Graphical Abstract: Eur. J. Inorg. Chem. 5/2004

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  • SHORT COMMUNICATIONSE. Kirillov, C. W. Lehmann, A. Razavi,943J.-F. Carpentier*

    [5:1-(3,6-tBu2Flu)SiMe2NtBu]Y(1-NC5H6)-(py)2: A 1,4-Hydride-Addition Product toPyridine that Provides Evidence for the FirstFluorenyl(hydrido)metal (Group 3) Complex

    Keywords: Fluorenyl / Hydrides / Insertion /Pyridine / Yttrium

    X. Wang, J. Zhuang, Y. Li*946

    Pr6O11 Single-Crystal Nanotubes from aMolten-Salt Synthetic Method

    Keywords: Lanthanides / Molten salts / Nanotubes /Three-dimensional structures / X-raydiffraction

    A. Villanueva, M. C. Morales-Varela,949E. Ruiz-Hitzky*

    Microwave-Assisted Synthesis of MPS3Materials (M Mn, Cd) Using a Dewar-Ampoule Device

    Keywords: Transition metals / Microwave-assistedreactions / Layered compounds / Synthesisdesign / Solid-phase synthesis

    Z.-E. Lin, J. Zhang, S.-T. Zheng,953G.-Y. Yang*

    A Novel Open-Framework Zinc Phosphite,Zn3(HPO3)4Ni(en)2(H2O)2, Templated by aTransition-Metal Complex

    Keywords: Open framework / Inorganic solid / Zinc /Nickel / Template synthesis

    920 2004 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.eurjic.org Eur. J. Inorg. Chem. 2004, 919926

  • J. Zhang, S. Gao,* C.-M. Che*956

    A Blue Photoluminescent 2-D CoordinationPolymer Constructed by Dinuclear Zinc(II) Sub-units [Zn2(oz)2] [Hoz 2-(2-Hydroxyphenyl)-2-oxazoline] and Dicyanamide

    Keywords: Zinc / Photoluminescence / Dinuclear sub-unit / Polymer / Thermal stability

    F. Bigoli, M. C. Cabras, P. Deplano,*960M. L. Mercuri, L. Marchio, A. Serpe,E. F. Trogu

    On the Use of the Bis(diiodine) Adduct of 1,4-Dimethylperhydro-1,4-diazepine-2,3-dithione(Me2dazdt) to Recover Liquid Mercury Pro-ducing [Hg(Me2dazdt)I2] in a One-Step Reaction

    Keywords: Mercury / S ligands / Iodine / Adducts /Oxidation

    T. Brasey, A. Buryak, R. Scopelliti,964K. Severin*

    Synthesis of a Metallamacrocyclic Re(CO)3Complex Using a Tridentate Bridging Ligand

    Keywords: Hostguest chemistry / Metallamacro-cycles / Rhenium / Silver

    FULL PAPERS

    W. Uhl,* A. El-Hamdan969

    Reactivity of Organoelement Subhalides of Gal-lium and Indium GaGa and InIn BondsBridged by Carboxylato Ligands

    Keywords: Carboxylate ligands / Gallium / Indium /Subvalent compounds

    Eur. J. Inorg. Chem. 2004, 919926 www.eurjic.org 2004 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim 921

  • C. R. Mayer,* M. Herve, H. Lavanant,973J.-C. Blais, F. Secheresse

    Hybrid Cyclic Dimers of Divacant Heteropoly-anions: Synthesis, Mass Spectrometry (MALDI-TOF and ESI-MS) and NMR MultinuclearCharacterisation

    Keywords: Polyoxometalates / Bridging ligands / Massspectrometry / Organic-inorganic hybridcomposites

    P. P. Pescarmona, J. C. van der Waal,978T. Maschmeyer*

    Fast, High-Yielding Syntheses of Silsesqui-oxanes Using Acetonitrile as a Reactive Solvent

    Keywords: Silsesquioxanes / NMR spectroscopy /Mass spectrometry / Solvent effects

    S. Ross, T. Weyhermller, E. Bill, E. Bothe,984U. Flrke, K. Wieghardt, P. Chaudhuri*

    Asymmetric Heterodinuclear FeIIIMII (M Zn,Cu, Ni, Fe, Mn), CoIIIFeII and FeIICoIII Species:Synthesis, Structure, Redox Behavior, andMagnetism

    Keywords: Electrochemistry / Heterodinuclear com-plexes / Iron / Magnetic properties /Pyridine-2-aldoxime

    R. C. Smith, J. D. Protasiewicz*998

    Systematic Investigation of PPV AnalogueOligomers Incorporating Low-Coordinate Phos-phorus Centres

    Keywords: Oligomers / Phosphorus / Phosphaalkenes

    T. D. Keene, H. R. Ogilvie,1007M. B. Hursthouse, D. J. Price*

    One-Dimensional Magnetism in New, LayeredStructures: Piperazine-Linked Copper andNickel Oxalate Chains

    Keywords: Magnetic properties / Layered compounds /Hydrothermal synthesis / Coordinationnetworks

    922 2004 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.eurjic.org Eur. J. Inorg. Chem. 2004, 919926

  • K. Kandasamy, S. Kumar, H. B. Singh,*1014R. J. Butcher, K. T. Holman

    Synthesis, Structural Characterization andFluorescence Properties of OrganoseleniumCompounds Bearing a Ligand Containing BothBulky and Nonbonding Groups The FirstObservation of Both Intramolecular SeN andSeO Interactions in a Diselenide Structure

    Keywords: Selenium / Intramolecular coordination /X-ray diffraction / Fluorescence

    X.-C. Huang, S.-L. Zheng, J.-P. Zhang,1024X.-M. Chen*

    Synthesis, Structure and PhotoluminescentStudies of a Novel Supramolecular [Ag(phen)-(CN)](phen) Complex

    Keywords: Density functional calculations /N ligands / Pi interactions / Photoluminesc-ence / Silver

    A. Brunetta, G. Strukul*1030

    Epoxidation versus BaeyerVilliger Oxidation:The Possible Role of Lewis Acidity in the Controlof Selectivity in Catalysis by Transition MetalComplexes

    Keywords: Lewis acids / Homogeneous catalysis /Oxidation / Peroxides

    Y.-Q. Tian,* L. Xu, C.-X. Cai, J.-C. Wei,1039Y.-Z. Li, X.-Z. You*

    Determination of the Solvothermal SynthesisMechanism of Metal Imidazolates by X-raySingle-Crystal Studies of a PhotoluminescentCadmium(II) Imidazolate and Its IntermediateInvolving Piperazine

    Keywords: Cadmium / Crystal engineering / Fluor-escence / Nitrogen heterocycles / Zeoliteanalogues

    Eur. J. Inorg. Chem. 2004, 919926 www.eurjic.org 2004 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim 923

  • V. Kirin, P. W. Roesky*1045

    Dinuclear Potassium-Chromium and Potassium-Tungsten Carbonyl Complexes

    Keywords: Chromium / Coordination chemistry /N Ligands / Potassium / Tungsten

    X.-B. Cui, J.-Q. Xu,* Y. Li, Y.-H. Sun,1051G.-J. Yang*

    Hydrothermal Synthesis and Characterization ofa Novel Sinusoidal Layer Structure ConstructedFrom Polyoxometalates and Coordination Com-plex Fragments

    Keywords: Hydrothermal synthesis / Magnetic proper-ties / Polyoxometalates / X-ray diffraction

    J. H. K. Yip,* J. Wu, K.-Y. Wong,*1056K. P. Ho, L. L. Koh, J. J. Vittal

    Electronic Interactions in Dinuclear Platinumand Palladium Ethynylferrocene and Ferrocenyl-vinylidene Complexes

    Keywords: Platinum / Palladium / Ferrocene / Alkenes

    D. Cauzzi, C. Graiff, R. Pattacini,1063G. Predieri,* A. Tiripicchio, S. Kahlal,J.-Y. Saillard

    Cluster Growth Reactions with Selenido-Car-bonyl Clusters Synthesis, Characterisationand Theoretical Study of the Dimetallic closoClusters [WRu3(4-Se)2(-CO)4(CO)6(L)2] (L Phosphane) and of the Donor-Acceptor Adduct[(CO)5W(4-Se)Ru3(3-Se)(CO)7{P(CH2Ph)-Ph2}2]

    Keywords: Ruthenium / Tungsten / Molybdenum /Cluster compounds / Selenium

    J. L. Shaw, T. B. Cardon, G. A. Lorigan,1073C. J. Ziegler*

    Synthesis and Characterization of a Series of(Diphenyldipyrazolylmethane)copper Complexesas Possible Precursors to Type I Blue CopperProtein Active Site Models

    Keywords: Copper / N ligands / Pyrazolylmethanes /Scorpionates

    924 2004 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.eurjic.org Eur. J. Inorg. Chem. 2004, 919926

  • J.-M. Camus, J. Andrieu,* P. Richard,1081R. Poli

    Allylpalladium(II) Complexes with Aminophos-phane Ligands: Solution Behaviour and X-rayStructure of cis-[Pd(3-CH2CHCHPh){Ph2P-CH2CHPhNH(2,6-C6H3iPr2)}][PF6]

    Keywords: Allyl ligands / N,P ligands / syn-antiexchange / Palladium

    B. Longato,* G. Bandoli, A. Dolmella1092

    Hydroxo and Oxo Complexes of Platinum(II)Stabilized by Phosphanes: Synthesis andCharacterization X-ray Structures of cis-[L2Pt-(-OH)]2(NO3)2 (L PMe2Ph, PMePh2) and[{cis-(PMe2Ph)2Pt}3(-O)2]Cl2

    Keywords: Platinum / Oxo and hydroxo ligands / X-raydiffraction / Deprotonation reactions

    J. Olkowska-Oetzel, P. Sevillano,1100A. Eichhfer, D. Fenske*

    Binary and Ternary Cluster Complexes Contain-ing Gold-Selenium, Gold-Indium-Selenium andGold-Gallium-Tellurium Synthesis andStructures of [Au5Se2(PPh3)4]Cl, [(Au3Se)2{Ph2P-(CH2)6PPh2}3]Cl2, [Au10Se4{Ph2P(CH2)5PPh2}4]-InCl5, [Au4(SeInCl3)2{Ph2P(CH2)5PPh2}2], [Au2-(TeGaCl3){Ph2P(CH2)6PPh2}]2 and [Au8Se4In-{Ph2P(CH2)2PPh2}4](InCl4)3

    Keywords: Cluster compounds / Gallium / Gold /Indium / Selenium / Tellurium

    R. Kumar P., A. K. Singh,* R. J. Butcher,1107P. Sharma, R. A. Toscano

    Tellurated Schiff Bases Formed from {2-[(4-Methoxyphenyl)telluro]ethyl}amine and Bis(2-aminoethyl) Telluride with o-Hydroxyaceto-phenone: Synthesis and Complexation Reactionswith HgII, PdII and RuII Crystal Structures ofthe Ligands, [Ru(p-cymene)Cl{H2NCH2CH2-TeC6H4-4-OCH3}]ClH2O and [RuCl{4-Me-OC6H4TeCH2CH2NHCH(CH3)C6H4-2-O}]

    Keywords: Schiff bases / Ruthenium / Tellurium /X-ray diffraction / Synthetic methods

    Eur. J. Inorg. Chem. 2004, 919926 www.eurjic.org 2004 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim 925

  • H. Nth,* M. Warchhold1115

    Sodium Hydro(isothiocyanato)borates: Syn-thesis and Structures

    Keywords: Crown compounds / Sodium / NMRspectroscopy / Borates

    P. Antoniotti, S. Borocci, F. Grandinetti*1125

    Nitrogen Trifluoride as a Bifunctional LewisBase: Implications for the Adsorption of NF3 onSolid Surfaces

    Keywords: Ab initio calculations / Nitrogen trifluor-ide / Lewis bases / Isomeric structures

    926 2004 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.eurjic.org Eur. J. Inorg. Chem. 2004, 919926