DR. RUDOLPH A. ABRAMOVITCH

List of Publications (Chronologically ascending)

1. The chlorination of β-D-Glucopyranose Pentacetate. Abnormal Reactions of

Phosphorus Pentachloride. J. Chem. Soc., 2996 (1951).

2. Internuclear Cyclization, Part VIII. Naphth[3,2,1-cd]oxindoles. With D. H. Hey, J.

Chem. Soc., 1967 (1954).

3. The Pattern of Picrate Formation in the Pyridylquinoline Series. J. Chem. Soc., 3839

(1954).

4. Internuclear Cyclization, Part XI. The Synthesis of ind-N-Methylcarbolines. With

D. H. Hey and R. D. Mulley, J. Chem. Soc., 4283 (1954).

5. Polyazabicyclic Compounds, Part I. Preliminary Experiments on the Bischler and

Bamberger Synthesis of Benzo-1,2,4-triazines. With K. Schofield, J. Chem. Soc., 2326

(1955).

6. The Bischler Synthesis of Benzo-1,2,4-triazines. Bull. Res. Counc. of Israel, 5, 14

(1955).

7. A Convenient Synthesis of Tryptamines and Tetrahydro-β-carbolines. With D.

Shapiro, Chem. and Ind., 1255 (1955).

8. Application of the Japp-Klingemann Reaction. A New Synthesis of Ornithine. With

D. Shapiro, J. Am. Chem. Soc. 77, 6690 (1955).

9. The Japp-Klingemann Reaction with α,β -Unsaturated β-Ketoesters. Synthesis of

Pyridazinones. With D. Shapiro and S. Pinchas, J. Am. Chem. Soc., 78, 2144 (1956).

10. Tryptamines, Carbolines, and Related Compounds, Part II . A Convenient Synthesis

of Tryptamines, and β-Carbolines. With D. Shapiro, J. Chem. Soc., 4589 (1956).

11. Tryptamines, Carbolines, and Related Compounds, Part III. 1-Methyl and 1,N-

Dimethyltryptamines. J Chem. Soc., 4593 (1956).

12. The Infrared Spectra of Some Diacylamines in the 6µ Region. J. Chem. Soc. 1413

(1957).

13. Pyrid(1,2-b)indazole. Chem. and Ind., 422 (1957).

14. Internuclear Cyclization, Part XII. The Synthesis of Some Benzophenanthridones.

Abnormal Reaction of 1-Amino-N-methyl-2-naphthanilide. With D. H. Hey and R. A. J.

Long., J. Chem. Soc., 1781 (1957).

15. The Isomeric Pyruvamide Phenylhydrazones. With I. D. Spenser. J. Chem. Soc.,

3767 (1957).

16. The Infrared Spectra of Malonate Esters. Can. J. Chem., 36, 151, (1958).

17. Tryptamines, Carbolines, and Related Compounds, Part IV. Attempted Synthesis of

the Physostigmine Ring System. Can. J. Chem., 36, 354. (1958).

18. Unsymmetrically Substituted 3,3'-Methylene-bridged 2,2'-Dihydroxy-chromones

(Dicoumarols). With J. R. Gear, Can. J. Chem., 36, 1501 (1958).

19. The Condensation of 1-Phenyl-2-propanones with Aromatic Aldehydes. With A.

Obach, Can. J. Chem., 37, 502 (1959).

20. The Infrared Spectra of Some Cyclic Malonates. Can. J. Chem., 37, 361 (1959).

21. The Infrared Spectra of Malonates and Oxalates: Temperature Effect. Can. J. Chem.,

37, 1146 (1959).

22. Orientation in the Reaction of Phenyllithium with 3-Substituted Pyridines. With A.

D. Notation and Giam Choo-Seng, Tetrahedron Lett., No. 8, 1 (1959).

23. The Structure of 2-p-Dimethylaminobenzylideneindoxyl and its Salts. With A. M.

Marko, Can. J. Chem., 38, 131 (1960).

24. Tryptamines, Carobolines, and Related Compounds, Part V. 3-( α-Alkyl- β-

aminoethyl)indoles. With J. M. Muchowski, Can. J. Chem., 38, 554 (1960).

25. Tryptamines, Carbolines, and Related Compounds, Part VI. Stereochemistry of the

Michael Addition of Ethyl Malonate to 1-Cyclohexene Cyanide. With J. M. Muchowski,

Can. J. Chem. 38, 557 (1960).

26. Differentiation Between Some 2,3- and 2,5-Disubstituted Pyridine Derivatives by

Infrared Spectroscopy. With Giam Choo-Seng and A. D. Notation, Can. J. Chem., 38,

624 (1960).

27. Arylpyridines, Part I. Orientation in the Reaction of Phenyllithium with some 3-

Substituted Pyridines. With Giam Choo-Seng and A. D. Notation, Can. J. Chem., 38,

761 (1960).

28. Arylpyridines, Part II. Reaction of Phenyllithium with 3-Methoxy- and 3-

Aminopyridines. With A. D. Notation, Can. J. Chem., 38, 1445 (1960).

29. Tryptamines, Carbolines, and Related Compounds, Part VII. Internuclear Cyclization

onto a Pyridine Ring. Can. J. Chem., 38, 2273 (1960).

30. Tryptamines, Carbolines, and Related Compounds, Part VIII. δ-Carboline. With K.

A. H. Adams and A. D. Notation, Can.J.Chem., 38, 2152 (1960).

31. Terminal Olefins in Low Temperature Lignite Tar. With J. M. Pepper and J. G. Saha,

Chem. and Ind., 368 (1961).

32. Some Neutral and Acidic Extractives from Ceanothus americanus L. With G.

Tertzakian, Can. J. Chem., 39, 1733 (1961).

33. A New Method for the Deoxygenation of Aromatic N-Oxides. With K. A. H. Adams,

Can. J. Chem., 39, 2134. (1961).

34. Oxidative Decarboxylation of Indole-3-acetic Acid by Mangani-versene and by

Wheat Leaf Enzyme. With K. S. Ahmed, Nature, 192, 259 (1961).

35. Tryptamines, Carbolines, and Related Compounds, Part IX. The Cyclization of Some

Nitro- and Azido-phenylpyridines. Pyrido[1,2-b]indazole. With K. A. H. Adams, Can. J.

Chem., 39, 2516 (1961).

36. The Formation of a Nitrene Intermediate in the Reaction of Nitro Compounds with

Ferrous Oxalate. With Y. Ahmed and D. Newman, Tetrahedron Lett., 21, 752 (1961).

37. Aromatic Substitution, Part I. The Reaction of Phenyllithium with 3-Alkylpyridines.

Steric Effect and Quantitative Analysis of Isomer Ratios. With Giam Choo-Seng, Can. J.

Chem., 40, 213 (1962).

38. Tryptamines, Carbolines, and Related Compounds, Part X. An Alternative Synthesis,

and the Nitration of δ-Carboline. With K. A. H. Adams, Can. J. Chem., 40, 864 (1962).

39. Extractives from Populus tremuloides Heartwood. The Structure and Synthesis of

Tremulone. With R. G. Micetich, Can. J. Chem., 40, 2017 (1962).

40. The Preparation and Infrared and N.M.R. Spectra of Monodeuterated Pyridine and 3-

Picoline. With D. J. Kroeger and G. Staskun, Can. J. Chem., 40, 2030 (1962).

41. On Paoloni's Note Entitled: The Structure of Carbolines and Related Compounds.

Can. J. Chem., 40, 2418 (1962).

42. Extractives from Populus tremuloides (Aspen Popular) Heartwood. With R. G.

Micetich and S. J. Smith, Tappi, 46, 37 (1963).

43. A New Ortho-Effect in the Homolytic Arylation of Pyridine. With J. G. Saha,

Tetrahedron Letters, 301 (1963).

44. Aromatic Substitution, Part II. The Reaction of Various 3-Substituted Pyridine

Derivatives and of Quinoline with Phenyllithium. With K. S. Ahmed and Giam Choo-

Seng, Can. J. Chem., 41, 1752 (1963).

45. Phenyllithium-Pyridine Adduct as a Reducing Agent for Ketones. With B. Vig. Can.

J. Chem., 41, 1961 (1963).

46. A New Synthetic Approach to the Benzo[c]phenanthridine System: Internuclear

Cyclization onto a Pyridine Ring. With G. Tertzakian, Can. J. Chem., 41, 2265 (1963).

47. Synthesis Involving Imino Intermediates: Phenanthridines and

Benzo[c]phenanthridines. With D. Newman and G. Tertzakian, Can. J. Chem., 41, 2390

(1963).

48. Biogenetic-Type Synthesis of the Amaryllidaceae Alkaloid Ring System. With S.

Takahashi, Chem. and Ind., 1039 (1963).

49. Extractives from Populus tremuloides Heartwood. The Triterpene Alcohols. With R.

G. Micetich, Can. J. Chem., 41, 2362 (1963).

50. The Thermal Decomposition of Diazonium Salts: Evidence for the Formation of

Radical Intermediates. (Aromatic Substitution, Part IV). With W. A. Hymers, J. B.

Rajan, and R. Wilson, Tetrahedron Lett., 1507 (1963).

51. On the Mechanism of the Pschorr Reaction. With G. Tertzakian, Tetrahedron Lett.,

1511 (1963).

52. Aromatic Substitution. Part V. The Mechanism of the Reaction of Phenyllithium

with Pyridine. Deuterium Isotope Effect Studies. With Giam Choo-Seng, Can.J.Chem.,

41, 3127 (1963).

53. Preparation and Properties of Imido Intermediates (Imidogens). With B. A. Davis,

Chem.Rev., 64, 149 (1964).

54. The Nuclear Magnetic Resonance Spectra of the Carbolines. With I. D. Spencer,

Can.J.Chem., 42, 945 (1964).

55. On the Mechanism of the Amination of Pyridine. (Aromatic Substitution, Part VI).

With F. Helmer and J. G. Saha, Chem.and Ind., 659 (1964).

56. Aromatic Substitution, Part III. Reaction of Pyridine with ortho-Substituted Phenyl

Radicals, and the Influence of Oxygen upon Isomer Ratios in the Gomberg-Hey Reaction

With J. G. Saha, J. Chem. Soc. 2175 (1964).

57. Aromatic Substitution, Part VII. Competitive Reactions of Pyridine, 3-Picoline and

3-Ethylpyridine with Phenyllithium. Activation of a Nucleophilic Aromatic Substitution

by Alkyl Groups. With C. S. Giam, Can. J. Chem., 42, 1627 (1964).

58. The Carbolines. With I. D. Spencer in "Advances in Heterocyclic Chemistry," Vol.

3, Academic Press Inc., New York, 1964, pp. 79-207.

59. The Mechanism of the Tschitschibabin Reaction. With F. Helmer and J. G. Saha,

Tetrahedron Lett., 3445 (1964).

60. Aromatic Substitution, Part VIII. Some Aspects of the Mechanism of the

Tschitschibabin Reaction. With F. Helmer and J. G. Saha, Can. J. Chem., 43, 752 (1965).

61. Aromatic Substitution. Part IX. On the Mechanism of the Pschorr Cyclization. With

G. Tertzakian, Can. J. Chem., 43, 940 (1965).

62. Some Comments on Craig's Rules. With K. L. McEwen, Can.J.Chem., 43, 2616

(1965).

63. Stereochemistry of the Reduction of Cyclic Ketones with the Pyridine-n-butyl-lithium

Adduct: Steric Approach and Product Development Controls. With W. C. Marsh and J.

G. Saha, Can. J. Chem., 43, 2631 (1965).

64. A Convenient Apparutus for Carrying out Sealed-Tube Reactions with Stirring. With

J. S. Williams, Chem. and Ind., 1786 (1965).

65. Reactions of Benzenesulphonylcarbene. With J. Roy, Chem. Comm., 542 (1965).

66. Arylation of Aromatic Compounds with Benzenediazonium Borofluoride. Nature of

Arylating Species. (Aromatic Substitution, Part X). With J. G. Saha, Can. J. Chem., 43,

3269 (1965).

67. The Reaction of Sulfonylimido Intermediates with Aromatic Compounds. (Aromatic

Substitution, Part XI). With J. Roy and V. Uma, Can. J. Chem., 43, 3407 (1965).

68. Arylations Using Diazonium Tetrafluoroborate and Pyridine. A Convenient Source

of Aryl Radicals. (Aromatic Substitution, Part XII). With J. G. Saha, Tetrahedron, 21,

3297 (1965).

69. Stereochemistry of the Michael Addition. An Interesting Solvent Effect. With D. L.

Struble, Tetrahedron Lett., 289 (1966).

70. An Interesting Stable Twist-boat Fused Cyclohexane Derivative. With D. L. Struble,

Chem.Comm., 150 (1966).

71. The Condensation of 2,3-Dihydro-2-oxoimidazo[1,2-a]pyridine with o-

Nitrobenzaldehyde. With D. H. Hey, J. Chem. Soc., C, 1095 (1966).

72. Aromatic Substitution, XIII. The Polarity of Aryl Radicals. Further Reactions of

Pyridine with Substituted Phenyl Radicals. With M. Saha, J. Chem. Soc., 733 (1966).

73. Aromatic Substitution, XIV. The Homolytic Phenylation of 3- and 4-Picoline. A

Quantitative Study of Isomer and Total Rate Ratios. With M. Saha, Can. J. Chem., 44,

1765 (1966).

74. Substitution in the Pyridine Series: Effect of Substituents. With J. G. Saha in

"Advances in Heterocyclic Chemistry," Vol. 6, Academic Press Inc., New York, 1966,

pp. 229-345.

75. The Proton Magnetic Resonance Spectra of Pyridine 1-Oxides and their Conjugate

Acids. With J. B. Davis, J. Chem. Soc. B., 1137 (1966).

76. Aromatic Substitution, XV. The Homolytic Methylation of 3- and 4-Picoline. With

K. Kenaschuk, Can. J. Chem., 45, 509 (1967).

77. Aromatic Substitution, XVI. Reactivity of 3-Isopropyl- and 3-Cyclohexylpyridine

and of Nicotine Towards Phenyllithium. With G. A. Poulton, J. Chem. Soc. B., 267

(1967).

78. Some Steam Volatile Components of the Extractives from Populus tremuloides

Heartwood. With O. A. Koleoso, Can. J. Chem., 44, 2913 (1966).

79. Intramolecular Free Radical Aromatic Substitution. Chapter in "Advances in Free

Radical Chemistry" (G. H. Williams, ed.), Vol. 2, Academic Press, 1967, pp. 87-138.

80. The Reaction of Simple Aromatic Nitro Compounds with Transition Metal Oxalates.

With B. A. Davis, J. Chem. Soc. C., 119 (1968).

81. Base Catalyzed Deprotonation in Pyridine N-oxides and Pyridinium Salts. With G.

M. Singer and A. R. Vinutha, Chem. Comm., 55 (1967).

82. A New Method of Effecting Pschorr-type Cyclizations. (Aromatic Substitution,

XVII). With A. Robson, J. Chem. Soc. C., 1101 (1967).

83. A New Convenient Alkylation and Acylation of Pyridine N-oxides. With M. Saha, E.

M. Smith, and R. T. Coutts, J. Am. Chem. Soc., 89, 1537 (1967).

84. Direct Evidence for an Intermediate Complex in a Nucleophilic Aromatic

Substitution. With G. A. Poulton, Chem. Comm., 274 (1967).

85. A Novel Synthesis of a Cyclic Hydroxamic Acid Involving a Molecular

Rearrangement. With R. T. Coutts and N. J. Pound, Chem.and Ind., 1871 (1967).

86. Some Extractives from the Bark of PopulusBalsamifera. With R. T. Coutts and E. E.

Knaus, Can. J. Pharm. Sci., 2, 71 (1967).

87. The Proton Magnetic Resonance Spectra of Malonate Esters. With J. B. Rajan and C.

Walker, J. Chem. and Eng. Data, 12, 594 (1967).

88. The Stereochemistry of the Michael Addition. With D. L. Struble, Tetrahedron, 24,

357 (1968).

89. Some cis- and trans-Decahydroisoquinoline Derivatives and their NMR Spectra.

With D. L. Struble, Tetrahedron, 24, 705 (1968).

90. Pyridine and Pyridine Derivatives. Kirk-Othmer "Encyclopedia of Chemical

Technology," Vol. 17, Interscience Publishers, (1968).

91. Identification of Constituents of OpuntiaFragilis Nutt., by means of Gas

Chromatography and Mass Spectrometry. With R. T. Coutts and E. E. Knaus,

PlantaMedica, 16, 147 (1968).

92. Aromatic Substitution, Part XVIII. Kinetics of Reactions Between some Halogeno-

pyridines and Picolines and their N-Oxides with Methoxide Ion in Methanol and in

Dimethyl Sulfoxide. Effect on Alkyl Groups on Rates and Orientation in Nucelophilic

Aromatic Substitution. With F. Helmer and M. Liveris, J. Chem. Soc. B., 492 (1968).

93. Aromatic Substitution, Part XIX. Arylation of Aromatic Compounds with

Benzenediazonium Tetrafluoroborate in Homogeneous Solution. With F. F. Gadallah, J.

Chem. Soc. B., 497 (1968).

94. Aromatic Substitution, Part XX. Homolytic Arylation of Aromatic Compounds with

Benzenediazonium Tetrafluoroborate and Pyridine in Homogeneous Solution. With O.

A. Koleoso, J. Chem. Soc. B., (1968).

95. Aromatic Substitution, Part XXI. Kinetics of Nucleophilic Substitution of some

Bromopyridines with Thiophenoxide Ion. Nature of Activation by ortho-Methyl Groups.

With F. Helmer and M. Liveris, J. Org. Chem., 34, 1730 (1968).

96. The Conversion of Azobenzenes to Phenazines: A New Molecular Rearrangement.

With B. A. Davis, J.Heterocyclic Chem., 5, 793 (1968).

97. 3,3-Dimethylindoline. With R. A. Brown, Org. Prep. & Proc., 1, 39 (1969).

98. Mechanism of the Reaction of Methanesulphonylnitrene with Benzene. With V.

Uma, Chem. Comm., 797 (1968).

99. Intramolecular Cyclization of Sulfonylnitrenes. With C. I. Azogu and I. T.

McMaster, J. Am. Chem. Soc., 91, 1219 (1969).

100. Aromatic Substitution by Alkyl Nitrenes. With E. P. Kyba, Chem. Comm., 265

(1969).

101. The Stereochemistry of Protonation of 2-Substituted Cyclohexyl Anions. With M.

M. Rogic', S. S. Singer, and M. Venkateswaran, J. Am. Chem. Soc., 91, 1571 (1969).

102. Aromatic Substitution, Part XXII. The Polarity of Aryl Radicals. With O. A.

Koleoso, J. Chem. Soc., B, 779 (1969).

103. The Reaction of o-Substituted Nitrobenzene Derivatives with Ferrous Oxalate.

With B. A. Davis and R. A. Brown, J. Chem. Soc. C., 1146 (1969).

104. Aromatic Substitution, Part XXIII. Reaction of Some 3-Substituted Pyridines with

Alkyl-lithium Compounds. With G. A. Poulton, J. Chem. Soc. B., 901, (1968).

105. Aromatic Substitution, Part XXIV. The Emmert Reaction. Effects of Substituents

on Orientation. With A. R. Vinutha, J. Chem. Soc.,C, 2104, (1969).

106. Aromatic Substitution, Part XXV. The Reaction of 3-Picoline with Some

Substituted Phenyl-lithium Derivatives. With C. S. Giam and G. A. Poulton, J. Chem.

Soc. C., 128 (1970).

107. Catalyzed Sodium Borohydride Reductions of Some Derivatives of Methyl ortho-

Nitrophenylpyruvate and Other Keto-esters. With R. T. Coutts, G. Mukherjee, and M. A.

Brewster, J. Chem. Soc. C., 2207 (1969).

108. A Direct Alkyl- and Arylamination of Heteroaromatic Nitrogen Compounds. With

G. M. Singer, J. Am. Chem. Soc., 91, 5672 (1969).

109. Synthesis of 1-Hydroxy-2-pyridinethiones, 1-Hydroxy-2-pyridones and

Halopyridine N-Oxides: Reactions of Lithiopyridine N-Oxides. With E. E. Knaus, J.

Heterocycl. Chem., 6, 989 (1969).

110. Aromatic Substitution by Sulfonyl Nitrenes. Singlet or Triplet Reactive

Intermediates. With G. M. Knaus and V. Uma, J. Am. Chem. Soc., 91, 7532 (1969).

111. Curtius-type Rearrangement of a Sulfonyl Azide. With W. D. Holcomb, Chem.

Comm., 1298 (1969).

112. A New Photochemical Source of Aryl Radicals. Photoisomerisation of

Methylbiphenyls. With T. Takaya, Chem. Comm., 1369 (1969).

113. A Novel Bridged Ferrocene Derivative. With C. I. Azogu and R. G. Sutherland,

Chem. Comm., 1439 (1969).

114. Polar Radicals in Aromatic Substitution, Intrascience Chemistry Reports, 3, 211

(1969).

115. Sulfonyl Nitrenes, Mechanisms of Reactions of Sulfur Compounds, 3, 1 (1968).

116. Intermolecular Substitution by Aryl Nitrenes. With E. F. V. Scriven, Chem.

Comm., 787 (1970).

117. Recent Aspects of the Chemistry of Sulphonyl Nitrenes. With R. G. Sutherland,

Fortsch. Chem. Forschung, 16 (1), 1 (1970).

118. The Alkaline Ferricyanide Oxidation of Pyridinium Salts. Effects of Substituents

and Mechanism. (Aromatic Substitution, Part XXVI). With A. R. Vinutha, J. Chem.

Soc. B., 131, (1971).

119. Photodecomposition of Alkyl Azides: Absence of Freedom of Choice and Non-

nitrene Mechanism. With E. P. Kyba, J. Am. Chem. Soc., 93, 1537 (1971).

120. Ferrocenyl Radical and Nitrene. Formation of Nitroferrocene with Oxygen. With

C. I. Azogu and R. G. Sutherland, Chem. Comm., 134 (1971).

121. The Thermolysis and Photolysis of Ferrocenyl Sulfonyl Azide. Evidence for a

Metal-Nitrene Complex in the Thermolysis. With C. I. Azogu and R. G. Sutherland,

Tetrahedron Lett., 1637 (1971).

122. Electron Impact Fragmentation of Organic Azides. Aryl Azides. With E. P. Kyba

and E. F. V. Scriven, J.Org.Chem., 36, 3796 (1971).

123. Alkyl, Aryl, and Sulfonyl Nitrenes. Chapter in Chem. Soc. Special Publ., #24, 323

(1970).

124. The Decomposition of Organic Azides. With E. P. Kyba. Chapter in "Chemistry of

the Azido Group," (S. Patai, ed.), John Wiley & Sons, 1971, pp. 221-330.

125. N-Aryloxypyridinium Salts and their Base-catalyzed Rearrangement. With S. Kato

and G. M. Singer, J. Am. Chem. Soc., 93, 3074 (1971).

126. 2,6-Dimethyl-4-[Mono- and Di-p-nitrobenzenesulfonylmethylene)-4H]-pyran.

With E. P. Kyba, Org. Prep. Proc. Int., 3, 127 (1971).

127. The Reaction of Quinoline-l-oxides with N-Phenylbenzimidoyl Chloride. With R.

B. Rogers, Tetrahedron Lett., 1951 (1971).

128. Process for Producing Certain Amide Derivatives of Pyridine and Reducing said

Amides to Corresponding Amines. With G. M. Singer, U.S. patent 3,624,096 (Nov 30,

1971).

129. On the Mechanism of Intermolecular Aromatic Substitution by Arylnitrenes. With

S. R. Challand and E. F. V. Scriven, J. Am. Chem. Soc., 94, 374 (1972).

130. Thermolysis of Organic and Organometallic Isocyanates. With R. G. Sutherland

and A. K. V. Unni, Tetrahedron Lett., 1065 (1972).

131. Intermolecular Aromatic Substitution by Aryl Nitrenes. With S. R. Challand and E.

F. V. Scriven, J. Org. Chem., 37, 2705 (1972).

132. The Direct Alkylation of Pyridine-l-Oxides. With E. M. Smith, E. E. Knaus, and

M. Saha, J. Org. Chem., 37, 1690, (1972).

133. The Reaction of Sulfonyl Azides with Pyridines and Fused Pyridine Derivatives.

With T. Takaya, J. Org. Chem., 37, 2022 (1972).

134. The Deoxygenation of Aliphatic Nitroso Compounds with Trialkyl Phosphites: The

Question of a Nitrene Intermediate. With J. Court and E. P. Kyba, Tetrahedron Lett.,

4059 (1972).

135. A Novel _β-Alkylation of Pyridine- and Quinoline-1-oxides. With G. Grins, R. B.

Rogers, J. L. Atwood, M. D. Williams, and C. Crider, J. Org. Chem., 57, 3383 (1972).

136. Reaction of Triplet Aryl Nitrenes and Azides with Molecular Oxygen. With S. R.

Challand, Chem. Comm., 964 (1972).

137. Stereochemistry of Nucleophilic Addition Reactions. The Addition of Thiophenol

and of Hydrogen Chloride to 4-tert-Butyl-1-cyanocyclohexene. With M. M. Rogic, S. S.

Singer, and N. Venkateswaran, J. Org. Chem., 37, 3571 (1972).

138. Intramolecular Cyclization of a Sulfonyl Carbene. With V. Alexanian and E. M.

Smith, Chem. Comm., 893 (1972).

139. The Direct Acylation of Pyridine-1-Oxides. With E. M. Smith and R. T. Coutts, J.

Org. Chem., 37, 3584 (1972).

140. Halogenation of Pyridine-1-oxides. With J. Campbell, E. E. Knaus and S.

Silhankova, J. Heterocycl. Chem., 9, 1367 (1972).

141. Nitrenes, in Organic Reactive Intermediates (S. McManus, Ed.) Academic Press,

1973, pp. 127-192.

142. The Addition of Aryl Nitrenes to Olefins. With S. R. Challand, J.C.S.,Chem.

Comm., 1160 (1972).

143. N-Hydroxypyrroles and Related Compounds. With B. W. Cue, Jr., J. Org. Chem.,

38, 173 (1973).

144. Properties and Reactions of Pyridines. With G. M. Singer, in "Pyridine and Its

Derivatives," (R. A. Abramovitch, ed.), Vol. 1, Interscience Publishers, Ch. 1, 1974.

145. Pyridine-1-oxides. With E. M. Smith, in "Pyridine and Its Derivatives," (R. A.

Abramovitch, ed.), Vol. 2, Interscience Publishers, Ch. IV, 1974, pp. 1-261.

146. Book Review: "Free Radical Substitution Reactions:" Bimolecular Homolytic

Substitutions (SH2 Reactions) at Saturated Multivalent Atoms, "by K. U. Ingold and B. P.

Roberts, Wiley-Interscience, 1971. J. Chem. Ed., 50, A415 (1973).

147. Book Review: "The Nitrile Oxides," by C. Grundmann and P. Grunanger, Springer

Verlag, 1972. Naturwissenschaften, 60, 163 (1973).

148. Editor of: "Pyridine and Its Derivatives," Vols. 1-4. Wiley-Interscience, 1974.

149. The Photolysis and Spectral Properties of Some N-Sulfonylmino Pyridinium

Ylides. With T. Takaya, J. Org. Chem., 38, 3311 (1973).

150. Pentafluoronitrosobenzene as a Source of Aryl Nitrene and as a Radical Trapping

Agent. Carbazolequinones. With S. R. Challand, J. Heterocycl. Chem., 10, 683 (1973).

151. Thermolysis of Aryloxypyridinium Salts. Possible Generation of Aryloxenium

Ions. With M. Inbasekaran and S. Kato, J. Am. Chem. Soc., 95, 5428 (1973).

152. Thermolysis of Tertiary Alkyl Azides. With E. P. Kyba, J. Am. Chem. Soc., 96,

480 (1974).

153. The β-Alkylation of Pyridine and Quinoline-1-oxides with Acetylenes: Studies of

the Mechanism. With I. Shinkai, J. C. S. ,Chem. Comm., 569 (1973).

154. Ring Contraction of 2-Azidoquinoline- and Quinoxaline-1-oxides. With B. W.

Cue, Jr., Heterocycles, 1, 227 (1973).

155. The Reaction of Methanesulfonyl Nitrene with Benzene. Attempts to Generate

Sulfonyl Nitrenes from Sources Other than the Azides. With T. D. Bailey, T. Takaya, &

V. Uma, J. Org. Chem., 39, 340 (1974).

156. The Reaction of Sulfonyl Azides with Tetracyclone. O- and N-Sulfonyl-2-

pyridones. With G. N. Knaus, J. C. S. Chem. Comm., 238 (1974).

157. The Reaction of Aromatic Substrates with Sulfonyl Nitrenes. With G. N. Knaus

and V. Uma, J. Org. Chem., 39, 1101 (1974).

158. The Direct Acylamination of Pyridine-1-oxides. With G. M. Singer, J. Org. Chem.,

39, 1795 (1974).

159. The Direct Acylamination of 3-Substituted Pyridine-1-oxides. Directive Effect of

the Substituents. With R. B. Rogers, J. Org. Chem., 39, 1802 (1974).

160. The Synthesis of (2H)-Pyrrole-1-oxides by Ring Contraction. With B. W. Cue, Jr.,

Heterocycles, 2, 297 (1974).

161. The Reaction of Benzene with Heteroaromatic N-oxides. Evidence for 2πs + 2πa +

4πs Rearrangements. With I. Shinkai, J. Am. Chem. Soc., 96, 5265 (1974).

162. The Decomposition of Sulfonyl Azides and tert-Butyl Azidoformate by Transition

Metal Carbonyls. With G. N. Knaus and (in part) R. W. Stowe, J. Org. Chem., 39, 2513

(1974).

163. Aromatic Substitution, XXVI. Kinetics of Nucleophilic Substitution of Some

Bromo-pyridines and -picolines with Methoxide, Thiomethoxide, Phenoxide, and

Thiophenoxide Ions. With A. J. Newman, Jr., J. Org. Chem., 39, 2690 (1974).

164. Decomposition of 2-Pyridyldiazomethane-1-Oxides. With C. S. Menon, M.

Murata, and E. M. Smith, J. C. S. ,Chem. Comm., 693 (1974).

165. Ratio of Seven- to Six-Membered Ring Sulfones in the Cyclization of a Sulfonyl

Carbene. With V. Alexanian, Heterocyles, 2, 595 (1974).

166. The Reaction of Sulfonyl Azides with Unstrained Olefins. With G. N. Knaus, M.

Pavlin, and W. D. Holcomb, J. Chem. Soc. Perkin I, 2169 (1974).

167. Aromatic Substitution, XXVII. Kinetics of Nucleophilic Substitution of some

Fluoropyridines and-picolines with Methoxide, Thiomethoxide and Thiophenoxide Ions.

With A. J. Newman, Jr. J. Org. Chem., 39, 3692 (1974).

168. 1,2-Benzisothiazole-1,1-dioxides. I. Synthetic Entry into 3-Alkyl- (or Aryl)-1,2-

Benzisothiazole-1,1-dioxides and Related Compounds. With Elizabeth M. Smith, B.

Purtschert, P. C. Srinivasan, and G. M. Singer, J. C. S. Perkin I, 2590 (1974).

169. Synthesis of Substituted Pyrido[1,2-b]indazoles. With J. Kalinowski, J. Heterocycl.

Chem., 11, 857 (1974).

170. The Stereochemistry of Nucleophilic Addition Reactions. The Addition of Diethyl

Malonate to Ethyl 4-tert-Butyl-1-cyclohexenecarboxylate. With S. S. Singer, J. Org.

Chem., 40, 34 (1975).

171. The Direct Acylamination of Quinoline-, Isoquinoline-, Benzimidazole-,

Pyridazine-, and Pyrimidine-1-oxides. A Novel 1,5-Sigmatropic Shift. With R. B.

Rogers and G. M. Singer, J. Org. Chem., 40, 41 (1975).

172. The Flash Vacuum Pyrolysis of Sulfonyl Azides. With W. D. Holcomb, J. Am.

Chem. Soc., 97, 676 (1975).

173. Thermal Decomposition of o- and p-Benzenedisulfonyl Azides in Benzene,

Cyclohexene, and Tetracyclone. With G. N. Knaus, J. Org. Chem., 40, 883 (1975).

174. Consecutive 3,5-Shifts in Pyridine 1-Oxide Rearrangements. One-step

Furopyridine Synthesis. With I. Shinkai, J. Am. Chem. Soc., 97, 3227 (1975).

175. The Addition of Aryl Nitrenes to Olefins. With S. R. Challand and Y. Yamada, J.

Org. Chem., 40, 1541 (1975).

176. The Direct Acylamination of Pyridine 1-Oxides. Effect of Substituents in N-

Phenylarylimidoyl Chloride. Trapping with Thiols. With P. Tomasik, J. Heterocycl.

Chem., 12, 501 (1975).

177. Process for the Synthesis of N-Hydroxypyrroles. With B. W. Cue, U.S. Patent 3,

886, 180 (1975).

178. 4-Nitrosoquinoline 1-Oxide. With E. M. Smith, J. Heterocycl. Chem., 12, 969

(1975).

179. The Direct Thionation and Aminoalkylation of Pyridine 1-Oxides and Related

Reactions. With E. E. Knaus, J. Heterocycl. Chem., 12, 683 (1975).

180. The Photolysis of N-Arylsulfonyldimethyl Sulphoximines in Aromatic Solvents.

Photoisomerisation of Methylbiphenyls. With T. Takaya, J. C. S. Perkin I, 1806 (1975).

181. Synthesis and Decomposition of Some Sulphamoyl Azides. With K. Miyashita, J.

C. S. Perkin I, 2413 (1975).

182. Decomposition of 3-Azidopyridazine 2-Oxides. Ring Opening of the Pyridazing

Ring. With I. Shinkai, J. C. S. ,Chem. Comm., 703 (1975).

183. Crystal Structure and Mossbauer Spectrum of [2]-Ferrocenophanethiazine 1,1-

Dioxide. With J. L. Atwood, M. L. Good, and B. A. Lampert, Inorg. Chem., 14, 3085

(1975).

184. Direct Side-chain Amination of Picoline 1-Oxides: A New Rearrangement. With

T. D. Bailey, J. Heterocycl. Chem., 12, 1079 (1975).

185. Reaction of Pyridine 1-Oxides and N-Iminopyridinium Ylides with Diazonium

Salts. N-Aryloxypyridinium Salts and Their Base-Catalyzed Rearrangement. With S.

Kato, M. Inbasekaran, and G. M. Singer, J. Org. Chem., 41, 1717 (1976).

186. Ring Contraction of 2-Azidopyridine 1-Oxides and Related Compounds. 2-Cyano-

1-hydroxypyrroles and -imidazoles. With B. W. Cue, Jr. J. Am. Chem. Soc., 98, 1478

(1976).

187. Aromatic Substitution via New Rearrangements of Heteroaromatic N-Oxides. With

I. Shinkai, Accounts Chem. Res., 9, 192 (1976).

188. Ferrocene-1,1'-disulfonyl Azide and 2,4,6-Trimethylpyridinium Ferrocenesulfonyl

Ylide. Synthesis and Decomposition. With W. D. Holcomb, J. Org. Chem., 41, 491

(1976).

189. Reaction of Pyridine 1-Oxides with Isocyanates: Structure of the Intermediates.

Rationalization of Rearrangements of Six-membered Heteroaromatic N-Oxide

Derivatives. With I. Shinkai and R. van Dahm, J. Heterocycl. Chem., 13, 171 (1976).

190. Derivatives of 2-Pyrazolin-5-one. IV. Preparation and Properties of Two

Spiro[benzothiazoline-2,4'-[2]pyrazoline] Derivatives. With R. T. Coutts, A.-M. M. K.

El-Hawari, and N. J. Pound. Can. J.Chem., 54, 993 (1976).

191. Stereochemistry of Nucleophilic Addition Reactions. The Addition of Thiophenol

to Ethyl 4-tert-Butylcyclohexene-1-carboxylate. With S. S. Singer, J. Org. Chem., 41,

1712 (1976).

192. The Alkylation of Pyridine 1-Oxides and Related Compounds with Activated

Acetylenes. A Novel Molecular Rearrangement of Heteroaromatic N-Oxides. With G.

Grins, R. B. Rogers, and I. Shinkai, J. Am. Chem. Soc., 98, 5671 (1976).

193. Generation and 1,3-Dipolar Behavior of Pyridinium Arylsulfonyl-methylides. A

Simple Route to Indolizines. With V. Alexanian, J. Org. Chem., 41, 2144 (1976).

194. A New Ring Transformation of 3-Halo-2-azidopyridine 1-Oxides. A Novel

Synthesis of 1,2-Oxazin-6-ones. With I. Shinkai, B. W. Cue, Jr., F. A. Ragan, and J. L.

Atwood, J. Heterocycl. Chem., 13, 415 (1976).

195. N-Alkoxydipyrrylmethenes. With V. Amarnath, R. Kress, and G. Molina, J.

Heterocycl. Chem., 13, 465 (1976).

196. Ring-expansion of 3-Bromoalkyl-1,2-benzixothiazole 1,1-Dioxides to (2H)-1,2-

Benzothiazin-4(3H)-one 1,1-Dioxides. With K. M. More, I. Shinkai, and P. C.

Srinivasan J. C. S.,Chem.Comm., 771 (1976).

197. A Simple Route to Indolizine-2-carboxylate. Cycloaddition Reactions of

Pyridinium Arylsulphonylmethylides. With S. S. Mathur, Heterocyles, 5, 91 (1976).

198. Ring Expansion of 3-Substituted 1,2-Benzoisothiazole 1,1-Dioxides to 1,2-

Benzothiazepine 1,1 Dioxides. With K. M. More, I. Shinkai, and P. C. Srinivasan,

Heterocycles, 5, 95 (1976).

199. Decomposition of 2-Azidosulphonylbenzophenones. Unusual Rearrangement

Products. With D. P. Vanderpool, J. C. S. ,Chem. Comm., 18 (1977).

200. Preparation and Novel Rearrangements of N-Aryloxypyridinium Salts. A 3,5-Shift

Leading to Pyridol[2,3-b]benzofurans. With M. N. Inbasekaran, Tetrahedron Lett., 1109

(1977).

201. Aryloxenium Ions from N-Aryloxypyridinium Salts and Aryloxyamine

Derivatives. With G. Alvernhe and M. N. Inbasekaran, Tetrahedron Lett., 1113 (1977).

202. Generation and Some Reactions of Benzenesulphonylcarbene. With V. Alexanian

and J. Roy, J. C. S. Perkin I, 1928 (1977).

203. Process for the Synthesis of N-Hydroxypyrroles, N-Hydroxyimidazoles, and

Derivatives Thereof. With B. W. Cue, Jr., U.S. Patent 4, 006, 160 (1977).

204. Intramolecular Cyclization of 2-Biarylsulfonyl Azides. With T. Chellathurai, I. T.

McMaster, T. Takaya, C. I. Azogu, and D. P. Vanderpool, J. Org. Chem., 42, 2914

(1977).

205. Intramolecular Insertion of Arylsulfonylnitrenes into Aliphatic Side-chains. With

T. Chellathurai, W. D. Holcomb, I. T. McMaster. and D. P. Vanderpool, J. Org. Chem.,

42, 2920 (1977).

206. Flash Vacuum Pyrolysis of 1,2-Benzoisothiazole 1,1-Dioxides. Benzoxazole and

Benzonitrile Formation. With S. Wake, J. C. S., Chem. Comm., 673 (1977).

207. Benzisoxazolo[2,3-a]pyridinium Tetrafluoroborates. Possible Generation of an

Aryloxenium Ion. With M. N. Inbasekaran, J. C. S. ,Chem. Comm., 149 (1978).

208. Neighboring Group Participation in the Conversion of β-Substituted

Ethanesulfonate Salts to β -Substituted Ethanesulfonyl Chlorides. With S. P. McManus,

M. R. Smith, and F. T. Herrmann, J. Org. Chem., 43, 647 (1978).

209. Intramolecular Cyclization of Diphenyl Ether, Benzophenone, and Related 2-

Sulfonylnitrenes. With C. I. Azogu, I. T. McMaster, and D. P. Vanderpool, J. Org.

Chem., 43, 1218 (1978).

210. The Reaction of 4-Chloroquinoline 1-Oxide with Activated Acetylenes. Furo-[3,2-

c]quinolines. With P. Canonne and G. Lemay, Heterocycles, 9, 1217 (1978).

211. The Azide Catalyzed Rearrangement of N-Aryloxypyridinium Salts. Facile

Synthesis of 3-o-Hydroxyphenylpyridines. With A. L. Miller, P. Tomasik, and T.

Radzikowska, J. Org. Chem., 44, 464 (1979).

212. Oxidation of Pyridines with Copper Sulfate. With P. Tomasik and A. Woszczyk, J.

Heterocycl. Chem., 16, 1283 (1979).

213. Flash Vacuum Pyrolysis of 3,5-Disubstituted β-Phenethylsulfonyl Azides. With S.

Wake, Heterocycles, 11, 377 (1979).

214. Addition of Enolates to Activated Acetylenes. C- versus O-Alkylation. With I.

Shinkai, Polish J. Sci., 53, 177 (1979).

215. Direct Side-chain Acylamination of 4-Picoline 1-Oxides and Related Compounds.

With D. A. Abramovitch and P. Tomasik, J. C. S. ,Chem. Comm., 956 (1979).

216. Photolysis of Alkyl Azides. Evidence for a Non-Nitrene Mechanism. With E. P.

Kyba, J. Am. Chem. Soc., 102, 735 (1980).

217. Pyridinium p-Toluenesulfonylmethylide as a Formyl Anion Equivalent. With S. S.

Mathur, D. W. Saunders, and D. P. Vanderpool, Tetrahedron Lett., 21, 705 (1980).

218. The Ring Contraction of 2-Azidoquinoline and Quinoxaline 2-Oxides. With B. W.

Cue, Jr., J. Org. Chem., 45, 5316-5319 (1980).

219. Amino- and Thiomethylenation of Maleimides. With L. Floch, Heterocycles, 15,

391 (1981).

220. The Decomposition of β-Phenethylsulfonyl Azides. Solution Chemistry and Flash

Vacuum Pyrolysis. With W. D. Holcomb and S. Wake, J. Am. Chem. Soc., 103, 1525

(1981).

221. Photolysis of 2-Azidopyridine 1-Oxides. A Convenient Synthesis of 1,2-Oxazines.

With C. Dupuy, J. C. S. ,Chem. Comm., 36 (1981).

222. The Reaction of Aromatic Sulfonyl Azides with Dienes. With S. P. McManus and

M. Ortiz, J. Org. Chem., 46, 330-385 (1981).

223. The Reaction of p-Nitrobenzenesulfonyl Azide with Alkylidenecycloalkanes. With

S. P. McManus and M. Ortiz, J. Org. Chem., 46, 336-342 (1981).

224. The Aryloxenium Ions. Generation from Aryloxypyridinium Tetrafluoroborates

and Reaction with Anisole and Benzonitrile. With G. Alvernhe, N. L. Dassanayake, M.

N. Inbasekaran, S. Kato, J. Am. Chem. Soc., 103, 4558 (1981).

225. Pyridine N-Sulphides. Some Simple N-Arylthiopyridinium Salts. A Possible

Source of Arylsulphenium Ions. With A. L. Miller and J. Pilski, J. C. S. ,Chem. Comm.,

703 (1981).

226. N,N-Diacylarylsulphenamides as an Unambiguous and Convenient Source of

Arylsulphenium Ions. With J. Pilski, J. C. S., Chem. Comm. , 704(1981).

227. The Mechanism of Direct Side-chain Acylamination and Aminoarylation of 2- and

4-Picoline 1-Oxides. With D. A. Abramovitch and P. Tomasik, J. C. S. ,Chem. Comm.,

561 (1981).

228. Pyrolysis of Phenylalkylsulphonyl Azides and 2-Phenethyl Azidoformate.

Selectivity of Sulphonylnitrenes and Contrast between Sulphonyl- and Carbonyl-

nitrenes. With S. B. Hendi and A. O. Kress, J. C. S. ,Chem. Comm., 1087-1088 (1981).

229. Pyridine N-Sulphides. Benzisothiazolo[2,3-a]pyridinium Tetrafluoroborates and

Benzothiopheno[3,2-b]pyridines. Novel Heterocyclic Systems. With M. N.

Inbasekaran, A. L. Miller, and J. M. Hanna, Jr., J. Heterocycl. Chem., 19, 509 (1982).

230. Intramolecular Cyclization of Aryloxenium Ions. C-O-C and C-C Bond

Formation. A Novel Ortho-effect. With R. Bartnik, M. Cooper, N. L. Dassanayake, H.-

Y. Hwang, M. N. Inbasekaran, G. Rusek, J. Org. Chem., 47, 4817 (1982).

231. Intramolecular Cyclization of Arylnitrenium Ions. Formation of Carbon-Carbon

Bonds and of Lactones. With M. Cooper, S. Iyer, R. Jeyaraman, J. A. R. Rodriguez, J.

Org. Chem., 47, 4819 (1982).

232. Base-Catalyzed Rearrangement of N-Aryloxypyridinium Salts. Effect of a 3-

Substituent in the Pyridine Ring Upon Orientation. Synthesis of Novel Tricyclic Rings.

With M. N. Inbasekaran, S. Kato, T. A. Radzikowska, and P. Tomasik, J. Org. Chem., 48,

680 (1983).

233. Heterocyclic Compounds, McGraw-Hill Encyclopedia of Science and Technology,

5th Edition, April 1982, pp. 570-572.

234. 1,2-Benzisothiazole 1,1-Dioxide: a Convenient Synthesis. The Question of the

Possible Aromaticity of 1,2-Benzothiazepine 1,1-Dioxides. With B. Mavunkel and J. R.

Stowers, J. C. S.,Chem. Comm., 520 (1983).

235. Friedlander Condensation of 1H-Pyrazole-5-ones with o-Aminobenzaldehydes.

Synthesis of 1H-Pyrazolo[3,4-b]quinolines. With D. Tomasik and P. Tomasik, J

Heterocycl. Chem. 20, 1539 (1983).

236. Book Review: "Heterocyclic Chemistry. Vol. 1 H. Suschitzky and O. Meth-Cohn,

The Royal Society of Chemistry, London, 1980. J. Am. Chem. Soc., 105, 2931 (1983).

237. Direct Acylamination of Pyridine 1-Oxide with N-Phenylareneimidoyl Chlorides

and Fluorides. With J. Pilski, A. Konitz, and P. Tomasik J. Org. Chem., 48, 4391-4393

(1983).

238. Book Review: "Reactivity in Organic Chemistry". Gerhard W. Klumpp, Wiley -

Interscience, 1982. AmericanScientist, 71, 413 (1983).

239. Thermolysis of Sulfonyl Azides Bearing Nucleophilic Neighboring Groups. A

Search for Anchimeric Assistance. With S. P. McManus, M. R. Smith, and M. N. Offor,

J.Org.Chem. 49, 683-687 (1984).

240. Book Review: "The Fisher Indole Synthesis." B. Robinson, Wiley Publishers

1983. J.Med.Chem., 1795 (1983).

241. The Uncatalyzed Cycloaddition of a Siloxydiene to N-Acylimines. The Synthesis

of 4-Pyridones. With J. R. Stowers, Heterocycles, 22, 671 (1984).

242. The Solution and Flash Vacuum Pyrolyses of 3-Arylpropanesulfonyl and 2-

Aryloxyethanesulfonyl Azides. Synthesis of 7-membered Sultams. With A. O. Kress, S.

P. McManus, and M R. Smith. J. Org. Chem., 49, 3114 (1984).

243. Nitrenium Ions in "Azides and Nitrenes" (E.F.V. Scriven, ed.). Academic Press,

Orlando, Ch. 6, pp. 297-357 (1984). With R. Jeyaraman.

244. Reactions of Aryloxenium Ions with Benzene, Phenol, and Aromatic Amines

Participation of Oxidative Processes. With R. Bartnik, J. Besse, and S. Kato.

Nouv.J.Chim. 8, 571 (1984).

245. The Solution and Flash Vacuum Pyrolysis of β-(3,5-Disubstituted

Phenethyl)sulfonyl Azides. Sultam, Pyrindine, Azepine Formation . With W. D.

Holcomb, W. M. Thompson, and S. Wake. J. Org. Chem., 49, 5124 (1984).

246. The Reaction of Saccharin Derivatives with N,N-Diethyl-1-propynamine:

Formation of Cyclobutenyl Saccharinates and of a Spiro-oxete. With C. H. Ooi, Han-Li

Sun, M. Pierrot, A. Baldy, and J. Estienne, J.C. S. ,Chem. Commun., 1583 (1984).

247. The Side-Chain Acylamination of Alicyclic Nitrones. A New Synthesis of an

Amino Acid. With D. A. Abramovitch and H. Benecke, Heterocycles, 23, 25 (1985).

248. Solution and Flash Vacuum Pyrolysis of some 2,6-Disubstituted β-

Phenethylsulfonyl Azides and of β-Styrenesulfonyl Azide. With A. O. Kress, K. S.

Pillay, and W. M. Thompson, J. Org. Chem. 50, 2066 (1985).

249. A Simple Synthesis of Conjugated Imine-α-Thio- and -Seleno-vinylamines. With

B. Mavunkel, J. R. Stowers, M. Wegrzyn, and C. Riche. J. C. S. ,Chem. Commun., 845

(1985).

250. Thermal and Photochemical Decomposition of 3- and 4-Azidopyridine-1-oxides in

Nucleophilic Solvents. With B. Bachowska and P. Tomasik, Polish J. Chem., 58, 805

(1984).

251. Ferrocenesulfonyl Azide. Structure and Kinetics of Solution Thermolysis. With S.

P. McManus, J. A. Knight, E. J. Meehan, M. N. Offor, J. L. Atwood, and W. E. Hunter,

J.Org.Chem. 1985, 50, 2742-2746.

252. Remote Intramolecular Functionalization of Arylnitrenium Ions. Seven-membered

Ring Formation. With R. Jeyaraman and K. Yannakopoulou, J. Chem. Soc., Chem.

Commun. 1985, 1107.

253. Remote Intramolecular Functionalization of Arylnitrenium Ions: Ipso Substitution

and Spiro-lactone Formation. With A. Hawi, J. A. R. Rodrigues, T. R. Trombetta, J.

Chem. Soc., Chem. Commun. 1986, 283.

254. Remote Intramolecular Functionalization of Arylnitrenium Ions: Synthesis of

Amino-Dihydrophenanthridines and Benzo[c]chromans. With M. M. Cooper, R.

Jeyaraman, G. Rusek, Tetrahedron Lett. 1986, 27, 3705.

255. A Novel [3,3]-Rearrangement of 1,2-Dihydro(N-arylamino)pyridines: Formation

of Unusual Fused Indolines. With A. C. Siani, G. Huttner, L. Zsolnai, J. Miller, J. Org.

Chem. 1986, 51, 4739.

256. Reaction of Pyridine 1-Oxide with Methyl Propiolate: A Pyrido-oxepine and Other

Novel Products. With D. Kishore, M. Konieczny, Z. Dauter, Heterocycles. 1987, 25, 13.

257. Regiospecific Amination of 3-Substituted Pyridines Using Imidoyl Chloride

Functionalized Polystyrene. With Y.-X. Wang, Heterocycles. 1987, 26, 2065.

258. Flash Vacuum Pyrolysis of α-Toluenesulfonyl Azide. With R. R. Harder, W. D.

Holcomb, Heterocycles. 1987, 26, 2327.

259. The Reaction of 4-Chloropyridine-1-Oxides With Activated Acetylenes. A

Convenient One Step Synthesis of Furo[3,2-c]pyridines. With A. Deeb, D. Kishore, G.

B. W. Mpango, and I. Shinkai, Gazzetta, 1988, 118, 167.

260. Thermolysis of 1-(N-Acetyl-N-arylamino)-2,4,6-triphenylpyridinium

Tetrafluoroborates: A New Source of Arylnitrenium Ions. With K. Evertz, G. Huttner,

H.H. Gibson, Jr., and H. G. Weems, J. Chem. Soc., Chem. Commun. 1988, 325.

261. Newer Methods of Arylation. With D. H. R. Barton and J.-P. Finet, Tetrahedron

Reports, 1988, 44, 3039.

262. Cyclization of Arylnitrenium Ions to Yield the Aporphine Ring System, and a

Remarkable Formation of a Sixteen-membered Ring by an Intramolecular Electrophilic

Aromatic Substitution. With P. Chinnasamy, K. Evertz, and G. Huttner, J. Chem. Soc.

Chem. Commun., 1989, 3.

263. Electrophilic Amination. Direct Primary Amination of Arenes Using Phthalimide

Derivatives. With J. M. Beckert, P. Chinnasamy, He Xiaohua, W.Pennington, and A. R.

Vinutha Sanjivamurthy, Heterocycles 1989, 28, 623-628.

264. Relationship of Conformational Effects in Phenyloxenium and Phenylnitrenium

Cations to Intramolecular Reactivites. Ab Initio Electronic Structures. With Yi Li and

K. N. Houk, J. Org. Chem. 1989, 54, 2911-2914.

265. Book Review: "Chemical Structure Software for Personal Computers", (D.C.

Meyer, et. al.,eds); American Chemical Society: Washington, D. C. 1988 J. Am. Chem.

Soc. 1989, 118, 7292.

266. 2-Azidoallylphosphonates: Synthesis and Applications to Formation of 4-Amino-2-

ethoxy-1,2-oxaphosphol-3-ene 2-oxides. With M. Konieczny, W. Pennington, S.

Kanamathareddy, and M. Vedachalam J. Chem. Soc., Chem. Commun. 1990, 269.

267. Application of Microwave Energy to Organic Synthesis: Improved Technology.

With D. A. Abramovitch, K. Iyanar, and T. Tamareselvy Tetrahedron Lett. 1991, 32,

5251.

268. 4-(1,2,4-Triazolyl) Cation: Possible Generation and Reactions. With J. M. Beckert

and W. Pennington J. Chem.Soc.,Perkin Commun. 1991, 1761.

269. Applications of Microwave Energy in Organic Chemistry. Org. Prep. Proc. Intern.

1991 ,23, 683.

270. A Novel Bridgehead Azocine. The End of a Controversy. With N. Martin, M.

Quinteiro, C. Seoane, A. Albert and F. Cano Tetrahedron 1992, 48, 1581-84.

271. Transition State Geometry in the Thermal Generation of Aryl- and Acyl-nitrenium

Ions. With Qing Shi and S. Olivella Heterocycles 1992, 33, 483.

272. Reactions of Copper(II)-β-Diketonates Under Free Radical Conditions. Diazonium

Salts as Aryl Radical Sources in the Arylation of beta-Diketones. With M.E. Lloris, J.

Marquet, and M.Moreno-Mañas Tetrahedron 1992, 48, 6909-6916.

273. Fischer Cyclizations by Microwave Heating. With A. Bulman Synlett. 1992, 795.

274. Reactivity of 4-Azido and 4-Amino-6-methyl-2-H-pyran-2-one. Preparation of 1-

(6-Methyl-2-oxopyran-4-yl)-1,2,3-triazoles and 5-Oxopyrano[4,3-b]pyridines. With R.

Malet, N. Serra, M.Moreno Mañas, and R. Pleixats J. Heterocycl. Chem. 1993, 30, 317.

275. Photolytic Generation of N-Acylnitrenium Ions Under Neutral Conditions: The

Synthesis of Polycyclic Lactams. With Qing Shi Heterocycles 1994, 37, 1463.

276 Organosolv Pulping Using a Microwave Oven. With K. Iyanar Holzforschung

1994, 48, 349-354.

277. Microwave-assisted Alkylation of Activated Methylene Groups. With Qing Shi

and D. Bogdal Synthetic Comm. 1995, 25, 1-8.

278. Attempted Generation and Structure of the 4-(1,2,4-Triazoyl) Cation. With H. H.

Gibson, Jr., T. Nguyen, S. Olivella, and A. Solé Tetrahedron Lett. 1994,35,2321.

279. Macrocycle Formation via Arylnitrenium Ions: Intramolecular Recognition. With

Qing Shi Heterocycles 1994, 38, 2147.

280. Decomposition of 4-Bromobiphenyl in Soil Mediated by Microwave Energy. With

Huang Bang-Zhou. Chemosphere 1994, 29, 2517-2521.

281. Reductions of 3-(N-Arylaminomethylene)succinimides. With Andrew V.

Chapman, Heterocycles 1995, 40, 89-92.

282. Synthesis of Cularine amd Sarcocapnine via Enium Ions and a New, Highly

Diastereoselective Reductive Methylation. With J. D. F. de Sousa and J.A. R. Rodrigues

J. Am.Chem. Soc. 1994, 116, 9745.

283. In Situ Remediation of Soils Contaminated with Solvents and Chlorinated

Aromatics Using Microwave Energy. With Huang BangZhou and D. A. Abramovitch,

Pollution Prevention in South Carolina,1996, III (4), 28.

284. New Ring Systems From 1,2-Benzisothiazole-1,1-dioxides and Related

Compounds. With I. Shinkai, B. J. Mavunkel, S. O’Connor, G. H. Ooi, W. T.

Pennington, P. C. Srinivasan, and J. B. Stowers, Tetrahedron, 1996, 52, 3339-3354.

285. Decomposition of PCBs and Other Polychlorinated Aromatics in Soil Using

Microwave Energy. With Huang Bang-Zhou. Chemosphere 1998, 37, 1427-1436.

286. In Situ Decomposition of PCBs in Soil Using Microwave Energy. With Huang

Bang- Zhou, Abramovitch, D. A., and Song Jiaogao. Chemosphere 1999, 38, 2227-

2237.

287. In Situ Decomposition of PAHs in Soil and Desorption of Organic Solvents

Using Microwave Energy. With Huang Bang-Zhou, Abramovitch, D. A., and Song

Jiaogao. Chemosphere 1999, 39, 81-87.

288. Intramolecular Cyclizations via Arylnitrenium Ions. Formation of a Six-membered

Ring Rather than a Macrocycle. With Xiaocong Ye. J. Org. Chem. 1999, 64, 5904-5912.

289. Synthesis of Thiamacrocycles and Conformational Studies on their Precusors. With

Xiaocong Ye, W. T. Pennington, G. Schiemek, and D. Bogdal. J. Org. Chem. 2000, 65,

343-351.

290. The 1,2,4-Triazolyl Cation: Thermolytic and Photolytic Studies. With J. M.

Beckert, H. H. Gibson, Jr., A. Belcher, G. Hundt, T. Sierra, S. Olivella, W. T.

Pennington, and A. Sole. J. Org. Chem. 2001, 66, 1242-1251.

291. Remediation of Waters Contaminated with Pentachlorophenol. With Michael

Capracotta. Chemosphere 2003, 50, 955-957.

292. In Situ Remediation of Soils Contaminated with Toxic Metal Ions Using Microwave

Energy. With Lu Changing, E. Hicks, and J. Sinard Chemosphere 2003, 53, 1077-1085.

293. The Formation of Medium-Sized Rings by the Intramolecular Cyclization of

Arylnitrenium Ions. With Joseph Miller and Antonio J. C. de Souza. Tetrahedron Lett.

2003, 44, 6965-6967.

294. Diastereoselective Synthesis of Cularine Alkaloids via Enium Ions and an Easy

Entry to Isoquinolines by Aza-Wittig Electrocyclic Ring Closure. With J. A. R.

Rodrigues, J.D.F. de Sousa, and G. C. Leiva. J. Org, Chem. 2004, 69, 2920-2928.

295. Intramolecular Cyclization of Ethyl ω-(Azidophenyl) 2-phenylalkanoates. The

formation of Medium-sized Rings. With A. P. Rauter and Orlando da Silva Pinto. J.

Org, Chem. In preparation 2005.

Books Published

Pyridine and Its Derivatives. A Supplement.

Part 1, Interscience Publishers, New York, 1974.

Pyridine and Its Derivatives. A Supplement.

Part 2, Interscience Publishers, New York, 1974.

Pyridine and Its Derivatives. A Supplement.

Part 3, Interscience Publishers, New York, 1974.

Pyridine and Its Derivatives. A Supplement.

Part 4, Interscience Publishers, New York, 1975.

Reactive Intermediates. Vol. 1

Plenum Publishing Corp., 1980.

Reactive Intermediates. Vol. 2 Reactive Intermediates. Vol. 3