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++- Gordon Conferences were supported by AFOSR during i90 h Cneecon Inorganic Chemistry was held in Wolfboro. NH July 30 to August 3. Totalattendance was 98. 22 papers and 40) posters were presented. The Conferenceon Glass was held in Tifton, NH, June 25-29. Total attendance was 80including 5 from Europe and Japan. 18 talks and 24 posters were presented.The Conference on Biocatalysis was held in Plymouth, NH, June 24--29. Totalattendance was 113. 26 papers and 30 posters were presented. The Conferenceon Dielectric Phenomena was held in Plymouth, NH, July 22-27 . Totalattendance was 76. 20 papers and 15 posters were presented. The Conferenceon Physical Electrochemistry was held in New London, NH, July 29 to August 3.The Conference on Organometallic Chemistry was held in Newport, RI. June24-29. Total attendance was 134. 26 papers and 57 posters were presented.

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THE GORDON CONFERENCE ON INORGANIC CHEMISTRY 1990

Final Program Report

The 1990 Gordon Conference on Inorganic Chemistry was held atBrewster Academy, Wolfboro, New Hampshire from July 30 to August 3 1990and had as its themes: the chemistry of inorganic molecular clusters,the chemistry of supermolecular inorganic materials, chemistry atinorganic surfaces, and reactive intermediates in inorganic chemistry.Twenty two papers were presented, plus an unscheduled contribution fromthe vice-chair at the end of the final session. Two poster sessiciis wereheld, comprising about forty posters. Invited speakers and sessionchairs were drawn from research groups in academia, industry and NationalLaboratories, and the program brought together world class chemists fromthe United States, Britain, France, West Germany, Canada and theU.S.S.R., in keeping with the worldwide level of research activity inthese areas. The international scope of the program was greater than hadbeen attempted in previous years for this conference.

The Conference was attended by ninety-eight registrants, and inaddition to the customary mix of academic and industrial scientists, asignificant number of graduate students and post-doctoral fellowsattended. This was undoubtedly due to a well publicised offer offinancial support for selected students and post-docs, awarded on thebasis of poster presentations. As a result the poster sessions were of auniformly high quality and gave to junior conferees a good oportunity toexpose their work in an informal but scientifically rigorous atmosphere.

The Conference was characterized by particularly stimulatingdiscussions between chemists in related but distinct areas of inorganicchemistry. Both after the formal talks and in the free discussionperiods these interactions were evident, and they will lead to newinitiatives, particularly in the areas of inorganic materials, clusterchemistry and catalysis. This was made clear to the organizers in thecomments of the attendees, many of whom were delighted to find their workso relevant to chemists in what had previously seemed unrelated fields.

ix

91-05932

GORDON RESEARCH CONFERENCE

Inorganic ChemistryBrewster Academy, Wolfboro, NH

July 30 - August 3 1990

John S. Bradley, Chairman Richard D. Adams, Vice Chairman

July 30, 1990

8:45 a.m. The Chemistry of Inorganic Clusters

Duward F. Shriver, Discussion Leader

1. Larry F. Dahl Experimental - Theoretical Studies ofUniversity of Wisconsin Small to Giant Transition Metal Clusters:Madison Problems and Solutions

2. Boon Teo Gold Fusion: From Clusters to ClustersUniversity of Illinois of ClustersChicago

3. D. Michael P. Mingos Synthesis, Structure and Bonding inOxford University Metal Clusters

7:30p.m.

4. Richard Finke Polyoxoanions as New Materials forUniversity of Oregon Atomically Dispersed Transition MetalEugene Catalysts: Synthesis, Characterization,

Catalytic Activity and Mechanism

5. Pierre Braunstein Molecular Aspects of the Metal-MetalLouis Pasteur University BondStrasbourg

July 31, 1990

9:00 a.m. The Chemistry of Inorganic Clusters (contd.)

Wayne Gladfelter, Discussion Leader

1. Thomas P. Fehlner Transition Metal-Main Group Clusters andUniversity of Notre Dame Solid State Materials

2. Suzanne Harris Bonding in Heterometallic ClustersExxon Corporate Research

Supermolecular Inorganic Chemistry

3. Brian F. G. Johnson Metal Clusters, Particles and CrystallitesCambridge University

7:30p.m.

4. Michael Steigerwald Molecular Routes to Solid State CompoundsAT&T Bell Laboratories

5. Thomas Bein Synthesis and Characterization ofUniversity of New Mexico Clusters and Organometallics in ZeolitesAlberquerque

August 1, 1990

Supermolecular Inorganic Chemistry(contd.)

9:00 a.m. John Bradley, Discussion Leader

1. Reinhard Kremer Electronic Delocalization and SpinMax Plank Institute Properties in Lanthanide Compounds withStuttgart Discrete and Condensed Clusters

2. Jeremy K. Burdett Some New Theoretical Ideas LinkingUniversity of Chicago Molecules,Surfaces and Solids

3. Ilya I. Moiseev Synthesis, Structure and CatalyticN. S. Kurnakov Institute of Activity of Giant Palladium Cluft orfGeneral and Inorganic ChemistryMoscow

7:30 p.m.

4. Larry Lewis Preparation and Characterization ofGeneral Electric Corporate Platinum Group Metal Colloids:Research and Development Crossroads Between Clusters and Surfaces

5. GUnther Schmid Large Transition Metal Clusters andInstitute for Inorganic Colloids: Bridges between HomogeneousChemistry and Heterogeneous CatalysisEssen

August 2, 1990

Inorganic Chemistry On and In Inorganic Solids

9:00 a.m. Robert J. Madix, Discussion Leader

1. Ralph Nuzzo Structure-Reactivity Correlations inAT&T Bell Laboratories Surface Organometallic Chemistry

2. Cynthia M. Friend Mechanistic and Structural SurfaceHarvard University Chemistry

3. Laurent Bonneviot Preparation, Structure and StabilityLaval University of Transition Metal Ion Deposits onQuebec Amorphous Silica

7:30p.m. RoLert J. Madix, Discussion Leader

4. Thomas E. Mallouk Light Driven Electron TransferUniversity of Texas Reactions in Microporous SolidsAusten

5. Shirley Chiang Scanning Tunneling Microscopy ofIBM Research Division Adsorbed Molecules on SurfacesAlmaden

August 3, 1990

Mechanistic Investigations in Inorganic Chemistry

9:00 a.m. R. D. Adams, Discussion Leader

1. Robin N. Perutz Plotting the Course of C-H ActivationUniversity of York Reactions-Reactive Intermediates in

Organometallic Chemistry

2. John R. Shapley Pressure Tuning Spectroscopy -University of Illinois Applications in Metal-Metal BondedUrbana Systems

3. Wrap-up and Discussion

INORGANIC CHEMISTRYBrewster Academy, Wolfeboro, New Hampshire

JULY 30-AUGUST 3, 1990

REGISTRATION LIST

Adams, Richard D. Afzal, DawoodUniv. of South Carolina Northeast Missouri State Univ.Dept. of Chemistry Dept. of ChemistryMain & Devine Streets Division of Science, NMSUColumbia SC 29208 Kirksville MO 63501

Anderson. Wayne P. Aufdembrink, BrentBloomsburg University Mobil Research & DevelopmentOept. of Chemistry Billingsport RoadBloomsburg, PA 17815 Paulsboro, NJ 08066

Babin, James E. Barron, Andrew R.Union Carbide Corporation Harvard UniversityPO Box 8361 Dept. of ChemistryBuilding 770/450 ! 2 Oxford St.South Charleston WV 25303 Cambridge MA 02138

Basolo. Fred Bein, ThomasChemistry Dept. Univ. of New MexicoNorthwestern University Dept. of ChemistryEvanston, IL 60201 Clark Hall

Albuquerque NM 87131

Bolinger, C. Mark Bonneviot, LaurentShell Development Company Universite LavalPO Box 1380 Dept. of ChemistryHouston, TX 77251 Cite Universitaire

Quebec Canada G IK 7P4

Bradley, John Braunstein, PierreExxon Research & Engineering Co. ULP/CNRSRt. 226 Institut Le BelAnnandale, NJ 08801 4 Rue Blaise Pas,,al

F-Strasbourg France F-67070

Briggs, John Burdett, Jeremy K.Union Carbide Corporation University of ChicagoPO Box 8361 5747 S. EllisCharleston, WV 25303 Chemistry Dept.

Chicago IL 60637

Chan, Edith Chiang, ShirleyCornell University IBM Almaden Research CenterBox 334. Baker Lab K33/801Dept. of Chemistry 650 Harry RoadIthaca NY 14853 San Jose CA 95120

REGISTRATION LISTINORG AN IC CHEMISTRY

Collins, Gary S. Cowley, AlanWashinqton State University Univ. of Texas

Dept. of ChemistryAustin, TX 78712

Czech, Paul T. Dahl, Lawrence F.Univ. of Chicago Univ. of Wisconsin-Madison5735 E. EllisChicago, IL 60637

Dahmen, K.H. Deaton, Joseph C.Laboratorium fur Anorganische Chemie Eastman Kodak CompanyE.T.H. Zentrum Research Laboratories6 Universitatstrasse 2nd Floor B-2Zurich Switzerland CH-8092 Rochester NY 14652-3208

Diebold, Michael P. Dunham, StephenDupont De Nemours Montana State UniversityJackson Laboratory 2101B Dept. of ChemistryChambers Works Bozeman, MT 59717Deepwater NJ 08023

Elliott, Denton Ernst, Richard D.6312 Kirby Road Univ. of UtahBethesda, MD 208317 Dept. of Chemistry

Salt Lake City, UT 84112

Fackler, John P. Faessler, Thomas F.Texas AX4'" Univ. Univ. of ChicagoCollege of Science Dept. of ChemistryDean's College 5735 S. Ellis Ave.College Station TX 77843-3257 Clicaqo IL 60637

Farr, James Fehlner, Thomas P.Clorox Technical Center Univ. of Notre Dame

Chemistry Dept.Notre Dame, IN 46556

Finke, Richard 0. Fisher, BarbaraUniv. of Oregon Eastman Kodak CompanyDept. of Chemistry 7181 HSD/RLEugene, OR 97403 Rochester, NY 14650-0233

Friend, Cynthia Furuya, Frederic R.Harvard University Brookhaver. National LaboratoryDept. of Chemistry Biologj Dept.12 Oxford St. Utpon, flY 11973Cambridge t1A 02138

REG ISTR AT ION L ISTINORG ANI'C CHEMISTRY

Glafeltet-, Wayne L. Hagen, Karl S.Univ. of Minnesota Emory UniversityChemistry Dept. Dept. of Chemistry207 Pleasant St. SE 5 15 Pierce Dr.Minneapolis MN 55455 Atlanta GA 30322

Han, Scott Harris, SuzanneMobil Research & Development Exxon Research & EngineeringPaulsboro Research Lab. Route 22 EastPaulsboro, NJ 08066 Annandale, NJ 08801

-Hawk, Eric L. Hembre, Robert T.Suny at Stony Brook Univ. of Nebraska-LincolnChemistry Dept. Dept. o; CietejltryStony Brook, NY 11794 746 Hamilton Hall

Lincoln NE 68588-0304

Horvath, Istvan T. Howe-Grant, MaryExxon Research & Engineering John Wiley & Sons, Inc.Route 22 East 605 Third Ave.Annandale, NJ 08901 Sci-Tech

New York NY -10158

Hubert-Pfalzgraf, Liliane Jackson, Sarah A.Laboratoire De Chimie Moleculaire Univ. of Paris-SudURAAU CNRS Laboratoire De Chimie TheoriqueUniv. De Nice, Parc Vairose Batiment 490Nice France 06034 Orsay Cedex France 91405

Jasinski, Jerry P. Jensen, Craig9Keene State College Univ. of HawaiiDept. of Chemnistry Dept. of ChemistryKeene, NH 03431 2545 The Mal

Honolulu HI 96822

Johnson, Brian F. Johnson, Kimberly A.Univ. of Cambridge Univ. of MinnesotaUniversity Chemn. Lab. Dept. of ChemistryLensfield Road 2407 Pleasant St. S.E.Cambridge UK C82 1 EW ftiaolis MN 55455

Kanis, David R. Kemp, Richard A.Northwestern University Shell Development Co.Dept. of Chemistry PO Box 13802145 Sheridan Road Houston, TX 77251Evanston IL 60208

Kiaaras., Kari o-LX Koteswara Rao, A.Allied Signal Pq AA Tech. Osmania UniversityMaterials *,cience Dept.50 East Algonquin RoadDes Plaines IL 60017-5016

REGISTR AT ION L ISTINORGANIC CHEMISTRY

Kremer, Reinhard Lattman, MichaelMax Planck Inst. fur Festkorperforschung Southern Methodist UniversixyHeisenbergstr. 1 Chemistry Dept.7000 Stuttgart 80, West Germany Dallas, TX 75275

Lauher, Joseph W. Lewis, LarryState Univ. of New York GE Corporation Res. & Dev.Chemistry Dept. K1 5AI5 1 River RoadStony Brook, NY 11794 Schenectady, NY 12301

Li, Yong-Xi Lissy, Daria N.Kansas State Univ. Mobil R&D Corp.Dept. of Chemistry Billingsport RoadWillard Hall Pauls'boro, NJ 08066Manhattan KS 6650A

Lookenmeyer. John Lyon, David K.Shell Development Co. Univ. of OregonWesthollow Research Center Dept. of Chemistry3333 Highway 6 S. '.ugene, OR 97403Houston TX 77082

Madan, Stanley K. Madix, Robert J.State Univ. of New York, Binghamton Stanford UniversityDept. of rhamidr Dept. of Chemilal EngineeringVestal Parkway East Stanford, CA 94305Binghamton NY 13901

Mallouck. Torn Marcus, M.Univ. of Texas at Austin AT&T Bell LabsDept. of Chemistry Room 1E-62Austin, TX 78712 600 Mountain Ave.

Murray Hill NJ 07974

Martin, Andrea E. Matuszko, Anthony J.Hercules Incorporated 4210 Elizabeth LaneResearch Center Annandale, VA 220038136/359Wilmington DE 19894

Mazany, Anthony M. Millar, John M.BF Goodrich R&D Center Exxon Research & Engineering9921 Brecksville Road Route 22 East Clinton TWPBrecksville, OH 44141 Annandale, NJ 08801

Mingos, D.iP. loiseev, llya I.Oxford Ur'versit. N.S. Kurnakov Inst. of r3enera, andInorganic Chemistry Inorganic Chem., Academy of SciencesSouth P.arks Road USSR, Leninsky Prospect, 31O-Aford UK OXI 30R Moscow USSR 117907

REGISTRATION LISTINORGANIC CHEMISTRY

Nuzzo, Ralph 0. Parry, RobertAT&T Bell Laboratories Univ. of Utah600 Mountain Ave. Dept. of Chemistry1 D-258 Salt Lake City, UT 84112Murray Hill NJ 07974

Perutz, Robin N. Pignolet, Louis H.Univ. of New York Univ. of MinnesotaDept. of Chemistry Chemsitry Dept.York, UK YOI 5DD 207 Pleasant St.

Minneapolis MN 55455

Poli, Rinaldo Porterfield, William W.Univ. of Maryland College Park Hampden-Sydney CollegeDept. of Chemistry & Biochemistry Dept. of ChemistryCollege Park, MD 20742 Harnpden-Sydney, VA 29343

Proserpio, David M. Ramprasad, DoraiCornell University Air Products and ChemicalsBaker Lab Box 538Dept. of Chemistry 7201 Hamilton BoulevardIthaca NY 14853-1301 Allentown PA 18195-1501

Reid, Austin H. Richard, Michael A.Du Pont Catalytica, Inc.Du Pont Co. Chemicals & Pigments Dept. 430 Ferguson DriveJohnsonville R&D I Du Pont Rd. Mountain View, CA 94043New Iohnsonville TN 37134

Samkoff, Deborah E. Schauer, Cynthia K.Univ. of Minnesota- Duluth Univ. of North CarolinaDept. of Chemistrj CB *3290 Venable & Kenan Labs.10 University Drive 'epi. of ChemistrVDuluth MN 55812 Chapel Hill NC 27599-3290

Schmid, Gunter Shapley, John R.Univ. of Essen Univ. of IllinoisUniversitatsstrasse 5-7 Dept. of ChemistryInstitut fur Anorgan. Chemie 505 S. MathewsD-4300 Essen 1 West Germany Urbana IL 61801

Shore, Sheldon G. Shriver, D.F.Ohio State University Northwestern UniversityDept. of Chemistry Chemistry Dept.120 Id 18th Ave. 2145 Sheridan RoadColumbus OH 43210 Evanston IL ,0208-3113

Steggerda, Jan J. Steigerwald, MichaelUniv. of Nijmegen AT&T Bell LaboratoriesDept. of Chemistry 600 Mountain Ave.Toerrooiveld Room I D 345Nijmegen The Netherlands 6525 ED Murray Hill NJ 07974

REGISTRA I iJN LISTINORGANIC CHEMISTRYStrauss, Steven H. Tanke, R' bi S.Colorado State University Yale UniversitDept. of Chemistry Dept. of ChemistryFt. Collins, CO 80523 flew Haven, CT 06551

Teo, Boon K. hor-steinson, ErlUniv. of Illinois at Chicago Union Carbide CorporationDept. of Chemistry', t/C IIIBox 4348Chicago IL 60680

Tindall, James Wagner, Klaus P.Exxon Research & Engineering nobil Chemical Co.Route 22 East LA 329 Edison Research LaboratoryAnnanda ,jw'-mn Route 27 and Viney ard Road

V I= Gt-l: Cif NEdison NJ 08818Wigeand,Benjamin C. '0ong, attirHarvard University Cornell UniversityDept. of Chemistry Baker Laboratory12 Oxford St. Box 353 Dept. of Chemistry;,mvbridqe MA 02138 Ithaca NY 14853

Zhang, HongChemistry Dept.Univ. of Illinois at ChicagoChicago, IL 60680

Adams, Richard D. House 2 6 Lattman, Michael Vaughn 6Afzal, Dawood Lamb 4 Lauhor, Joseph V. Vaughn 4Anderson, Wayne P. Sargent 201 Lewis, Larnj off siteAufdembrink, Brent off site Li, Yong-Xi Lamb 3Babin, James E. off site Lissy, Dar" N. House 3 6Barron, Andrew R. Sargent 304 Lockenmeyer, John Sargent 302Basolo, Fred House 1 6 Lyon, David K. Sargent 310Bein, Thomas Brown 7 Madan, Stanley K. Sargent 203Bolinger, C. Mark Sargent 301 Madix, Robert J. Lamb 5Bonneviot, Laurent Brown 4 Maliouck, Tom Brown 5Bradley, John Kupper 1 Marcus, M. Sargent 202Braunstein, Pierre House 1 3 Martin, Andrea E. House 3 7Briggs, John off site Matuszko, Anthony J. House 2 5Burdett, Jeren K. Kupper 2 Mazanj, Anthony M. Sargent 204Chan, Edith House 3 1 Millar, John M. Sargent 205Chiang, Shirley off site Mingos, D.MP. Brown 10Collins, Gary S. Sargent 107 Moisety, Ilya I. Vaughn ICowley, AlWn House 1 7 Nuzzo, Ralph G. Brown 3Czech, Paul T. Vaughn 3 Parry, Robert Kupper 5Dahl, Lawrence F. Brown 9 Perutz, Robin N. Estabrook 4Dahmen, K H. House 2 4 Pignolet, Louis H. Lamb 6Deaton, Joseph C. Harris 2 Poli, Rinaldo House 2 2Diebold, Michael P. off site Porterfield, 'ffltam V Lamb 2Dunham, Stephen Sargent 305 Proserpio, David M. Vaughn 5Elliott, Denton House 1 5 Rampresa, Dorai Lamb 7Ernst, Richard D. Harris I Reid, Austin H. Sargent 311Fackler, John P. Kupper 4 Richard, Michael A. Sargent 206Faessler, Thomas F. Vaughn 3 Samkoff, Deborah E. House 3 1Farr, James Sargent 107 Schauer, Cynthia K. House 3 2Fehbner, Thomas P. Estabrook 6 Schmid, Gunter House I IFinke, Richard G. House 1 4 Shapley, John R. Harris 3Fisher, Barbara Estabrook 2 Shore, Sheldon 0. Sargent 303Friend, Cynthia Lamb 5 Shriver, D.F. Lamb IFuruya, Frederic R. Sargent 306 Steggerda, Jan J. Sargent 207Gladfelter, Wayne L. Vaughn 2 Steigerwald, Michael Estabrook 5Hagen, Karl S. Sargent 307 Strauss, Steven H. Harris 2Han, Scott Sargent 308 Tanke, Robin S. House 3 2Harris, Suzanne Estabrook 1 Teo, Boon K. off siteHawk, Eric L. Vaughn 4 Thorsteinson, Erl Sargent 108Hembre, Robert T. Harris 1 Tindall, James Sargent 108Horvath, Istvan T. House 2 I Wagner, Klaus P. Sargent 208Howe-Grant, Marj Estabrook 3 Vieland, Benjamin C. Sargent 209Hubert-Pfalzgraf, Liliane House 3 4 Wong, Yatting House 2 2Jackson, Sarah A. House 3 3 Zhmng, Hong off siteJasinski, Jerry P. House 2 7Jensen, Craig Sargent 309Johnson, Brian F. Brown 6Johnson, Kimberly A. House 3 5Kanis, David R. House 2 3Kemp, Richard A. Vaughn 6Kharas, Karl C.C. House 2 3Koteswara Rao, A. Sargent 109

190_GORDON CONFERENCE ON GLASSTILTON, NEW HAMPSHIRE

JUNE 25-29. 1990

FINAL REPORTRobert J. Eagan, Chair

The 1990 Gordon Conference on Glass, entitled "Defects in Glass" successfully integratedscientific studies performed by scientists in the "classical" glass community, thesemiconductor community, and several involved in peripheral work, e.g., the surface forceinteractions of water with inorganic materials. Several previously unreported orunrecognized observations were reported. Three examples are:

1) The possible relationship of E' (optical defect) centers to fracture propagationemerged for the first time and will lead to further collaborative studies.

2) New nucleation and crystallization data for zinc fluoride glasses, obtained with a novelheating stage and optical microscope, were presented.

3) Surface force interaction measurements may lead to understanding electronic defectsin silica films-a surprise to the presenter! New collaborations will undoubtedlydevelop.

The attendees and presenters represented industry, academia (students and faculty),national laboratories, and several scientists from Europe and Japan. Eighteen speakerswere joined by twenty-four participants in two poster sessions. The nine discussion leadersdid a good job leading frequently spirited discussions. Total attendance was eighty,including five from Europe and Japan.

Enclosure:Program

WK=Vest Knowles

EK=East Knowles

M=Moore Hall

P=Pheiffer

GORDON RESEARCH CONFERENCES

Glass

Tilton School, Tilton, New Hampshire 03276

June 17 - 22, 1990

Xllan, Douglas off campus Cerqua, Kathleeu 115M

,orning, Inc. NYS College of Ceramics

SP PR 02 2 Alfred University

,orning NY 14831 Binns-Merrill Hall

Alfred NY 14802

krai, Kazuo 217EK

Electrotechnical Laboratory Chaiyasena, Izra 18P

qaterials Science Division Engineering Science & Mech. Dept.

L-1-4 LME IONO 227 Hammone Bldg.

rsukuba-Shi KBARAKI 305 Penn State University

Japan University Park

State College PA 16802

kraujo, Roger 248WK

Corning Inc. Chen, Din-Guo 247WK

SP FR 3-1 University of Florida

Corning NY 14831 Materials Science & Engineering

Room 166, Rhines Hall

Batey, John 203EK Gainesville FL 32611

IMB Corp., T.J. Watson Research Center

P.O. 3ox 704 Cheng, J. Joseph

forktown Heights NY 10598 L 0 F

Brinker, Jeff 205EK

Sandia National Labs

)iv 1846, P.O. Box 5800 Chiu-Sarourin, Martina 216M

klbuquerque NM 87185 AT&T Bell Labs

600 Mountain Ave.

Brow, Richard 206EK RM 60305

Sandia National Labs Murray Hill NJ 07974

Div. 1845

klbuquerque NM 87185 Cooper, A. 214EK

CWRU

Bruce, Allan 218EK White 500

kT&T Bell Labs Cleveland OH 44106

500 Mountain Avenue

4urray Hill NJ 07976 Cooper, Reid 102EK

University of Wisconsin

:apozzi, Carol -ff campus Dept. Material Science & Engineering

Institute of Glass Science & Engineering 1509 University Avenue

klfred University Madison WI 53706

klfred NY 14802

-3-

Knight, Diane 1IIM Lou, Victor I19EK

Penn State University GE Corporate Research & Development

209 Materials Research Lab. River Road

University Park PA 16802 Bldg. Ki, MB-177Schenectady NY 12309

Kohli, Jeffrey 107EK

NYS College of Ceramics McKinnis, Charles I5EK

Binn-Merrill Hall Owens Corning Fiberglass

Alfred NY 14802 109 Mt. Parnassus, Box 46Granville OH 43023

Kozlowski, Maureen 112M

Rensselaer Polytechnic Institute Michalske, Terry 233WK

Materials Research Center Sandia National Lab

Troy, NY 12180 Division 1114Box 5800

Kreidl, Norbert 109EK Albuquerque NM 87008

MTA and University of Arizona1433 Can-on Road Moddeman, William 221EK

Santa Fe, NM 87501 Mound LaboratoriesMound Road

Kruger, Albert 242WK Miamisburg OH 45443

Battelle-PNLMS P8-37 Nagasawa, Kaya 230WK

Materials & Chemical Sciences Shonan Institute of Technology

Richland WA 99352 1-1-25, Tiuido-Nishi-KaiganFujisawa Kanagawa 251, Japan

Kurkjian, C.R. 11OEKATfT Bell Lab. Nattermann, K. 229WK

600 Mountain Avenue Schott GlaswerkeRoom 2C261 Hattenbergstr 10Murray Hill NJ 07974 Mainz, FRG 6500

Lehman, Richard 232WK Perea, WillorageRutgers University RPICeramic EngineeringP.O. Box 909/Brett & Browser RoadsPiscataway NJ 08855-0909

Phifer, Carol 212Moore

Lenahan, Patrick 19P Sandia National Laboratories

Dept. Engineering Science division 1845Hammond Bldg. Albuquerque NM 87185Pennsylvania State UniversityUniversity Park PA 16827 Pye, L. David off campus

Institute of Glass Science & EngineeringLevin, Victor 244WK Alfred UniversityCase Western Reserve University Alfred NY 1480210900 Euclid AvenueMatl. Science & Engineering Dept. Rabinovich, Eliezer 9PWhite Bldg #502 AT& T Bell Labs

Cleveland OH 44106 600 Mountain Avenue, Room 7A-313Murray Hill NJ 07974

Li, Jie 245WKRutgers UniversityDept. of CeramicsPiscataway NJ 08855-0909

- 5-

t, Jon 231WKversity of Florida

-C #14Progress Blvd.

chua FL 32615

, ManT Bell Laboratories

nt, James 18Pt. Engr. Science & MechanicsHammond Bldg.

n State University

versity Park PA 16802

1, David 126WKgers University. Box 909cataway, NJ 08855-0909

Irone, R. K. lOP

..SNY 12180

GORDON CONFERENCE ON GLASS

Senior Poster Session - Tuesday Evening

Author/Institution Poster Title

R. J. Araujo Statistical MechanicalCorning, Inc. Calculation of Peroxyl

in Silica

R. Cooper Chemical Diffusion andUniversity of Wisconsin Crystalline Nucleation in

Transition-Metal-DopedAluminosilicates

J. T. Dickinson, S. C. Langford, Consequences ofand L. C. Jensen Simultaneous BombardmentWashington State University of Sodium Trisilicate Glass

With UV Excimer Irradiationand keV Electrons

D. Inniss, D. Brownlow, C. Kurkjian The Strength and Fatigue ofAT&T Bell Laboratories Silica Fibers in Sodium

Chloride Solutions

A. A. Kruger The Effect of SurfaceBattelle Pacific Northwest Lab. Treatments of Silica and

Silicate Glass Fibers onTheir Mechanical Properties

C. Kurkjian, R Farrow, D. Inniss High Resolution ScanningAT&T Bell Laboratories Microscopy of Glass Fiber

Surfaces

W. Moddeman Zero Valent NickelEG&G Mound Applied Technologies in Glass

K. Nagasawa The Cause of the IntrinsicSagami Institute of Technology Luminescence at 2.7 eV in

Pure Silica Glass

S. V. Raman and K. Matsuishi Glass-like Structural RelaxationTexas Center for Superconductivity in Crystalline YBa2Cu307-v

Perovskite Structure

J. Simmons XPS Studies of FluorideUniversity of Florida Glass Films

P. A. Tick, T. Kanamori Hot Stage Optical MicroscopyS. Mitachi, S. Takahashi, (includes video presentation)R. Maschmeyer, K. LuCorning, Inc.

1990 Gordon Conference on GlassJune 24-29, 1990The Tilton School

Tilton, New Hampshire

PROGRAM

Chair: Robert J. Eagan Vice-Chair- Marv~n J, Weber

Monday, June 25, 1990

Discussion Leder Robert J. Eagan

Spoaxer C. Jeffrey Brinker Stru.eturt of Sol Gal Silicate ClassesSpeaaker John Batty Structursl Plopertied of Thin Film, PZCV0 Si0 2

Discussion Leader Richard K. Brow

sr@OI1iF 4'a~ti . Kiiftl 2lefiiS' & PUh"& SaUE2 r.. a IuJhdn G Sflii6Speaker Minoru 1ioinoi&*i Water &S IJCecc its -jusi;

Tuesday, June 26, 1990

Discustion Leader Suresh Oulati

Speaker Terry A. M4KhiaiI.e The Role ei S3tvain Induced Det'ects in the Fraciure of Silica Gias3pat . Thornaa Dickinson Fracto-emnisaion irorn Glans Surisces ik lntrfa.as -

Speaker Charles R. Kurkj~an Strength Dcgrdationi n Hish Strengti. Fzbcre

Diacusio;n Leader Ma.-Yin 3. Weber

Poster Seaib, sirnlor SeientitjI' aduity rosters shno isiuior.

Wednesday, June 27, 1990

Discussion Leader Raoert J. Eagan

SptAker Douglas T. Sinith Surface F'orcms Int SiG2 -Water ints,'ctor.4Speaker Jon K. West Silica Cluster Models

Di~~inLea-dcr jares E. ghc!by. jr.

PO~ter Sessici '.2:Aiern postezs a.-d simio

Thursday, June 28, 1990Discussion Leader J~th$inn

Spea.ker DOUglas1 Allan Siruciurs it aDei'ecis i ZO xides 67 Fiazironi. Siructurei~otsi Zn~rgy WecnodisSpeaker lrazik L. Galeener X-ray Induction~ oi 3pin Active Deftctz in Vitreouii SilicaSpeaker K~auo Arai Nature of Defects of Doping in Silica Glaoses

Dilscua3ion~ Leadar Norbert J. Krcldl

S3pc.kte Delbert E. Day Tarceted Radiation Trierapy in Hurnuns Uairg G.,isis Mixcrosphercs

Friday, June 29, 1990

Diieussion Ltader Tetsuro hsumitani

speaker DJavid L. C..scom rnysIia ' ';.ffu'fitry 01 -Usactf in Silica Gtimi &1 At dfs i,311 . 2 'alareSpeaker Patrick Lenahan Detection of Defects in Clan.: Electron~ic NfeauremontsSpeaker Andrej. R. Sili Point Defects: Resdiation Inducei D.iec.ta in S0O2

Senior Poster Particii~ants:

Fibers on Their NMechanicaI Properrics

K Nagasawa T1he Cause of ihe I nti-ic Ly-u m'.seic aa 2. V 0 re 3.cGlass

S.v.im.nan ~ jasslK e 'ruut W IN UsLM1d.Xdii iFs k-1 1).1k11. I O.,.L~J-Perovskite Structure

P. A. Tick Hot Stage Optical MNIUC73copy

D. Inniss title unavailable

R. J. Araujo Statisuical Mechanical Calculatiion of Peroxyl in Silica

Reid Cooper Chemical Diffusion and CrysialIline 'INucleafion in 'I ransion -Metal-Doped Alurninosilicates

VV. IVILJ(U~kdler ZLcI V aICIIL 141xrIIKI 1 d1 b

J. Sim-mons title unavailable

StudepI Postgr P~axtciggtits:

C. A- Capozzi title unavailable

Kathleen Cerqua The Role of Defect Processes in IA'w-T, Chaicugenide GlaSses

I. 1-uang Str-ucturatl Relaxation in 'ifi Glas Fibers

Mark lupina A Nz~Si Hyperfine Srudy of' the rb Center and E'Center iri Metal-Oxide-Semiconductor Devices

Sriraman Karinan Excimer Laser Damoage Studies or 'Synithetic Silica Glasses andFibers

Jeffrey Kohli, fitle uinavailable

Vicor Levn title unavailable

i~ iDraw induced iect/ui tr avioiet X.ad a ion ResponseMechanisms in Synthetic Silica Optical 'Fibers

,Vviuorage rerera i t: aurlacc %oirrubMui UL IJI~b~

H-ema Slenapati Effects of Anion 'Mi~ng on Siru ciural "Mehaxauion andU V; 0S-11yDecoupling in Agl-Ag 2SO4-Ag2\V0 4 Glasses

Cathy Shaw Oxygen Related Defects in 113ariurn Galiosilicate GlassesI n .. . I,- I T.I om. Swier Molecular Llynamlucs rkracture or C..rysta1ine and vitreous S., hcon

Dioide

'Willia m, WYa r re n F-11ect ron 14uicl e ar Dli uble "Aesor. ance dd Ei 'ct ron Param agne ticResonance Study of Silicon Dan~ling-Bond Centers in SiliconNitride

David Zirl Simulations of 'be Structure and Properties of Sodiumr-Aluminosilicate Glasses

GORDON RESEARCH CONFERENCE

BIOCATALYSIS

PLYMOUTH STATE COLLEGE - NORTH

JUNE 24-29, 1990

Anton, David 201/203 Caruso, Andrew 223

El Dupont De Nemours General Electric Corp.

Experimental Station Pn Rox 8

PO Box 80328 KI 5B15

Wilmington, DE 19850-0328 Schenectady, NY 12301

Arnold, Frances 526 Chang, Ho Nam 703

Caltech Kaist/ Dept. of Chem. Engineering

Chem. & Engineering PO Box 150

210-41 Seoul, Kzrea 130-650

Pasadena, CA 91125Cheung, Alex 210

Baresi, Larry 622 Coors Biotech

4800 Oak Grove Dr. 6204 South College Ave

MS 125-112 Fort Collins, CO 80525

Pasadena, CA 91109

Chmurny, A.B. 217

Bhupathy, M. 317 WR Grace & Co./ Research Div.

Merck & Co. 7379 Route 32

Rahway, NJ 08820 Columbia, MD 21044

Bjorklong, Frederick 205 Crans, Debbie 502

Novonordisk A/S Colorado State U.

Dept. of Natural Products Dept. of Chemistry

Novoave Ft. Collins, CO 80523

Bagovaero, Denmark 2880

Dalton, H. 717

Boaz, Neil 206 University of Warwick

Eastman Kodak Lab/Corp. Research Lab Coventry, England CV311TA

Bldg. 82, 5th Floor

Rochester, NY 14650-2110 Dicosimo, Robert 218

E1 Dupont De Nemours

Bommarius, Andy 302 Central R & D Dept.

Degussa AG Sect. FCO PO Box 80328

PO Box 1345 Wilmington, DE 19880-0328

6450 Hanau

West Germany Dodds, David 219

Sepracor Inc.

Bratzler, Robert OC 33 Locke Dr.

Sepracor Inc. Marborough, MA 01752

33 Locke Dr.

Marlborough, MA 01752 Dordick, Jonathan 303

University of Iowa

Bray, Brian 208 Dept of Chemical & Biochem. Eng.

Glaxo Inc. 125 B Chemistry Bldg.

5 Moore Dr. Iowa City, IOWA 52242

Synthetic Organic Chem.

RTP, NC 27709 Elferink, V H M 220

Burgess, Kevin 209 Andeno B.V.

Rice University Grubbenvorsterweg 8

Chem. Box 1892 5928 NX Venlo, The Netherlands

Houston, TX 77251

BIOCATALYSISGORDON RESEARCH CONFERENCE

Plymouth State CollegeJune 25-29, 1990

Co-Chairmen: Co-Vice Chairmen:J.B. Jones & D.L. Anton J. Frost, J.D. Rozzell

Sunday, June 24 4:00-6:00 p.m.Chairmen's Reception

Monday, June 25 9:00 a.m. Chiral Synthesis

Discussion Leader: Larry Baresi

Charles Sih Chemo-enzvnmatic Synthesis of Natural Products

Keith Kyler Chemoenzymatic Synthesis

Manfred Schneider Enzymic Preparation of Enantiomerically PureCompounds

Monday, 4:00 - 6:00 p.m. Poster Session I.

Monday, 7:30 p.m. Synthesis of Commercially Important Compounds

Discussion Leader: John Frost

Hideaki Yamada Enzymatic Conversion of Nitriles into Useful Amidesand Acids

Hans Schoemaker Chemo-enzymatic synthesis of enantiomerically pureamino acids and related compounds

Tuesday, 9:00 a.m. Synthesis of Useful Compounds

Discussion Leader: Terry Lieb

Cary Morrow Enzymatic polymerizations

David Rozzell Cis-muconic Acid biosynthesis

George Whitesides Carbohydrate Synthesis

Tuesday 4:00 - 6:00 p.m, Poster Session I.

Tuecdrv 7:30 p.m. Mutagenesis

Discussion Leader: Byron Rubin

Frances Arnold Enzyme Engineering for non Aqueous solvents

Jeremy Knowles Manipulative Mutagenesis

Wednesday 9:00 a.m. Enzyme Models

Discussion Leader: Carl Johnson

T. Ross Kelly Bisubstrate Reaction Templates

Fraser Stoddart Enzyme Mimics to Molecular Self Assembly

Al Tramontano Catalytic Antibodies

Wednesday 4:00 - 6:00 p.m. Poster Session II.

Wednesday 7:30 p.m. Enzyme Structural Aspects

Discussion Leader: David Anton

Arieh Warshel Mutagenesis Calculations

Alexander Klibanov Irreversible Enzyme Inactivation

Thursday 9:00 a.m. Synthesis with Pathways

Discussion Leader: Bryan Jones

Greg Petsko Mandelate Racemase, Evolution of Metabolic Pathways

Charles Goodhue Pentaerythritol Pathway

Juan Ramos Metabolic Pathway Engineering

Thursday 4:00 - 6:00 p.m. Poster Session II.

Thursday 7:30 p.m. Alkane Activation

Discussion Leader: Jonathan Dordick

Howard Dalton Methane mono-oxygenase

John Lipscomb Methane mono-oxygenase

Friday 9:00 a.m. Engineering Aspects

Paul van Eikeren Membrane-Assisted Regeneration of NAD Cofactors

Jonathan Dordick Kinetics and Thermodynamics of Non-aqueous Enzvolog;-

Christian Wandrey Enzyme Reaction Engineering

Biocatalysis Gordon ConferencePoster Session Participants

Name Title Affiliation

Monday-Tuesday

Fredrik Bjorkling "Indirect Lipase Catalyzed Novo Nordisk A/SEpoxidation" Denmark

Debbie C. Crans "Spontaneously Formed Organic Colorado State Univ.Vandates Bind Better than Organic

Phosphates to Selective Enzymes:

Clucose-6-Phosphate Dehydro-

genase"

V. H. M. Elferink "Biotechnological Production of Andeno B. V.

S-2,2-dimethyl-l,3-dioxolane-4- The Netherlandsmethanol (S-DDM)"

Mark W. Empie "Biotechnological Resolution of International Bio-Racemic Isopropylidene Clycerol" Synthetics, Inc.

Kurt Faber "On the Catalytic Activity of Craz Univ. of Tech.Solid Enzymes in Organic Austria

Solvents"

Thomas Graycar "The Functional Consequences of Genencor, Int.

Introducing a Positive Chargein Close Proximity to theCatalytic Serine of Subtilisin"

A. B. Hanley I) "The Enzymic Production of AFRC Institute ofl-methoxyindolyl-3-methyl Food Research

isothiocyanate - An Unstable

Intermediate in Indole

Glucosinolate Breakdown"

2) "The Intrinsic ProteolyticActivity of Ubiquitin"

Ronald L. Hanson "Synthesis of L-P-Hydroxyvaline Bristol-Myers Squibb

by Leucine Dehydrogenase from

Bacillus Species"

David L. Hughes "Lipasc-Catalyzed Asymmetric Merck, Sharp & Dohme

Hydrolysis of Esters Having Research Laboratories

Remote Chiral/Prochiral Centers"

Ronald J. Huss "Biological Production of Bio-Technical

Phenylacetylene Cis-Dihydrodiol" Resources

Carl R. Johnson "Immobilization of Enzymes Wayne State Univ.

on Azlactone Beads"

Jerald K. Rasmussen "Azlactone-Functional ?olymer 3-M Heal-.i are

(to be adjacent Beads - A New Reactive Supportto Carl R. Johnson) for Proteins and Enzymes"

Romas J. Kazlauskas "A Rule to Predict Which McGill UniversitySecondary Alcohols areEfficiently Resolved byCholesterol Esterase, Lipase

from Pseudomonas cepacia, andLipase from Candida cylindracea"

Yu-Yen Iinko "Ester Synthesis by Various Helsinki UniversityH. -C. Yu Lipases" of Technology

FinlandWednesday-Thursday

Kevin Burgess "Biocatalytic Resolutions of Rice UniversitySulfoxide Esters"

Koji Kubota "Enzymatic Synthesis of Nucleo- Ajinomoto Co., Inc.side Analogs having Antiviral JapanActivity"

Terry K. Leib I) "Tyrosinase-catalyzed General Electric Co.Hydroxylations of AminoaromaticCompounds"

2) "Biological Reduction ofNitroaromatic Compounds"

David Mobley "Aspergillus-Catalyzed General Electric Co.Hydroxillations ofRiphenyls and Terphenyls"

Monica Palcic "Use of Glycosyltransferases Univ. of Albertafor the Synthesis of Oligo-saccharide Analogs"

Manfred Philipp "The Catalytic Hydrolysis CUNYof Mandelonitrile"

Sergio Riva "Regioselective Chemo- Instituto di Chimicaenzymatic Acylation of Degli OrmoniFlavonoid Glycosides" Italy

Enzo Santaniello "Enzymes in Organic Solvents: Univ. of MilanoEnantioselective Transesterifi- Italycation of A-Methyl SubstitutedPrimary Alcohols Catalyzed bya Lipase"

Peter Seifer-Wasserthal "Facile Preparation of Both Graz Univ. of Tech.Enantiomers of the UsefulIntermediate Dimethyl Maleic

Acid"

D. Stevenson "Enzymic Catalysis in Nitrile National ResearchChemistry" Council, Canada

Takayuki Uwajima "Chemo-Enzymatic Synthesis of Kyowa Hakko Kogyo Co.2-Leucovorin, an Augmentor of Tokyo, Japan5-Fluorouacil CytotoxicityAgainst Cancer"

Gregg Whited "Acyltransferase: A New Eastman KodakEnzyme for Chiral Synthesis" Research Laboratories

Edmund Ziomek "Aminoadipoyl Amidohydrolases: National ResearchA Use of Chromogenic Cephalo- Council, Canadasporin C Analogues"

Milton J. Zmijewski, Jr. "Enantioselective Acylation of Eli Lilly and Co.a Key Chemical Intermedi;.ce inthe Synthesis of Loracarbef, aNew Beta-lactam Antibiotic,Using Penicillin G Amidase"

Biocatalysis Sordon Conference

Poster Session Participants

Late Additions

Name r2itle Affiliation

Monday - Tuesday

M. Catriona Tedford "Novel Protein-Based Catalysts" Univ. ofStrathcyde

Thomas Roetig "Synth3sis of Hydrophobic FraunkhofesSubstances in Enzyme Membrane InstituteReactors"

Wednesday - Thursday

Ho Nam Chang "Continuous Production of Kaist,Penicillin Acylase from High South KoreaDensity Cell (ulture"

GORDON RESEARCH CONFERENC

BIOCATALYSIS

PLYMOUTH STATE COLLEGE - NORTH

JUNE 24-29, 1990

Anton, David 201/203 Caruso, Andrew 223

El Dupont De Nemours General Electric Corp.

Experimental Station PO Box 8

PO Box 80328 KI 5B15

Wilmington, DE 19850-0328 Schenectady, NY 12301

Arnold, Frances 526 Chang, Ho Nam 703

Caltech Kaist/ Dept. of Chem. Engineering

Chem. & Engineering PO Box 150

210-41 Seoul, Korea 130-650

Pasadena, CA 91125Cheung, Alex 210

Baresi, Larry 622 Coors Biotech

4800 Oak Grove Dr. 6204 South College Ave

MS 125-112 Fort Collins, CO 80525

Pasadena, CA 91109

Chmurny, A.B. 217

Bhupathy, M. 317 WR Grace & Co./ Research Div.

Merck & Co. 7379 Route 32

Rahway, NJ 08820 Columbia, MD 21044

Bjorklong, Frederick 205 Crans, Debbie 502

Novonordisk A/S Colorado State U.

Dept. of Natural Products Dept. of Chemistry

Novoave Ft. Collins, CO 80523

Bagovaero, Denmar 2880Dalton, H. 717

Boaz, Neil 206 University of Warwick

Eastman Kodak Lab/Corp. Research lab Coventry, England CV311TA

Bldg. 82, 5th Floor

Rochester, NY 14650-2110 Dicosimo, Robert 218

E1 Dupont De Nemours

Bommarius, Andy 302 Central R & D Dept.

Degussa AG Sect. FCO PO Box 80328

PO Box 1345 Wilmington, DE 19880-0328

6450 Hanau

West Germany Dodds, David 219

Sepracor Inc.

Bratzler, Robert OC 33 Locke Dr.

Sepracor Inc. Marborough, MA 01752

33 Locke Dr.

Marlborough, MA 01752 Dordick, Jonathan 303

University of Iowa

Bray, Brian 208 Dept of Chemical & Biochem. Eng.

Glaxo Inc. 125 B Chemistry Bldg.

5 Moore Dr. Iowa City, IOWA 52242

Synthetic Organic Chem.

RTP, NC 27709 Elferink, V H M 220

Burgess, Kevin 209 Andeno B.V.

Rice University Grubbenvorsterweg 8

Chem. Box 1892 5923 NX Venlo, The Netherlands

Houston, TX 77251

Knowles, Jeremy olL Linko, Yu-Yen o7

Harvard University/Dept of Chemistry Helsinki University of Tech.

12 Oxford St. Dept of Chem. Eng./Lab of Biotech & Food Eng.

Cambridge, MA 02138 Espoo, Finland SF-02150

Koritalla, S. 618 Lipscomb, John 305

Northern Reg. Research Ctr. University of Minnesota, Dept of Biochem.

1815 N. University 4-225 Millard Hall

Peoria, IL 61604 435 Delaware St., SEMinneapolis, IMN 55455-0326

Kurt, Faber 702

Graz University of Technology Margolin, Alexey 624

Stremaygasse 16/ Inst. of Org. Chem. Merrel Dow Research Institute

Graz, Austria 9550 N. Zionville Rd.

Indianapolis, IN 46268

Kubota, Koji OC

Ajinomoto Co. Masilamani, Divakar 625

Central Research Allieg-Signal, Inc./Biotech Dept.

1-1, Suzukicho, Kawasaki PO Box 1021R

Kawasaki, Japan 210 Morristown, NJ 07962

Kyler, Keith 306 Matuszko, Anthony 626

University of Miami/Dept of Chem. 4210 Elizabeth Lane

PO Box 249118 Annandale, VA 22003

Coral Gables, FL 33124McGarrity, John 402

Ladner, Wolfgang 711 Lonza AG

BASF AG COFO-3

Ludwigshafen, West Germany 6700 CH-3930 VISP Switzerland

Landis, Bryan 619 Mobley, David 403

Monsanto GE Corporate R & D700 Chesterfield Village Pkwy PO Box 8, KI/CEB-455

BPX, GG3N Schenectady, 14Y 12301

St. Louis, MO 63198

Morrow, Cary 404

Langrand, George 620 University of Mexico/Dept. of Chem.

State University of Utrecht Albuquerque, NM 87131

CBLE N 607

Padualaan 8, PO Box 80054 Nakamura, Charles 405

Utrecht 3508 TB The Netherlands Dupont CR & DPO Box 80328

Lanser, Alan 621 Wilmington, DE 19880-0328

USDA, NRRC

1815 N. University Navia, Manuel 706

Peoria, IL 61604 Vertex Pharmaceuticals Inc.40 Allison St.

Leib, Terry 622 Cambridge, MA 02139-4211

GE-CRD, Bio. Sciences Lab

PO Box 8 K-I 3B42 Nicholds, MJ 704

Schenetady, NY 12301 ICI Biological Products

PO Box 1

Lilly, Malcolm 517 Billingham, Cleveland UK

University College LondonDept of Chem. & Bio. Eng. Okumura, Masami GCTorrington Place Nitto Chem. Industry Co., Ltd

London, England WCIE 7JE 1-5-1 Marunouchi, Chiyoda-KuTokyo, Japan 100

Sauber, Klaus 418 Owajima, Takavuki 25Hoechst AG Tokyo Research Lab

PGE AI; H 780 Postfach 80 03 20 Kyowa Hakko Co., Ltd.

6000 Frankfurt, FRG 6230 3-6-6 Asahimachi

Machidashi, Tokyo Japan 194

Shutts, Bruce OCSchering-Plough Van Eikeren, Paul 3091011 Morris Ave Bend Research Inc.

U-2-B 64550 Research Rd.

Union, NJ 07083 Bend, OR 97701

Sih, Charles 422 Wallick, Dave 426

University of Wisconsin Dow Chemical Co.

School of Pharmacy Central Research

425 N. Charter St. 1707 Bldg.

Madison, WI 53706 Midland, MI 48674

Stevenson, David 519 Walts, Alan OC

Biotech Research Institute Genzyme Corp.

6100 Royal Mount Ave 75 Kneeland St.

Montreal Que. Canada H4P 2R2 Boston, MA 02111

Stoddard, Fraser 710 Wandrey, Christian 326

Sheffield University/Dept of Chem. Institute of Biotech/at Research Ctr Julich

Sheffield, England 53 7HF PO Box 1913, Leo-Brandt Strasse

D-5170 Julich FRG

Swanson, Paul 718

Dow Chemical Co./Central Research Co. Warshel, Arieh 325

Bldg. 1707 University of Southern CaliforniaMidland, MI 48674 Dept of Chemistry/University Park

Los Angeles, CA 90089

Tarbell, James OCE1 Dupont De Nemours & Co. Inc Wedekind, Frank 323

Engineering Dept. Boehringer Mannheim Corp.PO Box 6090 Bahnhofstrabe 9-15

Newark, DE 19714-6090 Tutzing, West Germany 8132

Tautvvdas, Kestutis 423 West, J. Blair 309

3M Biosciences Lab, 3M Center Bend Research Inc.

Bldg 270-2S-09 64550 Research Rd.

St. Paul, M2 55144 Bend, OR 97701

Tedford, Catriona 504 Whited, Gregory 322

University of Strathclyde Eastman Kodak Co.

Thomas Graham Bldg. Bldg. 82B, 4th Floor

Dept of P&A Chem, 295 Cathedral St. Life Sciences Research LabGlasgow, Scotland GI IXL Rochester, NY 14650-2118

Thompson, Jeffery 304 Whitesides, George 321

E1 DuPont De Nemours & Co. Harvard University/Dept. of Chem.

PO Box 80328 12 Oxford St.

Wilmington, DE 19880-0328 Cambridge, MA 02138

Tramontano, Alfonso 424 Yamada, Hideaki OC

Scripps Clinic & Research Fdn Kyoto University/Dept of Agricultureal Chem.Molecular 3iology Kitashirakawa-Oiwakecho Sakyo-Ku

10666 N. Torrey Pines Rd Kyoto, Japan 606

La Jolla, CA 92124

1990 GORDON RESEARCH CONFERENCE ON DIELECTRIC PHENOMENI

Final Progress Report

AFOSR Grant 69-oa27

The 1990 Gordon Conference on Dielectric Phenomena was heldat Holdermess School, Plymouth, New Hampshire from July 22 to 27.The conference had 76 participants of which 31% were fromoverseas. Countries represented included Great Britain, Germany,Argentina, Hungary, Canada, Japan, Italy as well as the U.S.Conferees were a mixture of scientists from universities,industries and national laboratories. A significant fractionwere first-time attendees at the Dielectric Phenomena conference.

As always in this Conference, there was a mix of scientistsinterested in microscopic (e.g. relaxation) and macroscopic (e.g.dielectric breakdown) phenomena in macromolecular and lowmolecular weight systems. The program consisted of twenty formalpresentations and a poster session of fifteen papers. Asignificant number of papers dealt (as usual at this Conference)with relaxation in glasses; new experimental techniques weredescribed which extended the frequencies into the gigahertzrange. Liquid crystals, both high and low molar mass, were dealtwith in three presentations. One session (3 papers) dealt withdielectric studies of the interaction of water with bothsynthetic and naturally-occurring polymers. Two papers dealtwith non-linear optical phenomena including applications toprocessing devices. The role of polymers and non-polar liquidsas dielectric insulators was covered from different points ofview in four contributions.

An informal assessment concluded that the Conference was asuccess in terms of quality of presentation, topics covered andaudience participation. At the business meeting there was aunanimous vote of approval for the Dielectric Phenemena GordonResearch Conference to be held again in the summer of 1992.

GORDON RESEARCH CONFERENCE 7/19

Dielectric Phenomena

Holdarness School

Frank E. Karasz (Chairman) J.T. Bendler (Vice-Chairman)

July 22-27, 1990

MONDAY A.M.

J.E. Anderson (Discussion Leader)

C. Austen Angell "Relation Between Structure and Non-exponential Relaxation(Arizona State) in Liquids and Glasses*

S. Sridhar (Northeastern "Dielectric Spectroscopy at Gigahertz Frequencies inUniversity) Liquids and Solids"

Marc L. Mansfield "Dielectric Relaxations of Dilute Polymer Solutions with(Michigan Molecular Application to the Poly(alkene sulfones)"Institute)

MONDAY P.M.

John T. Bendler (Discussion Leader)

Poster Session

TUESDAY A.M.

William J. MacKnight (Discussion Leader)

F. Kremer (Max Planck "Molecular Dynamics in Low Molar Mass and PolymericInstitute) Ferroelectric Liquid Crystals"

Graham Williams "Molecular Dynamics and Microscopic Alignment Behaviour of(Swansea, UK) Liquid Crystalline Polymers as Studied by Dielectric

Relaxation Spectroscopy"

Armand R. Tanguay (Univ. "The Critical Role of Dielectric Materials in Opticalof S. California) Information Processing and Computing Devices"

TUESDAY P.M.

Shiro Matsuoka (Discussion Leader)

Richard H. Boyd (Utah) "Subglass Dielectric Relaxations in Polymers"

H. Block (Cranfield Inst. "Fluid Flow, Polarization and Rheology"of Technology, UK)

WEDNESDAY A.M.

P. Keith Watson (Discussion Leader)

Erich E. Kunhardt "Electron Macro Kinetics in Liquids"(Polytechnic Univ.)

Martin A. Abkowitz "Electronic Transport in Polymeric Insulators"(Xerox)

T. Mizutani (Nagoya "High Field Phenomena in Insulating Polymeric Films"University)

WEDNESDAY P.M.

Robert L. Fulton (Discussion Leader)

P. Hedvig (Research "Dielectric and Mechanical Relaxation in CrosslinkedInst. for Plastics, Polymers"Budapest)

S. Havriliak (Rohm and "Dielectric Relaxation and Molecular Dynamics"Haas)

THURSDAY A.M.

Gyorgy Banhegyi (Discussion Leader)

Polykarpos Pissis "Dielectric Studies of Water in Polymers and Biopolymers"(National TechnicalUniv., Athens)

R. Pethig "Dielectric Studies of Protein-Water Interactions and(Bangor, UK) Associated Proton Transport Processes"

Douglas Kell "Linear and Nonlinear Dielectric Properties of Biological(Aberystwyth, UK) Materials"

THURSDAY P.M.

J.D. Hoffman (Discussion Leader)

David W. McCall "National Commission on Superconductivity"(Bell Labs)

FRIDAY A.M.

J. Pochan (Discussion Leader)

J. Keith Nelson "A Physical Basis for the Dielectric Design of Solid/Liquid(R.P.I.) Structures"

James M. O'Reilly "Study of Miscible and Immiscible Polymer Blends by(Kodak) Dielectric Relaxation"

George Stegeman (Univ. "Nonlinear Optical Phenomena in Thin Films"of Arizona)

B = BREWER GORDON RESEARCH CONFERENCE? M = MARSHALLC = COTTAGE. HOLDERNESS SCHOOL, PLYMOUTH, N,, , N = NiLESHAM = HMMO DIELECTRIC PHE(U A O L = URSEH = HOIT JULY 23-27, 1990 0 = OFF CAMPUSK = KELSER R = RATHBUNL = LIVERMORE S = SARGENTLo = LOOKWOOD W = WEBSTER

Abkowitz, Martin B4 Bendler, John H4Xerox Corp. GE R&D Center800 Phillips Road KI, Room 4BMWebster, NY 14580 Schenectady, NY 12301

Al Iinn. .John N27 Berborinn, lob, 1121Microwaves Research Group Saint Joseph's Univ.Dept. Physics, Kings College Chemistry DeptLondon, WC2 5600 City Line AveUK Philadelphia, PA 19131

Anderson, James N6 Block, H. N24Ford Motor Company Cranfield Inst. of Tech.Scientific Research School of Industrial ScienceP.O. Box 2053 Drop 3083 Centre for Molecular ElectronicsDearborn, MI 48121-2053 Cranfield, Bedford MK43 01K

EnglandAngell, C.A. N21Arizona State Univ., Chemistry Boyd, Richard Lo4Tempe, AZ 85287 Univ. of Utah

Science Dept. 304 EMRUArenbeck, Helmut H1 Salt Lake City, UT 84124Papierfabrik Oberschmitten GMBHRhoenstr. 13 Carlini, Carlo N506478 Nidda, Hessen 6478 Univ. of BolognaWest Germany Dipt Di Chimica Ind Le E Dei Materiali

Viale Risorgimento 4Avakian, Peter B3 Bologna 40136Dupont Company ItalyCRD, Experimental StationP.O. Box 80356 Cole, Robert RIOWilmington, DE 19880-0356 Brown Univ.

Chemistry Dept., Box HBanhegyi, Gyorgy N6 Providence, RI 02912Bio-Pharm Research & Development Ltd.Konyves Kalamn KRT. 76 Connolly, Michael R29H-1087 Budapest, Hungary PL Thermal Sciences, Inc.

160 Old Farm RoadBaron, Maximo C4 Amgerst, MA 01002Facultad De Ciencias Exactas Y NaturalesPabellon 1 - C Universitaria Dissado, Leonard N4Buenos Aires 1428 Kings CollegeArgentina Dept. of Physics

StrandBeatty, C.L. NI London WC2R 2LC101 Rhines Hall EnglandDept. of Mat. Sci. & Eng.Univ. of Fl. Fulton, Robert R8GainesviI c, FT 32A'1 Florida State Univ.

Dept. of ChemistryTallahassee, FL 32306-3006

-2-

Graybeal, Jark R9 Jonscher, Andrew N23Virginia Tech. Royal Holloway CollegeDept. of Chemistry Physics Dept.Davidson Hall Egham HillBlacksburg, VA 24061-0212 Egham, Surrey TW20 OEX

EnglandGerschel, Alain 0Universite Paris Sud Klnin, T.L. Ham3ChImile Physique Iloechst-Celanese Co.Bat 490 Research Division91405 Orsay 86 Morris AveFrance Summit, NJ 07901

Hager, Nathaniel III H8 Karasz, Frank Ham5Armstrong World Industries Univ. of MassachusettsResearch & Development Polymer Science & EngineeringLancaster, PA 17604 GRC 701

Amherst, MA 01003Havriliak, Stephen B2Rohm & Haas Co. Kell, Douglas N2Bristol Research Labs Univ. College of WhalesP.O. Box 219 Dept. of Biological ScienceBristol, PA 17007 Aberystwyth

Dyfed, Wales SY233DAHedvig, Peter NI United KingdomPlastics Research InstituteBudapest XIV Hungaria KRT 114 Kennedy, Alvin RiDept. Radiation Chemistry Dow Chemical Co.Budapest 1950 Bldg. 1712Hungary Midland, MI 48674

Hoffman, Drew M8 Kremer, F. M6Stanford Univ. Max Planck Institut F. PolmerforschungChemical Engineering Dept. Postfach 3148Stanford, CA 94305 Mainz 6500

FRGHoffman, John LolMichigan Molecular Inst. Kunhardt, Erich H71910 W. St. Andrews Rd. Polytechnic UniversityMidland, MI 48640 Weber Research Institute

Route 110Ichikawa, Kimio M7 Farmingdale, NY 11735Univ of Massachusettsc/o Dr. MacKnight, Room 701, PSE, LGRC MacKnight, William R30Amherst, MA 01003 Univ. Of Mass.

Amerst, MA 01003Johnson, Edward H3AT&T Bell Labs Mansfield, Marc MlRoom 70-214 Michigan Molecular Institute600 Mountain Ave. 1910 West St. AndrewsMurray Hill, NJ 07974 Midland, MI 48640

Jones, Marvin 0 Marand, Eva BI3M Virginia Polytechnic Inst.3M Center Chemistry Dept.Bldg. 260-3-02 Blacksburg, VA 24060St. Paul, MN 55144

-3-

Mason, James N25 O'Reilly, James H2Atochem North America Eastman Kodak Co900 First Ave Corporate Research LabKing of Prussia, PA 19406 Bldg 82-64DD

Rochester, NY 14650-2110

Maisuoka, S. R26

AT&T Bell Labs Pethig, Ronald M3Room 7F202 University of WalesMurray Hill, NJ 07974 School of Electronics

Dean Street

McCall, David Nol-2 Bangor, GWYNNEDD LL57 IUTAT&T Bell Labs United KingdomRoom 1A-263600 Mountain Ave. Pfeiffer, Matthias H28Nurray Hill, NJ 07974 Technische Hochschule

Physikalische Chemie IMizutani, Teruyoshi Kl Petersenstrasse 20Nagoya Univ. Darmstadt 6100Dept. of Elect. Engineering FRGFuro Cho, ChikusaNagayo 464-01 Pissis, P. H5Japan National Tech Univ of Athens

Dept. of Physics

Mopsik, Frederick Ham4 Zografou CampusNatl Inst of Standards & Technology GR 15773 AthensPolymers Division, B320, Bldg. 224 GreeceGaithersburg, MD 20899

Pochan, John R2Nachlis, Warren M2 Eastman KodakGE CR & 0 Bldg 82 604BP.O. Box 8, K-i 4B22 Rochester, NY 14650Schenectady, NY 12301

Richards, MarkNeill, John R29 Microwave Research GroupDept of Polymer Science & Engineering Physics Dept , King's CollegeUniv. of Massachusetts Stand, London WC2R 2LSAmherst, MA 01003 U.K.

Nelson, Keith H7 Rolla, Pierangelo N5Rensselaer Polytechnic Inst University of PisaDept. of Electric Power Eng Departimento Di Fisica110 8th Street Piazza Torricelli 2Troy, NY 12180-3570 Pisa 56100

ItalyNettelblad, Bo H6ABB Corporate Research Sarjeant, W.J. N26S-72118 Vasteas SUNY/ ABSweden Dept. of Elec. Engineering

Bonner Hall, Room 312, North CampusNozaki, Ryusuke R7 Buffalo, NY 14260Universite Du Quebec A Trois RivieresDept. De Physique, C.P. 500 Sedita, Joseph H5Trois Rivieres, Quebec G9A 5H7 Eastman Kodak Co.

Canada Corporate Research Labs

Bldg. 82, Room 6400O'Dwyer, J.J H2 Rochester, NY t4650-2110SUNY at OswegoPhysice Dept.Oswego, NY 13126

-4-

Shlesinger, Michael R21 Wei, Yanzhen Ham6

412 Green Pasture Dr. Northeastern Univ.

Rockville, MD 20852 Physics Dept.360 Huntington Ave

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Kodak ParkStarkweather N4 Mail Stop 02021E. I. Du Pont De Nemours & Co., INC Rochester, NY 14650

Central Research & Devel. Dept.

Experimental Station, Bldg. 356 Williams, Graham H27

Wilmington, DE 19880-0356 Univ. College of Swansea

Chemistry Dept.Stegeman, George R3 Singleton Park

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Waseda Univ. Yang, Arthur H23

Honjyo Senior High School Armstrong World Industries, Inc

1136 Okuboyama Nishiomita R&D

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Japan Lancaster, PA 17604

Tanguay, Armand Jr. C2 Zheng, Qing R28

520 Seaver Science Center Arizona State Univ.Univ. of Southern California Dept. of Chemistry

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THE CHAIRMAN'S REPORT ON THE GORDON CONFERENCE

ON PHYSICAL ELECTROCHEMISTRY

JULY 29 - AUGUST 3, 1990

COLBY JUNIOR COLLEGE

NEW LONDON, NEW HAMPSHIRE

Report on Gordon Con. :ence:

The meeting was divided into five sections: the first was on the structureof the interfacial region, (Dr. David Schiffrin from the University ofSouthhampton chaired this session.)

The second section was on experimental approaches to quantum aspects of thedouble layer. This section was chaired by Professor Joseph Hupp fromNorthwestern University. The session on nuclear electrochemistry, an unusualtopic, was chaired by Dr. Fritz Will, and that on new experimental methods byWilliam O'Grady. Finally, the bioelectrochemistry section on the Friday morningwas chaired by Professor Adam Heller from the University of Texas.

All these sectior had their outstanding moments and a few of these may berelated. Dr. McLaughlin, for example, speaking on the structure of interfaces,made clear that he thought that the Gouy-Chapman relationship was still true,even though it was not applicable to double layers at the metal-solutioninterface or the semiconductor interface. He managed to apply it by moving thefiducial plain out into the solution.

Dr. Heegar at the University of California was electrifying in the eveningwhen he told us about the progress that had been made with electronicallyconducting polymers and made clear that he thought it likely that the polymerswould exceed metals and their conductivity. It was a m.tter of the length of thesegment in which the electron was allowed to flow. If the segment was longenough then eventually the conductance of a fiber could rise to about 5 ordersof magnitude greater than that of a metal! This would make hot superconductivityunnecessary.

The new field of nuclear electrochemistry was, of course, as usual, one ofgreat controversy but the encouraging thing was that the Chairman had justreturned from a trip to Japan where he had got to talk to some of the 50 JapanesegrouM, amounting to 1000 workers who are now researching cold fusion in thatcountry. Dr. Will reported the neutron bursts about one million per second (l0greater than observed here) and he told us of the formation of tritium by gomeof these groups.

Then, on the Thursday, the most impressive paper turned out to be that inthe evening by Dr. Bruce Schardt. The Chairman described it as a tour de forcebecause of the vigorous way in which Dr. Schardt described the best way to obtaingood pictures at atomic resolution.

On the Friday morning the most outstanding paper was that given by Dr.Hill, - who has recently been appointed a Fellow of the Royal Society, - who toldus of his researches in electron transfer kinetics to substances of biologicalorigin.

The Gordon Conference in Physical Electrochemistry of 1990 was said by someto be the most outstanding of the three conferences which have been held so farand it is hoped that the new Chairman, Professor Hector Abruna from the CornellUniversity, will be joined by the freshly elected Vice Chairman, Dr. WilliamO'Grady, of the Naval Research Laboratory in Washington, for the 1992 Conference.

1ci

2 8 AUG N40

Chairman's Final Progress Report

1990 Gordon Research Conference on Organometallic Chemistry

Air Force Office of Scientific Research Contract No. 90-NC-047

The 1990 Gordon Research Conference on Organometallic Chemistry was held from June24 - 29, 1990 at Salve Regina College in Newport, R. I. A total of 134 participants wasselected from approximately 150 applications. Attendance was well divided betweenacademic (88), industrial (43) and national laboratory (3) participants. Thirteen participantswere from countries outside the United States, and 12 were women. A copy of theparticipants list is attached.

Based on its success in last year's program, the conference retained the policy of schedulinga relatively large number of short (30-minute) invited talks combined with substantialamount of time for discussion following each presentation. This format minimized thetendency of speakers to rehash published work and (as the Gordon Conferenceadministration suggests) encourages them to focus on their most important and timelyresults. In addition, 57 participants chose to present recent research results in poster form.Because of the large number of posters a full poster session was arranged for each eveningof the conference except Sunday. These sessions were held in the informal discussion area,which has been equipped by Salve Regina college with air conditioning, tables, excellentlighting, and a refreshment facility. Because of the quality of the contributions andfacilities, the posters attracted a great deal of attention and generated much lively discussionduring the conference.

Another successful policy continued from last year was the six speaking slots open until thefirst evening of the meeting. At that time, the best poster submissions were selected by acommittee appointed by the chairman, and the authors of these posters were invited to givetalks rather than poster presentations in the open time slots. One change from last year wasthat these "poster talks" were distributed throughout the five days of the meeting, rather thanbeing cc-centrated on Friday morning. This procedure was again very successful; some ofthe most exciting and timely discoveries presented at the meeting appeared in these last-minute selections. Including the poster talks, 32 oral presentations were made at themeeting. A copy of the complete program is enclosed with this report.

Individuals were invited to the conference in three categories: invited speakers, sessionchairs, and members of the committee to select the six poster talks. Because almost all theinvitations were accepted, this resulted in attendance by many of the most importantscientists in organometallic chemistry and allied fields. In assembling the speaker list weworked to maintain a balance of mainstream topics (e.g., transition metal and main grouporganometallic synthesis and reaction mechanisms; homogeneous catalysis- applications toorganic synthesis) withi new areas in which organometallic chemistry is currently orpotentially having a significant impact (synthesis of new materials such as thin films andpolymers, interfacial phenomena, surface science, new physical techniques).

Judging from informal comments of participants, the best talks at the meeting came fromboth mainstream organometailic and interdisciplinary areas. Highlights of the meeting wereJohn Ellis and John Cooper's presentations on the preparation of novel new anionic"negative oxidation state" organometallic complexes, Robert Miller's talk on the chemistryof polysilanes, the lecture by Tobin Marks on the use of lanthanide complexes as catalystsuseful in organic synthesis, Eric Jacobsen's poster talk on a dramatic new method forcatalytic asymmetric epoxidation of unfunctionalized alkenes, Morris Bullock's poster talk

i n , mu m m m mmun n n mamimu e nnnn m uam muulnn nuY

on radical intermediates involved in the reactions of metal hydrides with alkenes, SylviaCeyer's presentation on the mechanism of methane activation on metal surfaces, andBradford Wayland's lecture on C-H bond reactions of porphyrin complexes. Two invitedspeakers also received important awards just before the meeting--Harry Gray received thePriestly medal of the American Chemical Society, and Susan Thomas was awarded theMeldola medal of the Royal Society of Chemistry. We were especially gratified that Dr.Gray was able to participate. In true Gordon Conference tradition, he arrived Saturdayevening, spent the entire week at the meeting, and gave an excellent talk Thursday eveningon platinum photochemistry and photocatalysis. Gray's enthusiasm was mirrored by thehigh degree interaction of the other participants.

To provide an indication of the quality of the conference, as well as the sort of interactionstimulated among the attendees, attached to this report are copies of letters received by thechairman from several of the participants in early July. Although we have not yet receivedthe formal questionnaires filled out at the meeting, it seems clear from these letters and othercomments made to the organizers that the 1990 Gordon Conference on OrganometallicChemistry was exceptionally successful.

Attachments

GORDON CONFERENCE ON ORGANOMETALLIC CHEMISTRY

Salve Regina College, Newport, R. I.

June 24 -29, 1990

Chair: Robert G. Bergman; Vice Chair: Alfred P. Sattelberger

Poster talk selection committee: Maurice Brookhart, Henry E. Bryndza,Nancy M. Doherty, John A. Gladysz, Jack R. Norton, Peter T. Wolczanski

Monday, June 25

Session 1: Exploratory Organometallic Synthesis, Reactivity, andMechanisms

Chair: Denis Forster (Monsanto Company)

Heinz Berke (University ef Zurich)"How to Make Transition Metal Hydrogen Bonds More Reactive: A Conceptual Approachand Its Experimental Consequences"

Thomas C. Flood (University of Southern California)"Mechanisms of Bond Activations by Soluble Complexes of Iridium and Osmium"

John E. Ellis (University of Minnesota)

"New Synthetic Routes to Highly Reduced Organometallics"

Two papers selected from poster submissions

Session 2: Applications to Organic Synthesis and/or Chiral OrganometallicChemistry

Chair: Richard J. Piccolini (Rohm and Haas Company)

Yoshihiko Ito (Kyoto University)"Asymmetiric Aldol Reactions of a-Isocyanocarboxylates and Related IsocyanoDerivatives Catalyzed by Chiral IB Metal Complexes"

N. John Cooper (University of Pittsburgh)"The Application of Diastereomeric Tungstenocene Complexes Containing Chiral MetalCenters to the Study of Organometallic Reactions"

S.E. Thomas (University of Warwick)"Reactivity of Heterodiene Metal Cabonyl Complexes"

Tuesday, June 26

Session 3: Main Group Organometallic Chemistry

Chair: John E. Bercaw (California Institute of Technology)

2

Dr. Peter Jutzi (University of Bielefeld)"Tt-Complexation in Main-Group-Chemistry - Some Recent Results"

Lawrence R. Sita (Carnegie Mellon University)"New Chemistry of Polycyclic Organostannanes"

Gerard Parkin (Columbia University)"Poly(pyrazolyl)hydroborato Alkyl Derivatives of the s- and p-block Metals"

Two papers selected from poster submissions

Session 4: Organometallic Sulfur Chemistry

Chair: Eric R. Evitt (Catalytica Associates, Inc.)

Thomas B. Rauchfuss (University of Illinois at Urbana-Champaign)"Studies on Organoruthenium and Organorhodium Sulfides"

Robert J. Angelici (Iowa State University)"Reactions of Thiophene in Organometallic Complexes"

E.J.M. de Boer (Koninklijke/Shell-Laboratorium)

"Reactions of Rhenium Oxides with Alkynes"

Wednesday, June 27

Session 5: Materials, Solid State, Polymers

Chair: John P. Fackler Jr. (Texas A&M University)

Herbert D. Kaesz (University of California, Los Angeles)"Deposition of Transition Metal Thin Films from Organometallic Precursors"

R.D. Miller (IBM)"Soluble High Molecular Weight Polysilanes: Science and Applications"

Ralph G. Nuzzo (AT&T)"The Molecular Self-Assembly of Organic Thiols on Au(l 11) and the Application of TheseMaterials in Condensed Phase Studies"

One paper selected from poster submissions

Session 6: Lanthanides, Actinides, etc.

Chair: B. Duane Dombeck (Union Carbide Corporation)

Tobin J. Marks (Northwestern University)"New Homogeneous Catalysis with Organo-Lanathanides"

James C. Stevens (Dow Chemical Company)"Selective Propylene Dimerization Catalyzed by Organouranium Compounds"

3

F. G. N. Cloke (University of Sussex)"High and Low Oxidation State Organo-f-element Compounds Derived from BulkyAromatic Ligands"

Thursday, June 28

Session 7: Techniques, Theory

Chair: Cynthia M. Friend (Harvard University)

John D. Simon (University of Colorado)"Picosecond Studies of the Photodissociation of Chromium Hexacarbonyl"

Sylvia T. Ceyer (Massachusetts Institute of Technology)"The Activation of CH4 and the Synthesis of C6H6 from CH4 on Ni(1lI)"

Charles M. Lieber (Columbia University)"Scanning Tunneling Microscopy Studies of the Structural and Electronic Effects of MetalSubstitution in Inorganic Materials"

One paper selected from poster submissions

Session 8: Inspirations

Chair: Malcolm LH. Green (University of Oxford)

John A. Osborn (University of Strasbourg)"Catalysts for the Chemo- and Enantio- Selective Reduction of Imines"

Harry B. Gray (California Institute of Technology)"Binuclear Iridium and Platinum Photochemistry and Photocatalysis"

Friday, June 29

Session 9: Methane, Aikane Chemistry

Chair: Patricia L. Watson (E.I. duPont de Nemours)

Bradford B. Wayland (University of Pennsylvania)"C-H Bond Reactions of Rh(II) and Ir(II) Porphyrin Complexes"

D. Michael Heinekey (Yale University)"Reactions of Methane with Rhenium Complexes"

Jay A. Labinger (California Institute of Technology)"Practical Approaches to Alkane Activation: From Methane Mono-Oxygenase toOrganometallic"

Wrap-up session

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1990 Organometallic Gordon Research Conference Poster Schedule

Chair: Robert G. Bergman

Vice-Chair: Alfred P. Sattelberger

Session 1 - Monday, June 25

1. "Metal-Catalyzed Oxidation of Para-Substituted Phenolics. Approaches toBenzoquinones"Joseph J. BozellChemical Conversion Research BranchSolar Energy Research Institute

2. "Synthesis, Structure and Reactivity of Metallabenzenes"John R. BleekeDepartment of ChemistryWashington University

3. "Some Applications of Diolate-Derived Chiral Auxiliaries in Organo-TransitionMetal Chemistry"Joseph A. HeppertDepartment of ChemistryUniversity of Kansas

4. "The Binding of Heteroaromatic Nitrogen Compounds with Cp*Rh 2+, CpRu + , andCp*Ru+ Complexes and the Role of T11, N-Bonded Complexes in theRegioselective Hydrogenation of the Nitrogen Ring"Richard FishDepartment of ChemistryLawrence Berkeley Laboratory

5. "A New Carbon-Hydrogen Bond Activation Reaction: 'Vinylic' Deprotonation ofCationic Rhenium Alkene Complexes"John A. GladyszDepartment of ChemistryUniversity of Utah

6. "Unprecedented Reactions Between Transition Metal Alkynyl Complexes andNucleophiles: Synthesis and Crystal Structures of Fe2(CO)(I-CO){*i.-G:T13-

C(O)C(R)-CIC(O)R'])(TI 5-C5H5 )(I5 -C5 R"5) (R = CH3, C-CSiMe 3 ; R'= n-Bu, CH3 ,C6H5; R" = H, CH 3 )"Andrew WongDepartment of ChemistryOccidental College

7. "Photooxidation of Metal Carbynes: Metal Radical Reactivity VersusRearrangement of the Carbyne Ligands in the 17-Electron Intermediates"Lisa McElwee-WhiteDepartment of ChemistryStanford I Inivrsity

8. "Quantum Mechanical Exchange of Hydrides in Solution. Proton-ProtonExchange Couplings and Rotational Tunneling in Transition Metal Polyhydrides"Kurt W. ZilmDepartment of ChemistryYale University

9. "Metal Alkyl Versus Metal Vinyl Insertion Reactions"Kenneth M. DoxseeDepartment of ChemistryUniversity of Oregon

10. "Catalytic Hydroboration: The Study of a Model Iridium System"Joseph S. MerolaDepartment of ChemistryVirginia Polytechnic Institute and State University

11. "Transformations of Organo-Iridium Phosphide Complexes"Michael D. FryzukDepartment of ChemistryUniversity of British Columbia

12. "Synthesis, Structure and Reactivity of the Encapsulated Metallocenes[(i-Pr)4C5H]2Ca and [(i-Pr)4CsH]2 Ba"Timothy P. HanusaDepartment of ChemistryVanderbilt University

13. "Oxygen Containing Metallacycles From Ruthenium Enolates"Robert G. BergmanDepartment of ChemistryUniversity of California, Berkeley

14. "Formation of 2,3-Butanedione in the Carbonylation of a Binuclear RhodiumMethyl Complex Under Extremely Mild Conditions"Richard EisenbergDepartment of ChemistryUniversity of Rochester

15. "Carbon-Oxygen Bond Activation. The Deoxygenation of Phenols by OxygenAtom Transfer to CO"Clifford P. KubiakDepartment of ChemistryPurdue University

16. "Mass Spectroscopic Studies of Large Gold Clusters"John P. FacklerDepartment of ChemistryTexas A&M University

Session 2 - Tuesday, June, 26

17. "Asymmetric Synthesis and Applications of C2-Symmetrical ChiralCyclopentadienyl Metal Complexes"Ronald L. HaltermanDepartment of ChemistryBoston University

18. "Characterization of the Cationic Radicals {H3RU3[CXI(CO)9.nLn} + , where X =OMe, SEt or NMe 2 ; L = PPh3 , AsPh3 ; n = 2 or 3"Jerome B. KeisterDepartment of ChemistrySUNY Buffalo

19. "Mechanism of Alkyl Migration in Iron-Manganese Alkoxy-CarbeneDecomposition"William H. HerschCUNY Queens College

20. "The First Electron-Transfer Catalyzed Ligand Substitution Which is Faster for anEven- Versus the Parent Odd-Electron System"Rinaldo PoliDepartment of ChemistryUniversity of Maryland

21. "Rhodium-Catalyzed C-H Bond Functionalization. I. Thermal AldehydeDecarbonylation (and Alkene Carbonylation?) I1. Insertion of Acetylenes inBenzene C-H Bonds."Alan S. GoldmanDepartment of ChemistryRutgers University

"2. "Air-Sensitive Procatalysts for Ring-Opening Metathesis Polymerization ofNorbornene-Type Monomers"Larry F. RhodesResearch and Development CenterBF Goodrich Company

23. "Synthesis of Tungsten Oxo and Alkylidene Complexes Using OrganosiliconReagents"James M. MayerDepartment of ChemistryUniversity of Washinton

24. "Structure and Reactivity of Bimetallic Fischer Carbene Complexes"M. G. FinnDepartment of ChemistryUniversity of Virginia

25. "Hydrogen Atom Transfer Reactions of Transition Metal Hydrides. Kinetics andMechanism of the Hydrogenation of c-Cyclopropyl Styrene"R. Morris BullockDepartment of ChemistryBrookhaven National Laboratory

26. "Evidence for an c-Agostic Transition State for Olefin Insertion"John E. BercawDivision of Chemistry and Chemical EngineeringCalifornia Institute of Technology

27. "Bimetallic Hydroformylation: A Dramatic Example of HomobimetallicCooperativity"George G. StanleyDepartment of ChemistryLouisiana State University

28. "Cleavage of Dialkylsiloxanes by Trimethylaluminum"Andrew R. BarronDepartment of ChemistryHarvard University

29. "Transition Metal S20 Complexes and Transition Metal-Mediated ThiosulfinateEster Synthesis"Mark E. WelkerDepartment of ChemistryWake Forest University

30. "C-S Bond Cleavage by Rhodium: A Homogeneous Model for MechanisticStudies of the Hydrodesulfurization (HDS) Reaction"William D. JonesDepartment of ChemistryUniversity of Rochester

31. "Reactions of Mo/Co/S Clusters Relevant to HDS Catalysis"M. David CurtisDepartment of ChemistryThe University of Michigan

32. "Reactions of 1-Sila-3-Metallacyclobutane Complexes of Zirconium"Jeffrey L. PetersenDepartment of ChemistryUniversity of West Virginia

Session 3 - Wednesday, June 27

33. "C-C Bond Cleavage Reactions in Platinum Glycolate Complexes"Mark AndrewsDepartment of ChemistryBrookhaven National Laboratory

34. "E-H Activation Chemistry: Marked Differences in Ir-H Reactivity in ComplexesResulting From 9-H, C-H, N-H and O-H Oxidative Addition to Iridium"Joseph S. MerolaDepartment of ChemistryVirginia Polytechnic Institute and State University

35. "Simple Molybdenum and Tungsten Carbyne Complexes"Joseph L. TempletonDepartment of ChemistryUniversity of North Carolina

36. "Alkylation of Highly Reduced r-henium Oxo Complexes [Re(O)(RC-CR) 2]Na:Evidence for Radical and SN2 Pathways"James M. MayerDepartment of ChemistryUniversity of Washington

37. "Molecular Analogs of Multiple Quantum Wells?"Paul J. FaganCentral Research and Development DepartmentE. I. DuPont de Nemours and Company

38. "Chemical Vapor Deposition of Gold"Fred McCormickCorporate Research3M

39. "Molecular Precursors for Iridium Phosphide and the Synthesis of SmallSemiconductor Clusters in Solution"Klaus H. TheopoldDepartment of ChemistryCornell University

40. "Organometallic Complexes with Sterically Distressed Ligands: The 1,2,3-tri-t-butylcyclopentadienyl Ligand"Russell P. HughesDepartment of ChemistryDartmouth University

41. "The Ladder Structure of [ButCH 2)2TaN]5.NH 3.C7H8 and its Relationship toCubic Tantalum Nitride"Peter T. Wolczanski

Department of ChemistryCornell University

42. "Surface Organometallic Chemistry"Jeffrey SchwartzDepartment of Ch'enistryPrinceton University

43. "Cp* 2V2Br4 - A New Synthon in Mid-Valent Vanadium Chemistry. Preparation ofof Cp* 2V2(CH 3)4, a Complex with Four Bridging Methyl Groups"Louis MesserleDepartment of ChemistryUniversity of Iowa

44. "Cobalt Half-Sandwich Complexes with Intramolecular C-C Double BondCoordination"Jun OkudaAnorganisch-Chemisches InstitutTechnische Universit~t Mnchen

45. "KineticZs and Mechanism of Electron-Transfer from Pentacarbonylrhenate to MetalCarbonyl Dimers'Jim D. AtwoodDepartment of ChemistrySUNY Buffalo

46. "Acyclic Diene Metathesis Polymerization Chemistry"James M. BoncellaDepartment of ChemistryUniversity of Florida

Session 4 - Thursday, June 28

47. "A Puzzle in Para-Hydrogen-Induced Polarization. Signal Enhancement inAsymmetric Hydrogenation by Addition of a Second Substrate"Richard EisenbergDepartment of ChemistryUniversity of Rochester

48. Hydrogen Bonding Properties of Transition Metal Fluorides"Thomas RichmondDepartment of ChemistryUniversity of Utah

49. "Metal Tellurates: Synthesis, Structure and Reactivity"John ArnoldDepartment of ChemistryUniversity of California, Berkeley

50. "Interaction of Aldehydes with Monomeric Aluminum Complexes"Andrew BarronDepartment of ChemistryHarvard University

51. "Unsaturated Mixed-Metal Complexes: Synthesis, Structures and Reactivity"Michael J. ChetcutiDepartment of ChemistryUniversity of Notre Dame

52. "Rearrangement and C-X Bond Formation Using Nickel Complexes"Allan R. PinhasDepartment of ChemistryUniversity of Cincinnati

53. "Electrocyclic Reactions of (C5H5)Fe(pentadienoyl) Complexes"Neil T. AllisonDepartment of ChemistryUniversity of Arkansas

54. "IR Analysis of Anion Metathesis. Lability of Low Valent d6 Complexes"Norris W. HoffmanDepartment of ChemistryUniversity of South Alabama

55. "Reaction of Cyclopropylcarbene-Tungsten Complexes with Alkynes: A NewSeven-Membered Ring Synthesis"James W. HerndonDepartment of ChemistryUniversity of Maryland

56. "Structural Data from Solid -State Deuterium NMR Spectroscopy"Leslie ButlerDepartment of ChemistryLouisiana State University

57. "Neutral Dihydrogen Complexes of Iridium"Craig JensenDepartment of ChemistryUniversity of Hawaii

GORDON RESEAR CH CONFERENCES

ORGANOETALLIC CHEMISTRY

June 25-29, 1990

Salve Regina College, Newport, RI

Registration List

Anthony G. Abatjoglou non-resident Andrew R. Barron Miley 104

Union Carbide Corporation Chemistry Department

Tech Center, 770-420 Harvard University

P. 0. Box 8361 12 Oxford Street

South Charleston, WV 25303 Cambridge, MA 02138

Neil T. Allison 102B Thomas R. Beattie 314A

Dept. of Chemistry & Biochemistry Merck Sharp & Dohme Research Laboratories

University of Arkansas Basic Medicinal Chemistry Dept.

Fayetteville, AR 72701 125 East Lincoln AvenueRahway, NJ 07065

Mark Andrews 102B

Dept. of Chemistry John E. Bercaw 106B

Brookbaven National Laboratory Dept. of Chemistry. 127-72

Bldg. 555 California Institutes of Technology

Upton, NY 11973 Pasadena, CA 91125

Robert J. Angelici 103B Robert G. Bergman 209A

Dept. of Chemistry Dept. of Chemistry

Iowa State University University of California

Ames, IA 50011 Berkeley, CA 94720

Libby Angelici 103B Heinz Berke 107BAnorganisch-Chemisches Institut

John Arnold 211A University of Zurich

Chemistry Department Winterthurerstr. 190

University of California CH-8057 Zurich, Switzerland

Berkeley, CA 94720John R. Bleeke 201B

Jim D. Atwood 205A Dept. of Chemistry, Box 1134

Dept. of Chemistry Washington University

SUNY at Buffalo One Brookings Drive

Buffalo, NY 14214 St. Louis, MO 63130

Owen Bailey 05B Amy I. Blough 303A

Amoco Chemical Company Research Center

Research & Development Dept. Hercules, Inc.

P. 0. Box 3011 Wilmington, DE 19894

Naperville, IL 60566James M. Boncella 202B

Tina Bailey 05B Dept. of ChemistryUniversity of Florida

Alan C. Barker 314A Gainesville, FL 32611

ICI PharmaceuticalsHurdsfield Industrial Estate Joseph J. Bozell 107B

Macclesfield, Cheshire SK1O 2NA Solar Energy Research Institute

England 1617 Cole Blvd.Golden, CO 80401

-2-

Maurice Brookhart 203B E. J. M. DeBoer 101BDept. of Chemistry Koninklijke/Shell LaboratoriumUniversity of North Carolina PX DepartmentChapel Hill, NC 27599-3290 Postbus 3003

1003 AA Amsterdam, The Netherlands

Henry E. Bryndza 309AE. I. du Pont de Nemours & Co. Nancy M. Doherty 208BExperimental Station, E262/219 Dept. of ChemistryP. 0. Box 80262 University of CaliforniaWilmington, DE 19880-0262 Irvine, CA 92717

R. Morris Bullock 204B B. D. Dombek 208ADept. of Chemistry Union Carbide Corporation

Brookhaven National Laboratory P. 0. Box 8361Upton, NY 11973 South Charleston, WV 25303

Mark J. Burk 312A Kenneth It. Doxsee 313AE. I. du Pont de Nemours & Co. Dept. of ChemistryCRD, Experimental Station University of OregonWilmington, DE 19880-0328 Eugene, OR 97403

Leslie Butler Miley 111 Richard Eisenberg 210BLouisiana State University Dept. of ChemsitryDept. of Chemistry University of RochesterBaton, Rouge, LA 70803 Rochester, NY 14627

Stephen A. Butter non-resident John E. Ellis 209BU. S. Department of Energy Dept. of ChemistryChemical Sciences Division University of MinnesotaOffice of Basic Energy Sciences 207 Pleasant Street, SEWashington, DC 20545 Minneapolis, MN 55455

Sylvia T. Ceyer 305B Paul E. Ellis, Jr. non-residentDept. of Chemistry, Room 6-225 Sun Oil Co.Massachusetts Institute of Technology Research & Development77 Massachusetts Avenue P. 0. Box 1135

Cambridge, MA 02139 Marcus Hook, PA 19061

Michael J. Chetcuti 206B Eric R. Evitt 211B

Dept. of Chemistry & Biochemistry Catalytica, Inc.University of Notre Dame 430 Ferguson Drive, Bldg. 3Notre Dame, IN 46556 Mountain View, CA 94043

F. G. N. Cloke 207B John P. Fackler, Jr. 101ASchool of Chemistry Dept. of ChemistryUniversity of Sussex Texas A&M UniversityBrighton BNI 9QJ, England College Station, TX 77843

N. John Cooper 107A Paul J. Fagan 202BDept. of Chemistry E. I. du Pont de Nemours & Co.

University of Pittsburgh Experimental Station, CR&DD234 Chevron Science Center Box 80328Pittsburgh, PA 15260 Wilmington, DE 19809

M. Da',id Curtis 211A J. W. Faller Milev 102

Dept. of Chemistry Dept. of ChemistryUniversity of Michigan Yale University

Ann Arbor, MI 48109-1055 P. 0. Box 6666

New Haven, CT 06511-8118

-3-

Frank J. Feher 208B Alan S. Goldman 214BDept. of Chemistry Dept. of ChemistryUniversity of California Rutgers UniversityIrvine, CA 92717 P. 0. Box 934

Piscatowdy, NJ 08855

I. G. Finn 313ADept. of Chemistry Harry Gray 204AUniversity of Virginia Chemistry 127072McCormick Road California Institute of TechnologyCharlottesville, VA 22901 Pasadena, CA 91125

Richard H. Fish non-resident Malcolm L. Green 207BLawrence Berkeley Laboratory Inorganic Chemistry Lab70-1IOA Oxford UniversityUniversity of California South Parks RoadBerkeley, CA 94720 Oxford OXI 3QR, England

Thomas C. Flood 213A Marifaith Hackett 205BDept. of Chemistry Amoco Chemical CompanyUniversity of Southern California Research & Development Dept.Los Angeles, CA 90089-0744 P. 0. Box 3011

Naperville, IL 60566PeterC. Ford Miley 103Dept. of Chemistry Ronald L. Halterman Miley 107University of California Dept. of ChemistrySanta Barbara, CA 93106 Boston University

590 Commonwealth AvenueDenis Forster 207A Boston, MA 02215Monsanto CompanyR&D Timothy P. Hanusa 312A800 North Lindbergh Blvd. Dept. of ChemistrySt. Louis, MO 63167 Vanderbilt University

Box 1822BCynthia Friend 212B Nashville, TN 37235Dept. of ChemistryHarvard University Michael Heinekey 214B12 Oxford Street Dept. of ChemistryCambridge, MA 02138 Yale University

225 Prospect Street11. D. Fryzuk 214A New Haven, CT 06511-8118Dept. of ChemistryUniversity of British Columbia Joseph A. Heppert 206B2036 Main Mall Dept. of ChemistryVancouver, BC V6T 1Y6, Canada- University of Kansas

Lawrence, KS 66045Kevin P. Gable 215BDept. of Chemistry James W. Herndon 215BOregon State University Dept. of Chemistry & BiochemsitLyCorvallis, OR 97331-4003 University of Maryland

College Park, MD 207.2John A. Gladysz 213BDept. of Chemistry William H. Hersh 213BUniversity of Utah Dept. of Chemistry & BiochemistrySalt Lake City, UT 84112 'ns College of CUNY

65-30 Kissena Blvd.Stephen Godleski 305A Flushing, NY 11367-0904Eastman Kodak CompanyResearch Labs6th Floor, Bldg. 82CRochester, NY 14650-0211

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Norris W. Hoffman 301B P. Jutzi 304BDept. ofChemistry Faculty of ChemistryUniversity of South Alabama University of BielefeldMobile, AL 36688 4800 Bielefeld, West Germany

Jeffrey B. lloke 311A Herbert D. Kaesz 301BEnglehard Corporation Dept. of Chemistry & BiochemistryRCD Room 312 University of CaliforniaMenlo Park, CN 28 Los Angeles, CA 90024-1569Edison, NJ 08818

William C. Kaska Miley 113Istvan T. Horvath Miley 114 Dept. of ChemistryExxon Research & Engineering University of CaliforniaRoute 22 E Santa Barbara, CA 93106Annandale, NJ 08801

Susan Kegley 210AM. S. Howie 302B Dept. of ChemistryEthyl Corporation Williams CollegeTechnical Center, Research & Development Williamstown, MA 01267P. 0. Box 14799Baton Rouge, LA 70898 Jerry Keister 205A

Dept. of ChemistryHarriett C. Howie 302B University of Buffalo

Buffalo, NY 14214Russell P. Hughes 309BChemistry Department Donald R. Kelsey 104BDartmouth College Shell Development CompanyHanover, NH 03755 New Chemical Technology

Exploratory PolymersYoshihiko Ito 206A P. 0. Box 1380Dept. of Syntheti . Chemistry Houston, TX 77251Kyoto UniversityKyoto 606, Japan Rein U. Kirss 308A

Dept. of ChemistryEric N. Jacobsen 303B Northeastern UniversityDept. of Chemistry, Box 55-5 Boston, MA 02115University of Illinois470 Roger Adams Lab Cliff Kubiak 210BUrbana,