operacionesEQUILIBRIO DE FASES LIQUIDO VAPOR DEL ETANOL Y EL AGUAETANOL(1)AGUA(2)TC513.9647.3PC61.4221.2Tb351.4373.2VpA-8.51838-7.76451VpB0.341631.45838Patm1.01325VpC-5.73683-2.7758PHI1VpD8.32581-1.23303ESPECIFICACIONES DEL GRUPO UNIFACMOLECULAsub grupokRkQkvk1(etanol)vk2(aguaETANOLCH310.90110.84810CH220.67440.5410OH311.210AGUAH2O40.921.401PARAMETROS DE INTERACCION BINARIA aijaijCH3CH2OHH2OCH300986.51318CH200986.51318OH156.4156.40353.5H2O300300-229.100x1x2TOCTKr1r2Rq1q2QO1O2O3O4T11T21T31T41T12T22T32T42T13T23T33T43T14T24T34T44S11S21S31S41S12S22S32S42N1N2N3N4lnK1K1lnK2K2alfa1ln(Pvp/Pc)Pvpalfa2ln(pvp/pc)Pvpy1y2y1+y210199.9852988861373.13529888612.57550.920.922.5881.41.40001110.65760494880.447536174110.65760494880.4475361740.07108967840.071089678411.8477827430.0292396150.0292396150.38775656912.17712593852.17712593851.29867247360.50589246830.62655064360.62655064362.58689584021.40.62655064360.62655064362.58689584021.41.90977158036.751546436010.273914577-3.30362974082.25642137150.4235512145-5.38590339381.013250901101.00000088931.000000889320.050.9589.3783281576362.52832815762.57550.921.0027752.5881.41.45940.050.050.050.95110.64958955960.4371313579110.64958955960.43713135790.06579794580.065797945811.88127664930.02636868990.02636868990.377156064412.16750747162.16750747161.29132754870.48918701890.61198390110.61198390112.63378730911.40.68976007960.68976007962.56666432111.35445935091.52491431024.59474982940.00986303811.00991183820.2945547224-3.67950480181.54945775370.4399376979-5.77728028080.68508455450.35131363190.648686160.999999791930.10.985.7542604474358.90426044742.57550.921.085552.5881.41.51880.10.10.10.9110.64676594180.4334939187110.64676594180.43349391870.06401461370.064014613711.89331979360.02541823290.02541823290.373460762312.16411913012.16411913011.28885228380.4834334220.60689148620.60689148622.6506477111.40.76261425060.76261425062.51446816831.30834334221.21884402243.38327448280.03466089741.0352685870.3016068098-3.81410320611.35432967770.445536443-5.91707544370.59570590960.45221505450.54778589071.000000945240.150.8584.0340879998357.18408799982.57550.921.1683252.5881.41.57820.150.150.150.85110.64541003590.4317523857110.64541003590.43175238570.06317281890.063172818911.89914911560.02497265120.02497265120.371693479412.16249204312.16249204311.28768387270.48069421520.604453340.604453342.65880876191.40.83815914550.83815914552.45314002851.26210413230.97789011622.65884047520.06901032871.07144727570.3049541-3.87914282241.26904799960.4481939008-5.98456566140.5568282740.49951090840.50048883950.999999747950.20.883.0068964129356.15689641292.57550.921.25112.5881.41.63760.20.20.20.8110.64459548870.4307077904110.64459548870.43070779040.06267161230.062671612311.90266556130.02470829520.02470829520.370634048412.16151458652.16151458651.28698819790.47905597180.60299090650.60299090652.66373178581.40.91469564250.91469564252.38838306821.21581119440.78688252282.19653808410.10943313791.1156454740.3069529161-3.91834113571.22026579460.4497807873-6.02522271240.53464332170.52906198680.47093799330.999999980160.250.7582.2708615371355.42086153712.57550.921.3338752.5881.41.6970.250.250.250.75110.64400956560.4299571371110.64400956560.42995713710.06231315530.062313155311.90520180480.02451966580.02451966580.36987301712.16081147872.16081147871.28649065950.47788091660.6019399920.6019399922.66728252681.40.99165786370.99165786372.322084561.16947022910.63416416581.88544556290.15367185741.16610817420.3083851692-3.94659606781.18626980630.4509178719-6.05452086340.51920650030.55184977610.44815021770.999999993870.30.781.6698231287354.81982312872.57550.921.416652.5881.41.75640.30.30.30.7110.6435297010.4293428274110.6435297010.42934282740.06202086950.062020869511.90728320040.02436612710.02436612710.369250390312.16023564122.16023564121.28608496680.47692065280.60107995830.60107995832.67019648061.41.06882666321.06882666322.25496302651.12307619580.51111159421.66714335230.20024736311.22170492550.3095547322-3.96977309151.15909177250.4518464033-6.07854854410.50687985570.57213090840.42781182480.999942733280.350.6581.1427008945354.29270089452.57550.921.4994252.5881.41.81580.350.350.350.65110.64310780620.4288030762110.64310780620.42880307620.06176484690.061764846911.90911631730.02423183710.02423183710.368703462812.15972936742.15972936741.28572960750.47607794520.60032430670.60032430672.67276284421.41.14611607791.14611607792.18730121131.07662728080.4113195531.50880742350.24819336221.28170774210.3105804614-3.9901774151.13568094220.4526607432-6.09969802770.49627217740.59189078970.40804276320.999933552990.40.680.6621453152353.81214531522.57550.921.58222.5881.41.87520.40.40.40.6110.64272232870.4283101997110.64272232870.42831019970.06153170180.061531701811.91079379550.02410970950.02410970950.368204140412.15926679442.15926679441.28540600220.47530924520.59963427960.59963427962.67511131371.41.22348728551.22348728552.11922918911.03012369810.32996540781.39092001270.2968984751.34567867240.3115155763-4.00884270191.11467973810.4534031433-6.1190419450.48676458290.61206231650.38787784920.9999401656100.450.5580.2169399219353.36693992192.57550.921.6649752.5881.41.93460.450.450.450.55110.64236447870.427852891110.64236447870.4278528910.06131592980.061315929811.91235326840.02399682080.02399682080.367740942512.15883737452.15883737451.28510651060.47459671830.59899404740.59899404742.67729457581.41.30092354461.30092354462.05080994640.98356852320.26336483731.30130139560.34600969431.41341631790.3123819032-4.02618923081.0955106530.4540909317-6.13701660060.47809332220.63312636940.36679960190.9999259713110.50.579.8049139388352.95491393882.57550.921.747752.5881.41.9940.50.50.50.5110.64203267180.4274290724110.64203267180.42742907240.061116430.0611164311.91380116330.02389256420.02389256420.367311744912.15843920612.15843920611.28482960490.4739369730.59840070140.59840070142.67932162861.41.37841995371.37841995371.98207561670.93696848650.20866455821.23203165430.3953761151.48494259510.3131836662-4.0422896881.07801366340.4547274619-6.15369788420.47018426190.65538956680.34453325340.9999228202120.550.4579.4258180378352.57581803782.57550.921.8305252.5881.42.05340.550.550.550.45110.64172685040.4270386235110.64172685040.42703862350.06093303820.060933038211.91513729970.02379682630.02379682630.366916407612.15807222052.15807222051.2845750570.47332968410.59785407290.59785407292.68119221951.41.45597405411.45597405411.91305278020.89033132630.16362740991.17777540590.44502136291.56052353270.3139213504-4.05714315251.06211975770.4553131191-6.16908534830.46300469770.67901918660.32088662910.9999058157130.60.479.0824212477352.23242124772.57550.921.91332.5881.42.11280.60.60.60.4110.64144938590.4266845261110.64144938590.42668452610.06076705190.060767051911.91635090350.02371025830.02371025830.366557932812.15773926312.15773926311.28434466810.47277935780.59735833660.59735833662.6828912651.41.53358689251.53358689251.84376330680.84366761470.12648367481.13483092470.49513670971.64072252640.3145895675-4.07063090731.04789032410.4558436254-6.1830564880.45658097230.70417666650.29573064350.99990731140.650.3578.7772498128351.92724981282.57550.921.9960752.5881.42.17220.650.650.650.35110.6412024540.4263695124110.6412024540.42636951240.06061965120.060619651211.91743204930.02363344980.02363344980.366239069312.15744294482.15744294481.28414007590.47229011160.59691731740.59691731742.68440486911.41.61125897521.61125897521.77423275350.79698857250.09582615731.10056772170.54609480181.72649752060.3151834018-4.08264369351.03537754880.4563150783-6.19549859380.45093533810.73099138560.26892529990.9999166855150.70.378.5131848065351.66318480652.57550.922.078852.5881.42.23160.70.70.70.3110.64098851480.4260966778110.64098851480.42609667780.06049218810.060492188111.91836957310.02356708120.02356708120.365962934412.15718621772.15718621771.28396315710.47186662990.5965353490.5965353492.68571740231.41.68899095711.68899095711.70448943060.75030664090.07053946411.0730869170.5984843011.81935910870.3156972469-4.09305848651.02465026410.4567230267-6.20628468580.44609764490.75961229220.24029957470.9999118669160.750.2578.2948594876351.44485948762.57550.922.1616252.5881.42.2910.750.750.750.25110.64081144390.4258709244110.64081144390.42587092440.06038686150.060386861511.91914611560.02351227420.02351227420.36573447412.15697373272.15697373271.28381696380.47151640540.59621929420.59621929422.68680456191.41.76678512311.76678512311.63456386330.7036373040.04975543251.05101402110.65317193431.92162644510.316122087-4.10168342541.01585072060.4570603129-6.21521647740.4421309350.79028375330.20962509180.999908845170.80.278.1279609835351.27796098352.57550.922.24442.5881.42.35040.80.80.80.2110.6406759670.4256982391110.6406759670.42569823910.06030638030.060306380311.91974060590.02347041730.02347041730.365559732612.15681116042.15681116041.28370525590.47124861820.59597753470.59597753472.68763684821.41.84464443521.84464443521.56449157430.65699889460.03283174631.03337665510.71140214422.0368452080.3164468555-4.10828539141.00916619840.4573181508-6.22205293710.43911863310.82336938810.1765441270.9999135151180.850.1578.0203185755351.17031857552.57550.922.3271752.5881.42.40980.850.850.850.15110.6405885370.4255868145110.6405885370.42558681450.06025448980.060254489811.92012442420.02344343980.02344343980.36544698812.15670624442.15670624441.28363323180.471075880.59582154030.59582154032.68817419391.41.92257353881.92257353881.49431437610.6104144980.01935562711.01954416170.77495257532.17048918990.3166563172-4.11254735581.00487432040.4574844453-6.22646610390.43718499930.85944898550.140474510.9999234955190.90.177.9840294118351.13402941182.57550.922.409952.5881.42.46920.90.90.90.1110.64055905260.4255492414110.64055905260.42554924140.0602369990.06023699911.92025389010.02343434820.02343434820.365408971112.15667086322.15667086321.28360895460.47101764060.5957689380.5957689382.68835544621.42.00058067062.00058067061.42408360370.56391587650.00917859061.00922084310.8463765632.33118462950.3167269325-4.11398488291.00343082410.4575405076-6.2279545990.43653473560.89949664150.10043356190.9999302034200.950.0578.0399950079351.18999500792.57550.922.4927252.5881.42.52860.950.950.950.05110.64060452180.4256071852110.64060452180.42560718520.06026397410.060263974111.92005424110.023448370.023448370.365467599712.15672542622.15672542621.28364639610.47110745720.59585005930.59585005932.68807593751.42.07868165792.07868165791.35386787310.51755208430.00249623781.0024993560.92938476192.53295033060.3166180288-4.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x-y0000.35131363190.32310.45221505450.4320.49951090840.4960.52906198680.5340.55184977610.560.57213090840.5750.59189078970.5950.61206231650.6210.63312636940.6360.65538956680.6540.67901918660.6730.70417666650.6980.73099138560.7290.75961229220.7570.79028375330.7840.82336938810.8270.85944898550.8670.89949664150.8970.94523824970.9480.99995941161

unifacexpdiagonalx1y1x1-y1

T-x,y373.1352988861373.1352988861373373362.5283281576362.5283281576363.8363.8358.9042604474358.9042604474359.8359.8357.1840879998357.1840879998357.5357.5356.1568964129356.1568964129356.2356.2355.4208615371355.4208615371355.4355.4354.8198231287354.8198231287354.8354.8354.2927008945354.2927008945354.3354.3353.8121453152353.8121453152353.8353.8353.3669399219353.3669399219353.4353.4352.9549139388352.9549139388353353352.5758180378352.5758180378352.7352.7352.2324212477352.2324212477352.35352.35351.9272498128351.9272498128352352351.6631848065351.6631848065351.76351.76351.4448594876351.4448594876351.56351.56351.2779609835351.2779609835351.37351.37351.1703185755351.1703185755351.22351.22351.1340294118351.1340294118351.16351.16351.1899950079351.1899950079351.23351.23351.3790071026351.3790071026351.32351.32

expxexpyunifacxunifacyx-yTT-(x,y)

x-lngammai1.90977158031.51505127211.1841831250.90887978750.67744938490.48049230850.31086423110.16312619080.0330669328-0.0826448571-0.1867115568-0.2813939529-0.3686530349-0.4502686445-0.5279448369-0.6034165018-0.6785703979-0.7555969482-0.8371979724-0.9268885241-1.0294515342

x-DATOSX1Ln(k2/k1)Ln(k2/k1)-x1

resultadosx1y1TKy1expTexpK1K2LnK1/K200373.135298886101003736.75154643611.90977158030.050.3513136319362.52832815760.32390.8363.84.59474982941.00991183821.51505127210.10.4522150545358.90426044740.43286.8359.83.38327448281.0352685871.1841831250.150.4995109084357.18408799980.49684.5357.52.65884047521.07144727570.90887978750.20.5290619868356.15689641290.53483.2356.22.19653808411.1156454740.6774493849000.250.5518497761355.42086153710.5682.4355.41.88544556291.16610817420.4804923085110.30.5721309084354.81982312870.57581.8354.81.66714335231.22170492550.31086423110.350.5918907897354.29270089450.59581.3354.31.50880742351.28170774210.16312619080.40.6120623165353.81214531520.62180.8353.81.39092001271.34567867240.03306693280.450.6331263694353.36693992190.63680.4353.41.30130139561.4134163179-0.08264485710.50.6553895668352.95491393880.654803531.23203165431.4849425951-0.18671155680.550.6790191866352.57581803780.67379.7352.71.17777540591.5605235327-0.28139395290.60.7041766665352.23242124770.69879.35352.351.13483092471.6407225264-0.36865303490.650.7309913856351.92724981280.729793521.10056772171.7264975206-0.45026864450.70.7596122922351.66318480650.75778.76351.761.0730869171.8193591087-0.52794483690.750.7902837533351.44485948760.78478.56351.561.05101402111.9216264451-0.60341650180.80.8233693881351.27796098350.82778.37351.371.03337665512.036845208-0.67857039790.850.8594489855351.17031857550.86778.22351.221.01954416172.1704891899-0.75559694820.90.8994966415351.13402941180.89778.16351.161.00922084312.3311846295-0.83719797240.950.9452382497351.18999500790.94878.23351.231.0024993562.5329503306-0.926888524110.9999594116351.3790071026178.32351.3212.7995299671-1.0294515342