cinética practica, trabajo en exel tarabjo importante

7/26/2019 cintica practica, trabajo en exel tarabjo importante.

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CURVA PATRON r= 0.99748515

ABS m= 941.568627

0.0001 0.11 b= 0.0117451

0.0002 0.196

0.00025 0.252

0.0004 0.372

0.0005 0.494

[ K3Fe(CN)

6]


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0.00005 0.0001 0.00015 0.0002 0.00025 0.0003 0.00035 0.0004 0.00045 0

0

0.1

0.2

0.3

0.4

0.5

0.6

f() ! 941.568627451 " 0.011745098

R# ! 0.9949766185

Curva de Calibracion

[ K3Fe(CN)6]

ABS


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.0005 0.00055


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CORR$%A 1 CORR$%A 2 CORR

& ['] ABS [ K3Fe(CN)6 ] ABS [ K3Fe(CN) ] ABS

2 0.582 0.0006056435 0.832 0.0008711579 0.214

4 0.387 0.0003985423 0.813 0.0008509788 0.199

6 0.24 0.0002424198 0.775 0.0008106206 0.1628 0.164 0.0001617035 0.747 0.000780883 0.136

10 0.117 0.0001117868 0.729 0.0007617659 0.108

12 0.09 8.311120*+005 0.712 0.000743711 0.092

14 0.069 0.000060808 0.698 0.0007288421 0.08

16 0.054 4.487713*+005 0.696 0.000726718 0.071

18 0.048 3.850479*+005 0.674 0.0007033528 0.063

20 0.041 3.107039*+005 0.667 0.0006959184 0.057


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'!

$%A 3 CORR$%A 4 ,!

[ K3Fe(CN) ABS [ K3Fe(CN)6 ]

0.0002148 0.187 0.000186131

0.0001989 0.169 0.000167014

0.0001596 0.149 0.0001457730.000132 0.14 0.000136214

0.0001022 0.127 0.000122407

8.52*+005 0.104 0.00009798

7.25*+005 0.088 8.09871*+005

6.29*+005 0.077 6.93045*+005

5.44*+005 0.068 5.97459*+005

4.81*+005 0.061 5.23115*+005


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941.568627451

0.011745098


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CORR 1 CORR 2 CORR 3 CORR 4

& ['] [ K3Fe(CN)6] [ K3Fe(CN)6 ][ K3Fe(CN)6 ][ K3Fe(CN)6 ]

2 0.0006056435 0.00087116 0.00021481 0.0001861308

4 0.0003985423 0.00085098 0.00019888 0.0001670137

6 0.0002424198 0.00081062 0.00015958 0.0001457726

8 0.0001617035 0.00078088 0.00013197 0.0001362141

10 0.0001117868 0.00076177 0.00010223 0.000122407312 8.311120*+005 0.00074371 8.5235*+005 0.00009798

14 0.000060808 0.00072884 7.2491*+005 8.09870887*+005

16 4.487713*+005 0.00072672 6.2932*+005 6.93044565*+005

18 3.850479*+005 0.00070335 5.4436*+005 5.97459392*+005

20 3.107039*+005 0.00069592 4.8063*+005 5.23115369*+005

-! +0.8743442395 +0.97471829 +0.96753188 +0.9931056434

'! +2.73045*+005 +9.710*+006 +9.668*+006 +7.65968725*+006

,! 0.0004781966 0.0008742 0.00021941 0.0001960433

0 5 10 15 20 25

0

0.0001

0.0002

0.0003

0.0004

0.0005

0.0006

0.0007

f() ! + 2.73045322024914*+005 " 0.0004781966

R# ! 0.7644778492

corrida 1

/-- 1

e- (/-- 1)

t[min]

[K3Fe(CN)6]

0 5 10 15 20 25

0

0.00005

0.0001

0.00015

0.0002

0.00025

f() ! + 9.667941388058*+006 " 0.0002194086R# ! 0.9361179473

corrida 3

/-- 3

e- (/-- 3)[K3Fe(CN)6]


8/25

t[min]


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0 5 10 15 20 25

0

0.0002

0.0004

0.0006

0.0008

0.001

f() ! + 9.70978001590247*+006 " 0.0008742024

R# ! 0.9500757417

corrida 2

/-- 2

e- (/-- 2)

t[min]

[K3Fe(CN)6]

0 5 10 15 20 25

0

0.00005

0.0001

0.00015

0.0002

f() ! + 7.65968725152399*+006 " 0.0001960433

R# ! 0.9862588189

corrida

/-- 4

e- (/-- 4)[K3Fe(CN)6]


10/25

t[min]


11/25


12/25


13/25


& ['] [K3Fe(CN) [K3Fe(CN) [K3Fe(CN) [K3Fe(CN)6 ]

2 +7.40921906 +7.04568737 +8.44577372 +8.5890610193

4 +7.82769698 +7.06912339 +8.52283172 +8.6974344479

6 +8.32483952 +7.11771046 +8.74296932 +8.8334627207

8 +8.72974641 +7.15508527 +8.9329674 +8.9012828108

10 +9.09891747 +7.17987123 +9.18830261 +9.008156301812 +9.39533104 +7.2038581 +9.37009467 +9.2307470967

14 +9.70778925 +7.22405338 +9.53205326 +9.4212208146

16 +10.0115821 +7.226972 +9.67345401 +9.5770013468

18 +10.1647279 +7.25965199 +9.81849125 +9.7254093328

20 +10.3792554 +7.27027819 +9.94299152 +9.8582936212

-! +0.9898011 +0.9805377 +0.99552473 +0.9937285201

'! +0.1659206 +0.01252187 +0.08841227 +0.0730879259

,! +7.2797839 +7.03748859 +8.24445795 +8.3802397663

0 5 10 15 20 25

+12

+10

+8

+6

+4

+2

0

f() ! + 0.1659206017 + 7.279783899

R# ! 0.9797062214

corrida 1

/-- 1

e- (/-- 1)

t[min]

[K3Fe(CN)6]

0 5 10 15 20 25

+10.5

+10

+9.5

+9

+8.5

+8

+7.5

f() ! + 0.0884122728 + 8.2444579472

R# ! 0.9910694818

corrida 3

/-- 3

e- (/-- 3)[K3Fe(CN)6]


14/25

t[min]


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0.00060564 0.00087116 0.00021481 0.00018613

0.00039854 0.00085098 0.00019888 0.00016701

0.00024242 0.00081062 0.00015958 0.00014577

0.0001617 0.00078088 0.00013197 0.00013621

0.00011179 0.00076177 0.00010223 0.00012241

8.3111*+005 0.00074371 8.5235*+005 0.000097986.0808*+005 0.00072884 7.2491*+005 8.0987*+005

4.4877*+005 0.00072672 6.2932*+005 6.9304*+005

3.8505*+005 0.00070335 5.4436*+005 5.9746*+005

3.1070*+005 0.00069592 4.8063*+005 5.2312*+005

0 5 10 15 20 25

+7.3

+7.25

+7.2

+7.15

+7.1

+7.05

+7

+6.95

+6.9

f() ! + 0.0125218682 + 7.0374885881

R# ! 0.9614541751

corrida 2

/-- 2

e- (/--

t[min]

[K3Fe(CN)6]

0 5 10 15 20 25

+10

+9.5

+9

+8.5

+8

+7.5

f() ! + 0.0730879259 + 8.3802397663

R# ! 0.9874963716

corrida

/-- 4

e- (/--[K3Fe(CN)6]


16/25

t[min]


17/25

2)

4)


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19/25


& ['] 1[ K3Fe(CN) 1[ K3Fe(CN) 1[ K3Fe(CN) 1[ K3Fe(CN)6 ]

2 1651.1364 1147.89759 4655.356285372.5665697024

4 2509.14411 1175.11746 5028.27225 5987.5311720698

6 4125.07517 1233.62277 6266.47527 6860

8 6184.15969 1280.60163 7577.71816 7341.385109310510 8945.60358 1312.7392 9782.033 8169.4453895883

12 12032.0722 1344.60841 11732.2258 10206.163655686

14 16445.2055 1372.0392 13794.8865 12347.64721008

16 22283.0626 1376.04952 15890.13914429.086538462

18 25970.795 1421.76166 18370.313716737.539212269

20 32184.9866 1436.95015 20805.8925 19116.242038217

-! 0.97386771 0.98569838 0.98925736 0.9708856581

'! 1708.16894 16.9924338 931.724645 769.2244629053

,! +5556.7343 1126.12427 1141.360152195.2915975805

0 5 10 15 20 25

0

5000

10000

15000

20000

25000

30000

35000

f() ! 1708.1689438595 + 5556.734297127

R# ! 0.9484183118

corrida 1

/-- 1

e- (/-- 1)

t[min]

[K3Fe(CN)6]

0

5000

10000

15000

20000

25000

f() ! 931.7246452565 " 1141.3601487013

R# ! 0.9786301191

corrida 3

/-- 3

e- (/-- 3)[K3Fe(CN)6]


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0 5 10 15 20 25

t[min]


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0.00060564 0.00087116 0.00021481 0.00018613

0.00039854 0.00085098 0.00019888 0.00016701

0.00024242 0.00081062 0.00015958 0.00014577

0.0001617 0.00078088 0.00013197 0.00013621

0.00011179 0.00076177 0.00010223 0.000122418.3111*+005 0.00074371 8.5235*+005 0.00009798

6.0808*+005 0.00072884 7.2491*+005 8.0987*+005

4.4877*+005 0.00072672 6.2932*+005 6.9304*+005

3.8505*+005 0.00070335 5.4436*+005 5.9746*+005

3.1070*+005 0.00069592 4.8063*+005 5.2312*+005

0 5 10 15 20 25

0

200

400

600

800

1000

1200

1400

1600

f() ! 16.2009030027 " 1131.9288259394

R# ! 0.9711089613

corrida 2

/-- 2

e- (/--

t[min]

[K3Fe(CN)6]

0

5000

10000

15000

20000

25000

f() ! 769.2244629053 " 2195.2915975805

R# ! 0.9426189611

corrida

/-- 4

e- (/--[K3Fe(CN)6]


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23/25

2)

4)


24/25


25/25

Corrida [K3Fe(CN)6]i M

1 0.0010198558 #DIV/0!2 0.00065809 0.05633093 9.16"601805

3 0.0005053631 0.05518100"2 12.56133683

" 0.000399361" 0.0""310581 15.6"2926668

Co$%a%e de&e'oidad (i1)

*ie+o de&ida edia

(i)

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cinética practica, trabajo en exel tarabjo importante