(2013-II) 2da Practica - CuCO3 (Funda II)

7/24/2019 (2013-II) 2da Practica - CuCO3 (Funda II)

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Cu(+2a) + H2CO3(a) = CuCO3 + 2H(+a)

T K

C kJ J/K kJ

0 35.849 -11.291 38.933 3.583E-008

5 36.514 -8.877 38.983 4.771E-008

10 37.106 -6.765 39.022 6.320E-008

15 37.644 -4.883 39.051 8.325E-008

20 38.142 -3.170 39.071 1.090E-007

25 38.612 -1.579 39.083 1.420E-007

30 39.065 -0.073 39.087 1.839E-007

35 39.508 1.376 39.084 2.368E-007

40 39.947 2.790 39.073 3.033E-007

45 40.386 4.182 39.056 3.865E-007

50 40.828 5.559 39.032 4.901E-007

55 41.273 6.926 39.000 6.186E-007

60 41.720 8.279 38.962 7.773E-007

65 42.173 9.628 38.918 9.724E-007

70 42.636 10.985 38.866 1.211E-006

75 43.108 12.353 38.808 1.503E-006

80 43.592 13.733 38.743 1.858E-006

85 44.089 15.129 38.670 2.289E-006

90 44.599 16.543 38.591 2.810E-006

95 45.124 17.979 38.505 3.438E-006

100 45.665 19.439 38.411 4.194E-006

Cu(+2a) + HCO3(-a) = CuCO3 + H(+a)

T K

C kJ J/K kJ

0 24.615 72.640 4.773 1.222E-001

5 25.698 76.571 4.400 1.492E-001

10 26.626 79.878 4.009 1.821E-001

15 27.435 82.710 3.602 2.223E-001

20 28.156 85.190 3.182 2.710E-001

25 28.813 87.414 2.751 3.297E-001

30 29.428 89.461 2.308 4.002E-001

35 30.017 91.387 1.856 4.845E-001

40 30.592 93.236 1.395 5.853E-001

45 31.160 95.037 0.924 7.052E-001

50 31.727 96.806 0.444 8.476E-001

55 32.294 98.548 -0.044 1.016E+000

60 32.861 100.261 -0.541 1.216E+000

65 33.433 101.966 -1.047 1.451E+000

70 34.018 103.684 -1.561 1.728E+000

75 34.619 105.421 -2.084 2.054E+000

80 35.237 107.183 -2.615 2.437E+000

85 35.874 108.975 -3.155 2.886E+000

90 36.533 110.803 -3.705 3.412E+000

H S G

H S G


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95 37.217 112.672 -4.264 4.027E+000

100 37.927 114.590 -4.832 4.747E+000

CuOH(+a) + HCO3(-a) = CuCO3 + H2O

T K

C kJ J/K kJ

0 -27.281 50.148 -40.979 6.871E+007

5 -20.430 75.200 -41.347 5.826E+007

10 -19.663 77.933 -41.730 4.999E+007

15 -18.954 80.417 -42.126 4.336E+007

20 -18.285 82.718 -42.534 3.798E+007

25 -17.644 84.887 -42.953 3.356E+007

30 -17.019 86.965 -43.383 2.990E+007

35 -16.403 88.983 -43.823 2.685E+007

40 -15.787 90.963 -44.272 2.429E+007

45 -15.170 92.920 -44.732 2.212E+007

50 -14.546 94.863 -45.202 2.028E+007

55 -13.917 96.796 -45.681 1.871E+007

60 -13.283 98.715 -46.170 1.736E+007

65 -12.639 100.631 -46.668 1.620E+007

70 -11.983 102.558 -47.176 1.520E+007

75 -11.313 104.498 -47.694 1.433E+007

80 -10.627 106.454 -48.221 1.358E+007

85 -9.924 108.430 -48.758 1.293E+007

90 -9.203 110.429 -49.305 1.237E+007

95 -8.462 112.456 -49.862 1.189E+007

100 -7.699 114.514 -50.430 1.148E+007

Cu(OH)3(-a) + HCO3(-a) + 2H(+a) = CuCO3 + 3H2O

T K

C kJ J/K kJ

0 -135.635 14.145 -139.499 4.772E+026

5 -114.797 90.341 -139.925 1.902E+026

10 -112.040 100.166 -140.402 7.999E+025

15 -109.324 109.673 -140.926 3.537E+025

20 -106.635 118.925 -141.498 1.640E+025

25 -103.960 127.973 -142.115 7.945E+024

30 -101.289 136.858 -142.777 4.013E+024

35 -98.613 145.612 -143.484 2.109E+024

40 -95.928 154.257 -144.233 1.150E+024

45 -93.228 162.810 -145.026 6.497E+023

50 -90.512 171.281 -145.861 3.796E+023

55 -87.778 179.675 -146.739 2.289E+023

60 -85.028 187.992 -147.658 1.423E+023

65 -82.258 196.245 -148.619 9.105E+022

70 -79.464 204.447 -149.620 5.988E+022

75 -76.646 212.601 -150.663 4.042E+022

H

S

G

H

S

G


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80 -73.802 220.713 -151.746 2.797E+022

85 -70.930 228.786 -152.870 1.983E+022

90 -68.031 236.826 -154.034 1.438E+022

95 -65.102 244.837 -155.238 1.066E+022

100 -62.142 252.823 -156.482 8.067E+021

Cu(OH)3(-a) + CO3(-2a) + 3H(+a) = CuCO3 + 3H2O

T K

C kJ J/K kJ

0 -158.170 135.048 -195.058 2.014E+037

5 -135.427 218.153 -196.107 6.769E+036

10 -130.976 234.015 -197.237 2.448E+036

15 -126.732 248.875 -198.445 9.469E+035

20 -122.640 262.952 -199.725 3.897E+035

25 -118.658 276.422 -201.074 1.699E+035

30 -114.750 289.423 -202.488 7.815E+03435 -110.886 302.063 -203.967 3.780E+034

40 -107.047 314.421 -205.508 1.916E+034

45 -103.218 326.553 -207.111 1.016E+034

50 -99.391 338.490 -208.774 5.616E+033

55 -95.562 350.248 -210.496 3.231E+033

60 -91.734 361.825 -212.276 1.930E+033

65 -87.894 373.266 -214.114 1.195E+033

70 -84.030 384.608 -216.008 7.651E+032

75 -80.140 395.863 -217.960 5.061E+032

80 -76.219 407.045 -219.967 3.453E+03285 -72.265 418.164 -222.030 2.425E+032

90 -68.272 429.233 -224.148 1.753E+032

95 -64.239 440.264 -226.322 1.301E+032

100 -60.160 451.270 -228.551 9.906E+031

Cu(OH)4(-2a) + CO3(-2a) + 4H(+a) = CuCO3 + 4H2O

T K

C kJ J/K kJ

0 -214.230 219.222 -274.110 2.646E+052

5 -184.637 327.377 -275.697 6.003E+051

10 -179.334 346.276 -277.382 1.496E+051

15 -174.228 364.151 -279.158 4.064E+050

20 -169.267 381.221 -281.022 1.196E+050

25 -164.406 397.663 -282.970 3.795E+049

30 -159.610 413.617 -284.998 1.291E+049

35 -154.850 429.190 -287.105 4.692E+048

40 -150.106 444.461 -289.289 1.814E+048

45 -145.363 459.487 -291.549 7.435E+047

50 -140.613 474.301 -293.884 3.221E+047

55 -135.853 488.918 -296.292 1.470E+047

60 -131.086 503.337 -298.773 7.056E+046

H

S

G

H S G


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65 -126.298 517.604 -301.325 3.549E+046

70 -121.477 531.755 -303.949 1.867E+046

75 -116.620 545.805 -306.643 1.025E+046

80 -111.725 559.766 -309.407 5.866E+045

85 -106.787 573.650 -312.240 3.489E+045

90 -101.803 587.471 -315.143 2.154E+045

95 -96.768 601.240 -318.115 1.378E+045

100 -91.679 614.971 -321.155 9.120E+044


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[H(+a)] pH H2CO3(a)/HCO3(-a)/CO3(-2a)

Log(K) 1.00E+00 0.0 0.001

3.16E-01 0.5 0.001

-7.446 1.00E-01 1.0 0.001

-35.333 3.16E-02 1.5 0.001

-7.199 1.00E-02 2.0 0.001

-7.080 3.16E-03 2.5 0.001

-6.962 1.00E-03 3.0 0.001

-6.848 3.16E-04 3.5 0.001

-6.736 1.00E-04 4.0 0.001

-6.626 3.16E-05 4.5 0.001

-6.518 1.00E-05 5.0 0.001

-6.413 3.16E-06 5.5 0.001

-6.310 1.00E-06 6.0 0.001

-6.209 3.16E-07 6.5 0.001

-6.109 1.00E-07 7.0 0.001

-6.012 3.16E-08 7.5 0.001

-5.917 1.00E-08 8.0 0.001

-5.823 3.16E-09 8.5 0.001

-5.731 1.00E-09 9.0 0.001

-5.640 3.16E-10 9.5 0.001

-5.551 1.00E-10 10.0 0.001

-5.464 3.16E-11 10.5 0.001

-5.377 1.00E-11 11.0 0.001

3.16E-12 11.5 0.001

1.00E-12 12.0 0.001

Log(K) 3.16E-13 12.5 0.001

1.00E-13 13.0 0.001

-0.913 3.16E-14 13.5 0.001

-0.826 1.00E-14 14.0 0.001

-0.740 3.16E-15 14.5 0.001

-0.653 1.00E-15 15.0 0.001

-0.567 3.16E-16 15.5 0.001

-0.482 1.00E-16 16.0 0.001

-0.398 3.16E-17 16.5 0.001

-0.315 1.00E-17 17.0 0.001

-0.233 3.16E-18 17.5 0.001

-0.152 1.00E-18 18.0 0.001

-0.072 3.16E-19 18.5 0.001

0.007 1.00E-19 19.0 0.001

0.085 3.16E-20 19.5 0.001

0.162 1.00E-20 20.0 0.001

0.238

0.313

0.387

0.460

0.533Dia


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0.605

0.676

Log(K)

7.837

7.765

7.699

7.637

7.580

7.526

7.476

7.429

7.385

7.345

7.307

7.272

7.240

7.209

7.182

7.156

7.133

7.112

7.093

7.075

7.060

Log(K)

26.679

26.279

25.903

25.549

25.215

24.900

24.603

24.324

24.061

23.813

23.579

23.360

23.153

22.959

22.777

22.607

0 1 2

0%

5%

10%

15%

20%

25%30%

35%

40%

45%

50%

55%

60%

65%

70%

75%

80%

85%

90%

95%

# Co!e$ra!i%

0 1 2 3 4 5

-35

-30

-25

-20

-15

-10

-5

0

D

ogCuT*


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22.447

22.297

22.158

22.028

21.907

Log(K)

37.304

36.831

36.389

35.976

35.591

35.230

34.89334.577

34.282

34.007

33.749

33.509

33.286

33.077

32.884

32.704

32.53832.385

32.244

32.114

31.996

Log(K)

52.423

51.778

51.175

50.609

50.078

49.579

49.111

48.671

48.259

47.871

47.508

47.167

46.849

-60

-55

-50

-45

-40

0 1 2 3 4

1.000E-059

1.000E-055

1.000E-051

1.000E-047

1.000E-043

1.000E-039

1.000E-035

1.000E-031

1.000E-027

1.000E-023

1.000E-019

1.000E-015

1.000E-011

1.000E-007

1.000E-003

1.000E+001

ogCuT*


8/88

46.550

46.271

46.011

45.768

45.543

45.333

45.139

44.960


9/88

[Cu(+2a)] [CuOH(+a)] [Cu(OH)3(-a)] [Cu(OH)4(-2a)] [CuT]

7.043E+009 2.980E-005 1.2587130E-022 2.63494657E-047 7.043E+009

7.043E+008 2.980E-005 1.2587130E-021 2.63494657E-045 7.043E+008

7.043E+007 2.980E-005 1.2587130E-020 2.63494657E-043 7.043E+007

7.043E+006 2.980E-005 1.2587130E-019 2.63494657E-041 7.043E+006

7.043E+005 2.980E-005 1.2587130E-018 2.63494657E-039 7.043E+005

7.044E+004 2.980E-005 1.2587130E-017 2.63494657E-037 7.044E+004

7.046E+003 2.980E-005 1.2587131E-016 2.63494657E-035 7.046E+003

7.053E+002 2.980E-005 1.2587132E-015 2.63494657E-033 7.053E+002

7.073E+001 2.980E-005 1.2587136E-014 2.63494657E-031 7.073E+001

7.139E+000 2.980E-005 1.2587149E-013 2.63494657E-029 7.139E+000

7.346E-001 2.980E-005 1.2587189E-012 2.63494657E-027 7.347E-001

8.002E-002 2.980E-005 1.2587316E-011 2.63494657E-025 8.005E-002

1.008E-002 2.980E-005 1.2587719E-010 2.63494657E-023 1.011E-002

1.664E-003 2.980E-005 1.2588991E-009 2.63494657E-021 1.693E-003

3.738E-004 2.980E-005 1.2593016E-008 2.63494657E-019 4.036E-004

1.030E-004 2.980E-005 1.2605743E-007 2.63494657E-017 1.329E-004

3.104E-005 2.980E-005 1.2645991E-006 2.63494657E-015 6.210E-005

9.663E-006 2.980E-005 1.2773264E-005 2.63494657E-013 5.223E-005

3.040E-006 2.980E-005 0.0001317574 2.63494657E-011 1.646E-004

9.600E-007 2.980E-005 0.0014448465 2.63494657E-009 1.476E-003

3.034E-007 2.980E-005 0.0184731867 2.63494657E-007 1.850E-002

9.593E-008 2.980E-005 0.3120047533 2.63494657E-005 3.121E-001

3.033E-008 2.980E-005 7.1447695854 0.0026349466 7.147E+000

9.593E-009 2.980E-005 198.72058221 0.2634946575 1.990E+002

3.033E-009 2.980E-005 6011.92787479 26.349465747 6.038E+003

9.592E-010 2.980E-005 187392.165104 2634.946574696 1.900E+005

3.033E-010 2.980E-005 5898643.70373 263494.6574696 6.162E+006

9.592E-011 2.980E-005 186259323.393 26349465.74696 2.126E+008

3.033E-011 2.980E-005 5887315286.63 2634946574.696 8.522E+009

9.592E-012 2.980E-005 186146039222 263494657469.6 4.496E+011

3.033E-012 2.980E-005 5886182444917 26349465746958 3.224E+013

9.592E-013 2.980E-005 1.861347E+014 2.6349466E+015 2.821E+015

3.033E-013 2.980E-005 5.886069E+015 2.6349466E+017 2.694E+017

9.592E-014 2.980E-005 1.861336E+017 2.6349466E+019 2.654E+019

3.033E-014 2.980E-005 5.886058E+018 2.6349466E+021 2.641E+021

9.592E-015 2.980E-005 1.861335E+020 2.6349466E+023 2.637E+023

3.033E-015 2.980E-005 5.886057E+021 2.6349466E+025 2.636E+025

9.592E-016 2.980E-005 1.861335E+023 2.6349466E+027 2.635E+027

3.033E-016 2.980E-005 5.886057E+024 2.6349466E+029 2.635E+029

9.592E-017 2.980E-005 1.861335E+026 2.6349466E+031 2.635E+031

3.033E-017 2.980E-005 5.886057E+027 2.6349466E+033 2.635E+033

rama de Predomia!ia


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3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

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7 8 9 10 11 12 13 14 15 16 17 18 19 20

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5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20iagrama de &'errum

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[Cu(+2a)]/[CuT] [CuOH(+a)]/[CuT] [Cu(OH)3(-a)]/[CuT] [Cu(OH)4(-2a)]/[CuT]

1.000E+000 4.231E-015 1.787E-032 3.741E-057

1.000E+000 4.231E-014 1.787E-030 3.741E-054

1.000E+000 4.231E-013 1.787E-028 3.741E-051

1.000E+000 4.231E-012 1.787E-026 3.741E-048

1.000E+000 4.231E-011 1.787E-024 3.741E-045

1.000E+000 4.230E-010 1.787E-022 3.741E-042

1.000E+000 4.229E-009 1.786E-020 3.740E-039

1.000E+000 4.225E-008 1.785E-018 3.736E-036

1.000E+000 4.213E-007 1.780E-016 3.725E-033

1.000E+000 4.174E-006 1.763E-014 3.691E-030

1.000E+000 4.056E-005 1.713E-012 3.587E-027

9.996E-001 3.722E-004 1.572E-010 3.292E-024

9.971E-001 2.948E-003 1.246E-008 2.607E-021

9.824E-001 1.760E-002 7.434E-007 1.556E-018

9.261E-001 7.383E-002 3.120E-005 6.529E-016

7.748E-001 2.242E-001 9.486E-004 1.983E-013

4.998E-001 4.798E-001 2.036E-002 4.243E-011

1.850E-001 5.705E-001 2.445E-001 5.045E-009

1.847E-002 1.810E-001 8.005E-001 1.601E-007

6.505E-004 2.019E-002 9.792E-001 1.786E-006

1.640E-005 1.610E-003 9.984E-001 1.424E-005

3.074E-007 9.549E-005 9.998E-001 8.444E-005

4.244E-009 4.169E-006 9.996E-001 3.687E-004

4.821E-011 1.497E-007 9.987E-001 1.324E-003

5.024E-013 4.935E-009 9.956E-001 4.364E-003

5.048E-015 1.568E-010 9.861E-001 1.387E-002

4.923E-017 4.836E-012 9.572E-001 4.276E-002

4.512E-019 1.402E-013 8.761E-001 1.239E-001

3.559E-021 3.496E-015 6.908E-001 3.092E-001

2.133E-023 6.627E-017 4.140E-001 5.860E-001

9.410E-026 9.244E-019 1.826E-001 8.174E-001

3.400E-028 1.056E-020 6.598E-002 9.340E-001

1.126E-030 1.106E-022 2.185E-002 9.781E-001

3.615E-033 1.123E-024 7.014E-003 9.930E-001

1.149E-035 1.128E-026 2.229E-003 9.978E-001

3.638E-038 1.130E-028 7.059E-004 9.993E-001

1.151E-040 1.131E-030 2.233E-004 9.998E-001

3.640E-043 1.131E-032 7.064E-005 9.999E-001

1.151E-045 1.131E-034 2.234E-005 1.000E+000

3.640E-048 1.131E-036 7.064E-006 1.000E+000

1.151E-050 1.131E-038 2.234E-006 1.000E+000

Diagram


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u(+2a)]/[CuT]

uOH(+a)]/[CuT]

u(OH)3(-a)]/[CuT]

u(OH)4(-2a)]/[CuT]

0 1 2 3 4 5 6 7 8

-55

-50

-45

-40

-35

-30

-25

-20

-15

-10

-5

0

5

10

1520

25

30

35

40

ogCuT*

0 1 2 3 4 5 6 7 8

10

15

20

25

30

35

Diagram

ogCuT*

u(+2a)]

uOH(+a)]

u(OH)3(-a)]

u(OH)4(-2a)]


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-10

-5

0

5

7

-5

-4

-3

Diagram

ogCuT*

[Cu(+2a)]

[CuOH(+a)]

[Cu(OH)3(-a)]

[Cu(OH)4(-2a)]


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log[CuT] log[Cu(+2a)] log[CuOH(+a)] log[Cu(OH)3(-a)] log[Cu(OH)4(-2a)]

9.8477527993 9.8477527993 -4.5258152172 -21.9000732783 -46.579228186

8.8477532038 8.8477532038 -4.5258152172 -20.9000732783 -44.579228186

7.8477544828 7.8477544828 -4.5258152172 -19.9000732781 -42.579228186

6.8477585274 6.8477585274 -4.5258152172 -18.9000732777 -40.579228186

5.8477713171 5.8477713171 -4.5258152172 -17.9000732763 -38.579228186

4.8478117595 4.8478117593 -4.5258152172 -16.9000732719 -36.579228186

3.847939626 3.8479396241 -4.5258152172 -15.900073258 -34.579228186

2.8483437389 2.8483437206 -4.5258152172 -14.9000732141 -32.579228186

1.8496192997 1.8496191168 -4.5258152172 -13.9000730752 -30.579228186

0.8536296124 0.8536277996 -4.5258152172 -12.9000726361 -28.579228186

-0.1339161755 -0.133933791 -4.5258152172 -11.9000712475 -26.579228186

-1.0966307693 -1.0967924585 -4.5258152172 -10.9000668562 -24.579228186

-1.9954153638 -1.9966977751 -4.5258152172 -9.9000529701 -22.579228186

-2.7712561113 -2.7789668004 -4.5258152172 -8.9000090613 -20.579228186

-3.3940698512 -3.4273955088 -4.5258152172 -7.8998702388 -18.579228186

-3.8765024053 -3.9872988938 -4.5258152172 -6.8994315354 -16.579228186

-4.2069026831 -4.5081009758 -4.5258152172 -5.8980471425 -14.579228186

-4.2820466039 -5.0148920815 -4.5258152172 -4.8936981263 -12.579228186

-3.7835815791 -5.5170619076 -4.5258152172 -3.8802251231 -10.579228186

-2.8310293253 -6.0177503292 -4.5258152172 -2.8401783006 -8.579228186

-1.7327449083 -6.5179682545 -4.5258152172 -1.7334581807 -6.579228186

-0.505760509 -7.0180371913 -4.5258152172 -0.5058387896 -4.579228186

0.8541501756 -7.5180589933 -4.5258152172 0.8539882276 -2.579228186

2.2988183897 -8.0180658879 -4.5258152172 2.2982428509 -0.579228186

3.7809130586 -8.5180680682 -4.5258152172 3.7790137617 1.420771814

5.2788155674 -9.0180687577 -4.5258152172 5.272751429 3.420771814

6.7897314455 -9.5180689757 -4.5258152172 6.7707521642 5.420771814

8.3275812141 -10.0180690446 -4.5258152172 8.270118021 7.420771814

9.9305548745 -10.5180690665 -4.5258152172 9.7699172944 9.420771814

11.6528656121 -11.0180690733 -4.5258152172 11.2698537998 11.420771814

13.5083364074 -11.5180690755 -4.5258152172 12.7698337191 13.420771814

15.4504155999 -12.0180690762 -4.5258152172 14.2698273689 15.420771814

17.4303665201 -12.5180690764 -4.5258152172 15.7698253607 17.420771814

19.4238289009 -13.0180690765 -4.5258152172 17.2698247257 19.420771814

21.4217408779 -13.5180690765 -4.5258152172 18.7698245249 21.420771814

23.4210784927 -14.0180690765 -4.5258152172 20.2698244614 23.420771814

25.4208688178 -14.5180690765 -4.5258152172 21.7698244413 25.420771814

27.4208024916 -15.0180690765 -4.5258152172 23.2698244349 27.420771814

29.4207815154 -15.5180690765 -4.5258152172 24.7698244329 29.420771814

31.4207748819 -16.0180690765 -4.5258152172 26.2698244323 31.420771814

33.4207727842 -16.5180690765 -4.5258152172 27.7698244321 33.420771814

de Souiidad


18/88

10 11 12 13 14 15 16 17 18 19 20

log[CuT]

log[Cu(+2a)]

log[CuOH(+a)]

log[Cu(OH)3(-a)]

log[Cu(OH)4(-2a)]

ECA A1! A2 " A3

"H

9 10 11 12 13 14 15 16 17 18 19 20

a de Souiidad

log[CuT]

ECA A1! A2 " A3


19/88

"H

8 9

de Souiidad

log[CuT]

ECA A1! A2 " A3

"H


20/88


21/88

log([Cu(+2a)]/[CuT]) log([CuOH(+a)]/[CuT]) log([Cu(OH)3(-a)]/[CuT])

-1.832222186451E-015 -14.3735680166 -31.7478260776

-1.837043823784E-014 -13.373568421 -29.7478264821

-1.837525987518E-013 -12.3735697 -27.7478277609

-1.837429554775E-012 -11.3735737446 -25.747831805

-1.837371695162E-011 -10.3735865343 -23.7478445934-1.837203902532E-010 -9.3736269767 -21.7478850314

-1.836662918318E-009 -8.3737548432 -19.748012884

-1.834954772455E-008 -7.3741589561 -17.748416953

-0.000000183 -6.3754345169 -15.749692375

-1.812760335461E-006 -5.3794448296 -13.7537022485

-1.761546434202E-005 -4.3918990417 -11.766155072

-0.0001616892 -3.4291844479 -9.8034360869

-0.0012824113 -2.5303998534 -7.9046376063

-0.0077106891 -1.7545591059 -6.1287529501

-0.0333256576 -1.1317453661 -4.5058003877-0.1107964885 -0.6493128119 -3.02292913

-0.3011982928 -0.3189125341 -1.6911444594

-0.7328454777 -0.2437686134 -0.6116515224

-1.7334803285 -0.7422336381 -0.0966435439

-3.1867210039 -1.6947858919 -0.0091489753

-4.7852233462 -2.7930703089 -0.0007132725

-6.5122766823 -4.0200547082 -7.82806227519245E-005

-8.3722091689 -5.3799653928 -0.000161948

-10.3168842776 -6.8246336069 -0.0005755388

-12.2989811268 -8.3067282758 -0.0018992969

-14.2968843251 -9.8046307846 -0.0060641384

-16.3078004212 -11.3155466627 -0.0189792813

-18.3456502587 -12.8533964313 -0.0574631931

-20.448623941 -14.4563700917 -0.1606375801

-22.6709346854 -16.1786808293 -0.3830118122

-25.0264054829 -18.0341516246 -0.7385026883

-27.4684846761 -19.9762308171 -1.1805882311

-29.9484355965 -21.9561817373 -1.6605411593

-32.4418979774 -23.9496441181 -2.1540041752

-34.9398099544 -25.9475560951 -2.651916353

-37.4391475693 -27.9468937099 -3.1512540314

-39.9389378943 -29.946684035 -3.6510443765

-42.4388715682 -31.9466177089 -4.1509780567

-44.9388505919 -33.9465967326 -4.6509570825

-47.4388439584 -35.9465900991 -5.1509504496

-49.9388418607 -37.9465880014 -5.6509483521

ECA Cu A1


22/88

#g/$ A2

#g/$ A3

ECA & A1

#ol/$ A2

#ol/$ A3

ECA & A1

log[#ol/$] A2

log[#ol/$] A3

'o u#pl o& lo* l#,* p#,*,l*

ga * po &,#a la l&a u, u#o* *olu,o&a * pol#a


23/88

a u &o *a la l pH "a u &o a

oa #,a #,a,& (gu&a

O*a#o* & la ga au&a u l pH;8!4. 'o a"ua & #u


24/88


25/88

log([Cu(OH)4(-2a)]/[CuT])

-56.4269809853

-53.4269813898

-50.4269826688

-47.4269867133

-44.4269995031-41.4270399455

-38.4271678119

-35.4275719249

-32.4288474857

-29.4328577983

-26.4453120105

-23.4825974166

-20.5838128221

-17.8079720747

-15.1851583348

-12.7027257807

-10.3723255029

-8.2971815821

-6.7956466069

-5.7481988607

-4.8464832777

-4.073467677

-3.4333783616

-2.8780465757

-2.3601412446

-1.8580437534

-1.3689596315

-0.9068094

-0.5097830605

-0.232093798

-0.0875645934

-0.0296437859

-0.009594706

-0.0030570869

-0.0009690639

-0.0003066787

-9.70037303678148E-005

-3.06776150350001E-005

-9.70134790919395E-006

-3.0678590016438E-006

-9.70144541045492E-007

2


26/88

2

2

3.15E-05

3.15E-05

3.15E-05

-4,.2.2

-4,.2.2

-4,.2.2

oo l a&go pH! ao u lo

#,&a l ECA (A1! A2 " A3). o&a#,&a,&! &*,a#o* oa


27/88

uaa & &aa. E* ,! &*,a#o*

5).

,* u& #&,#o log[CuT];-4!3 ua&o u &aa) llga a * #&,#o.


28/88


29/88

Cu(+2a) + H2CO3(a) = CuCO3 + 2H(+a)

T K

C kJ J/K kJ

0 35.849 -11.291 38.933 3.583E-008

5 36.514 -8.877 38.983 4.771E-00810 37.106 -6.765 39.022 6.320E-008

15 37.644 -4.883 39.051 8.325E-008

20 38.142 -3.170 39.071 1.090E-007

25 38.612 -1.579 39.083 1.420E-007

30 39.065 -0.073 39.087 1.839E-007

35 39.508 1.376 39.084 2.368E-007

40 39.947 2.790 39.073 3.033E-007

45 40.386 4.182 39.056 3.865E-007

50 40.828 5.559 39.032 4.901E-007

55 41.273 6.926 39.000 6.186E-00760 41.720 8.279 38.962 7.773E-007

65 42.173 9.628 38.918 9.724E-007

70 42.636 10.985 38.866 1.211E-006

75 43.108 12.353 38.808 1.503E-006

80 43.592 13.733 38.743 1.858E-006

85 44.089 15.129 38.670 2.289E-006

90 44.599 16.543 38.591 2.810E-006

95 45.124 17.979 38.505 3.438E-006

100 45.665 19.439 38.411 4.194E-006

Cu(+2a) + HCO3(-a) = CuCO3 + H(+a)

T K

C kJ J/K kJ

0 24.615 72.640 4.773 1.222E-001

5 25.698 76.571 4.400 1.492E-001

10 26.626 79.878 4.009 1.821E-001

15 27.435 82.710 3.602 2.223E-001

20 28.156 85.190 3.182 2.710E-001

25 28.813 87.414 2.751 3.297E-001

30 29.428 89.461 2.308 4.002E-001

35 30.017 91.387 1.856 4.845E-001

40 30.592 93.236 1.395 5.853E-001

45 31.160 95.037 0.924 7.052E-001

50 31.727 96.806 0.444 8.476E-001

55 32.294 98.548 -0.044 1.016E+000

60 32.861 100.261 -0.541 1.216E+000

H S G

H S G


30/88

65 33.433 101.966 -1.047 1.451E+000

70 34.018 103.684 -1.561 1.728E+000

75 34.619 105.421 -2.084 2.054E+000

80 35.237 107.183 -2.615 2.437E+000

85 35.874 108.975 -3.155 2.886E+000

90 36.533 110.803 -3.705 3.412E+000

95 37.217 112.672 -4.264 4.027E+000100 37.927 114.590 -4.832 4.747E+000


T K

C kJ J/K kJ

0 -27.281 50.148 -40.979 6.871E+007

5 -20.430 75.200 -41.347 5.826E+007

10 -19.663 77.933 -41.730 4.999E+00715 -18.954 80.417 -42.126 4.336E+007

20 -18.285 82.718 -42.534 3.798E+007

25 -17.644 84.887 -42.953 3.356E+007

30 -17.019 86.965 -43.383 2.990E+007

35 -16.403 88.983 -43.823 2.685E+007

40 -15.787 90.963 -44.272 2.429E+007

45 -15.170 92.920 -44.732 2.212E+007

50 -14.546 94.863 -45.202 2.028E+007

55 -13.917 96.796 -45.681 1.871E+007

60 -13.283 98.715 -46.170 1.736E+007

65 -12.639 100.631 -46.668 1.620E+007

70 -11.983 102.558 -47.176 1.520E+007

75 -11.313 104.498 -47.694 1.433E+007

80 -10.627 106.454 -48.221 1.358E+007

85 -9.924 108.430 -48.758 1.293E+007

90 -9.203 110.429 -49.305 1.237E+007

95 -8.462 112.456 -49.862 1.189E+007

100 -7.699 114.514 -50.430 1.148E+007


T K

C kJ J/K kJ

0 -135.635 14.145 -139.499 4.772E+026

5 -114.797 90.341 -139.925 1.902E+026

10 -112.040 100.166 -140.402 7.999E+025

15 -109.324 109.673 -140.926 3.537E+025

H S G

H S G


31/88

20 -106.635 118.925 -141.498 1.640E+025

25 -103.960 127.973 -142.115 7.945E+024

30 -101.289 136.858 -142.777 4.013E+024

35 -98.613 145.612 -143.484 2.109E+024

40 -95.928 154.257 -144.233 1.150E+024

45 -93.228 162.810 -145.026 6.497E+023

50 -90.512 171.281 -145.861 3.796E+023

55 -87.778 179.675 -146.739 2.289E+023

60 -85.028 187.992 -147.658 1.423E+023

65 -82.258 196.245 -148.619 9.105E+022

70 -79.464 204.447 -149.620 5.988E+022

75 -76.646 212.601 -150.663 4.042E+022

80 -73.802 220.713 -151.746 2.797E+022

85 -70.930 228.786 -152.870 1.983E+022

90 -68.031 236.826 -154.034 1.438E+022

95 -65.102 244.837 -155.238 1.066E+022100 -62.142 252.823 -156.482 8.067E+021


T K

C kJ J/K kJ

0 -158.170 135.048 -195.058 2.014E+037

5 -135.427 218.153 -196.107 6.769E+036

10 -130.976 234.015 -197.237 2.448E+03615 -126.732 248.875 -198.445 9.469E+035

20 -122.640 262.952 -199.725 3.897E+035

25 -118.658 276.422 -201.074 1.699E+035

30 -114.750 289.423 -202.488 7.815E+034

35 -110.886 302.063 -203.967 3.780E+034

40 -107.047 314.421 -205.508 1.916E+034

45 -103.218 326.553 -207.111 1.016E+034

50 -99.391 338.490 -208.774 5.616E+033

55 -95.562 350.248 -210.496 3.231E+033

60 -91.734 361.825 -212.276 1.930E+03365 -87.894 373.266 -214.114 1.195E+033

70 -84.030 384.608 -216.008 7.651E+032

75 -80.140 395.863 -217.960 5.061E+032

80 -76.219 407.045 -219.967 3.453E+032

85 -72.265 418.164 -222.030 2.425E+032

90 -68.272 429.233 -224.148 1.753E+032

95 -64.239 440.264 -226.322 1.301E+032

H S G


32/88

100 -60.160 451.270 -228.551 9.906E+031

Cu(OH)4(-2a) + CO3(-2a) + 4H(+a) = CuCO3 + 4H2O

T K

C kJ J/K kJ0 -214.230 219.222 -274.110 2.646E+052

5 -184.637 327.377 -275.697 6.003E+051

10 -179.334 346.276 -277.382 1.496E+051

15 -174.228 364.151 -279.158 4.064E+050

20 -169.267 381.221 -281.022 1.196E+050

25 -164.406 397.663 -282.970 3.795E+049

30 -159.610 413.617 -284.998 1.291E+049

35 -154.850 429.190 -287.105 4.692E+048

40 -150.106 444.461 -289.289 1.814E+048

45 -145.363 459.487 -291.549 7.435E+04750 -140.613 474.301 -293.884 3.221E+047

55 -135.853 488.918 -296.292 1.470E+047

60 -131.086 503.337 -298.773 7.056E+046

65 -126.298 517.604 -301.325 3.549E+046

70 -121.477 531.755 -303.949 1.867E+046

75 -116.620 545.805 -306.643 1.025E+046

80 -111.725 559.766 -309.407 5.866E+045

85 -106.787 573.650 -312.240 3.489E+045

90 -101.803 587.471 -315.143 2.154E+045

95 -96.768 601.240 -318.115 1.378E+045

100 -91.679 614.971 -321.155 9.120E+044

H S G


33/88

[H(+a)] pH

Log(K) 1.00E+00 0.0

3.16E-01 0.5

-7.446 1.00E-01 1.0

-7.321 3.16E-02 1.5-7.199 1.00E-02 2.0

-7.080 3.16E-03 2.5

-6.962 1.00E-03 3.0

-6.848 3.16E-04 3.5

-6.736 1.00E-04 4.0

-6.626 3.16E-05 4.5

-6.518 1.00E-05 5.0

-6.413 3.16E-06 5.5

-6.310 1.00E-06 6.0

-6.209 3.16E-07 6.5-6.109 1.00E-07 7.0

-6.012 3.16E-08 7.5

-5.917 1.00E-08 8.0

-5.823 3.16E-09 8.5

-5.731 1.00E-09 9.0

-5.640 3.16E-10 9.5

-5.551 1.00E-10 10.0

-5.464 3.16E-11 10.5

-5.377 1.00E-11 11.0

3.16E-12 11.5

1.00E-12 12.0

3.16E-13 12.5

1.00E-13 13.0

Log(K) 3.16E-14 13.5

1.00E-14 14.0

-0.913 3.16E-15 14.5

-0.826 1.00E-15 15.0

-0.740 3.16E-16 15.5

-0.653 1.00E-16 16.0

-0.567 3.16E-17 16.5

-0.482 1.00E-17 17.0

-0.398 3.16E-18 17.5

-0.315 1.00E-18 18.0

-0.233 3.16E-19 18.5

-0.152 1.00E-19 19.0

-0.072 3.16E-20 19.5

0.007 1.00E-20 20.0

0.085


34/88

0.162

0.238

0.313

0.387

0.460

0.533

0.6050.676

Log(K)

7.837

7.765

7.6997.637

7.580

7.526

7.476

7.429

7.385

7.345

7.307

7.272

7.240

7.209

7.182

7.156

7.133

7.112

7.093

7.075

7.060

Log(K)

26.679

26.279

25.903

25.549

# Co!e$ra!i%

0

-

-5

0


35/88

25.215

24.900

24.603

24.324

24.061

23.813

23.579

23.360

23.153

22.959

22.777

22.607

22.447

22.297

22.158

22.02821.907

Log(K)

37.304

36.831

36.38935.976

35.591

35.230

34.893

34.577

34.282

34.007

33.749

33.509

33.28633.077

32.884

32.704

32.538

32.385

32.244

32.114

-65

-60

-55

-50

-45

-40

-35

-30

-25

-20

-15

-

ogCuT*

1.000E

1.000E

1.000E

1.000E

1.000E

1.000E

1.000E

1.000E

ogCuT*


36/88

31.996

Log(K)

52.423

51.778

51.175

50.609

50.078

49.579

49.111

48.671

48.259

47.87147.508

47.167

46.849

46.550

46.271

46.011

45.768

45.543

45.333

45.139

44.960

1.000E

1.000E

1.000E

1.000E

1.000E

.


37/88

H2CO3(a)/HCO3(-a)/CO3(-2a) [Cu(+2a)] [CuOH(+a)] [Cu(OH)3(-a)] [Cu(OH)4(-2a)]

0.001 2.096E+010 1.717E-005 5.2581099E-024 1.66583170E-049

0.001 2.096E+009 1.717E-005 5.2581099E-023 1.66583170E-047

0.001 2.096E+008 1.717E-005 5.2581099E-022 1.66583170E-045

0.001 2.096E+007 1.717E-005 5.2581099E-021 1.66583170E-0430.001 2.096E+006 1.717E-005 5.2581099E-020 1.66583170E-041

0.001 2.096E+005 1.717E-005 5.2581099E-019 1.66583170E-039

0.001 2.097E+004 1.717E-005 5.2581100E-018 1.66583170E-037

0.001 2.098E+003 1.717E-005 5.2581103E-017 1.66583170E-035

0.001 2.103E+002 1.717E-005 5.2581114E-016 1.66583170E-033

0.001 2.117E+001 1.717E-005 5.2581145E-015 1.66583170E-031

0.001 2.163E+000 1.717E-005 5.2581246E-014 1.66583170E-029

0.001 2.308E-001 1.717E-005 5.2581566E-013 1.66583170E-027

0.001 2.766E-002 1.717E-005 5.2582576E-012 1.66583170E-025

0.001 4.216E-003 1.717E-005 5.2585771E-011 1.66583170E-0230.001 8.800E-004 1.717E-005 5.2595872E-010 1.66583170E-021

0.001 2.330E-004 1.717E-005 5.2627817E-009 1.66583170E-019

0.001 6.914E-005 1.717E-005 5.2728836E-008 1.66583170E-017

0.001 2.141E-005 1.717E-005 5.3048286E-007 1.66583170E-015

0.001 6.725E-006 1.717E-005 5.4058475E-006 1.66583170E-013

0.001 2.122E-006 1.717E-005 0.000057253 1.66583170E-011

0.001 6.707E-007 1.717E-005 0.0006735486 1.66583170E-009

0.001 2.120E-007 1.717E-005 0.0099299828 1.66583170E-007

0.001 6.705E-008 1.717E-005 0.200318692 1.66583170E-005

0.001 2.120E-008 1.717E-005 5.1976838944 0.0016658317

0.001 6.705E-009 1.717E-005 152.995703124 0.1665831701

0.001 2.120E-009 1.717E-005 4724.45400578 16.658317011

0.001 6.705E-010 1.717E-005 148263.404238 1665.831701099

0.001 2.120E-010 1.717E-005 4677131.01692 166583.1701099

0.001 6.705E-011 1.717E-005 147790174.35 16658317.01099

0.001 2.120E-011 1.717E-005 4672398718.04 1665831701.099

0.001 6.705E-012 1.717E-005 147742851361 166583170109.9

0.001 2.120E-012 1.717E-005 4671925488150 16658317010990

0.001 6.705E-013 1.717E-005 1.477381E+014 1.6658317E+015

0.001 2.120E-013 1.717E-005 4.671878E+015 1.6658317E+017

0.001 6.705E-014 1.717E-005 1.477376E+017 1.6658317E+019

0.001 2.120E-014 1.717E-005 4.671873E+018 1.6658317E+021

0.001 6.705E-015 1.717E-005 1.477376E+020 1.6658317E+023

0.001 2.120E-015 1.717E-005 4.671873E+021 1.6658317E+025

0.001 6.705E-016 1.717E-005 1.477376E+023 1.6658317E+027

0.001 2.120E-016 1.717E-005 4.671873E+024 1.6658317E+029

0.001 6.705E-017 1.717E-005 1.477376E+026 1.6658317E+031


38/88

0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

0%

5%

10%15%

20%

25%

30%

35%

40%

45%

50%

55%60%

65%

70%

75%

80%

85%

90%

95%

100%

Diagrama de Predomia!ia

"H

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19

Diagrama de &'errum


39/88

"H

0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19

034

029

024

019

014

009

004

001

Diagrama de &'errum


40/88

064

059

054

049

044

"H


41/88

[CuT] [Cu(+2a)]/[CuT] [CuOH(+a)]/[CuT] [Cu(OH)3(-a)]/[CuT]

2.096E+010 1.000E+000 8.190E-016 2.509E-034

2.096E+009 1.000E+000 8.190E-015 2.509E-032

2.096E+008 1.000E+000 8.190E-014 2.509E-030

2.096E+007 1.000E+000 8.190E-013 2.509E-0282.096E+006 1.000E+000 8.190E-012 2.509E-026

2.096E+005 1.000E+000 8.189E-011 2.509E-024

2.097E+004 1.000E+000 8.187E-010 2.508E-022

2.098E+003 1.000E+000 8.182E-009 2.506E-020

2.103E+002 1.000E+000 8.164E-008 2.501E-018

2.117E+001 1.000E+000 8.108E-007 2.484E-016

2.163E+000 1.000E+000 7.936E-006 2.431E-014

2.308E-001 9.999E-001 7.437E-005 2.278E-012

2.768E-002 9.994E-001 6.201E-004 1.900E-010

4.233E-003 9.959E-001 4.055E-003 1.242E-0088.972E-004 9.809E-001 1.913E-002 5.862E-007

2.501E-004 9.314E-001 6.862E-002 2.104E-005

8.636E-005 8.006E-001 1.988E-001 6.106E-004

3.911E-005 5.475E-001 4.389E-001 1.356E-002

2.930E-005 2.296E-001 5.859E-001 1.845E-001

7.654E-005 2.773E-002 2.243E-001 7.480E-001

6.914E-004 9.700E-004 2.483E-002 9.742E-001

9.948E-003 2.132E-005 1.726E-003 9.982E-001

2.004E-001 3.346E-007 8.567E-005 9.998E-001

5.199E+000 4.078E-009 3.301E-006 9.997E-001

1.532E+002 4.377E-011 1.121E-007 9.989E-001

4.741E+003 4.472E-013 3.620E-009 9.965E-001

1.499E+005 4.472E-015 1.145E-010 9.889E-001

4.844E+006 4.377E-017 3.544E-012 9.656E-001

1.644E+008 4.077E-019 1.044E-013 8.987E-001

6.338E+009 3.345E-021 2.708E-015 7.372E-001

3.143E+011 2.133E-023 5.461E-017 4.700E-001

2.133E+013 9.940E-026 8.047E-019 2.190E-001

1.814E+015 3.697E-028 9.465E-021 8.146E-002

1.713E+017 1.238E-030 1.002E-022 2.728E-002

1.681E+019 3.989E-033 1.021E-024 8.791E-003

1.671E+021 1.269E-035 1.028E-026 2.797E-003

1.667E+023 4.021E-038 1.030E-028 8.861E-004

1.666E+025 1.272E-040 1.030E-030 2.804E-004

1.666E+027 4.024E-043 1.030E-032 8.868E-005

1.666E+029 1.273E-045 1.030E-034 2.804E-005

1.666E+031 4.025E-048 1.030E-036 8.869E-006


42/88

[Cu(+2a)]/[CuT]

[CuOH(+a)]/[CuT]

[Cu(OH)3(-a)]/[CuT]

[Cu(OH)4(-2a)]/[CuT]

0 1 2

-55

-50

-45

-40

-35

-30

-25

-20

-15

-10

-5

0

5

10

15

20

25

30

35

40

ogCuT*

0 1 2

30

35

0


43/88

-10

-5

0

5

10

15

20

25

ogCuT*

8

-4

-3

ogCuT*

log[Cu(+2a)]

log[CuOH(+a)]

log[Cu(OH)3(-a)]

log[Cu(OH)4(-2a)]

20

[Cu(+2a)]

[CuOH(+a)]

[Cu(OH)3(-a)]

[Cu(OH)4(-2a)]


44/88

-5


45/88

[Cu(OH)4(-2a)]/[CuT] log[CuT] log[Cu(+2a)] log[CuOH(+a)] log[Cu(OH)3(-a)]

7.948E-060 10.3213619556 10.3213619556 -4.7653520957 -23.2791703431

7.948E-057 9.321362256 9.321362256 -4.7653520957 -22.2791703431

7.948E-054 8.3213632059 8.3213632059 -4.7653520957 -21.279170343

7.948E-051 7.3213662099 7.3213662099 -4.7653520957 -20.27917034277.948E-048 6.3213757092 6.3213757092 -4.7653520957 -19.2791703419

7.947E-045 5.3214057474 5.3214057473 -4.7653520957 -18.2791703393

7.946E-042 4.3215007228 4.3215007225 -4.7653520957 -17.2791703309

7.940E-039 3.3218009272 3.3218009237 -4.7653520957 -16.2791703045

7.923E-036 2.3227489152 2.3227488798 -4.7653520957 -15.2791702211

7.869E-033 1.3257333871 1.325733035 -4.7653520957 -14.2791699573

7.702E-030 0.3350404855 0.3350370388 -4.7653520957 -13.2791691229

7.218E-027 -0.6367557489 -0.636788049 -4.7653520957 -12.2791664844

6.018E-024 -1.5578298408 -1.5580992404 -4.7653520957 -11.2791581409

3.935E-021 -2.3733335476 -2.3750981591 -4.7653520957 -10.27913175741.857E-018 -3.0471092352 -3.0554988655 -4.7653520957 -9.2790483362

6.659E-016 -3.6018091741 -3.6326925455 -4.7653520957 -8.2787846403

1.929E-013 -4.0636928405 -4.1602642133 -4.7653520957 -7.277951813

4.260E-011 -4.4077480235 -4.6693604549 -4.7653520957 -6.2753286435

5.686E-009 -4.533184492 -5.1722770458 -4.7653520957 -5.2671362127

2.176E-007 -4.1161092709 -5.6732034441 -4.7653520957 -4.2422019669

2.409E-006 -3.1602793751 -6.1734968087 -4.7653520957 -3.1716310747

1.675E-005 -2.0022848925 -6.67358962 -4.7653520957 -2.0030515046

8.315E-005 -0.6982050552 -7.1736189737 -4.7653520957 -0.6982785243

3.204E-004 0.7159504661 -7.6736282565 -4.7653520957 0.7158098636

1.088E-003 2.1851518892 -8.1736311921 -4.7653520957 2.1846792339

3.514E-003 3.675880246 -8.6736321204 -4.7653520957 3.6743516253

1.111E-002 5.1758863278 -9.1736324139 -4.7653520957 5.1710339676

3.439E-002 6.6851785088 -9.6736325067 -4.7653520957 6.6699795356

1.013E-001 8.2160298936 -10.1736325361 -4.7653520957 8.1696455615

2.628E-001 9.8019680234 -10.6736325454 -4.7653520957 9.6695398961

5.300E-001 11.4973803356 -11.1736325483 -4.7653520957 11.1695064764

7.810E-001 13.3289957929 -11.6736325492 -4.7653520957 12.6694959077

9.185E-001 15.25853428 -12.1736325495 -4.7653520957 14.1694925655

9.727E-001 17.2336433825 -12.6736325496 -4.7653520957 15.6694915086

9.912E-001 19.2254657716 -13.1736325497 -4.7653520957 17.1694911744

9.972E-001 21.2228474093 -13.6736325497 -4.7653520957 18.6694910687

9.991E-001 23.2220161145 -14.1736325497 -4.7653520957 20.1694910352

9.997E-001 25.2217529046 -14.6736325497 -4.7653520957 21.6694910247

9.999E-001 27.2216696371 -15.1736325497 -4.7653520957 23.1694910213

1.000E+000 29.2216433023 -15.6736325497 -4.7653520957 24.6694910203

1.000E+000 31.2216349741 -16.1736325497 -4.7653520957 26.1694910199


46/88

3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

Diagrama de Souiidad

lolo

lo

lo

lo

EC

"H

3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20



47/88

l

E

"H

9 10


l

E


48/88

"H


49/88

log[Cu(OH)4(-2a)] log([Cu(+2a)]/[CuT]) log([CuOH(+a)]/[CuT])

-48.7783688775 -3.375146132937E-016 -15.0867140513

-46.7783688775 -3.568011626247E-015 -14.0867143517

-44.7783688775 -3.558368351582E-014 -13.0867153016

-42.7783688775 -3.556921860383E-013 -12.0867183056-40.7783688775 -3.556777211276E-012 -11.0867278049

-38.7783688775 -3.556526486266E-011 -10.0867578431

-36.7783688775 -3.555752614784E-010 -9.0868528186

-34.7783688775 -3.553295183965E-009 -8.0871530229

-32.7783688775 -3.545547584241E-008 -7.0881010109

-30.7783688775 -3.521267388317E-007 -6.0910854829

-28.7783688775 -3.446620404280E-006 -5.1003925812

-26.7783688775 -3.230011940039E-005 -4.1285963468

-24.7783688775 -0.0002693996 -3.2075222549

-22.7783688775 -0.0017646115 -2.3920185481-20.7783688775 -0.0083896302 -1.7182428605

-18.7783688775 -0.0308833715 -1.1635429217

-16.7783688775 -0.0965713728 -0.7016592552

-14.7783688775 -0.2616124314 -0.3576040722

-12.7783688775 -0.6390925538 -0.2321676037

-10.7783688775 -1.5570941732 -0.6492428248

-8.7783688775 -3.0132174336 -1.6050727206

-6.7783688775 -4.6713047275 -2.7630672032

-4.7783688775 -6.4754139185 -4.0671470405

-2.7783688775 -8.3895787226 -5.4813025618

-0.7783688775 -10.3587830813 -6.950503985

1.2216311225 -12.3495123663 -8.4412323417

3.2216311225 -14.3495187417 -9.9412384235

5.2216311225 -16.3588110156 -11.4505306045

7.2216311225 -18.3896624297 -12.9813819894

9.2216311225 -20.4756005688 -14.5673201191

11.2216311225 -22.6710128839 -16.2627324313

13.2216311225 -25.0026283421 -18.0943478886

15.2216311225 -27.4321668296 -20.0238863758

17.2216311225 -29.9072759322 -21.9989954783

19.2216311225 -32.3990983213 -23.9908178673

21.2216311225 -34.8964799589 -25.988199505

23.2216311225 -37.3956486642 -27.9873682103

25.2216311225 -39.8953854543 -29.9871050003

27.2216311225 -42.3953021868 -31.9870217328

29.2216311225 -44.8952758519 -33.986995398

31.2216311225 -47.3952675238 -35.9869870699


50/88

ECA Cu

#g/$

#g/$

ECA &

#ol/$

#ol/$

ECA &

log[#ol/$]

log[#ol/$]

[CuT][Cu(+2a)]

[CuOH(+a)]

[Cu(OH)3(-a)]

[Cu(OH)4(-2a)]

A A1! A2 " A3


51/88

Cu#pl l,ga#&,& #ago! *

la l pH. ?&a#u" o*o*o! po l

&o pa*a*! "a u

O*a#o* & lal pH;8!85. aa

g[CuT]

CA A1! A2 " A3

g[CuT]

CA A1! A2 " A3


52/88


53/88

log([Cu(OH)3(-a)]/[CuT]) log([Cu(OH)4(-2a)]/[CuT])

-33.6005322987 -59.099730833

-31.6005325991 -56.0997311334

-29.6005335489 -53.0997320834

-27.6005365527 -50.0997350874-25.6005460511 -47.0997445867

-23.6005760866 -44.0997746248

-21.6006710538 -41.0998696003

-19.6009712317 -38.1001698047

-17.6019191363 -35.1011177927

-15.6049033444 -32.1041022646

-13.6142096084 -29.1134093629

-11.6424107355 -26.1416131286

-9.7213283001 -23.2205390366

-7.9057982098 -20.4050353299-6.2319391009 -17.7312596422

-4.6769754662 -15.1765597034

-3.2142589725 -12.714676037

-1.8675806199 -10.3706208539

-0.7339517207 -8.2451843855

-0.126092696 -6.6622596065

-0.0113516996 -5.6180895023

-0.0007666121 -4.7760839849

-0.000073469 -4.0801638223

-0.0001406025 -3.4943193436

-0.0004726554 -2.9635207667

-0.0015286206 -2.4542491234

-0.0048523602 -1.9542552053

-0.0151989732 -1.4635473863

-0.0463843322 -0.9943987711

-0.1324281273 -0.5803369009

-0.3278738591 -0.275749213

-0.6594998852 -0.1073646703

-1.0890417146 -0.0369031575

-1.564151874 -0.01201226

-2.0559745973 -0.0038346491

-2.5533563406 -0.0012162867

-3.0525250793 -0.000384992

-3.5522618799 -0.0001217821

-4.0521786158 -3.85145610582428E-005

-4.552152282 -1.21797428494638E-005

-5.0521439542 -3.85160979859869E-006


54/88

A1 2

A2 2

A3 2

A1 3.15E-05

A2 3.15E-05

A3 3.15E-05

A1 -4,.2.2

A2 -4,.2.2

A3 -4,.2.2


55/88

o& lo* l#,* p#,*,l* & l a&go pH 8!7 a 9!1.pH &o * l u &o#al#& =u>a! po lo u #o*

a * la al! po a@aa#o* la* ua*! a#* *o u opa#o* po u*a oa* ao&aaa*. T& u,ao

l a&go p#,*,l * #u" oo.

ga au&a u :,* u& #&,#o log[CuT];-4!6 ua&o* a*o! *ula ao&*al llga a * #&,#o.


56/88


57/88


58/88


59/88


60/88


61/88

Cu(+2a) + H2CO3(a) = CuCO3 + 2H(+a)

T K

C kJ J/K kJ

0 35.849 -11.291 38.933 3.583E-008

5 36.514 -8.877 38.983 4.771E-00810 37.106 -6.765 39.022 6.320E-008

15 37.644 -4.883 39.051 8.325E-008

20 38.142 -3.170 39.071 1.090E-007

25 38.612 -1.579 39.083 1.420E-007

30 39.065 -0.073 39.087 1.839E-007

35 39.508 1.376 39.084 2.368E-007

40 39.947 2.790 39.073 3.033E-007

45 40.386 4.182 39.056 3.865E-007

50 40.828 5.559 39.032 4.901E-007

55 41.273 6.926 39.000 6.186E-00760 41.720 8.279 38.962 7.773E-007

65 42.173 9.628 38.918 9.724E-007

70 42.636 10.985 38.866 1.211E-006

75 43.108 12.353 38.808 1.503E-006

80 43.592 13.733 38.743 1.858E-006

85 44.089 15.129 38.670 2.289E-006

90 44.599 16.543 38.591 2.810E-006

95 45.124 17.979 38.505 3.438E-006

100 45.665 19.439 38.411 4.194E-006

Cu(+2a) + HCO3(-a) = CuCO3 + H(+a)

T K

C kJ J/K kJ

0 24.615 72.640 4.773 1.222E-001

5 25.698 76.571 4.400 1.492E-001

10 26.626 79.878 4.009 1.821E-001

15 27.435 82.710 3.602 2.223E-001

20 28.156 85.190 3.182 2.710E-001

25 28.813 87.414 2.751 3.297E-001

30 29.428 89.461 2.308 4.002E-001

35 30.017 91.387 1.856 4.845E-001

40 30.592 93.236 1.395 5.853E-001

45 31.160 95.037 0.924 7.052E-001

50 31.727 96.806 0.444 8.476E-001

55 32.294 98.548 -0.044 1.016E+000

60 32.861 100.261 -0.541 1.216E+000

H S G

H S G


62/88

65 33.433 101.966 -1.047 1.451E+000

70 34.018 103.684 -1.561 1.728E+000

75 34.619 105.421 -2.084 2.054E+000

80 35.237 107.183 -2.615 2.437E+000

85 35.874 108.975 -3.155 2.886E+000

90 36.533 110.803 -3.705 3.412E+000

95 37.217 112.672 -4.264 4.027E+000100 37.927 114.590 -4.832 4.747E+000


T K

C kJ J/K kJ

0 -27.281 50.148 -40.979 6.871E+007

5 -20.430 75.200 -41.347 5.826E+007

10 -19.663 77.933 -41.730 4.999E+00715 -18.954 80.417 -42.126 4.336E+007

20 -18.285 82.718 -42.534 3.798E+007

25 -17.644 84.887 -42.953 3.356E+007

30 -17.019 86.965 -43.383 2.990E+007

35 -16.403 88.983 -43.823 2.685E+007

40 -15.787 90.963 -44.272 2.429E+007

45 -15.170 92.920 -44.732 2.212E+007

50 -14.546 94.863 -45.202 2.028E+007

55 -13.917 96.796 -45.681 1.871E+007

60 -13.283 98.715 -46.170 1.736E+007

65 -12.639 100.631 -46.668 1.620E+007

70 -11.983 102.558 -47.176 1.520E+007

75 -11.313 104.498 -47.694 1.433E+007

80 -10.627 106.454 -48.221 1.358E+007

85 -9.924 108.430 -48.758 1.293E+007

90 -9.203 110.429 -49.305 1.237E+007

95 -8.462 112.456 -49.862 1.189E+007

100 -7.699 114.514 -50.430 1.148E+007


T K

C kJ J/K kJ

0 -135.635 14.145 -139.499 4.772E+026

5 -114.797 90.341 -139.925 1.902E+026

10 -112.040 100.166 -140.402 7.999E+025

15 -109.324 109.673 -140.926 3.537E+025

H S G

H S G


63/88

20 -106.635 118.925 -141.498 1.640E+025

25 -103.960 127.973 -142.115 7.945E+024

30 -101.289 136.858 -142.777 4.013E+024

35 -98.613 145.612 -143.484 2.109E+024

40 -95.928 154.257 -144.233 1.150E+024

45 -93.228 162.810 -145.026 6.497E+023

50 -90.512 171.281 -145.861 3.796E+023

55 -87.778 179.675 -146.739 2.289E+023

60 -85.028 187.992 -147.658 1.423E+023

65 -82.258 196.245 -148.619 9.105E+022

70 -79.464 204.447 -149.620 5.988E+022

75 -76.646 212.601 -150.663 4.042E+022

80 -73.802 220.713 -151.746 2.797E+022

85 -70.930 228.786 -152.870 1.983E+022

90 -68.031 236.826 -154.034 1.438E+022

95 -65.102 244.837 -155.238 1.066E+022

100 -62.142 252.823 -156.482 8.067E+021


T K

C kJ J/K kJ

0 -158.170 135.048 -195.058 2.014E+037

5 -135.427 218.153 -196.107 6.769E+036

10 -130.976 234.015 -197.237 2.448E+03615 -126.732 248.875 -198.445 9.469E+035

20 -122.640 262.952 -199.725 3.897E+035

25 -118.658 276.422 -201.074 1.699E+035

30 -114.750 289.423 -202.488 7.815E+034

35 -110.886 302.063 -203.967 3.780E+034

40 -107.047 314.421 -205.508 1.916E+034

45 -103.218 326.553 -207.111 1.016E+034

50 -99.391 338.490 -208.774 5.616E+033

55 -95.562 350.248 -210.496 3.231E+033

60 -91.734 361.825 -212.276 1.930E+033

65 -87.894 373.266 -214.114 1.195E+033

70 -84.030 384.608 -216.008 7.651E+032

75 -80.140 395.863 -217.960 5.061E+032

80 -76.219 407.045 -219.967 3.453E+032

85 -72.265 418.164 -222.030 2.425E+032

90 -68.272 429.233 -224.148 1.753E+032

95 -64.239 440.264 -226.322 1.301E+032

H S G


64/88

100 -60.160 451.270 -228.551 9.906E+031

CuO2(-2a) + CO3(-2a) + 4H(+a) = CuCO3 + 2H2O

T K

C kJ J/K kJ0 -215.628 252.223 -284.522 2.594E+054

5 -198.323 315.404 -286.052 5.286E+053

10 -193.560 332.379 -287.673 1.184E+053

15 -189.207 347.618 -289.373 2.889E+052

20 -185.167 361.522 -291.147 7.621E+051

25 -181.356 374.413 -292.987 2.160E+051

30 -177.708 386.547 -294.890 6.539E+050

35 -174.171 398.119 -296.851 2.107E+050

40 -170.706 409.273 -298.870 7.192E+049

45 -167.287 420.106 -300.944 2.593E+04950 -163.897 430.678 -303.071 9.841E+048

55 -160.532 441.013 -305.250 3.922E+048

60 -157.195 451.104 -307.480 1.636E+048

65 -153.863 461.033 -309.761 7.133E+047

70 -150.513 470.866 -312.091 3.241E+047

75 -147.140 480.624 -314.469 1.532E+047

80 -143.737 490.328 -316.897 7.521E+046

85 -140.298 499.999 -319.373 3.828E+046

90 -136.815 509.657 -321.897 2.017E+046

95 -133.280 519.324 -324.469 1.099E+046

100 -129.686 529.019 -327.090 6.178E+045

H S G


65/88

[H(+a)] pH

Log(K) 1.00E+00 0.0

3.16E-01 0.5

-7.446 1.00E-01 1.0

-7.321 3.16E-02 1.5-7.199 1.00E-02 2.0

-7.080 3.16E-03 2.5

-6.962 1.00E-03 3.0

-6.848 3.16E-04 3.5

-6.736 1.00E-04 4.0

-6.626 3.16E-05 4.5

-6.518 1.00E-05 5.0

-6.413 3.16E-06 5.5

-6.310 1.00E-06 6.0

-6.209 3.16E-07 6.5-6.109 1.00E-07 7.0

-6.012 3.16E-08 7.5

-5.917 1.00E-08 8.0

-5.823 3.16E-09 8.5

-5.731 1.00E-09 9.0

-5.640 3.16E-10 9.5

-5.551 1.00E-10 10.0

-5.464 3.16E-11 10.5

-5.377 1.00E-11 11.0

3.16E-12 11.5

1.00E-12 12.0

3.16E-13 12.5

1.00E-13 13.0

Log(K) 3.16E-14 13.5

1.00E-14 14.0

-0.913 3.16E-15 14.5

-0.826 1.00E-15 15.0

-0.740 3.16E-16 15.5

-0.653 1.00E-16 16.0

-0.567 3.16E-17 16.5

-0.482 1.00E-17 17.0

-0.398 3.16E-18 17.5

-0.315 1.00E-18 18.0

-0.233 3.16E-19 18.5

-0.152 1.00E-19 19.0

-0.072 3.16E-20 19.5

0.007 1.00E-20 20.0

0.085


66/88

0.162

0.238

0.313

0.387

0.460

0.533

0.6050.676

Log(K)

7.837

7.765

7.6997.637

7.580

7.526

7.476

7.429

7.385

7.345

7.307

7.272

7.240

7.209

7.182

7.156

7.133

7.112

7.093

7.075

7.060

Log(K)

26.679

26.279

25.903

25.549

# Co!e$ra!i

0

-5

0


67/88

25.215

24.900

24.603

24.324

24.061

23.813

23.579

23.360

23.153

22.959

22.777

22.607

22.447

22.297

22.158

22.028

21.907

Log(K)

37.304

36.831

36.38935.976

35.591

35.230

34.893

34.577

34.282

34.007

33.749

33.509

33.286

33.077

32.884

32.704

32.538

32.385

32.244

32.114

-60

-55

-50

-45

-40

-35

-30

-25

-20

-15

-10

ogCuT*

1.000E

1.000E

1.000E

1.000E

1.000E

1.000E

1.000E

1.000E

1.000E

1.000E

ogCuT*


68/88

31.996

Log(K)

54.414

53.723

53.073

52.461

51.882

51.334

50.816

50.324

49.857

49.41448.993

48.593

48.214

47.853

47.511

47.185

46.876

46.583

46.305

46.041

45.791

1.000E

1.000E

1.000E

1.000E

1.000E

1.000E


69/88

H2CO3(a)/HCO3(-a)/CO3(-2a) [Cu(+2a)] [CuOH(+a)] [Cu(OH)3(-a)] [CuO2(-2a)]

0.001 2.909E+008 8.409E-005 9.3827861E-020 9.102232E-044

0.001 2.909E+007 8.409E-005 9.3827861E-019 9.102232E-042

0.001 2.909E+006 8.409E-005 9.3827861E-018 9.102232E-040

0.001 2.909E+005 8.409E-005 9.3827861E-017 9.102232E-0380.001 2.909E+004 8.409E-005 9.3827862E-016 9.102232E-036

0.001 2.909E+003 8.409E-005 9.3827863E-015 9.102232E-034

0.001 2.911E+002 8.409E-005 9.3827869E-014 9.102232E-032

0.001 2.917E+001 8.409E-005 9.3827885E-013 9.102232E-030

0.001 2.933E+000 8.409E-005 9.3827938E-012 9.102232E-028

0.001 2.987E-001 8.409E-005 9.3828104E-011 9.102232E-026

0.001 3.157E-002 8.409E-005 9.3828630E-010 9.102232E-024

0.001 3.694E-003 8.409E-005 9.3830292E-009 9.102232E-022

0.001 5.392E-004 8.409E-005 9.3835549E-008 9.102232E-020

0.001 1.076E-004 8.409E-005 9.3852172E-007 9.102232E-0180.001 2.774E-005 8.409E-005 9.3904740E-006 9.102232E-016

0.001 8.144E-006 8.409E-005 0.000094071 9.102232E-014

0.001 2.512E-006 8.409E-005 0.0009459665 9.102232E-012

0.001 7.882E-007 8.409E-005 0.0096258984 9.102232E-010

0.001 2.486E-007 8.409E-005 0.1015157484 0.000000091

0.001 7.856E-008 8.409E-005 1.1813909543 9.102232E-006

0.001 2.484E-008 8.409E-005 17.0706734488 0.0009102232

0.001 7.853E-009 8.409E-005 336.940205134 0.0910223209

0.001 2.483E-009 8.409E-005 8626.1659573 9.1022320922

0.001 7.853E-010 8.409E-005 252495.130219 910.223209224

0.001 2.483E-010 8.409E-005 7781715.20815 91022.3209224

0.001 7.853E-011 8.409E-005 244050622.728 9102232.09224

0.001 2.483E-011 8.409E-005 7697270133.24 910223209.224

0.001 7.853E-012 8.409E-005 243206171978 91022320922

0.001 2.483E-012 8.409E-005 7688825625748 9102232092236

0.001 7.853E-013 8.409E-005 2.431217E+014 9.102232E+014

0.001 2.483E-013 8.409E-005 7.687981E+015 9.102232E+016

0.001 7.853E-014 8.409E-005 2.431133E+017 9.102232E+018

0.001 2.483E-014 8.409E-005 7.687897E+018 9.102232E+020

0.001 7.853E-015 8.409E-005 2.431124E+020 9.102232E+022

0.001 2.483E-015 8.409E-005 7.687888E+021 9.102232E+024

0.001 7.853E-016 8.409E-005 2.431124E+023 9.102232E+026

0.001 2.483E-016 8.409E-005 7.687887E+024 9.102232E+028

0.001 7.853E-017 8.409E-005 2.431123E+026 9.102232E+030

0.001 2.483E-017 8.409E-005 7.687887E+027 9.102232E+032

0.001 7.853E-018 8.409E-005 2.431123E+029 9.102232E+034

0.001 2.483E-018 8.409E-005 7.687887E+030 9.102232E+036


70/88

0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 1

0%

5%

10%15%

20%

25%

30%

35%

40%

45%

50%

55%60%

65%

70%

75%

80%

85%

90%

95%

100%

Diagrama de Predomia!ia

"H

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18

Diagrama de &'errum


71/88

"H

0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 1

035

031

027

023

019

015

011

007

003

001

Diagrama de &'errum


72/88

059

055

051

047

043

039

"H


73/88

[CuT] [Cu(+2a)]/[CuT] [CuOH(+a)]/[CuT] [Cu(OH)3(-a)]/[CuT]

2.909E+008 1.000E+000 2.891E-013 3.226E-028

2.909E+007 1.000E+000 2.891E-012 3.226E-026

2.909E+006 1.000E+000 2.891E-011 3.226E-024

2.909E+005 1.000E+000 2.891E-010 3.226E-0222.909E+004 1.000E+000 2.891E-009 3.226E-020

2.909E+003 1.000E+000 2.890E-008 3.225E-018

2.911E+002 1.000E+000 2.888E-007 3.223E-016

2.917E+001 1.000E+000 2.883E-006 3.217E-014

2.934E+000 1.000E+000 2.866E-005 3.198E-012

2.988E-001 9.997E-001 2.814E-004 3.140E-010

3.165E-002 9.973E-001 2.656E-003 2.964E-008

3.778E-003 9.777E-001 2.226E-002 2.484E-006

6.234E-004 8.650E-001 1.349E-001 1.505E-004

1.926E-004 5.586E-001 4.365E-001 4.872E-0031.212E-004 2.289E-001 6.937E-001 7.747E-002

1.863E-004 4.371E-002 4.513E-001 5.049E-001

1.033E-003 2.433E-003 8.143E-002 9.161E-001

9.711E-003 8.117E-005 8.659E-003 9.913E-001

1.016E-001 2.447E-006 8.276E-004 9.992E-001

1.181E+000 6.649E-008 7.117E-005 9.999E-001

1.707E+001 1.455E-009 4.925E-006 9.999E-001

3.370E+002 2.330E-011 2.495E-007 9.997E-001

8.635E+003 2.876E-013 9.738E-009 9.989E-001

2.534E+005 3.099E-015 3.318E-010 9.964E-001

7.873E+006 3.154E-017 1.068E-011 9.884E-001

2.532E+008 3.102E-019 3.322E-013 9.640E-001

8.607E+009 2.885E-021 9.769E-015 8.943E-001

3.342E+011 2.349E-023 2.516E-016 7.277E-001

1.679E+013 1.479E-025 5.008E-018 4.579E-001

1.153E+015 6.809E-028 7.291E-020 2.108E-001

9.871E+016 2.516E-030 8.519E-022 7.788E-002

9.345E+018 8.403E-033 8.998E-024 2.601E-002

9.179E+020 2.705E-035 9.161E-026 8.375E-003

9.127E+022 8.604E-038 9.213E-028 2.664E-003

9.110E+024 2.726E-040 9.230E-030 8.439E-004

9.105E+026 8.625E-043 9.236E-032 2.670E-004

9.103E+028 2.728E-045 9.237E-034 8.445E-005

9.102E+030 8.627E-048 9.238E-036 2.671E-005

9.102E+032 2.728E-050 9.238E-038 8.446E-006

9.102E+034 8.627E-053 9.238E-040 2.671E-006

9.102E+036 2.728E-055 9.238E-042 8.446E-007


74/88

20

[Cu(+2a)]/[CuT]

[CuOH(+a)]/[CuT]

[Cu(OH)3(-a)]/[CuT]

[CuO2(-2a)]/[CuT]

0 1 2

-50

-45

-40

-35

-30

-25

-20

-15

-10

-5

0

510

15

20

25

30

35

40

45

ogCuT*

0 1 2

35

4019 20


75/88

-10

-5

0

5

10

15

20

25

30

ogCuT*

6

-4

-3

ogCuT*

log[Cu(+2a)]

log[CuOH(+a)]

log[Cu(OH)3(-a)]

log[CuO2(-2a)]

8 19 20

[Cu(+2a)]

[CuOH(+a)]

[Cu(OH)3(-a)]

[CuO2(-2a)]


76/88

-5


77/88

[CuO2(-2a)]/[CuT] log[CuT] log[Cu(+2a)] log[CuOH(+a)] log[Cu(OH)3(-a)]

3.129E-052 8.463693953 8.463693953 -4.0752740753 -19.0276681841

3.129E-049 7.4636947547 7.4636947547 -4.0752740753 -18.027668184

3.129E-046 6.4636972899 6.4636972899 -4.0752740753 -17.0276681838

3.129E-043 5.463705307 5.4637053069 -4.0752740753 -16.0276681833.129E-040 4.4637306592 4.4637306579 -4.0752740753 -15.0276681806

3.129E-037 3.4638108276 3.4638108151 -4.0752740753 -14.0276681729

3.127E-034 2.4640643223 2.4640641969 -4.0752740753 -13.0276681485

3.121E-031 1.4648657412 1.4648644891 -4.0752740753 -12.0276680716

3.103E-028 0.4673980218 0.4673855732 -4.0752740753 -11.0276678283

3.046E-025 -0.5246147968 -0.5247370293 -4.0752740753 -10.0276670589

2.876E-022 -1.4995719417 -1.5007271612 -4.0752740753 -9.0276646257

2.409E-019 -2.4227349717 -2.4325112291 -4.0752740753 -8.0276569315

1.460E-016 -3.2052542157 -3.2682585177 -4.0752740753 -7.0276326012

4.725E-014 -3.7152574282 -3.9681339807 -4.0752740753 -6.0275556717.509E-012 -3.9164332965 -4.5568782108 -4.0752740753 -5.0273124859

4.886E-010 -3.7297849551 -5.0891870875 -4.0752740753 -4.0265443623

8.815E-009 -2.986082492 -5.5999253624 -4.0752740753 -3.0241242444

9.373E-008 -2.0127461548 -6.1033771133 -4.0752740753 -2.0165587245

8.959E-007 -0.9931055464 -6.6044743871 -4.0752740753 -0.9934665795

7.704E-006 0.0724279261 -7.1048219532 -4.0752740753 0.0723936412

5.332E-005 1.2322759507 -7.6049319212 -4.0752740753 1.2322506546

2.701E-004 2.5276702504 -8.104966702 -4.0752740753 2.5275528359

1.054E-003 3.9362758344 -8.6049777012 -4.0752740753 3.9358178092

3.592E-003 5.4038157857 -9.1049811795 -4.0752740753 5.4022530065

1.156E-002 6.8961257726 -9.6049822794 -4.0752740753 6.8910753326

3.596E-002 8.4033828293 -10.1049826273 -4.0752740753 8.3874799202

1.057E-001 9.9348766955 -10.6049827373 -4.0752740753 9.8863367283

2.723E-001 11.5240434706 -11.104982772 -4.0752740753 11.3859745921

5.421E-001 13.2250780545 -11.604982783 -4.0752740753 12.8858600117

7.892E-001 15.0619592132 -12.1049827865 -4.0752740753 14.3858237719

9.221E-001 16.994362481 -12.6049827876 -4.0752740753 15.8858123112

9.740E-001 18.9705953562 -13.104982788 -4.0752740753 17.385808687

9.916E-001 20.9628006245 -13.6049827881 -4.0752740753 18.8858075409

9.973E-001 22.9603063203 -14.1049827881 -4.0752740753 20.3858071785

9.992E-001 24.9595145622 -14.6049827881 -4.0752740753 21.8858070639

9.997E-001 26.9592638857 -15.1049827881 -4.0752740753 23.3858070276

9.999E-001 28.9591845848 -15.6049827881 -4.0752740753 24.8858070162

1.000E+000 30.9591595046 -16.1049827881 -4.0752740753 26.3858070125

1.000E+000 32.9591515732 -16.6049827881 -4.0752740753 27.8858070114

1.000E+000 34.9591490651 -17.1049827881 -4.0752740753 29.385807011

1.000E+000 36.9591482719 -17.6049827881 -4.0752740753 30.8858070109


78/88

3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20


"H

3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20



79/88

"H

7 8



80/88

"H


81/88

log[CuO2(-2a)] log([Cu(+2a)]/[CuT]) log([CuOH(+a)]/[CuT]) log([Cu(OH)3(-a)]/[CuT])

-43.0408520949 -1.255554361453E-013 -12.5389680282 -27.4913621371

-41.0408520949 -1.255506145081E-012 -11.53896883 -25.4913629387

-39.0408520949 -1.255486858548E-011 -10.5389713652 -23.4913654737

-37.0408520949 -1.255466125671E-010 -9.5389793823 -21.49137349-35.0408520949 -1.255392597334E-009 -8.5390047344 -19.4913988397

-33.0408520949 -1.255160933984E-008 -7.5390849029 -17.4914790005

-31.0408520949 -1.254428686926E-007 -6.5393383976 -15.4917324709

-29.0408520949 -1.252117616215E-006 -5.5401398165 -13.4925338128

-27.0408520949 -1.244854194431E-005 -4.5426720971 -11.4950658501

-25.0408520949 -0.0001222325 -3.5506592785 -9.503052262

-23.0408520949 -0.0011552195 -2.5757021335 -7.528092684

-21.0408520949 -0.0097762574 -1.6525391036 -5.6049219598

-19.0408520949 -0.063004302 -0.8700198596 -3.8223783855

-17.0408520949 -0.2528765525 -0.360016647 -2.3122982428-15.0408520949 -0.6404449143 -0.1588407788 -1.1108791895

-13.0408520949 -1.3594021324 -0.3454891201 -0.2967594071

-11.0408520949 -2.6138428704 -1.0891915833 -0.0380417524

-9.0408520949 -4.0906309585 -2.0625279205 -0.0038125697

-7.0408520949 -5.6113688406 -3.0821685288 -0.000361033

-5.0408520949 -7.1772498793 -4.1477020014 -3.42848740954274E-005

-3.0408520949 -8.837207872 -5.307550026 -2.5296096332801E-005

-1.0408520949 -10.6326369524 -6.6029443257 -0.0001174145

0.9591479051 -12.5412535356 -8.0115499097 -0.0004580252

2.9591479051 -14.5087969651 -9.4790898609 -0.0015627792

4.9591479051 -16.5011080521 -10.9713998479 -0.00505044

6.9591479051 -18.5083654566 -12.4786569046 -0.0159029092

8.9591479051 -20.5398594327 -14.0101507707 -0.0485399672

10.9591479051 -22.6290262427 -15.5993175459 -0.1380688786

12.9591479051 -24.8300608375 -17.3003521298 -0.3392180428

14.9591479051 -27.1669419997 -19.1372332884 -0.6761354413

16.9591479051 -29.5993452687 -21.0696365563 -1.1085501698

18.9591479051 -32.0755781441 -23.0458694314 -1.5847866692

20.9591479051 -34.5677834126 -25.0380746998 -2.0769930836

22.9591479051 -37.0652891084 -27.0355803956 -2.5744991418

24.9591479051 -39.5644973504 -29.0347886375 -3.0737074984

26.9591479051 -42.0642466739 -31.034537961 -3.5734568581

28.9591479051 -44.5641673729 -33.03445866 -4.0733775686

30.9591479051 -47.0641422927 -35.0344335798 -4.573352492

32.9591479051 -49.5641343613 -37.0344256485 -5.0733445618

34.9591479051 -52.0641318532 -39.0344231403 -5.573342054

36.9591479051 -54.5641310601 -41.0344223472 -6.073341261


82/88

ECA Cu A1

#g/$ A2

#g/$ A3

ECA & A1

#ol/$ A2

#ol/$ A3

ECA & A1

log[#ol/$] A2

log[#ol/$] A3

log[CuT]log[Cu(+2a)]

log[CuOH(+a)]

log[Cu(OH)3(-a)]

log[CuO2(-2a)]

ECA A1! A2 " A3


83/88

'o u#pl o& lo* l#,* p#,*,l*ga * po &,#a la l&a u

E*a ,&lu*o po (#* po &,#a l, u#o* *olu,o&a * pol#aa u &o *a la l pH "a u &o

oa #,a #,a,& (gu&a

O*a#o* & la ga au&a ul pH;7!0. 'o a"ua & #u


84/88


85/88

log([CuO2(-2a)]/[CuT])

-51.5045460479

-48.5045468496

-45.5045493848

-42.5045574019-39.504582754

-36.5046629225

-33.5049164172

-30.5057178361

-27.5082501167

-24.5162372981

-21.5412801531

-18.6181171232

-15.8355978792

-13.3255946667-11.1244187984

-9.3110671397

-8.0547696029

-7.0281059401

-6.0477465484

-5.113280021

-4.2731280456

-3.5685223453

-2.9771279293

-2.4446678806

-1.9369778675

-1.4442349242

-0.9757287903

-0.5648955655

-0.2659301494

-0.102811308

-0.0352145759

-0.0114474511

-0.0036527194

-0.0011584152

-0.0003666571

-0.0001159806

-3.6679641507542E-005

-1.1599455923682E-005

-3.6681035185931E-006

-0.00000116

-3.6681174565666E-007


86/88

2

2

2

3.15E-05

3.15E-05

3.15E-05

-4,.2.2

-4,.2.2

-4,.2.2


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& oo l a&go pH! ao u lo#,&a l ECA (A1! A2 " A3).

a l&a lo* ECA) u a 25 C. o&a#,&a,&! &*,a#o* oa"uaa & &aa. E* ,! &*,a#o*

5).

:,* u& #&,#o log[CuT];-3!91 ua&o * u &aa) llga a * #&,#o.


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Documents

(2013-II) 2da Practica - CuCO3 (Funda II)