57
University of Miskolc Faculty of Earth Science and Engineering Petroleum and Natural Gas Institute Analysis of Heavy Oil in a Two Phase-Flow Thesis Authors name: Omunakwe Emmanuel Buduka, petroleum engineering MSc student Department supervisor: László Kis, assistant lecturer Miskolc 2016

Analysis of Heavy Oil in a Two Phase-Flow

  • Upload
    others

  • View
    2

  • Download
    0

Embed Size (px)

Citation preview

Page 1: Analysis of Heavy Oil in a Two Phase-Flow

University of Miskolc

Faculty of Earth Science and Engineering

Petroleum and Natural Gas Institute

Analysis of Heavy Oil in a Two Phase-Flow

Thesis

Author’s name: Omunakwe Emmanuel Buduka,

petroleum engineering MSc student

Department supervisor: László Kis, assistant lecturer

Miskolc 2016

Page 2: Analysis of Heavy Oil in a Two Phase-Flow

MISKOLCI EGYETEM

Műszaki Földtudományi Kar

KŐOLAJ ÉS FÖLDGÁZ INTÉZET

UNIVERSITY OF MISKOLC

Faculty of Earth Science & Engineering

PETROLEUM AND NATURAL GAS INSTITUTE ——————————————————————————————————————————————————————————————————————————————————————————

: H-3515 Miskolc-Egyetemváros, Hungary : (36) (46) 565-078 FAX: (36) (46) 565-077

e-mail: [email protected]

Diploma Thesis

Project Assignment

for

Omunakwe Emmanuel Buduka

Preliminary Title of Thesis:

Analysis of Heavy Oil in a Two Phase-Flow

Contents:

Review the literature regarding the two-phase flow pressure drop calculations.

Introduce the empirical methods for horizontal transportation.

Analyze the effect of temperature changes on pressure loss along the flowline during

multiphase flow of high-viscosity crude.

Investigate the effect of parameters affecting pressure drop.

Give recommendations for the supposed transporting scenarios.

Faculty Advisor: László Kis, assistant lecturer

Deadline of submission: 9 May 2016.

Zoltán Turzó, PhD

Head of Institute

Miskolc, 01 June 2015.

Page 3: Analysis of Heavy Oil in a Two Phase-Flow

Proof Sheet for thesis submission for MSc students

Name of student: Omunakwe Emmanuel Buduka Neptune code: KK0Y36

Degree program: Petroleum Engineering

Department supervisor: László Kis Institute: University of Miskolc

Title of Thesis: Analysis of Heavy Oil in a two Phase-Flow

1. Statement of the degree program leader:

Thesis assignment was delivered to the student.

9 May 2016 Signature of the program leader

2. Statement of the Department supervisor about the kick-off meeting:

The student have completed the introductory presentation

9 May 2016 Signature of Department Advisor

3. Statement of the Department supervisor about the submission of the first draft

The student have submitted the first draft of the Thesis work

9 May 2016 Signature of Department Advisor

4. Statement of the Department supervisor about the submission of the final version

The student have submitted the final version of the Thesis work

Undersigned agree/ do not agree to the submission of this Thesis.4

9 May 2016 Signature of Department supervisor

5. The thesis (two copies + electronic version on CD) has been submitted

9 May 2016 Administrator of Institute

___________________________

4 Thesis can be submitted regardless of the consultant's consent

Proof Sheet for thesis submission

Page 4: Analysis of Heavy Oil in a Two Phase-Flow

for Petroleum Engineering MSc students

Name of student: Omunakwe Emmanuel Buduka

Neptune code: KK0Y36

Title of Thesis: Analysis of Heavy Oil in a two Phase-Flow

Declaration of Originality

I hereby certify that I am the sole author of this thesis and that no part of this thesis has been

published or submitted for publication.

I certify that, to the best of my knowledge, my thesis does not infringe upon anyone’s

copyright nor violate any proprietary rights and that any ideas, techniques, quotations, or any

other material from the work of other people included in my thesis, published or otherwise,

are fully acknowledged in accordance with standard referencing practices.

9 May 2016

Signature of the student

Statement of the Department Advisor1

Undersigned agree/ do not agree to the submission of this Thesis.

9 May 2016

Signature of

Department Advisor

The thesis has been submitted:

Date 9 May 2016.

Administrator of

Petroleum and Natural Gas Institute

1 Thesis can be submitted regardless of the consultant’s consent.

Page 5: Analysis of Heavy Oil in a Two Phase-Flow

i

Table of Contents 1 Introduction ................................................................................................................ 1

1.1 Background Theories .......................................................................................... 2

2 Literature Review ....................................................................................................... 3

2.1 Challenges of heavy Oil ...................................................................................... 3

2.2 Effects of high viscosity on pipeline design........................................................ 3

2.3 Methods of transporting heavy oil ...................................................................... 4

2.3.1 Heating: ........................................................................................................ 4

2.3.2 Dilution ........................................................................................................ 7

2.3.3 Oil in water Emulsion .................................................................................. 9

2.3.4 Core-annular flow ...................................................................................... 10

2.3.5 Partial upgrading ........................................................................................ 10

2.4 Choice of Method .............................................................................................. 10

2.5 Importance of two-phase flow........................................................................... 11

2.6 Basic Principles of two-phase flow ................................................................... 12

2.7 Flow Patterns ..................................................................................................... 13

2.7.1 Bubble flow ................................................................................................ 13

2.7.2 Dispersed Bubble flow ............................................................................... 14

2.7.3 Slug Flow ................................................................................................... 14

2.6.4 Transition (churn) flow .................................................................................. 15

2.8 Flow Maps ......................................................................................................... 16

2.9 Superficial Velocity........................................................................................... 18

2.10 Gas Slippage .................................................................................................. 19

2.11 Liquid Holdup ............................................................................................... 20

2.12 Mixture Properties ......................................................................................... 21

2.13 Multiphase flow ............................................................................................. 23

2.14 Pressure Gradient Equations .......................................................................... 24

3 Empirical correlations for pressure drop calculations .............................................. 26

3.1 Beggs-Brill ........................................................................................................ 26

3.1.1 The flow patterns ....................................................................................... 27

3.2 Mukherjee-Brill ................................................................................................. 28

Page 6: Analysis of Heavy Oil in a Two Phase-Flow

3.2.1 Phase Slippage and liquid holdup .............................................................. 28

3.2.2 Development of liquid holdup calculation ................................................. 29

3.2.3 Effects of Inclination and Viscosity ........................................................... 29

3.3 Fancher Brown .................................................................................................. 30

3.3.1 Methods of Predicting Pressure Gradient .................................................. 30

4 Investigation of a transportation problem ................................................................. 32

4.1 Statement of problem ........................................................................................ 32

4.1.1 Fluid Pvt Data ............................................................................................ 32

4.1.2 Pipeline Data .............................................................................................. 33

4.1.3 Measured viscosities .................................................................................. 33

4.1.4 Measured Density ...................................................................................... 34

4.1.5 Calculated density ...................................................................................... 34

4.2 Calculation and Results ..................................................................................... 34

4.2.1 Effect of the used empirical method .......................................................... 35

4.2.2 The Effect of condensate concentration on the pressure ........................... 38

4.2.3 The effect of diameter on the pressure ....................................................... 41

4.2.4 Calculation summary ................................................................................. 43

4.2.5 The effects of economic evaluation ........................................................... 44

5 Conclusion and Recommendations .......................................................................... 46

6 References ................................................................................................................ 48

7 Acknowledgment ...................................................................................................... 49

8 Appendices ............................................................................................................... 50

Page 7: Analysis of Heavy Oil in a Two Phase-Flow

1

1 Introduction

The most economic means of transporting petroleum and natural gas ever since its

discovery in 1851 is by pressure pipelines. Transporting heavy oil tends to be highly

challenging due to the high viscosity effects which results to pressure drop along the

pipeline.

Several transportation methods of these crude is discussed such as the heating, dilution, oil

and water emulsion, core annular flow and partial upgrading, which is the most recent

method mentioned above. The flow patterns, importance of multiphase flow and empirical

correlations were also discussed in order to achieve the aim, which is investigating the

pressure drop along a given horizontal pipeline of 2000m. Also the viscosity and density

data used were measured and calculated.

However, the empirical correlations chosen were based on horizontal flow, investigating

the effects of condensate concentrations, pipe diameters and the base oil on how they

affects the pressure drop. Calculations were made using the using different correlations

such as the Beggs-Brill, Fancher-Brown and Mukherjee-Brill. The results were analysed

based on the chosen pipe diameter, condensate concentration and the base oil on different

situations. A comparison was also made between different pipe sizes and condensate

concentration in order to investigate the results and evaluate the economic cost involved in

implementing such design.

Therefore a conclusion was made based on the best results gotten from different pipe

diameters, condensate concentrations and the base oil, for the pipe design, the flow and

generally the aim which is the pressure drop. A solution to the transportation problem was

also made and possible means of encountering such cases in the near future.

Page 8: Analysis of Heavy Oil in a Two Phase-Flow

2

1.1 Background Theories

Heavy oil transportation has existed in western Canada for a number of years because

Substantial reserves of proven oil have been restricted to local requirement, due to the

challenges involved

The steady-state simultaneous flow of petroleum liquids and gases in wells and surface

pipes is a common occurrence in the petroleum industry. However, oil wells produce

normally a mixture of liquids and gases to the surface while phase conditions usually

change along the flow path. Also, this results in the case of higher pressures, where at the

bottom of the well, the flow maybe single but with continuous production which leads to

pressure decrease, causing dissolved gases to evolved from the flowing liquid resulting to a

multiphase flow.

In some cases, both oil and gas wells can be vertical, inclined and also contain larger

horizontal sections. The importance of a proper description of flow behaviour in oil wells

cannot be overemphasized because the greatest challenge is the pressure drop in the well

and the most decisive part of the total production system. It therefore considers the

boundary of the drainage area, formation fluids first flow in the porous media surrounding

the well and wellbore.

The multiphase flow system is not just restricted to the above cases, but it’s also applied in

artificial lifting methods where a mixture of phases presents in the well tubing. Such as

Gas lifting where the injection of high pressure gas into the well at a specific depth, to a

multiphase system2.

The calculation of the pressure drop and analysis of the pressure traverse helps the

production engineer in the description of the multiphase flow phenomena for producing oil

and gas wells, is off great importance for the design and optimization problem in the

petroleum industry.

Page 9: Analysis of Heavy Oil in a Two Phase-Flow

3

2 Literature Review

2.1 Challenges of heavy Oil

The challenges or difficulties encountered in the transportation of heavy oil can be

summarized in one word as viscosity. Viscosity can be defined as a measure of a fluid

resistance to flow. It describes the internal friction of a moving fluid. Its unit is the

centipoise (cP). It also has the following characteristics:

Viscosity generally increases as API gravity increases.

The viscosity of these crudes is very much greater than that of light crudes such

as (the Western Canada crude which is greater than the Alberta light crude).

In the range of flowing temperature which can be expected in a pipeline, small

difference in temperature has a major effect on viscosity4.

Also, it is said to be that from various researches carried out and literatures that these crude

have a very high pour point of about 20 °C. They are generally thixotropic, which means

their flow behaviour is time dependent.

2.2 Effects of high viscosity on pipeline design

In the most economic size of pipe design, the flow tends to be generally a

laminar rather than turbulent, because in the laminar flow pressure drop for a

given pumping rate is directly proportional to viscosity.

High pressure per mile will be encountered resulting in fairly close pump station

spacing.

In case where high viscosity oil rate is too high, to get an economic efficiency or

reasonable efficiency from centrifugal pump is limited, hence positive

displacement pumps are required.

If positive displacement pumps are used in a situation where temperature

variation will have an effect on pipeline flow capacity, the additional method is

used in adjusting the pumping rates1.

However, it’s important that we understand that these effects concerning the transportation

of heavy oils exist in almost all parts of the world which can be overcome. Heavy oil has

been pipelined in several areas such as California since early in the century; also some

extreme viscous oil is moved in pipeline systems in Venezuela and Indonesia. Basically,

Page 10: Analysis of Heavy Oil in a Two Phase-Flow

4

some production from small wells scattered pools like in the case of Canada, these

difficulties are more of economic than technical, because heavy oil can be moved

economically by pipeline than by truck or rail1.

2.3 Methods of transporting heavy oil

The followings are the various ways or schemes by which to reduce the excessive power

consumption in pumping high viscous oil4.

1. Heating

2. Dilution

3. Oil water emulsions

4. Core annular flow

5. Partial field upgrading

2.3.1 Heating:

This method is well known and widely proven in several parts of the world, especially in

Venezuela and United States. The process consists in heating the crude in order to raise its

flowing temperature and hence reduce its viscosity to acceptable limits for transportation1.

Also, it is well known that viscosity decreases rapidly with increasing temperature.

Most heavy oil pipelines are specially designed below 500cP at the pump outlet. The

process of evaluating temperature and pressure profiles of heavy oil flow along pipelines

are always complicated and tedious. Thus, involves the solution of the first law of

thermodynamics (simultaneous solution of the total energy) and the mechanical energy

balance equations, over finite sections along the length of the pipeline1.

However, the heat loss from flowing fluids can be calculated by determining an overall

heat transfer coefficient which depends on the thermal conductivity of the pipe wall, and

the surrounding soil and also the ambient thermal conditions. Temperature and pressure

profiles at several flow rates for a typical heated oil line are shown in the Figure 11. The

cooling of the oil along the direction of flow, and its consequent increase in viscosity,

results in a hydraulic profile which is not a straight line. The curvature of the line is more

pronounced for more viscous material.

Page 11: Analysis of Heavy Oil in a Two Phase-Flow

5

Another characteristic of the heating method is the fact that at a low flow rate, the pumping

pressure has a high value. This is due to the high viscosity effect caused by the rapid

decrease in temperature associated to the low fluid velocity, as shown in the Fig. 21 below.

Figure 1. Profile for typical heated oil line at different flow rates2

Thus, the heating method proves the fact that at a low flow rate the pumping pressure has a

high value. This is due to the high viscosity effect caused by the rapid decrease in

temperature which enables the low fluid velocity shown in Figure 21.

Page 12: Analysis of Heavy Oil in a Two Phase-Flow

6

Figure 2. The effect of flow rate on the pumping pressure for different pipeline

lengths and diameters2

Another important aspect of heating heavy oil is the maximum distance between pumping

stations. This distance heavily depends on the flow rate of the crude oil.

The following are considerations in the design of hot pipeline transporting heavy oil

The heat losses which includes with special focus on insulation thickness

Temperature required to achieve optimum viscosity

The pipeline material used

The number of pumping stations

Coating and insulation type.

Prevention of plugging

Expansion of the pipeline

Start up and shut conditions

It should be noted that a direct fixed heater is generally used to raise the temperature of the

oil and the heaters can be natural gas or fuel oil fired4.

It is also important to know that variation of temperature due to flow rate changes causes a

longitudinal expansion of the pipeline. For above ground lines, expansion is absorbed by

expansion loops, and for buried lines thicker steel is required in order to absorb

longitudinal compression stresses.

Page 13: Analysis of Heavy Oil in a Two Phase-Flow

7

Plugging must be prevented because generally it occurs when the lines are cooled down to

ambient temperature, therefore displacement oil must be used during start up and shut

down operations.

Let make certain assumptions, in order to calculate the temperature at any point along the

pipeline Moreau (1965)

𝑇 = 𝑇𝑔 + (𝑇𝑖 − 𝑇𝑔)𝑒−3.94×𝑈×𝑑𝑜×𝐿

𝑆𝑒𝑄 (1)

Where T = temperature of flowing oil, F

Tg = ground temperature, F

Ti = inlet temperature of oil into the pipeline, F

e = base of natural logs- - dimensionless

U = overall heat transfer coefficient, BTU/h/ft2/F

do= outside diameter of pipe, in

L = distance from inlet, in

Se = specific gravity of oil

c = specific heat of oil, BTU/lb/F

Q = flow rate, bbl/day

It should be noted that the distance that the oil will travel for a given temperature drop is

dependent upon the flow rate. Also to be noted that the above equation is for a stabilized

flowing condition which may take some time to reach or achieve.

2.3.2 Dilution

Dilution is an alternative method of reducing the pressure gradient in a heavy oil line by

blending a less viscous hydrocarbon such as condensate, natural gasoline or naphtha to the

heavy oil to reduce its viscosity. This method has been intensively applied in Canada,

U.S.A. and Venezuela4.

Figure 3. shows the reduction in viscosity that can be obtained by blending condensate

with heavy crude oils because of an exponential relationship between the resulting

viscosity of the mixture and the volume fraction of the diluent. Because of this

relationship, small percentages of diluent have marked effect on the viscosity of the

Page 14: Analysis of Heavy Oil in a Two Phase-Flow

8

mixture and therefore it is evident that there is optimum percentage above which there is

little further reduction4.

Figure 3. Effect of dilution with condensate on crude viscosities of different API

gravity2

However, it is better to actually make test blends in the laboratory and to determine

viscosities experimentally. In such cases, pressure losses may be calculated by using

conventional methods, assuming isothermal one phase flow of a homogenous mixture with

a viscous value.

It’s imperative to note that diluent with similar characteristics to condensate can be

manufactured from any light crude in refineries from fractions normally used to produce

gasoline, Jet fuels and middle distillates. Many light types of crude can also be used

directly as diluent such with API gravity between 35 to 45 degrees1. Although a greater

volume is required to do the same job as condensate, because the cost of the crude is lower

than diluents as there are no manufacturing costs involved, therefore leading to the

requirement of large capacity of pipeline.

.

Page 15: Analysis of Heavy Oil in a Two Phase-Flow

9

2.3.3 Oil in water Emulsion

This method involves a process where a high viscous hydrocarbon is been handled in the

form of an emulsion4. An extra heavy crude or bitumen is suspended in the water (the

external phase) in the form of micro spheres are stabilized with the addition of chemical

additives in order to achieve a reduction in the apparent viscosity of the heavy oil as occurs

in the case of a diluent or heat, therefore helping to reduce the amount of horsepower

required to pump the heavy crude through flow lines.

The design of a programme to apply the emulsion technology must consider the following

aspects:

Selection of the best chemical for the formation of the emulsion

Dispersion mechanism (mixers & homogenizers)

Disintegration of emulsion (breaking)

Rheological & stability characteristics of emulsion.

In selecting the accurate and suitable chemical you ensure that it has the ability to exhibit

the required stability of the emulsion under different conditions. The most relevant

parameter are temperature, hydrocarbon/water ratio, water salinity and pH. Also non-ionic

surfactants are the most effective in producing a more suitable and stable emulsion due to

their ability in producing smaller mean droplet size4, this produces an effect of the volume

of water on the viscosity of the emulsion, whereby viscosity decreases exponentially with

water content. Such reactions are greatly important in selecting the optimum amount of

water to be present in the emulsion.

The rheological behaviour of the emulsion must be assessed in order to predict pressure

losses. According to rheological models developed by states that the behaviour must be

Newtonian for oil content below 65% and for oil content above this value, the emulsion

behaves as a pseudoplastic fluid. As mentioned above that stability is one of the most

important properties of emulsions, since emulsion must possess the ability to withstand

severe handling through power equipment, valves and accessories. Finally, the emulsion

breaking or disintegration process is determined by temperature, water pH, water salinity

and surfactant concentration.

Page 16: Analysis of Heavy Oil in a Two Phase-Flow

10

2.3.4 Core-annular flow

This method is practically based on the flow regime determined by laboratory loop test

analysis and field tests. This mode of transportation method uses a less viscous immiscible

fluid, where water is introduced into the flow to act as a lubricating layer which absorbs

the shear stress existing between the walls of the pipes and the fluid, reducing the

resistance to flow.

However, besides the annular flow pattern, it’s important to note that other flow patterns

can be developed where two immiscible liquids are flowing in a pipe. This technology is

being studied in Venezuela presently by Marven and Intevep, affiliated companies of

Petroleos de Venezuela4.

2.3.5 Partial upgrading

This is also a new concept which consists an infield partial upgrading of the heavy crude

and bitumen, which modifies the crude composition for the purpose of making it less

viscous to be able to be transported, without significantly altering the refining

characteristics. This method have recorded successful results in some part of the world

such as the Resource Technology Associates (RTA), Boulder Colorado, where the

Geotrater process was used which consist of a thermal treatment of the heavy crudes in a

vertical tubular reactor4. The aim is to improve the crude transportability by lowering the

viscosity and pour point and increasing API gravity4.

2.4 Choice of Method

In choosing or selecting the most economical method for the pipeline transportation of

various oils. The choice depends upon many variables such as viscosity of the oil, cost and

availability of diluents and fuel, soil temperatures and conditions, the distance the oil is to

be moved or transported.

For the purpose of this research, the considered method of diluents is used with base oil

and condensate. Measured data were gotten from different percentage of dilution and in

respect to the pipe diameter, length and densities, thereby monitoring the rate of pressure

reduction along the flow path. The determination of the most appropriate method for

Page 17: Analysis of Heavy Oil in a Two Phase-Flow

11

pipeline transportation of heavy oils is dependent upon number of factors, but the most

significant is the economic one, therefore some of the major factors are the followings:

Pipeline length

Climate

Existing facilities

Diluent availability

Water disposal

Electricity supply

Topographical profile

Type of crude oil

Environment

Markets.

For very long pipeline in a cool region or country, dilution or emulsion might be better

choices, as heating might require larger investment in heaters and insulated pipes, because

the emulsions used for long distance can be made to be very stable over long periods of

time. Also some crudes oil is suitable to form very stable emulsions at low surfactant

concentration influencing operating cost.

However, heated pipeline may be feasible in warm parts of the world like Venezuela and

California, as the low horsepower requirement and the use of non-insulated pipes may

minimize the initial investment and operating cost. In a case where there is shortage of

diluents, the heating and dilution methods on the marketing strategy which may also

change or influence the overall economic survey and make or create a platform of some

transportation methods more attractive than others.

2.5 Importance of two-phase flow

This is important for designing gas-liquid transportation systems, which will lead to the

development of empirical correlations which can be used to develop a model and predict

the pressure drop using the given parameters as stated earlier.

Page 18: Analysis of Heavy Oil in a Two Phase-Flow

12

2.6 Basic Principles of two-phase flow

The multiphase flow is more complex than the single-phase flow. Due to the fact that the

sing-phase flow is more defined and most often have analytical solutions developed by

previous research works over the years. In terms of two-phase flow, its greatest problem is

the calculation of the pressure drop along the pipe which requires a careful observation

with high degree of accuracy. Also, predicting the phase conditions becomes more difficult

due to the introduction of the second phase. The following principles are outlined by2, for

the multiphase flow problem

That for any multiphase problem, the number of variables affecting the pressure

drop is enormous. In addition, the thermodynamic parameters for each phase

several variables describing the interaction of two phases (interfacial tension

etc).

The two-phase mixture is compressible that is the density depends on the actual

flowing pressure and temperature, since in most flow problems temperature and

pressure varies in a wide range, the effect must be properly accounted for.

Frictional pressure losses are much more difficult to be described since the it

involves more than one phase, in contact with the pipe wall which leads to

difficulty in multiphase mixture velocity which is more different to that of the

single-phase laminar or turbulent flows, adding to the difficult of pressure drop

prediction.

In addition to the pressure losses, energy loss is also observed which is called

the slippage loss. This happens due to the great difference in densities of the

liquid and the gas phases. In other words, it means that the slippage loss greatly

influences or contributes to the total pressure drop.

Physical phenomena and pressure losses considerably vary with the spatial

arrangement in the pipe of the flowing phases, conventionally called the flow

pattern, enabling different correlations to be used in calculating the pressure

drop which is the vital focus of the work.

It’s important to note that due to the complexity of the two-phase flow, early research by

several scholars, shows there was no evidence or proper documentation of necessary

differential equations which was used to resolve this problem rather a general simple

energy equation was used. This equation allows for a simple treatment of the two-phase

Page 19: Analysis of Heavy Oil in a Two Phase-Flow

13

flow problem and has resulted to numerous models employed for the calculation of the

phases in order to ensure engineering accuracy2. Therefor a suitable empirical correlations

model based on horizontal pipe flow is used to determine the accurate pressure drop on

different situations, depending on the pipe diameters, condensate concentrations and the

base oil.

2.7 Flow Patterns

This is the arrangement by which liquid and gas, flowing together in a pipe taking different

geometrical configuration related to each other. Also, the flow pattern which occurs in

vertical, inclined and horizontal pipes have many common features but there is a basic

difference.

In horizontal flow, which is the purpose and focus of this research, considers the effect of

gravity which is pronounced compared to the other such as vertical flows, leading to the

separation of the gas from the heavier fluid phase and travels to the top (surface) of the

pipe. The following classification of flow patterns are universally accepted as proposed

by2.

Bubble flow

Dispersed bubble flow

Slug flow

Transition (churn) flow

2.7.1 Bubble flow

The bubble flow patterns occurs when the gas flow velocities are at the range of low to

medium, then the gas phase takes the form of distributed discrete bubbles rising in the

continuous liquid phase. Due to their low density, the gas tends to overtake the liquid

particles, leading to the formation of the gas slippage.

In this case, the liquid remains in contact with the pipe wall, which makes the calculation

of the pressure losses simpler.

Page 20: Analysis of Heavy Oil in a Two Phase-Flow

14

Figure 4. Bubble flow Pattern2

2.7.2 Dispersed Bubble flow

In the dispersed bubble flow pattern, assuming the liquid velocity is relatively high why

the gas velocity is low, it means that the resistance of gas phase is small i.e. small bubbles

will be distributed along the continuous liquid phase which has a velocity rate. Thus, this

will result to no formation of slippage because of both phases travels at the same velocity.

It is seen that the multiphase mixture can also behaves like a homogenous phase, therefore

the mixture density can be calculated as є = λ since no formation of slippage occurred from

the liquid holdup2.

2.7.3 Slug Flow

The slug flow patterns helps to eliminate or diminish the continuous liquid phase present in

bubble and dispersed bubble flow patterns, because the liquid slugs and large bubbles

begins to follow each other in succession. Also, the separation of the Taylor bubbles which

contains in the pipe cross-sectional area are done by the liquid slugs occupying the pipe

cross section, containing small amounts of distributed gas bubbles2.

Page 21: Analysis of Heavy Oil in a Two Phase-Flow

15

Figure 5. Slug flow pattern2

2.6.4 Transition (churn) flow

In this case, the shear forces destroy both the Taylor bubbles and liquid slugs which are

formed in the slug flow pattern, due to the high rate of gas present which are greater than

in the liquid slug flow and therefore the phase is not continuous.

Moreso, as the liquid slug’s collapses they are lifted by the smaller Taylor bubbles of

discrete shape. The liquid makes or undergoes an oscillatory motion in constant alternating

directions2. Also when there is an increase in gas rates, transition takes place which

eventually leads to the formation of the annular flow, governed by two mechanisms, the

liquid film stability and bridging. This is due to the fact that at low liquid rates, there will

be an increase in gas velocity which stabilizes the liquid film and annular flow can

develop. Also at higher liquid rates, higher gas velocities are needed to overcome the

bridging of the liquid phase and off course results to the annular flow2.

Page 22: Analysis of Heavy Oil in a Two Phase-Flow

16

Figure 6. Transition (churn) flow pattern2

2.8 Flow Maps

It’s imperative to evaluate the determination of the actual flow pattern, the individual

boundaries of the visually observed flow patterns are usually plotted on so called flow

pattern maps. That is. graphical representations of the ranges of occurrence for each pattern

which is described by different empirical correlations by several researcher, as stated in2,

naming several authors whom were first to propose such map in a vertical flow in oil wells,

by using two dimensional parameter groups given as follows.

𝑁𝑙𝑣 = 1.938𝑣𝑠𝑙 × √𝜌𝑙

𝜎𝑙

4 (2)

𝑁𝑔𝑣 = 𝑣𝑠𝑔 √𝜌𝑙

𝑔𝜎𝑙

4= 1.938𝑣𝑠𝑔 √

𝜌𝑙

𝜎𝑙

4 (3)

The above parameters are called the liquid and gas velocity number, respectively, which

depends on their values according to the2, flow pattern in the figure below.

Page 23: Analysis of Heavy Oil in a Two Phase-Flow

17

Figure 7. Vertical flow pattern map2

From the figure 7 above, it helps to find out the actual flow pattern irrespective of the

condition involved in the phases. Its also recalled that mechanistic models flow map are

the most comprehensive among the flow maps in a two-phase system. Therefore according

to this work, we will be considering the Aziz-Govier-Fogarasi2. flow pattern map.The

contionous efforts of committed and practising engineers and researcher which has led to

the great improvement of the calculation of pressure drop predictions, can therefore be said

that though not all all emperical mthods have successfully cover all aspects but the areas of

flow pattern maps which has contributed in a wide range of accuracy.

He focused on the bubble and slug flow patterns, but its limitation was the flow pattern

prediction.This flow pattern was based on vertical oil wells for the prediction of the

pressure drop in the multiphase system, its also important to know that our focus and aim

lies on the horizontal pipeline, but for reference and in accordance with every research

which is required to include various works done on the same topic by evaluating and

making corrections in order to suit and fit the present research work model to be able to

achieve it puropose, which is to develop a empirical model bys using the Prosper software,

for a horizontal pipeline transporting heavy oil and to know the basic cuases of the

pressure drop along the flow path. Therefore the basic equation for the Aziz-Govier-

Fogarasi, according to2, flow pattern is given below, where the authors used their own flow

Page 24: Analysis of Heavy Oil in a Two Phase-Flow

18

pattern map in the figure. The coordinates axes of the map, in contrary to most other maps,

are dimensioned variables as given below2.

𝑁𝑥 = 𝑣𝑠𝑔 (𝜌𝑔

0.00764)

1/3

[(72

𝜎𝑙) (

𝜌𝑙

62.4)]

1/4

(4)

𝑁𝑦 = 𝑣𝑠𝑙 [(72

𝜎𝑙) (

𝜌𝑙

62.4)]

1/4

(5)

Where 𝜌𝑙 = liquid density, lb/cuft,

𝜌𝑔 = gas density, lb/cuft,

𝑣𝑠𝑙 = liquid superficial velocity, ft/s,

𝑣𝑠𝑔= gas superficial velocity, ft/s,

𝜎𝑙 = interfacial tension, dyne/cm.

2.9 Superficial Velocity

In a two-phase flow, the calculation of the velocities of the gas and the liquid particles it’s

of great challenge because of the irregular motion comparing to that of the single-phase

flow, where its estimation is totally different2. In order to calculate the velocities in the

two-phase flow, we employ a special parameter known as superficial velocity, because it

considers the cross-sectional average velocity in a given pipe transporting a fluid fully

occupied with the given phase. Therefore, to do this it’s based on the in situ rate and the

pipe cross-sectional area as given below2.

𝑣𝑠 =𝑞𝑠𝑐𝐵(𝑃,𝑇)

𝐴𝑃 (6)

Also, considering the rate of production at standard conditions, its vital or important to

know the thermodynamic parameters of the phases involved, at the given temperature and

pressures, while the produced water is seen as negligible, the liquid and gas superficial

velocities can now be written and calculated from the following equations2.

𝑣𝑠𝑙 = 6.5 × 10−5 𝑞𝑜𝑠𝑐𝐵𝑜(𝑃,𝑇)

𝐴𝑃 (7)

Page 25: Analysis of Heavy Oil in a Two Phase-Flow

19

𝑣𝑠𝑔 = 1.16 × 10−5 𝑞𝑜𝑠𝑐[𝐺𝑂𝑅−𝑅𝑠(𝑃,𝑇)]𝐵𝑔(𝑃,𝑇)

𝐴𝑃 (8)

Defining individual parameters

Where 𝑞𝑜𝑠𝑐 = oil flow rate, STB/d

Bo = oil volume factor at pressure and temperature, bbl/STB,

Bg = gas volume factor at pressure and temperature, ft3/scf,

GOR = gas-oil ratio at standard conditions, scf/STB,

Rs = solution gas-oil ratio at pressure and temperature, scf/STB,

Ap = pipe cross sectional area, ft2.

2.10 Gas Slippage

This is the process by which gas overtakes a liquid when they flow together in a vertical or

inclined pipe, due to their different in velocities. It is a basic phenomenon in a two-phase

flow that requires a high standard of understanding. The gas slippage is caused by the

following factors according to2.

The difference in density of gas (light phase) and liquid (dense phase) which

results in force acting on the gas phase leading to an increase in the gas

velocity.

Their energy losses occurring in both phases in the direction of flow which is

less in the gas phase than in the liquid phase. Thus, gas moves faster.

Since pressure decreases in the direction of flow, it therefore means that gas

is incompressible practically, gas expands and takes the shape of the

containing vessel, leading to an increase in its velocity

The above factors facilitate the effects of an increase in gas, relative to that of the liquid

phase. This causes the increase in mixture density, compared to that of the no-slip case,

where the two phase flow at identical velocities. The amount of slippage is governed by so

many factors such as the flow pattern, phase densities, the pipe size, etc.

Finally, the gas slippage is always significant at low liquid rates and diminishes with

increase in liquid rates as frictional pressure drop takes over. This is also describes with the

drift-flux model which, according to2, give the average cross-sectional velocity of the gas

phase in a two-phase mixture as:

Page 26: Analysis of Heavy Oil in a Two Phase-Flow

20

𝑣𝑔 = 𝐶0𝑣𝑚 + 𝑣𝑏 (9)

Where 𝑣𝑔 = gas velocity, ft/s,

𝐶0 = distribution factor, -,

𝑣𝑚 = mixture velocity, ft/s,

𝑣𝑏 = bubble rise velocity, ft/s.

The distribution factor Co reflects the velocity and concentration distribution over the pipe

cross-section and can attain a value between 1.0 and 1.5. Relative to that, it can be said that

mixture velocity is the sum of individual phase’s superficial velocities. The term Vb

represents the terminal rising velocity of a single gas bubble or swarm of bubbles. It can be

calculated according to2. As

𝑣𝑏 = 1.53√𝑔𝜎𝑙(𝜌𝑙−𝜌𝑔)

𝜌2𝑙

4= 0.79√

𝜎𝑙(𝜌𝑙−𝜌𝑔)

𝜌2𝑙

4 (10)

Where 𝜌𝑙 = liquid density, lb/cuft,

𝜌𝑔 = gas density, lb/cuft,

𝜎𝑙 = interfacial tension, dyne/cm.

Also, the slip velocity between the phases can be calculated from the gas liquid phase

velocities as given below;

𝑣𝑠 = 𝑣𝑔 − 𝑣𝑙 (11)

2.11 Liquid Holdup

In a two-phase flow system, the liquid holdup is calculated based on the actual liquid

content of a pipe section from the given flow rates entering the pipe section. This

parameter is known as the no-slip liquid holdup. It is given by equation 12.

𝜆𝑙 =𝑞𝑙(𝑃,𝑇)

𝑞𝑙(𝑃,𝑇)+𝑞𝑔(𝑃,𝑇) =

𝑣𝑠𝑙

𝑣𝑠𝑙+𝑣𝑠𝑔 =

𝑣𝑠𝑙

𝑣𝑚 (12)

Where 𝜆𝑙 is the liquid holdup.

Considering the sum of the liquid and gas volumes which must be equal to the pipe

sections volumes. Therefore, the relationship of the gas and gas void fraction is introduced.

Page 27: Analysis of Heavy Oil in a Two Phase-Flow

21

Now, let’s consider a relatively short pipe section containing a flowing two-phase mixture

as given below.

𝜆𝑙 = 1 − 𝜆𝑙 (13)

Also, if the pipe length is decreased to an infinitesimal dl, its ratio approaches to the cross

sectional liquid contact called liquid holdup and it is denoted by the symbol 𝜀𝑙. This applies

to the gas content and gas void fraction 𝜀𝑔2. Employing both phases with a cross sectional

area denoted by Ap𝜀𝑙 and Ap𝜀𝑔 respectively. The actual velocities can now be written as;

𝑣𝑔 =𝑣𝑠𝑔

𝜀𝑔 𝑎𝑛𝑑 𝑣𝑙 =

𝑣𝑠𝑙

𝜎𝑙 (14)

Therefore the gas void ratio and the liquid holdup is also given as

𝜀𝑔 =𝑣𝑠𝑔

𝐶0𝑣𝑚+𝑣𝑏 (15)

𝜀𝑙 = 1 − 𝜀𝑔 = 1 −𝑣𝑠𝑔

𝐶0𝑣𝑚+𝑣𝑏 (16)

Liquid holdup can also be derived from the definition of the slip velocity by substituting

the equation of the gas and liquid phase velocities into the slip velocity, we get

𝑣𝑠 =𝑣𝑠𝑔

1−𝜀𝑙−

𝑣𝑠𝑙

𝜀𝑙 (17)

Therefore the above equation can be solved for liquid holdup 𝜀𝑙

𝜀𝑙 =𝑣𝑠−𝑣𝑚+√(𝑣𝑚−𝑣𝑠)2+4𝑣𝑠𝑣𝑠𝑙

2𝑣𝑠 (18)

The liquid holdup, calculated from either equation (5) and (7), includes the effect of gas

slippage and must therefore always be greater than or equal to the no-slip liquid holdup, ie

1 ≥ 𝜆𝑙, this indicates the difference in magnitude of the actual gas slippage. The value of

the 𝜀𝑙 gives the proportion of the pipe cross-section occupied by the liquid phase in the

flowing two-phase mixture2. If the liquid holdup is known, the two-phase mixture density

can be easily calculated which is the main purpose of this research.

2.12 Mixture Properties

The mixture properties in a two-phase flow help to evaluate and facilitate the solutions of

the vital and relevant equations, which describes the behaviour of two-phase flows. In this

case, the calculation of the individual parameters is based on the thermodynamics

properties of the fluids such as mixture density and viscosity. Therefore two-phase mixture

Page 28: Analysis of Heavy Oil in a Two Phase-Flow

22

density can understand the densities of the phases and the liquid holdup respectively. The

calculation can be done from the liquid holdup and no-slip mixture density2.

𝜌𝑛𝑠 = 𝜌𝑔𝜆𝑙 + 𝜌𝑔𝜆𝑔 (19)

Or a density including the effect of gas slippage

𝜌𝑚 = 𝜌𝑔𝜀𝑙 + 𝜌𝑔𝜀𝑔 (20)

Also, it important to note that the above equations actually depends on the temperature and

pressure valid at the given pipe section, assuming the water flow rate is zero, and then the

liquid density equals the in situ density of the oil phase. Finally, in order to analyse the

situation, the equation below is considered when the effects of the dissolved gas in the oil

phase is included;

𝜌𝑜 =350.4𝛾𝑜+0.0764𝛾𝑔𝑅𝑠(𝑃,𝑇)

5.61𝐵𝑜(𝑃,𝑇) (21)

The gas density is also determined as shown,

𝜌𝑔 = 2.7𝛾𝑔𝑃

𝑍𝑇𝑎 (22)

Where γo = specific gravity of oil,

γg = specific gravity of gas,

Ta = absolute temperature, R,

Z = gas deviation factor,

Rs = solution gas-oil ratio at pressure and temperature, scf/STB,

Bo = oil volume factor at pressure and temperature, bbl/STB.

Similarly, the calculation of the mixture viscosity is done in the most common way, by

using the no-slip holdup equation2.

𝜇𝑛𝑠 = 𝜇𝑙𝜆𝑙 + 𝜇𝑔𝜆𝑔 (23)

Another frequently applied expression is given as

𝜇𝑚 = 𝜇𝜀𝑙𝑙𝜇𝜀𝑔

𝑔 (24)

Therefore, the viscosity can now be calculated from this equation;

𝜇𝑚 = 𝜇𝑙𝜀𝑙 + 𝜇𝑔𝜀𝑔 (25)

Where: 𝜇𝑙= liquid viscosity at pressure and temperature, cP,

𝜇𝑔= gas viscosity at pressure and temperature, cP.

Page 29: Analysis of Heavy Oil in a Two Phase-Flow

23

2.13 Multiphase flow

It’s said that the most of the pressure drop calculation of a horizontal pipeline models were

developed for two discrete phases, usually liquid and gas, therefore called two-phase flow

methods. Let’s consider a phase where there is pure oil or water but a mixture of oil and

water. We apply the mixing rule in order to evaluate the actual flow rates of the

components. If the flowing is a mixture of oil and water, then the superficial velocities of

the liquid and gas phases are determined by the following equations below2:

𝑣𝑠𝑙 = 6.5 × 10−5 𝑞𝑙𝑠𝑐

𝐴𝑝[𝐵𝑜(𝑃, 𝑇)

1

1+𝑊𝑂𝑅+ 𝐵𝑤(𝑃, 𝑇)

𝑊𝑂𝑅

1+𝑊𝑂𝑅] (26)

𝑣𝑠𝑙 = 1.16 × 10−5 𝑞𝑙𝑠𝑐

𝐴𝑝[𝐺𝐿𝑅 − 𝑅𝑠(𝑃, 𝑇)

1

1+𝑊𝑂𝑅] 𝐵𝑔(𝑃, 𝑇) (27)

Defining the each individual parameter of the above both equations:

Where: 𝑞𝑙𝑠𝑐 = liquid flow rate, STB/d,

𝐵𝑜 = oil volume factor at pressure and temperature, bbl/STB,

𝐵𝑤= water volume factor at pressure and temperature, bbl/STB,

𝐵𝑔 = gas volume factor at pressure and temperature, ft3/scf,

GLR = gas liquid ratio at standard conditions, scf/STB,

𝑅𝑠 = solution gas-ratio at pressure and temperature, scf/STB,

WOR = water-oil ratio at standard conditions, -,

𝐴𝑝 = pipe cross sectional area, ft2.

More so, in a multiphase flow system, the thermodynamic parameters, density and

viscosity of the liquid phases are always found as already explained above in the previous

sections of this literature. This approach has its limitation since oil-water mixtures may

behave very differently from this assumption. But we know that liquid density is always

affected by oil slippage, a phenomenon which has the same properties compare to that of

the gas slippage, where the lighter oil particles overtakes the denser (heavier) water phase.

Due to this fact, it’s said to be that mixture density increases beyond the value calculated

from a mixing rule. The viscosity of oil-water mixture may sometime exhibit non-

Newtonian behaviour, if the emulsion is formed. Its density can be calculated from the

expression below, with regards to the above limitation2.

Page 30: Analysis of Heavy Oil in a Two Phase-Flow

24

𝜌𝐿 = 𝜌𝑂𝑊𝑂𝑅

1+𝑂𝑊𝑅+ 𝜌𝑤

1

1+𝑊𝑂𝑅 (28)

Then the actual density of formation water is found from its specific gravity and volume

factor:

𝜌𝑤 =350.4𝛾𝑤

5.61𝐵𝑤(𝑃,𝑇)=

𝛾𝑤

𝐵𝑤(𝑃,𝑇) (29)

2.14 Pressure Gradient Equations

The pressure gradient equations focus on the most challenge which is the calculation of the

pressure distribution along the pipeline, which is the aim of this research. This is due to the

pipe complexity of the flow phenomena in any of the flow patterns and the existence of

many flow patterns.

However, it is difficult to analyse the differential equations, the conversation of mass and

momentum, because it applies to both phases of the flow. In order to overcome this

challenge, the consideration is that the multiphase flow mixture is treated as a homogenous

fluid and which helps to write up the General Energy (Bernoulli) equation for the particular

hypothetical phase2. This equation helps to describe the conversation of energy between

two points (lying close to each other) in an inclined pipe; this can be solved by the function

of the pressure gradients equations.

Also, different pressure drops empirical correlations models from previous research work

will be investigated, which will be compared and help to derive our model for the

calculation of the pressure drop along the pipeline, with a given parameters such as the

flow rates, length and pipe sizes.

𝑑𝑝

𝑑𝑙=

𝑔

𝑔𝑐𝜌𝑚 sin 𝛼 + (

𝑑𝑝

𝑑𝑙)

𝑓+

𝜌𝑣𝑑𝑣𝑚

𝑔𝑐𝑑𝑙 (30)

Where α = pipe inclination angle, measured from the horizontal, radians

Note that in a vertical pipe α = 90 and sin α =1.0, hence dl = dh, and the above equation

can be rewritten in function of the vertical distance h as

𝑑𝑝

𝑑𝑙=

𝑔

𝑔𝑐𝜌𝑚 + (

𝑑𝑝

𝑑ℎ)

𝑓+

𝜌𝑣𝑑𝑣𝑚

𝑔𝑐𝑑ℎ (31)

Page 31: Analysis of Heavy Oil in a Two Phase-Flow

25

It is clearly seen from the above equations the pressure gradients dp/dl or dp/dh is

composed of three terms describing the different kinds of energy changes occurring in any

pipe. Also, among all the second serves as most focused because, it’s irreversible pressure

losses are due to the fluid friction, which is conveniently expressed with the Darcy-

Weisbach equation helped by the friction factor.

(𝑑𝑝

𝑑𝑙)

𝑓= 𝑓

𝜌2𝑣

2𝑔𝑐 (32)

Where f = friction factor, -,

gc = 32.2 a conversion factor, -,

d = pipe diameter, in.

From equation (32), the friction factor f, is a function of the Reynolds number NRe and the

pipes relative roughness and is usually determined from the moody diagram. Therefore, the

most important component of the pressure gradient is listed according to their relative

importance for an inclined and a vertical pipe, respectively, using the field measurements.

The hydrostatic components represent the change in potential energy in the multiphase

flow due to the gravitational force acting on the mixture. This is usually found from the

mixture density which includes the effect of the slippage. As discussed already, the

mixture density from equation 19, and the frictional components represents the

irreversible pressure losses in the second term from the equations above, occurring in the

pipe due to fluid friction on the pipe inner wall.

Page 32: Analysis of Heavy Oil in a Two Phase-Flow

26

3 Empirical correlations for pressure drop calculations

Empirical two-phase pressure drop correlations were first classified by Orkiszewski a

scientist, who indicated the flow patterns that is, the effective of the differential spatial

arrangements of two phases.

However, several research and consideration have been investigated and also carried out to

finalise the most important empirical correlations needed for the determination of pressure

drop in transportation of heavy oil. Therefore, for the purpose of this work, we should be

considering the following correlations which are in relations with the PROSPER software

used for the calculations:

Beggs-Brill correlation

Fancher Brown correlation

Mukherjee-Brill correlation

3.1 Beggs-Brill

The Beggs-Brill correlation is based on gas-liquid flow in inclined pipes, which he

investigated and determine the erect of pipe inclination angle or liquid holdup and pressure

losses5. He concentrated his correlation for liquid holdup and friction factor in order to

predict pressure gradients for two-phase flow in horizontal pipes at an angle for many flow

pressure gradients for two-phase in pipes at all angles for any conditions.

The begs-brill basic equation is derived and written up with the pipe length, L instead of

vertical depth coordinate because of the pipe is considered to be inclined. Also they took

into account all three components of the multiphase pressure drop; that is the elevation,

friction, and acceleration which can also be the kinetic term5:

𝑑𝑝

𝑑𝑙 =

(𝑑𝑝

𝑑𝑙)

𝑒𝑙+ (

𝑑𝑝

𝑑𝑙)

𝑓

1−𝐸𝑘 (33)

They express the component of the pressure gradients as:

(𝑑𝑝

𝑑𝑙)

𝑒𝑙=

1

144𝜌𝑚 sin 𝛼 =

1

144 [𝜌𝑙𝜀𝑙(𝛼) + 𝜌𝑔(1 − 𝜀𝑙(𝛼))] sin 𝛼 (34)

(𝑑𝑝

𝑑𝑙)

𝑓 = 1.294 × 10−3 𝑓

𝜌𝑛𝑠 𝑉2

𝑚

𝑑 (35)

Page 33: Analysis of Heavy Oil in a Two Phase-Flow

27

Ek = 2.16 × 10−4 𝑣𝑚 𝑣𝑠𝑔𝜌𝑛𝑠

𝑃 (36)

Where: 𝜌𝑚 = mixture density, lb/cu ft,

𝜌𝑛𝑠 = no-slip mixture density, lb/cu ft,

𝜀𝑙(𝛼) = liquid holdup at an inclination angle of 𝛼, -,

𝛼 = pipe inclination angle, measured from the horizontal, rad,

f = friction factor, -,

𝑣𝑚 = mixture superficial velocity, ft/s,

𝑣𝑠𝑔= gas superficial velocity, ft/s,

p = pressure, psi,

d = pipe diameter, in.

3.1.1 The flow patterns

In the Beggs-Brill correlation, flow patterns are determined for horizontal flow only, using

empirically developed flow pattern map. Since this map is valid for horizontal flow only,

actual flow patterns in inclined or vertical cases cannot be predicted2. In this approach,

flow pattern is a correlating parameter only and does not indicate the actual flow pattern.

Therefore, two parameters were used to describe the horizontal flow patterns transitions,

that is, the no-slip liquid holdup 𝜆𝑙, and Froude number 𝑁𝐹𝑟 , which is defined belwo2:

𝜆𝑙 = 𝑣𝑠𝑙

𝑣𝑚 (37)

𝑁𝐹𝑟 =𝑣2

𝑚

𝑔𝑑= 0.373

𝑣2𝑚

𝑑 (38)

Where; 𝑣𝑠𝑙= liquid superficial velocity, ft/s,

𝑣𝑚= mixture superficial velocity, ft/s,

d = pipe diameter, in.

Page 34: Analysis of Heavy Oil in a Two Phase-Flow

28

Figure 8. Flow pattern map of Beggs-Brill5

The Figure 8, above depicts the modified flow pattern map of the Beggs-Brill correlation,

designated for horizontal flow patterns and indicated the different boundaries of the flow

patterns as shown in the map.

3.2 Mukherjee-Brill

This correlation is developed for all pipe inclination angles, where they considered two set

of empirical equations, one each for uphill and downhill flow. Also it’s the first correlation

to consider the change of flow patterns with pipe inclination, using a large experimental

data base, covering the uphill and downhill flow patterns6.

The liquid holdup equation is a function of dimensionless liquid and gas velocity numbers

in addition to liquid viscosity number and angle of inclination. The mentioned parameters

defined the flow pattern transition uniquely in inclined two-phase flow.

3.2.1 Phase Slippage and liquid holdup

In an inclined two-phase pipe flow, a substantial part of the total pressure drop losses

maybe contributed by the hydrostatic pressure difference. The relative contribution of

friction gradient and hydrostatic gradient may be dictated by the prevailing flow patterns,

angle of inclination, and direction of flow6.

Page 35: Analysis of Heavy Oil in a Two Phase-Flow

29

Base on their assumptions that the void fraction is a unique fraction of quality and physical

properties of the fluids. This is probably true where homogenous flow can be assumed or

during bubble flow at very low gas flow rates. Similar situations may also arise where the

phase velocity is very high, so that friction pressure drop governs the total pressure loss.

The concept of slip velocity comes from the physical phenomenon called slippage, which

is used to describe the natural phenomenon of one phase slipping past the other in two-

phase pipe flow. There are several causes for slippage between phases, frictional resistance

to flow or irreversible energy losses in the direction of flow are much less in the gas phase

than in the liquid phase.

3.2.2 Development of liquid holdup calculation

Several liquid holdup measurements at uphill and downhill inclination angles from 0 to ±

90 from horizontal were obtained accordingly6. In correlating this data, at each uphill and

downhill angle void fraction was plotted as a function of superficial gas velocity for fixed

superficial liquid velocity. The basic equation of the Mukherjee-Brill correlation is stated

as6:

𝐻𝑙 = 𝑒𝑥𝑝 [(𝑐1 + 𝑐2 sin 𝜃 + 𝑐3𝑠𝑖𝑛2𝜃 + 𝑐4𝑁2𝑙)

𝑁𝑐𝑠𝑔𝑣

𝑁𝑐6𝑙𝑣

] (39)

Where: 𝐻𝑙 = liquid hold up, -,

C = empirical constant, -,

Ngv = gas velocity number. 𝑣𝑠𝑔 = [𝜌𝑙

(𝑔𝜎)]

0.5

,

g = gravitational acceleration, ft/sec2,

𝑁𝑙 = liquid viscosity number, 𝜇𝑙 = [𝑔

(𝑝𝑙𝜎3)]

0.5

.

3.2.3 Effects of Inclination and Viscosity

The begs-brill correlation focuses basically on the liquid hold up, relating the importance

on the flow which passes through maximum and minimum at fixed inclination angles of

approximately +50 and -50 respectively6. The second degree polynomial function of the

form 𝑐1 + 𝑐2 sin 𝜃 + 𝑐3𝑠𝑖𝑛2𝜃 was selected by plotting liquid holdup for different angles of

inclination at a fixed liquid and gas velocity numbers6. This relation was also confirmed by

comparing results of other equation forms in trial runs of the regression analysis.

Page 36: Analysis of Heavy Oil in a Two Phase-Flow

30

3.3 Fancher Brown

The Fancher Brown correlation was chosen in this work based on the fact that the Prosper

software acknowledges its importance in the vertical flow; therefore it established a

pressure traverse by using a 23/8𝑖𝑛 outside diameter tubing for varying liquid flow rates as

produced with varying gas liquid rate7. It was further intended to establish the reliability of

known methods for calculating pressure traverses.

Another objective of this correlation was to obtain sufficient pressure traverse data to allow

accurate prediction of the pressure traverse in 2in tubing for vary liquid flow rates, and for

any gas-liquid ratio in the range of the test carried out7.

3.3.1 Methods of Predicting Pressure Gradient

The Fancher-Brown used the method of measured data from previous different 49 wells,

34 flowing wells and gas-lift wells to predict the pressure gradients, which they related to

the Poettmann and Carpenter correlation, covering only a limited range of flow rates and

gas liquid ratios. The basic equation was derived from the irreversible energy-loss term,

evaluated by back calculation using the field data to determine the pressure gradients from

the following equation.

𝑓 = 7.413 × 1010𝜌𝑑5 × [𝑑𝑝

𝑑𝐻] − 𝜌𝑣𝑞2 × 𝑚2 (40)

Where f = fanning type friction factor,

𝜌 = Flowing density, lb/ft3

𝑑𝑝

𝑑𝐻= Pressure gradient, Psi/ft,

q = oil flow rate, bbl/day,

d = diameter of pipe, ft.

Page 37: Analysis of Heavy Oil in a Two Phase-Flow

31

1.4737× 10−5 𝑚𝑄/𝐷7

Figure 9. Back calculated friction factor7

The figure above shows that the funning-type friction factor was plotted against the

Reynolds number. Also, that the scattering points in this correlation suggests that an

important parameter was neglected according to the Fancher-Brown correlation7.

Page 38: Analysis of Heavy Oil in a Two Phase-Flow

32

4 Investigation of a transportation problem

The transportation problem was investigated by using the dilution method whereby the

base oil was diluted with a condensate. The effect of the used empirical method, the

condensate concentration and the pipe diameter on the pressure gradients along the pipe

were investigated using the PROSPER software. The best correlation with best fit for the

prediction of the pressure drop will be selected for the subsequent calculations and

investigations for the purpose of this research because of its accuracy in predicting the

pressure gradients for two-phase flow in horizontal pipes.

In addition, series of calculations were done using the PROSPER software in order to

determine the best results whereby different pipe diameters in 3 different situation and

percentage of condensate viscosities and known densities were used, helping to investigate

the behaviour of the pressure gradients along the pipe length with the effects of the

surrounding temperature, thereby making the oil more viscous to flow.

4.1 Statement of problem

A 2000 meter long pipe transporting heavy oil in a horizontal direction and was not

subjected to a flow test.

A PROSPER model is built.

The data was not matched.

An empirical correlation model is chosen to predict the GOR values along the

pipe in respect to the base oil, condensate concentration and an increase in pipe

diameter sizes in order for the reduction of pressure drop.

4.1.1 Fluid Pvt Data

Table 1: The available Pvt Data used in the calculation

Solution GOR 0, 100, 200, 300, 400, 500 scf/stb

Gas Gravity 0.8

Density Table 3.

Viscosity Figure 9.

Water salinity 0

Impurities (CO2, N2, H2S) None

Bubble Point Pressure 2500 psig at 200 °C

Bo 1.214 rb/stb

Page 39: Analysis of Heavy Oil in a Two Phase-Flow

33

4.1.2 Pipeline Data

Table 2: The pipeline data

Parameter Value

Pipeline Length 2000 meter

Pipeline internal diameter 3.548 in, 4.026 in, 4.506 in

Pipeline inside roughness 0.0006 in

Temperature of surroundings 10 °C

Over heat transfer coefficient 7 BTU/h/ft2/F

Total pipe height above origin 0 ft

Fluid inlet temperature 50 °C

4.1.3 Measured viscosities

The measured viscosities of the base and condensate concentration

Figure 10. Measured viscosity values

0.0

0.2

0.4

0.6

0.8

1.0

1.2

1.4

0 10 20 30 40 50 60 70 80

Din

am

ic V

isco

sity

[cP

]

Temperature [°C]

10% concentration

20

30

40

50

66

0

Page 40: Analysis of Heavy Oil in a Two Phase-Flow

34

4.1.4 Measured Density

Table 3: shows the different calculated densities used in the pipe diameters.

Density (kg/m3)

Base 905

10% 889.84

20% 874.68

30% 859.52

40% 844.36

50% 829.2

66% 804.94

4.1.5 Calculated density

Figure 11. Shows the graphical representation of the temperature dependency of the

density

4.2 Calculation and Results

The PROSPER software is used to calculate the following and to estimate the correlation

needed for the pipeline design and determining the pressure gradients:

The effect of the used empirical method.

The Base oil on different pipe diameter sizes.

The effects of the condensate concentration on the pressure drop using three

different concentrations.

The effects of the different pipe diameter sizes on the pressure drop.

The effect of the GOR on the pressure drop.

The effect of economic considerations.

700

750

800

850

900

950

1000

0 20 40 60 80 100

Den

sity

, k

g/m

3

Temperature, ͦͦC

Page 41: Analysis of Heavy Oil in a Two Phase-Flow

35

4.2.1 Effect of the used empirical method

In this case, the used empirical method will be able to predict the best correlation after

investigating their effects on the pressure drop, using base oil with a 3.548in pipe diameter

and a 20% condensate concentration with a 4.026in pipe diameter size.

Case 1.

Figure 12. 0% condensate of 3.548 in pipe diameter of beggs-brill correlation.

The Figure 12. above showed a solution of the Beggs-Brill correlation whereby as the

GOR values increases along the pipeline, the pressure drop is reduced with the effect of the

diameter and surrounding temperature.

Case 2.

The Francher-Brown correlation is shown below in Figure 13, proved to be similar

solutions compared to that of the Beggs-Brill correlation. The GOR values are seen as they

increase along the pipe length with same pipe diameter of 3.548 in, as the pressure drop

reduces.

Page 42: Analysis of Heavy Oil in a Two Phase-Flow

36

Figure 12. 0% condensate of 3.548in pipe diameter of Fancher-Brown correlation.

Also the correlation above showed that the surrounding temperature along the pipe is

increased.

Case 3.

Figure 13. 0% condensate of 3.548 in, pipe diameter of Mukherjee-Brill

correlation.

In this case, the Mukherjee-Brill correlation only showed the solution of the pressure drop

and the surrounding temperature along the pipeline, why the values of the GOR could not

be estimated, and does not give an accurate or similar result compared to the already

discussed correlations above.

Page 43: Analysis of Heavy Oil in a Two Phase-Flow

37

Case1

Figure 14. 20% condensate of 4.026in pipe Beggs-Brill correlation.

As it is clearly seen in the Figure 14 above, the solution from the correlation showed the

same with pressure drop continuously reducing in a similar way compared in the previous

pipe diameter of 3.548in. The GOR values are clearly seen and continue to decrease along

the pipeline effecting the pressure reduction.

Case 2

Figure 15. 20% condensate of 4.026in pipe Fancher-Brown correlation.

The Fancher-Brown correlation also showed a similar solution but with a slight difference

when used with same condensate and pipe diameter as seen in the Beggs-Brill correlation.

The GOR values are also seen clearly.

Case 3

Page 44: Analysis of Heavy Oil in a Two Phase-Flow

38

Figure 16. 20% condensate of Mukherjee-Brill correlation.

The Mukherjee-Brill correlation also showed the same solution as in the previous case of

3.548in pipe diameter even when the condensate concentration is increased, the GOR

values cannot be estimated along the pipe length but predicting only the pressure drop, and

however will not be considered as a good correlation in the subsequent investigations.

Therefore, the Beggs-Brill correlation is chosen to be used for the subsequent calculations

and investigation of the pressure drop because of its accuracy and similar solution to the

Fancher-Brown correlation. Its GOR values solution fits to what is expected in the design

and transportation of the crude.

.

4.2.2 The Effect of condensate concentration on the pressure

The effect of condensate concentration on how they affect the pressure drop along the

pipeline will be investigated by using the following scenario

Base oil with 0% condensate concentration of 3.548in pipe

10% Condensate concentration of 3.548in pipe.

30% condensate concentration of 3.548in pipe.

66% condensate concentration of 3.548in pipe.

Page 45: Analysis of Heavy Oil in a Two Phase-Flow

39

Case 1

Figure 17. 0% condensate concentration of 3.548in pipe.

From Figure 17 and with a zero percent condensate, the outcome of the simulated results

for the pressure drop was higher than that observed for the case of 10% condensate

concentration as indicated in Figure 18 below. Additionally, sensitivity for the effect of an

increase in GOR was done and the results shown in Table 4 below. As can be seen from

Figure 17, an increase in GOR results in a corresponding increase in pressure drop along

the pipeline due to the additional mass of the gas phase. Ultimately, lesser outlet pressures

are obtained when the GOR increases.

Case 2

Figure 18. 10% condensate concentration on 3.548 in pipe.

Page 46: Analysis of Heavy Oil in a Two Phase-Flow

40

Figure 18 indicates that the addition of the condensate concentration to the base oil results

in a decreased pressure drop along the pipeline. Sensitivity for increasing GOR values was

done and Table 5 shows the results from the calculation.

Case 3

Figure 19. 30% condensate concentration of 3.548in pipe

The effect of an increase in concentration is a decrease in density of the oil. This produces

a reduction in pressure required to initiate fluid flow. Figure 19 shows the result of

pressure drop for 30% condensate concentration. In comparison with the previous two

scenarios, much lower pressure drop values were recorded for 30% condensate

concentration and this result in higher outlet pressure even at increasing GOR values.

Case 4

Figure 20. 66% condensate concentration of 3.548in pipe

Page 47: Analysis of Heavy Oil in a Two Phase-Flow

41

With the addition of 66% condensate to the base oil, the pressure drop reduction was

maximal and the changes in pressure drop with increasing GOR cannot be easily

interpreted from the inlet to the outlet. The transportation of this oil will be faster than in

all previous cases. Results of the simulation can be found in Table 8 of the appendix.

4.2.3 The effect of diameter on the pressure

The effect of the diameter on the pressure drop along the pipeline transportation of the

crude is investigated using different pipe diameters sizes and the Base oil in three different

cases, such as:

Base oil with a 3.548in pipe diameter.

Base oil with a 4.026in pipe diameter.

Base oil with a 4.506in pipe diameter.

Case 1

Figure 21. 0% condensate concentration of 3.548in pipe.

The size of the pipe diameter determines and influences the pressure drop such that the

pressure drop decreases with an increase in pipe diameter. However, the reduction of the

pressure from 65bars to 34.54bar for the case of 0 scf/STB GOR, is as a result of high

density of the oil is and it can only be optimized by the addition of the condensate or an

increase in temperature of the surrounding.

Page 48: Analysis of Heavy Oil in a Two Phase-Flow

42

Case 2

Figure 22. 0% condensate concentration of 4.026 in pipe.

In Figure 22 above, as it is clearly seen, the outlet pressure is reduced from 32.5bar to

48.75bar for the 0 scf/STB case. This is as a result of an increase in the pipe diameter, with

same base oil and comparing it to the previous case of 3.548 in size pipe. The values of the

GOR between the first and second are almost the same but with a slight different.

Case 3

Figure 23. 0% condensate concentration of 4.506 in pipe.

Similarly, Figure 23 shows a much reduced pressure drop for a 4.026 in pipe. Outlet

pressure values between 48.75bar to 55.42bar were observed for the range of GOR

investigated. This emphasizes that larger the pipe diameter the smaller the pressure losses.

Page 49: Analysis of Heavy Oil in a Two Phase-Flow

43

4.2.4 Calculation summary

4.2.4.1 Comparison of the pressure drop results between the base and condensate

concentration.

Table 4. The pressure drop difference for the Base oil

Crude

Sample

Pipe Size

(in)

GOR Outlet

Pressure(bar) 𝑑𝑝 = 𝑝𝑖𝑛 − 𝑝𝑜

( bar)

Base Oil (0%

Condensate)

3.548 0 54.7604 7.239

100 53.6203 11.379

200 49.5016 15.498

300 45.568 19.432

400 42.1688 22.831

500 37.6758 27.324

4.026 0 58.8867 6.113

100 58.525 6.47

200 55.8594 9.1406

300 53.625 11.375

400 51.9742 13.0258

500 50.1109 14.889

4.506 0 61.0594 3.940

100 60.891 4.109

200 59.231 5.769

300 57.310 7.769

400 56.7845 8.2155

500 55.7882 9.2118

From Table 4 above it is clear that the pressure drop along the pipe length was influenced

mostly by the pipe diameter. The larger diameter recorded a lower pressure drop compared

to others, and the investigation was done using the base oil.

However, from this we will investigate and record the pressure drop along the pipe length

and see how the condensate and different pipe diameters sizes will affect the reduction of

the pressure drop.

Page 50: Analysis of Heavy Oil in a Two Phase-Flow

44

Table 5. Pressure difference of condensate concentration

Crude Sample Pipe Size

(in)

GOR Outlet

Pressure(bar) 𝑑𝑝 = 𝑝𝑖𝑛 − 𝑝𝑜

( bar)

Condensate

concentration

(10%)

3.548 0 55.4612 9.538

100 54.9313 10.068

200 50.8607 14.139

300 47.5366 17.139

400 44.2358 20.764

500 40.4352 24.564

4.026 0 59.3531 5.646

100 59.1235 5.876

200 56.5912 8.408

300 54.8122 10.187

400 53.0959 11.904

500 51.3495 13.6505

4.506 0 61.5489 3.451

100 61.2309 3.769

200 59.8110 5.189

300 58.6010 6.399

400 57.5859 7.414

500 56.5906 8.409

4.2.5 The effects of economic evaluation

The economic evaluation of facility investment is one of the most critical tasks involve in

the conceptual phase in pipeline transportation of heavy oil. Due to the commitment of

resources spending when a decision is made. Also, the evaluation also involves cash flow

considering all capital requirements and revenues, which includes the following analytical

steps8;

i. Project planning.

ii. Construction of pipeline cost.

iii. Projection of all expenditure and revenues.

iv. Cash flow that is maximization of profits.

However, the above mentioned should be properly considered and the availability pipeline

protection and creation of awareness during the design should be stated out in the chosen

area. The essential element of economic evaluation is project cash flow analysis which is

the profits and the purpose of any embarking projects. Therefore, these require quantifying

all monetary items and extend of the project, because all expenditure and revenues should

be encountered for the analysis in forms of quantity and within the estimated time or

prediction period.

Page 51: Analysis of Heavy Oil in a Two Phase-Flow

45

As the values of the GOR reduces in table 5, the pressured drop along the pipe also

reduced. The pipe with large diameter sizes recorded lower pressure drop and the

condensate concentration has an effect on the base oil compared to the pressure drop

values as seen in table 4.

Page 52: Analysis of Heavy Oil in a Two Phase-Flow

46

5 Conclusion and Recommendations

The major problem in transporting heavy oil is the high viscosity effects which results to

pressure drop along the pipeline. Several methods of viscosity reduction were analysed

such as the dilution and emulsion methods. The minimization of cost, availability of

diluents and surrounding temperatures and the conditions, the distance the oil is to be

moved. The importance of two-phase flow, choice of design of the pipeline and its

economic evaluation were discussed.

A Prosper model was built and a correlation chosen to calculate the pressure drops in a

horizontal pipeline of 2000 m. This was determined by series of investigations using the

base oil, condensate concentrations, different pipe diameters, the GOR values and

surrounding temperatures which influences the rate of pressure drop along the pipeline.

The solution to the transportation problem can be solved by using different cases as

discussed earlier:

Since size of the pipe diameter determines and influences the pressure drop

such that the GOR values can increase constantly in a large pipe diameter.

However, the loss of the pressure from 65bars to 34.54bar is as a result of high

viscosity of the oil which produces a high pressure loss but with an addition of

condensate and an increase in the pipe diameter from 3.548 in to 4.026 in and

temperature of the surrounding. Therefor the pressure drop is 30.46bars.

In Figure 22 above, the outlet pressure is increased from 32.5bar to 48.75bar,

which is 16.25bars pressure drop reduction. This is as a result of an increase in

the pipe diameter of 4.026 in, with same base oil and comparing it to the

previous case of 3.548 in size pipe where the pressure drop was 32.5bars.

With an increase of pipe diameter of 4.506 in and 50% condensate

concentration addition to the base oil, the pressure drop reduction was maximal

and was 63.395bars.

A large pipe diameter size of either 4.026in or 4.506in and approximately 30%

to 40% condensate concentration, should be considered during design and

evaluation of cost and markets demand, because the outlet pressure is increased

to 58.826bars and 61.506bars respectively compared to the base oil flowing in

the 3.548 in pipe.

Page 53: Analysis of Heavy Oil in a Two Phase-Flow

47

The addition of 30% condensate concentration to the base oil with a pipe

diameter of 3.548 in showed a slight pressure drop difference of 55.0875bar to

55.1281bars.

For a very long pipeline transporting heavy oil, the dilution or emulsion method

might be a better choice, as heating the pipeline might require larger investment

and cost. Also the emulsion method provides more stability over a long period

of time.

Recommendation

In pipeline transportation of heavy oil, the minimization of the cost of design, the

availability of the diluents for the reduction of viscosity, the soil temperatures and the

conditions, the distance the oil is to be moved should be considered. A large diameter pipe

size should be used, because the larger the size, the smaller the pressure drop and the

market demand should be a factor in considering the investment cost in order to maximize

profits.

Page 54: Analysis of Heavy Oil in a Two Phase-Flow

48

6 References

1. Moreau, B.L. The pipeline transportation of heavy oils. Heavy oil seminar, the

petroleum society of C.I.M, Calgary, May 5, 1965, P. 252

2. Takacs, G. Ph.D (2012.): Production engineering fundamentals vol 1., University of

Miskolc. pp.:33-61.

3. Guevara, E. et al, Core Annular flow: the most economical method for the

transportation of viscous hydrocarbons, the 4th Unitar, Aug 1985, 5 (194), P 531

4. D. Escojido. Maraven S.A. transportation of heavy crude oil and natural bitumen.

Part 1, Lagunillas, Estado Zulia, Venezuela. P.

5. B.H Beggs (U. of Tulsa) J.P (U.of Tulsa) A study of two-phase flow in inclined

pipes, Society of Petroleum Engineers, Journal of Petroleum. May 1973, vol 25.

6. Hermanta Mukherjee, and James .P. Brill, Liquid holdup correlations for inclined

two-phase flow, Society of Petroleum Engineers. Johnston-macco Schlumberger.

May 1983.

7. George .H. Fancher and Kermit .E. Brown, Prediction of pressure gradients for

multiphase floe in inclined pipes, Society of Petroleum Engineers, The U of Texas,

Austin, and March 1963.

8. Hyung-Jin Kim. An economic evaluation system for building construction projects

in the conceptual phase. Department of Research and development, Kunwon

Engineering Co. Ltd, Seoul, Kina 2004.

Page 55: Analysis of Heavy Oil in a Two Phase-Flow

49

7 Acknowledgment

I would like to express my deepest appreciation to God almighty for his grace and love, my

advisor, Dr Zoltán Turzó and László Kis for their unwavering support, guidance and the

great opportunity to work with them. Their constant approaches in making sure this work

was concluded and great efforts to my thesis, without them and persistent help this

research would not have been possible.

A special thanks to László Kis for his support with computer software which made a

valuable contribution to my thesis. Thank you so much, I’m really grateful.

I would also say a special thank you to my family, relatives and friends for always

inspiring, supportive and for believing in my future.

Finally, I would like to say a big thank you to the University of Miskolc, academic staffs of

the Petroleum Engineering Department, for always been there and making sure that all that

is needed is made available during the period of my study here.

Page 56: Analysis of Heavy Oil in a Two Phase-Flow

50

8 Appendices

APPENDIX A

Table 6. Pressure difference of condensate concentration

Crude Sample Pipe Size

(in)

GOR Outlet

Pressure(bar) 𝑑𝑝 = 𝑝𝑖𝑛 − 𝑝𝑜

( bar)

Condensate

concentration

(20%)

3.548 0 55.0489 9.951

100 54.7016 10.298

200 52.6215 12.378

300 47.4094 17.590

400 43.941 21.059

500 39.9344 25.065

4.026 0 59.0281 5.971

100 58.7539 6.246

200 58.2285 6.771

300 54.7569 10.243

400 52.9344 12.065

500 51.0047 13.995

4.506 0 61.3438 3.656

100 60.9874 4.012

200 60.6556 4.344

300 58.5625 6.437

400 57.525 7.475

500 56.5094 8.490

APPENDIX B

Table 7. Pressure difference of condensate concentration

Crude Sample Pipe Size

(in)

GOR Outlet

Pressure(bar) 𝑑𝑝 = 𝑝𝑖𝑛 − 𝑝𝑜

( bar)

Condensate

concentration

(30%)

3.548 0 55.1094 9.890

100 54.8844 10.481

200 54.5187 10.481

300 48.3482 16.651

400 45.0531 19.946

500 41.3734 23.626

4.026 0 58.9875 6.012

100 58.8632 6.136

200 58.6625 6.337

300 55.2681 9.731

400 53.4203 11.579

500 51.6783 13.321

4.506 0 61.1812 3.818

100 61.1002 3.899

200 60.8835 4.116

300 58.8553 6.144

400 57.8104 7.189

500 56.7245 8.275

Page 57: Analysis of Heavy Oil in a Two Phase-Flow

51

APPENDIX C

Table 8. Pressure difference of condensate concentration.

Crude Sample Pipe Size

(in)

GOR Outlet

Pressure(bar) 𝑑𝑝 = 𝑝𝑖𝑛 − 𝑝𝑜

( bar)

Condensate

concentration

(66%)

3.548 0 64.4719 0.528

100 64.4512 0.548

200 64.4403 0.559

300 64.4313 0.568

400 64.2271 0.772

500 64.1129 0.887

4.026 0 64.7969 0.203

100 64.7571 0.242

200 64.7462 0.253

300 64.6982 0.301

400 64.4948 0.505

500 64.3906 0.609

4.506 0 64.9986 0.0014

100 64.9974 0.0026

200 64.9965 0.0035

300 64.9913 0.0087

400 64.6871 0.312

500 64.6674 0.332