ALUMINIUM COMPOSITE PANEL

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ACP SPECIFICATION AND TECHNIQUES FOR MANUFACTURING

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  • Efficient Building Materials

    Aluminium

    Composite Panels Life Cycle Assessment

    Roopa Iyer

    Semester 11: TAE114 E11

    Rachana Sansads Institute of Environmental Architecture

    YCMOU

  • CONTENTS

    SR.NO DESCRIPTION PAGE

    Acknowledgement

    1. Introduction to Aluminum Composite panel sheet

    2. Introduction to chosen brand

    3. Raw material :

    Introduction

    Processing

    Properties

    Source

    4. Process of ACP sheet

    5. Methods of installation

    6. Properties of ACP

    7. Energy consumption calculation table:

    Primary Energy

    Transportation

    Total embodied energy

    8. Labour

    9. Applications

    10. Maintenance

    11. Cost

    12. Environmental impact

    13. Modes of reducing the impact

    14. Alternative material:

    Clay tile cladding

    Bibliography

  • Efficient Building Materials LCA

    1

    ACKNOWLEDGEMENT

    This assignment would not have been possible without the help of my guides

    Prof. Roshini Udyavar, Prof. Ashok Joshi.

    I would also like to thank Mr. Mehul Joshi, technical manager of Eurobond Industries Pvt. Ltd, &

    Mr. Vineet (Fabricator) for helping with the collection of data.

    I am Thankful to Ar. Chirag Jain (Partner), UCJ architecture & environment, for helping with data

    access & information.

    I am grateful to my family for their patience.

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    INTRODUCTION

    Today our cityscape consists of these buildings - MODERN BUILDINGS!!!

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    3

    Aluminium Composite Panel (ACP) is a widely-

    used term, describing flat panels that consist

    of a non-aluminium core bonded between two

    aluminium sheets. Aluminium sheets can be

    coated with PVDF or Polyester paint. ACPs are

    frequently used for external cladding of

    buildings (building facades).

    The main advantage of ACP is that it is very rigid and strong despite its light weight. Due to the

    ability of painting the aluminium in any kind of colour, ACPs are produced in a wide range of

    metallic and non-metallic colours as well as patterns that imitate other materials, such as wood

    or marble.

    Applications of ACPs are not limited to external building cladding, but can also be used in any

    form of cladding such as partitions, false ceilings etc. Aluminium Composite Panels are also

    widely used within the signage industry as an alternative to heavier, more expensive substrates.

    The idea of this ACP came out form the sandwich panel was made for big refrigeration area such

    as rooms, the thickness was not less than 10cm and also it is used in big roof bulidings in the area

    of the Arabic gulf , The ACP main idea is to have good looking surface along with good isolating

    material , as most of ACP's inside layer is made of low density Polyethylene .

    Aluminium Composite Panel (ACP) sheet also known as sandwich panels consists of low density

    polyethylene (LDP) core sandwiched between two aluminium foils.

    The entire panel consists of the following layers:

    1. Top Aluminium foil

    2. Low density Polyethylene Core

    3. Bottom Aluminium foil

    The top Aluminium sheet is coated with either Polyester or PVDF paint

    The Core is either Low density Polyethylene or a Fire resistant core which is specially treated for

    fire resistance

    The bottom aluminium sheet comes with anti corrosive primer or (6-8 micron) backside paint

    PROTECTIVE FILM

    PVDF CLEAR COAT

    PVDF BASE COAT

    PVDF PRIMER COAT

    HIGH STRENGTH ALUMINUM FOIL

    ADHESIVE FILM

    LOW DENSITY POLYETHYLENE CORE

    ADHESIVE FILM

    HIGH STRENGTH ALUMINUM FOIL

    BACK COAT

    DOUBLE PE LAYER TO BE REMOVED

    AFTER INSTALLATION

    PROTECTIVE FILM

  • Efficient Building Materials LCA

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    BRAND INTRODUCTION

    Eurobond Aluminum Composite panels:

    Eurobond Industries' Aluminum Panel Sheet lounge has a very compatible,

    composite adaptable and flexible range of decorative products that have got

    culminatedly the result of German technology by the names Platinum, Pearl, Ruby,

    Gold, Silver, Bronze, Kohinoor, Diamond and Crystal, in their ethnic collection for the

    customers.

    Eurobond Aluminium panel Sheet is sandwich with top & bottom layers of aluminium, non toxic

    polyethylene cores materials. Both surface of foil coated with special baking varnish.

    Eurobond Industries Pvt. Ltd., established in 2002, is one of the leading manufacturing

    companies in construction materials. They manufacture Eurobond brand Aluminium Panel

    Sheet, Fire resistance Aluminium Panel Sheet and so on. The manufacturing unit is in Jammu,

    India. Eurobond Industries Pvt. Ltd. is an ISO 9001:2000 Certified Company.

    Eurobond imports the Aluminium foil from China. The Aluminium foil is produced within

    China. They use Aluminium alloy 1100-H18. The Aluminium content for unalloyed aluminium

    not made by a refining process is the difference between 100% & the sum of all other

    analyzed metallic elements present in amounts of 0.010% of more each, expressed to the

    second decimal before determining the sum.

    Eurobond uses 2nd grade LDPE which is one time recycled for its production. It is sourced

    from local companies

    The protective film (Double PE) protects panels when cutting, transiting, grooving and folding

    to avoid mechanical damage and contaminated surface. After finishing installation, protective

    film should be peeled off.

    Adhesive film (protective film): EAA ethylene crylic acid co-polymer.Eurobond panel sheets

    adopt the first grade adhesive film supplied by DU Pont. Film thickness >0.07mm for 0.50mm

    aluminium sheet & >0.05mm for 0.25mm aluminium sheet

    Coating: PVDF KYNAR 500 (70% min)

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    Map showing Eurobond ACP office (with stocking facilities):

    Sandwiching plant location

    Depots for ACPs

    Study location

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    6

    Aluminium foil:

    Aluminium foil is aluminium prepared in thin metal leafs,

    with a thickness less than 0.2 mm / 0.008 in, although

    much thinner gauges down to 0.006 mm are commonly

    used. Foils are commonly gauged in Mils. The foil is

    extremely pliable, and can be bent or wrapped around

    objects with ease. However, thin foils are fragile and

    easily damaged, and are often laminated to other

    materials such as plastics or paper to make them more

    useful. It replaced tin foil in the mid 20th century.

    Annual production of aluminium foil was approximately

    800,000 tonnes in Europe and 600,000 tonnes (1.3 billion lbs) in the USA in 2003. Approximately

    75% of aluminium foil is used for packaging of foods, cosmetics, and chemical products, and 25%

    used for industrial applications (eg. thermal insulation, cables and electronics).

    Manufacture:

    Aluminium foil is produced by rolling sheet ingots cast

    from molten aluminium, then re-rolling on sheet and foil

    rolling mills to the desired thickness, or by continuously

    casting and cold rolling.

    To maintain a constant thickness in aluminium foil

    production, beta radiation is passed through the foil to a

    sensor the other side. The continuous casting method is

    much less energy intensive

    Some lubrication is needed during the rolling stages;

    otherwise the foil surface can become marked with a

    herringbone pattern. These lubricants are sprayed on the

    foil surface before passing through the mill rolls. Kerosene

    based lubricants are commonly used.

    Aluminium becomes work hardened during the cold rolling process and is annealed for most

    purposes. The rolls of foil are heated until the degree of softness is reached, which may be up to

    340C for 12 hours. During this heating, the lubricating oils are burned off leaving a dry surface.

    Lubricant oils may not be completely burnt off for hard temper rolls, which can make subsequent

    coating or printing more difficult.

    EARTH RAW MATERIAL PROCESS END PRODUCT

    Alumina ALUMINIUM

    FOIL

    LDP

    PVDF

    DOUBLE PE FILM

    Sandwiching of

    Aluminium

    Product testing

    Pre-fabrication

    Installation

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    Properties :

    Aluminium foils thicker than 0.025 mm (0.001 in) are impermeable to oxygen and water. Foils

    thinner than this become slightly permeable due to minute pinholes caused by the production

    process.

    Aluminium foil has a shiny side and a matte side. The reflectivity of bright aluminium foil is

    88% while dull embossed foil is about 80%.

    World production trend of aluminium: output in 2005

    In 2005, the People's Republic of China was the top producer of aluminium with almost a one-

    fifth world share, followed by Russia, Canada, and the USA, reports the British Geological Survey.

    Euro Source :

    Aluminium foil is outsourced from China.

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    Low Density Polyethylene:

    Low-density polyethylene (LDPE) is a thermoplastic made from petroleum. LDPE is commonly

    recycled, and has the number "4" as its recycling symbol.

    Properties:

    LDPE is defined by a density range of 0.910 - 0.940 g/cm.

    It is unreactive at room temperatures, except by strong oxidizing agents, and some solvents

    cause swelling.

    It can withstand temperatures of 80 C continuously and 95 C for a short time. Made in

    translucent or opaque variations, it is quite flexible, and tough but breakable.

    LDPE has more branching (on about 2% of the carbon atoms) than HDPE, its tensile strength is

    lower, and its resilience is higher.

    Its density is lower.

    LDPE contains the chemical elements carbon and hydrogen.

    Chemical resistance:

    Excellent resistance (no attack) to dilute and concentrated acids, alcohols, bases and esters

    Good resistance (minor attack) to aldehydes, ketones and vegetable oils

    Limited resistance (moderate attack suitable for short-term use only) to aliphatic and aromatic

    hydrocarbons, mineral oils, and oxidizing agents

    Poor resistance, and not recommended for use with Halogenated hydrocarbons.

    Euro Source :

    LDPE sourced from a local company.

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    PVDF:

    Polyvinylidene Fluoride or PVDF is a highly non-reactive and pure

    thermoplastic fluoropolymer.

    Processing:

    PVDF may be synthesized from the gaseous VDF monomer via a

    free radical (or controlled radical) polymerization process.

    This may be followed by processes such as melt casting, or

    processing from a solution (e.g. solution casting, spin coating, and

    film casting).

    A quantitative defluorination process was described by mechanochemistry (Zhang , 2001), for

    safe eco-friendly PVDF waste processing.

    KYNAR 500 PVDF:

    Kynar 500 is a premier finish for colorful metal buildings. Originally specified by many architects

    for long life finishing on metal curtain walls for tall buildings and large industrial parks, Kynar 500

    has grown in use for painted aluminum extrusions such as windows and storefronts.

    KYNAR 500 paint haS extremely good gloss and color retention, and they have been used on

    many prominent buildings around the world, e.g. the Petronas Towers in Malaysia and Taipei 101

    in Taiwan, as well as on commercial and residential metal roofing.

    Euro Source :

    PVDF sourced from a local company.

    Double PE protective film:

    Polyethylene film is a resinous material with thermoplastic

    properties that is synthesized by inducing oxidative

    polymerization of ethylene gas.

    While the polyethylene is still supple, the tube is closed off at

    one end and then blown to inflate and stretch the film into the

    desired length and thickness.

    The thickness of polyethylene film can be as thin as .0004 inch (10.16 microns).

    Polyethylene or polythene (IUPAC name polyethene or poly(methylene)) is the most widely

    used plastic, with an annual production of approximately 80 million metric tons.

    Properties:

    Polyethylene film has ability to self-seal under controlled heat.

    Polyethylene sheets can be sewn or stapled together, or even bonded with glue.

    This material also helps to prevent the escape of moisture and heat.

    Euro Source :

    Double PE is sourced from DU PONT.

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    1. Sandwiching of Panel:

    The raw materials used in

    EUROBOND APS production are

    Aluminium sheet (0.50mm,

    0.30mm, 0.25mm & 0.21mm) of

    thickness in the form of coils, Low

    density Polyethylene & special

    adhesive in the roll form.

    The melted thermoplastic is

    blended with special adhesive &

    passes between the two

    aluminium foils.

    With qualified high molecular film,

    proper technology & strict quality

    control, composite panel is

    produced.

    The three parts (two aluminium

    sheets & adhesive along with

    polyethylene) are highly

    compressed within the rolls

    resulting in panel sheet.

    EARTH RAW MATERIAL PROCESS END PRODUCT

    Alumina Aluminium Foil

    LDP

    PVDF

    Double PE film

    SANDWICHING

    OF

    ALUMINIUM

    PRODUCT

    TESTING

    PRE-

    FABRICATION

    Installation

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    2. Product testing (@ Jammu plant):

    The test includes :

    180 peeling strength

    Dynamic character of raw materials by electronic universal tester,

    Colour difference,

    Boiling water resistance,

    finish coating thickness,

    Impact resistance,

    Gloss test,

    Adhesion test,

    Peel off Strength,

    Pencil hardness etc.

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    3. Pre fabrication:

    The process of designing is mainly subjected to geometrical sizes of building & local wind load

    etc. to calculate the parameters of the geometrical size of the single panel the density of the

    reinforcement & the span of the column.

    Ordinary Aluminium processing & wood working machines and tools can be used for fabrication

    of the panel.

    o Saw cutting: Usually vertical saws, of good quality

    are being used. Even portable circular saws equipped

    with a system of guides can be used, so as to ensure

    straight-line cuttings.

    o Shearing: Shear cutting can also be used for sizing a large

    quantity of panels. Some shear drop may be observed at

    the cut edge.

    o Grooving:

    Hand operated router machine: These tools are consisted of

    routers that are available in the market and are used for wood

    processing. If they are equipped with special routing bits-carbide

    tipped cutter the hand operated router can be used for a limited

    number of processes. In this case the stability of the tool and the

    guide - system considerably affect the quality of the routing.

    Circular routing blades & router bits: Details of various types of

    circular blades & router bits are shown in the figure. The supplier

    of vertical panel saw offer special circular blades for the routing process of composite

    aluminium panels.

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    o Bending: Grooved panels can be bent with jig. Press brake or

    plate punch.

    o Bending with brake press: While bending the panel with press

    brake, use of top die having desired radius

    o Bending with 3 Roller bender: Eurobond panels are bent in 3 roller bending machine for large size bending radius.

    o Fastening / Riveting & Bolting: Eurobond panels can be faster together or joined to aluminium extruded elements with rivets which are quite common to aluminium construction

    works.

    o Welding: Eurobond panel edges can be joined by welding the core with the help of hot jet gun.

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    EARTH RAW MATERIAL PROCESS END PRODUCT

    Alumina Aluminium Foil

    LDP

    PVDF

    Double PE film

    Sandwiching of

    Aluminium

    Product testing

    Pre-fabrication

    INSTALLATION

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    PROPERTIES OF ACP SHEET

    Panel thickness Units 3mm 4mm 6mm

    Panel Dimensions

    Alumnium

    thickness

    mm 0.25 0.50 0.50

    EUROBOND

    weight

    Kg/m2 3.8 5.6 7.4

    Max. standard

    width

    mm 1220, 1550

    Standard Length mm 2440, 3050, 3660

    Panel Dimensions Tolerances

    Panel Thickness mm + 0.20

    Panel width mm + 2.0

    Panel length mm + 4.2

    + 3.0

    Mechanical characteristics of Aluminum

    Tensile strength

    tolerances (Rm)

    N/mm2 145

    Yield strength

    (Rp0.2)

    N/mm2 120

    Elongation (AS) % 5%

    Modulus of

    elasticity

    N/mm2 70000

    Rigidity KNm 0.11 0.25 0.60

    Alloy Al.1100 H18

    Surface paint characteristics

    Visible surface

    layers

    3 layers & 2 layers PVDF 70% KYNAR - 500

    Temperature behaviour

    Behavior in

    temperatures

    From -50 C to + 80 C

    Thermal

    expansion

    1.4mm per liner meter for temperature difference of 60 C

    Thermal Insulation

    Thermal

    insulation of LDP

    W/m2K 0.29

    Sound Insulation

    Average

    airborne

    Db 24 25 26

    Panel thickness Units 3mm 4mm 6mm

    Visible surface protection

    Surface covered with self adhesive

    film, for protection against damage

    from handling and placing of the

    material

    Film thickness of 80 microns, film to be removed within

    45 days after installation

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    ENERGY CONSUMPTION CALCULATIONS

    Primary energy:

    204 MJ/KG

    103 MJ/KG

    90.4 MH/KG

    85.9 MJ/KG

    1.92 MJ/KG

    0.018MJ/KG

    20.1MJ/KG (RE-CYCLED) ALUMINUM FOIL

    LDPE

    PVDF

    DOUBLE PE FILM

    ACP SHEET

    PRE - FABRICATION

    0.002MJ/KG INSTALLATION

    TOTAL PRIMARY ENERGY = 485.24 MJ/KG

    TOTAL PRIMARY ENERGY(re-cycled aluminium)

    = 301.34 MJ/KG

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    TOTAL EMBODIED ENERGY = PRIMARY + TRANSPORTATION

    580.863 MJ/KG

    TOTAL EMBODIED ENERGY = PRIMARY + TRANSPORTATION

    396.963 MJ/KG

    Transportation energy:

    89.88 MJ/KG

    ANDHERI MALAD

    DEPOT PRE -

    FAB

    MALAD SITE

    PRE -

    FAB

    INSTALL

    JAMMU MUMBAI

    ACP

    SHEET

    DEPOT

    5.65 MJ/KG

    0.022 MJ/KG

    0.071 MJ/KG

    3210km

    CHINA JAMMU

    AL FOIL PLANT

    1982 km

    8 km

    25 km

    TOTAL TRANSPORTATION ENERGY = 95.623 MJ/KG

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    MALAD SITE 2500 Rs/Truck

    LABOUR

    Assuming installation of ACP sheet for a building of 30,000sq.ft.

    Labour required for fabrication : 6nos.

    Labour required for fixing : 4nos.

    4 x 4 ft panel installation would take : 30 mins.

    COST

    Transportation Cost:

    Market Cost: (After Pre Fabrication)

    4mm(0.50mm) 200 to 250 per sq. ft.

    Labour Cost:

    450 Rs. /day

    4000 Rs/MT

    ANDHERI MALAD

    JAMMU MUMBAI 33,000 Rs/Truck

    1000 Rs/Truck

    CHINA JAMMU

  • Efficient Building Materials LCA

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    APPLICATIONS

    Externally ACP is used as a cladding material.

    1. Exteriors of Multi storey apartment

    2. Curtain wall

    3. Industrial & commercial construction

    4. Wall cladding

    5. Fascias & Soffit

    6. Canopies

    7. Elevators

    8. Sign boards

    9. Kitchen units

    10. Display unit

    11. Shop fronts

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    MAINTENANCE

    Routine cleaning of the APS surface is recommended. It may be washed with solution of water

    & detergent, followed by clean water rinse.

    The frequency with which the cleaning is to be carried out and the choice ofsuitable

    cleaning agent depends largely on the position of the building being cleaned and

    degree of contamination.

    The cleaning procedure involves the following steps:

    o Machine cleaning

    o Pre cleaning

    o Soil removal

    o Clean detergent & solutions

    o Operation sequence

    o Coating protection

    o Scratch prevention

    Frequency of washing for various building types:

    Rural area : 1-2 times/ year

    Urban area : 2-3 times/ year

    Low rainfall/coastal area : 3-4 times/ year

    Heavy industrialized area : 6-8 times/ year

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    ENVIRONMENTAL IMPACT

    ACP sheet is a composite material which is made up of high embodied raw materials.

    Waste produced during manufacturing process is approximately 10% of the material

    produced. The waste produced is sent to Landfill sites or Incinerated.

    The Double Polyethylene film is to be removed after application, recycling the same involves

    high energy & is difficult to re-cycle.

    The energy spent on importing & transportation of the material is 16% approx. of the total

    embodied energy.

    Transportation cost is very high due to import of raw material from China.

    Material is manufactured & pre-fabricated in an enclosed, supervised environment. No

    harmful gases are produced during the manufacturing process.

    Economic considerations:

    o The high cost of Aluminum making process because of the huge amounts of electricity it

    uses.

    o The end product cost is very high.

    The individual raw material production has a huge impact on the environment:

    o Environmental problems in mining and transporting the bauxite:

    Loss of landscape due to mining, processing & transporting the bauxite.

    Noise, water & air pollution involved in the operation.

    Disposal of red mud into unsightly lagoons.

    Transport of the finished aluminium.

    The life of the material is approx 12 20 yrs. As compared to almost lifetime of a

    conventional material used building.

    The building would require a lot of maintainance energy, as given in the section above,

    resulting in wastage of water.

    The main problems with aluminium are the very high energy costs when using virgin material,

    and the unnecessary use of polyester powder coatings to colour the sheets.

    Once the life of the building is over, the panels cannot be recycled due to its composite

    nature, where it becomes difficult to separate each raw material. Separation of the material

    is a high energy involved process, even then the energy only 10 15% of the material can be

    recycled & reused, and the energy involved is high.

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    MODES OF REDUCING IMPACT

    Use of Re-cycled Aluminum:

    o Saving of raw materials and particularly electrical energy by not having to extract the

    aluminium from the bauxite. Recycling aluminium uses only about 5% of the energy used

    to extract it from bauxite.

    o Avoiding the environmental problems in the extraction of aluminium from the bauxite.

    Transportation of raw material from long distances to be controlled or avoided completely.

    Centrally located plants, to minimize transportation energy & cost

    Use of bio- degradable plastic: Biodegradable plastics are plastics that will decompose in natural aerobic (composting) and anaerobic (landfill) environments. Biodegradation of

    plastics can be achieved by enabling microorganisms in the environment to metabolize the

    molecular structure of plastic films to produce an inert humus-like material that is less

    harmful to the environment.

    o Bio-derived polyethylene

    The basic building block (monomer) of polyethylene is ethylene. This is just one small

    chemical step from ethanol, which can be produced by fermentation of agricultural

    feedstocks such as sugar cane or corn. Bio-derived polyethylene is chemically and

    physically identical to traditional polyethylene - it does not biodegrade but can be

    recycled. It can also considerably reduce greenhouse gas emissions. Brazilian chemicals

    group Braskem claims that using its route from sugar cane ethanol to produce one

    tonne of polyethylene captures (removes from the environment) 2.5 tonnes of carbon

    dioxide while the traditional petrochemical route results in emissions of close to 3.5

    tonnes.

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    ALTERNATIVE MATERIAL

    Though building faade design should be such that an external cladding application is not

    required. Even if required Clay tile cladding could be adopted.

    Clay tiles are manufactured from kaolinite clay with various additives. The minerals are vitrified

    to bind the tiles at a high firing temperature in excess of 1100C, the higher the temperature the

    longer the life of the tile. The high temperatures involved lead to a high embodied energy.

    Though the embodied energy is high,toxicity issues involved in the manufacture of clay tiles is

    less.

    The embodied energy of a single clay tile = 5-15MJ/KG

    Clay tile faade:

    Alupro Building systems

    Moeding Clay tile faade

    (Ventilated Clay Tile Cladding

    based on the rain screen

    principle.)

    The Concept of Rain screen:

    Rain screen system

    The Rain Screen Principle is based on fundamental laws of physics

    Resists water penetration not by sealing joints, but by

    eliminating pressure differentials > Pressure equalization

    Back ventilation

    Heat-insulation fitted on the outside of the building

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    Various clay tile sections:

    Characteristics:

    Based on the excellent material properties of clay the faade comes with additional advantages

    of a natural material.

    Natural Clay with good insulation properties.

    Wide Variety of colours & finishes.

    Effective water drainage, base channel and weather protection of rear wall.

    A single tile could be replaced separately.

    High resistance with uniform weathering. Non-fading, anti fungal properties, UV resistant.

    Remarkable reduced heat losses.

    Effective weather protection and drainage of moister.

    High resistance against aggressive environmental effects of any nature.

    Uniform but natural weathering.

    Long life and high cost-effectiveness.

    Resistant to frost, UV, fire and salt-water. Non-fading colours.

    Noise insulation.

    Fully recyclable.

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    Technology of Clay tile faade:

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    Bibliography:

    1. Information from Eurobond catalogue

    2. http://eurobondindia.com

    3. http://en.wikipedia.org/wiki/Aluminium_composite_panel

    4. http://en.wikipedia.org/wiki/Aluminium_foil#Manufacture

    5. http://en.wikipedia.org/wiki/Aluminium#Production_and_refinement

    6. http://en.wikipedia.org/wiki/Low-density_polyethylene

    7. http://www.gganeshan.com/picture/PE_LDPE_Process.jpg

    8. http://www.symonite.co.nz/alucomat_xsec.jpg

    9. http://www.alustrong.com/wall.jpg

    10. http://en.wikipedia.org/wiki/Kynar

    11. http://www.arkema-inc.com/kynar/page.cfm?pag=979

    12. http://www.wisegeek.com/what-is-polyethylene-film.htm

    13. http://en.wikipedia.org/wiki/Container_ship#Specifications

    14. http://www.aluproindia.com/s-moeding.htm

    15. http://www.archdaily.com/32778/nbk-terracotta-facade-panels-hunter-douglas-contract/

    16. Embodied Energy in Buildings by Prof. B. V. Venkatarama Reddy Department of Civil

    EngineeringIndian Institute of Science, Bangalore

    17. http://www.greenbuildingpress.co.uk/archive/sustainable_roofing.php

    18. http://en.wikipedia.org/wiki/Bioplastic

    19. http://www.chemguide.co.uk/inorganic/extraction/aluminium.html