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![Page 1: GC/MS [ 2 TOTM]DOIP TOTM ¹ 50 (mainlib) 1,3-Benzenedicarboxylic acid, bis(2-ethylhexyl) ester 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 0 50 100 65 70 76 83 104](https://reader033.pdfslide.tips/reader033/viewer/2022060720/6080136892b0281d087f6ff2/html5/thumbnails/1.jpg)
-GC/MS
[ 2-
TOTM]
4 RoHS2 2019 7
2- TOTM IEC62321-8
-GC/MS TOTM
2- DEHP
IEC62321-8 Edition1.0 340ºC
DEHP 100
240ºC 5 min
TOTM DEHP DEHP
-GC/MS
TOTM
Key word RoHS IEC 62321-8 DEHP TOTM -GC/MS
Authors
![Page 2: GC/MS [ 2 TOTM]DOIP TOTM ¹ 50 (mainlib) 1,3-Benzenedicarboxylic acid, bis(2-ethylhexyl) ester 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 0 50 100 65 70 76 83 104](https://reader033.pdfslide.tips/reader033/viewer/2022060720/6080136892b0281d087f6ff2/html5/thumbnails/2.jpg)
2
DIBP n-
DBP BBP
2- DEHP 4
RoHS2 2019 7
2-
TOTM IEC62321-8
-GC/MS [1]
[2] TOTM
DEHP
NMIJ CRM 8152-a
PVC DEHP
TOTM 30% THF 50 mg/mL
10 µL
50ºC 10
GC/MS /
1.5 m
0.15 mm GC 300 C
MS
EGA/PY-3030D
PY-GC 300 C
GC Agilent 7890B
DB-5ms
15 m 0.25 mm 0.1 m Agilent 122-5511
1.5 ml/min
1/50
300 C
80 C 50 C/min 200 C
15 C/min 300 C 2 min
MSD 280 C
MS Agilent 5977B Inert Plus
280 C
EI etune
150 C
SIM/
m/z 50-400
SIM 1
30 msec
0.7
1 SIM
m/z
m/z
DIBP 223 149, 205
DBP 223 149, 205
BBP 206 91, 149
DEHP 279 149, 167
PVC DEHP
GC/MS
DEHP 1 0
ppm IEC 62321-8 340
C -GC/MS [1] [2]
TICC 1 2-
EHTM DEHP 2-
DOIP 2-
DOTP TOTM EHTM
TOTM
DEHP
100 500 ppm
TOTM DEHP
TOTM
DEHP
3
TOTM DEHP
TOTM
DEHP TOTM 10wt% PVC EGA
2 300 350 C PVC
400 450 C PVC
C7H7+; m/z 91
DEHP 200 320 C 250 370
C TOTM
340 C
TOTM DEHP
5 min 200 300 C
![Page 3: GC/MS [ 2 TOTM]DOIP TOTM ¹ 50 (mainlib) 1,3-Benzenedicarboxylic acid, bis(2-ethylhexyl) ester 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 0 50 100 65 70 76 83 104](https://reader033.pdfslide.tips/reader033/viewer/2022060720/6080136892b0281d087f6ff2/html5/thumbnails/3.jpg)
3
DEHP 3
200 C 80%
220 C 100%
PVC
TOTM DEHP
3 200 240 C
50 ppm 240 C
TOTM DEHP
DEHP
240 C
4 100 mg/kg PVC 500 µg
MDL [3]
10 50 mg/kg IEC 62321-8
1.
IEC62321-8 Edition1.0 340 C
TOTM PVC
TOTM DEHP
100
240 C 5 min
TOTM DEHP
DEHP
-GC/MS
TOTM
2.
3.
º
1. IEC62321-8 Edition1.0 (2017).
2. Agilent GC/MS , Agilent Technologies,
publication GC-MS-201609NK-002
www.agilent.com/chem/jp
3.
Agilent Technologies, publication 5990-7651JAJP
www.agilent.com/chem/jp
DEHP
TOTM
m/z 36
TICC
m/z 91
m/z 149
m/z 167
m/z 305
100 200 300 400 500 600
/ ºC
0
20
40
60
80
100
120
140
160
180
60
70
80
90
100
180 200 220 240 260 280 300 320
/ ºC
TO
TM
DE
HP
PV
C/
pp
m
DE
HP
/ %
(replib) tri(2-Ethylhexyl) trimellitate
60 90 120 150 180 210 240 270 300 3300
50
100
57
71
83
104
113
121
148
176
193
211
220 260 276
305
323
O
O
O O
O O
(replib)
1,2
,4-B
enze
netr
icarb
oxylic a
cid
, cyclic 1
,2-anhydri
de, nonyl
este
r
60
90
120
150
180
210
240
270
300
0
50
100
55
69 7
5
83
103
126
148
162
175
193
233
248
O
O
O
O
O
(mainlib) 1,3-Benzenedicarboxylic acid, bis(2-ethylhexyl) ester
60
90
120
150
180
210
240
270
300
330
360
050
100
57
70
83
104 1
12
132
149
1671
79
203221
261
2792
89
318
361
O
OO
O DOIP
TOTM
×50
(mainlib) 1,3-Benzenedicarboxylic acid, bis(2-ethylhexyl) ester
60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 3600
50
100
57
65
70
76
83
104
112
121
132
149167
179203 217 231
261
279
289 304 318 333 361
O
O
OO
(replib)
1,4
-B
enze
nedic
arb
oxylic a
cid
, bis
(2-eth
ylh
exyl)
este
r
60
80
100
120
140
160
180
200
220
240
260
280
300
320
340
360
0
50
100
57
657
0 76
83
1041
12 1
21
132
149
167
179
203
215
231
261
279
291
304
318
333
361
O
O
O
O
(replib) Bis(2-ethylhexyl) phthalate
60 80 100 120 140 160 180 200 220 240 260 280 300 3200
50
100
57
65
71
76
83
93
104
113
122 132
149
162
167
179 261
279
O O
O
O
DEHP
EHTM
DOTP
![Page 4: GC/MS [ 2 TOTM]DOIP TOTM ¹ 50 (mainlib) 1,3-Benzenedicarboxylic acid, bis(2-ethylhexyl) ester 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 0 50 100 65 70 76 83 104](https://reader033.pdfslide.tips/reader033/viewer/2022060720/6080136892b0281d087f6ff2/html5/thumbnails/4.jpg)
www.agilent.com/chem/jp
0120-477-111
© Agilent Technologies, Inc. 2017
Printed in Japan, September 20, 2019
GC-MS-201909HO-001
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