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Alcohols, C12-14, ethoxylated, sulfates, sodium C12-14, ethoxylated, sulfates, sodium salts ... life cycle stage and use desriptors only. ... C12-14, ethoxylated, sulfates, sodium

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  • Alcohols, C12-14, ethoxylated, sulfates, sodium salts REACH reg-no.: 01-2119488639-16-0008 01-2119488639-16-0009 CAS-no.: 68891-38-3 EC-no.: 500-234-8 Version: 2.00 16.09.2015

    000000000356_EN_01_COLIPA.pdf Page 1 of 22

    Sasol Global Product Safety phone: +49 (0) 23 65 49 47 05

    EXPOSURE ASSESSMENT Overview of exposure scenarios EXPOSURE ASSESSMENT pages 002 011 RISK CHARACTERISATION pages 012 019 QUALITATIVE CSA - SKIN IRRITATION AND EYE DAMAGE pages 020 022 The following table summarizes all exposure scenarios that are assessed in this CSR. The summary lists use volumes, life cycle stage and use desriptors only. For details on use conditions and exposure calculation results please refer to the corresponding subchapters 9.x and 10.x. Exposure scenarios 9.2 to 9.x have been calculated using EasyTRA 4.0.0. EasyTRA uses algorithms on the basis of the latest versions of the ECHA REACH Guidance chapters R12 (as of March 2010), R14, R15, and R16 (as of October 2012) and EUSES. EasyTRA is a graphical user interface which works in compliance with ECETOC Targeted Risk Assessment 3 (as of July 2012; for detailed information see ECETOC Technical Report No. 114) for the calculation of worker and consumer exposure and complies with EU TGD 2003 Risk Assessment Spreadsheet Model 1.24a for the environmental exposure (see ECHA REACH Guidance chapter R16.6.2 ). Results obtained by EasyTRA are routinely validated against the results obtained by performing the same calculations with the original tools. The format of this CSR follows the current ECHA template for CSRs.

  • Alcohols, C12-14, ethoxylated, sulfates, sodium salts REACH reg-no.: 01-2119488639-16-0008 01-2119488639-16-0009 CAS-no.: 68891-38-3 EC-no.: 500-234-8 Version: 2.00 16.09.2015

    000000000356_EN_01_COLIPA.pdf Page 2 of 22

    Sasol Global Product Safety phone: +49 (0) 23 65 49 47 05

    EXPOSURE ASSESSMENT pages 002 011 Overview on exposure scenarios and coverage of substance life cycle

    ES

    nu

    mb

    er

    Short description of

    exposure scenario

    Resulting life cycle stage

    Sec

    tor

    of

    use

    (S

    U)

    Pro

    cess

    Ca

    teg

    ory

    (P

    RO

    C)

    Pro

    du

    ct C

    ate

    go

    ry (

    PC

    )

    Art

    icle

    Ca

    teg

    ory

    (A

    C)

    En

    vir

    on

    men

    tal

    Rel

    ease

    Ca

    teg

    ory

    (E

    RC

    )

    Vo

    lum

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    )

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    fact

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    Fo

    rmu

    lati

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    En

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    for

    art

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    Pro

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    Co

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    9.177 Manufacture of cosmetic

    products (COLIPA M1,

    COLIPA M2, COLIPA

    M3, COLIPA M4,

    COLIPA M5.1, COLIPA

    M5.2, COLIPA M6,

    COLIPA M7, COLIPA

    M8)

    x x 3, 22,

    10

    1, 2,

    3, 5,

    8A,

    8B,

    9, 14,

    15

    2 10000

    9.178 End use of cosmetic

    products (COLIPA U1)

    x 21 39 8A 10000

  • Alcohols, C12-14, ethoxylated, sulfates, sodium salts REACH reg-no.: 01-2119488639-16-0008 01-2119488639-16-0009 CAS-no.: 68891-38-3 EC-no.: 500-234-8 Version: 2.00 16.09.2015

    000000000356_EN_01_COLIPA.pdf Page 3 of 22

    Sasol Global Product Safety phone: +49 (0) 23 65 49 47 05

    9.177 Scenario 177: Manufacture of cosmetic products (COLIPA M1,

    COLIPA M2, COLIPA M3, COLIPA M4, COLIPA M5.1, COLIPA

    M5.2, COLIPA M6, COLIPA M7, COLIPA M8)

    This scenario is described by the following combinations of use descriptors. The corresponding contributing

    scenarios are described in the respective subchapters.

    An overall exposure scenario may be described by a number of contributing scenarios which may be subdivided

    into environmental exposure, worker exposure and consumer exposure.

    The following scenarios contribute to the scenario Manufacture of cosmetic products.

    The corresponding release to the environment, exposure of workers and consumers resulting from these

    contributing scenarios is summarized in chapter 10.177 ff.

    Table 1. Description of ES 177

    Free short title Manufacture of cosmetic products (COLIPA M1, COLIPA

    M2, COLIPA M3, COLIPA M4, COLIPA M5.1, COLIPA

    M5.2, COLIPA M6, COLIPA M7, COLIPA M8)

    Systematic title based on use descriptor ERC 2; PROC 1, 2, 3, 5, 8A, 8B, 9, 14, 15

    Name of contributing environmental scenario

    and corresponding ERC

    ERC 2 Formulation of preparations

    Name(s) of contributing worker scenarios and

    corresponding PROCs

    PROC 1 - Use in closed process, no likelihood of exposure

    PROC 2 - Use in closed, continuous process with

    occasional controlled exposure

    PROC 3 - Use in closed batch process (synthesis or

    formulation)

    PROC 5 - Mixing or blending in batch processes (multistage

    and/or significant contact)

    PROC 8a - Transfer of chemicals from/to vessels/ large

    containers at non dedicated facilities

    PROC 8b - Transfer of chemicals from/to vessels/ large

    containers at dedicated facilities

    PROC 9 - Transfer of chemicals into small containers

    (dedicated filling line)

    PROC 14 - Production of preparations or articles by

    tabletting, compression, extrusion, pelletisation

    PROC 15 - Use of laboratory reagents in small scale

    laboratories

    9.177.1 Contributing Scenario (1) controlling environmental exposure for ERC 2

  • Alcohols, C12-14, ethoxylated, sulfates, sodium salts REACH reg-no.: 01-2119488639-16-0008 01-2119488639-16-0009 CAS-no.: 68891-38-3 EC-no.: 500-234-8 Version: 2.00 16.09.2015

    000000000356_EN_01_COLIPA.pdf Page 4 of 22

    Sasol Global Product Safety phone: +49 (0) 23 65 49 47 05

    Operational conditions

    Annual tonnage 1.00E4 to/year

    Daily amount used at site 1.67E4 kg/day

    Release times per year 220 days/year

    Local freshwater dilution factor 10

    Local marine water dilution factor 100

    Release fraction to air from process 0 %

    Release fraction to wastewater from process 0.100 %

    Release fraction to soil from process 0 %

    Fraction tonnage to region 100 %

    Fraction used at main source 36.74 %

    STP yes

    River flow rate 18000 m3/day

    Municipal sewage treatment plant discharge 2000000 L/day

    Risk management measures

    SpERC COLIPA SPERC 2.1.a.v1 - COLIPA - Formulation of low

    viscosiy liquids (Shampoo, hair conditioner, shower gel,

    foam bath) (large scale)

    9.177.2 Contributing Scenario (2) controlling industrial worker exposure for PROC 1 (PC 39)

    Name of contributing scenario 1 - Use in closed process, no likelihood of exposure

    Scenario subtitle Closed process

    Product characteristics

    Physical state liquid

    Concentration in substance 100 %

    Fugacity / Dustiness low

    Frequency and duration of use

    Duration of activity >4 hours (default)

    Frequency of use 5 days / week

    Human factors not influenced by risk management

    Exposed skin surface 240 cm2

    Other given operational conditions affecting workers exposure

    Location indoors

    Domain industrial

    Technical conditions and measures to control dispersion and exposure

  • Alcohols, C12-14, ethoxylated, sulfates, sodium salts REACH reg-no.: 01-2119488639-16-0008 01-2119488639-16-0009 CAS-no.: 68891-38-3 EC-no.: 500-234-8 Version: 2.00 16.09.2015

    000000000356_EN_01_COLIPA.pdf Page 5 of 22

    Sasol Global Product Safety phone: +49 (0) 23 65 49 47 05

    Local exhaust ventilation no

    Conditions and measures related to personal protection, hygiene and health evaluation

    Protective gloves No

    Respiratory protection no

    9.177.3 Contributing Scenario (3) controlling industrial worker exposure for PROC 2 (PC 39)

    Name of contributing scenario 2 - Use in closed, continuous process with occasional

    controlled exposure

    Scenario subtitle Closed process, controlled exposure

    Product characteristics

    Physical state liquid

    Concentration in substance 100 %

    Fugacity / Dustiness low

    Frequency and duration of use

    Duration of activity >4 hours (default)

    Frequency of use 5 days / week

    Human factors not influenced by risk management

    Exposed skin surface 480 cm2

    Other given operational conditions affecting workers exposure

    Location indoors

    Domain industrial

    Technical conditions and measures to control dispersion and exposure

    Local exhaust ventilation no

    Conditions and measures related to personal protection, hygiene and health evaluation

    Protective gloves No

    Respiratory protection no

    9.177.4 Contributing Scenario (4) controlling industrial worker exposure for PROC 3 (PC 39)

    Name of contributing scenario 3 - Use in closed batch process (synthesis or formulation)

    Scenario subtitle Closed batch process

    Product characteristics

    Physical state liquid

    Concentration in substance 100 %

    Fugacity / Dustiness low

    Frequency and duration of use

    Duration of activity >4 hours (default)

  • Alcohols, C12-14, ethoxylated, sulfates, sodium salts REACH reg-no.: 01-2119488639-16-0008 01-2119488639-16-0009 CAS-no.: 68891-38-3 EC-no.: 500-234-8 Version: 2.00 16.09.2015

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