ) :

- (Preparation, ) :

- (Article) :

- (Polymer) :

(monomer units)

?

- EUREACH

(159 10)

- (SVHC) 161(14. 12/17)163

(15. 6/15)168(15. 12/17) /

4

, Phthalate Di-cyclohexyl

phthalate(DCHP, CAS No. 84-61-7)

? [ REACH ]

5LG POLYMER JOURNAL | 2016 SUMMER.

3) RoHS

?

- ,

,

No Substance Name CAS No. (mg/kg)

1 Dibutyl phthalate(DBP) 84-74-2 800

2 Bis(2-Ethylhexyl) phthalate(DEHP) 117-81-7 800

3 Benzyl butyl phthalate(BBP) 85-68-7 800

4 Diisobutyl phthalate(DIBP) 84-69-5 800

51,2-Benzenedicarboxylic acid, di-C7-11-branched

68515-42-4 1,000and linear alkyl esters(DHNUP)

61,2-Benzenedicarboxylic acid, diC6-8-branched alkyl

71888-89-6 1,000Esters, C7-rich(DIHP)

7 Bis(2-methoxyethyl) phthalate(BMP) 117-82-8 1,000

8 Diisopentyl phthalate(DIPP) 605-50-5 1,000

9 N-pentyl-isopentyl phthalate 776297-69-9 1,000

10 Di-n-pentyl phthalate(DPP) 131-18-0 1,000

11 Dihexyl phthalate 84-75-3 1,000

12 1,2-Benzenedicarboxylic acid, dihexyl ester, branched and linear 68515-50-4 1,000

1.2-Benzenedicarboxylic acid, di-C6-10-alkyl esters, 68515-51-5

13 1,2-benzenedicarboxylic acid, mixed decyl and hexyl and 68648-93-1

1,000

octyl diesters with 0.3% of dihexyl phthalate

14 Dicyclohexyl phthalate 84-61-7 1,000

15 Di-isononyl phthalate(DINP)28553-12-0

68515-48-0

16 Di-isodecyl phthalate(DIDP)26761-40-0 ()68515-49-1

17 Di-n-octyl phthalate(DNOP) 117-84-0

? REACH SVHC

. . . .?6

?

- WEEE(Waste electrical and electronic

equipment) 1,000V, 1,500V

, 8

?

?

- EU ,

EU RoHS

4) RoHS

?

- RoHS ,

,

?

- 811(No. 8, 9, 11 )

No

1 , , ,

2 , , ,

3 , , , ,

4 TV, , , ,

5 , , ()

6 , , , , ,

7 , , ,

8 ,,

No (mg/kg)

1 (Pb) 1,000

2 (Hg) 1,000

3 (Cd) 100

4 6(Cr 6+) 1,000

5 PBBs 1,000

6 PBDEs 1,000

No

1 , , ,

2 , , ,

3 , , , ,

4 TV, , , ,

5 , , ()

6 , , , , ,

7 , , ,

8 , ,

9 , ,

10 , ,

11

7LG POLYMER JOURNAL | 2016 SUMMER.

?

- 6104

?

- CE marking:

(DoC),

- : Corrective action,

,

5)

?

- 12

Phthalate

-

(16 2/12)

?

- Phthalate

(14 7/1)

?

- DMEP(Di-methoxyethyl phthalate)

(14 5/6)

- DBP, BBP,DEHP 0.1wt%

- DIDP,DINP, DNOP 0.1wt%

BBP, DBP, DEHP,DIDP, DNOP 0.1wt%

(mg/kg)

BBP, DBP, DEHP 1,000

(Class 1 phthalates)

4 DINP, DIDP, DNOP 1,000

(Class 2 phthalates)

No (mg/kg)

1 (Pb) 1,000

2 (Hg) 1,000

3 (Cd) 100

4 6(Cr 6+) 1,000

5 PBBs 1,000

6 PBDEs 1,000

7DEHP

1,000Bis(2-ethylhexyl) phthalate

8BBP

1,000Butyl benzyl phthalate

9DBP

1,000Dibutyl phthalate

10DIBP

1,000Diisobutyl phthalate

. . . .?8

?

- DEHP, DBP, BBP, DIBP

(13. 12/1)

- RoHS

(14 12/1)

?, ,

- Phthalate

03

EU

Phthalate

.

DEHP DINP

,

,

RoHS

.

Phthalate

Phthalate

.