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B GIO DC V O TO TRNG I HC BCH KHOA H NI

CHNG TRNH O TO TIN S

CHUYN NGNH HA L THUYT V HA L

M S: 62440119

c Hi ng Xy dng Chng trnh o to bc Tin s thng qua ngy 15 thng 12 nm 2014

H NI - 2014

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MC LC

Trang

PHN I TNG QUAN V CHNG TRNH O TO 1 Mc tiu o to 1.1 Mc tiu chung 1.2 Mc tiu c th 2 Thi gian o to 3 Khi lng kin thc 4 i tng tuyn sinh 4.1 nh ngha 4.2 Phn loi i tng 5 Quy trnh o to, iu kin cng nhn t 6 Thang im 7 Ni dung chng trnh 7.1 Cu trc 7.2 Hc phn b sung 7.3 Hc phn Tin s 7.3.1 Danh mc hc phn Tin s 7.3.2 M t tm tt hc phn Tin s 7.3.3 K hoch hc tp cc hc phn Tin s 7.4 Chuyn Tin s 8 Danh sch Tp ch / Hi ngh Khoa hc PHN II CNG CHI TIT CC HC PHN 9 Danh mc hc phn chi tit ca chng trnh o to 9.1 Danh mc hc phn b sung 9.2 Danh mc hc phn Tin s 10 cng chi tit cc hc phn Tin s

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PHN I

TNG QUAN V CHNG TRNH O TO

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TRNG I HC BCH KHOA H NI VIN K THUT HA HC

CNG HA X HI CH NGHA VIT NAM c lp - T do - Hnh phc

CHNG TRNH O TO TIN S CHUYN NGNH HA L THUYT V HA L

Tn chng trnh: Chng trnh o to Tin s chuyn ngnh Ha l thuyt v Ha l Trnh o to: Tin s Chuyn ngnh o to: Ha l thuyt v Ha l Theoretical and Physical Chemistry M chuyn ngnh: 62440119 (Ban hnh theo Quyt nh s 3446/Q-HBK-SH ngy 4 thng 9 nm 2014 ca Hiu trng

trng H Bch Khoa H Ni) 1 Mc tiu o to 1.1 Mc tiu chung o to Tin s chuyn ngnh Ha l thuyt v Ha l c trnh chuyn mn su cao, c kh

nng nghin cu c lp v lnh o nhm nghin cu cc lnh vc ca chuyn ngnh, c t duy khoa hc, c kh nng tip cn v gii quyt cc vn khoa hc chuyn ngnh, c kh nng trnh by - gii thiu cc ni dung khoa hc, ng thi c kh nng o to cc bc i hc v Cao hc.

1.2 Mc tiu c th Sau khi kt thc thnh cng chng trnh o to, Tin s chuyn ngnh Ha l thuyt v Ha

l C kh nng tip cn v trc tip gii quyt cc vn chuyn mn thuc lnh vc Ha l thuyt v Ha l.

C kh nng dn dt, lnh o nhm nghin cu thuc lnh vc Ha l thuyt v Ha l.

C kh nng nghin cu, xut v p dng cc gii php cng ngh thuc lnh vc Ha l thuyt v Ha l trong thc tin.

C kh nng cao trnh by, gii thiu (bng cc hnh thc bi vit, bo co hi ngh, ging dy i hc v sau i hc) cc vn khoa hc thuc lnh vc Ha l thuyt v Ha l.

2 Thi gian o to H tp trung lin tc: 3 nm lin tc i vi NCS c bng ThS, 4 nm i vi NCS c bng

H. H khng tp trung lin tc: NCS c vn bng ThS ng k thc hin trong vng 4 nm m

bo tng thi gian hc tp, nghin cu ti Trng l 3 nm v 12 thng u tin tp trung lin tc ti Trng.

3 Khi lng kin thc

Khi lng kin thc bao gm khi lng ca cc hc phn Tin s v khi lng ca cc hc phn b sung c xc nh c th cho tng loi i tng ti mc 4.

NCS c bng ThS: ti thiu 8 tn ch + khi lng b sung (nu c).

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NCS mi c bng H: ti thiu 8 tn ch + 28 tn ch (khng k lun vn) ca Chng trnh Thc s Khoa hc chuyn ngnh Ha l thuyt v Ha l. i vi NCS c bng H ca cc h 4 hoc 4,5 nm (theo quy nh) s phi thm cc hc phn b sung ca Chng trnh Thc s Khoa hc chuyn ngnh Ha l thuyt v Ha l.

4 i tng tuyn sinh i tng tuyn sinh l cc th sinh c bng Thc s vi chuyn ngnh tt nghip ph hp

(ng ngnh) hoc gn ph hp vi chuyn ngnh Ha l thuyt v Ha l. Ch tuyn sinh mi c bng H vi chuyn ngnh tt nghip ph hp. Mc ph hp hoc gn ph hp vi chuyn ngnh Ha l thuyt v Ha l, c nh ngha c th mc 4.1 sau y.

4.1 nh ngha Ngnh ph hp: L nhng hng o to chuyn su thuc ngnh Ha l thuyt v Ha l.

Ngnh gn ph hp: L nhng hng o to chuyn su thuc cc ngnh sau Mi trng, Sinh hc Thc phm, Hu c Ha du, Ha Hu c, Ha Phn tch v ngnh Ha ca cc trng i hc K thut khc.

4.2 Phn loi i tng C bng ThS Khoa hc ca H Bch Khoa H Ni vi ngnh tt nghip cao hc ng vi

chuyn ngnh Tin s. y l i tng khng phi tham gia hc b sung, gi tt l i tng A1.

C bng tt nghip i hc loi xut sc vi ngnh tt nghip ng vi chuyn ngnh Tin s. y l i tng phi tham gia hc b sung, gi tt l i tng A2.

C bng ThS ng ngnh, nhng khng phi l ThS Khoa hc ca H Bch Khoa H Ni hoc c bng ThS tt nghip ngnh gn ph hp. y l i tng phi tham gia hc b sung, gi tt l i tng A3.

5 Quy trnh o to, iu kin cng nhn t

Quy trnh o to c thc hin theo hc ch tn ch, tun th Quy nh 1035/2011 v t chc v qun l o to sau i hc ca H Bch Khoa H Ni.

Cc hc phn b sung phi t mc im C tr ln (xem mc 6).

Cc hc phn Tin s phi t mc im B tr ln (xem mc 6). 6 Thang im Khon 6a iu 62 ca Quy nh 1035/2011 quy nh: Vic chm im kim tra - nh gi hc phn (bao gm cc im kim tra v im thi kt thc hc

phn) c thc hin theo thang im t 0 n 10, lm trn n mt ch s thp phn sau du phy. im hc phn l im trung bnh c trng s ca cc im kim tra v im thi kt thc (tng ca tt c cc im kim tra, im thi kt thc nhn vi trng s tng ng ca tng im c quy nh trong cng chi tit hc phn).

im hc phn c lm trn n mt ch s thp phn sau du phy, sau c chuyn thnh im ch vi mc nh sau:

im s t 8,5 10 chuyn thnh im A (Gii) im s t 7,0 8,4 chuyn thnh im B (Kh) im s t 5,5 6,9 chuyn thnh im C (Trung bnh) im s t 4,0 5,4 chuyn thnh im D (Trung bnh yu)

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im s di 4,0 chuyn thnh im F (Km) 7 Ni dung chng trnh 7.1 Cu trc Cu trc chng trnh o to trnh Tin s gm c 3 phn nh bng sau y.

Phn Ni dung o to A1 A2 A3

1 HP b sung 0 CT ThS KH (28TC) 4TC

HP TS 8TC

2 TLTQ Thc hin v bo co trong nm hc u tin

CTS Tng cng 3 CTS, mi CTS 2TC

3 NC khoa hc Lun n TS

Lu : - S TC qui nh cho cc i tng trong l s TC ti thiu NCS phi hon thnh. - i tng A2 phi thc hin ton b cc hc phn qui nh trong chng trnh ThS Khoa hc

ca ngnh tng ng, khng cn thc hin lun vn ThS. - Cc HP b sung c la chn t chng trnh o to Thc s ca ngnh ng chuyn ngnh

Tin s. - Vic qui nh s TC ca HP b sung cho i tng A3 do ngi hng dn (NHD) quyt nh

da trn c s i chiu cc hc phn trong bng kt qu hc tp ThS ca th sinh vi chng trnh ThS hin ti ca ngnh ng chuyn ngnh Tin s nhng phi m bo s TC ti thiu trong bng.

- Cc HP TS c NHD xut t chng trnh o to Thc s v Tin s ca trng nhm trang b kin cn thit phc v cho ti nghin cu c th ca LATS. 7.2 Hc phn b sung Cc hc phn b sung c m t trong quyn Chng trnh o to Thc s chuyn ngnh

K thut ha hc hin hnh ca trng H Bch Khoa H Ni.

NCS phi hon thnh cc hc phn b sung trong thi hn 2 nm k t ngy c quyt nh cng nhn l NCS.

7.3 Hc phn Tin s 7.3.1 Danh mc hc phn Tin s

TT M S TN HC PHN GING VIN TN CH KHI

LNG

1 CH7100 ng hc v c ch cc phn ng xc tc phc GS. TSKH Nguyn Vn Xuyn 3 3(3-0-0-6)

2 CH7101 Cu trc lin kt ha hc v nhng c trng ha l ca cc cht xc tc phc

GS. TSKH Nguyn Vn Xuyn 2 2(2-0-0-4)

3 CH7102 Mt s ng dng thc tin ca xc tc phc GS. TSKH Nguyn Vn Xuyn 2 2(2-0-0-4)

4 CH7103 Quang ha hc TS Trn Vn Anh 2 2(2-0-0-4) 5 CH7104 Cc phng php cng hng t TS Trn Vn Anh 2 2(2-0-0-4)

7.3.2 M t tm tt hc phn Tin s

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CH7100 ng hc v c ch cc phn ng xc tc phc Cung cp cho NCS chuyn ngnh ha l thuyt v ha l v cc lnh vc c lin quan nhng

kin thc v: Quy lut ng hc, c ch v cc iu kin ti u ca phn ng xc tc phc ph thuc rt nhy cm, a chiu, nhiu bin vo cc yu t nh hng khc nhau: Cu trc phn t, cc c trng vt l v ha l, tng quan nng ca cht xc tc, cc cht phn ng, pH mi trng. Cc c trng ng hc: tc v hng s tc phn ng, cc hng s tc phn ng giai on, nng lng hot ha, bc chung, bc ring ca phn ng, phng trnh ng hc tng qut. Cc c trng c ch: S to thnh v phn hy phc trung gian hot ng c to thnh gia xc tc phc v cc cht phn ng, chu trnh oxi ha kh thun nghch, s pht sinh v hy dit gc t do, cc trng thi ha tr ca kim loi, cc loi c ch mch gc, phn t, hn hp, ni cu, ngoi cu, s c ch, mi quan h gia nhit ng hc, ng hc v c ch ca phn ng xc tc phc...

CH7100 Kinetics and mechanism of catalytic reactions by complexes PhD students of theoretical chemistry and physical chemistry and related fields will be provided

with fundamental knowledge about thermodynamics, kinetics, mechanism, their relations and optimal conditions of the complex catalyst reactions depending upon different influential factors such as molecular structure, physical and physiochemical properties, concentration correlation of catalyst, reactants and pH of medium.

To study problems mentioned above, it is necessary to use physical and physicochemical methods of thermodynamics, kinetics, electrochemistry, inhibitors and concurrents, electron absorption spectroscopy of molecules (UV-VIS), atomic absorption spectroscopy (AAS), infrared spectroscopy (IRS), Raman spectroscopy (RS), Gas chromatography (GC), Mass-spectroscopy (MS), Electron paramagnetic resonance (EPR), Nuclear magnetic resonance (NMR), Magnetic chemistry, etc.

CH7101 Cu trc lin kt ha hc v nhng c trng ha l ca cc cht xc tc phc

Trn c s l thuyt hin i ca ha hc lng t, ha l, ha hc phi tr,... cung cp cho

nghin cu sinh chuyn ngnh ha l thuyt v ha l v cc lnh vc c lin quan nhng kin thc c bn v: Cu trc electron, cu trc hnh hc, cc tnh cht nhit ng hc, ng hc, in ha, quang hc, t hc, c ch hot ng, hot tnh, chn lc xc tc... c trng cho mi dng phc cht ca kim loi chuyn tip vi ligan c bn cht khc nhau ng vai tr xc tc (xc tc phc): phc n nhn, a nhn, phc hn hp kim loi, phc hn hp ligan. Cc cht xc tc phc ny c xem l m hnh ha ca cc cht xc tc sinh hc, do , c tnh u vit hot tnh v chn lc rt cao nhit v p sut thng v s dng lm xc tc hu hiu cho nhiu phn ng ha hc khc nhau: oxy ha, hydro ha, hydroxyl ha, carbonyl ha, carboxyl ha, polime ha, oligome ha...

CH7101 Structure, chemical bond and characteristics of complex catalysts On the basis of modern theories of quantum chemistry, physical chemistry, coordinate chemistry, etc, PhD students of theoretical chemistry and physical chemistry and related fields will be provided with fundamental knowledge on electron structure, geometrical structure and properties of thermodynamics, kinetics, electrochemistry, optics, magnetics, acting mechanism, activity and selectivity typical for every type of mono-, polynuclear-, mixed metal-, mixed ligand complex catalysts formed by transition metal ions and various ligands. Considered as models of biocatalysts, the complex catalysts have superiorities such as very high activity and selectivity at normal temperature and pressure for many different chemical reactions including oxidation, reduction, hydrogenation, carbonization, carboxylation, polymerization, oligomerization, etc.

CH7102 Mt s ng dng thc tin ca xc tc phc Cung cp cho sinh vin chuyn ngnh Ha l thuyt v ha l v cc lnh vc c lin quan

nhng kin thc v: C s khoa hoc, k thut thc nghim, hiu lc ca mi phng php: ph hp

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th electron phn t (UV vis) ph hng ngoi (IRS), ph Raman, ph hunh quang, ph hp th nguyn t (AAS), cc ph , ph khi lng (MS), sc k, cng hng t electron (EPR), cng hng t ht nhn (NMR), ng hc, cc cht c ch, cc cht cnh tranh c ng dng nghin cu xc nh cu trc phn t, thnh phn, bn nhit ng, hot tnh, chn lc, c ch hot ng, cc tnh cht vt l v ha l c trng khc cng nh iu kin to thnh ti u ca mi dng phc cht ng vai tr xc tc. Trn c s tng hp ra cht xc tc phc hu hiu, thch hp cho mi loi phn ng ha hc.

CH7102 Some practical applications of complex catalysis The research outcomes on synthesizing complex catalysts, thermodynamics, kinetics,

mechanism of catalysis, their relations and optimal conditions of catalytic reactions are applied to solve various actual practical problems such as:

Establishing scientific and experimental bases for improving and innovating technological processes.

Applying in industrial processes: isomerization, hydroxylation, hydroformylation, oxidation, hydrogenation, polymerization, oligomerization, synthesis of organic compounds.

Using in waste water treatment and environment protection. Microanalysis of super-clean materials by means of catalytic kinetic method. Color bleaching in paper and textile industries. Keeping and preserving the quality of industrial products, food, pharmaceutical and

agricultural products. Producing multi-, medium- and micro fertilizers for higher productivity of plants.

CH7103 Quang ha hc Hc phn cung cp cho sinh vin kin thc c bn v phn ng quang ha, cc giai on ca

phn ng quang ha nh kt qu mt qu trnh kch thch phn t. Ngoi ra, hc phn b sung cc kin thc v nhng cht mang c tnh quang ha trn v d zn, ng dng ca quang ha trong cc phng php phn tch Ha l hin i trn v d Laser, Ph quang electron, Ph Raman, ...

CH7103 Photochemistry The subject provides PhD students with basic knowledge on photochemical processes as a result

of molecular excitation. Moreover, knowledge on photochemical sensitive substances (sensitive to ozone, for example) and application of photochemistry in modern physico-analytical methods, such as Laser, Photoelectron spectroscopy, Photoemission spectroscopy, Photolysis are also provided.

CH7104 Cc phng php cng hng t Hc phn cung cp cho sinh vin kin thc l thuyt c bn v hin tng cng hng t,

nguyn l cc phng php cng hng t cng nh ng dng ca chng trong nghin cu hin i.

CH7104 Magnetic resonance spectroscopy The subject provides PhD students with the basic theoretical background on the magnetic

resonance phenomena, basic principles of the magnetic resonance spectroscopy as well as their applications in modern research.

7.3.3 K hoch hc tp cc hc phn Tin s Cc hc phn Tin s c thc hin linh hot, ty theo cc iu kin thi gian c th ca ging

vin. Tuy nhin, nghin cu sinh phi hon thnh cc hc phn Tin s trong vng 24 thng k t ngy chnh thc nhp trng.

7.4 Chuyn Tin s

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Mi nghin cu sinh phi hon thnh 3 chuyn Tin s, c th ty chn t danh sch hng chuyn su. Mi hng chuyn su u c ngi hng dn do Hi ng Xy dng chng trnh o to chuyn ngnh ca Vin K thut ha hc quyt nh. Ngi hng dn khoa hc lun n ca nghin cu sinh s xut ti c th. u tin xut ti gn lin, thit thc vi ti ca lun n Tin s.

Sau khi c ti c th, NCS thc hin ti di s hng dn khoa hc ca ngi hng dn chuyn .

Danh mc hng chuyn su cho Chuyn Tin s

TT M S HNG CHUYN SU NGI HNG DN TN CH

1 CH7150 Xc tc phc GS. TSKH Nguyn Vn Xuyn 2

2 CH7151 Xc tc phc trong bo v mi trng GS. TSKH Nguyn Vn Xuyn 2

3 CH7152 Phng php ng hc xc tc trong phn tch vi lng

GS. TSKH Nguyn Vn Xuyn 2

4 CH7153 Cng hng t electron TS Trn Vn Anh 2 5 CH7154 n mn v bo v kim loi TS Trn Vn Anh 2

6 CH7155 Mt s phng php x l nc thi TS Trn Th Thanh Thy 2

8 Danh sch Tp ch / Hi ngh khoa hc Cc din n khoa hc trong nc trong bng di y l ni NCS c th chn cng b cc kt

qu nghin cu khoa hc phc v hon thnh lun n Tin s.

S TT Tn din n a ch lin h

nh k xut bn /

hp

1 Tp ch Ha hc 70 Trn Hng o 6 s/1 nm

2 Tp ch Khoa hc cng ngh S 1 i c vit, H Ni 6 s /1 nm

3 Ha hc ng dng 139 L c 4 s /1 nm

4 Cc tp ch, hi ngh khoa hc quc t chuyn ngnh

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PHN II

CNG CHI TIT CC HC PHN

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9 Danh mc hc phn chi tit ca chng trnh o to 9.1 Danh mc hc phn b sung Danh mc hc phn b sung c th xem chi tit trong quyn Chng trnh o to Thc s K

thut ha hc. 9.2 Danh mc hc phn Tin s

S TT M S TN HC PHN TN TING ANH

KHI LNG

Khoa/Vin B mn

nh gi

1 CH 7100 ng hc v c ch cc phn ng xc tc phc

Kinetics and mechanism of catalytic reactions by complexes

3(3-0-0-6) CNHH

2 CH 7101

Cu trc lin kt ha hc v nhng c trng ha l ca cc cht xc tc phc

Structure, chemical bond and physico-chemical characteristics of complex catalysts

2(2-0-0-4) CNHH

3 CH 7102 Mt s ng dng thc tin ca xc tc phc

Some practical applications of complex catalysis

2(2-0-0-4) CNHH

4 CH 7103 Quang ha hc Photochemistry 2(2-0-0-4) CNHH

5 CH 7104 Cc phng php cng hng t Magnetic resonance 2(2-0-0-4) CNHH

10 cng chi tit cc hc phn Tin s CH7100 ng hc v c ch cc phn ng xc tc phc Kinetics and mechanism of catalytic reactions by complexes 1. Tn hc phn: ng hc v c ch cc phn ng xc tc phc 2. M hc phn: CH7100 3. Tn ting Anh: Kinetics and mechanism of catalytic reactions by complexes 4. Khi lng: 3(3-0-0-6) - L thuyt: 45 tit - Bi tp: - Th nghim: 5. i tng tham d: Tt c NCS thuc chuyn ngnh Ha l thuyt v Ha l 6. Mc tiu ca hc phn: Hc phn ny nhm mang li cho NCS: - Cc kin thc nng cao, hin i ca chuyn ngnh Ha l thuyt v ha l v phn ng cc

xc tc phc - Rn luyn kh nng t duy khoa hc. - Rn luyn k nng thc nghim cho vic nghin cu cc phn ng xc tc phc, to c s khoa

hc v thc nghim cho vic gii quyt nhiu vn thc tin khc nhau c lin quan 7. Ni dung tm tt: - Phn ng xc tc phc l m hnh ca cc phn ng sinh hc - Cc phng php vt l v ha l nghin cu phn ng xc tc phc - Nhit ng hc, ng hc v c ch ca cc phn ng xc tc 8. Nhim v ca NCS: - D lp: - Bi tp: 9. nh gi kt qu: - Mc d gi ging:

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- Kim tra nh k: - Thi kt thc hc phn: 10. Ni dung chi tit hc phn: PHN M U Gii thiu mn hc Gii thiu cng mn hc Gii thiu ti liu tham kho CHNG 1: ng dng cc phng php vt l v ha l nghin cu phn ng xc tc

phc 1.1 Phng php nhit ng hc 1.2 Phng php ng hc 1.3 Phng php cc cht c ch v cc cht cnh tranh 1.4 Phng php in ha hc 1.5 Phng php ph dao ng (IRS, Raman) 1.6 Phng php ph hp th electron phn t (UV-Vis) 1.7 Phng php ph pht quang phn t 1.8 Phng php ph hp th nguyn t (AAS) 1.9 Phng php sc k v ph khi lng (GC/MS) 1.10 Phng php cng hng t electron (EPR) v cng hng t ht nhn (NMR) 1.11 Phng php ha t 1.12 ng dng tin hc CHNG 2: ng hc cc phn ng xc tc phc 2.1 Phc cht ng vai tr xc tc cho phn ng 2.1.1 Cu trc thnh phn hng s bn v cc c trng ca cc cht xc tc phc 2.1.2 Hot tnh v chn lc ca cht xc tc phc 2.1.3 b tr trong phn ng xc tc phc 2.2 Phc trung gian hot ng 2.2.1 S to thnh t cht xc tc phc v cc cht phn ng 2.2.2 Cu trc, thnh phn, hng s bn v cc c trng ha l 2.3 Phn ng to thnh phc trung gian hot ng 2.3.1 S ph thuc tc phn ng v cc yu t nh hng khc nhau 2.3.2 Bc ring ca phn ng 2.3.3 Phng trnh ng hc ca phn ng 2.4 Phn ng xc tc phc 2.4.1 S ph thuc tc phn ng v cc yu t nh hng khc nhau 2.4.2 Bc ring, hng s tc v nng lng hot ha ca phn ng 2.4.3 Phng trnh ng hc v cc iu kin ti u ca phn ng 2.4.4 Mi quan h gia cc thng s nhit ng hc v ng hc ca phn ng 2.4.5 Mi quan h gia thng s cu trc v thng s nng lng ca phn ng CHNG 3: C ch ca phn ng xc tc phc 3.1 C ch vn chuyn electron gia cc cu t hp thnh phc trung gian hot ng 3.1.1 C ch vn chuyn electron ni cu 3.1.2 C ch vn chuyn electron ngoi cu 3.2 S phn hy phc trung gian hot ng 3.2.1 S pht sinh v hy dit cc gc t do 3.2.2 S thay i cc trng thi ha tr ca ion kim loi 3.2.3 Chu trnh oxy ha kh thun nghch- ngun pht sinh gc t do v hon nguyn cht xc

tc phc 3.3 C ch cc phn ng xc tc phc

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3.3.1 nh hng ca cc cht c ch tng tc c th vi cc gc t do v ca cc cht cnh tranh n tc phn ng xc tc phc

3.3.2 Tc phn ng sinh mch v cc yu t nh hng 3.3.3 Phng trnh ng hc phn ng sinh mch 3.3.4 C ch ca phn ng xc tc phc - C ch mch gc - C ch phn t- ion - C ch hn hp 11. Ti liu hc tp: Nguyn Vn Xuyn (2007), Cu to phn t v lin kt ha hc, Nh xut bn Khoa hc v K

thut, H Ni. 12. Ti liu tham kho:

[1] o nh Thc (2007), Mt s phng php ph ng dng trong ha hc, Nh xut bn i hc Quc Gia H Ni.

[2] T Vn Mc (2003), Phn tch ha l: Phng php ph nghim nghin cu cu trc phn t, Nh xut bn Khoa hc v k thut, H Ni

[3] Nguyn Vn Xuyn (1994), Xc tc ng th oxy ha kh bng phc cht mt nhn v hai nhn mt s ion kim loi chuyn tip, Lun n tin s khoa hc Ha hc, Trng i hc Bch Khoa H Ni, H Ni. [3] Trn Th Minh Nguyt (2002), Nghin cu tnh cht catalaza v peroxidaza ca phc cht

mt s kim loi chuyn tip vi etylendiamin, Lun n tin s ha hc, Trng i hc Bch Khoa H Ni, H Ni.

[4] V Th Kim Loan (2008), Xc tc ng th oxy ha- kh bng phc cht ca ion kim loi chuyn tip, Lun n Tin s ha hc, Trng i hc Bch Khoa H Ni, H Ni.

[5] Nguyn Vn Dng (2010), Nghin cu tnh cht catalaza v peroxidaza ca phc Co(II)-Axit citric, Lun n Tin s ha hc, Trng i hc Bch Khoa H Ni, H Ni.

[6] Nguyn Vn Xuyn, Trn Th Minh Nguyt (2001), Xc tc phc, Cc bo co khoa hc Hi ngh xc tc hp ph Ton quc ln th 2, H Ni, tr 127-160.

[7] G. Henrici-Olive, S. Olive (1997), Coordination and Catalysis, Verlagchimie-Weinheim-New- York.

[8] Cristopher Masters (1981), Homogeneous Transition- Metal Catalysis, London New York Chapman and Hall.

[9] Piet W.N.M. VanleenWen, Keij Morokuma and Jooph. Van Lenthe (1995), Theorical Aspects of Homogeneous Catalysis, Kluwer Academic Publishers.

[10] Surit Bhaduri, Doble Mukesh (2000), Homogenous Catalysis Mechanisms and Industrial Application, A.John Wiley and Sons Publication, New York- Chichester-Weiheim- Brisbane-Singapore-Toronto

[11] W. P. Kwar, B.M.Voeler (2003), Rates of hydroxyl radical generation and organic compound oxidation in mineral-catalyzed Fenton-like system, Environ.Sci.Tech, 37,pp 1150-1158

[12] Maria Papadaki, Jun Gao (2005), Kinetic models of complex reaction systems, Computers and Chemical Engineering, 29 (11-12), pp 2449-2460

[13] Syuhei Yamaguchi, Hideki Masuda (2004), Basic approach to development of enviroment-friendly oxidation catalyst materials, Mononuclear hydroperoxo copper(II) complexes, Sc. And Tech of Advanced materials, 20. pp 1-14.

[14] Udai P Singh, Vaibhave Aggarwal and Asish K. Sharma (2007), Mononuclear cobalt (II) carboxyllate complexes: Synthesis, molecular structure and selective oxygenation study, Inorganica Chimica Acta, 360 (10), pp 3226-3332

[15] Anirban J.S, Jubaraj B.B (2007), Synthesis and Characterisation of dinuclear and mononuclear cobalt (II) benzoate complexes, Polyhedron, 26(6), pp 1347-1355

14

[16] Kassinos D, Varnava N, Micheal C, Piera P (2009), Homogenous oxidation of aqueous solution of a7trazine and fenitrothion through dark and photo-Fenton reactions, Chemosphere, 74(6), pp 866-872.

15

CH7101 Cu trc, lin kt ha hc v nhng c trng ha l ca cc cht xc tc phc ng th

Structure, chemical bond and physico-chemical characteristics of complex catalysts

1. Tn hc phn: Cu trc, lin kt ha hc v nhng c trng ha l ca cc cht xc tc

phc ng th 2. M hc phn: CH7101 3. Tn ting Anh: Structure, chemical bond and physico-chemical characteristic of complex

catalysts 4. Khi lng: 2(2-0-0-4) - L thuyt: - Bi tp: - Th nghim: 5. i tng tham d: Tt c NCS thuc chuyn ngnh Ha l thuyt v Ha l 6. Mc tiu ca hc phn: Hc phn ny nhm mang li cho NCS: - Cc kin thc nng cao, hin i ca chuyn ngnh Ha l thuyt v ha l v cc cht xc tc

phc. - Rn luyn kh nng t duy khoa hc. - Rn luyn k nng vn dng nhng kin thc vo nghin cu khoa hc v gii quyt nhng

vn thc tin v xc tc phc v cc lnh vc c lin quan. 7. Ni dung tm tt: - Xc tc phc l m hnh ha tm hot ng ca xc tc sinh hc (enzym) - Cc l thuyt hin i v s to phc gia ion kim loi chuyn tip vi ligan c bn cht khc nhau - Cu trc, lin kt ha hc, thnh phn v cc c trng ha l ca cc cht xc tc phc. 8. Nhim v ca NCS: - D lp: - Bi tp: 9. nh gi kt qu: - Mc d gi ging: - Kim tra nh k: - Thi kt thc hc phn: 10. Ni dung chi tit hc phn: PHN M U Gii thiu mn hc Gii thiu cng mn hc Gii thiu ti liu tham kho CHNG 1: Mi quan h tng h gia xc tc sinh hc v xc tc phc

1.1 Xc tc sinh hc l m hnh xc tc phc hon ho 1.1.1 c im cu trc tm hot ng ca cc cht xc tc sinh hc 1.1.2 C ch vn chuyn electron ca tm hot ng ca xc tc sinh hc 1.1.3 Cc tnh cht u vit v hn ch ca cc cht xc tc sinh hc 1.2 Xc tc phc l m hnh ha tm hot ng ca xc tc sinh hc

1.2.1 Ch to (tng hp) cc cht xc tc phc trn c s m phng theo cu trc, thnh phn, c ch vn chuyn electron ca tm hot ng xc tc sinh hc. 1.2.2 u nhc im ca cc cht xc tc phc 1.2.3 Vn d th ha cc cht xc tc phc ng th CHNG 2: S to phc gia ion kim loi chuyn tip (Mz+) v ligan (L) trong dung dch

16

2.1 c im cu trc electron v cc c trng ha l ca Mz+ 2.2 Bn cht ha hc v s phn loi ligan 2.3 Cc l thuyt hin i v s to phc gia Mz+ v (L)

2.3.1 L thuyt lin kt ha tr (VB) 2.3.2 L thuyt t hp tuyn tnh cc orbital nguyn t thnh cc orbital phn t

(MOLCAO) 2.3.3 L thuyt trng ligan

2.4 Nhit ng hc s to phc trong dung dch 2.4.1 Cu trc, thnh phn, bn nhit ng ca cc dng phc c to thnh 2.4.2 Hm to thnh v t phn nng ca mi dng phc

2.5 Xc nh dng phc ng vai tr xc tc 2.5.1 Hot tnh, chn lc xc tc 2.5.2 Cc tiu chun mt dng phc tr thnh cht xc tc

2.5.3 Mi quan h bin i tng ng gia tc phn ng xc tc v t phn nng ca dng phc tng ng.

CHNG 3: Tc dng ca s to phc xc tc 3.1 Tng bn thy phn ca Mz+ 3.2 Tng hot tnh v chn lc xc tc 3.3 Thay i th oxy ha- kh ca Mz+ 3.4 Thay i c ch ca phn ng 3.5 Xc tc cho cc phn ng b ngn cm bi quy tc bo ton tnh i xng orbital phn t 3.6 Hot ha cc cht phn ng

11. Ti liu hc tp: Nguyn Vn Xuyn (2007), Cu to phn t v lin kt ha hc, Nh xut bn Khoa hc v K thut, H Ni.

12. Ti liu tham kho: [1] Nguyn Vn Xuyn (1994), Xc tc ng th oxy ha kh bng phc cht mt nhn v hai nhn mt s ion kim loi chuyn tip, Lun n tin s khoa hc Ha hc, Trng i hc Bch Khoa H Ni, H Ni. [2] Trn Th Minh Nguyt (2002), Nghin cu tnh cht catalaza v peroxidaza ca phc cht mt s kim loi chuyn tip vi etylendiamin, Lun n tin s ha hc, Trng i hc Bch Khoa H Ni, H Ni. [3] V Th Kim Loan (2008), Xc tc ng th oxy ha- kh bng phc cht ca ion kim loi chuyn tip, Lun n Tin s ha hc, Trng i hc Bch Khoa H Ni, H Ni. [4] Nguyn Vn Dng (2010), Nghin cu tnh cht catalaza v peroxidaza ca phc Co(II)-Axit citric, Lun n Tin s ha hc, Trng i hc Bch Khoa H Ni, H Ni. [5] Nguyn Vn Xuyn, Trn Th Minh Nguyt (2001), Xc tc phc, Cc bo co khoa hc Hi ngh xc tc hp ph Ton quc ln th 2, H Ni, tr 127-160. [6] G. Henrici-Olive, S. Olive (1997), Coordination and Catalysis, Verlagchimie-Weinheim-New- York. [7] Cristopher Masters (1981), Homogeneous Transition- Metal Catalysis, London New York Chapman and Hall. [8] Piet W.N.M. VanleenWen, Keij Morokuma and Jooph. Van Lenthe (1995), Theorical Aspects of Homogeneous Catalysis, Kluwer Academic Publishers. [9] Surit Bhaduri, Doble Mukesh (2000), Homogenous Catalysis Mechanisms and Industrial Application, A.John Wiley and Sons Publication, New York- Chichester-Weiheim- Brisbane-Singapore-Toronto [10] W. P. Kwar, B.M.Voeler (2003), Rates of hydroxyl radical generation and organic compound oxidation in mineral-catalyzed Fenton-like system, Environ.Sci.Tech, 37,pp 1150-1158 [11] Maria Papadaki, Jun Gao (2005), Kinetic models of complex reaction systems, Computers and Chemical Engineering, 29 (11-12), pp 2449-2460

17

[12] Syuhei Yamaguchi, Hideki Masuda (2004), Basic approach to development of enviroment-friendly oxidation catalyst materials, Mononuclear hydroperoxo copper(II) complexes, Sc. And Tech of Advanced materials, 20. pp 1-14. [13] Udai P Singh, Vaibhave Aggarwal and Asish K. Sharma (2007), Mononuclear cobalt (II) carboxyllate complexes: Synthesis, molecular structure and selective oxygenation study, Inorganica Chimica Acta, 360 (10), pp 3226-3332 [14] Anirban J.S, Jubaraj B.B (2007), Synthesis and Characterisation of dinuclear and mononuclear cobalt (II) benzoate complexes, Polyhedron, 26(6), pp 1347-1355 [15] Kassinos D, Varnava N, Micheal C, Piera P (2009), Homogenous oxidation of aqueous solution of atrazine and fenitrothion through dark and photo-Fenton reactions, Chemosphere, 74(6), pp 866-872.

18

CH7102 Mt s ng dng thc tin ca xc tc phc Some practical applications of complex catalysis 1. Tn hc phn: Mt s ng dng thc tin ca xc tc phc 2. M hc phn: CH7102 3. Tn ting Anh: Some practical applications of complexe catalysis 4. Khi lng: 2(2-0-0-4) - L thuyt: - Bi tp: - Th nghim: 5. i tng tham d: Tt c NCS thuc chuyn ngnh Ha l thuyt v Ha l 6. Mc tiu ca hc phn: Cung cp cho NCS: - Nhng kin thc c bn, hin i v xc tc phc - Rn luyn kh nng t duy khoa hc. - ng dng cc kin thc vo gii quyt nhng vn thc tin cp thit c lin quan. 7. Ni dung tm tt: - Loi phn ng xc tc phc cn chn p ng c yu cu ca vn thc tin cn c gii

quyt - Dng phc ng vai tr cht xc tc tng ng vi cc c trng v cu trc, thnh phn,

bn nhit ng, hot tnh v chn lc. - Cc kin thc v quy lut ng hc, c ch v iu kin ti u ca phn ng. 8. Nhim v ca NCS: - D lp: - Bi tp: 9. nh gi kt qu: - Mc d gi ging: - Kim tra nh k: - Thi kt thc hc phn: 10. Ni dung chi tit hc phn: PHN M U Gii thiu mn hc Gii thiu cng mn hc Gii thiu ti liu tham kho CHNG 1: Cc phn ng xc tc phc trong x l cc cht c hi bo v mi trng

1.1 Tnh u vit ca phn ng xc tc phc 1.1.1 Tc nhanh, chn lc cao nhit v p sut bnh thng 1.1.2 Nng sut cao, cht lng sn phm tt 1.1.3 Tit kim nguyn vt liu, nng lng, khng c cht thi

1.1.4 Di tc dng ca xc tc phc, O2(kk) v H2O2 tr thnh cc tc nhn oxy ha rt mnh tng ng l g2

1

O v gc t do OH thay th cho cc cht oxy ha KMnO4, K2Cr2O7, NaClO, Cl2t tin v c hi.

1.2 ng dng cc phn ng oxy ha cc cht c bng H2O2(O2) di tc dng ca cc xc tc phc trong x l cc loi nc thi (sn phm l cc cht khng c hoc CO2 v H2O)

1.2.1 X l nc thi cng nghip dt nhum, xc tc l [CoL]2- hoc [Mn(En)2]2+ 1.2.2 X l nc thi cng nghip giy, xc tc l [FeHLHCO3] 1.2.3 X l nc thi cng nghip ch bin thy sn, xc tc l [MnDETA]2+ 1.2.4 X l chuyn ha phenol, xc tc l [CoL]2- 1.2.5 X l r rc thi qua h sinh hc, xc tc l [MnHLHCO3] 1.2.6 X l chuyn ha thuc tr su 4,4-DDT, xc tc l [FeDETA]2+

CHNG 2: Cc phn ng xc tc phc trong i mi cc qu trnh cng ngh.

19

2.1 Qu trnh oxy ha hi etanol thnh axetandehit 370-500C c thay bng s tng hp axetandehit t etylen v O2 trong dung dch nc c xc tc bng phc palai-ng 20-60C v 1 atm (qu trnh Waker)

2.2 Trn c s c ch mch gc v cc thng s ng hc c bn nh hng n s phn b trng lng phn t cc polime m ngi ta thit lp c mt s c ch mi cho qu trnh tng hp polistirn vi nng sut v cht lng cao

2.3 Cacbonyl ha metanol c xc tc bng phc cht Roi, ime ha, oligome ha, polime ha anken vi s tham gia ca phc cht xc tc ng th Zeigler.

2.4 thay th cht oxy ha NaClO bng H2O2 oxy ha sorboza di tc dng ca xc tc phc kim loi. Kt qu b qua c giai on axeton ha sorboza. Qu trnh cng ngh c tin hnh trong iu kin thun khit, khng c cn b v kh thi gy nhim mi trng, t hiu qu kinh t cao.

2.5 Ty mu trong cng nghip dt, giy v mt s ngnh cng nghip khc bng cch nghin cu to ra cc h xc tc phc- ngun pht sinh ra cc tc nhn oxy ha rt mnh OH , g2

1

O dng ty mu, ty trng t, la, bng, vi si, giyvi tc nhanh nhit thng, tit kim nng lng, ha cht.

2.6 Chuyn ha parafin ca du m, kh CO v than thay th cho cc qu trnh hin hnh c chn lc thp.

2.7 Kh CO2 t do v rng buc ( dng CaCO3) chim 99,9% ccbon t nhin nhit thp c ngha tim nng ln- ngun nguyn liu mi cho cc hp cht hu c, khi m du m, than v kh t nhin ang dn cn kit.

2.8 Chuyn ha nng lng mt tri thnh nng lng dng trong cng nghip c d tr di dng ha nng ca cc sn phm phn ng quang hp nhn to (H2 v O2 hoc cc hp cht hu c v O2), c xc tc bng phc a nhn, tng t nh tm hot ng ca cc cht xc tc sinh hc trong qu trnh quang hp thc vt t nhin.

CHNG 3: Cc phn ng xc tc phc trong phn tch siu vi lng v mt s ng dng khc

3.1 Phn tch siu vi lng bng phng php ng hc xc tc phc 3.1.1 C s khoa hc ca phng php: Da trn mi quan h ph thuc tuyn tnh tc

phn ng oxy ha c cht hu c c mu S cht ch th bng H2O2 vo nng ion kim loi chuyn tip Mz+ cn c phn tch dng phc ng vai tr cht xc tc c hot tnh v chn lc rt cao nhit v p sut thng. nhy ca phng php ~ppb.

3.1.2 Cc i tng cn phn tch cc cht liu siu sch cn c s dng trong cc lnh vc cng ngh v k thut cao: Cc loi thuc th, cc cht bn dn, vt liu t, vt liu pht quang, phn tch cc mu thc vt, xc nh nhim mi trng, m khng b nh hng bi cc yu t khc

3.1.3 Xc nh vi lng Co2+ trong t v trong thc vt, xc tc l [CoL]2- 3.1.4 Xc nh hm lng vt Mn2+ trong bn t, xc tc l [MnDETA]2+ 3.1.5 Phn tch vt v siu vt Mn2+ trong nc ngm v bt ngc trai, xc tc l

[MnEn2]2+ 3.1.6 Xc nh hm lng vt Cu2+ trong nc sng, h, nc ngm, xc tc l [CuGlu] 3.1.7 D bo v kh nng t lm sch nc t nhin v nhim mi trng 3.2 ng dng cc h xc tc phc trong nng nghip v cng nghip thc phm 3.2.1 Ch to cc loi phn vi lng bn l v bn gc c hot tnh xc tc cao lm tng

trng v tng nng sut cc loi cy trng: la, ng, ch, cc loi cy n qu, 3.2.2 S dng h xc tc phc Cu[Glu] vi H2O2 ct mch Alginate (mt loi

polysaccharide trong rong m) thnh cc oligoalginate c tc dng kch thch s ny mm ht thc v tng trng cy la.

3.2.3 Ngc li i vi nhng phn ng oxy ha xc tc c hi lun tn ti v din ra trong cc loi nng sn, thc phm, cc loi qu ti, cc loi ru vang, ch thnh phm, gy bin cht, i thiu, c hi, cn phi nghin cu to ra cc cht chng oxy ha xc tc vi lng rt

20

nh, khng c hi, quy trnh x l n gin, t hiu qu kinh t cao trong vic bo qun cht lng cc loi sn phm kh bo qun ni trn.

11. Ti liu hc tp: 12. Ti liu tham kho:

[1] Nguyn Vn Xuyn (1994), Xc tc ng th oxy ha kh bng phc cht mt nhn v hai nhn mt s ion kim loi chuyn tip, Lun n tin s khoa hc Ha hc, Trng i hc Bch Khoa H Ni, H Ni. [2] Trn Th Minh Nguyt (2002), Nghin cu tnh cht catalaza v peroxidaza ca phc cht mt s kim loi chuyn tip vi etylendiamin, Lun n tin s ha hc, Trng i hc Bch Khoa H Ni, H Ni. [3] V Th Kim Loan (2008), Xc tc ng th oxy ha- kh bng phc cht ca ion kim loi chuyn tip, Lun n Tin s ha hc, Trng i hc Bch Khoa H Ni, H Ni. [4] Nguyn Vn Dng (2010), Nghin cu tnh cht catalaza v peroxidaza ca phc Co(II)-Axit citric, Lun n Tin s ha hc, Trng i hc Bch Khoa H Ni, H Ni. [5] Nguyn Vn Xuyn, Trn Th Minh Nguyt (2001), Xc tc phc, Cc bo co khoa hc Hi ngh xc tc hp ph Ton quc ln th 2, H Ni, tr 127-160. [6] G. Henrici-Olive, S. Olive (1997), Coordination and Catalysis, Verlagchimie-Weinheim-New- York. [7] Cristopher Masters (1981), Homogeneous Transition- Metal Catalysis, London New York Chapman and Hall. [8] Piet W.N.M. VanleenWen, Keij Morokuma and Jooph. Van Lenthe (1995), Theorical Aspects of Homogeneous Catalysis, Kluwer Academic Publishers. [9] Surit Bhaduri, Doble Mukesh (2000), Homogenous Catalysis Mechanisms and Industrial Application, A.John Wiley and Sons Publication, New York- Chichester-Weiheim- Brisbane-Singapore-Toronto [10] W. P. Kwar, B.M.Voeler (2003), Rates of hydroxyl radical generation and organic compound oxidation in mineral-catalyzed Fenton-like system, Environ.Sci.Tech, 37,pp 1150-1158 [11] Maria Papadaki, Jun Gao (2005), Kinetic models of complex reaction systems, Computers and Chemical Engineering, 29 (11-12), pp 2449-2460 [12] Syuhei Yamaguchi, Hideki Masuda (2004), Basic approach to development of enviroment-friendly oxidation catalyst materials, Mononuclear hydroperoxo copper(II) complexes, Sc. And Tech of Advanced materials, 20. pp 1-14. [13] Udai P Singh, Vaibhave Aggarwal and Asish K. Sharma (2007), Mononuclear cobalt (II) carboxyllate complexes: Synthesis, molecular structure and selective oxygenation study, Inorganica Chimica Acta, 360 (10), pp 3226-3332 [14] Anirban J.S, Jubaraj B.B (2007), Synthesis and Characterisation of dinuclear and mononuclear cobalt (II) benzoate complexes, Polyhedron, 26(6), pp 1347-1355 [15] Kassinos D, Varnava N, Micheal C, Piera P (2009), Homogenous oxidation of aqueous solution of atrazine and fenitrothion through dark and photo-Fenton reactions, Chemosphere, 74(6), pp 866-872. [16] Xchyov A.Ya, Travin C.O, Duka G.G, Xkurlatov Yu.L (1983), Katalitichexkie reaktxii okhrana okrujausei xre. Stiintxa, Kisinev. [17] Chen Weng Xing (2007), Photocatalytic oxidation of phenol in aqueous solution, J.Science in China Series B, Chemistry, 50(3), June.

21

CH7103 Quang ha hc Photochemistry

1. Tn hc phn: Quang ha hc 2. M hc phn: CH7103 3. Tn ting Anh: Photochemistry 4. Khi lng: 2(2-0-0-4) - L thuyt: - Bi tp: - Th nghim: 5. i tng tham d: Tt c NCS thuc chuyn ngnh Ha l thuyt Ha l 6. Mc tiu ca hc phn: Hc phn ny nhm mang li cho NCS: - Cc kin thc nng cao kin thc v Quang ha hc - Rn luyn kh nng t duy c lp ca NCS chuyn ngnh Ha l thuyt Ha l, chuyn su

Quang ha - Cung cp cho sinh vin nhng thng tin khoa hc mi nht trong lnh vc Quang ha. 7. Ni dung tm tt: Hc phn cung cp cho sinh vin kin thc c bn v phn ng quang

ha, cc giai on ca phn ng quang ha nh kt qu mt qu trnh kch thch phn t. Ngoi ra, hc phn b sung cc kin thc v nhng cht mang c tnh quang ha trn v d zn, ng dng ca quang ha trong cc phng php phn tch Ha l hin i trn v d Laser , Ph quang electron, Ph Raman,

8. Nhim v ca NCS: - D lp: 9. nh gi kt qu: (cch cho im ging nh quy nh i vi Cao hc) - Mc d gi ging: - Kim tra nh k: - Thi kt thc hc phn: 10. Ni dung chi tit hc phn: PHN M U Gii thiu mn hc Gii thiu cng mn hc Gii thiu ti liu tham kho CHNG 1: Gii thiu chung

1.1 M u: Cc khi nim c bn 1.2 Cc giai on ca phn ng ha quang 1.3 ng hc cc phn ng ha quang

CHNG 2: Kch thch phn t v bin i ca phn t sau khi b kch thch 2.1 Hp th v pht x nng lng in t 2.2 H s Einstein v kh nng hp th 2.3 Nguyn l Frank-Condom 2.3 Hunh quang v Ln quang 2.4 Dch chuyn electron gia cc mc nng lng cng trng thi, dch chuyn cm

(singlet-triplet) 2.5 S Jablonski 2.6 Phn ly v tin phn ly

CHNG 3: Laser 3.1 Phng trnh Laser c bn 3.2 M t thit b laser 3.4 c im ca nh sng laser 3.5 Phn loi laser

22

3.6 ng dng ca laser 3.6.1 Ph laser (laser Spectroscopy) 3.6.2 Laser to Hunh quang (LIF) 3.6.3 Laser nh v, o v iu chnh (LIDAR)

CHNG 4: Ph quang electron (PES) 4.1 Nguyn l phng php 4.2 Ph quang electron trong vng cc tm 4.3 Ph quang electron vng tia X

CHNG 5: Ph Raman 5.1 Nguyn l phng php 5.2 Quy tc chn la Raman 5.3 Quang phn v tin quang phn 5.4 V d ph Raman

CHNG 6: Ha quang hc zn 6.1 S phn ng ha quang zn 6.2 c im phn ng ha quang zn 6.3 Vn thiu ht zn v bu kh quyn

11. Ti liu hc tp: 12. Ti liu tham kho:

[1 ] Atkins, P.W. and de Paula, J. (2006) Physical Chemistry. 7th. Edn. Oxford Press [2 ] Pilling, M.J. and Seakins, P.W. (1994) Ozone deficit. V 265, pp.1831-8 [3 ] Andrews, D.L. (2004) Lasers in Chemistry. Oxford Press

23

CH7104 Cc phng php cng hng t Magnetic resonance

1. Tn hc phn: Cc phng php cng hng t 2. M hc phn: CH7104 3. Tn ting Anh:Magnetic resonance 4. Khi lng: 2(2-0-0-4) - L thuyt: - Bi tp: - Th nghim: 5. i tng tham d: Tt c NCS thuc chuyn ngnh Ha l thuyt Ha l 6. Mc tiu ca hc phn: Hc phn ny nhm mang li cho NCS: - Cc kin thc v cng hng t, mt mng l thuyt hin c s dng rng ri trong nghin

cu cu to cht - Rn luyn kh nng t duy c lp ca NCS chuyn ngnh Ha l thuyt Ha l, chuyn su

v nghin cu cu to cht v ng hc cc qu trnh ha - Hng dn sinh vin phng php nghin cu v thc nghim bng cc phng php cng

hng t (nu c thit b) 7. Ni dung tm tt: Hc phn cung cp cho sinh vin kin thc l thuyt c bn v hin

tng cng hng t, nguyn l cc phng php cng hng t cng nh ng dng ca chng trong nghin cu hin i.

8. Nhim v ca NCS: - D lp: 9. nh gi kt qu: (cch cho im ging nh quy nh i vi Cao hc) - Mc d gi ging: - Kim tra nh k: - Thi kt thc hc phn: 10. Ni dung chi tit hc phn: PHN M U Gii thiu mn hc Gii thiu cng mn hc Gii thiu ti liu tham kho CHNG 1: Tnh cht t v spin

1.1 Mmen t v s lng t t. 1.2 Tng tc vi t trng ngoi, khi nim t s hi chuyn, h s Bohn magneton 1.3 Th nghim Stern-Gelash v khi nim spin electron. 1.4 Mmen spin v s lng t spin 1.5 S lng t ha khng gian

CHNG 2: Cng hng t ht nhn 2.1 Mmen t ht nhn 2.2 Nng lng ht nhn trong t trng 2.3 Dch chuyn ha hc 2.3 Cu trc tinh 2.4 Vc t t ha 2.5 Chiu rng ca pick ph v tc phn ng 2.6 Hiu ng ht nhn Overhauser 2.7 Cng hng t ht nhn hai chiu. 2.8 Cng hng t ht nhn dng rn

CHNG 3: Cng hng t electron 3.1 Gi tr g

24

3.2 Cu trc Hyperfine 11. Ti liu hc tp: 12. Ti liu tham kho:

[1] Atkins, P.W. and de Paula, J. (2006) Physical Chemistry. 7th. Edn. Oxford Press [2] Atkins (2004) Physical Chemistry. 6th. Edn. Oxford Press [3] Joseph P. Hornak (2007) The basics of NMR. [4] Web http://www.cis.rit.edu/htbooks/nmr/