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DPF+SCR retrofit of Construction Machines: Real-time characterization of emission reduction and optimization during realistic operating conditions Morten Køcks 1 , Thomas N. Jensen 1 , Troels Dyhr Pedersen 1 , and Mende Trajkovski 2 1 Danish Technological Institute, Kongsvang Allé 29, DK-8000 Aarhus C, Denmark 2 Purefi A/S, Rugmarken 37, DK-3520 Farum, Denmark E-mail: [email protected] , phone: +45 7220 2380 Introduction Construction machines are responsible for a significant part of the total particle and NO x pollution in urban areas. The engines used in construction machines are regulated by the EU Stage standards, which are less stringent than the Euro standards with respect to NO x and PM. An important issue relating to construction machines is also that the construction site workers are working on and around the machines and hence continuously exposed to the emissions. Exposure to nanoparticles can lead to increased risk of cardio- Exposure to nanoparticles can lead to increased risk of cardio vascular diseases and cancer, as the nanoparticles penetrate deep into the lungs and enter the bloodstream. Exposure to high concentrations of NO 2 irritates the respiratory system and is suspected to have a large negative impact on several body functions as well. For both PM and NO 2 , international studies have shown that an increase of 10 µg/m 3 leads to a 5-8 % increase in mortality rate. Reducing the emissions of PM and NO x will have a large impact on public health and the national economy. The goals of this work are to develop suitable and effective retrofit technology for selected construction machinery as well as to develop a method for online emission characterization during realistic operating diti Sh h i ff t f DPF+SCR t fit d l ti Figures 3 and 4: The asphalt paver with the DPF+SCR solution, developed by Purefi A/S conditions. Shown here iseffect of DPF+SCR retrofit and real-time emission data from a Deutz TCD 2011 45-kW Stage IIIA diesel engine powering an VÖGELE Super 800 asphalt paver. Average raw emission data for the regulated gases, measured during normal operation, are summarized in Table 1. Experimental Measurements were carried out from a van driving right next to the machines on a test facility. Probes were installed in the exhaust system and the gas and particle sample stream is transferred to the instruments inside the van, as seen in figures 1 and 2. Particle size distribution (PSD) and number (PN) concentration are measured in the size interval 10-420 nm in 13 size bins using a N S SMPS (TSI) td ft t ti di dil t (M tt ) Figures 5 and 6: Average PSD for the asphalt paver, averaged over several measurement cycles of normal operating conditions and measured with NanoScan SMPS. PSD are shown in the full measuring range of 10-420 nm. Note that the scales on the y-axes differ by a factor of 1,000 on the two figures No after‐treatment With after‐treatment Reduction The specific emissions were calculated for the engine at normal operation, which is close to full load. Table 2 shows the specific emissions compared to the Stage IIIA demands (for the untreated exhaust) and Stage IV (for the treated exhaust). NanoScan SMPS (TSI) connected after a rotating disc diluter (Matter) heated to 150 °C and a catalytic stripper heated to 350 °C (Catalytic Instruments) for removing the semi-volatile particle fraction. This setup is much similar to the Particle Measurement Program (PMP), defining Euro VI particle measurement, but gives additional particle size information. Gas emissions (CO, CO 2 , THC, NO, NO 2 , NO x , NH 3 , and N 2 O) are measured using Fourier-Transformed Infrared Spectroscopy (FTIR). Table 1: Average emission data from the final after-treatment solution NO x 450 ppm 50 ppm 89% THC 150 ppm 4 ppm 97% CO 89 ppm 0 ppm 100% Untreated Stage IIIA Treated Stage IV The measured ammonia concentration was below the detection limit of 5 ppm. The Stage IIIA and Stage IV demand of 25 ppm NH 3 was thus met. Conclusions Figures 1 and 2: Experimental setup with measurement equipment inside the van driving next to the selected asphalt paver on a test facility Results The selected asphalt paver was retrofitted with two different THC+NO x 4,45 g/kWh 4,7 g/kWh NO x 0,37 g/kWh 0,4 g/kWh THC 0,04 g/kWh 0,19 g/kWh CO 0,57 g/kWh 5 g/kWh 0 g/kWh 5 g/kWh Table 2: Specific emissions before and after the system, compared with Stage IIIA (conformity of the engine) and Stage IV (conformity for new engines from 2014) Conclusions Development and implementation of DPF and SCR technology for the asphalt paver was successfully carried out. The measurement approach and setup with a van driving next to the construction equipment was successful. Real-time emission data were acquired with accurate instruments during realistic operating conditions. Without after-treatment, the asphalt paver was shown to be compliant with Stage IIIA limits, measured on-site during realistic operating conditions. With the downscaled and optimized DPF+SCR retrofit solution, the The selected asphalt paver was retrofitted with two different DPF+SCR solutions. Figures 3 and 4 show the size and position of the first system. The systems were developed and installed by Purefi A/S. The first system was oversized to ensure trouble-free engine operation, mainly with respect to DPF counter-pressure. The second solution was optimized for the particular machine, and a down-scaled version of SCR and DPF was implemented. In addition, an ammonia slip catalyst was installed following SCR in order to minimize ammonia emission. With respect to particle emission, the two tested DPF+SCR solutions reduce PN by more than 99.9 % in the size interval 23-420 nm, with 23 nm being the lower cut-off in PMP. Data were averaged over several measurement cycles during warm engine conditions and measured during This work was part of a 2-year project, co-financed by the Danish Environmental Protection Agency. The consortium is constituted by Danish Technological Institute and the companies NCC Roads A/S, Purefi A/S and LiqTech International A/S. asphalt paver was shown to be compliant with Stage IV limits on PN, NOx, THC and CO during the described measurement conditions (not standardized test according to ISO 8178). Particle emission was characterized according to PMP, with additional size information, and with a DPF efficiency of >99.9 % (by number). measurement cycles during warm engine conditions and measured during realistic and normal operating conditions. In addition, the average measured PN concentration downstream DPF+SCR is about a factor of 5-10 below the PN reference value being suggested by the Swiss Federal Office for the Environment FOEN (2.5x10 5 particles/cm 3 ), for passing a DPF test. This reference value is analogous to the proposed limit in the future Stage V standard (1x10 12 particles/kWh), but is much easier to measure on-site. Interestingly, a significant amount of the particles measured downstream DPF+SCR have a size below the PMP limit of 23 nm, as also seen in figure 6.

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DPF+SCR retrofit of Construction Machines: Real-time characterization of emission reduction and

optimization during realistic operating conditionsMorten Køcks1, Thomas N. Jensen1, Troels Dyhr Pedersen1, and Mende Trajkovski2

1 Danish Technological Institute, Kongsvang Allé 29, DK-8000 Aarhus C, Denmark2 Purefi A/S, Rugmarken 37, DK-3520 Farum, Denmark

E-mail: [email protected], phone: +45 7220 2380

IntroductionConstruction machines are responsible for a significant part of the

total particle and NOx pollution in urban areas. The engines used inconstruction machines are regulated by the EU Stage standards, whichare less stringent than the Euro standards with respect to NOx and PM.An important issue relating to construction machines is also that theconstruction site workers are working on and around the machines andhence continuously exposed to the emissions.

Exposure to nanoparticles can lead to increased risk of cardio-Exposure to nanoparticles can lead to increased risk of cardiovascular diseases and cancer, as the nanoparticles penetrate deep intothe lungs and enter the bloodstream. Exposure to high concentrations ofNO2 irritates the respiratory system and is suspected to have a largenegative impact on several body functions as well. For both PM and NO2,international studies have shown that an increase of 10 µg/m3 leads to a5-8 % increase in mortality rate. Reducing the emissions of PM and NOxwill have a large impact on public health and the national economy.

The goals of this work are to develop suitable and effective retrofittechnology for selected construction machinery as well as to develop amethod for online emission characterization during realistic operating

diti Sh h i ff t f DPF+SCR t fit d l ti

Figures 3 and 4: The asphalt paver with the DPF+SCR solution, developed by Purefi A/S

conditions. Shown here is effect of DPF+SCR retrofit and real-timeemission data from a Deutz TCD 2011 45-kW Stage IIIA diesel enginepowering an VÖGELE Super 800 asphalt paver.

Average raw emission data for the regulated gases, measured duringnormal operation, are summarized in Table 1.

ExperimentalMeasurements were carried out from a van driving right next to the

machines on a test facility. Probes were installed in the exhaust systemand the gas and particle sample stream is transferred to the instrumentsinside the van, as seen in figures 1 and 2.

Particle size distribution (PSD) and number (PN) concentration aremeasured in the size interval 10-420 nm in 13 size bins using aN S SMPS (TSI) t d ft t ti di dil t (M tt )

Figures 5 and 6: Average PSD for the asphalt paver, averaged over several measurement cycles of normal operating conditions and measured with NanoScan SMPS. PSD are shown in the full measuring range of 10-420 nm. Note that the scales on the y-axes differ by a factor of 1,000 on the two figures

No after‐treatment With after‐treatment Reduction

The specific emissions were calculated for the engine at normaloperation, which is close to full load. Table 2 shows the specific emissionscompared to the Stage IIIA demands (for the untreated exhaust) andStage IV (for the treated exhaust).

NanoScan SMPS (TSI) connected after a rotating disc diluter (Matter)heated to 150 °C and a catalytic stripper heated to 350 °C (CatalyticInstruments) for removing the semi-volatile particle fraction. This setup ismuch similar to the Particle Measurement Program (PMP), defining EuroVI particle measurement, but gives additional particle size information.

Gas emissions (CO, CO2, THC, NO, NO2, NOx, NH3, and N2O) aremeasured using Fourier-Transformed Infrared Spectroscopy (FTIR).

Table 1: Average emission data from the final after-treatment solution

NOx 450 ppm  50 ppm 89%

THC 150 ppm 4 ppm 97%

CO 89 ppm 0 ppm 100%

Untreated Stage IIIA Treated Stage IV

The measured ammonia concentration was below the detection limit of 5ppm. The Stage IIIA and Stage IV demand of 25 ppm NH3 was thus met.

Conclusions

Figures 1 and 2: Experimental setup with measurement equipment inside the van driving next to the selected asphalt paver on a test facility

ResultsThe selected asphalt paver was retrofitted with two different

THC+NOx 4,45 g/kWh 4,7 g/kWh

NOx 0,37 g/kWh 0,4 g/kWh

THC  0,04 g/kWh 0,19 g/kWh

CO 0,57  g/kWh 5  g/kWh 0 g/kWh 5 g/kWh

Table 2: Specific emissions before and after the system, compared with Stage IIIA (conformity of theengine) and Stage IV (conformity for new engines from 2014)

ConclusionsDevelopment and implementation of DPF and SCR technology forthe asphalt paver was successfully carried out.The measurement approach and setup with a van driving next to theconstruction equipment was successful. Real-time emission datawere acquired with accurate instruments during realistic operatingconditions.Without after-treatment, the asphalt paver was shown to be compliantwith Stage IIIA limits, measured on-site during realistic operatingconditions.With the downscaled and optimized DPF+SCR retrofit solution, the

The selected asphalt paver was retrofitted with two differentDPF+SCR solutions. Figures 3 and 4 show the size and position of thefirst system. The systems were developed and installed by Purefi A/S.The first system was oversized to ensure trouble-free engine operation,mainly with respect to DPF counter-pressure. The second solution wasoptimized for the particular machine, and a down-scaled version of SCRand DPF was implemented. In addition, an ammonia slip catalyst wasinstalled following SCR in order to minimize ammonia emission.

With respect to particle emission, the two tested DPF+SCR solutionsreduce PN by more than 99.9 % in the size interval 23-420 nm, with 23nm being the lower cut-off in PMP. Data were averaged over severalmeasurement cycles during warm engine conditions and measured during

This work was part of a 2-year project, co-financed by the Danish Environmental Protection Agency. The consortium is constituted by Danish Technological Institute and the companies NCC Roads A/S, PurefiA/S and LiqTech International A/S.

asphalt paver was shown to be compliant with Stage IV limits on PN,NOx, THC and CO during the described measurement conditions(not standardized test according to ISO 8178).Particle emission was characterized according to PMP, withadditional size information, and with a DPF efficiency of >99.9 % (bynumber).

measurement cycles during warm engine conditions and measured duringrealistic and normal operating conditions.

In addition, the average measured PN concentration downstreamDPF+SCR is about a factor of 5-10 below the PN reference value beingsuggested by the Swiss Federal Office for the Environment FOEN(2.5x105 particles/cm3), for passing a DPF test. This reference value isanalogous to the proposed limit in the future Stage V standard (1x1012

particles/kWh), but is much easier to measure on-site. Interestingly, asignificant amount of the particles measured downstream DPF+SCR havea size below the PMP limit of 23 nm, as also seen in figure 6.