ECOSYS CHLORINE DIOXIDE PRESENTASI

8/18/2019 ECOSYS CHLORINE DIOXIDE PRESENTASI

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Different States Approved of Legal Provisions on Chlorine Dioxide

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References!

EPA – National Primary Drinking Water Regulation: Disinfectants and DisinfectionByproducts; Final Rule. 1998

!

US EPA Chapt 4 – Alternative Disinfectants and Oxidants Guidance Manual. 1999

!

WHO – Guidelines for Drinking-water Quality. Fourth Ed., 2011

!

American Biological Safety Association (ABSA) – Chlorine Dioxide Gas Decontaminationof Large Animal Hosppital Intensive and Neonatal Care Units. 2006

!

The Building Services Research and Information Association (BSRIA) – Chlorine DioxideWater Treatment, for hot and cold water services. 1997

!

Chlorine Chemical Council – Comparing Clorine Disinfection Methods, Douglas Smorol

!

Applied Microbial and Cell Physiology – Measurement of Chlorine Dioxide Penetration in

Dairy Process Pipe Biofilms During Disinfection. 2005

! Jornal Diary Scientific – Corrosivity of Chlorine Dioxide Used as Sanitizer in

Ultrafiltration Systems. 1991

! etc

.


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FDA REGULATION

! Chlorine Dioxide is a DIRECT foodadditive permitted for human

consumption

! Max 3ppm residual chlorine dioxide asan antimicrobial agent in water used

in poultry processing and to washfruits and vegetables


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SPECTRUM OF CHLORINE DIOXIDE

! Bakteri: Bacillus cereus, Bacillus circulans, Bacillus subtilis, Bifidobacterium animalis, Campylobacter jejuni,

Clostridium difficile, Clostridium perfringens, Corynebacterium parvum, Enterobacter cloacae,

Enterobacter hafnia, Eschericia coli, E. coli O157:H7, Flavobacterium sp., Fusobacterium nucleatum,

Klebsiella pneumonia, Listeria monocytogenes, methicillin-resistance Staphylococcus aureus (MRSA),

Mycobacterium bovis (TB), Mycobacterium smegmatis, Mycobacterium kansasii, Pseudomonas

aeroginosa, Pseudomonas sp., Salmonella choleraesuis, Salmonella enteridis, Salmonella typhi,

Salmonella typhimurium, Salmonella typhosa, Sarcina lutea, Staphylococcus aureus, Staphylococcus

epidermidis, Streptococcus faecalis, Streptococcus pyogenes, Yersinia enterocolitica, vancomycin-resistance Enterococcus faecalis (VRE), dll.

! Virus: Adenovirus, Bluetongue virus, Canine Parvovirus, Coxsackievirus, Corona virus, Encephalomyocarditis

(EMS), Echovirus, Feline calicivirus, Feline parvovirus, Hepatitis A virus, Herpes virus I, Herpes virus II,

Human Immunodeficiency Virus Type 1 (HIV-1), Influenza-A virus, Iridovirus, Mouse virus, Mouse hepatitis

virus, Minute virus of Mice (MVM), Mouse encephalomyelitis virus, Mouse polio virus (MEV), Newcastle

disease virus, Norovirus, Parainfluenza, Pertiviries - Togaviridae, Poliovirus-1, Rotavirus, Rhinovirus type

37, Vaccinia virus, Vesicular stomatitis virus, dll.

! Fungus: Aspergillus flavus, Aspergillus niger, Candida albicans, Fonsecaea pedrosoi, Fusarium sp., Mucor sp.,

Scopulariosis sp., Trichophyton rubrum, Trichophyton mentagrophytes, Sachromyces cerevisiae, dll.


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Safety of ECOSYS ClO2

◆ Tidak menghasilkan THMs, HAAs dan senyawa

lain yang bersifat sebagai senyawa carcinogenic atau

estrogenic.

◆Tidak merusak dan korosif terhadap barang,

filters, peralatan, pompa, pipa air。

◆Tidak menghasilkan residu


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Definisi dari ClO2 Generating Material

Solid ClO2 Generating Material ：

!

Tablet/Powder CLO2 bila dimasukan kedalam air, maka tablet akan

larut dan akan menghasilkan larutan Chlorine Dioksida. Atau bila

tablet/powder mengabsorsi air di udara, maka gas Chlorine Diokside

akan keluar ke udara.

Liquid ClO2 Generating Material：

!

Chlorine dioxide dalam bentuk larutan, adalah gas ClO2 yang diikat

oleh senyawa kimia yang stabil.

!


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A

Good ClO2 Product Must be:

1

、

High quantity of ClO2 Generating

！

Test Mthod: DPD Method

2

、

High purity of ClO2 produced

No or little Cl

2

, chlorite salt and chlorate salt

produced

Test Mthod: Five-Step Iodometry or Ionchromatography

3

、

Long shielf LifeTest Method: Accelerated Stability Test

4

、

Generated solution clear and no sediment

Test Method: Eye

5

、

Using simply


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ClO2 Tablet from Ecosys

◆Tablet Features：

★High ClO2

#Generating : ≥10$；

★High purity : ≥95$；

★Dissolve quickly : "5 min

★Using simplely : Add to water directly without limit of

water quantity

★Low heavy metals : Pb%10.0 mg/kg、As≤0.25 mg/kg

（can be used for drinking water）

★High stability : Accelerated Stability Test: 54℃ ；14 days。


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E

&

ect on killing pathogenic microbes in water

! On bacteria： 1.0 ppm of ClO2 can kill Staphyloccocus aureus (100%)

Bacillaceae(99.999%), E.coli (99.9999%) in the water

! On virus： Lab test show: 1.0 ppm of ClO2 can 100% kill Herpesviruses includingMarek's disease virus, Laryngotracheitis virus, Pseudorabies virus、

Bovine mastitis virus and adenovirus including body hepatitis and Eggdrop syndrome, and influenza virus (I, II, III) for 30 min

! On algae： 1.0 ppm of ClO2 can kill algaes in ponds


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Sebagai Desinfektan! Chlorine Diokside ada dalam air sebagai ClO2 yang dapat

masuk/menyerap melalui membran sel bakteri danmenghancurkan sel-sel bakteri (Junli et. Al, 1977b).

! Pada virus akan masuk/menyerap ke mantel protein kapsid

virus dan bereaksi dengan RNA virus. Akibatnya, kemampuangenetik dari virus rusak (Junli et. Al, 1977a).

! Dibandingkan dengan Chlorine, Chlorine Diokside dapat lebihefektif sebagai desinfektan karena fakta bahwa Chlorine

dalam air sebagai HOCl atau OCl- sama dengan dinding selbakteri adalah bermuatan negatif, sehingga akan salingmenolak, yang menyebabkan kurangnya penetrasi danpenyerapan disinfektan ke dalam membran.


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Mechanisme:

Proteíns ClO2 Membran

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tidak ada yang resisten

O2 ClO2


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MALARIA

! O2! CO2

! AFINITAS

ClO2

KILLING

RED OX

MALARIA


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Environment Disinfection

：

Kill rate to E.coli in air（$）

Concentration

(ppm)Sample method

Contact time (min)

2 7 12 20

>?

Sedimentation

43.5% 65.07% 69.69% 90.792%

50 67.35% 92.03% 99.53% 100.00%

Disinfection method：Spray


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Kill rate to Staphyloccocus aureus in air （$）

Concentration(ppm) Sample method

Contact time (min)

2 7

12 20

20ppm Sedimentation

38.65% 64.73% 85.46% 97.72%

50ppm 52.30% 94.57% 99.58% 100.00%

Disinfection method：Spray


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Result of microbe test in water with no treatment：

Sample site Total plate count of

bacteria (Cfu/ml)

Total E.coli (MPN/

100ml)

Thermotoletant

E.coli (MPN/100ml)

Water source 10 0 0

Near water source 2000 2 0

Middle water source 2400 2 0

Far water source 3000 5 5

Result of microbe test in water with 1 ppm of ClO2 treatmentproduced by ECOSYS Tab :

Sample site Total plate count of bacteria (Cfu/ml)

Total E.coli (MPN/100ml) Thermotoletant E.coli(MPN/100ml)

Water source 0 0 0

Near water source 0 0 0

Middle water source 0 0 0

Far water source 2 0 0


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Water pipe with 20 ppm of ClO2 treatmentproduced by ECOSYS Tab for 1 hour


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Only Chlorine Dioxide disinfectioncan remove the biofilm bypenetrating it and oxidizing it.

Chlorine Dioxide uses the power of

the 2 Oxygen molecules tocompletely destroy the cellmembrane and nucleus.

The oxidising process is so strong,that resistance cannot build up.


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Result of water treatment by ClO2 '1 ppm(

：

No. Item Unit Standard Before treat After treat

1 chroma !15 20 5

2 turbidity !5 6.5 0.29

3 PH 6.5-8.5 6.96 6.79

4 Fe mg/L !0.3 0.45 0.05

5 Mn mg/L !0.1 0.15 0.07

6 As mg/L !0.01 0.001 0.001

7 Cd mg/L !0.005 0.0002 0.0002

8 Cr mg/L !0.05 0.001 0.001

9 Pb mg/L !0.01 0.0002 0.0002

10 Hg mg/L !0.001 0.0001 0.0001

Total metal mg/L!0.076 0.0025 0.0027


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Usos

70% ClO-

30% Cl- & ClO2ClO3-

0,5-1%ClO2(aq)


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@K)-. %7 RJS T,/ .% C('4,$/

NH3 Gas (ppm) Symptom

10ppm No

20ppmResult in Respiratory Tract Infection and other disease

50ppmDecline animal production capability，exposed long time

to lead Respiratory Tract Infection and Pneumonia >80ppm

Result in Sneezeing, Salivation, Anorexia, also

convulsions


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NH3 Gas in animal house treat by ECOSYS ClO2


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THE CLO2 COMPARES WITH OTHER DISINFECTANT

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COMPARISON WITH OTHER BIOCIDAL AGENT

.

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OXIDIZING VALUES - CORROSIVE


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CORROSIVITY OF CHLORINE DIOXIDE

.


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CORROSIVITY OF CHLORINE DIOXIDE

.

From: British Stainless Stell Association

ADVANTAGES THAT CHLORINE DIOXIDE TREATMENTS


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ADVANTAGES THAT CHLORINE DIOXIDE TREATMENTSHAVE OVER CHLORINE BASED SYSTEMS

CHLORINE

Does not remove biofilm

Produces unwanted by-products including carcinogent

Is corrosive and unpleasant to handle

Already Banned in certain parts of Europe and the USA

Is pH dependent and very ineffective above pH 7

Is ineffective against complex organisms (e.g: Cysts &Protozoa)

Limited oxidative effect against various chemicalcontaminants. Forms chlorinated phenols

Neutralisation required before dumping to the foul drain

Can not be used at temperatures above 40oC due to therelease of chlorine gas

Increased disinfection time and more service workrequired to combat high bug counts

CHLORINE DIOXIDE

Will remove biofilm and thus clean tanks and pipes

Does not form chlorinated by-products

Is much less corrosive than chlorine. Does not hydrolyseto form an acid

Is rapidly replacing chlorine in many of these areas

Is not pH dependent (


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Documents

ECOSYS CHLORINE DIOXIDE PRESENTASI