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第八章 合成树脂及塑料 synthetic resin and Plastics

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第八章 合成树脂及塑料 synthetic resin and Plastics. 学习目的与要求   掌握塑料的分类、性能及应用;掌握 PE 、 PMMA 、 PVC 、 PS 、 ABS 树脂、酚醛树脂、环氧树脂、聚氨酯树脂等生产工艺技术、结构、性能及应用。. 天然树脂 → 天然橡胶、树胶、虫胶、琥珀等. 树脂按来源分类. 合成树脂 → 由单体合成或天然高聚物改性获得. § 8-1  塑料的分类与应用. 树脂 (resin) 是指遇热变软,具有可塑性的天然高分子化合物的统称。一般是无定型的透 明或半透明的固体或半固体。 树脂的用途 - PowerPoint PPT Presentation

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  • synthetic resin and PlasticsPEPMMAPVCPSABS

  • 8-1(resin)

    20009MtLDPE795ktLLDPD834ktHDPE1.11MtPP2.666MtPVC2.3MtPSABS1.5Mt200017Mt

  • 8-1(plastics)

  • 8-1

  • 8-1

    2000150Mt18Mt13%50Mt44.4%15Mt10%

  • 8-2polyethylenePE20%200048Mt3.23Mt2.75Mt

    MPa 98.1-245.2150-3302-7125-150260-%16-27100100 0.910-0.92550 0.926-0.9400.941-0.97078

  • 8-2CH2CH2

    -103.8 28.05169.4103.80.56999.90MPakJ/mol%4.97537953.02-34

  • 8-214.7-245.2MPa150-290 99.9%

    %cm3/cm3 cm3/cm3CO cm3/cm3 cm3/cm399.9500.10.50.5CO2H2SH2SH2O0.50.50.10.1

  • 8-20.003%-0.007%1%-25%230 150 108-245MPa16%-27%95%40-160-280

  • 8-210000-50000100000MI

    1.18MPa12329.43MPa4567113196.20MPa89

    20.96.424000280001.80.2532000480000.0050.001530007600

  • 8-2

  • 8-2101124.5329.43MPa4514111249.1kPa1315161718192021222324

  • 8-225

    108-245.2MPa130-280 10%10-120s323.6MPa330 30%60-300

  • 8-2CrO3-Al2O3-SiO2150 4.9MPaMOO3-Al2O3-200-2606.87MPaCrO3Al2O3-SiO22%-3%9010

  • 8-2C5-C125509010013015017020401001401101201401606080120

  • 8-240000 0.2%0.6%123.43MPa10037MPa

  • 8-24145620TiCl4TICl36075

  • 8-2

    %%%%%%%%990.0210.00020.00010.00050.00050.001NONO2%N2O%%%O2%CO2%CO%0.00050.00020.00020.00050.00050.00020.0002

    %C2C2CH4C2CO2COO2H2O1234599.07

    99.499.00.47

    0.580.00484

    0.015240.0002

    0.001140.46240.003

    0.005620.00230.00020.0027

    0.00010.00077

  • 8-2Al/Ti11-120.5-1.0g/L

  • 8-260-70 0-981kPaAl(C2H5)3-TiCl460750981kPa

  • 8-2

  • 8-2CH2CH210001520250005000050%60%0.910.93115450005000085%350000100000080%0.920.97127HDPELDPEUHMWPELLDPE-EVACPE

  • 8-20.01%17.4 LDPELLDPEHDPELDPELLDPEHDPELLDPE

  • 8-2501402024105/K6060100

  • 8-2

    LDPEHDPE300LLDPE20%30%200215LLDPE

  • 8-2

    ,g/10minLDPELLDPEHDPE0.3~8.00.1~1.01.4 ~2.50.1 ~5.00.3 ~0.50.2 ~0.41.5 ~5020 ~2000.75 ~200.3 ~3.30.1 ~1.62.5 ~4.01.0 ~2.00.2 ~2.00.3 ~1.00.4 ~1.02.3 ~503.3 ~111.0 ~250.5 ~8.03.0 ~6.0.25 ~1.20.1 ~5.00.2 ~1.50.5 ~8.02.0 ~205.0 ~103.0 ~20

  • 8-2

    LDPE50%

    HDPE10%LLDPE70%HDPE30%LDPE10%LLDPE10%HDPEHDPEHDPEHDPELLDPELDPEHDPELLDPELDPE

  • 8-3polymethyl methacrylatePMMA

    10048.8100.60.936 kJ/mol%101.411856.52.12-12.5

  • 8-3

    PMMA

  • 8-3

    PMMA

  • 8-35%98.5%7585510min909215min8415min182012%MMAPMMA20%22%

  • 8-3

    4mm

    56mm820mm

    2050mm

  • 8-3

    12h20mm35503038h6510035h4565

  • 8-315o20o851003545406090100607010080

  • 8-3N270801.2m10mm6h50mm24hN2200300MMAPMMA1002000.085%20NaHPO412H2O10

  • 8-3NaHPO412H2O40min8251h9340min651%

    PMMA1000.736000.0360.1%25.740120120

  • 8-370%75%90%92%1.4917.380

  • 8-3PEPS1802302600.02%

  • 8-31001104h70802h30mm85

  • 8-4PVC206060PVCPVCPVC5001500170080%85%PVCPVC

  • 8-4PVC

    CH2CHCl 4%22%

    KSG-1SG-2SG-3SG-4SG-5SG-6SG-7XSJ-1XSJ-2XSJ-3XSJ-4XSJ-5XSJ-677757573737171696866656362601541441431361351271261181171071069695851800165016501500150013501350120011501000950850850750

  • 8-475%10cm3/m3 1.44D

    //MPa/ / 62.5-13.85.59156.5-78/%() //(kJ/mol)422 -153.61.3895.6

  • 8-4--

  • 8-4 PVC300%0.1%0.0005% 99.9%8-16

  • 8-4

    %%%0.00020.00020.00020.00021--3-0.000100.00010.005HCl00.00001

    PH%0.57.00.00001SiO2%SiO3%000.00001%%00

  • 8-4

    % ABCDE0.050.050.050.020.15050505555

    % A0.020.0255

    B0.020.250C0.020.0355D0.020.250

  • 8-4

    I%Nr10.1mol/tPVCAIBN0.9DCPDEHP1.1Mt(h) t1/2h510ht1/223ht1/212ht1/246h

  • 8-4-0.05%0.2% 7590%11.111.3

  • 8-411.412.0 [ CH2CHClOO ]n pHpH78HClpH

  • 8-4R14.739.2MPaC6C200.50.2

  • 8-410050700.050.50.020.300.100.0025058PVC0.6870.981MPa0.2940.196MPa812h90% NaOH36%42%0.05%0.2%70801.52.0h

  • 8-48%15%15%20%4015015m/s1.2s4%12012min0.3%8-24

  • 8-4

  • 8-450580.560%70%0.687-0.981MPa0.2940.196MPa 36%42%NaOH0.05%0.2%70801.52.0h65 70801401504%1200.3%

  • 8-4PVC

    MSTA

  • 8-4AABABB-30%0.2%8-18 33m3127m3200m3

  • 8-4

    m313.533LF-308033127714mm61505400500050005400790030503700mm16002600260040002600420016002000 3.852.081.921.252.081.881.91.85m234.5525090529017.528m22820161516m2/m32.551.581.121.851.122.5233233645O33-45-68U83124

  • 8-4

    LHDV30M3L/D30M3L/D L/D L/D1.5-4

  • 8-4A/Vm2/m3L/D1.2A4.77V0.6514m350m373%

  • 8-4

    K

    1 1111

  • 8-4 22 5825820 W/(m2K)223263489W/(m2K)22582698 W/(m2K) 2221163 W/(m2K)23m/s2[3489-5819W/(m2K)]

  • 8-42

    11512 W/(m2K)21745 W/(m2K)10.1mm23mm315mm40.4mm10.16 W/(m.K) 217 W/(mK) 352 W/(mK) 41.7 W/(mK) K391W/(m2K)25.84%51.77%24.4%6.8%11.27%9.3%22.39%

  • 8-410mmK516.9312mmK399.740mmK430.2

  • 8-4301215581535

  • 8-4 8-29dpmaxdpmaxdpmix dpmax dpmix dpmaxdpmix

  • 8-4dpmax PE5%~15%

  • 8-41.35~1.451500~3000MPa1.5~15MPa200%~450%0.4~0.50.2314018016045

  • 8-4PEPP 50250m3070m12m0.11m160160190

  • 8-416014011011.5h110

  • 8-4

  • 8-5ABS1939ABSCH2CH30.60.9019145.21.5463313734.1MPa

  • 8-5ABS

    3025/ cPApHA/ %/ %/ %/ kJ/mol0.8970.751.54351.5445150.00199.70.0269.9/ %/ % / %(H2O2)/ %/ %-/ %/ %0.0050.0050.00050.0010.10.050.00050.0010.0015

  • 8-5ABS10%50%300360r/min80

  • 8-5ABS607030%35%6m0.8m10011010011015015018018020095%3%4%8-2611512045h50%14020034h97%98%8-325%20%10%

  • 8-5ABSS3h11%7h37%4h85%10% 11512050%PS14020097%98%PS 110115110115 130 135 140

    16511%15%PS35%40%PS85%90%PS

  • 8-5ABS

    11.411.690%80%10%20%99.5%5%NaOH3490%

  • 8-5ABS

    906h11013523h0.3MPa6089hHCl2%3%800.05% 20104

  • 8-5ABSMgCO3Na2CO3 MgSO4-

  • 8-5ABS6016%Na2CO378MgSO40.5h752.7104Pa2,6-90N20.15MPa1500..6MPa2h1550.70.75MPa2h1250.5h1404h98%H2SO4pH34 PS PSPS

  • 8-5ABS PSPSSPS106GyPSPS0.05%PEPS88%~92%PCPMMAPS1.59~1.60

  • 8-5ABSPSPS60MPaPSPS PS70~9060~80PS-30PS0.04~0.13W/(mK)(6~8)10-5K-1PS PS()()PS

  • 8-5ABSPS PS120~180300PSPSPS()70~801.5hPS65~851~3hPS0.4%~0.7%PS

  • 8-5ABS PSPS PSABSABS--

  • 8-5ABS--20%30%20%40%6570-150200303535%15018020min1501701.3713.7MPaABS6280-826826ABS

  • 8-5ABSABS

  • 8-5ABSABS10018050.561075% 3030050200.50.50.150CaCl2ABSABS ABSABSABSABS

  • 8-5ABSABSABS90%ABS1.05ABSABS18.2 ABSABSABSABSPSFPCPAPOMABSABS ABS93~11810ABS-40-40~100 ABS ABS

  • 8-5ABSABSABS ABSPS ABSPVCPCPEPAPSPOMHIPSABS ABSABS80~852~4h()70~8018~18hABS70~802~4h ABS

  • 8-5ABS ABS 7 7

  • 8-5ABS-2%7%-1.01.2mm CHCH2CHCH2CHCH2-

  • 8-5ABS 0.4%-98%801207hpH5

  • 8-5ABS-ZnCl238402530h15%NaOH

  • 8-5ABS

    CH3CH2ClZnCl2N(CH3)3

  • 8-6PF

  • 8-665OH94.111821.07140.9 37%

  • 8-660%70% 31.03210.81592 116576

  • 8-6

    n412

  • 8-61 100 26.527.5 pH1.62.30.056 1.52.0

  • 8-6

    5minpH1.62.3556595980246820406080100120habcdef

  • 8-6 20min45min1.151.1853.3kPa9510520min

  • 8-6254120mm2330%0.25

  • 8-6 2167 CH2OCH2OHCH2O

  • 8-6

    CH2OH26-24-CH2OHOCH2CH2OH246-

  • 8-6

  • 8-6

  • 8-6211PFPFPF

  • 8-6PF100PF5%24.5105/KPF

    %0.05 0.20.2 0.40.5 0.60.3 0.50.6 0.81 1.4

  • 8-6PFSIPF160140160180 2PF2E 200B

  • 8-6

  • 8-7EPAFSA92.5325.61.43585115.21.1801

  • 8-7AAA228.3150155220 A AA1A21

  • 8-711 NaOH30%10%ANaOHAA2AA505546h657034h-

  • 8-7

    -

  • 8-73 5001500A859534h4A1

  • 8-76%8%8%10%14%16%DOPDBP15%5%20%DOPDBP5%20%PA200%2EPEP EPEP60EP250PA

  • 8-7EP90EP200 EP EP101415cm2.5831024.03 EP 3

  • 8-8PUPUR 1TDI2,42,680/20TDI-8065/35TDI-65MDIPAPIPU0.0002% NCO

  • 8-8

    2

    24TDI-65TDI-8024%26%%65 2.5 99.5 21246-2471.56541.2265 235 2 99.54-6246-2471.56661.2280 220 2 99.512-14246-2471.56631.22

  • 8-8

  • 8-8

    10003000

  • 8-8PUPUN-1

  • 8-8

  • 8-8

  • 8-8 21500mgKOH/g1001001.5301.00.5AB0.0331.04%0.2kg/m22.57105N/m2-601200.92W/(mK)

  • 8-82475495mgKOH/g100 TDI30%NCO141.60.41.425

    30%NCO45min24h 0.030.042%0.20.4kg/m222.6104N/m2-837012W/(mK) 95%

  • 8-83156mgKOH/g100TDI37.50.10.31.02.00.20.50.20.6122.70.0350.045150%35% 9.81104N/m215%2.94104N/m2 2-56mkKOH/g100TDI1.052.8-8030.10.20.20.4

  • 8-815s45s6070s1002h0.0360.042250%400%25%1.76105N/m28%50%7.8103N/m2 200300/cm2 4PUPUPUPUPU

  • 8-8PUNCO/OH11.0280MDI601,4-10118 0.20.50.510.20.7015140601525min10.020.04

  • 8-890%5%15%0.0080.025W/(mK)200150 11

  • 8-8PU2PUPUPU3PU6%8%

  • 8-8