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PP/PET 摻合物添加奈米二氧化矽之熱性質研究 指導老師:汪輝雄 學生姓名:黃皆穎 摘要 1 1. 前言 2 及表面硬度;而 PP 則能提高 PET 的加工、耐衝擊等性能。 3 1.5 實驗動機 聚丙烯因其為非極性脂肪族結構,且不含任何反應官能基,又具高度結晶 性,所以親水性不佳,不易染色。本研究採取高分子熔融摻合法,藉由聚丙烯接 枝馬來酸酐(PP-g-MA)為相容劑,使聚丙烯與聚酯熔融摻合,過程中並添加熱 塑性聚烯烴(TPO)為抗老化劑。此外,在摻合過程中添加二氧化矽,並探討其 熱性質。【8】 2.原理 4 (2) 聚酯 (Poly(ethylene terephthalate)﹐PET) 來源:新光合纖股份有限公司 熔點:253℃ 體系的聚合物卻是很多。換言之界面結合良好的海-島結構兩相體系在實際應用 價值大大高於均相體系。【10】 (4) 熱塑性聚烯烴 Thermoplastic Polyolefin (TPO) 來源:禾宏企業股份有限公司 3.實驗 5 (5) 二
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1
PP/PET
Study on the Thermal Properties of Polypropylene/Polyester blends Adding Nano Silica Dioxide
: :
PP/PET PP/PET (PP-g-MA) FTIR PP-g-MA PET TGA PP/PET/SiO2 2wt% DMA PP/PET/SiO2 DSC PP/PET/SiO2
ABSTRACT
In this experiment to investigate the different proportion of Silicon Dioxide on the PP / PET blends of thermal properties of the study. And polypropylene and polyester mainly to melt mixture of PP / PET blends , because of polypropylene and polyester are non-polar and compatibility was poor, so PP-g-MA was used as the compatibilizer, it is not easy mixing, it is necessary to use PP-g-MA to improve its compatibility. In consideration of FTIR, PP-g-MA would react with PET theoretically, but there is only a small portion, it looked like a physical blending. From TGA, it reached the highest temperature as 2wt% of SiO2 was added into PP/PET/SiO2. From DMA, the compatibility of blends was good. Form DSC, adding of SiO2 into PP/PET/SiO2, the crystallization temperature was increased.
2
1.
polyblend
1.1 1954Giulio Natta10.90~.091g/cm30.01%8~152HDPE3164~170100150-35-35
1.2 JR JT 1941 1948 PET 50 1966 PET,1976 PET PP PET PP
3
PP PET
1.3
1,2 PET PP PP/PET
PP-g-MA PP PP MA PET 1998 K. H. Yoon PET/PP PET/MAgPP MA SEM 31999 Michel F. Champagne PP-g-GMA 0.2 wt%1.2wt% PP-g-GMA PET/PP 42000 C.P. Papadopoulou N.K. Kalfoglou PET/PP PP-g-MA TPO PET/ PP TPO PP-g-MA PET 5
1.4 / 2006 Feng Yang
Gordon L. Nelson /PMMA/ PS PC /6Y. Lin M. Kontopoulou / PP-g-MA TPO PP/7
4
1.5 PP-g-MATPO8
2.
2.1 2.1.1 (1) (2) (3) (4) 9
2.1.2
5
10
3. 3.1 (1) (PolypropylenePP) 164
(2) (Poly(ethylene terephthalate)PET) 253
(3) (Polypropylene grafted Maleic AnhydridePP-g-MA) 163
(4) Thermoplastic Polyolefin (TPO)
6
(5) Alfa Aesar SiO2
(6) (Acetone) CH3COCH3
3.2 (1)
Brabender PL2000
(2)(thermoplastics)(thermosets)(elastomers)(roller)(screw)
2. (2)
FC60 TON
7
3.3
3.
SiO2 PET PP PP-g-MA TPO
1 265 50
SiO2
7
250 5
TGA FTIR DMA DSC
8
3.4 1.
PP(%) PET(%) PP-g-MA(%) TPO(%) SiO2(%) PP 100 0 0 0 0 S0 80 10 5 5 0 S1 80 10 5 5 1 S2 80 10 5 5 2 S3 80 10 5 5 3
PET 0 100 0 0 0
3.5 3.3(PP)(PET)
(80/10)(PP-g-MA)(TPO)(Brabender)265C50 rpmPET1PPPP-g-MATPOSiO27(FT-IR)(TGA)(DMA)(DSC)PP/PET
3.6 (1) (Thermogravimetry AnalysisTGA)
Du Pont Du Pont TGA 2050TA2000 10 600
100 cm3/min (2)(DMA)
Perkin Elmer DMA 7e -50 10/min 100
(3)(DSC) TA :DSC2920 30~200 10 /min
9
(4) Fourier Transform Infared, FTIR Shimadzu FTIR-8300 400 ~ 4700 cm-1 20
4. 4.1 FTIR
4 S0 FTIR PP29752950 cm-1 CH PET 17401715 cm-1 CO 900860 cm-1 CH 18411776 cm-1 CO TPO 29402915 cm-128702845 cm-114851445 cm-1 CH2 770690 cm-1 R1CH=CHR2
5 S FTIR 5 PP/PET/SiO2 11001000 cm-1
4. S FTIR
4000 3500 3000 2500 2000 1500 1000 500
T(%
)
Wavenumber(cm-1)
PP PET PP-g-MA TPO S0
10
5. S FTIR
2. 11
( cm-1 ) 29752950 CH3 CH 29402915 CH2 CH 18411776 CO 17301715 CO 14851445 CH2 CH 11001000 SiO2 OSi 900860 CH 770690 R1CH=CHR2 CH
4000 3 500 3000 2500 2000 1500 100 0 500
T(%)
W avenum ber(cm -1)
B 0 B 1 B 2 B 3 S iO 2
11
4.2(TGA) Tdi Tdt
TGA
6 PP/PET PP PET PET 7 S TGA 2 wt%
6. PPPETS0
7. S
12
3. PP/PET/SiO2 Tdi Tdt PP 300.30 469.18 S0 294.25 465.55 S1 299.70 472.11 S2 324.25 498.24 S3 302.72 498.24
PET 328.75 494.00
Tdi Tdt
4.3 (DMA) 8~ 13 PPPET S DMA PP PET
DMA Tg PET Tg S Tg
8. PP DMA
13
9. PET DMA
10. S0 DMA
14
11. S1 DMA
12.S2 DMA
15
13. S3 DMA
4. Tg Tg PP -12.11
S0 2.22 S1 2.07 S2 4.24 S3 4.65
PET 83.82
4.4 (DSC)
4.4.1 14 PP/PET DSC 15 S DSC
15 S
Tc 5
16
14. PP/PET PP/PET DSC
15. S DSC 4.4.2
16 PP/PET 17 S
17
17
12~14 Tm 5
16. PP/PET S0
17. S
18
5. Tm Tc
code Tm1() Tm2() Tc () PP 164.28 121.47
S0 163.29 253.72 119.29
S1 163.13 251.67 121.02
S2 163.57 251.26 121.99
S3 163.80 254.01 122.72
PET 253.00 210.85
5. 1. FTIR
PP/PETPP/PET/SiO2 PP-g-MA PET
2. TGA PP/PET PPPET PET PP/PET/SiO2 2wt%
3. DMA PP/PET Tg
4. PP/PET/SiO2
19
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