7
2BeO + CCl4(g) = 2BeCl2(g) + CO2(g) T deltaH deltaS deltaG K Log(K) C kJ J/K kJ 0 197.622 376.6 94.754 7.56E-19 -18.121 50 197.887 377.513 75.894 5.39E-13 -12.269 100 197.728 377.067 57.025 1.04E-08 -7.983 150 197.275 375.935 38.198 1.93E-05 -4.716 200 196.61 374.453 19.437 7.15E-03 -2.146 250 195.784 372.796 0.756 8.41E-01 -0.075 300 194.834 371.063 -17.841 4.23E+01 1.626 350 193.785 369.31 -36.35 1.12E+03 3.047 400 192.658 367.571 -54.772 1.78E+04 4.251 450 191.469 365.867 -73.108 1.91E+05 5.281 500 190.23 364.211 -91.36 1.49E+06 6.173 550 188.954 362.612 -109.53 8.93E+06 6.951 600 187.647 361.071 -127.622 4.32E+07 7.635 650 186.317 359.59 -145.638 1.74E+08 8.241 700 184.977 358.176 -163.582 6.04E+08 8.781 750 183.633 356.829 -181.457 1.84E+09 9.265 800 182.292 355.549 -199.266 5.01E+09 9.7 850 180.953 354.33 -217.013 1.24E+10 10.094 900 179.611 353.161 -234.7 2.82E+10 10.451 950 178.263 352.036 -252.33 5.98E+10 10.777 1000 176.901 350.945 -269.904 1.19E+11 11.075 1050 175.518 349.879 -287.425 2.23E+11 11.348 1100 174.109 348.834 -304.892 3.97E+11 11.599 1150 172.67 347.804 -322.308 6.77E+11 11.831 1200 171.197 346.787 -339.673 1.11E+12 12.045 1250 169.688 345.78 -356.987 1.75E+12 12.243 1300 168.141 344.781 -374.251 2.68E+12 12.428 1350 166.555 343.789 -391.465 3.97E+12 12.599 1400 164.929 342.802 -408.63 5.73E+12 12.758 1450 163.262 341.821 -425.746 8.07E+12 12.907 1500 161.555 340.844 -442.812 1.11E+13 13.046 1550 159.807 339.872 -459.83 1.50E+13 13.176 1600 158.019 338.904 -476.799 1.98E+13 13.297 1650 156.191 337.941 -493.721 2.58E+13 13.411 1700 154.325 336.983 -510.594 3.30E+13 13.518 1750 152.421 336.03 -527.419 4.15E+13 13.618 1800 150.479 335.082 -544.197 5.16E+13 13.713 1850 148.503 334.14 -560.927 6.33E+13 13.801 1900 146.492 333.204 -577.611 7.67E+13 13.885 1950 144.449 332.275 -594.248 9.19E+13 13.963 2000 142.374 331.352 -610.839 1.09E+14 14.038

Ellingham. Problema 5

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Page 1: Ellingham. Problema 5

2BeO + CCl4(g) = 2BeCl2(g) + CO2(g)T deltaH deltaS deltaG K Log(K)C kJ J/K kJ

0 197.622 376.6 94.754 7.56E-19 -18.12150 197.887 377.513 75.894 5.39E-13 -12.269

100 197.728 377.067 57.025 1.04E-08 -7.983150 197.275 375.935 38.198 1.93E-05 -4.716200 196.61 374.453 19.437 7.15E-03 -2.146250 195.784 372.796 0.756 8.41E-01 -0.075300 194.834 371.063 -17.841 4.23E+01 1.626350 193.785 369.31 -36.35 1.12E+03 3.047400 192.658 367.571 -54.772 1.78E+04 4.251450 191.469 365.867 -73.108 1.91E+05 5.281500 190.23 364.211 -91.36 1.49E+06 6.173550 188.954 362.612 -109.53 8.93E+06 6.951600 187.647 361.071 -127.622 4.32E+07 7.635650 186.317 359.59 -145.638 1.74E+08 8.241700 184.977 358.176 -163.582 6.04E+08 8.781750 183.633 356.829 -181.457 1.84E+09 9.265800 182.292 355.549 -199.266 5.01E+09 9.7850 180.953 354.33 -217.013 1.24E+10 10.094900 179.611 353.161 -234.7 2.82E+10 10.451950 178.263 352.036 -252.33 5.98E+10 10.777

1000 176.901 350.945 -269.904 1.19E+11 11.0751050 175.518 349.879 -287.425 2.23E+11 11.3481100 174.109 348.834 -304.892 3.97E+11 11.5991150 172.67 347.804 -322.308 6.77E+11 11.8311200 171.197 346.787 -339.673 1.11E+12 12.0451250 169.688 345.78 -356.987 1.75E+12 12.2431300 168.141 344.781 -374.251 2.68E+12 12.4281350 166.555 343.789 -391.465 3.97E+12 12.5991400 164.929 342.802 -408.63 5.73E+12 12.7581450 163.262 341.821 -425.746 8.07E+12 12.9071500 161.555 340.844 -442.812 1.11E+13 13.0461550 159.807 339.872 -459.83 1.50E+13 13.1761600 158.019 338.904 -476.799 1.98E+13 13.2971650 156.191 337.941 -493.721 2.58E+13 13.4111700 154.325 336.983 -510.594 3.30E+13 13.5181750 152.421 336.03 -527.419 4.15E+13 13.6181800 150.479 335.082 -544.197 5.16E+13 13.7131850 148.503 334.14 -560.927 6.33E+13 13.8011900 146.492 333.204 -577.611 7.67E+13 13.8851950 144.449 332.275 -594.248 9.19E+13 13.9632000 142.374 331.352 -610.839 1.09E+14 14.038

Formula FM Conc. Amount Amount Volumeg/mol wt-% mol g l or ml

Page 2: Ellingham. Problema 5

BeO 25.012 24.54 2 50.023 16.619 mlCCl4(g) 153.823 75.46 1 153.823 22.414 l

g/mol wt-% mol g l or mlBeCl2(g) 79.918 78.41 2 159.836 44.827 lCO2(g) 44.01 21.59 1 44.01 22.414 l

Page 3: Ellingham. Problema 5

2BeO + 2Cl2(g) + C = 2BeCl2(g) + CO2(g)T deltaH deltaS deltaG K Log(K)C kJ J/K kJ

0 101.829 233.485 38.052 5.28E-08 -7.27750 102.46 235.634 26.315 5.57E-05 -4.254

100 102.701 236.336 14.512 9.30E-03 -2.032150 102.688 236.31 2.694 4.65E-01 -0.333200 102.483 235.855 -9.112 1.01E+01 1.006250 102.125 235.139 -20.888 1.22E+02 2.086300 101.645 234.264 -32.623 9.41E+02 2.973350 101.066 233.296 -44.312 5.19E+03 3.715400 100.404 232.275 -55.952 2.20E+04 4.342450 99.675 231.231 -67.54 7.57E+04 4.879500 98.89 230.181 -79.075 2.20E+05 5.343550 98.059 229.14 -90.558 5.59E+05 5.747600 97.19 228.115 -101.989 1.26E+06 6.102650 96.289 227.112 -113.37 2.60E+06 6.415700 95.368 226.141 -124.701 4.94E+06 6.694750 94.435 225.206 -135.984 8.77E+06 6.943800 93.496 224.31 -147.222 1.47E+07 7.167850 92.551 223.449 -158.416 2.33E+07 7.368900 91.594 222.615 -169.567 3.55E+07 7.551950 90.623 221.805 -180.678 5.21E+07 7.716

1000 89.63 221.009 -191.748 7.37E+07 7.8681050 88.609 220.223 -202.779 1.01E+08 8.0061100 87.556 219.442 -213.771 1.36E+08 8.1331150 86.464 218.661 -224.723 1.77E+08 8.2491200 85.333 217.88 -235.637 2.27E+08 8.3561250 84.16 217.097 -246.511 2.85E+08 8.4551300 82.943 216.31 -257.346 3.51E+08 8.5461350 81.68 215.52 -268.142 4.26E+08 8.631400 80.37 214.726 -278.898 5.10E+08 8.7081450 79.013 213.927 -289.615 6.03E+08 8.781500 77.608 213.123 -300.291 7.03E+08 8.8471550 76.155 212.315 -310.927 8.11E+08 8.9091600 74.653 211.502 -321.522 9.26E+08 8.9671650 73.104 210.686 -332.077 1.05E+09 9.021700 71.506 209.866 -342.591 1.18E+09 9.071750 69.861 209.043 -353.064 1.31E+09 9.1161800 68.17 208.217 -363.495 1.44E+09 9.1591850 66.432 207.389 -373.885 1.58E+09 9.1991900 64.65 206.559 -384.234 1.72E+09 9.2361950 62.823 205.728 -394.541 1.87E+09 9.2712000 60.954 204.896 -404.807 2.01E+09 9.303

Formula FM Conc. Amount Amount Volumeg/mol wt-% mol g l or ml

0 500 1000 1500 2000 2500

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Page 4: Ellingham. Problema 5

BeO 25.012 24.54 2 50.023 16.619 mlCl2(g) 70.906 69.568 2 141.812 44.827 lC 12.011 5.892 1 12.011 4.584 ml

g/mol wt-% mol g l or mlBeCl2(g) 79.918 78.41 2 159.836 44.827 lCO2(g) 44.01 21.59 1 44.01 22.414 l

Page 5: Ellingham. Problema 5

0 500 1000 1500 2000 2500

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