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 Miniaturization Technologies

November 1991

OTA-TCT-514

NTIS order #PB92-150325

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Recommended Citation:

U.S. Congress, Office of Technology Assessment,  Miniaturization Technologies, OTA-TCT-514 (Washington, DC: U.S. Government Printing Office, November 1991).

For sale by the U.S. Government Printing Office

Superintendent of Documents, Mail Stop: SSOP, Washington, DC 20402-9328

I S B N O - 1 6 - 0 3 5 9 8 3 – X

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Advances in miniaturization technologies have had dramatic impacts on our lives. Radios, com-puters, and telephones that once occupied large volumes now fit in the palm of a hand. Dozens of sen-sors are sent on spacecraft to the planets and on instruments into the human body. Electronic brainsare in everything from bombs to washing machines.

This report analyzes various technologies that may be important for future advances in miniatur-ization. Current research in the United States and other nations is pushing the limits of miniaturizationto the point that structures only hundreds of atoms thick will be commonly manufactured. Researchersstudying atomic and molecular interactions are continuing to push the frontiers, creating knowledgeneeded to continue progress in miniaturization. Scientists and engineers are creating microscopic me-chanical structures and biological sensors that will have novel and diverse applications.

OTA characterizes U.S. research and development in miniaturization technologies as the best in

the world. Despite the growing prowess of foreign research, American researchers continue to innovateand push the frontiers of miniaturization. The more elusive challenge is to translate success in the labo-ratory to success in the global marketplace.

OTA gratefully acknowledges the contributions of the workshop participants, contractors, review-ers, and contributors who provided information, advice, and assistance. OTA, of course, bears soleresponsibility for the contents of this report.

(JJOHN H. GI BBONS Director

. 111

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Miniaturization of Electronic and Mechanical Devices Workshop, Feb. 19, 1991

Karl Hess, ChairmanProfessor of Electrical Engineering

Fernand BedardResearch PhysicistNational Security Agency

T.H. Phillip ChangIBM T.J. Watson Research Center

Harold Craighead

DirectorNational Nanofabrication FacilityCornell University

Eric DrexlerVisiting Scholar

Beckman Ins t i tu t e-

University of Illinois

Wen Hsiung KoProfessor of Electrical EngineeringProfessor of Biomedical EngineeringMember of the Electronics Design CenterCase Western Reserve University

Carl KukkonenDirectorCenter for Space Microelectronics TechnologyJet Propulsion Laboratory

Richard S. MullerDepartment of Electrical Engineering/ 

Computer ScienceUniversity of California at Berkeley

Stanford Computer Science DepartmentStanford University

.

David K. FerryRegents ProfessorDepartment of Electrical EngineeringArizona State University

Kaigham GabrielAT&T Bell Labs

Stephen Jacobsen

DirectorCenter of Engineering DesignUniversity of Utah

James S. MurdaySuperintendent of Chemistry

Naval Research LaboratoryRichard PotemberJohns Hopkins Applied Physics Lab

Arati PrabhakarDirectorMicroelectronics Technology OfficeDARPA

George Sai-HalaszResearch Staff MemberIBM T.J. Watson Research Center

NOTE: OTA appreciates and is grateful for the valuable assistance and thoughtful critiques provided by the workshop participants. Theworkshop participants do not, however, necessarily approve, disapprove, or endorse this report. OTA assumes full responsibilityfor the report and the accuracy of its contents.

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Miniaturization Technologies Project Staff 

John Andelin, Assistant Director, OTA

Science, Information, and Natural Resources Division

James W. Curlin, Program Manager Telecommunication and Computing Technologies Program

  Project Staff 

Sunil Paul, Project Director 

Contractor Staff 

Harold Craighead, Cornell UniversityMichael Skvarla, Cornell University

Clayton Teague,  National Institute of Standards and Technology

 Administrative Staff 

Liz Emanuel, Office Administrator Jo Anne Young, Secretary

Karolyn St. Clair, PC Specialist 

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Miniaturization Technologies

Reviewers

John AlicIndustry, Technology and

Employment ProgramOffice of Technology Assessment

Samuel BaldwinEnergy and Materials ProgramOffice of Technology Assessment

Robert BateTexas Instruments

Fernand Bedard

National Security AgencyRobert BirgeCenter for Molecular ElectronicsSyracuse University

Frederico CapassoAT&T Bell Labs

Kenneth DavisElectronics DivisionOffice of Naval Research

Bob DennardIBM

Eric DrexlerStanford Computer Science

DepartmentStanford University

Larry DworskyMotorola, Inc.

David K. FerryArizona State University

Kaigham GabrielAT&T Bell Labs

Joseph GiachinoFord Motor Co.

L Val Giddings

U.S. Department of Agriculture

Lance GlasserDARPA

Henry GuckelUniversity of Wisconsin-

Madison

George HazelriggElectrical and Communications

Systems DivisionNational Science Foundation

Karl HessUniversity of Illinois

Stephen JacobsenCenter of Engineering DesignUniversity of Utah

Wen Hsiung KoElectrical Engineering and

Applied PhysicsCase Western Reserve University

Carl KukkonenCenter for Space Microelectronics

TechnologyJet Propulsion Laboratory

Rolf LandauerIBM

Ralph MerkleXerox Palo Alto Research Center

Lester W. MilbrathState University of New York 

at Buffalo

Richard S. MullerDepartment of Electrical

Engineering/Computer ScienceUniversity of California at Berkeley

James S. Murday

Naval Research Laboratory

Robyn NishimiBiological Applications Program

Office of Technology Assessment

Wally ParceMolecular Devices

Carl PilcherOffice of Space Science

and ApplicationsNational Aeronautics and

Space Administration

Richard PotemberJohns Hopkins Applied Physics Lab

Arati PrabhakarDARPA

George Sai-HalaszIBM T.J. Watson Research Center

Charles ShanleyMotorola, Inc.

Clayton TeagueNIST

William TrimmerPrinceton University

William TroutmanAT&T

Matthew WeinbergEnergy and Materials ProgramOffice of Technology Assessment

Sheryl WinstonBiological Applications ProgramOffice of Technology Assessment

Ken D. Wise

The University of Michigan

NOTE: OTA appreciates and is grateful for the valuable assistance and thoughtful critiques provided by the reviewers. Thereviewers do not, however, necessarily approve, disapprove, or endorse this report. OTA assumes full responsibility for thereport and the accuracy of its contents.

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Contents

 Page

Chapter 1. Introduction and Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1FINDINGS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . “ 1

WHY IS MINIATURIZATION IMPORTANT? . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. ... ... ......4COMPETITIVENESS OF U.S. MINIATURIZATION TECHNOLOGIES . . . . . . . . . . . . . . . . . . . . . . . . 5

Semiconductors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5

Quantum Effect Devices . . . . . . . . . . . . . . . . . . . .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7

Molecular and Biological Computing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. ... ... .......7Packaging and Interconnection . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8Biosensors and Chemical Sensors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8Micro-Mechanical Systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8Fabrication Technology Research and Development . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10

Chapter 2. Technology . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13INTEGRATED CIRCUITS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .......... 13

Physical Limits to Transistor Miniaturization . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13Continuing the Trend in Miniaturization . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15

Fabrication Technologies . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17COMPUTING SYSTEMS TECHNOLOGIES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19

Display Technology . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ...... 23Data Storage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23Interconnection and Packaging . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23

SENSORS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ... ......27Charge Coupled Devices . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27Chemical and Biological Sensors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28Micromachined Silicon Sensors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30

ACTUATORS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32Micro-Electro-Mechanical Actuators . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32

Integrating Actuators, Sensors, and Electronics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33

Appendix A. Fabrication Technology for Miniaturization . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35

Appendix B. Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 43

 Boxes Box  Page

2-A Molecular Machines . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20

2-B Bedside Analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 292-C A New Way To Machine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32

Figures Figure  Page

1-1 How Small Is Small? . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21-2 Cost of a New Memory Fabrication Facility . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31-3 Price History of Electronic Logic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41-4 Use of Surface Mount Technologies . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61-5 Semiconductor R&D Spending-Top Four Merchant Companies in the U.S. and Japan 6

2-1 TransistorTrends . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

. . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 142-2 Microprocessor Clock Speeds . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 152-3 The Photolithographic Process . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 182-4 Three Approaches to Electronics Miniaturization . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 222-5 Relative Cost of a Chip at Different Levels of Interconnection . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 252-6 Relationship of Die Size and Yield . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 262-7 Impact of Surface Mount Technologies on Calculator Thickness . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 272-8 Cut-away View ofa S ilicon Pressure Sensor . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 302-B-1 Bedside Analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 292-C-1 Surface Micromachining . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32

A-1 Fabrication Sequence for a Metal-Oxide-Semiconductor (MOS) Circuit . . . . . . . . . . . . . . . . . . . . . . . . . 36A-2 Ion Implantation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39

vii

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Chapter 1

Introduction and Summary

“Small is Beautiful.” The truth of that state-ment is debated in economic and sociologicalcircles, but when it comes to technology, there isno debate; small is beautiful because small is fast,small is cheap, and small is profitable. The revo-lution begun by electronics miniaturization dur-ing World War II is continuing to change theworld and has spawned a revolution in miniatur-

ized sensors and micromechanical devices.

Miniaturization plays a major role in the tech-nical and economic rivalry between the UnitedStates and its competitors. It translates to marketshare and competitive advantage for many com-mercial and scientific products. Those compa-nies and nations that can successfully developand capitalize on miniaturization developmentswill reap handsome rewards. Personal comput-ers, portable radios, and camcorders are exam-ples of products that created massive new mar-kets through miniaturization: they added billionsof dollars to the GNP of countries where theywere designed and built.

FINDINGS

The United States remains strong in miniatur-ization technologies research and development

(R&D), although the lead over other nations isless substantial than it has been in the past.

U.S. researchers continue to innovate and pro-duce world-leading research despite strong re-

search programs in Japan and Europe. There aresome areas where Japanese or European re-search surpasses the United States in quantityand in a few cases in quality as well. But on thewhole, U.S. researchers lead in miniaturizationtechnology R&D. The danger is that U.S. com-panies will lag other nations in implementingadvanced technologies, especially when new

technology is driven by a product or market dom-inated by another nation’s industry.

The trends in silicon electronics miniaturiza-

tion show no signs of slowing in the near future.

The current pace of miniaturization will pro-duce memory chips (dynamic random access

memory, DRAM) with a billion transistors andthe capacity to store 1 billion bits (1 gigabit) of in-formation around the year 2000.

1Transistors will

continue to shrink until the smallest feature isaround 0.1 micron (1 micrometer or one millionthof a meter). By comparison, today’s most ad-vanced mass-produced integrated circuits havefeatures as small as 0.8 microns. A human hair is50 to 100 microns in width (see figure l-l).

Achieving such tiny features will require a hugeengineering and research effort. New fabricationequipment and processing techniques must bedeveloped, pushing the cost of chip fabricationplants to over $1 billion, compared to hundreds of millions for a current state-of-the-art plant (seefigure 1-2). It is likely that despite the high costs,chips having features around 0.1 micron will be

manufactured; progress beyond the era of O.l-mi-cron transistors is uncertain.

The technology of semiconductor manufactur-ing is being applied to other fields to create new

capabilities. Sensors created with semiconduc-tor manufacturing technology hold the promiseof widespread applications over the next 1 0

years.

Micromechanical sensors for pressure and ac-celeration have used semiconductor manufactur-ing technology for several decades now, but re-cent innovations allow further miniaturization,greater flexibility, and compatibility with micro-electronics. A wider range of sensors can now befabricated using micromechanical structures.

l~i~  ~omPre~  t. t~ay~s  ~m t  dense  memoy  chip, which have about 4 million transistors and hold 4 million bits (4 megabits)  ofinformation.

-1-

 

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2 q  Miniaturization Technologies

Figure 1-1 -How Small Is Small?

Human hand

m wide

Grain of sand

mm

Human hair50-100 microns

wide

Smoke particle

microns

DNA nm wide

Atoms 1-4

100m

1 foot0.3m

10-1m

1 i n c h

25.4 mm

10-2m.

1 0-3

m .

l o- 4

m .

-

1 0-lOrn-

  – 1 meter (m)

 —

0.1 m Printed circuit board100 mm 0.05-1 m wide

  – 0.01 m10 mm1 centimeter

- 1 millimeter(mm)

- 0.1 mm100 microns

- 0.01 mm10 microns

- 1 micrometer1 micron

- 0.1 micron100 nm

- 0.01 micron10 nm

-1 nanometer (rim)

10A

. 0.1 mm

Integrated circuit chip (die)

mm wide

Micromechanicalcomponents

10-1000 microns wide

Transistor on integrated circuit2-20 microns wide

(smallest feature -O.8 micron)

 Quantum electronics structures

wide

Atomic lettering usingscanning tunneling microscope

65A high

1 angstrom

Each increment on the vertical scale indicates change in scale bye factor of 10. On the right of the scale are examples of miniaturizationtechnologies. For comparison, several objects of similar scale are shown on the left.

SOURCES: of Technology Assessment, 1991. Data from Philip Morrison, (San Francisco, CA: American

Books, 1982); David Michael Valley, CA: Jones and 1987), p. 183;Douglas M. cd., Van Scientific Encyclopedia (New NY: Van Nostrand Reinhold Co., 1983).

 

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Chapter l–Introduction and Summary q 3

$1,800

$1,600

$1,400

$1,200

Figure 1-2–Coat of a New Memory Fabrication Facility (DRAM Fab)

0’$1,000

 / / ,

 –

$600 –  

$400  –

$200 –

 I  I I I I

6 4 K 256K 1Mb 4Mb 16Mb 64Mb 256Mb

1979 1982 1985 1988 1991 1994 1997

SOURCE: Dataquest (August 1991) and Graydon Texas Instruments, personalSept. 18, 1991.

Biosensors and chemical sensors that can sensegases and chemicals are being perfected using in-tegrated circuit manufacturing techniques andwill be used in medical, food processing, andchemical processing applications. The economics

of microelectronics fabrication will result in thesenew sensors becoming cheap and ubiquitoussince hundreds or thousands can be created on asingle wafer. Integrating sensors with electronicspromises to increase the versatility of sensors forconsumer, medicine, automotive, aerospace,and robotics markets.

Materials and surface science research is criti-

cal to further advancement of all miniaturiza-tion technologies.

In every miniaturization technology-from sil-icon microelectronics to quantum electronics, tomicromechanics and biosensors—better under-

standing of materials and surface interactionswill be a critical part of further technology ad-vances. Better characterization of manufacturingprocesses will be necessary to make future gener-ations of miniaturized semiconductors. Making

practical miniaturized biosensors and chemicalsensors will require better understanding of howto bond molecules to surfaces. Progress in micro-mechanics will depend on how well the mechani-cal and surface properties of materials like siliconare understood. Resolving problems in quantumelectronics and molecular computing—the fron-tier of electronics miniaturization-are highly

dependent on improved understanding and con-trol of materials and surfaces. Basic research onmaterial properties and surface interactions—es-pecially in semiconductor processing and man-ufacturing-will be necessary for further minia-turization in many technology areas.

 

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4 q Miniaturization Technologies

Packaging is playing an increasingly larger

role in miniaturization of electronics.

Trends in miniaturization are creating pressurein the electronics industry to improve packaging:

1.

2.

3.

The proliferation of electronics into porta-ble devices, consumer electronics, automo-biles, and industrial applications is forcing

more compact and ruggedized packaging;

The miniaturization of transistors causesthem to operate faster and is forcing atten-tion to better packaging because fast elec-tronics must be packed close together toavoid delay in sending signals from chip tochip; and

As the costs of integrating more and moretransistors onto the same piece of siliconincrease, alternative ways to integrate tran-sistors into a single package, such as multi-chip modules and surface mount technolo-gies, are becoming more attractive.

10

0.001

n

WHY IS MINIATURIZATION

IMPORTANT?

Miniaturization has inherent advantages,among them higher speed, lower cost, and greaterdensity. Smaller electronics devices are generallyfaster because the signals do not have to travel asfar within the device. Packing more functionalityinto a smaller or same-sized device reduces the

cost of electronics. For example, a l-megabitDRAM chip has four times the memory capacityof a 256-kilobit DRAM, but costs only abouttwice as much and occupies the same space as thelower capacity chip. Since the number of compo-nents (e.g., chips) on a circuit board largely deter-mines the cost of the system, every l-megabitDRAM used instead of four 256-kilobit DRAM

reduces the number of memory chips on a boardand reduces cost. Similarly, decreasing transistorsize and greater integration has caused the priceof logic devices to decline (see figure 1-3).

Miniaturization is important because it cancreate new markets by enabling new applications.Development of the microprocessor-a tiny com-

Figure 1-3-Price History of Electronic Logic

I Discrete d \ \ transistors

 r scale \ \ 

I   Large-

scale

 in t egra t ion

 —

1 I I I I 1955 1960 1965

19701975 1980 1985 1990 1995

The price per gate-a circuit that performs a simple Iogic function -has continued on a steep downwardtrend since the introduction of the integrated circuit.

SOURCE: John S. Mayo, “The Microelectronics in Communications,(San Francisco, CA: Freeman & Co., 1977), p. 106. Copyright(c) 1977 Scientific

American, Inc. All rights reserved. Additional data from Graydon TexasInstruments, personal communication, Sept. 30, 1991.

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Chapter l–Introduction and Summary q 5

puter on an integrated circuit—in 1970 led to astill expanding personal computer market cur-rently valued at $70 billion per year. Flat panel

displays and improved chip packaging have led tobattery-powered portable personal computersthe size of notebooks (and some even smaller—the size of a checkbook), one of the newest mar-kets created by miniaturization. Personal com-munications is a developing major consumermarket created by miniaturization. With thesimultaneous reduction in the size of personal

computers and cellular telephones, the two aremerging into a cordless appliance that can com-municate with the rest of the world through a net-work. Nippon Electric Co. (NEC) already offers alaptop computer with a built in cellular phone forsale in Japan; similar products are under devel-opment by American companies.

COMPETITIVENESS OF U.S.MINIATURIZATION

TECHNOLOGIES

The competitive position of U.S. R&Din min-iaturization technology remains strong, althoughcompetition from Japanese and European indus-

try and governments has increased. As a result,the U.S. lead is less substantial than it was in thepast. The rejuvenation of postwar Japanese andEuropean economies has resulted in greaterquality and quantity of research in those nations.There are now many more sources of competitionin research worldwide.

Although U.S. R&D strength is still sound,

U.S. industry has a mixed record in the imple-mentation of miniaturization technology. Manyminiaturization technologies that are crucial tothe success of consumer electronics, for example,were embraced by Japanese industry more quick-ly than by U.S. industry. Surface mount technolo-gy, which allows more electronic chips to be

placed on a circuit board, has had greater pene-tration into Japanese industry than U.S. industry(see figure 1-4). Concerned with packing more

electronics into portable consumer products, e.g.,cameras, calculators, and stereo receivers, Japa-nese consumer electronics companies were eagerto reduce the size of their products. U.S. compa-nies that produce computers, industrial controls,and other large systems serve markets that arenot as concerned with size and portability.

Semiconductor

Shrinking the size of transistors and their inter-connections is being pursued vigorously by U.S.industry, government, and universities. Themainstream approaches to transistor miniatur-ization use silicon with designs similar to those of past devices. In many respects, the United States

leads world research on smaller transistors. De-sign of miniaturized transistors draws heavily onbasic sciences and computer modeling, areas inwhich the United States remains strong. Imple-menting smaller transistors in products, however,is a strength of Japanese industry. DRAM chipshave historically been the first commercial prod-ucts produced with each new generation of semi-

conductor manufacturing equipment. SinceDRAM chips are made primarily by Japanesecompanies, they are the leaders in implementingsmall transistors in products.

R&D in semiconductor technology is done pri-marily by industry in both the United States andJapan. The Federal Government spends about$0.5 billion per year on semiconductor R&D.

2

Japanese merchant semiconductor firms, com-panies that sell chips to other companies, havebeen outspending U.S. merchant firms on R&D(see figure 1-5). Total U.S. and Japanese industryR&D spending is roughly equal; $3.7 billion isspent in the United States and $4 billion inJapan.

3

@ffice of Management and Budget estimates for fiscal year 1990.3Dataquest estimates for 1990”

 

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6 q  Miniaturization Technologies

Figure 1-4-Use of Surface Mount Technologies

100%

o%Japan W. U.S. Japan W. U.S. Japan W. U.S.

Europe Europe Europe1985 1991 1995

Use of surface mount technologies (SMT), which can reduce the thickness and volume of electronic products, haslagged in the United States compared to other nations. This graph shows past, current, and projected estimates ofSMT use on printed circuit boards for Japan, Western Europe and the United States.

- -

SOURCE: Office of Assess 1991. Data from VLSI R Inc. (Fall

Figure 1-5-Semiconductor R&D Spending-Top Four Merchant Companies in theUnited States and Japan

 $3

Top fourJapanese merchant

companies$2 — (then-yr. conversion)

~ @ @- 0 0 - - - -

# & ~

- - - - - - - - --‘Top four Japanese

merchant companieso (avg. conversion)

m

$1

q U.S. merchantcompanies

1985 1986 1987 1988 1989 1990

U.S. semiconductor merchant companies are outspent in R&D by Japanese merchant firms. There are twocurves for Japanese spending. The more dramatic increase results from converting yen to dollars at annualconversion rates. The other curve accounts for changes in the exchange rate by using a single conversion rateaveraged over 5 years.

SOURCE: Office of Technology Assessment, 1991. Data from Dataquest.

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Chapter l–Introduction and Summary q 7 

Quantum Effect Devices

Significant momentum is left in the current

trend in silicon miniaturization. But what hap-pens when today’s silicon designs hit physicallimits in further miniaturization, as many expertsexpect will happen in about 10 years? One optionwill be to change the way switching devices (usedto make computer logic) are made. Several alter-native approaches are being pursued by theUnited States, Japan, and Europe. One ap-proach—quantum effect electronics—is still are-

search topic, but is receiving worldwide support.In the United States, about $8 million are spentannually by the Federal Government in this area.Most of the research is being sponsored by theDefense Advanced Research Project Agency(DARPA), with significant efforts at other DoDresearch agencies and the National Science Foun-dation (NSF). Industry support for this basic re-

search is sparse; AT&T Bell Laboratories andTexas Instruments both have research activitiesin the area. IBM has a small research effort aswell. Most of the research in the United States isbeing conducted at universities supported bygovernment agencies.

The United States leads in research related toquantum effect devices, but this lead competes

with other nations’ efforts. Japanese efforts aresignificant and are beginning to make an impact;the Japanese involvement at recent conferenceshas grown. The United States can expect to main-tain its lead in research, but, as the researchmoves toward development and implementation,the competition with Japanese researchers andcorporations grows more fierce. Japanese indus-

tries have the advantage of being the world lead-ers in semiconductor processing technology andoptoelectronics technology.

4U.S. companies

have the advantage of proximity to the world’sleading researchers in the field. The JapaneseGovernment will spend less than $3 million in fis-cal year 1991 on quantum effect device research.With two new projects initiated in 1991 and 1992,

funding will increase to about $6 million per yearover the next 5 years. Japanese industry is activelypursuing quantum effect device research. Fujitsu

and NTT have the two largest research efforts.Estimates of Japanese industrial investment inthe field are difficult to confirm, but the sum maybe more than double the government investment.The Ministry of International Trade and Industry(MITI) 1992 Large Scale Program, “AngstromTechnologies,” will also fund research in quantumelectronics. The program will spend 25 billion yen

($183 million) over ten years to conduct researchon technologies at the scale of angstroms. It is notknown, however, how much funding will go toquantum electronics.

  Molecular and Biological Computing

One proposed way to continue the miniaturiza-tion of computers is to use individual molecules

as switching devices in place of today’s semicon-ductor transistors. U.S. investment in researchrelated to molecule-based computing has dimin-ished substantially since a period of intense inter-est in the early 1980s. NSF was the principal fund-ing source for much of the original research.NSF’s current funding for molecule-based com-puting is a few hundred thousand dollars and

may end next year. Funding from U.S. industry islimited to a few venture capital firms and DigitalEquipment Corp. Much of the effort in theUnited States has turned to development of mo-lecular or biologically derived materials for appli-cations in computing-related areas. For example,films of molecules rather than individual mole-cules

5are being considered for use in optical

disks and other data storage technologies.

Japanese and European governments continueto fund molecular computing research. How-ever, differences in terminology complicatecomparisons of programs between countries.Portions of one of the Japanese Exploratory Re-search for Advanced Technology (ERATO) proj-ects are designed to pursue molecule-based com-

qMany ~ument  app]imtions for suFr]attius—a structure used to create quantum effect detius-invoke oPto electronics.

!$Films of bactenorh~owin,  a light ~nsitfie biologi~]  molecule, are being prepared by re~archers at syracu~ university, Mitsubishi, and afew American companies.

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8.  Miniaturization Technologies

puting6and the Ministry of International Trade

and Industry (MITI) Basic Technologies forFuture Industries Program spends about 300 mil-

lion yen ($4 million) on research for biologicalmolecular computing.

  Packaging and Interconnection

As electronics become more ubiquitous, faster,and denser, the pressure on improving electronicpackaging technology will increase. Federal fund-

ing has not addressed the issue of packaging as awhole, but many different programs fund re-search on packaging. Technologies such as sur-face mount technologies (SMT) and multichipmodule (MCM) technology can place more semi-conductor chips into a system than traditionalpackaging. SMT is maturing and is seeing wide-spread application. Over 50 companies and re-

search institutions worldwide are now pursuingMCM or related technology.

7One focus of the

Microelectronics and Computing TechnologyConsortium (MCC)–a consortium of U.S. com-panies—is packaging and interconnection tech-nology, including MCM technology. A NationalResearch Council report in 199@ found that theAmerican and Japanese industries are about

equally matched in printed wiring boards, multi-chip modules, and other interconnection technol-ogy. The report also found that U.S. industry wasdependent on Japanese suppliers for materialsrequired for several packaging technologies.

  Biosensors and Chemical Sensors

There is intense worldwide interest in develop-ing biosensors and chemical sensors, particularly

in Japan. Biosensors can detect the presence of chemicals or molecules such as glucose, urea, andoxygen. Diverse applications are seen in medical

diagnosis, industrial process monitoring and con-trol, fermentation process control, and food qual-ity monitoring. Most of the R&D is being done byindustry. Within the Federal Government, theDepartment of Defense (DOD) is a primary sup-porter of biosensor R&D with the National Insti-tutes of Health supporting some development.

According to a 1989 Japanese Technology and

Evaluation Center (JTEC) Panel report, the U.S.efforts in chemical and biological sensors trailthose of Japan.

9The panel report rated Japanese

efforts more advanced in commercialization,product development and quantity of basic re-search. In quality of research, the U.S. and Japa-nese efforts were considered equal. OTA inter-views in the biosensor industry indicate the

situation has not changed much since the JTECreport. According to the report, in 1985 therewere more Japanese publications and patents forbiosensors than U.S. publications and patents.

10

A consortia has been established by 35 Japanesecompanies to conduct R&Din biological sensors.The annual budget for the consortia is about $2million from industry matched by funds from theMinistry of Agriculture, Forestry and Fisheries.

ll

In addition, a large number of Japanese compan-ies are funding independent development of bio-sensors.

12

  Micro-Mechanical Systems

Development of new manufacturing tech-niques by researchers at American universities

during the 1980s has led to an expansion of inter-est in micromechanics around the world. Build-

6Kunitake  molecuiar architecture project (1987-92).

TDenni~ Hemel and HasSan Hashemi, “Hybrid wafer Scale Integration, “ MCC Ikchnical Report P/I-329-89, 1989.8National  Re=arch Council,  commission on Engineering and Ikchnical Systems, National Materials Advisov  Board, Matefia~~or Hi@

-

 Density Electronic Packuging and Interconnection (Wshington, DC: National Materials AdvisogI Board, March 1990).9u.s. Depa~ment of Commerw,  C4JTECH (Japanese lkchnology Evaluation Program) Panel Report on Advanced Sensom in Japan,” JanUaV

1989, p. 184.

IofibliMtions:  59 Japan,  35 United States; patents: 74 Japan, 9 United States.

llHi&  Tec~olo~ Business, September-October 1989, p. 29 .

12National  science Foundation,  JaPnew ~ChnoloW  and Evaluation Center (~c), Viewgraphs for “~c Workshop on Bioprocess Engi-neering in Japan” (Washington, DC: National Science Foundation, May 21, 1991); and U.S. Congress, Office of Technology Assessment,  Bio-

 technology in a Global Economy, OTA-BA-494 (Washington, DC: U.S. Government Printing OffIce, October 1991).

 

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Chapter l–Introduction and Summary q 9

ing upon established semiconductor processing

techniques, researchers have been able to fabri-cate elaborate mechanical structures: motors andturbines as wide as a hair (see photograph), canti-levers capable of measuring acceleration, andgear assemblies smaller than a fleck of dust.These new techniques are closely related to tech-niques traditionally used to create mechanicalstructures for use as pressure sensors. The firstapplications with sizeable markets for the newtechnology are in sensors and instrumentation.Future applications may involve micromechani-cal actuators or systems of actuators and sensors.Some niche applications are already using micro-mechanical actuators made with conventionalmilling and extrusion techniques (non-microelec-tronics techniques).

Researchers at U.S. universities are the ac-knowledged leaders in micromechanical sensorresearch. The European nations, especially Ger-many, have a strong technology base in sensortechnology and are supported with extensive gov-ernment funding. Germany’s Karlsruhe NuclearResearch Center and Fraunhofer Institute co-developed a new lithographic process for making

relatively thick (hundreds of microns) microme-chanical structures, called LIGA. Although theirindustrial research in pressure and accelerationsensors is impressive, the Japanese trail theUnited States and Europe in R&D.

Although still relatively modest in scale, in the

last few years funding for micromechanics hasbeen increasing rapidly. In the United States, re-search in the field is sponsored by several differ-ent agencies, including DOD, NSF, the NationalInstitutes of Health (NIH), the National Aero-nautics and Space Administration (NASA), andthe Department of Energy (DOE). Total Federalspending in the field is planned to be over $15 mil-lion in 1991-from under $6 million in 1990 and1991. DOD and NSF were early supporters of thetechnology. DARPA has been spending about $2million per year, and plans to spend about $3 mil-lion per year in 1992. NSF has been funding muchof the research at universities since 1983 at about$2 million per year. Efforts at the DOE have beenmostly at Sandia and Lawrence Livermore Na-tional Laboratories. Starting in 1991, DOE will

spend about $16 million over 3 years at LouisianaTechnical University (LTU) as directed by Con-gress. Other State governments including Cali-fornia and Louisiana have shown interest in pro-moting micromechanics research.

On the whole, U.S. industry is playing "waitand see” while trying to sort out what commercial

applications the technology might have. Sensorand instrumentation companies, however, seeclearer potential for applications and are pushingforward more aggressively. Analog Devices, Inc.,for example, has developed the first commercialproduct that uses the new manufacturing tech-nique—an acceleration sensor targeted for auto-mobile airbag deployment applications. Othercompanies are abandoning micromechanics. A

pioneer in the field, AT&T Bell Laboratories, ter-minated its efforts in micromechanics. U.S. in-dustry spent over $20 million in fiscal year 1991on micromechanics R&D.

In Europe the largest and most advanced re-search efforts are being pursued by Germany. In1990, the Germany Federal Ministry for Research

and Technology initiated a 4-year program thatwill spend 400 million marks ($230 million) on re-search. The German Government recently an-nounced it will extend the program for at leastanother year. The Karlsruhe Nuclear ResearchCenter and the Fraunhofer Institute are conduct-

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10. Miniaturization Technologies

ing leading research in micromechanics. TheFraunhofer Institute is designed to encourageparticipation from industry and receives about 50

percent of its funding for micromechanics fromindustry. A consortium of German companieshas licensed technology from Karlsruhe and isdeveloping industrial applications based on thetechnology. Germany companies are interested inapplications of the technology. Bosch has thelargest effort, and Siemens and Messerschmidtalso have significant R&D efforts in the field.

Other European nations and industries arealso pursuing micromechanics research. Themost notable research efforts besides Germanyare in Switzerland and the Netherlands. The In-stitute of Microelectronics in Neuchatel, Switzer-land, is developing solid-state sensors and is ac-tive in the field of micromechanics research. TheUniversity of Twente and the University of Delft

in the Netherlands are active in the field, with anew institute formed at the University of Twente—the Micro-Electromechanical Sensorsand Actuators (MESA) Institute. Almost everynation in Europe has research activity in micro-mechanics—much of which is at universities.

Perceiving themselves as behind in microme-chanics research, Japanese researchers are vigor-

ously pursuing the technology with a new MITIprogram that will spend 25 billion yen ($183 mil-lion) over the next 10 years. The program, initi-ated in April of 1991, aims to develop microro-bots for health and industrial applications.Micromechanical systems will be a major part of the program’s research, although portions of theprogram will bean extension of a previous MITI

program to develop miniature robots. Fiscal year1991 funding for the program is only about $3 mil-lion, but that will increase to over $20 million an-nually as the program accelerates to full speed.Japanese industry typically adds its own invest-ment of labor and equipment to work sponsoredby MITI, so the total research effort associatedwith this program is substantially larger than thegovernment investment. In addition to the MITIprogram, the Japanese Science and Technology

Agency (STA) funds research at several universi-ties in Japan, including the University of Tokyo,

13

at a total of about $1 million per year. Japanese

industry is pursuing research in the field, with1991 expenditures estimated at over $20 million.One of the largest industrial research efforts is atToyota’s central R&D facility in Nagoya. Otherindustrial research is underway at NTT, NECCorp., Ricoh Corp., IBM-Tokyo, and MatsushitaCentral Research. The MITI project has in-creased the interest of industry in micromechan-

ics, and R&D can be expected to increase overthe next several years.

  Fabrication Technology Research

  and Development

Making miniaturized electronics, sensors, and

micromechanics requires increasingly sophisti-cated manufacturing equipment as each genera-tion of miniaturized components demands great-er precision in fabrication.

Lithography—the technique used to etch fea-tures into integrated circuits—is one of the mostchallenging hurdles for future miniaturization of integrated circuits. The size of a transistor, the

lines connecting transistors, and other devices ina circuit can only be made as small as the resolu-tion of the tools used to make them. As the size of transistors become smaller, making tools of ade-quate resolution becomes increasingly difficultand more expensive. The current approach to in-creasing the resolution of lithography has been toreduce the wavelength of the light source, pro-

gressing from visible wavelengths, to ultraviolet,to deep ultraviolet. Now many experts are pre-dicting that the trend will continue to x-ray lithog-raphy, but the outcome is far from certain. Someexperts predict ultra-violet lithography will beuseful in creating features as small as those possi-ble with x-ray lithography. Using a techniquecalled phase–shifting, this approach would re-quire very sophisticated masks and computersoftware to be successful. Other lithographic ap-

lsothem include ~hoku University, University of Osaka Prefecture, and K..shu  university.

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Chapter 2

Technology

INTEGRATED CIRCUITS

Since World War II, system designers havetried to create smaller electronics. Reduction inthe size of vacuum tubes progressed slowly aspractical limits were encountered. Replacementof vacuum tubes with transistors in the 1960s wasa breakthrough in miniaturization. Transistorsbecame smaller, but each transistor was pack-aged individually, thus mounting large numbersof transistors on a circuit board still resulted inlarge assembly units. Invention of the integratedcircuit overcame that problem by embeddingmany transistors on a single silicon chip thatcould be then connected to other components ona circuit board. Integrated circuits accelerated

the drive toward transistor miniaturization be-cause, unlike discrete transistors, the connectionsbetween transistors could shrink with the transis-tor. The smaller the transistor and its intercon-nections, the greater the transistor density (thenumber of transistors in a given chip area). Aschip designers were able to pack more and moretransistors onto a single silicon chip, the number

of transistors per chip increased nearly ahundred fold each decade (see figure 2-l). As thesize of a transistor shrinks it operates faster, lead-ing to faster computation (see figure 2-2).

If this trend continues, sometime after 2000 thesmallest feature on an integrated circuit will beabout 0.1 micron (1 micron is 1 micrometer or onemillionth of a meter). For comparison, today’s

dynamic random access memory (DRAM) tran-sistor has a smallest feature of about 0.8 micron.The equivalent capacity of a DRAM

1chip will be

over 1 billion bits (1 gigabit). With O.1-microntransistors, microprocessors will contain over 400million transistors. Industry experts believe that

such densities are possible and that there are nofundamental physical limits to prevent achievingthem.

The time needed to overcoming engineeringand manufacturing problems to reach these highdensities is uncertain. Several problems must beovercome to develop high-density chips, includ-

ing: 1) higher resistance of the minute connec-tions between transistors and within transistors;2) the tendency of very small transistors (about0.1 micron) to “leak,” rendering them useless; and3) lack of high-volume manufacturing equipmentcapable of creating very small features.

Fabrication technologies, especially lithogra-phy, have paced the miniaturization of transis-

tors in the past and may ultimately determine thepractical economic limits of transistor miniatur-ization. Fabrication equipment used to makecircuits at 0.1 microns must be affordable andcapable of sustaining reliable, high-volume pro-duction. Electron-beam lithography can now pro-duce features much smaller than 0.1 micron, butis unable to manufacture a sufficient volume of 

chips to be economical.2

X-ray lithography andphase-shifted masks (another lithography tech-nique using visible light) are the two most likelycontenders for achieving manufacturable O.l-mi-cron transistors. Other prospects include projec-tion electron beam, and projection focused ionbeam.

  Physical Limits to Transistor Miniaturization

What are the prospects for increasing densitiesof transistor based integrated circuits beyond 1gigabit DRAM and 400 million transistor micro-processors? On this question, experts’ opinions

ID~  is the ~nmay means ofstonng information in a computer system temporanlywhile the computer is working on the info~ation.  Massstorage (e.g., hard disk) is used for permanent storage.zElectron.beam  lithography  is  Currentb used in production of masks and may be useful in some production applimtion% e.g., manufacturing

chips for high-performance computers.

-13-

 

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14 q  Miniaturization Technologies

Figure 2-1 –Transistor Trends

Decreasing transistor size. . .100

1 0

1

0 . 1

0 . 0 1

I

1970 1980 1990

  and increasing die (chip) size. . .

1

6 4 M A / n’

u

I I I  I n

101970

of Technology Assessment,Texas Instruments.

1980 1990

  is resulting in rapid growth in the number of transistors per chip.

10,OOO

100 I

10

I

I I 1 I

1970 1980 1990

Data from Intel David Ferry, Arizona State and Graydon

 

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18. Miniaturization Technologies

Figure 2-3-The Photolithographic Process

Silicon dioxide

Photoresist

Ultraviolet radiation

Hardenedphotoresist

Photolithography is the process by which a microscopic pattern is transferred from a photomask to a layer of material in a circuit. In thisillustration a pattern is shown being etched into a silicon dioxide layer (shaded) on the surface of a silicon wafer. The oxidized wafer (1) is firstcoated with a layer of a light-sensitive material called photoresist (2) and then exposed to ultraviolet light through the photomask (3). Theexposure renders the photoresist insoluble in a developer solution; hence a pattern of the photoresist is Ieft wherever the mask is opaque (4).The wafer is next immersed in a solution of hydrofluoric acid, which selectively attacks the silicon dioxide, leaving the photoresist pattern andthe silicon substrate unaffected (5). In the final step the photoresist pattern is removed by means of another chemical treatment (6). Thereare variations on this process such as use of photoresists that become soluble instead of insoluble (4), and use of reactive gases instead ofliquid acid solutions for etching (5).

SOURCE: Adapted from William G. “The Fabrication of Microelectronic Circuits,” (San Francisco, CA:Freeman & Co., 1977), p. 47. Copyright (c) 1977 Scientific American Inc.–George Kelvin.

most common current technology uses visible or The current state-of-the-art photolithographyultraviolet wavelengths of light for the photolitho- uses ultraviolet light, typically with a wavelengthgraphic process. of less than 400 nanometers. Use of excimer laser

 

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Chapter 2-–Technology .19

sources could achieve wavelengths less than 200

nanometers. By improving mask technology, op-tics, and resists, ultraviolet systems may be us-able to 0.25- or 0.2-micron minimum featuresize—dimensions that are expected to be neededin the mid-1990s. There are several lithographytechnologies that can create features smaller than0.25 or 0.2 microns. The likely candidates for thenext generation of lithography tools are x-ray li-thographies, optical lithographies using phaseshift masks, electron-beam lithographies, andion-beam lithographies. Combinations of thetechniques are also possible. (For a more detaileddescription of the photolithographic process, seeapp. A.)

Materials and the principles of surfacesciences are fundamental to advancing miniatur-

ization of transistors and electronics. Improve-ments in semiconductor manufacturing rely onunderstanding how materials react to processingand fabrication techniques. Physical phenomenaunderlying the critical fabrication steps are notwell understood; knowledge has developed most-ly from experience, not derivation from physicallaws. Better understanding of the physical laws

affecting small-scale structures would accelerateadvances in miniaturization.

There are more speculative ideas for futurefabrication technologies that would require evenmore rigorous understanding of surface interac-tions. Some exploratory work is currently under-way to use proximal probes to fabricate inte-

grated circuits. Using a scanning tunnelingmicroscope (STM) or some variation of an STM,scientists are beginning to fashion crude struc-tures from individual atoms and clusters of atoms. Researchers have been able to move ordeposit atoms on or below surfaces to “draw”figures, maps, and company logos (see photo-graph). Even if these techniques do not result inusable manufacturing tools, they will increase ourunderstanding of surface interactions of atoms,leading to better understanding of traditionalsemiconductor manufacturing. Even more spec-ulative is the prospect of creating molecular-sizedrobots and machines that could be programmed

Photo credit: IBM 

Scientists at IBM’s Almaden Research Center used a scanningtunneling microscope (STM) to move xenon atoms around on anickel surface and spell out the company name. The distancebetween each atom of xenon is about 13 angstroms.

to manufacture virtually any molecular structure(see box 2-A).

COMPUTING SYSTEMS

TECHNOLOGIES

Computer systems have shrunk dramatically

during the last 30 years. Mainframe computersonce filled large rooms and required air condi-tioning to dissipate the heat generated by vacuumtubes and early transistors. Computers have be-come so small that laptops and notebook com-puters are more powerful than mainframe com-puters of 10 years ago. Equivalent power will soonbe available in a checkbook-size package. Past

miniaturization of electronics has played the ma-  jor role in bringing this capability about and fu-ture miniaturization advances will be driven pri-marily by electronics (see figure 2-4). Othercomponents in addition to integrated circuitsalso had to shrink in size to accommodate today’snotebook-sized computers. Increased massmemory density, greater circuit board density,and thinner flat panel displays have improvedcomputer system performance and alloweddownsizing. Trends toward smallness are ex-pected to continue as customers demand higherquality, higher performance, and portability fromsmaller boxes.

Chapter 2–Technology .17 

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The technical problems associated with mak-ing practical memory or logic systems from mo-lecular devices are substantial and are not likely

to be solved in this decade. The most vexing prob-lem is the interface (connection) between the mol-ecule and the circuit itself, a problem common tomany forms of miniature transistors. At 0.1 mi-cron, transistors begin to experience problemswith high resistance, but a molecular transistorwould be smaller still—0.001 microns or less. Inorder to avoid the electrical interface problem,some researchers are exploring optical interfaces.The diameter of an optical interface, however, islimited by the wavelength of light. The stability of the molecules is also a problem. To be useful forcomputation, a molecule must remain in a specif-ic configuration until changed by an external sig-nal. Individual molecules sometimes change con-figurations unexpectedly. Using clusters of molecules makes them easier to connect to cir-

cuits and reduces the errors in the stored data,but makes the computing device larger.

Related research is underway in the use of biologically derived or organic material for stor-ing information or computing. These approachesminimize the interface and stability problems of individual molecule computation. A few U.S.companies are working on organic materials foroptical disks and at least one Japanese firm, Mit-subishi, is working on an optical disk that will usebacteriorhodopsin as the storage material.

5Few

materials have suitable properties for computing;this has been a major stumbling block for molec-ular computing. U.S. research is directed at bet-ter understanding materials that might serve as

the basis of future molecule-based computers.The more immediate results may be faster datastorage, but proponents of molecule-based com-puting hope that the experience gained will leadto true molecule-based computing and process-ing systems in the future.

  Fabrication Technologies

There are several manufacturing technologiesthat are important in making semiconductor de-vices. The most critical manufacturing technolo-gy by many accounts, is lithography–the tech-niques used to pattern and etch transistors andtheir interconnections on a substrate like siliconor GaAs.

There are several different lithographic tech-nologies including photolithography, electron-

beam lithography, ion-beam lithography, and x-ray lithography. In addition, there are severalnovel technologies still in early stages of develop-ment—e.g., scanned photolithography, com-bined patterning and growth, and proximal probefabrication.

One of the most critical steps in lithography isexposing the resist—usually an organic com-

pound layered on top of the semiconductor wa-fer–to an energy source (see figure 2-3). Theenergy source can be optical, ultraviolet, or x-ray.It can also be a beam of charged electrons or abeam of charged atoms (ions). Some of the resistis exposed to the energy source and some is not,depending on whether the resist lies under atransparent or opaque portion of the mask. In theplaces exposed to the energy source, the resist ismodified so that certain chemicals can dissolveit.

6Exposing the wafer with a series of etching

chemicals removes the resist and a layer of mate-rial (usually silicon dioxide) underneath. The re-maining resist is then removed by another chemi-cal that does not affect the semiconductormaterial. A layer of material is typically depos-ited again and the process is repeated—as many

as 12 or more times—to make an integrated cir-cuit. The minimum feature size that can beformed is determined primarily by the precisionthat the energy source can be focused to discrimi-nate between the areas of the resist that are ex-posed to the energy and those that are not.

7The

5Robefi Birg~,  Syacuw University,  personal communication, Ju&  29)  1991-

%ere are different types of resists. Exposure to radiation causes some types to become susceptible to the subsequent etching step, and causesothers to become resistant to etching.

TOther key factom are the ability to align subsequent layers of masks to create the proper vertical geometxy and the ability to control the rateand direction of etching.

18. Miniaturization Technologies

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Figure 2-3-The Photolithographic Process

Silicon dioxide

/ Photoresist/ /

Ultraviolet radiation

Hardenedphotoresist

Photolithography is the process by which a microscopic pattern is transferred from a photomask to a layer of material in a circuit. In thisillustration a pattern is shown being etched into a silicon dioxide layer (shaded) on the surface of a silicon wafer. The oxidized wafer (1) is firstcoated with a layer of a light-sensitive material called photoresist (2) and then exposed to ultraviolet light through the photomask (3). The

exposure renders the photoresist insoluble in a developer solution; hence a pattern of the photoresist is Ieft wherever the mask is opaque (4).The wafer is next immersed in a solution of hydrofluoric acid, which selectively attacks the silicon dioxide, leaving the photoresist pattern andthe silicon substrate unaffected (5). In the final step the photoresist pattern is removed by means of another chemical treatment (6). Thereare variations on this process such as use of photoresists that become soluble instead of insoluble (4), and use of reactive gases instead ofliquid acid solutions for etching (5).

SOURCE: Adapted from William G. Oldham, “The Fabrication of Microelectronic Circuits,” Microekctronics (San Francisco, CA: W.H.

Freeman & Co., 1977), p. 47. Copyright (c) 1977 Scientific American Inc.–George V. Kelvin.

most common current technology uses visible or The current state-of-the-art photolithographyultraviolet wavelengths of light for the photolitho- uses ultraviolet light, typically with a wavelengthgraphic process. of less than 400 nanometers. Use of excimer laser

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22 q  Miniaturization Technologies

Smaller transistor sizeallows more transistorsper area

Figure 24–Three Approaches to Electronics Miniaturization

Make Transistors Smaller

 

u

u

Make Die Larger

Larger area allows moretransistors per die (chip)

Multi-chip modulesand

multi-chip packages

Three basic strategies areused to miniaturize electronics systems. By making each transistor smaller (l), more can be placed on an inte-grated circuit, incorporating the functions of other chips. Increasing the size of the chip (2) has a similar effect by increasing the available

area for transistors and their interconnections. These first two approaches have been the driving force behind electronics miniaturization forat Ieast the past two decades. Improved packaging (3) is a way to improve use of space on a printed circuit board. Atypical printed circuitboard has only a small fraction of its space covered with integrated circuits; the rest is primarily packaging and interconnection.

SOURCE: Office of Technology Assessment, 1991.

Chapter 2–Technologyq  23

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  Display Technology

The size of a typical cathode ray tube (CRT)desktop computer display is about a cubic foot.New technologies, e.g., as liquid crystal display(LCD) and electroluminescence displays, haveallowed the development of flat panel displaysthat occupy a tenth of the volume. Flat paneldisplay technologies are discussed in detail in theOTA report The  Big Picture: HDTV & High Reso-

lution Systems. New technologies required to ad-vance high-resolution video technology are many

of the same that are required for advanced elec-tronics and more powerful computer systems.

8

Japanese producers of flat panel displays favorLCD technology and are increasingly adapting itto larger screens, but current fabrication tech-niques are limiting screen size to about 15 inches.Further increases in screen size await improvedlithography.

  Data Storage

“Mass Storage” refers to storage technologieswith large capacities, including optical and mag-netic media that retain data when the power is off.These devices encode data on a surface that canchange its magnetic or optical characteristics. By

moving the surface under a device that can senseand change the characteristics of the surface—aread/write head—data is stored and retrieved.

Semiconductor memory storage increases ca-pacity as constraints on transistor miniaturiza-tion can be overcome, but mass storage operateson different physical principles and therefore has

different limitations. There are two major typesof mass storage technologies—magnetic and op-tical. The trends in magnetic storage show no signof slowing as they approach densities that will put

1 billion bits onto 1 square inch. Researchers atIBM’s Almaden Research Center have demon-strated such densities.

9Today’s storage densities

are about 50 to 100 million bits per square inch in

high-end storage systems. Optical storage tech-nology uses lasers to write and read data from anoptical disk and is limited by the size of the laserbeam spot on the disk. The spot size, in turn, islimited by the wavelength of the laser source.Most optical disks today use a red (wavelength of 800 nanometers) laser to write and read data.Efforts are underway now to develop blue lasers

(wavelength of 400 to 500 nanometers) that wouldhave smaller spot sizes and be able to increase thecapacity of optical disks by four times.

Another technique that promises much higherdensities uses STM

1O

to write and read data. TheSTM and related instruments use sharp tips inclose proximity to a surface to create an atom-by-atom image of the surface. These tools also have

the capability to physically modify surfaces byeither etching away or building up a few hundredatoms at a time. Such techniques could result inmassive data density-more than 1,000 billionbits (1 terabit) per square centimeter. The majorproblem with STM and related approaches todata storage is that the data access speed is pain-fully slOW.

llThere is research currently underway

at a few labs to combine many tips in parallel,increasing the speed of writing and reading.These approaches remain speculative, but mightyield useful technology in the long term.

  Interconnection and Packaging

The basic packaging component of most com-puter systems is one or more circuit boards. Vari-ous components are placed on the circuit boardand interconnected with strips of metal. Due tomanufacturing costs, the number of components

8~e  techniques  ~wd  t.  make  ~D  displays are many  of the same that are used to make integrated Circuits. For more information see OTA’sBackground Paper, The Big Picture: HDTV& High-Resolution Systems, OTA-BP-CIT-64 (Washington, DC: U.S. Government Printing Office,June 1990}

gRobefi M. ~ite, “Peripherals,”   IEEE Spectrum, February 1990,  pp.  28-30.

IOSee app.

A for details on theSTM.

non e~stimate is that 32 ~entunes  would be required  t.  ~te  one  ~uare centimeter with  one profirna] probe. see James S. Murday andRichard J. Colton, “Proximal Probes: lkchniques for Measuring at the Nanometer Scale,” in ChemiszryandPhysics of Solid Surfaces, R. Vanelowand R. Howe (eds.) (New York, NY: Spnnger-Verlang, 1990), p. 347.

 24 q  Miniaturization Technologies

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is the greatest contributor to the overall cost of anelectronics system (see figure 2-5). System design-ers seek to reduce the number of components on aboard to improve reliability as well. The intercon-

necting strips of metal on a board and connec-tions between boards are more likely to break than connections elsewhere in the system. Eversince the invention of the integrated circuit, thebest way to reduce costs and increase reliability isby putting more transistors on integrated cir-cuits, hence reducing the number of circuit boardcomponents. By decreasing the size of each tran-

sistor and their interconnections, more transis-tors have been crammed onto integrated circuits.

While the density of circuits on a chip havebeen increasing, the size of the chip has beenincreasing as well. The first microprocessor in1971 was on a 19,000 square mil (1 mil = one-thousandth of an inch) chip. For the next 20 years,chip size increased by about 14 percent per year.

Current microprocessors are on chips of about260,000 square roils. Chip size may rise even fast-er over the next few years, yielding a chip size of 625,000 square roils in production by 1994.

12

Since the probability that a chip is defective in-creases with its size, chip size is limited by thenumber of defects on a wafer (see figure 2-6).

If the increase in chip size is taken to its limit,

an entire wafer can become one large circuit.Since a typical wafer produces about a hundredchips, a huge number of transistors could be puton one wafer. But there are significant problemswith such an approach. There are defects in everywafer (primarily caused by particulate from themanufacturing equipment), so a wafer-scale cir-cuit is virtually guaranteed to have defects. With

the high defect rate, strategies for routing connec-tions around defective components must be con-sidered in circuit design. Another problem is thatthe complexity of interconnecting wafer-scale cir-cuits increases the number of processing steps.

Finally, the fine lines of metal used to link theimbedded transistors together are not suited forthe relatively long interconnections needed forwafer-scale integrated systems. There are some

specialized applications that could use wafer-scale integration such as image processing andlarge memory storage,

13but unless fabrication

problems are solved, it will likely not be an impor-tant technology. Applications that have regulardesigns —e.g., memory is essentially the same cir-cuit pattern repeated over and over—haveachieved marginal success with wafer-scale inte-

gration because errors in the circuit are relativelyeasy to detect and correct or bypass.

Hybrid wafer-scale integration—known asmultichip module (MCM)—is another approachto increasing circuit density. MCMs take severalchips, place them on a substrate (usually siliconor a ceramic), and connect them with thin films of conducting metal using techniques like those

used in integrated circuits. Multichip modulesplace chips closer together than is possible usingsingle chip packages—an important advantage aschip speeds increase. The distance a signal cantravel in one clock cycle—the “heartbeat” of acomputer system—shrinks as cycle times short-en. Machines with clock cycles of 2 nanosecondswill soon be available,

14which corresponds to 500

megahertz. (The fastest of today’s personal com-puters operate at about 33 to 50 megahertz.) Reli-ability is also enhanced because the number of printed circuit board connections and board-to-board connections are reduced.

MCMs have been successfully used in the IBM3090 and the NEC SX-AP; high manufacturingcosts, however, keep them from being used in

mass production items like personal computersand workstations.

15The Microelectronics &

Computer Technology Corp. (MCC)–-a privateconsortium of electronics companies—has devel-oped a MCM technology capable of producing

lzJe~  Sulllvan, c’~e  Nem Generation of Electronics Design Automation Technology for Systems in Silicon,” MCC l’kchnical  Repofl No.CAD-043-90, Jan. 24, 1990.

13’(A Dream Remembered,” The EconomisI, Nov. 17, 1990, p. 12.IdDennis  He~ell and HasSan Hashemi, “Hybrid Wafer Scale Integration,” MCC  llchnieal Report P/I-329-89, 1989.

IsIbid.

 

h h l

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Chapter 2–Technology q 25

Figure 2-5–Relative Cost of a Chip at Different Levels of Interconnection

Chip in wafer, untested

Testing and yieldper good chip

Package, packagingand testing

Space on printed-circuit board

Share of back panel and wiringShare of cabinet and

power supply

Total

Averagecost

$0.55

$0.15

$1.00

$0.35

$2.63

Space on the printed circuit board is one of the most expensive commodities in a system design. By integrating more functions onto a chip,system designers can reduce the number of chips on board, lowering overall system cost. The illustration shows the steps that a chip goesthrough on its way to becoming part of a computer system and the relative cost per chip for each stage.

SOURCE: Adapted from Ivan E. Sutherland and A. Mead, “Microelectronics and Computer Science,” (San Francisco, CA: Freeman &Co., 1977), p. 113. Copyright(c) 1977 by Scientific American, Inc. All rights reserved. Data fromGraydon Texas Instruments, personal communications, Sept. 20, 1991.

 

26 qMiniaturization Technologies

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26 q Miniaturization Technologies

Full wafer

Figure 2-6- Relationship of Die Size and Yield

s Defects

Yield = O

Large die

Yield = 25%

Small die

Yield = 71%

Smaller die (chip) size means higher yield (percentage of good chips) for a given density of defects.

SOURCE: Adapted from Sand, Systems, Howard K. (cd.) (Scottsdale, AZ: DM Data Inc.,1986), p. 7-12.

computers that are fast (3 nanosecond cycle time,

or 333 megahertz), use 10 million gates, and cost$5,000. Costs must be reduced further for thetechnology to be affordable for workstations andpersonal computers.

A major obstacle to widespread use of MCMsis the lack of standardized interfaces for the hard-ware and software needed to design the modules.For the last 30 years the electronics industry has

been building an infrastructure that is focused onthe same objective: improving the performance of the integrated circuit. All the manufacturingequipment and computer software is geared fordesigning and optimizing a single chip. It is diffi-cult to obtain “naked” chips (dice) outside theirpackage from semiconductor vendors. Com-puter-aided design and testing are all difficult

with MCMs.Dissipating the heat generated by dense cir-

cuitry is a major problem facing circuit designers.This becomes more difficult as the number of transistors in a chip increases. The simplest ap-proach to accomplish this in a computer system isto flow air over the circuits. In high-performancesystems (supercomputers and some main-

frames), however, where speed is critical, othermeans for cooling are often used. Some super-computers flow inert fluids, e.g., freon, directlyover the circuitry. Sometimes fluid distributionsystems attached directly to the chip package are

used to dissipate heat, a scheme used in several

mainframe computers.Many options for increasing the density of elec-

tronic circuits now being investigated operatebest at very low temperatures and require exter-nal refrigeration units. Advancements in refriger-ation and heat dissipation technology are impor-tant to pushing the miniaturization of electronicsdevices. This is because as the cross-section of a

conductor decreases, the resistance to currentflow rises. Greater resistance means greater heatgeneration because the same current flowingthrough a high resistance material creates moreheat than in a low resistance material.

The need for better interconnection is greatestin two areas: 1) consumer electronics and 2) high-performance computers. Consumer electronicsmust combine low costs with high dependability.High-performance computers demand ultra-fastcomputing speeds and extensive interconnection;while the field is highly competitive, cost is less afactor than performance. In high-performancecomputing, the need for better interconnectionresults from the short distance that an electronicsignal can travel before another clock cycle starts.

Supercomputers push clock cycles to the limit, sodesigners must devise ways to minimize intercon-nection distance. The Cray supercomputers havean unconventional circular shape in order to keepcomponents close together and reduce the time

 

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Chapter 2-–Technology .27 

needed to communicate among components.Massively parallel computers face an even moreserious interconnection problem because manymore components (processors) must be con-nected. A conventional serial (von Neumann ar-chitecture) mainframe has only one central pro-cessing unit (CPU) that is centrally located sothat other components can be closely connectedto the CPU. A massively parallel computer mayhave over 1,000 CPUs that must be intercon-

nected.

In consumer electronics, a major objective is tomake the product smaller, lighter, cheaper, andmore reliable. Each of these objectives demandbetter interconnection and packaging. Japaneseindustry, with its emphasis on consumer electron-ics, tends to adopt packaging innovations to meetthe demands of the market. The impact can beseen in the many consumer products around us(see figure 2-7).

SENSORS

Sensors are devices that can monitor and

translate observed conditions—light level, accel-eration, pressure, or temperature—into a signal.The signal can then be transmitted, processedthrough a system or stored as data. A mercurythermometer, for example, responds to an envi-ronmental condition—temperature—and trans-lates to a visual readout indicated by the level of mercury gauged against a calibrated scale. Anelectrical temperature sensor might sense thechange in temperature by measuring the changein voltage across a material. The resulting electri-cal signal can be manipulated and displayed forread-out.

There are a wide variety of sensors; each can beclassified as imaging or non-imaging.

16Imaging

sensors take many measurements of radiated en-

ergy from the imaged target. Camcorders, forexample, use a charge coupled device (CCD) asan imaging sensor to convert a visible light imageto an electrical signal that can be recorded on a

Figure 2-7–impact of Surface Mount Technologieson Calculator Thickness

1969

1973

1975

1976

1977

1978

1979

26mm

9mm

7mm

5mm

 1.6mm

Implementing surface mount technologies in calculators had a

dramatic impact on thickness. Surface mount technologies in-clude surface mounted packages as well as surface mounted key-boards and displays.

SOURCE: VLSI Research.

VCR tape. Non-imaging sensors act at a singlepoint, typically in contact with the object beingsensed. Sensors can be made to sense differentsubstances and energies: electromagnetic radi-ation, temperature, pressure, acceleration, chem-icals, and biological materials. Of the many sen-sor technologies, a few are key to miniaturizingsystems: CCDs, chemical and biological sensors,and micromechanical sensors.

Charge Coupled Devices

CCDs are solid-state image sensors that detectlight. They are used in cameras—from camcord-ers to professional cameras to astronomical cam-

t. this include some tactile sensors that detect sensations of touch an of 

  28. Miniaturization Technologies

19

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eras on satellites. The resolution of a CCD isdetermined by the number of picture elements(pixels) on a CCD. The devices are a special kindof integrated circuit with problems similar to oth-

er integrated circuit manufacturing. Reducingthe size of each pixel improves the pixel densityand the image resolution. Increasing the size of the CCD can increase the number of pixels, butdefects in the circuit cause yield to plummet asthe CCD size increases. Manufacture of CCDs isdominated by Japanese industry. More than 20Japanese companies manufacture CCD chips

and they are the leaders in small pixel size, andinnovative design.

17In the United States, Tek-

tronix, Texas Instruments, and Kodak produceCCDs designed for military, industrial and spaceapplications. The majority of the image-sensingmarket is in consumer electronics.

18

Imaging sensors are particularly important tothe Department of Defense (DOD). DOD relies

on imaging data for things like aiming missiles,detecting rocket launches, and enhancing night-vision. Most DOD applications sense areas of theelectromagnetic spectrum that are unique to mili-tary needs.

Chemical and Biological Sensors

By combining information technologies withbiotechnologies, researchers are developing newsensors that are cheaper, faster, more versatile,and more efficient than previous generations.These sensors, known as biosensors, can detectgases, chemicals, and biological molecules. Thefirst biosensor was invented in 1%2 by Leland C.Clark Jr., but it was not until the 1970s that bio-

sensors came into practical use. The early biolog-ical and chemical sensors were relatively large;Clark’s first glucose sensor was about a centime-

ter in diameter.19

There are many ways to makebiological and chemical sensors; some can bemade using techniques borrowed from integratedcircuit manufacturing. By applying this technolo-

gy, it is now possible to make sensors that are onlya few thousandths of a centimeter wide.

Smaller biosensors have two advantages: 1)they can be placed in areas that were previouslyinaccessible, and 2) they are fast since the mea-surement can be done in the field instead of at acentral lab. Because they offer similar economiesof production as microelectronics, biosensors

will become cheap and widely available. Biosen-sors will be useful in portable systems. A marketanalysis by Arthur D. Little, Inc. in 1991 pre-dicted that portable biosensors sales would reach$1 billion by 2000.

20With sensors for substances

like glucose, urea, and carbon monoxide availablein an inexpensive and small package, portablediagnostic kits could be made available (see box

2-B). The industrial food processing industry isexpected to make use of portable biological sen-sors to determine the freshness of food. Becausebiosensors are small enough to be placed on thetip of a hypodermic needle, blood chemistrycould be monitored continuously by placing sev-eral biosensors onto a chip inserted on a cathetertip into the patient during surgery. The capability

to measure chemicals concentrations will be use-ful for process industries such as biotechnologyand chemical production.

Miniaturization of biosensors and chemicalsensors relies on a device called a chemical fieldeffect transistor (ChemFET).

21ChemFETs are

similar to the field effect transistors (FET) thatare used in normal microelectronics. A micro-

electronics FET conducts electricity (turns on)when a voltage is applied to one of it inputs (gate),creating an electric field in the FET. A ChemFET

ITu.s.  Depafiment  of Commerce, ‘TI’E(X-I (Japanese Technology Evaluation Program) Panel Report on Advanced Sensors in Jwm”  JanU-ary 1989, p. 40.

181bid., p. 44.lgJerome S. Schulz, “Biosenmrs,” Scientific 4UriC~, August 1991, pp. 64-69.

z@Strong  Gro~h for Biosensors,” New  Technolo~ Week, Feb. 19 , 1991,  P. 8.21~w  knom as ion ~nsitjve  fje]d effect transistor (ISF~. “CHEMF~”  js  usual ly  used  to refer to sensors that use whole mOleCUleS, while

“lSFET” refers to sensors designed with ions (charged atoms or molecules).

 

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Chapter 2–Technology 29

Box 2-B--Bedside Analysis1

A hand-held analyzer currently un-der evaluation at the Hospital of theUniversity of Pennsylvania demon-strates how biosensors might findtheir way into clinical use. It simulta-neously makes six commonly re-quested chemical measurements on apatient’s blood-sodium, potassium,chloride, urea nitrogen, glucose, and

hematocrit-producing results in lessthan 2 minutes. The bedside tests costmore than ones performed in a cen-tral laboratory, but their immediacymay make them more effective.

The device achieves accuracy com-parable to that of laboratory equip-ment by using a disposable cartridgecontaining six biosensors and a cali-

bration sample. A medical workerplaces 60 microliters of blood in thecartridge; the analyzer then measuresboth the calibration sample and thepatient sample. It displays test resultsand also stores them, keyed to timeand the patient’s identification num-ber, for later analysis: The cartridge-based design adopted by manufactur-ers will make it possible to perform adifferent set of tests once the appro-priate sensors have been developed.

from

Schultz,

1991, pp. 64-69.

Figure 2-B-1 -Bedside Analysis

Display

Sample

Calibrationsolution

Cartridge

Sample inlet

Sensors

SOURCE: Adapted from Jerome S. Schultz, Scientific American,1991, pp. 64-69. Copyright (c) 1977 American, Inc. All

rights reserved.

uses a FET that is specially coated with a chemi- testosterone, the male hormone, to produce acal or molecules that will create an electric fieldwhen the sensor is exposed to a specific chemical,gas, or molecule.

Fiber-optics technology aids biosensor andchemical sensor development and miniaturiza-tion. Certain chemical and biological moleculeswill change their optical properties (either give off or absorb light differently) when exposed to otherchemicals or molecules. For example, the en-zymes dehydrogenase and luciferase react with

secondary chemical that gives off light (fluo-resces). A fiber-optic-based glucose sensor mightone day serve as the basis of an implantable artifi-

22In the meantime, glucose sensorscial pancreas.

are being incorporated into the latest generationblood sugar monitors for diabetics. These devicesare portable, take measurements in seconds com-pared to hours with earlier monitors, and somefunction without drawing blood by measuring

absorption of light through skin.23

  footnote18”

  6, 1991, p. 4.

 

30 q Miniaturization Technologies

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 30 q  Miniaturization Technologies

New generations of biosensors and chemical

sensors will take advantage of theircommon heri-tage within formation technology to integrate log-ic functions into the same package with biosen-sors. Integrating logic with sensors can result inmore useful devices. For example, a glucose sen-sor with integrated logic might respond different-ly to blood sugar levels at different times of day.

Integrated circuit fabrication holds promise forhigh integration by placing biosensors and elec-

tronics on the same chip. It also promises reduc-tion in prices because large numbers of sensorscan be fabricated at one time. Major challengesremain, however, such as isolating the microelec-tronics from the environment while allowing the

sensor access to the environment.

Researchers are actively pursuing refinementsto the fabrication processes that will make wide-

spread use of biosensors possible. The yield anduniformity of the manufacturing process needs tobe improved before large scale production is

practical. Shelf life is a problem with biosensors;compared to microelectronics and fiber optics,biosensors are perishable. Biomolecules thatmust be affixed to a chip or optical fiber are not

stable outside their cellular environments. As a

result, biosensors can only be stored for weeks ormonths—sometimes years. This limitation pro-hibits some applications, but for some industriesshort lifetime products are normal and expected.In medicine, for example, instruments are oftendiscarded after use to avoid risk of contamina-tion. The price and capabilities of biosensors inother applications (e.g., detecting explosive gases

or critical chemicals in a process) are valuableenough that users are willing to accommodatelimited lifetimes.

  Micromachined Silicon Sensors

A significant field for future sensor develop-ments will be mechanical sensors—devices that

rely on the mechanical properties of a material tosense energy of their surroundings. Since 1958,silicon has been used in pressure sensors. By

fabricating a covered cavity, changes in ambient

conditions can be detected by monitoring theresistance across resistors on a membrane cover-

ing the cavity (figure 2-8). Improvements in sili-

con processing technology have reduced the size

and cost of silicon pressure sensors, with major

gains made during the 1980s. Cost has gone from

about $1,000 per sensor in the 1960s to a fewdollars per sensor today. The 1958 silicon pres-

sure sensor that was half an inch wide is now one

hundredth of an inch wide. Growth in the 1980s

was very strong; silicon pressure sensors are 60

percent of the pressure sensor market—up from

40 percent in 1985 and 16 percent in 1980.24

Silicon mechanical sensors are also used to

detect acceleration. Accelerometers are madewith a mechanical silicon structure that places a

mass of material—the “proof mass’’—on the endof a thin “arm” of silicon. Acceleration makes the

Figure 2-8-Cut-away View of a SiliconPressure Sensor

Top entrypressure

Implanted

strain gagesSilicon frame

Electrostaticglass-siliconbond

Silicon diaphragm

Glass

 Bottomentry

pressure

SOURCE: Adapted from et al., Sensors and Microstructure  (Fremont, CA: NovaSensor),1990, p. 7.3.

CA: NovaSensor, June p.

 

Chapter 2–Technology q 31

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Chapter 2 Technology q 31

silicon arm bend; the degree of bending deter-

mines the acceleration. Accelerometers are find-ing applications in automobiles for airbag de-

ployment and automatic suspension systems.

Analog Devices, Inc., for example, is using a sur-

face-micromachined cantilever as the basis for a

accelerometer. The separation between the canti-

lever and the chip surface changes with accelera-

tion, changing the voltage. The voltage change

can be translated into an acceleration measure-ment.

The miniaturization of silicon sensors resulted

from developments in micromachining–a tech-

nique to precisely shape the surface of a material

such as silicon. Silicon in its crystalline form has

different orientations in the crystal that can be

specified for a particular silicon wafer. Chemicals

used to etch silicon “eat away” crystalline siliconat different rates depending on orientation of the

crystal to the surface. This process is called pref-

erential etching. By combining preferential etch-ing with special chemicals that stop short the

etching process, complex structures can be

created in silicon. This technique is known as

“bulk micromachining,” and has been used since

the 1960s.

Use of “sacrificial layers’’—technique devel-

oped during the 1980s--can create more intricate

structures. Sacrificial layers are thin films (usual-

ly less than 10 microns) that are removed by etch-

ing chemicals to release movable parts from the

substrate (see box 2-C). The process of using

multiple layers of sacrificial layers to create com-

plex structures is called surface micromachining.Using surface micromachining, researchers atthe University of California at Berkeley and atAT&T Bell Labs fabricated a working motor

about the width of a hair (100 microns) in 1988

(see photograph). That achievement set off aflurry of research activities. Laboratories around

the world were soon duplicating and improving

upon the original work. Work at the Massachu-

setts Institute of Technology (MIT) improved the

sacrificial layer technique, making it more com-

patible with traditional silicon electronics pro-

cessing. The Karlsruhe Nuclear Research Centerin Germany developed a variation on the surface-

micromachining technique known as “LIGA.” It

uses x-ray lithography technologies to fabricatemicrocomponents from other materials including

plastic and metal.

The new complex structures have created a

need for better understanding and characteriza-

tion of the materials used in the structures. Sili-

con is a well known material, but not enough is

understood of its mechanical properties. Struc-

tures that are released from the substrate, forexample, can warp due to strains in the material.

In microelectronics these strains are not impor-

tant because structures remain connected to the

substrate, but for surface micromachining, these

strains can ruin a component. Wear and frictionare not well understood at such small scales, and

researchers need to understand these properties

to improve the reliability of micromotors andother movable parts. Characteristics of surfaceinteractions, flow of fluids, and air flow are not

well understood at such small scales. Under-

Photo credit: Analog Devices, Inc.

An acceleration sensor (accelerometer) made by Analog De-vices, Inc. will be the first commercial product that uses surfacemicromachining, a new processing technique that uses sacrificialmaterial Iayers to free structures from a substrate. The microstruc-ture, similar to ones fabricated at the Berkeley Sensor and Actua-tor Center, can be seen in the center of this microphotograph ofthe sensor chip. The sensor is surrounded by electronics thatprovide calibration and signal conditioning.

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Appendix A

Fabrication Technology for Miniaturization

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Many of advances in

INTRODUCTION

the technologies that have enabledminiaturization were first developed

for microelectronics and allow both lateral andthickness control in the creation of structures.Although the early techniques and tools weredirected at silicon, recent years have seen in-

creased attention to materials other than silicon:compound semiconductors, superconductors,metals, and insulators. Furthermore, they are be-ing applied to more diverse areas: micromechani-cal structures, biosensors, and chemical sensors.

The same processes that have allowed for de-creases in size also allow parallel production of many devices. Thousands or millions of transis-

tors or other devices can refashioned simulta-neously on one chip the size of a thumbnail, andmany chips preprocessed at the same time on onewafer. The key steps in the process of creatingthese structures are:

q lithography,

q pattern transfer, and

q characterization.

LITHOGRAPHY

Integrated circuit fabrication techniques allrely on lithography, an ancient technique firstused for artistic endeavors. The basic processinvolves covering an object with a thin layer of material (ancient artisans sometimes used wax)that can be patterned but will resist subsequentprocessing and protect the material underneath.Industrial lithographers use a hydrocarbon poly-mer, appropriately called “resist.” A pattern isproduced in the resist—usually by exposure to

visible light or ultraviolet (UV) radiation —expos-ing selected areas of the material below. The ex-posed areas can then be modified in some way.Successive applications of this basic process pro-duce a multilevel structure with millions of indi-vidual transistors in a square centimeter as de-scribed in figure A-1.

Photolithography is the most widely used form

of lithography and is likely to continue to be so forthe near future. UV light, usually with a wave-length less than 400 nanometers, is used to createpatterns resist layers on flat surfaces. Diffractionof light—the interference of light waves with oneanother—limits the resolution or minimum re-producible feature size. Diffraction is minimizedby reducing the wavelength of the exposing radi-

ation. Mercury vapor lamps are routinely used asa source of 436 nanometer (G-line) and 365 nano-meter (I-line) light. Shorter wavelength excimerlaser sources are a new source of UV light withoperation possible at 248 nanometers and in thefuture 193 nanometers and other wavelengths. Bycombining shorter wavelengths with improvedmask technology (including phase shiftedmasks

2), better optics, and more sophisticated

resist chemistries, it is likely that photolithogra-phy will be usable to 0.25-microns minimum fea-ture sizes and possibly below 0.2 microns.

The longevity of UV lithography is a subject of debate in the semiconductor industry. Many ex-perts argue the limits of diffraction and depth of focus will prevent use of UV photolithography

below 0.2 microns and that x-ray lithography,which uses substantially shorter wavelength radi-ation, will be the successor to UV lithography.X-ray lithography is a candidate for high volumeproduction of integrated circuits with line widthsbelow 0.5 microns. The most studied and devel-oped form of x-ray use is “proximity printing,”

IH.G. Craighead and M. Skvarla, “Micro and Nanofabrication lkchnology, Applications & Impact,” contractor repofi  prepared for the OffIce

of lkchnology Assessment, April 1990; and Tlm Studt, “Thin Films Get Thinner as Research Heats Up,’’ R&D Magazine, March 1990, pp.70-80.Zphase sh i f t ma s k s function by  Care fu l& controlling light diffraction, using the constructive and destructive interference to help create the

circuit pattern. Phase shift masks hold greatest promise for manufacturing memory and otherICS with regular, repeated patterns.

-35-

 

36 q  Miniaturization Technologies

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Figure A-1 -Fabrication Sequence for a Metal-Oxide-Semiconductor (MOS) Circuit

Silicon nitride Silicon dioxide

1

First polysilicon 

p-Type silicon

Insulatingoxide film

Contact “window”

Aluminum

Fabricating this MOS circuit element (a two-level n-channel-negative charge carrier- polysilicon-gate metal-oxide-semiconductor) re-quires six masking steps. The first few process steps involve the selective oxidation of silicon with the aid of a film of silicon nitride, which actsas the oxidation mask. A thin film of silicon dioxide is grown over the entire wafer, and a Iayer of silicon nitride is deposited from a chemical (l).The layer is selectively removed in a conventional photolithographic step in accordance with the pattern on the first mask (2). A p-typedopant (e.g., boron) is implanted using the silicon nitride as a mask, followed by an oxidation step, resulting in a thick layer of silicon dioxidein the unmasked-(3). The silicon nitride is then removed in selective etchant that does not attack either the silicon or silicon dioxide (4).Since silicon is consumed in the oxidationprocess, the thick oxide layer is partly recessed”into the silicon substrate. The first layer of poly-

crystalline silicon is then deposited and patterned in the second masking step (5). A second insulating film of oxide is grown or deposited,followed by the deposition of the second polysilicon layer, which is in turn patterned in the third masking step (6). A short etch in the hydro-fluoric acid at this stage exposes certain regions to an implantation or diffusion of n-type dopant. A thin layer of silicon dioxide is depositednext, and contact “windows” are opened with the fourth mask (7). Finally a layer of aluminum is deposited and patterned in the fifth maskingoperation (8). The wafer will also receive a protective overcoating of silicon dioxide or silicon nitride (not shown); the fact that openings mustbe provided in this overcoating at the bonding pads accounts for 6 masking steps. Vertical dimensions are exaggerated for clarity.

SOURCE: William G. ‘The Fabrication of Microelectronic Circuits,” (San Francisco, CA: Freeman & Co.,1977), p. 48. Copyright (c) 1977 by Scientific American, Inc.–George Kelvin.

  AppendixA-Fabrication Technology for Miniaturization .37 

where the mask is placed on the substrate materi- laboratories, and in industry for mask-making

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pal and its pattern is reproduced by exposure tox-rays, resulting in a substrate pattern the samesize as the mask. Practical problems that must beaddressed include complexity of mask technolo-gies, difficulty in alignment of multiple layers,economical x-ray sources, and resolution limita-tions. X-ray lithography operates similarly to UVphotolithography, but with much shorter wave-lengths–around 5 nanometers. Proximity print-ing requires a bright source of x-rays. Synchro-tron sources are the highest intensity sources of 

x-rays but they are very expensive. Most expertsfeel it is unlikely that proximity printing withx-rays will be practical below 0.2 microns, whileothers hold that the technology will be usable to0.1 microns.

More recent exploratory work in x-rays in-volves “reduction projection lithography.” X-rays

are focused through a mask that is kept awayfrom the substrate. The principal advantages of this approach are cheaper x-ray sources (a syn-chrotron is not required) and improved resolu-tion. In this country, AT&T Bell Laboratoriesand other laboratories are investigating this tech-nology. One of the greatest challenges to makingprojection x-ray lithography useful for manufac-

turing is the optics used in the process; they arecomplex, involving the creation of multiple-layerfilms with precisely controlled thickness.

Another way to get beyond the diffraction limitof radiation-based lithography is to use electronsor atoms to expose the resist. Diffraction does notlimit the resolution of electron-beam lithography

because the quantum mechanical wavelengths of high energy electrons are exceedingly small. Elec-trons scatter quickly in solids, limiting practicalresolution to dimensions greater than 10 nanome-ters—significantly greater than current demandsof any practical technology. Electron-beam lith-ography has demonstrated resolution as small as2 nanometers (0.02 microns) in a few materials.Electron beam technology, however, is limited in

usefulness because an electron beam must bescanned across the entire wafer. Electron-beamlithography tools are in use in universities, in

, y gand small manufacturing production runs.

There are approaches still in research that may

yield a more versatile lithography tool. A possiblealternative is to use photolithography for largefeature definition and reserve the scanned elec-tron beam for the critical dimensions. A varietyof approaches for parallel exposure, rather thanserial scanned exposure, of electron-beams havebeen studied for years. There is currently activeresearch in electron beams reduction projectionusing masks at AT&T Bell Laboratories, and inmultiple source systems and proximity printing atIBM. These approaches would exploit the resolu-tion and alignment possibilities of electronbeams with the speed of parallel exposure tech-niques.

Ion beam lithography is in many ways similarto electron beam lithography with beams of 

charged atoms (ions) taking the place of elec-trons. Recent advances in ion sources have in-creased the utility of scanned focused ion beams.Compared to photons (x-rays and light) or elec-trons, ions chemically react with the substrate,allowing a greater variety of modifications. Somescattering effects are also reduced compared toelectrons and, as with electrons, diffraction limitsof ion beams are negligible. The fundamentalresolution limits for charged particle lithogra-phies are below 1(M) nanometers. Ion beam lithog-raphy suffers the same draw back as electronbeam systems; it relies on a serially scannedbeam. That limits its applications to productsthat do not require high throughput—e.g., masksand small batches of electronics. Research effortsare underway to develop parallel projection and

multiple source ion beam lithographic equipmentthat might overcome the limitations of seriallyscanned ion beam lithography.

Scanned probe modification of surfaces, usingrecently developed scanning tunneling microsco-

py (STM) methods, is being done by researchersin many research laboratories. Since STMs canmanipulate individual atoms, such approacheshave theoretical resolution limits of single atoms.This approach is still in early phases of researchand is focusing on basic physics measurements

  38• Miniaturization Technologies

and better understanding of the behavior of sur- q sputtering,

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faces. The lack of stability of STM tips and slowspeed, however, make it far from a practical tech-nology for manufacturing in the foreseeable fu-

ture.

PATTERN TRANSFER

The various lithography systems produce relief patterns in resists, and a subsequent patterntransfer step is necessary to fabricate the struc-

ture. There are a number of options available andeach involves some engineering tradeoffs. Oncethe resist pattern is in place, and selected areas of the underlayer are exposed, there are three possi-ble next steps: 1) add to, 2) remove, or 3) modifythe exposed areas.

Adding to the exposed area involves either dep-osition or growth of a material on the exposed

areas. Growth is different from deposition be-cause it involves consumption of the surface (usu-ally combining with some introduced chemical)to create the new substance. The most commonexample is a silicon surface being consumed inthe process of forming silicon dioxide. It involvesheating the silicon wafer in the presence of oxy-gen, causing the growth of silicon dioxide from

the exposed silicon. A number of materials aregrown in this way, since the consumption of thesurface results in excellent adhesion, better elec-trical and mechanical properties, and improve-ments in other materials properties. This specificreaction has been exhaustively investigated andperfected and now can be used to grow oxidefilms whose thickness, and even lateral dimen-sions, can be measured in atomic layers (a fewangstroms).

Deposition creates new layers of material onthe exposed area. These techniques usually in-volve evaporating or sputtering a piece of mater-ial-the target-so its atoms or molecules fly off and land on the sample. Deposition techniquesinclude:

q spin-on,

q thermal evaporators,

. laser ablation deposition,

q chemical vapor deposition; and

q molecular beam epitaxy such as organo-metallic chemical vapor deposition.

Spin-on deposition is the simplest depositiontechnique. It involves spinning the sample while aliquid is poured onto it; the spinning action dis-tributes the liquid evenly. Subsequent heatingbakes the liquid into a solid thin film.

Thermal evaporators use a heated filament oran electron beam to vaporize material. The mate-rial passes through a vacuum to impinge on thesample, building up a film. Evaporators emit ma-terial from a point source, resulting in “shadow-ing” and sometimes causing problems with verysmall structures.

Sputter deposition systems erode atoms from a

broad target that then travel to the sample. Thisresults in better line width control and uniformi-ty, especially with high aspect ratio (height/width)structures. Refinements of these processes, e.g.,in situ cleaning with an ion gun, or using electroncyclotron resonance to confine and densify aplasma, result in better adhesion, higher qualityfilms, and more versatility. Using lasers or par-

ticle beams in conjunction with deposition pre-sents the possibility of defining patterns on thesample in a single step.

Laser ablation deposition uses intense laserradiation to erode a target and deposit the mate-rial onto a substrate. This technique is particular-ly useful in dealing with compounds of differentelements —e.g., yttrium-barium-copper oxide su-

perconductor films.Chemical vapor deposition (CVD) deposits

thin films by passing reactive gases over the sam-ple. The substrate is heated to accelerate deposi-tion. CVD is used extensively in the semiconduc-tor industry and has played an important role inpast transistor miniaturization by making it pos-sible to deposit very thin films of silicon. Most

CVD is performed in vacuum, but new tech-niques allow operation without vacuums. Radiofrequency (RF) or photon radiation can be used

 

  Appendix A--Fabrication Technologyfor Miniaturization .39

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to enhance the process and is known as plasmaenhanced CVD (PECVD).

Some deposition techniques are so precise thatmaterial can be built up literally atom by atomwith the crystal structure of the new materialexactly matching that of the underlying layer. Inmolecular beam epitaxy (MBE), the sample isplaced in an ultra high vacuum in the path of streams of atoms from heated cells that contain

targets of various types. These atomic streamsimpinge on the surface, creating layers whosestructure is controlled by the crystal structure of the surface, the thermodynamics of the constitu-ents and the sample temperature. Organo-metal-lic chemical vapor deposition (OMVPE, or some-times MOCVD) relies on the flow of gases(hydrides like arsine and phospine or organome-

tallics like tri methyl gallium and tri methyl alu-minum) past samples placed in the stream.Again, the sample surface and thermodynamicsof the processes determine the compounds de-posited. Both MBE and OMVPE provide thick-ness control within one atomic layer (a few ang-stroms) and are especially useful in creatingcompound semiconductors and exploiting quan-tum effects and band-gap engineering. Thisstructural control enables researchers to exploit

optical transitions in some materials, producinglasers, detectors, and other optical elements.

Materials modification processes are usedmainly to vary the electrical conductivity in theappropriate areas. In the past, dopants (atomsthat can either contribute or subtract electronsfrom silicon atoms) were diffused into the sub-strate thermally; now they are implanted as highenergy ions (see figure A-2). Implantation offersthe advantage of being able to place any ion at anydepth in the sample, independent of the thermo-dynamics of diffusion and problems with solidvolubility and precipitation. Ion implantation,originally developed for high energy physics, isnow an indispensable part of semiconductormanufacturing. Ion beams produce crystal dam-age in addition to the chemical or electronic effectof the dopants. Since crystal damage reduces

electrical conductivity, this effect can be ex-ploited to electrically isolate devices from oneanother. Ion beams can implant enough materialto actually form new materials--e.g., oxides andnitrides-some of which show improved wearand strength characteristics.

Subtractive processes —the removal of materi-al-are also vital to the field. Some of the stepsare still done the same way they were centuries

Figure A-2–ion Implantation

Accelerated boron ions

p-Type-

silicon Thick oxide

Polysilicon

/

gate

Ion implantation is employed to place a precisely controlled amount of dopant (in this ease boron ions) below the gate oxide of a MOStransistor. By choosing a suitable acceleration voltage the ions can be made to just penetrate the gate oxide but not the thicker oxide (left).After the boron ions are implanted polycrystalline silicon is deposited and patternedto form the gate regions of the transistor. A thin layer ofthe oxide is then removed and the source and drain regions of the transistor are formed by the diffusion n

-of an n-type impurity (right).

SOURCE: William G. “The Fabrication of (San  CA: Freeman Co.,1977), p. 50. Copyright (c) 1977 by -George V. Kelvin.

 40 q  Miniaturization Technologies

ago. The object, with its lithographically definedareas exposed and the remainder protected by

tigating new materials, since it can be exploited touncover ways to etch new and exotic materials

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areas exposed and the remainder protected bythe “resist,” is dipped into a chemical bath and areaction or dissolution is allowed to take place.

Unfortunately, liquid chemicals usually have nosense of direction and will dissolve at an equalrate on all sides. As device geometries shrink, itbecomes important to control directionality.Most modern etching is done in vacuum withoutcontact with liquids.

Ion milling uses the sputtering process to bom-

bard the substrate with accelerated ions. Thesputtering process relies on a physical mecha-nism whereby energy is transferred to a surfaceby impinging ions. This energy is enough thatsome atoms break free of the surface. This mech-anism erodes all materials, with small differencesin rate between any two. Selectivity is poor, andany masking material (resist) will disappear as

fast as the underlayer, limiting the (relief) depth.

Reactive ion etching (RIE) can be highly selec-tive because it is a chemical reaction between ions(radicals) formed in a plasma and atoms on thesample surface, and can be highly selective. RIEhas excellent lateral control because the electricfields produced by the plasma cause ions to dif-fuse directionally. Straight parallel trenches a mi-

cron or more deep can be etched without affect-ing a rather fragile resist mask; minimum featuresizes of a few nanometers are possible. RIE ishighly selective in its etching: oxygen etches hy-drocarbons (resists), fluorine compounds areuseful in working with silicon systems, and manymaterials are susceptible to chlorine etch, espe-cially the compound semiconductors like gallium

arsenide. A great deal of work is directed at dis-covering the etching characteristics of other com-pounds.

The combination of physical and chemicaletching is achieved in a process called chemicallyassisted ion beam etching (CAIBE). The com-bined effects of ion sputtering and chemical reac-

tion with reactive ions results in a faster etch ratethan that due to either mechanism alone. CAIBEis of particular interest to research groups inves-

uncover ways to etch new and exotic materials.

Unlike ancient lithographs, modern semicon-

ductors must undergo many processing steps.The mask must remain intact until the substrateetch is complete, without changing feature size orshape or surface characteristics (morphology).Multiple operations are often required because of the processing limitations of materials. For exam-ple, to grow a thin layer of silicon dioxide at1,000°C, a resist is used to pattern a silicon ni-

tride layer which is then capable of surviving thehigh temperature during the oxide growth. Multi-ple layers are often processed in succession tobetter allow a straightedge to be carried througha thick stack of material.

CHARACTERIZATION

Characterization has become an indispensabletool in the art and science of fabrication. Thedesigner needs information about device per-formance, the experimenter needs to know com-position and concentration, and the process engi-neer must have immediate confirmation of theelectrical, mechanical, optical, or chemical prop-

erties of a thin film. In fact characterization, orfailure analysis, is in some cases as difficult andextensive as the original experiment. The mostcommon questions addressed by characteriza-tion concern the shape and size of the structure.Optical and electron microscopes provide thisinformation over size ranges from hundreds of microns to fractions of a nanometer (near-atomicdimensions).

Instruments also exist to measure a range of materials properties, including the thickness, re-fractive index, and electrical resistivity. Whilethese techniques involve the measurement of thinfilm properties over large distances, microchar-acterization can determine composition or struc-ture on a size scale comparable to the mean free

path of an electron and some techniques have anultimate resolution on the order of a few atomicdiameters.

  Appendix A--Fabrication Technology for Miniaturization .41

There are a wide range of techniques usuallyid ifi d b d f h

IMMA – Ion microprobe mass analysis:hi h l i d i

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identified by acronyms, and some of the moreuseful are listed here:

SCANNED BEAM TECHNIQUES

A E S –

RBS –

SEM – Scanning electron microscope:creates image of a surface bymeasuring the reflection from abeam of electrons.

TEM – Transmission electron micro-scope: determines crystal struc-ture by measuring transmissionof electrons through a thin sam-ple; has high resolution.

Auger electron microscopy: iden-tifies constituents in the surface

layer by measuring energy of elec-trons emitted due to “Auger tran-sitions.”

Rutherford backscattering spec-troscopy: identifies constituentsby measuring the spectrum of scattered ions off a sample.

SIMS – Secondary ion mass spectrosco-py: analyzes composition of mate-rial removed by ion bombard-ment.

XRF – X-ray fluorescence: identifiescomposition from photon emis-sion due to x-rays.

EDS (EDX)— Energy dispersive x-ray spectros-copy: identifies composition fromdispersion of x-rays.

EELS –

ED –

LEED –

RHEED –

high resolution secondary ionmass spectroscopy (SIMS).

Electron energy loss spectrosco-py: identifies composition bymeasuring energy loss of elec-trons during electron interaction.

Electron diffraction: measurescrystal structure by diffraction of electrons.

Low energy electron diffraction:measures surface structure bydiffraction of electrons.

Reflection high energy electrondiffraction: measures surfacestructure; particularly useful forepitaxial film growth.

SCANNED PROBE TECHNIQUES

S T M – Scanning tunneling microscopy:creates image of surface usingelectron tunneling between thesurface and a sharp tip near thesurface; very high resolution.

AFM – Atomic force microscopy: createsimage of surface using repulsionof electron charge distributionsbetween surface and a tip; near-atomic resolution is possible.

SxM – Other developing scanned probemicrocopies: create images of surface characteristics for mag-

netic force, electrochemical mea-surement, etc., using the principleof the STM.

Appendix B

Glossary

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Actuator: Causes mechanical force or motion inresponse to an electrical signal.

Analog: Refers to electrical signals that can varycontinuously over a range, as compared todigital signals, which are restricted to a pairof nominally discrete values.

Angstrom: One tenth of a nanometer, 10-10

meters.

Architecture: The overall logic structure of acomputer or computer-based system.

Capacitor: Passive circuit element that storeselectrical charge, creating a voltage differen-tial. Capacitors can be fabricated within inte-grated circuits, as well as in the form of dis-crete components.

Charge-Coupled Devices (CCD): A type of solid-state electronic device used as a sensor insome types of cameras.

Circuit Board: A card or board of insulatingmaterial on which components such as semi-conductor devices, capacitors, and switchesare installed.

Clock An electronic circuit, often an integratedcircuit, that produces high-frequency timingsignals. A common application is synchroni-zation of the operations performed by a com-puter or microprocessor-based system. Typi-cal clock rates in microprocessor circuits arein the megahertz range, 1 megahertz equaling10

6cycles per second.

Compact Disk (CD): An optical storage mediumused for music and for computer data, amongothers.

Deposition: An operation by which a film isplaced on a surface.

Die Bonder: Assembly equipment that bonds theback side of an integrated circuit die to vari-

ous materials. A die is a small piece of siliconwafer that contains the complete circuit beingmanufactured.

Doping: Adding to a semiconducting materialsmall amounts of other elements (dopants) tochange its electronic properties.

Dynamic Random Access Memory (DRAM): Themost common type of computer memory.DRAM architecture usually uses one transis-tor and a capacitor to represent a bit, which isa memory cell in a computer.

Electron Cyclotron Resonance (ECR): A technol-ogy that uses a high-frequency microwave en-ergy source to create a plasma in a confinedregion using a magnetic field for the purposeof etching and deposition.

Etching: A process in which chemicals are usedto remove previously defined portions of the

silicon oxide layer covering the wafer to ex-pose the silicon underneath.

Flat Panel Displays: A thin display screen that

uses any of a number of technologies, such asliquid crystal display. Flat panel displays are

used in laptop computers in order to keep theoverall size and weight of the machine to aminimum.

Gallium Arsenide (GaAs): A compound semi-

conductor with properties necessary for veryhigh-frequency microwave (analog) devices

and optoelectronics.

Gate: A simple electronic circuit that can imple-ment a specified logical operation. In essence,

gates act like switches. Computer processingunits depend on large assemblies of gates, as

do integrated circuit memory chips.

Integrated Circuit (IC): Electronic circuits, in-cluding transistors, resistors, capacitors, and ‘their interconnections, fabricated on a singlesmall piece of semiconductor material (chip).Categories of ICs such as LSI and VLSI refer

to the level of integration, which denotes the

number of transistors on a chip. ICs may bedigital (logic chips, memory chips, or micro-processors) or analog.

-43-

  44. Miniaturization Technologies

Ion Implantation: A process in which silicon is

bombarded with high voltage ions in order to

Microprocessor: A computer central processingunit on a single chip

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bombarded with high-voltage ions in order to

implant them in specific locations and pro-

vide the appropriate electronic characteris-tics.

Liquid Crystal Display (LCD): A liquid crystal

display is a technique that uses a transistorfor each monochrome or each red, green and

blue dot. It provides sharp contrast and

speeds screen refresh. LCD technology iscommonly used in digital watches and laptop

computers.Lithography A process in which the desired cir-

cuit pattern is projected onto a photoresist

coating covering a silicon wafer. When devel-oped, portions of the resist can be selectivelyremoved with a solvent, exposing parts of the

wafer for etching and diffusion.

Logic Chips: ICs that manipulate digital data.

LSI: Large-scale integration. Typically involvingbetween 2,000 and 64,000 transistors.

Mainframe Computer: A system, normally in-tended for general-purpose data processing,characterized by high performance and ver-satility. Mainframes have grown steadily incapability as smaller and less expensive ma-

chines have progressed.

Mask: Stencil-like grid used in creating litho-graphic patterns on semiconductor chips.

Mass Storage: Refers to peripheral equipmentfor computer memory suitable for largeamounts of data or for archival storage. Typi-cal mass storage devices are disk and tape

drives.Memory Chips: Devices for storing information

in the form of electronic signals.

Microcomputer: Refers to integrated circuitsthat contain a microprocessing unit plusmemory, as well as to computers designedaround microprocessors or single-chip mi-crocomputers.

Micrometer: One-millionth of a meter.

Micron: One-millionth of a meter.

unit on a single chip.

Nanometer: One-billionth of a meter.

Optical Disks: Recording media including CDsthat store information in patterns of micro-scopic pits on the surface of the disk, whichcan then be detected by a solid state laser anddetector system and reproduced as sound,images, or data.

Optoelectronic Devices: Devices that convert

light signals to electronic signals and viceversa.

RAM (Random Access Memory): Most common-ly, an integrated circuit that stores data insuch form that it can be read, erased, andrewritten under the control of a computerprocessor. Any memory location in a RAMcan be addressed directly (random access) as

opposed to sequentially or serially.Resist, Photoresist: Chemicals used in litho-

graphic processing of integrated circuitswhich, much like photographic emulsions,can be exposed by light, X-rays, or other radi-ation to form patterns.

Semiconductors: Materials, e.g., silicon, that

have four electrons in their outer electronshells and have electrical conductivities thatare lower than good conductors such as met-als but higher than insulators such as glass.Other semiconductors include germanium,gallium arsenide (GaAs), iridium phosphide(InP), mercury telluride(HgTe), cadmium tel-luride (CdTe), and alloys of these compoundsemiconductors.

Sensor: Converts a pressure, temperature, or oth-er physical parameter into an electrical sig-nal, often for use in a control system. A digitalspeedometer for an automobile transformsthe output of a sensor into a miles-per-hourreading, as does an airplane’s air speed indi-cator. In the case of the automobile speedom-eter, rotary motion is converted into an elec-trical signal, while an air speed indicatordepends on the pressure created by the mo-tion of the airplane.

  Appendix B-Glossary .45

Silicon: One of the most common elements foundin nature and the basic material used to make

Wafer: A thin disk, cut from silicon or other semi-conductor material The wafer is the base

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in nature and the basic material used to makethe majority of semiconductor wafers.

Stepper: A sophisticated piece of equipmentused to transfer an integrated circuit patternfrom a mask onto a wafer.

Substrate: A piece of material, typically a semi-conductor, on which layers of materials aredeposited and etched to fabricate a device ora circuit.

Transistor: An electronic device that can be used

to switch or amplify electronic signals.VLSI: Very large-scale integration. Typically in-volving more than 64,000 transistors.

conductor material. The wafer is the basematerial on which integrated circuits are fab-ricated. It is typically 4 to 8 inches in diame-ter.

Yield: In the production of microelectronic de-vices, the fraction that survive all tests andinspection, function correctly, and can besold or incorporated into the manufacturer’sown end products. Production costs dependheavily on yields, which themselves dependon circuit design, fabrication equipment, andcontrol of the manufacturing process.

Index

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Accelerometer, 1,30-31Analog Devices, In c., 9,31Angstrom technology, 7Arthur D. Little, Inc., 28Assemblers, 20,21AT&T Bell Laboratories, 7,9, 11,31,33,37Automobiles, 3,4,9

Biosensors, 3,8,28-30Blood analysis, 29Bosch, 10

Bulk micromachining, 31

California, 9Canon, 33

Cellular automata, 16cellular ph one, 5Characterization, 3,35,40-41Charge cou pled device, 27-28Chem ical field effect transistor, 28Chem ical s ensor s, 3,8,28-30Chemical vapor deposition, 38

Chemically assisted ion beam etching, 40chip size, 14,22,24Clark, Leland C., 28Clock cycle, 4, 15,24

Communications, 5, 16

Consumer electronics, 4,5, 16,26,27,28,33

Defense Advanced Research Project Agency, 7,9, 11Department of Defense, 7,8,9,28Department of Energy, 9

Digital Equipment Corp., 7Display technology, 5,23Doping, 39

Drexler, Eric, 21Dynamic random access memory, 1,4,5,13,15

Electron-beam lithogr aph y, 11,13, 17,37Etching, 39-40

Eutaxic control, 20

Feynman m achines, 20

Feynman, Richard, 21Fiber-optics, 29

Flat panel display, 5,23Fluid flow, 31,33

Food processin g, 28

Fraunh ofer Institu te, 9, 10Fujitsu, 7

Galliu m arsen ide, 16, 17German Federal Ministry for Research and Technology, 9

German Karlsruhe Nuclear Research Center, 9, 10,31

Glucose sensor, 28,29-30

Hewlett-Packard, 33High electron mobility transistor, 16

High-performance computers, 15,26Hitachi, 33Hybrid wafer-scale integration, 24

Interconnection, 8, 13, 15, 17,21,23-27Inte rnat ional Busin ess M achin es, 7, 10, 11,23,24,37Ion-beam lithography, 11, 17,37Ion implantation, 39

Ion millin g, 40

Japanese Basic Technologies for the Future Industries Program,

7Japanese Exploratory Research for Advanced Technology, 7

Japanes e Large Scale Program , 7Japanese Ministry of Agriculture, Forestry and Fisheries, 8

Japanese Ministry of In ternational Trade and Indu stry, 7,33Japanese Science and Technology Agency, 10Japanese Technology and Evaluation Center, 8Jet Propulsion Laboratory, 33

Kodak, 28

Laptop computer, 5,19Lasers, 16, 18,23,38Lawrence Livermore National Laboratory, 9,33LIGA, 31

Lithography, 10-11, 13, 17-19,23,31,32,35-38Louisiana, 9, 11

Louisiana Technical University, 9

Magn etic storage, 23Mainframe computer, 19Ma nu facturin g, 3, 13,30,32Manufacturing costs, 1,3, 13Ma ss stora ge, 17,23Massachusetts Institute of Technology, 31Ma teri als scien ce, 3, 16, 19,31,4041Matsushita Central Research, 10Mechanical properties, 31

Medical applications, 16,28-30,33Messerschmidt, 10

Micro-Electromechanical Sensors and Actuators Institute, 10Microelectronics and Computing Technology Consortium, 8,24

Micromachining, 30Micromechanics, 1,3,8,9,20,30-34Micromotors, 32-33Micropro cessor, 4Mi crorobots, 10,33Military applications, 16Mitsubishi, 17Mo lecular b eam epita xy, 16,38,39Molecular electronics, 3,7, 16, 17Molecular machin es, 20-21Motorola, 11

Multi-chip modules and packages, 4,8,24,25

Nanob ots, 20Nanotechnology, 20

- 4 7 –

  48 . Miniaturization Technologies

National Aeronau tics and Space Admin istration, 9,33National Institutes of Health, 9

National Research Council 8

Siemens, 10Space applications, 16

Spin on 38

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National Research Council, 8National Science Foundation, 7,9

Netherlands, 10

New York, 11Nip pon Electric Co., 5, 10,24Nippon Telephone & Telegraph, 7, 10

Noise, 15

Optical storage, 17,23

Optics, 16,33,39Optoelectronics, 7,39Organo-metallic chemical vapor deposition, 39

Packaging, 4,5,23-27,32Phase-shift lithography, 10, 19,35Pressure sensor, 30

Quantum electronics, 3,7,15,16

Reactive ion milling, 40Refrigeration, 15, 19,26Ricoh, 10

Sacrificial layer, 31-32

Sandia National Laboratory, 9scaling laws, 15Sc ann ing tun nelin g m icroscope, 19,20,23,37,41Semiconductor manufacture“ g eq uip men t, 1,3,4,9, 10-11,

17-19,30,31-32,35-41

Spin on , 38

Sputtering, 38

Surface m icro-machin ing, 31-32

Surface mount technologies, 4,6,8Su rface scie nce, 3, 19,31,38,40-41

Switzerland, 10

Tektronix, 28

Texas Instruments, 7,28Thermal evaporation, 38

Toyota, 10Traditional machining, 33

U.S. Congress, 9, 11Ultraviolet lithography, 10, 17,31,35,37University of California at Berkeley, 31,33University of D elft, 10University of Pennsylvania, 29

University of Tokyo, 10

University of Twente, 10University of Utah , 33

von Neumann architecture, 16, 27

X-ray lit ho graphy , 10, 11, 13, 17,31,32,35,37

U S G O V E R N M E N T P R I N T I N G O F F I C E : 1991 0 - 297-927 : QL 3