JAEA-Data/Code 2010-005jolissrch-inter.tokai-sc.jaea.go.jp/pdfdata/JAEA-Data... · 2013. 2. 25. · ii ii JAEA-Data/Code 2010-005 Development of Grout Materials for a Geological Disposal

JAEA-Data/Code

2010-005

Geological Isolation Research UnitGeological Isolation Research and Development Directorate

地層処分研究開発部門地層処分基盤研究開発ユニット

July 2010

Japan Atomic Energy Agency 日本原子力研究開発機構

福岡奈緒美新貝文昭三浦律彦延藤遵山田勉内藤守正

Naomi FUKUOKA, Fumiaki SHINKAI, Norihiko MIURA, Jun NOBUTOTsutomu YAMADA and Morimasa NAITO

地層処分を対象としたグラウト材料の開発Development of Grout Materials for a Geological Disposal System

for High-level Radioactive Waste

JAEA

-Data/C

ode

i i

JAEA-Data/Code 2010-005

*1 *2

*3

(2010 3 26 )

1920

19

pH 11

319-1194 4-33

*1 *2 *3


*1 *2

*3

(2010 3 26 )

1920

19

pH 11

319-1194 4-33

*1 *2 *3

ii ii


Development of Grout Materials for a Geological Disposal System for High-level Radioactive Waste

Naomi FUKUOKA , Fumiaki SHINKAI , Norihiko MIURA*1, Jun NOBUTO*2, Tsutomu YAMADA*3and Morimasa NAITO

Geological Isolation Research Unit

Geological Isolation Research and Development Directorate Japan Atomic Energy Agency

Tokai-mura, Naka-gun, Ibaraki-ken

(Received March 26 , 2010)

This project was carried out by the Geological Isolation Research and Development Directorate of Japan Atomic Energy Agency with the fund of Agency for Natural Resources and Energy of the Ministry of Economy, Trade and Industry in 2007 and 2008.

High-level radioactive waste (HLW) management in Japan is based on the multi-barrier concept, composed of the engineered barrier system and the surrounding geological formations (natural barrier). Although cementitious materials are commonly used for rock support, lining, and grouting, their pH plume are considered to have an adverse effect on long-term safety of a geological disposal system. In addition, during the emplacement of waste package with buffer material, it is required to limit amount of groundwater inflow into a disposal pit or tunnel to a certain level by grouting because the bentonite clay buffer is easy to swell in time by contact with the groundwater. Therefore, it is necessary to develop new grout materials with penetrability for smaller fractures.

We have developed new grout materials, which have better penetrability and are environmentally more friendly than exinting cementitious grout materials since FY 2007. This report shows the most appropriate composition of new grout materials to be suitable for the in-situ experiment based on the result of indoor test. Keywords: Grout Material, Low Alkaline Cement, Colloidal Silica, Superfine Spherical Silica,

Geoogical Disposal System This work was carried out by JAEA under the contract with the Natural Resources and Energy Agency, Ministry of Economy, the Trade and Industry

Special Topic Researcher 1 Obayashi Corporation 2 Shimizu Corporation 3 Toda Corporation


Development of Grout Materials for a Geological Disposal System for High-level Radioactive Waste

Naomi FUKUOKA , Fumiaki SHINKAI , Norihiko MIURA*1, Jun NOBUTO*2, Tsutomu YAMADA*3and Morimasa NAITO

Geological Isolation Research Unit

Geological Isolation Research and Development Directorate Japan Atomic Energy Agency

Tokai-mura, Naka-gun, Ibaraki-ken

(Received March 26 , 2010)

This project was carried out by the Geological Isolation Research and Development Directorate of Japan Atomic Energy Agency with the fund of Agency for Natural Resources and Energy of the Ministry of Economy, Trade and Industry in 2007 and 2008.

High-level radioactive waste (HLW) management in Japan is based on the multi-barrier concept, composed of the engineered barrier system and the surrounding geological formations (natural barrier). Although cementitious materials are commonly used for rock support, lining, and grouting, their pH plume are considered to have an adverse effect on long-term safety of a geological disposal system. In addition, during the emplacement of waste package with buffer material, it is required to limit amount of groundwater inflow into a disposal pit or tunnel to a certain level by grouting because the bentonite clay buffer is easy to swell in time by contact with the groundwater. Therefore, it is necessary to develop new grout materials with penetrability for smaller fractures.

We have developed new grout materials, which have better penetrability and are environmentally more friendly than exinting cementitious grout materials since FY 2007. This report shows the most appropriate composition of new grout materials to be suitable for the in-situ experiment based on the result of indoor test. Keywords: Grout Material, Low Alkaline Cement, Colloidal Silica, Superfine Spherical Silica,

Geoogical Disposal System This work was carried out by JAEA under the contract with the Natural Resources and Energy Agency, Ministry of Economy, the Trade and Industry

Special Topic Researcher 1 Obayashi Corporation 2 Shimizu Corporation 3 Toda Corporation

iii iii

JAEA-Data/Code 2010-005 JAEA-Data/Code 2010-005

1. ....................................................................................................................................... 1

1.1 .............................................................................................................................. 1

1.2 ...................................................................................................................... 1

2. ..................................................................................................................... 2

2.1 ...................................................................................... 2

2.1.1 .......................................................................................................... 2 2.1.2 ............................................................................. 2 2.1.3 .......................................................................................................... 2 2.1.4 .................................................................................... 2 2.1.5 ................................................................................................... 3

2.2 .................................................................................. 4

2.2.1 ......................................................................................................................... 4 2.2.2 ............................................................................................................................ 9 2.2.3 .......................................................................................................................... 13 2.2.4 .......................................................................................................................... 26 2.2.5 .............................................................................................................................. 39

2.3 ............................................................................................................. 41

2.3.1 ....................................................................................................................... 41 2.3.2 .......................................................................................................................... 46 2.3.3 .......................................................................................................................... 48 2.3.4 .......................................................................................................................... 61 2.3.5 .............................................................................................................................. 79

2.4 ....................................................................................... 80

2.4.1 ....................................................................................................................... 80 2.4.2 .......................................................................................................................... 82 2.4.3 .......................................................................................................................... 84 2.4.4 .......................................................................................................................... 85 2.4.5 .............................................................................................................................. 88

3. ................................................................................................................... 89

3.1 ................................................................................ 89

1. ....................................................................................................................................... 1

1.1 .............................................................................................................................. 1

1.2 ...................................................................................................................... 1

2. ..................................................................................................................... 2

2.1 ...................................................................................... 2

2.1.1 .......................................................................................................... 2 2.1.2 ............................................................................. 2 2.1.3 .......................................................................................................... 2 2.1.4 .................................................................................... 2 2.1.5 ................................................................................................... 3

2.2 .................................................................................. 4

2.2.1 ......................................................................................................................... 4 2.2.2 ............................................................................................................................ 9 2.2.3 .......................................................................................................................... 13 2.2.4 .......................................................................................................................... 26 2.2.5 .............................................................................................................................. 39

2.3 ............................................................................................................. 41

2.3.1 ....................................................................................................................... 41 2.3.2 .......................................................................................................................... 46 2.3.3 .......................................................................................................................... 48 2.3.4 .......................................................................................................................... 61 2.3.5 .............................................................................................................................. 79

2.4 ....................................................................................... 80

2.4.1 ....................................................................................................................... 80 2.4.2 .......................................................................................................................... 82 2.4.3 .......................................................................................................................... 84 2.4.4 .......................................................................................................................... 85 2.4.5 .............................................................................................................................. 88

3. ................................................................................................................... 89

3.1 ................................................................................ 89

iv iv


3.2 ............................................................................................................. 89

3.3 ....................................................................................... 89

...................................................................................................................................... 90

1 ............................................................................................... 92

2 ................................. 97

3 ........................... 255

4 2007 .................................... 283

5 2008 .................................... 296

93

103

265

303

321

3.2 ............................................................................................................. 89

3.3 ....................................................................................... 89

...................................................................................................................................... 90

1 ............................................................................................... 92

2 ................................. 97

3 ........................... 255

4 2007 .................................... 283

5 2008 .................................... 296

93

103

265

303

321

v v


CONTENTS

1. Introduction ................................................................................................................................. 1

1.1 Background and purpose ....................................................................................................... 1

1.2 Structure of the report........................................................................................................... 1

2. Development of grout materials ................................................................................................. 2

2.1 Kind and Application of grout materials .............................................................................. 2

2.1.1 Kind of grout materials .................................................................................................. 2 2.1.2 Low alkaline cement ....................................................................................................... 2 2.1.3 Colloidal silica ................................................................................................................. 2 2.1.4 Superfine Spherical silica ............................................................................................... 2 2.1.5 Application of grout materials ........................................................................................ 3

2.2 Low alkaline cement .............................................................................................................. 4

2.2.1 Outline ............................................................................................................................. 4 2.2.2 Material ........................................................................................................................... 9 2.2.3 Method ........................................................................................................................... 13 2.2.4 Result ............................................................................................................................. 26 2.2.5 Summary ....................................................................................................................... 39

2.3 Colloidal silica ...................................................................................................................... 41

2.3.1 Outline ........................................................................................................................... 41 2.3.2 Material ......................................................................................................................... 46 2.3.3 Method ........................................................................................................................... 48 2.3.4 Result ............................................................................................................................. 61 2.3.5 Summary ....................................................................................................................... 79

2.4 Superfine Spherical silica ................................................................................................... 80


3. Summary and Future issues .................................................................................................... 89

3.1 Low alkaline cement ............................................................................................................ 89

CONTENTS

1. Introduction ................................................................................................................................. 1

1.1 Background and purpose ....................................................................................................... 1

1.2 Structure of the report........................................................................................................... 1

2. Development of grout materials ................................................................................................. 2

2.1 Kind and Application of grout materials .............................................................................. 2

2.1.1 Kind of grout materials .................................................................................................. 2 2.1.2 Low alkaline cement ....................................................................................................... 2 2.1.3 Colloidal silica ................................................................................................................. 2 2.1.4 Superfine Spherical silica ............................................................................................... 2 2.1.5 Application of grout materials ........................................................................................ 3

2.2 Low alkaline cement .............................................................................................................. 4

2.2.1 Outline ............................................................................................................................. 4 2.2.2 Material ........................................................................................................................... 9 2.2.3 Method ........................................................................................................................... 13 2.2.4 Result ............................................................................................................................. 26 2.2.5 Summary ....................................................................................................................... 39





3. Summary and Future issues .................................................................................................... 89

3.1 Low alkaline cement ............................................................................................................ 89

vi vi




References................................................................................................................................... 90

Appendix 1 : Test result table for basic characteristics .......................................................... 92

Appendix 2 : Viscosity test result data of low alkaline cement .............................................. 97

Appendix 3 : Injection test result of low alkaline cement using visible parallel plate model.................................................................................................................................................. 255

Appendix 4 : Test result of colloidal silica for basic characteristics(FY2007) ..................... 283




References................................................................................................................................... 90

Appendix 1 : Test result table for basic characteristics .......................................................... 92

Appendix 2 : Viscosity test result data of low alkaline cement .............................................. 97

Appendix 3 : Injection test result of low alkaline cement using visible parallel plate model.................................................................................................................................................. 255



93

103

265

303

321

93

103

265

303

321

vii vii


2.2-1 ................................................................................................................... 4 2.2-2 ............................................................................... 5 2.2-3 ..................................................................................................... 8 2.2-4 2007 .................................................................... 12 2.2-5 2008 .................................................................... 13 2.2-6 .................................................................................... 19 2.2-7 ................................................................................ 30 2.2-8 pH ................................................................................. 34 2.2-9 1MPa ......................................................................... 36 2.2-10 2MPa ....................................................................... 37 2.2-11 2008 ................................................................... 40 2.3-1 .......................................................................................................... 42 2.3-2 .................................................................. 43 2.3-3 ........................................................................................... 46 2.3-4 2007 ................................................................ 47 2.3-5 2008 .............................................. 47 2.3-6 2008 1000mL 48 2.3-7 ................................................................................ 51 2.3-8 2008 ........................................................................... 52 2.3-9 ............................................................................. 53 2.3-10 ....................................................................... 53 2.3-11 .............................................. 55 2.3-12 ...................................................................................... 55 2.3-13 ........................................................................................................ 57 2.3-14 2008 ............................. 59 2.3-15 ............................................................................................. 60 2.3-16 pH Hi ............ 61 2.3-17 pH MEYCO MP32OT 62 2.3-18 2007 kN/m2 . 63 2.3-19 2007 E50 kN/m2 .. 63 2.3-20 2008 kN/m2 . 65 2.3-21 2008 E50 kN/m2 .. 66 2.3-22 2007 ......................... 68 2.3-23 2007 ........................................ 68 2.3-24 2008 ............................. 72 2.3-25 2008 ............... 73 2.3-26 2008 ................................. 75 2.3-27 2007 .............................................................. 76

2.2-1 ................................................................................................................... 4 2.2-2 ............................................................................... 5 2.2-3 ..................................................................................................... 8 2.2-4 2007 .................................................................... 12 2.2-5 2008 .................................................................... 13 2.2-6 .................................................................................... 19 2.2-7 ................................................................................ 30 2.2-8 pH ................................................................................. 34 2.2-9 1MPa ......................................................................... 36 2.2-10 2MPa ....................................................................... 37 2.2-11 2008 ................................................................... 40 2.3-1 .......................................................................................................... 42 2.3-2 .................................................................. 43 2.3-3 ........................................................................................... 46 2.3-4 2007 ................................................................ 47 2.3-5 2008 .............................................. 47 2.3-6 2008 1000mL 48 2.3-7 ................................................................................ 51 2.3-8 2008 ........................................................................... 52 2.3-9 ............................................................................. 53 2.3-10 ....................................................................... 53 2.3-11 .............................................. 55 2.3-12 ...................................................................................... 55 2.3-13 ........................................................................................................ 57 2.3-14 2008 ............................. 59 2.3-15 ............................................................................................. 60 2.3-16 pH Hi ............ 61 2.3-17 pH MEYCO MP32OT 62 2.3-18 2007 kN/m2 . 63 2.3-19 2007 E50 kN/m2 .. 63 2.3-20 2008 kN/m2 . 65 2.3-21 2008 E50 kN/m2 .. 66 2.3-22 2007 ......................... 68 2.3-23 2007 ........................................ 68 2.3-24 2008 ............................. 72 2.3-25 2008 ............... 73 2.3-26 2008 ................................. 75 2.3-27 2007 .............................................................. 76

viii viii


2.3-28 1 2008 ............................. 78 2.3-29 2008 ................................................................... 79 2.4-1 ................................................................................................................. 80 2.4-2 ............................................................................. 81 2.4-3 ................................................................................................... 82 2.4-4 ................................................................................................... 82 2.4-5 ........................................................................................ 84 2.4-6 ................................................................................................... 85 2.4-7 .......................................................................................................... 86 2.4-8 ........................................................................................ 86 2.4-9 ................................................................................................... 87 2.4-10 pH ......................................................................................................... 88

2.1-1 ............................................................................................. 2 2.1-2 ................................................................................................. 3 2.2-1 2007 ............................................................................. 6 2.2-2 2008 ............................................................................. 7 2.2-3 (2008 ) ............................................................ 9 2.2-4 ........................................................................................... 10 2.2-5 8) ............................................................................. 15 2.2-6 .......................................................... 16 2.2-7 + +

......................................................................................................................... 18 2.2-8 ........................................................................................ 20 2.2-9 ......................................................................... 21 2.2-10 JP ................................................... 26 2.2-11 ................................................................ 26 2.2-12 SP/B W/B ............................................ 27 2.2-13 SP/B W/B ............................................... 27 2.2-14 ............................... 28 2.2-15 ...................................................................................... 29 2.2-16 ...................................................................................... 29 2.2-17 ................................................................... 30 2.2-18 W/B ................................................................................ 31 2.2-19 W/B ................................................................................ 31 2.2-20 W/B .............................................................. 32 2.2-21 .............................................................................. 33 2.2-22 ........................................................ 34

2.3-28 1 2008 ............................. 78 2.3-29 2008 ................................................................... 79 2.4-1 ................................................................................................................. 80 2.4-2 ............................................................................. 81 2.4-3 ................................................................................................... 82 2.4-4 ................................................................................................... 82 2.4-5 ........................................................................................ 84 2.4-6 ................................................................................................... 85 2.4-7 .......................................................................................................... 86 2.4-8 ........................................................................................ 86 2.4-9 ................................................................................................... 87 2.4-10 pH ......................................................................................................... 88

2.1-1 ............................................................................................. 2 2.1-2 ................................................................................................. 3 2.2-1 2007 ............................................................................. 6 2.2-2 2008 ............................................................................. 7 2.2-3 (2008 ) ............................................................ 9 2.2-4 ........................................................................................... 10 2.2-5 8) ............................................................................. 15 2.2-6 .......................................................... 16 2.2-7 + +

......................................................................................................................... 18 2.2-8 ........................................................................................ 20 2.2-9 ......................................................................... 21 2.2-10 JP ................................................... 26 2.2-11 ................................................................ 26 2.2-12 SP/B W/B ............................................ 27 2.2-13 SP/B W/B ............................................... 27 2.2-14 ............................... 28 2.2-15 ...................................................................................... 29 2.2-16 ...................................................................................... 29 2.2-17 ................................................................... 30 2.2-18 W/B ................................................................................ 31 2.2-19 W/B ................................................................................ 31 2.2-20 W/B .............................................................. 32 2.2-21 .............................................................................. 33 2.2-22 ........................................................ 34

ix ix


2.2-23 ........................................................ 35 2.2-24 ................................... 35 2.2-25 1.0MPa .............................................. 36 2.2-26 2.0MPa .............................................. 37 2.2-27 .................................................................................. 38 2.2-28 R=0.1m ............................................................................ 38 2.2-29 R=0.4m ............................................................................ 39 2.2-30 R=0.8m ............................................................................ 39 2.3-1 ................................................................................ 41 2.3-2 2007 ...................................................................................... 44 2.3-3 2008 ............................................................................... 45 2.3-4 ............................................................................................... 57 2.3-5 .............................................................. 57 2.3-6 .................................................................................... 58 2.3-7 ......................................................................... 59 2.3-8 .................................................................................... 59 2.3-9 ....................................................... 63 2.3-10 2007 .......................................................... 64 2.3-11 E50 2007 ........................................................... 64 2.3-12 2008 ............................................... 65 2.3-13 2008 .............................................................. 66 2.3-14 ........................................................................................................... 67 2.3-15 2007 ............................................ 68 2.3-16 2008 .............................................................. 69 2.3-17 ............................................................................................. 70 2.3-18 2007 ............... 71 2.3-19 2008 .............................................................. 73 2.3-20 28 2008 . 74 2.3-21 28 2008 ......... 74 2.3-22 2007

......................................................................................................................... 76 2.3-23 2007

......................................................................................................................... 77 2.3-24 1-2 100μm 2008

................................................................................................................................ 77 2.3-25 3-1 100μm 2008

................................................................................................................................ 78 2.3-26 1-2 200μm 2008

................................................................................................................................ 78 2.4-1 SFP ..................................................................................................... 80

2.2-23 ........................................................ 35 2.2-24 ................................... 35 2.2-25 1.0MPa .............................................. 36 2.2-26 2.0MPa .............................................. 37 2.2-27 .................................................................................. 38 2.2-28 R=0.1m ............................................................................ 38 2.2-29 R=0.4m ............................................................................ 39 2.2-30 R=0.8m ............................................................................ 39 2.3-1 ................................................................................ 41 2.3-2 2007 ...................................................................................... 44 2.3-3 2008 ............................................................................... 45 2.3-4 ............................................................................................... 57 2.3-5 .............................................................. 57 2.3-6 .................................................................................... 58 2.3-7 ......................................................................... 59 2.3-8 .................................................................................... 59 2.3-9 ....................................................... 63 2.3-10 2007 .......................................................... 64 2.3-11 E50 2007 ........................................................... 64 2.3-12 2008 ............................................... 65 2.3-13 2008 .............................................................. 66 2.3-14 ........................................................................................................... 67 2.3-15 2007 ............................................ 68 2.3-16 2008 .............................................................. 69 2.3-17 ............................................................................................. 70 2.3-18 2007 ............... 71 2.3-19 2008 .............................................................. 73 2.3-20 28 2008 . 74 2.3-21 28 2008 ......... 74 2.3-22 2007

......................................................................................................................... 76 2.3-23 2007

......................................................................................................................... 77 2.3-24 1-2 100μm 2008

................................................................................................................................ 77 2.3-25 3-1 100μm 2008

................................................................................................................................ 78 2.3-26 1-2 200μm 2008

................................................................................................................................ 78 2.4-1 SFP ..................................................................................................... 80

x x


2.4-2 SFP SEM ................................................................................................... 81 2.4-3 SFCa SEM ................................................................................................ 81 2.4-4 SPF .................................................................................................. 83 2.4-5 SFCa ................................................................................................ 83 2.4-6 SFCa .......................................................... 85 2.4-7 SFCa ............................................................................ 87 2.4-8 ............................................................................................... 87

2.2-1 ................................................................................................. 14 2.2-2 ................................................................................................... 14 2.2-3 ................................................................................ 15 2.2-4 .................................................................................... 16 2.2-5 ...................................................................................................... 17 2.2-6 .................................................................................... 17 2.2-7 ........................................ 19 2.2-8 ..................................................................... 21 2.2-9 .......................................................................................................... 22 2.2-10 ................................................................................................. 22 2.2-11 O ............................................................... 22 2.2-12 CCD ....................................... 23 2.2-13 ......................................................................................... 23 2.2-14 ............................................................................................................... 23 2.2-15 ............................................................................................. 24 2.2-16 ........................................................................................................... 24 2.2-17 ............. 24 2.2-18 ................................... 25 2.2-19 ........................................................................................................... 25 2.2-20 ( 50mm) ...................................................... 33 2.2-21 ............................................................ 34 2.3-1 2007 2 7 ............................ 49 2.3-2 ...................... 50 2.3-3 Anton Paar Physica MCR301 ............................................... 51 2.3-4 ............................................................................................... 52 2.3-5 10μm ......................................... 53 2.3-6 2007 1 7 100kPa 54 2.3-7 (pH=9.02) ........................................................ 55 2.3-8 (pH=13.1) .................... 56 2.3-9 ..................................................................... 56

2.4-2 SFP SEM ................................................................................................... 81 2.4-3 SFCa SEM ................................................................................................ 81 2.4-4 SPF .................................................................................................. 83 2.4-5 SFCa ................................................................................................ 83 2.4-6 SFCa .......................................................... 85 2.4-7 SFCa ............................................................................ 87 2.4-8 ............................................................................................... 87

2.2-1 ................................................................................................. 14 2.2-2 ................................................................................................... 14 2.2-3 ................................................................................ 15 2.2-4 .................................................................................... 16 2.2-5 ...................................................................................................... 17 2.2-6 .................................................................................... 17 2.2-7 ........................................ 19 2.2-8 ..................................................................... 21 2.2-9 .......................................................................................................... 22 2.2-10 ................................................................................................. 22 2.2-11 O ............................................................... 22 2.2-12 CCD ....................................... 23 2.2-13 ......................................................................................... 23 2.2-14 ............................................................................................................... 23 2.2-15 ............................................................................................. 24 2.2-16 ........................................................................................................... 24 2.2-17 ............. 24 2.2-18 ................................... 25 2.2-19 ........................................................................................................... 25 2.2-20 ( 50mm) ...................................................... 33 2.2-21 ............................................................ 34 2.3-1 2007 2 7 ............................ 49 2.3-2 ...................... 50 2.3-3 Anton Paar Physica MCR301 ............................................... 51 2.3-4 ............................................................................................... 52 2.3-5 10μm ......................................... 53 2.3-6 2007 1 7 100kPa 54 2.3-7 (pH=9.02) ........................................................ 55 2.3-8 (pH=13.1) .................... 56 2.3-9 ..................................................................... 56

xi xi


2.3-10 ................................................................................................. 60 2.3-11 ............................................................................................................ 60 2.3-12 1 7 14 28 ......................... 62 2.3-13 ............................................. 70 2.3-14 ................ 70 2.3-15 1 7 14 28 71 2.3-16 2007 .................. 75

2.3-10 ................................................................................................. 60 2.3-11 ............................................................................................................ 60 2.3-12 1 7 14 28 ......................... 62 2.3-13 ............................................. 70 2.3-14 ................ 70 2.3-15 1 7 14 28 71 2.3-16 2007 .................. 75

This is a blank page.

－1－－1－


1.

1.119

20

1)

Ordinary Portland Cement OPC

19pH 11

1.23 1 2

33

1.

1.119

20

1)

Ordinary Portland Cement OPC

19pH 11

1.23 1 2

33

－2－－2－


2.

2.12.1.1

1.1

2.1-1 3

2.1-1

2.1.2 OPC B

2)

OPC OPC

2.2

2.1.3

2.3

2.1.42

2.

2.12.1.1

1.1

2.1-1 3

2.1-1

2.1.2 OPC B

2)

OPC OPC

2.2

2.1.3

2.3

2.1.42

－3－－3－


2.4

2.1.5

3 3),4)

SKB100μm

5) 2.1-2

6)

2.1-2

0 50μm 100μm

15μm3μm

20 30nm

1μm300 800nm

2.4

2.1.5

3 3),4)

SKB100μm

5) 2.1-2

6)

2.1-2

0 50μm 100μm

15μm3μm

20 30nm

1μm300 800nm

－4－－4－


2.22.2.1(1)

Ca2+ K+ Na+

7

8) 9 10)

2007 11)

2008 12)

(2)Ca(OH)2

Ca(OH)28 9)

SF JIS FASS OPC

4.26μm OPC

2.2-1

2.2-1

B

OPC

OPC4.26μm 3.16g/cm3

12000cm2/g ( )

SF JIS

0.72μm 2.20g/cm3

2000000cm2/g ( )940U

SS 1.10μm 2.40g/cm3

62000cm2/g ( )SFP-30M

FA JIS

2.99μm 2.40g/cm3

5460cm2/g ( ) FA20

SP 150

SS

W ASTM AB

2.22.2.1(1)

Ca2+ K+ Na+

7

8) 9 10)

2007 11)

2008 12)

(2)Ca(OH)2

Ca(OH)28 9)

SF JIS FASS OPC

4.26μm OPC

2.2-1

2.2-1

B

OPC

OPC4.26μm 3.16g/cm3

12000cm2/g ( )

SF JIS

0.72μm 2.20g/cm3

2000000cm2/g ( )940U

SS 1.10μm 2.40g/cm3

62000cm2/g ( )SFP-30M

FA JIS

2.99μm 2.40g/cm3

5460cm2/g ( ) FA20

SP 150

SS

W ASTM AB

－5－－5－


(3)SKB POSIVA

100μm 50 100μm

13, 14)

POSIVA R20 IMA-project15) 16) 2.2-2

2.2-2

2.2-2

30 50mPa s30 5Pa 30 45s

bmin*1 30 80μm2 2%6 500Pa

28 4MPa pH 11

*1

(3)SKB POSIVA

100μm 50 100μm

13, 14)

POSIVA R20 IMA-project15) 16) 2.2-2

2.2-2

2.2-2

30 50mPa s30 5Pa 30 45s

bmin*1 30 80μm2 2%6 500Pa

28 4MPa pH 11

*1

－ 6－－ 6－


(4)1 2007

2007 2.2-1 10

OPC SF SS FA 50 80%W/B 100 200 300 400% 2 4 SP SP/B

2 3.5% 1 9696

3131

1010

pH

2.2-1 2007

2007

96

31

10

pH

2007

W/B=100 400% 2 4SP =2 3.5% 1

LP

W/B=100 400% 1 2SP =2 3.5% 1 2

LP

W/B=100 200% 1 2SP =2 3.5% 1 2

(4)1 2007

2007 2.2-1 10

OPC SF SS FA 50 80%W/B 100 200 300 400% 2 4 SP SP/B

2 3.5% 1 9696

3131

1010

pH

2.2-1 2007

2007

96

31

10

pH

2007

W/B=100 400% 2 4SP =2 3.5% 1

LP

W/B=100 400% 1 2SP =2 3.5% 1 2

LP

W/B=100 200% 1 2SP =2 3.5% 1 2

－7－－7－


2 20082008 10 2.2-2

1

W/B 100 125 150 200% 2 4 SP/B 1 6% 363

63

4343

2020

1010

11

2.2-2 2008

2008

63

43

10

2008

W/B=100 200% 2 4SP =1 6% 1 3

W/B=100 200% 1 4SP =1 6% 1 3

W/B=100 150% 1 3SP =4.5 6% 1 2

1

20 W/B=100 200% 2 4SP =2 6% 1 3

OPC/SF/SS/FA=5/5/0/0W/B=125%SP =5.5%

2 20082008 10 2.2-2

1

W/B 100 125 150 200% 2 4 SP/B 1 6% 363

63

4343

2020

1010

11

2.2-2 2008

2008

63

43

10

2008

W/B=100 200% 2 4SP =1 6% 1 3

W/B=100 200% 1 4SP =1 6% 1 3

W/B=100 150% 1 3SP =4.5 6% 1 2

1

20 W/B=100 200% 2 4SP =2 6% 1 3

OPC/SF/SS/FA=5/5/0/0W/B=125%SP =5.5%

－8－－8－


(5)2.2-3 2.2.3

2.2-3

2007 20085

305

305

301

5305

30

30

30

A

A +B

A +B

2311MPa2MPa3.5MPa5MPa2MPa52MPa

――

681211.5

JGS T142-2000 677

JSCE-G505-1999 28282820

20

50

50

JSCEF531-1999

JSCE-F5022MPa 5

JISA5201-1997

JSCEF532-1999

pH

JSCEF521-1999

JSCEF531-1999

JSCEF502-20075

JGS0521

(5)2.2-3 2.2.3

2.2-3

2007 20085

305

305

301

5305

30

30

30

A

A +B

A +B

2311MPa2MPa3.5MPa5MPa2MPa52MPa

――

681211.5

JGS T142-2000 677

JSCE-G505-1999 28282820

20

50

50

JSCEF531-1999

JSCE-F5022MPa 5

JISA5201-1997

JSCEF532-1999

pH

JSCEF521-1999

JSCEF531-1999

JSCEF502-20075

JGS0521

－ 9－－ 9－


2.2.2(1)1a.

LMS-350 0.1500μm 670nm 2mW

0.1%40W 40kHz

b. 2.2-3

SF SS FA OPCSS SF FA OPC SF

2.2-3 (2008 )

OPC

0

20

40

60

80

100

0.1 1 10 100μm

(%)

0

5

10

15

20

(%)

SF

0

20

40

60

80

100

0.1 1 10 100μm

(%)

0

5

10

15

20

(%)

SS

0

20

40

60

80

100

0.1 1 10 100μm

(%)

0

5

10

15

20

(%)

FA

0

20

40

60

80

100

0.1 1 10 100μm

(%)

0

5

10

15

20

(%)

OPC

2.2.2(1)1a.

LMS-350 0.1500μm 670nm 2mW

0.1%40W 40kHz

b. 2.2-3

SF SS FA OPCSS SF FA OPC SF

2.2-3 (2008 )

OPC

0

20

40

60

80

100

0.1 1 10 100μm

(%)

0

5

10

15

20

(%)

SF

0

20

40

60

80

100

0.1 1 10 100μm

(%)

0

5

10

15

20

(%)

SS

0

20

40

60

80

100

0.1 1 10 100μm

(%)

0

5

10

15

20

(%)

FA

0

20

40

60

80

100

0.1 1 10 100μm

(%)

0

5

10

15

20

(%)

OPC

－10－－10－


2 (2007 )a.

OPC JIS A 62012 JIS A 6207

47 28 JIS SF SS SF

10% FA 25% JIS W/B=50%OPCW/B 60% SP/B=2%

b.2.2-4

SS SF

SP

2.2-4

(2)2007

1 50L2

2008 2007 SF

1Hany HCM High

shear Colloidal Mixer TKM-220

0

20

40

60

80

100

120

0 20 40 60 80 100

(

OPC100%OPC90%+SF10%OPC90%+SS10%OPC75%+FA25%

SF 1 4 FA 4 13 JIS W/B

2 (2007 )a.

OPC JIS A 62012 JIS A 6207

47 28 JIS SF SS SF

10% FA 25% JIS W/B=50%OPCW/B 60% SP/B=2%

b.2.2-4

SS SF

SP

2.2-4

(2)2007

1 50L2

2008 2007 SF

1Hany HCM High

shear Colloidal Mixer TKM-220

0

20

40

60

80

100

120

0 20 40 60 80 100

(

OPC100%OPC90%+SF10%OPC90%+SS10%OPC75%+FA25%

SF 1 4 FA 4 13 JIS W/B

－11－－11－


200L 50HZ 1500rpm 70HZ 2100rpm

2SF

SF100% SF

SP/B=0.2%

3SF SP

SFSF SP 1500rpm 20

2000rpm OPCOPC SS FA 2

(3)2007 11) 2.2-4

962008 12) 2.2-5 W/B 2 100% 150% 4100% 125% 150% 200% SP/B 3 1 6%

638)

OPC SF FA 50% 80%

SF FA SSLP

SPAE

OPC/SF/SS/FA 104/5/1/0 OPC OPC

200L 50HZ 1500rpm 70HZ 2100rpm

2SF

SF100% SF

SP/B=0.2%

3SF SP

SFSF SP 1500rpm 20

2000rpm OPCOPC SS FA 2

(3)2007 11) 2.2-4

962008 12) 2.2-5 W/B 2 100% 150% 4100% 125% 150% 200% SP/B 3 1 6%

638)

OPC SF FA 50% 80%

SF FA SSLP

SPAE

OPC/SF/SS/FA 104/5/1/0 OPC OPC

－12－－12－


2.2-4 2007*2,3 SP/B %

OPC SF SS FA W/B*2 %

100 200 300*1 400*1

10 0 0 0 1.0 1.0 6

10 0 0 0 2.0 2.0 2.0 1.0 5 5 0 0 4.0 2.0 2.0 2.0

85 0 5 0 2.0 2.0 5 0 0 5 2.0 2.0 4 5 1 0 3.0 2.0 3.0 3.0

68

4 4 2 0 2.5 2.0 4 3 3 0 2.5 2.0 4 2 4 0 2.5 2.0 4 5 0 1 4.0 2.0 3.0 3.0 4 4 0 2 3.0 2.0 4 3 0 3 3.0 2.0 4 2 0 4 2.5 2.0 3 6 1 0 3.5 2.0 3.0 3.0 3 5 2 0 3.0 2.0 3.0 3.0 3 4 3 0 2.5 2.0 3 3 4 0 3.0 2.0 3 2 5 0 2.0 2.0 3 6 0 1 5.0 2.0 3.0 3.0 3 5 0 2 3.0 2.5 3.0 3.0 3 4 0 3 3.0 3.0 3 3 0 4 3.0 3.0 3 2 0 5 2.0 2.0 2 5 3 0 3.0 2.5 3.0 3.0 2 4 4 0 2.5 2.5 2 3 5 0 3.0 2.5 2 2 6 0 2.5 2.5 2 5 0 3 4.0 3.0 3.0 3.0 2 4 0 4 3.0 3.0 2 3 0 5 2.0 2.5 2 2 0 6 2.5 2.0 4 4 1 1 2.5 2.5

14

3 4 2 1 2.5 2.5 3 4 1.5 1.5 2.5 2.5 3 4 1 2 2.5 2.5 2 4 3 1 2.5 2.0 2 4 2 2 2.5 2.0 2 4 1 3 2.0 2.0

96 *1 SF 50% W/B 300% LP W/B

300% 400% W/LP 133% 150%*2 B OPC SF SS FA W/B %*3 SS SS

2.2-4 2007*2,3 SP/B %

OPC SF SS FA W/B*2 %

100 200 300*1 400*1

10 0 0 0 1.0 1.0 6

10 0 0 0 2.0 2.0 2.0 1.0 5 5 0 0 4.0 2.0 2.0 2.0

85 0 5 0 2.0 2.0 5 0 0 5 2.0 2.0 4 5 1 0 3.0 2.0 3.0 3.0

68

4 4 2 0 2.5 2.0 4 3 3 0 2.5 2.0 4 2 4 0 2.5 2.0 4 5 0 1 4.0 2.0 3.0 3.0 4 4 0 2 3.0 2.0 4 3 0 3 3.0 2.0 4 2 0 4 2.5 2.0 3 6 1 0 3.5 2.0 3.0 3.0 3 5 2 0 3.0 2.0 3.0 3.0 3 4 3 0 2.5 2.0 3 3 4 0 3.0 2.0 3 2 5 0 2.0 2.0 3 6 0 1 5.0 2.0 3.0 3.0 3 5 0 2 3.0 2.5 3.0 3.0 3 4 0 3 3.0 3.0 3 3 0 4 3.0 3.0 3 2 0 5 2.0 2.0 2 5 3 0 3.0 2.5 3.0 3.0 2 4 4 0 2.5 2.5 2 3 5 0 3.0 2.5 2 2 6 0 2.5 2.5 2 5 0 3 4.0 3.0 3.0 3.0 2 4 0 4 3.0 3.0 2 3 0 5 2.0 2.5 2 2 0 6 2.5 2.0 4 4 1 1 2.5 2.5

14

3 4 2 1 2.5 2.5 3 4 1.5 1.5 2.5 2.5 3 4 1 2 2.5 2.5 2 4 3 1 2.5 2.0 2 4 2 2 2.5 2.0 2 4 1 3 2.0 2.0

96 *1 SF 50% W/B 300% LP W/B

300% 400% W/LP 133% 150%*2 B OPC SF SS FA W/B %*3 SS SS

－13－－13－


2.2-5 2008SP/B %

OPC SF SS FA W/B %

100 125 150 200

10 0 0 0 3.0 2.0

64.0 3.0 5.0 4.0

5 5 0 0 4.5 4.5 3.0 2.5

12 5.5 5.0 4.0 3.0 6.0 5.5 4.5 3.5

4 5 1 0 5.0 4.0 3.0 2.0

45

5.5 5.0 4.0 2.5 6.0 5.5 4.5 3.0

4 4 0 2 3.5 1.5 1.0 4.0 3.0 2.0 4.5 4.0 3.0

4 2 0 4 2.5 1.0 3.0 1.5 3.5 2.0

3 6 1 0 5.0 3.0 5.5 4.0 6.0 5.0

3 6 0 1 5.0 3.5 5.5 4.0 6.0 5.0

2 5 3 0 4.5 3.0 5.0 4.0 5.5 5.0

63

2.2.3(1)1a. JP 2007

JSCE F531 JP JP5 30

b.JSCE F531

2.2-1 4.8mm 500cm3

5 30 60W/B 100 400% 14mm JP

2 3

2.2-5 2008SP/B %

OPC SF SS FA W/B %

100 125 150 200

10 0 0 0 3.0 2.0

64.0 3.0 5.0 4.0

5 5 0 0 4.5 4.5 3.0 2.5

12 5.5 5.0 4.0 3.0 6.0 5.5 4.5 3.5

4 5 1 0 5.0 4.0 3.0 2.0

45

5.5 5.0 4.0 2.5 6.0 5.5 4.5 3.0

4 4 0 2 3.5 1.5 1.0 4.0 3.0 2.0 4.5 4.0 3.0

4 2 0 4 2.5 1.0 3.0 1.5 3.5 2.0

3 6 1 0 5.0 3.0 5.5 4.0 6.0 5.0

3 6 0 1 5.0 3.5 5.5 4.0 6.0 5.0

2 5 3 0 4.5 3.0 5.0 4.0 5.5 5.0

63

2.2.3(1)1a. JP 2007

JSCE F531 JP JP5 30

b.JSCE F531

2.2-1 4.8mm 500cm3

5 30 60W/B 100 400% 14mm JP

2 3

－14－－14－


2.2-1

c. 2008JSCE F521 P P 2.2-2

13.0mm 1725cc

P

2.2-2

2LVDV-1+

(mPa s) (Pa)

363 75 90 106 125μm

2.2-317) 0.1MPa

2.2-1

c. 2008JSCE F521 P P 2.2-2

13.0mm 1725cc

P

2.2-2

2LVDV-1+

(mPa s) (Pa)

363 75 90 106 125μm

2.2-317) 0.1MPa

－15－－15－


2

4

18) 2.2-5

40.1MPa

0.1 0.3 0.5MPa

2.2-5

2.2-3

2.2-4 50mm 65mm 2.2-6 Posiva 15

5 10mm 35mm

5 8)

m 500mm5)

m

2

4

18) 2.2-5

40.1MPa

0.1 0.3 0.5MPa

2.2-5

2.2-3

2.2-4 50mm 65mm 2.2-6 Posiva 15

5 10mm 35mm

5 8)

m 500mm5)

m

－16－－16－


(a) (b) (c) 2.2-4

2.2-6

5

SS20

1/5

6JSCE F5322 24

7JSCE F532

80mm

0

20

40

60

80

100

0.01 0.10 1.00 10.00(mm)

POSIVATable4.1

(a) (b) (c) 2.2-4

2.2-6

5

SS20

1/5

6JSCE F5322 24

7JSCE F532

80mm

0

20

40

60

80

100

0.01 0.10 1.00 10.00(mm)

POSIVATable4.1

－17－－17－


2.2-3No.5-B 0.21mm 8μm 2MPa

8JIS R 5201 2.2-5

12

(a) (b) 2.2-5

9

19) 6 86 12

10JGS T142 6

2.2-6GLO-8520) 8.73kPa 4.0mm 0.98kPa 13.0mm

0.5kPa18.4mm

2.2-6

2.2-3No.5-B 0.21mm 8μm 2MPa

8JIS R 5201 2.2-5

12

(a) (b) 2.2-5

9

19) 6 86 12

10JGS T142 6

2.2-6GLO-8520) 8.73kPa 4.0mm 0.98kPa 13.0mm

0.5kPa18.4mm

2.2-6

－18－－18－


11JGS05211 20

12JSCE G505

1 20

13

3cm 2

2850mm

14 pH

75μm72

(2)1

+

2.2-7

50×1

20 RH9

0 28

238 255m

20 50 1420

2 pH

+2

5

+

×100mm

90%

50mm×100mm

5mm

5 1pH

2.2-7

50 100 200μm

+

11JGS05211 20

12JSCE G505

1 20

13

3cm 2

2850mm

14 pH

75μm72

(2)1

+

2.2-7

50×1

20 RH9

0 28

238 255m

20 50 1420

2 pH

+2

5

+

×100mm

90%

50mm×100mm

5mm

5 1pH

2.2-7

50 100 200μm

+

－19－－19－


Hz 1.0MPa

2.2-7

2.2-7

2

5MPa 1

3a.

10 2.2-6

2.2-6

No. W/B (%)

SP/B (%)OPC SF SS FA

1 5 5 0 0 100 6.0 2 5 5 0 0 125 5.5 3 5 5 0 0 150 4.5 4 4 5 1 0 100 6.0 5 4 5 1 0 125 5.5 6 4 5 1 0 150 4.5 7 4 4 0 2 100 4.5 8 4 4 0 2 150 4.0 9 3 6 0 1 100 6.0

10 3 6 1 0 100 6.0

2m 50mmSS 2m 60mm 2.2-8

20 50 100μm

Hz 1.0MPa

2.2-7

2.2-7

2

5MPa 1

3a.

10 2.2-6

2.2-6

No. W/B (%)

SP/B (%)OPC SF SS FA

1 5 5 0 0 100 6.0 2 5 5 0 0 125 5.5 3 5 5 0 0 150 4.5 4 4 5 1 0 100 6.0 5 4 5 1 0 125 5.5 6 4 5 1 0 150 4.5 7 4 4 0 2 100 4.5 8 4 4 0 2 150 4.0 9 3 6 0 1 100 6.0

10 3 6 1 0 100 6.0

2m 50mmSS 2m 60mm 2.2-8

20 50 100μm

－20－－20－


2.0MPa

90°

2.2-8

2

SS

0

0.1m 0.4m 0.8m 2.2-9

2.2-8

2000

0.1 1.02.0MPa

90°

2.2-8

2

SS

0

0.1m 0.4m 0.8m 2.2-9

2.2-8

2000

0.1 1.0

－21－－21－


2.2-9

2.2-8

10 × 3 20 50 100μm × 3 0.11.0 2.0MPa 90

b.

20 50 100μm 2.2-9

S

N

E

W

ch2

ch3 ch4

ch5ch6

ch7

ch8

ch9 ch10

ch11

ch12

ch13

2.2-9

2.2-8

10 × 3 20 50 100μm × 3 0.11.0 2.0MPa 90

b.

20 50 100μm 2.2-9

S

N

E

W

ch2

ch3 ch4

ch5ch6

ch7

ch8

ch9 ch10

ch11

ch12

ch13

－22－－22－


50mm 40mm 40100×50mm 40 50mm×50mm 16

2.2-10

2.2-9

2.2-10

SS O2

O 2.2-11

2.2-11 O

CCD CCD 2.2-12

50mm

50mm 40mm 40100×50mm 40 50mm×50mm 16

2.2-10

2.2-9

2.2-10

SS O2

O 2.2-11

2.2-11 O

CCD CCD 2.2-12

50mm

－23－－23－


2.2-12 CCD

2.2-13 2.2-16

2.2-13 2.2-14

2.2-12 CCD

2.2-13 2.2-16

2.2-13 2.2-14

－24－－24－


2.2-15 2.2-16

c.

2.2-17

2.2-17

2.2-18

0

2.2-15 2.2-16

c.

2.2-17

2.2-17

2.2-18

0

－25－－25－


2.2-18

2.2-19

2.2-19

2.2-18

2.2-19

2.2-19

－26－－26－


2.2.4(1)1a. JP (2007 )

5 30 JP 2.2-10JP 2.1 2.5 20 35

2.2-10 JP

b.2008 2.2-11

30 303 8 5 30

30 90mPa s25 SP/B 30

30

2.2-11

5

0

20

40

60

80

100

1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2JP

30

0

20

40

60

80

100

1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2JP

2.2.4(1)1a. JP (2007 )

5 30 JP 2.2-10JP 2.1 2.5 20 35

2.2-10 JP

b.2008 2.2-11

30 303 8 5 30

30 90mPa s25 SP/B 30

30

2.2-11

5

0

20

40

60

80

100

1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2JP

30

0

20

40

60

80

100

1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2JP

－27－－27－


c. (2008 )b

P

230 2008 2.2-12

2.2-13W/B SP/B

2.2-2 50mPa s 5Pa SP/B6.0% 2.2-5 SP

Posiva 4% 21)

2.2-5

2.2-12 SP/B W/B

2.2-13 SP/B W/B

32008

2.2-14W/B SP/B

SS 4/5/1/0

0

200

400

600

800

1000

75 100 125 150 175 200 225

mPa

s30

4/5/1/0 SP2.0% 4/5/1/0 SP2.5% 4/5/1/0 SP3.0% 4/5/1/0 SP4.0% 4/5/1/0 SP4.5% 4/5/1/0 SP5.0% 4/5/1/0 SP5.5% 4/5/1/0 SP6.0%

SF 5/5/0/0

0

200

400

600

800

1000

75 100 125 150 175 200 225

mPa

s30


FA 4/4/0/2

0

200

400

600

800

1000

75 100 125 150 175 200 225

mPa

s30

4/4/0/2

FA 4/4/0/2

0

10

20

30

40

50

75 100 125 150 175 200 225

Pa30

4/4/0/2

SS 4/5/1/0

0

10

20

30

40

50

75 100 125 150 175 200 225

Pa30


SF 5/5/0/0

0

10

20

30

40

50

75 100 125 150 175 200 225

Pa30


c. (2008 )b

P

230 2008 2.2-12

2.2-13W/B SP/B

2.2-2 50mPa s 5Pa SP/B6.0% 2.2-5 SP

Posiva 4% 21)

2.2-5

2.2-12 SP/B W/B

2.2-13 SP/B W/B

32008

2.2-14W/B SP/B

SS 4/5/1/0

0

200

400

600

800

1000

75 100 125 150 175 200 225

mPa

s30


SF 5/5/0/0

0

200

400

600

800

1000

75 100 125 150 175 200 225

mPa

s30


FA 4/4/0/2

0

200

400

600

800

1000

75 100 125 150 175 200 225

mPa

s30

4/4/0/2

FA 4/4/0/2

0

10

20

30

40

50

75 100 125 150 175 200 225

Pa30

4/4/0/2

SS 4/5/1/0

0

10

20

30

40

50

75 100 125 150 175 200 225

Pa30


SF 5/5/0/0

0

10

20

30

40

50

75 100 125 150 175 200 225

Pa30


－28－－28－


bmin 0 2.2-2 bmin 80μm

bmin SS 40 50μm SF42 57μm FA bmin 56 63μm

2.2-14

4 (2008 ) 2.2-15

FA 4/4/0/2 4/2/0/4 5/5/0/0 W/B=125%SS 4/5/1/0

W/B SP/B 5/5/0/0 4/2/0/4 W/BW/B SP/B W/B

300cm3

300cm3

0

50

100

150

200

250

300

0 50 100 150

g

μm

SS 3/6/1/0

3/6/1/0 W/B100% SP5.0%3/6/1/0 W/B100% SP5.5%3/6/1/0 W/B100% SP6.0%

0

50

100

150

200

250

300

0 50 100 150

g

μm

SS 4/5/1/0

4/5/1/0 W/B100% SP5.0%4/5/1/0 W/B100% SP5.5%4/5/1/0 W/B100% SP6.0%

0

50

100

150

200

250

300

0 50 100 150

g

μm

SF 5/5/0/0

5/5/0/0 W/B100% SP5.0%5/5/0/0 W/B100% SP5.5%5/5/0/0 W/B100% SP6.0%

0

50

100

150

200

250

300

0 50 100 150

g

μm

SF 5/5/0/0

5/5/0/0 W/B125% SP4.5%5/5/0/0 W/B125% SP5.0%5/5/0/0 W/B125% SP5.5%

0

50

100

150

200

250

300

0 50 100 150

g

μm

FA 3/6/0/1

3/6/0/1 W/B100% SP5.0%3/6/0/1 W/B100% SP5.5%3/6/0/1 W/B100% SP6.0%

(3/6/0/1 W/B100% SP6.0%)

0

50

100

150

200

250

300

0 50 100 150

g

μm

FA 4/4/0/2

4/4/0/2 W/B100% SP3.5%4/4/0/2 W/B100% SP4.0%4/4/0/2 W/B100% SP4.5%

bmin 0 2.2-2 bmin 80μm

bmin SS 40 50μm SF42 57μm FA bmin 56 63μm

2.2-14

4 (2008 ) 2.2-15

FA 4/4/0/2 4/2/0/4 5/5/0/0 W/B=125%SS 4/5/1/0

W/B SP/B 5/5/0/0 4/2/0/4 W/BW/B SP/B W/B

300cm3

300cm3

0

50

100

150

200

250

300

0 50 100 150

g

μm

SS 3/6/1/0

3/6/1/0 W/B100% SP5.0%3/6/1/0 W/B100% SP5.5%3/6/1/0 W/B100% SP6.0%

0

50

100

150

200

250

300

0 50 100 150

g

μm

SS 4/5/1/0

4/5/1/0 W/B100% SP5.0%4/5/1/0 W/B100% SP5.5%4/5/1/0 W/B100% SP6.0%

0

50

100

150

200

250

300

0 50 100 150

g

μm

SF 5/5/0/0

5/5/0/0 W/B100% SP5.0%5/5/0/0 W/B100% SP5.5%5/5/0/0 W/B100% SP6.0%

0

50

100

150

200

250

300

0 50 100 150

g

μm

SF 5/5/0/0

5/5/0/0 W/B125% SP4.5%5/5/0/0 W/B125% SP5.0%5/5/0/0 W/B125% SP5.5%

0

50

100

150

200

250

300

0 50 100 150

g

μm

FA 3/6/0/1

3/6/0/1 W/B100% SP5.0%3/6/0/1 W/B100% SP5.5%3/6/0/1 W/B100% SP6.0%

(3/6/0/1 W/B100% SP6.0%)

0

50

100

150

200

250

300

0 50 100 150

g

μm

FA 4/4/0/2

4/4/0/2 W/B100% SP3.5%4/4/0/2 W/B100% SP4.0%4/4/0/2 W/B100% SP4.5%

－29－－29－


2.2-15

5 (2008 ) 2.2-16

5/5/0/0 W/B=125% SP/B=5.5% 10 42

2.2-16

62008 2.2-7

W/B=150% 0.1% 2.2-22.0%

4/2/0/4 4/4/0/2FA

0

100

200

300

400

500

600

700

0 30 60 90 120 150

(cm

3 )

sec

0.1MPa

4/2/0/4 W/B100% SP3.5%4/2/0/4 W/B150% SP2.0%4/5/1/0 W/B100% SP6.0%4/5/1/0 W/B125% SP5.5%4/5/1/0 W/B150% SP4.5%

0

100

200

300

400

500

600

700

0 30 60 90 120 150

(cm

3 )

sec

0.1MPa

5/5/0/0 W/B100% SP6.0%5/5/0/0 W/B125% SP5.5%5/5/0/0 W/B150% SP4.5%

0

100

200

300

400

500

600

700

0 30 60 90 120 150

(cm

3 )

sec

0.1MPa

4/4/0/2 W/B100% SP4.5%4/4/0/2 W/B150% SP4.0%4/4/0/2 W/B200% SP3.0%

0

100

200

300

400

500

600

700

0 30 60 90 120 150

(cm

3 )

sec

0.1MPa

4/4/0/2 W/B100% SP4.0%4/4/0/2 W/B100% SP4.5%

/ SS/ =5/1/4

0

10

20

30

40

50

60

0 2 4 6 8 10 12g

5/5/0/0 W/B100% SP6.0%5/5/0/0 W/B125% SP5.5%

W/B100%

W/B150%

W/B125%

W/B100%

W/B150%

W/B125%,W/B150%,W/B100%

SP4.0%

SP4.5%

W/B200% W/B150%

W/B100%

2.2-15

5 (2008 ) 2.2-16

5/5/0/0 W/B=125% SP/B=5.5% 10 42

2.2-16

62008 2.2-7

W/B=150% 0.1% 2.2-22.0%

4/2/0/4 4/4/0/2FA

0

100

200

300

400

500

600

700

0 30 60 90 120 150

(cm

3 )

sec

0.1MPa

4/2/0/4 W/B100% SP3.5%4/2/0/4 W/B150% SP2.0%4/5/1/0 W/B100% SP6.0%4/5/1/0 W/B125% SP5.5%4/5/1/0 W/B150% SP4.5%

0

100

200

300

400

500

600

700

0 30 60 90 120 150

(cm

3 )

sec

0.1MPa

5/5/0/0 W/B100% SP6.0%5/5/0/0 W/B125% SP5.5%5/5/0/0 W/B150% SP4.5%

0

100

200

300

400

500

600

700

0 30 60 90 120 150

(cm

3 )

sec

0.1MPa

4/4/0/2 W/B100% SP4.5%4/4/0/2 W/B150% SP4.0%4/4/0/2 W/B200% SP3.0%

0

100

200

300

400

500

600

700

0 30 60 90 120 150

(cm

3 )

sec

0.1MPa

4/4/0/2 W/B100% SP4.0%4/4/0/2 W/B100% SP4.5%

/ SS/ =5/1/4

0

10

20

30

40

50

60

0 2 4 6 8 10 12g

5/5/0/0 W/B100% SP6.0%5/5/0/0 W/B125% SP5.5%

W/B100%

W/B150%

W/B125%

W/B100%

W/B150%

W/B125%,W/B150%,W/B100%

SP4.0%

SP4.5%

W/B200% W/B150%

W/B100%

－30－－30－


0

10

20

30

40

50

0 200 400 600 800

(cm

3 )

sec

2.0MPa

5/5/0/0 W/B100% SP6.0%5/5/0/0 W/B125% SP5.5%5/5/0/0 W/B150% SP4.5%

0

10

20

30

40

50

0 200 400 600 800

(cm

3 )

sec

2.0MPa

4/5/1/0 W/B100% SP6.0%4/5/1/0 W/B125% SP5.5%4/5/1/0 W/B150% SP4.5%

0

10

20

30

40

50

0 200 400 600 800

(cm

3 )

sec

2.0MPa

4/2/0/4 W/B100% SP3.5%

4/2/0/4 W/B150% SP2.0%

0

10

20

30

40

50

0 200 400 600 800

(cm

3 )

sec

2.0MPa

4/4/0/2 W/B100% SP4.0%4/4/0/2 W/B150% SP4.0%4/4/0/2 W/B200% SP3.0%

2.2-7

OPC/SF/SS/FA

2 24W/B % W/B %

100 125 150 200 100 125 150 200 5/5/0/0 0.0 0.0 0.0 0.4 0.0 0.0 0.0 0.0 4/5/1/0 0.0 0.0 0.1 0.2 0.0 0.0 0.0 0.0 4/4/0/2 0.0 0.1 0.7 0.0 0.0 1.5 4/2/0/4 0.1 1.2 0.0 1.9 3/6/1/0 0.0 0.0 0.0 0.0 3/6/0/1 0.0 0.1 0.0 0.0

72008 2.2-17

W/BW/B

4/2/0/4 W/B=150% 4/4/0/2W/B=200% FA

2.2-17

8 (2008 )W/B SP/B 2.2-18 W/B

2.2-196 8 20 27 12

W/B SP/B 6)

W/B150% W/B125%

W/B100%

W/B150%

W/B125%

W/B100%

W/B100%

W/B150% W/B150%

W/B100%

W/B200%

0

10

20

30

40

50

0 200 400 600 800

(cm

3 )

sec

2.0MPa

5/5/0/0 W/B100% SP6.0%5/5/0/0 W/B125% SP5.5%5/5/0/0 W/B150% SP4.5%

0

10

20

30

40

50

0 200 400 600 800

(cm

3 )

sec

2.0MPa

4/5/1/0 W/B100% SP6.0%4/5/1/0 W/B125% SP5.5%4/5/1/0 W/B150% SP4.5%

0

10

20

30

40

50

0 200 400 600 800

(cm

3 )

sec

2.0MPa

4/2/0/4 W/B100% SP3.5%

4/2/0/4 W/B150% SP2.0%

0

10

20

30

40

50

0 200 400 600 800

(cm

3 )

sec

2.0MPa

4/4/0/2 W/B100% SP4.0%4/4/0/2 W/B150% SP4.0%4/4/0/2 W/B200% SP3.0%

2.2-7

OPC/SF/SS/FA

2 24W/B % W/B %

100 125 150 200 100 125 150 200 5/5/0/0 0.0 0.0 0.0 0.4 0.0 0.0 0.0 0.0 4/5/1/0 0.0 0.0 0.1 0.2 0.0 0.0 0.0 0.0 4/4/0/2 0.0 0.1 0.7 0.0 0.0 1.5 4/2/0/4 0.1 1.2 0.0 1.9 3/6/1/0 0.0 0.0 0.0 0.0 3/6/0/1 0.0 0.1 0.0 0.0

72008 2.2-17

W/BW/B

4/2/0/4 W/B=150% 4/4/0/2W/B=200% FA

2.2-17

8 (2008 )W/B SP/B 2.2-18 W/B

2.2-196 8 20 27 12

W/B SP/B 6)

W/B150% W/B125%

W/B100%

W/B150%

W/B125%

W/B100%

W/B100%

W/B150% W/B150%

W/B100%

W/B200%

－31－－31－


24

0.44 10.5 7.77 186.5 W/B

2.2-18 W/B

2.2-19 W/B

9 (2007 ) 2.2-2 500Pa 1

150R

2/5/3/0 3/6/0/1 3/5/2/0 3/6/1/0

10 (2008 )6 W/B SP/B

5/5/0/0

0

5

10

15

20

75 100 125 150 175 200 225

h

5/5/0/0 SP2.5%

5/5/0/0 SP3.0%

5/5/0/0 SP3.5%

5/5/0/0 SP4.0%

5/5/0/0 SP4.5%

5/5/0/0 SP5.0%

5/5/0/0 SP5.5%

5/5/0/0 SP6.0%

4/5/1/0

0

5

10

15

20

75 100 125 150 175 200 225h

4/5/1/0 SP2.0%

4/5/1/0 SP2.5%

4/5/1/0 SP3.0%

4/5/1/0 SP4.0%

4/5/1/0 SP4.5%

4/5/1/0 SP5.0%

4/5/1/0 SP5.5%

4/5/1/0 SP6.0%

4/5/1/0

0.0

1.0

2.0

3.0

4.0

5.0

6.0

7.0

8.0

75 100 125 150 175 200 225

4/4/0/2

0.0

1.0

2.0

3.0

4.0

5.0

6.0

7.0

8.0

75 100 125 150 175 200 225

5/5/0/0

0.0

1.0

2.0

3.0

4.0

5.0

6.0

7.0

8.0

75 100 125 150 175 200 225

24

0.44 10.5 7.77 186.5 W/B

2.2-18 W/B

2.2-19 W/B

9 (2007 ) 2.2-2 500Pa 1

150R

2/5/3/0 3/6/0/1 3/5/2/0 3/6/1/0

10 (2008 )6 W/B SP/B

5/5/0/0

0

5

10

15

20

75 100 125 150 175 200 225

h

5/5/0/0 SP2.5%

5/5/0/0 SP3.0%

5/5/0/0 SP3.5%

5/5/0/0 SP4.0%

5/5/0/0 SP4.5%

5/5/0/0 SP5.0%

5/5/0/0 SP5.5%

5/5/0/0 SP6.0%

4/5/1/0

0

5

10

15

20

75 100 125 150 175 200 225

h

4/5/1/0 SP2.0%

4/5/1/0 SP2.5%

4/5/1/0 SP3.0%

4/5/1/0 SP4.0%

4/5/1/0 SP4.5%

4/5/1/0 SP5.0%

4/5/1/0 SP5.5%

4/5/1/0 SP6.0%

4/5/1/0

0.0

1.0

2.0

3.0

4.0

5.0

6.0

7.0

8.0

75 100 125 150 175 200 225

4/4/0/2

0.0

1.0

2.0

3.0

4.0

5.0

6.0

7.0

8.0

75 100 125 150 175 200 225

5/5/0/0

0.0

1.0

2.0

3.0

4.0

5.0

6.0

7.0

8.0

75 100 125 150 175 200 225

－32－－32－


2.2-206 0.2 8kPa 2.2-2 500Pa

18.4mm 6 W/B SP/BSP/B

2.2-20 W/B

11 (2007 )FA 5/0/0/5 W/B=100% 1,176kPa

SF 5/5/0/0 SS 5/0/5/04/5/1/0 4/2/0/4 3/6/1/0 3/6/0/1 200kPa10kPa W/B=200%

0

1228 2008 2.2-21

SF 5/5/0/0 SS 4/5/1/0 W/B=100%18 21MPa

OPC FA 4/4/0/2 15 16 MPaSS 3/6/1/0 FA 3/6/0/1 4/2/0/4 8 MPa

OPC 20% 2/5/3/05/5/0/0 4/5/1/0

OPC SF

OPC SF

5/5/0/0 6h

0

10

20

30

40

50

75 100 125 150 175 200 225

mm

5/5/0/0 SP4.0%5/5/0/0 SP4.0% 5.0%5/5/0/0 SP5.0% 6.0%5/5/0/0 SP6 0%

2kPa

0.5kPa

4/5/1/0 6h

0

10

20

30

40

50

75 100 125 150 175 200 225

mm

4/5/1/0 SP3.0%4/5/1/0 SP3.0% 4.0%4/5/1/0 SP4.0% 5.0%4/5/1/0 SP5.0% 6.0%4/5/1/0 SP6.0%

2kPa

0.5kPa

2.2-206 0.2 8kPa 2.2-2 500Pa

18.4mm 6 W/B SP/BSP/B

2.2-20 W/B

11 (2007 )FA 5/0/0/5 W/B=100% 1,176kPa

SF 5/5/0/0 SS 5/0/5/04/5/1/0 4/2/0/4 3/6/1/0 3/6/0/1 200kPa10kPa W/B=200%

0

1228 2008 2.2-21

SF 5/5/0/0 SS 4/5/1/0 W/B=100%18 21MPa

OPC FA 4/4/0/2 15 16 MPaSS 3/6/1/0 FA 3/6/0/1 4/2/0/4 8 MPa

OPC 20% 2/5/3/05/5/0/0 4/5/1/0

OPC SF

OPC SF

5/5/0/0 6h

0

10

20

30

40

50

75 100 125 150 175 200 225

mm

5/5/0/0 SP4.0%5/5/0/0 SP4.0% 5.0%5/5/0/0 SP5.0% 6.0%5/5/0/0 SP6 0%

2kPa

0.5kPa

4/5/1/0 6h

0

10

20

30

40

50

75 100 125 150 175 200 225

mm

4/5/1/0 SP3.0%4/5/1/0 SP3.0% 4.0%4/5/1/0 SP4.0% 5.0%4/5/1/0 SP5.0% 6.0%4/5/1/0 SP6.0%

2kPa

0.5kPa

－33－－33－


2.2-21

13 (2008 )0.05MPa

2.2-20(a)0.115MPa 3/6/0/1 W/B=100% SP/B=6.0%

(b)

(a) (b) 2.2-20 50mm

14 pH (2007 )3 pH 2.2-8

pH 11.0 OPC 30% 3/6/1/0 3/6/0/1 2/5/3/020

50 pH 1150% pH 11

0

10

20

30

0.25 0.50 0.75 1.00 1.25B/W

MPa

10/0/0/05/5/0/04/5/1/03/6/1/02/5/3/03/5/2/04/4/0/24/2/0/43/6/0/1

2.2-21

13 (2008 )0.05MPa

2.2-20(a)0.115MPa 3/6/0/1 W/B=100% SP/B=6.0%

(b)

(a) (b) 2.2-20 50mm

14 pH (2007 )3 pH 2.2-8

pH 11.0 OPC 30% 3/6/1/0 3/6/0/1 2/5/3/020

50 pH 1150% pH 11

0

10

20

30

0.25 0.50 0.75 1.00 1.25B/W

MPa

10/0/0/05/5/0/04/5/1/03/6/1/02/5/3/03/5/2/04/4/0/24/2/0/43/6/0/1

－34－－34－


2.2-8 pH

OPC/SF/SS/FA W/B (%)

pH20 2 50 2

5/5/0/0 100 12.11 11.40 10.60 9.61 5/5/0/0 200 12.09 11.49 10.63 9.40 4/5/1/0 200 12.29 11.54 10.50 9.32 4/4/0/2 100 11.98 11.16 10.68 9.52 4/4/0/2 200 12.28 11.44 10.66 9.47 4/2/0/4 100 12.35 11.83 10.37 9.97 3/6/1/0 100 11.56 10.30 10.60 9.61 3/6/0/1 100 11.31 10.02 10.49 9.28 2/5/3/0 100 10.93 9.71 10.22 9.05

(2)1 2007

2.2-221.0MPa

2.2-21

2.2-22

2.2-21

2.2-23

0.1MPa

2.2-8 pH

OPC/SF/SS/FA W/B (%)

pH20 2 50 2

5/5/0/0 100 12.11 11.40 10.60 9.61 5/5/0/0 200 12.09 11.49 10.63 9.40 4/5/1/0 200 12.29 11.54 10.50 9.32 4/4/0/2 100 11.98 11.16 10.68 9.52 4/4/0/2 200 12.28 11.44 10.66 9.47 4/2/0/4 100 12.35 11.83 10.37 9.97 3/6/1/0 100 11.56 10.30 10.60 9.61 3/6/0/1 100 11.31 10.02 10.49 9.28 2/5/3/0 100 10.93 9.71 10.22 9.05

(2)1 2007

2.2-221.0MPa

2.2-21

2.2-22

2.2-21

2.2-23

0.1MPa

－35－－35－


－36－－36－


0.1MPa 1.0MPa 2.0MPa 5/5/0/0 2.0MPa

No.1 3 5/5/0/0 1

2.2-9 1MPa

No. OPC/SF/SS/FA W/B (%)

SP/B (%) ( m) (mPa s) (Pa) (MPa) (L)

1 5/5/0/0 100 6.0

100

100.5 3.8 1.46 1.0 0.07 2 5/5/0/0 125 5.5 72.4 3.4 1.35 1.0 3.38 3 5/5/0/0 150 4.5 102.8 7.7 1.33 1.0 1.49 4 4/5/1/0 100 6.0 73.8 1.5 1.44 1.0 0.57 5 4/5/1/0 125 5.5 92.1 4.9 1.38 1.0 0.44 6 4/5/1/0 150 4.0 55.0 4.4 1.33 1.0 1.65 7 4/4/0/2 100 4.5 68.9 3.2 1.46 1.0 0.65 8 4/4/0/2 150 4.0 43.2 2.9 1.33 1.0 0.89 9 3/6/0/1 100 6.0 71.6 1.5 1.43 1.0 0.42

10 3/6/1/0 100 6.0 95.0 3.7 1.42 1.0 0.05 1 5/5/0/0 100 6.0

50

100.6 2.3 1.46 1.0 0.28 2 5/5/0/0 125 5.5 70.4 2.3 1.35 1.0 0.34 3 5/5/0/0 150 4.5 60.8 4.8 1.33 1.0 0.45 4 4/5/1/0 100 6.0 88.8 1.7 1.44 1.0 0.36 5 4/5/1/0 125 5.5 70.4 2.3 1.38 1.0 0.29 6 4/5/1/0 150 4.0 49.2 3.1 1.33 1.0 0.22 7 4/4/0/2 100 4.5 67.7 3.2 1.46 1.0 0.07 8 4/4/0/2 150 4.0 42.9 2.0 1.33 1.0 0.37 9 3/6/0/1 100 6.0 103.6 2.9 1.43 1.0 0.23

10 3/6/1/0 100 6.0 94.1 2.1 1.42 1.0 0.25 1 5/5/0/0 100 6.0

20

120.2 3.6 1.46 1.0 0.10 2 5/5/0/0 125 5.5 79.6 4.0 1.35 1.0 0.11 3 5/5/0/0 150 4.5 71.9 7.0 1.33 1.0 0.07 4 4/5/1/0 100 6.0 101.9 2.4 1.44 1.0 0.09 5 4/5/1/0 125 5.5 63.8 2.1 1.38 1.0 0.16 6 4/5/1/0 150 4.0 71.9 7.0 1.33 1.0 0.14 7 4/4/0/2 100 4.5 78.1 3.0 1.46 1.0 0.07 8 4/4/0/2 150 4.0 41.3 2.4 1.33 1.0 0.12 9 3/6/0/1 100 6.0 134.9 3.5 1.43 1.0 0.11

10 3/6/1/0 100 6.0 122 3.0 1.42 1.0 0.14

2.2-25 1.0MPa

0.1MPa 1.0MPa 2.0MPa 5/5/0/0 2.0MPa

No.1 3 5/5/0/0 1

2.2-9 1MPa

No. OPC/SF/SS/FA W/B (%)

SP/B (%) ( m) (mPa s) (Pa) (MPa) (L)

1 5/5/0/0 100 6.0

100

100.5 3.8 1.46 1.0 0.07 2 5/5/0/0 125 5.5 72.4 3.4 1.35 1.0 3.38 3 5/5/0/0 150 4.5 102.8 7.7 1.33 1.0 1.49 4 4/5/1/0 100 6.0 73.8 1.5 1.44 1.0 0.57 5 4/5/1/0 125 5.5 92.1 4.9 1.38 1.0 0.44 6 4/5/1/0 150 4.0 55.0 4.4 1.33 1.0 1.65 7 4/4/0/2 100 4.5 68.9 3.2 1.46 1.0 0.65 8 4/4/0/2 150 4.0 43.2 2.9 1.33 1.0 0.89 9 3/6/0/1 100 6.0 71.6 1.5 1.43 1.0 0.42

10 3/6/1/0 100 6.0 95.0 3.7 1.42 1.0 0.05 1 5/5/0/0 100 6.0

50

100.6 2.3 1.46 1.0 0.28 2 5/5/0/0 125 5.5 70.4 2.3 1.35 1.0 0.34 3 5/5/0/0 150 4.5 60.8 4.8 1.33 1.0 0.45 4 4/5/1/0 100 6.0 88.8 1.7 1.44 1.0 0.36 5 4/5/1/0 125 5.5 70.4 2.3 1.38 1.0 0.29 6 4/5/1/0 150 4.0 49.2 3.1 1.33 1.0 0.22 7 4/4/0/2 100 4.5 67.7 3.2 1.46 1.0 0.07 8 4/4/0/2 150 4.0 42.9 2.0 1.33 1.0 0.37 9 3/6/0/1 100 6.0 103.6 2.9 1.43 1.0 0.23

10 3/6/1/0 100 6.0 94.1 2.1 1.42 1.0 0.25 1 5/5/0/0 100 6.0

20

120.2 3.6 1.46 1.0 0.10 2 5/5/0/0 125 5.5 79.6 4.0 1.35 1.0 0.11 3 5/5/0/0 150 4.5 71.9 7.0 1.33 1.0 0.07 4 4/5/1/0 100 6.0 101.9 2.4 1.44 1.0 0.09 5 4/5/1/0 125 5.5 63.8 2.1 1.38 1.0 0.16 6 4/5/1/0 150 4.0 71.9 7.0 1.33 1.0 0.14 7 4/4/0/2 100 4.5 78.1 3.0 1.46 1.0 0.07 8 4/4/0/2 150 4.0 41.3 2.4 1.33 1.0 0.12 9 3/6/0/1 100 6.0 134.9 3.5 1.43 1.0 0.11

10 3/6/1/0 100 6.0 122 3.0 1.42 1.0 0.14

2.2-25 1.0MPa

－37－－37－


2.2-10 2MPa

No. OPC/SF/SS/FAW/B(%)

SP/B(%) ( m) (mPa s) (Pa) (MPa) (L)

1 5/5/0/0 100 6.0

100

65.1 7.5 1.46 2.0 32.3420.230.253.19.19.875.55210/0/5/5224.130.233.12.64.975.40510/0/5/5337.20.244.16.11.970.60010/1/5/4424.20.283.13.26.475.55210/1/5/4555.40.233.10.59.260.40510/1/5/46

7 4/4/0/2 100 4.5 107.4 6.1 1.46 2.0 1.6723.30.233.17.27.840.40512/0/4/48

9 3/6/0/1 100 6.0 101.6 2.2 1.43 2.0 1.0859.30.224.16.20.790.60010/1/6/301

1 5/5/0/0 100 6.0

50

122.8 3.3 1.46 2.0 0.222 5/5/0/0 125 5.5 103.8 4.4 1.35 2.0 0.25

82.20.233.19.41.575.40510/0/5/5352.00.244.14.13.750.60010/1/5/4452.00.283.14.13.755.55210/1/5/4532.00.233.17.45.660.40510/1/5/46

7 4/4/0/2 100 4.5 111.6 5.1 1.46 2.0 0.2862.00.233.12.25.7440512/0/4/4811.00.234.11.24.90160011/0/6/3932.00.224.10.47.22160010/1/6/301

1 5/5/0/0 100 6.0

20

47.5 2.2 1.46 2.0 0.2632.00.253.10.77.985.55210/0/5/5282.00.233.19.41.575.40510/0/5/53

4 4/5/1/0 100 6.0 101.8 2.4 1.44 2.0 0.1761.00.283.18.28.175.55210/1/5/4502.00.233.14.33.350.40510/1/5/4651.00.264.12.33.785.40012/0/4/4751.00.233.19.10.830.40512/0/4/4851.00.234.16.13.580.60011/0/6/3981.00.224.19.13.190.60010/1/6/301

2.2-26 2.0MPa

No.3 1.0MPa2.2-27 2.2-28 2.2-30

2.2-25 2.2-26 No.2 5/5/0/0W/B=125% SP/B=5.5% No.3 5/5/0/0 W/B=150% SP/B=4.5%

2.2-10 2MPa

No. OPC/SF/SS/FAW/B(%)

SP/B(%) ( m) (mPa s) (Pa) (MPa) (L)

1 5/5/0/0 100 6.0

100

65.1 7.5 1.46 2.0 32.3420.230.253.19.19.875.55210/0/5/5224.130.233.12.64.975.40510/0/5/5337.20.244.16.11.970.60010/1/5/4424.20.283.13.26.475.55210/1/5/4555.40.233.10.59.260.40510/1/5/46

7 4/4/0/2 100 4.5 107.4 6.1 1.46 2.0 1.6723.30.233.17.27.840.40512/0/4/48

9 3/6/0/1 100 6.0 101.6 2.2 1.43 2.0 1.0859.30.224.16.20.790.60010/1/6/301

1 5/5/0/0 100 6.0

50

122.8 3.3 1.46 2.0 0.222 5/5/0/0 125 5.5 103.8 4.4 1.35 2.0 0.25

82.20.233.19.41.575.40510/0/5/5352.00.244.14.13.750.60010/1/5/4452.00.283.14.13.755.55210/1/5/4532.00.233.17.45.660.40510/1/5/46

7 4/4/0/2 100 4.5 111.6 5.1 1.46 2.0 0.2862.00.233.12.25.7440512/0/4/4811.00.234.11.24.90160011/0/6/3932.00.224.10.47.22160010/1/6/301

1 5/5/0/0 100 6.0

20

47.5 2.2 1.46 2.0 0.2632.00.253.10.77.985.55210/0/5/5282.00.233.19.41.575.40510/0/5/53

4 4/5/1/0 100 6.0 101.8 2.4 1.44 2.0 0.1761.00.283.18.28.175.55210/1/5/4502.00.233.14.33.350.40510/1/5/4651.00.264.12.33.785.40012/0/4/4751.00.233.19.10.830.40512/0/4/4851.00.234.16.13.580.60011/0/6/3981.00.224.19.13.190.60010/1/6/301

2.2-26 2.0MPa

No.3 1.0MPa2.2-27 2.2-28 2.2-30

2.2-25 2.2-26 No.2 5/5/0/0W/B=125% SP/B=5.5% No.3 5/5/0/0 W/B=150% SP/B=4.5%

－38－－38－


No.2 No.32.2-15 No.2

2.2-2No.2 5/5/0/0 W/B=125% SP/B=5.5%

2.2-27

2.2-28 R=0.1m

No.2 No.32.2-15 No.2

2.2-2No.2 5/5/0/0 W/B=125% SP/B=5.5%

2.2-27

2.2-28 R=0.1m

－39－－39－


2.2-29 R=0.4m

2.2-30 R=0.8m

2.2.52007 2008 2

2007 OPCSF SS FA 37 W/B 100% 400% 2

4 SP/B 2 3.5% 1 9696

31 3110 W/B

300 400%pH

2008

2.2-29 R=0.4m

2.2-30 R=0.8m

2.2.52007 2008 2

2007 OPCSF SS FA 37 W/B 100% 400% 2

4 SP/B 2 3.5% 1 9696

31 3110 W/B

300 400%pH

2008

－40－－ 40－


2008 8 W/B 100 200%4 SP/B 1 6% 3 63 2008

SF SP/B63 43

20 20 SS FA

10

1 10 2.2-11

2.2-2

OPC/SF/SS/FA= 5/5/0/0 W/B=125% SP/B=5.5%

2.2-11 2008

*1 W/B (%)

SP/B (%)

*2*3

5/5/0/0 100 6.0

5/5/0/0 125 5.5

5/5/0/0 150 4.5

4/5/1/0 100 6.0

4/5/1/0 125 5.5

4/5/1/0 150 4.5

4/4/0/2 100 4.5

4/4/0/2 150 4.0

3/6/0/1 100 6.0

3/6/1/0 100 6.0

*1 OPC/SF/SS/FA*2*3

21

2008 8 W/B 100 200%4 SP/B 1 6% 3 63 2008

SF SP/B63 43

20 20 SS FA

10

1 10 2.2-11

2.2-2

OPC/SF/SS/FA= 5/5/0/0 W/B=125% SP/B=5.5%

2.2-11 2008

*1 W/B (%)

SP/B (%)

*2*3

5/5/0/0 100 6.0

5/5/0/0 125 5.5

5/5/0/0 150 4.5

4/5/1/0 100 6.0

4/5/1/0 125 5.5

4/5/1/0 150 4.5

4/4/0/2 100 4.5

4/4/0/2 150 4.0

3/6/0/1 100 6.0

3/6/1/0 100 6.0

*1 OPC/SF/SS/FA*2*3

21

－41－－ 41－


2.32.3.1(1)

2.1.4

100μm

1 2007

2008 22)

4

(2)

2.3-1

2.3-1

2 Na

2.3-1

2.32.3.1(1)

2.1.4

100μm

1 2007

2008 22)

4

(2)

2.3-1

2.3-1

2 Na

2.3-1

－42－－ 42－


2.3-1

2007 2008

Hi -20

10 20nm Na2O0.35%SiO2 20.6% pH9.0 10.5

(25 )1.132 (25 )6mPa s

Hi -30( AT)

10 20nm Na2O0.60%SiO2 30.6% pH9.0 10.5

(25 )1.213 (25 )6mPa s

2007

AT(α )

Hi -40

15 20nm Na2O0.60%SiO2 40.5% pH9.0 10.5

(25 )1.3 (25 )6mPa s

Hi-20AL

10 20nm Na2O0.35%SiO2 20 21% pH9.0 10.5

(25 )1.13 (25 )6mPa s

Al

Hi-30B

10 20nm Na2O0.05%SiO2 30 31% pH9.0 10.5

(25 )1.205 (25 )6mPa s

Hi-20P

10 20nm Na2O0.35%SiO2 20 21% pH4.0 6.0

(25 )1.153 (25 )20mPa s

NO3

Hi-30S

7 10nm Na2O0.60%SiO2 30 31% pH9.0 10.5

(25 )1.212 (25 )10mPa s

Hi-20G

40 50nm Na2O0.40%SiO2 20 21% pH9.0 10.5

(25 )1.128 (25 )6mPa s

MEYCOMP320T

Na2O 0.40%SiO2 29 31% pH9.5 10.5

(20 )1.2 (20 )10mPa sBASF

αHi

NC pH7(20 )1.07 (20 )1mPa s

BASFMEYCOMP320T

(3)2.2.1(3)

20072.3-2

2.3-2

2.3-1

2007 2008

Hi -20

10 20nm Na2O0.35%SiO2 20.6% pH9.0 10.5

(25 )1.132 (25 )6mPa s

Hi -30( AT)

10 20nm Na2O0.60%SiO2 30.6% pH9.0 10.5

(25 )1.213 (25 )6mPa s

2007

AT(α )

Hi -40

15 20nm Na2O0.60%SiO2 40.5% pH9.0 10.5

(25 )1.3 (25 )6mPa s

Hi-20AL

10 20nm Na2O0.35%SiO2 20 21% pH9.0 10.5

(25 )1.13 (25 )6mPa s

Al

Hi-30B

10 20nm Na2O0.05%SiO2 30 31% pH9.0 10.5

(25 )1.205 (25 )6mPa s

Hi-20P

10 20nm Na2O0.35%SiO2 20 21% pH4.0 6.0

(25 )1.153 (25 )20mPa s

NO3

Hi-30S

7 10nm Na2O0.60%SiO2 30 31% pH9.0 10.5

(25 )1.212 (25 )10mPa s

Hi-20G

40 50nm Na2O0.40%SiO2 20 21% pH9.0 10.5

(25 )1.128 (25 )6mPa s

MEYCOMP320T

Na2O 0.40%SiO2 29 31% pH9.5 10.5

(20 )1.2 (20 )10mPa sBASF

αHi

NC pH7(20 )1.07 (20 )1mPa s

BASFMEYCOMP320T

(3)2.2.1(3)

20072.3-2

2.3-2

－43－－ 43－


2.3-2

bmin

40μm ( L/ /100m)

10 /m40μm ( 10L/ /100m) 40μm ( 5L/ /100m)

1 /m70μm ( 10L/ /100m) 60μm ( 5L/ /100m)

0.1 /m90μm ( 10L/ /100m) 80μm ( 5L/ /100m)

pH 11

(4)1 2007

2007AT

2.3-2

4 5 57 105 180

pH5 3

57

2.3-2

bmin

40μm ( L/ /100m)

10 /m40μm ( 10L/ /100m) 40μm ( 5L/ /100m)

1 /m70μm ( 10L/ /100m) 60μm ( 5L/ /100m)

0.1 /m90μm ( 10L/ /100m) 80μm ( 5L/ /100m)

pH 11

(4)1 2007

2007AT

2.3-2

4 5 57 105 180

pH5 3

57

－44－－ 44－


2.3-2 2007

2 20082008 10 2.3-3

4AT Hi Hi 30 9

1010 120

pH

9

9 4

22

2.3-2 2007

2 20082008 10 2.3-3

4AT Hi Hi 30 9

1010 120

pH

9

9 4

22

－45－－ 45－


2.3-3 2008

(5) 2.3-3 2.3.2

2.3.3

2.3-3 2008

(5) 2.3-3 2.3.2

2.3.3

－46－－ 46－


2.3-3

2.3.2(1)

2.3-1

(2)A B

B 10 A B

120 20

1 2 3 4 1-1 1-2 1-3 2-1 2-2 2-3 3-1 3-2 3-3 4

120

pH pH

17

1428

20°98%RH95%RH5

10203040506080100120140160180

3

10μm 3017

1428

25μm 46mm 2000mm

JIS A1216:1998 28

3

728

1

ICP1

JGS0521-2000

20082007

JIS A1216:1998

3

2.3-3

2.3.2(1)

2.3-1

(2)A B

B 10 A B

120 20

1 2 3 4 1-1 1-2 1-3 2-1 2-2 2-3 3-1 3-2 3-3 4

120

pH pH

17

1428

20°98%RH95%RH5

10203040506080100120140160180

3

10μm 3017

1428

25μm 46mm 2000mm

JIS A1216:1998 28

3

728

1

ICP1

JGS0521-2000

20082007

JIS A1216:1998

3

－47－－ 47－


20

(3)2007 2.3-4 320mL Hi -30

5 180 α 8.0g 6.5g 6.0g 5.5g1 4 1mm

20082.3-1 9 2.3-5 10

2.3-6

2.3-4 2007No. Hi -30

(mL) α

(g) (mL) pH SiO2 (%)

1 320 8.0 76.00 9.02 30 24 5

2 320 6.5 76.75 9.19 30 24 57

3 320 6.0 77.00 9.17 30 24 105

4 320 5.5 77.25 9.28 30 24 180

2.3-5 2008

nm

SiO2 %

1-1 Hi -20 10 20 20 161-2 Hi -30 10 20 30 241-3 Hi -40 15 20 40 32

2-1 Hi -20AL 10 20 20 16AL

2-2 Hi -30B 10 20 30 16

2-3 Hi -20P 10 20 20 16 NO3

3-1 Hi -30S

7 1030

243-2 7 10 163-3 Hi -20G 40 50 20 164 MEYCO MP320T 30 24

20

(3)2007 2.3-4 320mL Hi -30

5 180 α 8.0g 6.5g 6.0g 5.5g1 4 1mm

20082.3-1 9 2.3-5 10

2.3-6

2.3-4 2007No. Hi -30

(mL) α

(g) (mL) pH SiO2 (%)

1 320 8.0 76.00 9.02 30 24 5

2 320 6.5 76.75 9.19 30 24 57

3 320 6.0 77.00 9.17 30 24 105

4 320 5.5 77.25 9.28 30 24 180

2.3-5 2008

nm

SiO2 %

1-1 Hi -20 10 20 20 161-2 Hi -30 10 20 30 241-3 Hi -40 15 20 40 32

2-1 Hi -20AL 10 20 20 16AL

2-2 Hi -30B 10 20 30 16

2-3 Hi -20P 10 20 20 16 NO3

3-1 Hi -30S

7 1030

243-2 7 10 163-3 Hi -20G 40 50 20 164 MEYCO MP320T 30 24

－48－－ 48－


2.3-6 2008 1000mLNo1-1

Hi20

No1-2

Hi30

No1-3

Hi40

No2-1

20AL

No2-2

30B

No2-3

20P*1

No3-1

30S24%

No3-2

30S16%

No3-3

20G

No4

MP320T

mL 800.00 800.00 800.00 800.00 500.00 NA 800.00 500.00 800.00 863.83

g 905.60 970.40 1040.00 905.60 602.50 NA 969.60 606.00 902.40 1040.90

mL 8.16 7.34 6.84 6.07 7.05 NA 6.19 7.80 11.66 0.00

g 16.33 14.68 13.68 12.14 14.11 NA 12.37 15.60 23.31 0.00

mL 191.83 192.65 193.15 193.93 492.95 NA 193.83 492.20 188.35 136.20

g 191.83 192.65 193.15 193.93 492.95 NA 193.83 492.20 188.35 145.73

% 16.3% 24.7% 33.4% 16.3% 16.3% NA 24.7% 16.3% 16.2% 28.1%

*1 No.2-3

2.3.3(1)1 2008

2.3-5 10α NC

120

2 pHpH pH pH

3JIS A1216:1998

2.3-1 5cm 10cm2007 2.3-4 1 7 14 28

2008 2.3-6 No.2-3 91 7 28 1mm/ 1%/

2.3-6 2008 1000mLNo1-1

Hi20

No1-2

Hi30

No1-3

Hi40

No2-1

20AL

No2-2

30B

No2-3

20P*1

No3-1

30S24%

No3-2

30S16%

No3-3

20G

No4

MP320T

mL 800.00 800.00 800.00 800.00 500.00 NA 800.00 500.00 800.00 863.83

g 905.60 970.40 1040.00 905.60 602.50 NA 969.60 606.00 902.40 1040.90

mL 8.16 7.34 6.84 6.07 7.05 NA 6.19 7.80 11.66 0.00

g 16.33 14.68 13.68 12.14 14.11 NA 12.37 15.60 23.31 0.00

mL 191.83 192.65 193.15 193.93 492.95 NA 193.83 492.20 188.35 136.20

g 191.83 192.65 193.15 193.93 492.95 NA 193.83 492.20 188.35 145.73

% 16.3% 24.7% 33.4% 16.3% 16.3% NA 24.7% 16.3% 16.2% 28.1%

*1 No.2-3

2.3.3(1)1 2008

2.3-5 10α NC

120

2 pHpH pH pH

3JIS A1216:1998

2.3-1 5cm 10cm2007 2.3-4 1 7 14 28

2008 2.3-6 No.2-3 91 7 28 1mm/ 1%/

－49－－ 49－


2.3-1 2007 2 7

4 2008

i. 2.3-6 9

ii. 2.3-2 20 98%RH 95%RH 3

50%RH1

80%RH98%RH 95%RH

2.3-1 2007 2 7

4 2008

i. 2.3-6 9

ii. 2.3-2 20 98%RH 95%RH 3

50%RH1

80%RH98%RH 95%RH

－50－－50－


2.3-2

iii. 1

1 2 1

5a. 2007

2007 2 4 3 2.3-3 Anton PaarPhysica MCR301 2.3-7

Gustafson Stille 2005

0.01 200 (1/s)1 60 1

12 5 10 20 103 4 5 20 40 20

98%RH 95%RH

2.3-2

iii. 1

1 2 1

5a. 2007

2007 2 4 3 2.3-3 Anton PaarPhysica MCR301 2.3-7

Gustafson Stille 2005

0.01 200 (1/s)1 60 1

12 5 10 20 103 4 5 20 40 20

98%RH 95%RH

－51－－51－


2.3-3 Anton Paar Physica MCR301

2.3-7

2.3-3 Anton Paar Physica MCR301

2.3-7

－52－－52－


b. 20082008 4 1-2 2-1 3-1 4

2007 Anton Paar Physica MCR301

2007 2.3-8

2.3-8 2008

1Hz

5%

60

180 3

240 4

6 20072.3-4 400mL 0.01MPa 2.3-5

10μm2 3 4 3 Hi 2.3-9

10 2.3-10

2.3-4

L

b. 20082008 4 1-2 2-1 3-1 4

2007 Anton Paar Physica MCR301

2007 2.3-8

2.3-8 2008

1Hz

5%

60

180 3

240 4

6 20072.3-4 400mL 0.01MPa 2.3-5

10μm2 3 4 3 Hi 2.3-9

10 2.3-10

2.3-4

L

－53－－53－


2.3-5 10μm

2.3-9

pHmin mPa s

HI 6.5 2 9.19 57 2.3 3 9.17 105 2.3 4 9.28 180 2.6

2.3-10

pHmPa s

MC 10 1% 12.0 1.3

7JGS0521-2000

2.3-6 5cm 10cm2007 2 1 7 14 28

25 50 100kPa 3 20084 1 7 28 50 100 150kPa

3 1mm/ 1%/

2.3-5 10μm

2.3-9

pHmin mPa s

HI 6.5 2 9.19 57 2.3 3 9.17 105 2.3 4 9.28 180 2.6

2.3-10

pHmPa s

MC 10 1% 12.0 1.3

7JGS0521-2000

2.3-6 5cm 10cm2007 2 1 7 14 28

25 50 100kPa 3 20084 1 7 28 50 100 150kPa

3 1mm/ 1%/

－54－－ 54－


2.3-6 2007 1 7 100kPa

8 2007

25μm 46mm 2,000mm 5mm

2 2.3-10 103 500mm 0.5MPa

9 2008

4

a.pH13

28 2.3.3 (1) 3

pH 8.22.3-11

pH=8.2 pH=9.02 2.3-7

2.3-6 2007 1 7 100kPa

8 2007

25μm 46mm 2,000mm 5mm

2 2.3-10 103 500mm 0.5MPa

9 2008

4

a.pH13

28 2.3.3 (1) 3

pH 8.22.3-11

pH=8.2 pH=9.02 2.3-7

－55－－ 55－


2.3-11g

6 222.23

2 30.70

6 0.85

13.89

4.02

2.01

0.54

0.06

490.68

81.88

2.3-7 (pH=9.02)

pH13pH13 1.0

2.3-12 2.3-8

2.3-12(kg)

L (kg)

1L

(kg/L)

1.0 25 25 0.25 33.33 50 1.50 0.75

2.3-11g

6 222.23

2 30.70

6 0.85

13.89

4.02

2.01

0.54

0.06

490.68

81.88

2.3-7 (pH=9.02)

pH13pH13 1.0

2.3-12 2.3-8

2.3-12(kg)

L (kg)

1L

(kg/L)

1.0 25 25 0.25 33.33 50 1.50 0.75

－56－－56－


2.3-8 (pH=13.1)

b. ( )

5) b

3 10vol%

10a. 2007i.

2007 27 28

2.3-9 2.3-4 2.3-13

1/2 3/8 1/4 5mm 2.3-9

2.3-8 (pH=13.1)

b. ( )

5) b

3 10vol%

10a. 2007i.

2007 27 28

2.3-9 2.3-4 2.3-13

1/2 3/8 1/4 5mm 2.3-9

－57－－57－


2.3-4

2.3-13

(mm) (mm)

1/2 16.7 100 150 200 1 3 7 28

3/8 12.8 100 150 200 1 3 7 28

1/4 9.1 100 150 200 1 3 7 28

5mm 5 300 2 7 28

ii. 2.3-4

sw LDpD4

2

( 2.3-1)

ws pLD4 ( 2.3-2)

iii. 2.3-5

2.3-5

sreq

bpL2

wpL

s

D

2.3-4

2.3-13

(mm) (mm)

1/2 16.7 100 150 200 1 3 7 28

3/8 12.8 100 150 200 1 3 7 28

1/4 9.1 100 150 200 1 3 7 28

5mm 5 300 2 7 28

ii. 2.3-4

sw LDpD4

2

( 2.3-1)

ws pLD4 ( 2.3-2)

iii. 2.3-5

2.3-5

sreq

bpL2

wpL

s

D

－58－－58－


b. 2008i.

20081 50mm

100 200μm 2 50 100 200mm 3 62.3-6

21-2 3-1 100μm

1-2 200μm

2.3-14

2.3-6

100mm

200mm

50mm

200mm

100mm50mm

b. 2008i.

20081 50mm

100 200μm 2 50 100 200mm 3 62.3-6

21-2 3-1 100μm

1-2 200μm

2.3-14

2.3-6

100mm

200mm

50mm

200mm

100mm50mm

－59－－59－


2.3-14 2008

1-2 3-1

100μm 50mm 100mm 200mm

200μm 50mm 100mm 200mm

ii.

2.3-14 6 P 3 4 Qe 2.3-7 (2.3-3)

2.3-7

312

BPQLe

2.3-3

0.01MPa

iii. 2007 2.3-8

2.3-8

L

ps c

e

Lpe s2

B

Q vP

L

2.3-14 2008

1-2 3-1

100μm 50mm 100mm 200mm

200μm 50mm 100mm 200mm

ii.

2.3-14 6 P 3 4 Qe 2.3-7 (2.3-3)

2.3-7

312

BPQLe

2.3-3

0.01MPa

iii. 2007 2.3-8

2.3-8

L

ps c

e

Lpe s2

B

Q vP

L

－ 60－－ 60－


11 20084 1-2 2-1 3-1 4

200mL 2.3-10100mL 100mL 200mL20 1

2.3-15 2.3-11

2.3-10

2.3-15

ICP-AES Na ICP-AES K ICP-AES Cl

ICP (SPS7800) (ICS3000) 2.3-11

11 20084 1-2 2-1 3-1 4

200mL 2.3-10100mL 100mL 200mL20 1

2.3-15 2.3-11

2.3-10

2.3-15

ICP-AES Na ICP-AES K ICP-AES Cl

ICP (SPS7800) (ICS3000) 2.3-11

－ 61－－ 61－


2.3.4(1)1 2008

1-1 3-3 α120 2.3-16

2-3 3-31,200 20 40mPa s

2.3-16 pH Hi

Hi[mL] α

[g] [mL] pHmin

120α[g]

1-1 1 320 6.75 76.63 9.01 101

6.53 2 320 6.50 76.75 9.02 1233 320 6.00 77.00 9.02 215

1-2

1 320 8.00 76.00 9.02 5

5.87

2 320 6.50 76.75 9.19 573 320 6.00 77.00 9.17 1054 320 5.75 77.13 8.99 1345 320 5.50 77.25 9.28 1806 320 4.00 78.00 9.30 1200

1-3

1 320 6.50 76.75 8.96 30

5.47 2 320 6.00 77.00 9.08 72

3 320 5.50 77.25 9.13 114

4 320 5.00 77.50 9.00 228

2-1 1 320 5.50 77.25 8.98 56

4.85 2 320 5.00 77.50 8.77 743 320 4.50 77.75 8.93 232

2-2 1 200 6.00 197.00 9.85 73

5.64 2 200 5.80 197.10 9.89 853 200 5.50 197.25 9.93 152

2-3 1 300 32.00 84.00 4.96

3-1 1 320 6.00 77.00 9.45 36

4.95 2 320 5.00 77.50 9.43 1093 320 4.50 77.75 9.56 216

3-2 1 200 6.50 196.75 9.40 88

6.24 2 200 6.20 196.90 9.42 1253 200 6.00 197.00 9.49 155

3-3 1 320 10.00 75.00 8.91 45

9.32 2 320 9.00 75.50 8.90 156

2.3.4(1)1 2008

1-1 3-3 α120 2.3-16

2-3 3-31,200 20 40mPa s

2.3-16 pH Hi

Hi[mL] α

[g] [mL] pHmin

120α[g]

1-1 1 320 6.75 76.63 9.01 101

6.53 2 320 6.50 76.75 9.02 1233 320 6.00 77.00 9.02 215

1-2

1 320 8.00 76.00 9.02 5

5.87

2 320 6.50 76.75 9.19 573 320 6.00 77.00 9.17 1054 320 5.75 77.13 8.99 1345 320 5.50 77.25 9.28 1806 320 4.00 78.00 9.30 1200

1-3

1 320 6.50 76.75 8.96 30

5.47 2 320 6.00 77.00 9.08 72

3 320 5.50 77.25 9.13 114

4 320 5.00 77.50 9.00 228

2-1 1 320 5.50 77.25 8.98 56

4.85 2 320 5.00 77.50 8.77 743 320 4.50 77.75 8.93 232

2-2 1 200 6.00 197.00 9.85 73

5.64 2 200 5.80 197.10 9.89 853 200 5.50 197.25 9.93 152

2-3 1 300 32.00 84.00 4.96

3-1 1 320 6.00 77.00 9.45 36

4.95 2 320 5.00 77.50 9.43 1093 320 4.50 77.75 9.56 216

3-2 1 200 6.50 196.75 9.40 88

6.24 2 200 6.20 196.90 9.42 1253 200 6.00 197.00 9.49 155

3-3 1 320 10.00 75.00 8.91 45

9.32 2 320 9.00 75.50 8.90 156

－ 62－－ 62－


4 NS120 2.3-17

2.3-17 pH MEYCO MP32OT

MP320T [g] NC

[g] [%] pHmin

120NC

[%]

4

1 393.40 78.68 20.0 9.56 25

14 2 402.70 70.47 17.5 9.61 45

3 412.40 61.86 15.0 9.65 100

4 422.50 52.81 12.5 9.69 190

2-3 92.3-6

2 pH2007 pH 1 4 9.02 9.19 9.17 9.28

2008 pH 2.3-16 2.3-17 8.77 9.93pH 11

3a. 2007 1 4

2007 2.3-12

2.3-12 1 7 14 28

2.3-9

4 NS120 2.3-17

2.3-17 pH MEYCO MP32OT

MP320T [g] NC

[g] [%] pHmin

120NC

[%]

4

1 393.40 78.68 20.0 9.56 25

14 2 402.70 70.47 17.5 9.61 45

3 412.40 61.86 15.0 9.65 100

4 422.50 52.81 12.5 9.69 190

2-3 92.3-6

2 pH2007 pH 1 4 9.02 9.19 9.17 9.28

2008 pH 2.3-16 2.3-17 8.77 9.93pH 11

3a. 2007 1 4

2007 2.3-12

2.3-12 1 7 14 28

2.3-9

－ 63－－ 63－


2.3-9

2.3-18 2.3-19 2.3-10 2.3-117

28 MPa 7

2.3-18 2007 kN/m2

1 2 3 4

1 21.2 15.2 11.0 9.1

7 30.3 26.1 13.1 9.2

14 33.2 23.6 31.6 25.7

28 37.8 22.9 28.7 30.9

2.3-19 2007 E50 kN/m2

1 2 3 4

1 615 234 184 109

7 811 602 442 164

14 728 516 713 568

28 1605 511 846 736

2.3-9

2.3-18 2.3-19 2.3-10 2.3-117

28 MPa 7

2.3-18 2007 kN/m2

1 2 3 4

1 21.2 15.2 11.0 9.1

7 30.3 26.1 13.1 9.2

14 33.2 23.6 31.6 25.7

28 37.8 22.9 28.7 30.9

2.3-19 2007 E50 kN/m2

1 2 3 4

1 615 234 184 109

7 811 602 442 164

14 728 516 713 568

28 1605 511 846 736

－ 64－－ 64－


2.3-10 2007

2.3-11 E50 2007

b. 2008 1-1 1-2 1-3 2-1 2-2 3-1 3-2 3-3 42008 2.3-20 2.3-21

2.3-12 2.3-131-2 3-1 4 3 3-1

1-3 1-2

3-3 7

(d)

(d)

2.3-10 2007

2.3-11 E50 2007

b. 2008 1-1 1-2 1-3 2-1 2-2 3-1 3-2 3-3 42008 2.3-20 2.3-21

2.3-12 2.3-131-2 3-1 4 3 3-1

1-3 1-2

3-3 7

(d)

(d)

－ 65－－ 65－


2.3-20 2008 kN/m2

1 7 28

1-1 (Hi20)

16.3% 7.2 6.2 5.2

6.2 11.6 11.8 11.0

11.416.5 17.1 16.5

16.7

1-2 (Hi30)

24.7% 18.9 17.1 18.6

18.2 26.3 27.6 24.9

26.236.9 32.7 40.0

36.5

1-3 (Hi40)

33.4% 17.2 17.3 14.3

16.3 22.6 14.9 18.0

18.532.9 34.5 33.0

33.5

2-1 (20AL)

16.3% 7.3 6.4 4.7

6.1 8.1 9.1 8.6

8.612.7 12.7 12.6

12.7

2-2 (30B)

16.3% 5.0 5.1 5.1

5.1 7.5 7.5 7.7

7.68.3 8.4 8.5

8.4

3-1 (30S24)

24.7% 27.0 31.2 33.8

30.7 46.9 58.4 57.9

54.459.4 67.6 53.1

60.0

3-2 (30S16)

16.3% 10.9 11.2 10.1

10.7 20.6 21.3 21.0

21.026.8 26.6 27.7

27.0

4(MP320T)

28.1% 15.5 11.1 11.2

12.635.4 32.4 35.8

34.537.9 47.0 42.7

42.5

2.3-12 2008

2.3-20 2008 kN/m2

1 7 28

1-1 (Hi20)

16.3% 7.2 6.2 5.2

6.2 11.6 11.8 11.0

11.416.5 17.1 16.5

16.7

1-2 (Hi30)

24.7% 18.9 17.1 18.6

18.2 26.3 27.6 24.9

26.236.9 32.7 40.0

36.5

1-3 (Hi40)

33.4% 17.2 17.3 14.3

16.3 22.6 14.9 18.0

18.532.9 34.5 33.0

33.5

2-1 (20AL)

16.3% 7.3 6.4 4.7

6.1 8.1 9.1 8.6

8.612.7 12.7 12.6

12.7

2-2 (30B)

16.3% 5.0 5.1 5.1

5.1 7.5 7.5 7.7

7.68.3 8.4 8.5

8.4

3-1 (30S24)

24.7% 27.0 31.2 33.8

30.7 46.9 58.4 57.9

54.459.4 67.6 53.1

60.0

3-2 (30S16)

16.3% 10.9 11.2 10.1

10.7 20.6 21.3 21.0

21.026.8 26.6 27.7

27.0

4(MP320T)

28.1% 15.5 11.1 11.2

12.635.4 32.4 35.8

34.537.9 47.0 42.7

42.5

2.3-12 2008

－ 66－－ 66－


2.3-21 2008 E50 kN/m2

1 7 28

1-1 (Hi20)

16.3% 77 76 71

74 199 188 190

192 323 328 327

326

1-2 (Hi30)

24.7% 256 233 232

240 542 594 482

540 862 788 961

871

1-3 (Hi40)

33.4% 157 165 155

159 465 416 416

433 849 754 798

800

2-1 (20AL)

16.3% 66 65 58

63 145 148 142

145 232 209 236

225

2-2 (30B)

16.3% 51 47 47

48 103 106 105

105 146 151 151

149

3-1 (30S24)

24.7% 392 436 413

414 120311561175

11781428 1558 1657

1548

3-2 (30S16)

16.3% 155 142 140

146 392 359 358

370 567 533 546

549

4(MP320T)

28.1% 197 226 168

197900 847 843

863 1317 1464 1603

1461

2.3-13 2008

2.3-21 2008 E50 kN/m2

1 7 28

1-1 (Hi20)

16.3% 77 76 71

74 199 188 190

192 323 328 327

326

1-2 (Hi30)

24.7% 256 233 232

240 542 594 482

540 862 788 961

871

1-3 (Hi40)

33.4% 157 165 155

159 465 416 416

433 849 754 798

800

2-1 (20AL)

16.3% 66 65 58

63 145 148 142

145 232 209 236

225

2-2 (30B)

16.3% 51 47 47

48 103 106 105

105 146 151 151

149

3-1 (30S24)

24.7% 392 436 413

414 120311561175

11781428 1558 1657

1548

3-2 (30S16)

16.3% 155 142 140

146 392 359 358

370 567 533 546

549

4(MP320T)

28.1% 197 226 168

197900 847 843

863 1317 1464 1603

1461

2.3-13 2008

－ 67－－ 67－


4 200820 98%RH 95%RH 3 1-1 1-2

1-3 2-1 2-2 3-1 3-2 4 8

5a. 2007

2.3-14 2.3-22

20074 2.3-4

2.3-23

2.3-15 2.3-22

2.3-14

y

4 200820 98%RH 95%RH 3 1-1 1-2

1-3 2-1 2-2 3-1 3-2 4 8

5a. 2007

2.3-14 2.3-22

20074 2.3-4

2.3-23

2.3-15 2.3-22

2.3-14

y

－ 68－－ 68－


2.3-22 20072 3 4

57 105 180

5

10

20

30

40

50

60

80

100

120

140

160

180

200

2.3-23 2007

2 3 4 50 100 140

57 105 180

2.3-15 2007

(min)

2.3-22 20072 3 4

57 105 180

5

10

20

30

40

50

60

80

100

120

140

160

180

200

2.3-23 2007

2 3 4 50 100 140

57 105 180

2.3-15 2007

(min)

－ 69－－ 69－


b. 20084

2.3-16120

0 120

2.3-16 2008

6 20073 2.3-17

Hi 24 3

4 Hi 3 2α

2.3-13 2.3-14

b. 20084

2.3-16120

0 120

2.3-16 2008

6 20073 2.3-17

Hi 24 3

4 Hi 3 2α

2.3-13 2.3-14

－70－－70－


2.3-13

2.3-14

2.3-17

(sec)

2.3-13

2.3-14

2.3-17

(sec)

－71－－71－


7a. 2007 2

2007 2.3-15 2.3-18

7 7

2.3-15 1 7 14 28

2.3-18 2007

7a. 2007 2

2007 2.3-15 2.3-18

7 7

2.3-15 1 7 14 28

2.3-18 2007

－72－－72－


b. 2008 1-2 2-1 3-1 42008 2.3-24

2.3-19

(=0) 2.3-24

qu/2 2.3-2528 qu/2 1.4 1.6

2.3-24 20081 7 28

(kN/m2) (kN/m2) (kN/m2) (kN/m2) (kN/m2) (kN/m2)

1-2 (Hi30)

24.7% 50kPa

100kPa 150kPa

16.5 14.9 15.7

15.7 19.3 18.9 18.5

18.9 27.9 27.2 29.9

28.3

2-1 (20AL)

16.3% 50kPa

100kPa 150kPa

6.5 6.6 5.3

6.1 8.8 7.7 8.3

8.3 9.2 9.1 9.4

9.2

3-1 (30S24)

24.7% 50kPa

100kPa 150kPa

27.0 26.9 27.3

27.1 34.5 35.6 34.3

34.8 48.7 51.2 46.8

48.9

4(MP320T)

28.1% 50kPa

100kPa 150kPa

16.5 16.7 16.0

16.4 22.7 22.4 21.0

22.0 34.8 33.7 35.6

34.7

b. 2008 1-2 2-1 3-1 42008 2.3-24

2.3-19

(=0) 2.3-24

qu/2 2.3-2528 qu/2 1.4 1.6

2.3-24 20081 7 28

(kN/m2) (kN/m2) (kN/m2) (kN/m2) (kN/m2) (kN/m2)

1-2 (Hi30)

24.7% 50kPa

100kPa 150kPa

16.5 14.9 15.7

15.7 19.3 18.9 18.5

18.9 27.9 27.2 29.9

28.3

2-1 (20AL)

16.3% 50kPa

100kPa 150kPa

6.5 6.6 5.3

6.1 8.8 7.7 8.3

8.3 9.2 9.1 9.4

9.2

3-1 (30S24)

24.7% 50kPa

100kPa 150kPa

27.0 26.9 27.3

27.1 34.5 35.6 34.3

34.8 48.7 51.2 46.8

48.9

4(MP320T)

28.1% 50kPa

100kPa 150kPa

16.5 16.7 16.0

16.4 22.7 22.4 21.0

22.0 34.8 33.7 35.6

34.7

－73－－73－


2.3-19 2008

2.3-25 20081 7 28

qu/2

kN/m2 kN/m2

qu/2

kN/m2 kN/m2

qu/2

kN/m2 kN/m2

1-2 9.1 15.7 1.7 13.1 18.9 1.4 18.3 28.3 1.5

2-1 3.1 6.1 2.0 4.3 8.3 1.9 6.4 9.2 1.4

3-1 15.4 27.1 1.8 27.2 34.8 1.3 30.0 48.9 1.6

4 6.3 16.4 2.6 17.3 22.0 1.3 21.3 34.7 1.6

8 20072 10

3500mm 10

40μm

9 2008a.

2.3-20 2.3-21

2.3-19 2008

2.3-25 20081 7 28

qu/2

kN/m2 kN/m2

qu/2

kN/m2 kN/m2

qu/2

kN/m2 kN/m2

1-2 9.1 15.7 1.7 13.1 18.9 1.4 18.3 28.3 1.5

2-1 3.1 6.1 2.0 4.3 8.3 1.9 6.4 9.2 1.4

3-1 15.4 27.1 1.8 27.2 34.8 1.3 30.0 48.9 1.6

4 6.3 16.4 2.6 17.3 22.0 1.3 21.3 34.7 1.6

8 20072 10

3500mm 10

40μm

9 2008a.

2.3-20 2.3-21

－74－－74－


4 3-1 1-2 2-1 2-1

2.3-20 28 2008

2.3-21 28 2008

4 3-1 1-2 2-1 2-1

2.3-20 28 2008

2.3-21 28 2008

－75－－75－


b. 2.3-16 2.3-26

10vol% 2

2.3-26 2008

1-2 2-1 3-1 4 93 126 136 110

177 224 258 293

18 17 12 5

180 204 180 241

10a. 2007

2.3-162.3-27 2.3-22

2.3-16 2007

b. 2.3-16 2.3-26

10vol% 2

2.3-26 2008

1-2 2-1 3-1 4 93 126 136 110

177 224 258 293

18 17 12 5

180 204 180 241

10a. 2007

2.3-162.3-27 2.3-22

2.3-16 2007

－76－－76－


2.3-27 2007

mm mm

7 28

kN/m2 kN/m2 kPa kN/m2

1/2 16.7 100 50 2.1 20 0.8 150 70 1.9 60 1.7 200 130 2.7 50 1.0

3/8 12.8 100 350 11.2 370 11.8 150 500 10.7 450 9.6 200 500 8.0 770 12.3

1/4 9.1 100 600 13.7 400 9.1 150 800 12.1 520 7.9 200 1300 14.8 1200 13.7

5mm 5.0 300 1600 6.7 4000 16.7 300 1900 7.9 3200 13.3

2.3-22 2007

μm mm28 10kN/m2 2.3-5

2.3-23

10MPa 0.1 5mm

2.5 5 10 15kN/m2

10kN/m2 5mm 2.510MPa 1000m

2.3-27 2007

mm mm

7 28

kN/m2 kN/m2 kPa kN/m2

1/2 16.7 100 50 2.1 20 0.8 150 70 1.9 60 1.7 200 130 2.7 50 1.0

3/8 12.8 100 350 11.2 370 11.8 150 500 10.7 450 9.6 200 500 8.0 770 12.3

1/4 9.1 100 600 13.7 400 9.1 150 800 12.1 520 7.9 200 1300 14.8 1200 13.7

5mm 5.0 300 1600 6.7 4000 16.7 300 1900 7.9 3200 13.3

2.3-22 2007

μm mm28 10kN/m2 2.3-5

2.3-23

10MPa 0.1 5mm

2.5 5 10 15kN/m2

10kN/m2 5mm 2.510MPa 1000m

－77－－77－


2.3-23 2007

b. 2008

2.3-24 2.3-261-2 3-1

c

2.3-24 1-2 100μm 2008

2.3-23 2007

b. 2008

2.3-24 2.3-261-2 3-1

c

2.3-24 1-2 100μm 2008

－78－－78－


2.3-25 3-1 100μm 2008

2.3-26 1-2 200μm 2008

11 20081 2.3-28

100 300mg/L 0.03 0.09%

2.3-28 1 2008

1-2 2-1 3-1 4

pH - 9.19 9.12 9.89 9.91

% 0.83 0.66 0.69 0.84

Si mg/L 103 116 193 315

Na mg/ L 909 554 1224 2654

K mg/ L 2809 2386 1562 0

Cl mg/ L 3840 3020 3325 4495

2.3-25 3-1 100μm 2008

2.3-26 1-2 200μm 2008

11 20081 2.3-28

100 300mg/L 0.03 0.09%

2.3-28 1 2008

1-2 2-1 3-1 4

pH - 9.19 9.12 9.89 9.91

% 0.83 0.66 0.69 0.84

Si mg/L 103 116 193 315

Na mg/ L 909 554 1224 2654

K mg/ L 2809 2386 1562 0

Cl mg/ L 3840 3020 3325 4495

－79－－79－


2.3.52007 2008 2

20071 4

45 3

1

20089 10

2.3-29

1-2 2-1 3-1 44 1

2.3-29 2008

Si(%)

*1 *2

1-1 Si 16

1-2 Si 24

1-3 Si 32

2-1 Al 16

2-2 NH3 16

2-3 NO3 16

3-1 24

3-2 16

3-3 16

4 24

*1*2

2.3.52007 2008 2

20071 4

45 3

1

20089 10

2.3-29

1-2 2-1 3-1 44 1

2.3-29 2008

Si(%)

*1 *2

1-1 Si 16

1-2 Si 24

1-3 Si 32

2-1 Al 16

2-2 NH3 16

2-3 NO3 16

3-1 24

3-2 16

3-3 16

4 24

*1*2

－80－－ 80－


2.42.4.1(1)

15μm 100μm20~30nm

28 2 3

2008 1Superfine silica powder SFP

(2) 2.4-1 SFP

Superfine calcium hydroxide SFCaSP

2.4-1

SFP 1.0μm

0.30.8μm

SFP-20M

SFCa 1.0μm LT

SP 150

W

SFP 2.4-1

2.4-2 SFP SEM SFP1μm 0.3 0.8μm

2.4-1 SFP

100μm SFPSFCa SFCa SEM 2.4-3 SFP

2.42.4.1(1)

15μm 100μm20~30nm

28 2 3

2008 1Superfine silica powder SFP

(2) 2.4-1 SFP

Superfine calcium hydroxide SFCaSP

2.4-1

SFP 1.0μm

0.30.8μm

SFP-20M

SFCa 1.0μm LT

SP 150

W

SFP 2.4-1

2.4-2 SFP SEM SFP1μm 0.3 0.8μm

2.4-1 SFP

100μm SFPSFCa SFCa SEM 2.4-3 SFP

－81－－ 81－


C-S-HC: CaO S: SiO2 H: H2O

SP

150 150R

2.4-2 SFP SEM 2.4-3 SFCa SEM

(3)POSIVA

2.2-2 2.4-2

2.4-2

30 45s2 2%

28 4MPa pH 11

(4) 2.4-3 2.3.2

2.3.3

C-S-HC: CaO S: SiO2 H: H2O

SP

150 150R

2.4-2 SFP SEM 2.4-3 SFCa SEM

(3)POSIVA

2.2-2 2.4-2

2.4-2

30 45s2 2%

28 4MPa pH 11

(4) 2.4-3 2.3.2

2.3.3

－82－－ 82－


2.4-3

2.4.2(1)1

2.4-1

LA-92010

22.4-4 2.4-4 2.4-5

SFP SFCa 50% D50 0.464μm 0.416μm SFP 2.4-4 2.4-5 SFCa

SFP 95% D95 0.708μm SFP 1μmSFCa D95 1.304μm 1μm

SFCa SFP1μm

1 100μm 23)

μm1

2.4-4% μm

SFP SFCa D5 0.284 0.228 D50 0.464 0.416 D95 0.708 1.304

30

302

JSCE-G505-1999 28

50

2008

JSCEF532-1999

JSCEF531-1999

2.4-3

2.4.2(1)1

2.4-1

LA-92010

22.4-4 2.4-4 2.4-5

SFP SFCa 50% D50 0.464μm 0.416μm SFP 2.4-4 2.4-5 SFCa

SFP 95% D95 0.708μm SFP 1μmSFCa D95 1.304μm 1μm

SFCa SFP1μm

1 100μm 23)

μm1

2.4-4% μm

SFP SFCa D5 0.284 0.228 D50 0.464 0.416 D95 0.708 1.304

30

302

JSCE-G505-1999 28

50

2008

JSCEF532-1999

JSCEF531-1999

－83－－ 83－


2.4-4 SPF

2.4-5 SFCa

(2)SFP SFCa

SFP SPSFCa SP

(3)2.4-5 W/B SP/B

120% 1.5% 1 SFCa SP

0

5

10

15

20

25

0

20

40

60

80

100

(%)

(%)

μm

0

5

10

15

20

25

0

20

40

60

80

100

(%)

(%)

μm

2.4-4 SPF

2.4-5 SFCa

(2)SFP SFCa

SFP SPSFCa SP

(3)2.4-5 W/B SP/B

120% 1.5% 1 SFCa SP

0

5

10

15

20

25

0

20

40

60

80

100

(%)

(%)

μm

0

5

10

15

20

25

0

20

40

60

80

100

(%)

(%)

μm

－84－－ 84－


2.4-5

No. W/B SP/B A B

SFP SFCa SFP W SFCa SP W(%) (%) (%) (%) (g) (g) (g) (g) (g)

1 100 0 120 0.0 100 120 0 0 0 2 95 5 120 1.5 95 95 5 1.5 253 90 10 120 1.5 90 90 10 1.5 304 85 15 120 1.5 85 85 15 1.5 355 80 20 120 1.5 80 80 20 1.5 406 70 30 120 1.5 70 70 30 1.5 50

B :binder (=SFP+SFCa)

2.4.3(1)

20

1JSCE-F 531-1999

30 4.8mm 500cm3

230

3JSCE-F 532

2 24

4JSCE-G 505 50×100mm

1 20

5 pH50 14 50

1mm 20 5 172 pH pH

2.4-5

No. W/B SP/B A B

SFP SFCa SFP W SFCa SP W(%) (%) (%) (%) (g) (g) (g) (g) (g)

1 100 0 120 0.0 100 120 0 0 0 2 95 5 120 1.5 95 95 5 1.5 253 90 10 120 1.5 90 90 10 1.5 304 85 15 120 1.5 85 85 15 1.5 355 80 20 120 1.5 80 80 20 1.5 406 70 30 120 1.5 70 70 30 1.5 50

B :binder (=SFP+SFCa)

2.4.3(1)

20

1JSCE-F 531-1999

30 4.8mm 500cm3

230

3JSCE-F 532

2 24

4JSCE-G 505 50×100mm

1 20

5 pH50 14 50

1mm 20 5 172 pH pH

－85－－ 85－


2.4.4(1)1

2.4-62.4-6 30 SFCa

20% SFCa 20%

30 SFCa 20% 2.4-245sec SP/B W/B

W/B

2.4-6

No. (sec)

SFP (%)

SFCa (%) 30

1 100 0 20.34 20.33 2 95 5 33.56 33.24 3 90 10 41.26 42.26 4 85 15 44.99 51.09 5 80 20 38.47 50.75 6 70 30 67.34 127.85

2.4-6 SFCa

2 2.4-7

SFCa 20%

0

30

60

90

120

150

0 5 10 15 20 25 30

(sec

)

SFCa (wt%)

30

2.4.4(1)1

2.4-62.4-6 30 SFCa

20% SFCa 20%

30 SFCa 20% 2.4-245sec SP/B W/B

W/B

2.4-6

No. (sec)

SFP (%)

SFCa (%) 30

1 100 0 20.34 20.33 2 95 5 33.56 33.24 3 90 10 41.26 42.26 4 85 15 44.99 51.09 5 80 20 38.47 50.75 6 70 30 67.34 127.85

2.4-6 SFCa

2 2.4-7

SFCa 20%

0

30

60

90

120

150

0 5 10 15 20 25 30

(sec

)

SFCa (wt%)

30

－86－－ 86－


SFCa 20%

2.4-7

No. (%) (mPa s)

SFP SFCa 30

1 100 0 2 95 5 35.2 53.3 3 90 10 61.0 58.0 4 85 15 78.3 75.0 5 80 20 41.2 55.6 6 70 30 100.0 101.0

3 2.4-8

2 0% 2.4-22 2%

24 1%

2.4-8

No. (%) (%)

SFP SFCa 2 24

1 100 0 0.00 0.00 2 95 5 0.00 1.00 3 90 10 0.00 1.22 4 85 15 0.00 0.61 5 80 20 0.00 1.11

4 2.4-9 2.4-7 2.4-8

SFCa SFCa 20% 2.4-228 4MPa SFCa 30%

SFCa 30%

SFCa 20% 4MPa MPa

SFCa 20%

2.4-7

No. (%) (mPa s)

SFP SFCa 30

1 100 0 2 95 5 35.2 53.3 3 90 10 61.0 58.0 4 85 15 78.3 75.0 5 80 20 41.2 55.6 6 70 30 100.0 101.0

3 2.4-8

2 0% 2.4-22 2%

24 1%

2.4-8

No. (%) (%)

SFP SFCa 2 24

1 100 0 0.00 0.00 2 95 5 0.00 1.00 3 90 10 0.00 1.22 4 85 15 0.00 0.61 5 80 20 0.00 1.11

4 2.4-9 2.4-7 2.4-8

SFCa SFCa 20% 2.4-228 4MPa SFCa 30%

SFCa 30%

SFCa 20% 4MPa MPa

－87－－ 87－


2.4-9

No. (%) (MPa)

SFP SFCa 3 7 14 281 100 0 0.00 0.00 0.00 0.00 2 95 5 0.46 0.47 0.50 0.38 3 90 10 0.36 1.27 2.40 2.52 4 85 15 0.27 1.12 2.85 3.11 5 80 20 0.21 1.10 3.42 3.82 6 70 30 0.17 0.97 3.41 4.83

2.4-7 SFCa

2.4-8

5 pHpH 2.4-10SFCa 5 20% pH 10.2

0

1

2

3

4

5

6

0 5 10 15 20 25 30

(MP

a)

SFCa (wt%)

28

0

1

2

3

4

5

6

0 7 14 21 28

(MPa)

(day)

SFCa: 5%

SFCa: 10%

SFCa: 15%

SFCa: 20%

SFCa: 30%

2.4-9

No. (%) (MPa)

SFP SFCa 3 7 14 281 100 0 0.00 0.00 0.00 0.00 2 95 5 0.46 0.47 0.50 0.38 3 90 10 0.36 1.27 2.40 2.52 4 85 15 0.27 1.12 2.85 3.11 5 80 20 0.21 1.10 3.42 3.82 6 70 30 0.17 0.97 3.41 4.83

2.4-7 SFCa

2.4-8

5 pHpH 2.4-10SFCa 5 20% pH 10.2

0

1

2

3

4

5

6

0 5 10 15 20 25 30

(MP

a)

SFCa (wt%)

28

0

1

2

3

4

5

6

0 7 14 21 28

(MPa)

(day)

SFCa: 5%

SFCa: 10%

SFCa: 15%

SFCa: 20%

SFCa: 30%

－88－－ 88－


SFCa SFPC-S-H Ca/Si

2.4-10 pH

No. (%)

pHSFP SFCa

1 100 0 5.7 2 95 5 10.2 3 90 10 10.2 4 85 15 10.2 5 80 20 10.2

2.4.52008

1μmSP/B 1.5%

28 MPa2 0%

pH 11

SFCa SFPC-S-H Ca/Si

2.4-10 pH

No. (%)

pHSFP SFCa

1 100 0 5.7 2 95 5 10.2 3 90 10 10.2 4 85 15 10.2 5 80 20 10.2

2.4.52008

1μmSP/B 1.5%

28 MPa2 0%

pH 11

－89－－ 89－


3.

20072008

3

3.1

/ / / = 5/5/0/0 125% 5.5%

3.24 1

100 300mg/L 0.03 0.09%

3.3

3.

20072008

3

3.1

/ / / = 5/5/0/0 125% 5.5%

3.24 1

100 300mg/L 0.03 0.09%

3.3

－ 90－－ 90－


1) 20052) 2001 .3) Hansen, T-S., Roald, S., Nomeland, T. and Grant, B. (2003): Predictable and successful

rock injection – the first time around, A new improved system for cost-effective control of water in-leakage during tunnel excavation may reduce the need for expensive sandwich lining systems, ICGGE-2003.

4) 1993No.462/ -18, pp.101-110.

5) Emmelin, A., Brantberger, M., Eriksson, M., Gustafson, G. and Stille, H. (2007): Rock grouting, Current competence and development for the final repository, SKB, R-07-30.

6) 20092 64 CS5-002 pp.137-138

7) (2005)

8) (2002)JNC TJ8400 2002-013, pp.75-81

9) (2003) No.66 pp.63-70

10) (2006)

JAEA-Research 2006-040,59p 11) (2008)

, 63 CS05-32, pp.231-232 12) (2009)

3 64CS5-003 pp.139-140

13) Bodén A. Sievänen U. (2005): Low-pH injection grout for deep repositories. Summary report from a co-operation project between NUMO (Japan) Posiva (Finland) and SKB (Sweden) SKB R-05-40

14) Sievänen U. Syrjänen P. Ranta-aho S. (2005): Injection Grout for Deep Repositories. Low pH Cementitious Grout for Larger Fractures. Subproject 3 Field Testing in Finland Pilot Tests. Posiva Oy Working Report 2004-47

15) Penetrability Meter, R20 Programme(2008): Field Testing of Grouting Materials, Posiva, Working Report 2007-102

16) Raivio, P. and Hansen, J.(2007): Technical Performance of Grouting Materials for ONKALO, Laboratory Tests 2006, Posiva Working Report 2007-76

17) Finnish Tunnelling Association (2003): Hard Rock Tunnel Grouting in Finland, Sweden, and Norway – Literature Study.

1) 20052) 2001 .3) Hansen, T-S., Roald, S., Nomeland, T. and Grant, B. (2003): Predictable and successful

rock injection – the first time around, A new improved system for cost-effective control of water in-leakage during tunnel excavation may reduce the need for expensive sandwich lining systems, ICGGE-2003.

4) 1993No.462/ -18, pp.101-110.

5) Emmelin, A., Brantberger, M., Eriksson, M., Gustafson, G. and Stille, H. (2007): Rock grouting, Current competence and development for the final repository, SKB, R-07-30.

6) 20092 64 CS5-002 pp.137-138

7) (2005)

8) (2002)JNC TJ8400 2002-013, pp.75-81

9) (2003) No.66 pp.63-70

10) (2006)

JAEA-Research 2006-040,59p 11) (2008)

, 63 CS05-32, pp.231-232 12) (2009)

3 64CS5-003 pp.139-140

13) Bodén A. Sievänen U. (2005): Low-pH injection grout for deep repositories. Summary report from a co-operation project between NUMO (Japan) Posiva (Finland) and SKB (Sweden) SKB R-05-40

14) Sievänen U. Syrjänen P. Ranta-aho S. (2005): Injection Grout for Deep Repositories. Low pH Cementitious Grout for Larger Fractures. Subproject 3 Field Testing in Finland Pilot Tests. Posiva Oy Working Report 2004-47

15) Penetrability Meter, R20 Programme(2008): Field Testing of Grouting Materials, Posiva, Working Report 2007-102

16) Raivio, P. and Hansen, J.(2007): Technical Performance of Grouting Materials for ONKALO, Laboratory Tests 2006, Posiva Working Report 2007-76

17) Finnish Tunnelling Association (2003): Hard Rock Tunnel Grouting in Finland, Sweden, and Norway – Literature Study.

－ 91－－ 91－


18) (2008)Vol.43, 2 1, pp.677-678

19) (1996)51

20) GLO-85 (1985): Finnish Geotechnical Society 21) Arenius, M., Hansen, J., Juhola, P., Karttunen, P., Koskinen, K., Lehtinen, A., Lyytinen,

T., Mattila, J., Partamies, S., Pitkänen, P., Raivio, P., Sievänen, U., Vuorinen, U. and Vuorio, M. (2008): R20 Summary Report: The Groundwater Inflow Management in ONKALO, the Future Strategy, POSIVA Working Report 2008-44

22) (2009) 564 CS5-005

pp.143-144 23) (1997)

18) (2008)Vol.43, 2 1, pp.677-678

19) (1996)51

20) GLO-85 (1985): Finnish Geotechnical Society 21) Arenius, M., Hansen, J., Juhola, P., Karttunen, P., Koskinen, K., Lehtinen, A., Lyytinen,

T., Mattila, J., Partamies, S., Pitkänen, P., Raivio, P., Sievänen, U., Vuorinen, U. and Vuorio, M. (2008): R20 Summary Report: The Groundwater Inflow Management in ONKALO, the Future Strategy, POSIVA Working Report 2008-44

22) (2009) 564 CS5-005

pp.143-144 23) (1997)

This is a blank page.

Documents

JAEA-Data/Code 2010-005jolissrch-inter.tokai-sc.jaea.go.jp/pdfdata/JAEA-Data... · 2013. 2. 25. · ii ii JAEA-Data/Code 2010-005 Development of Grout Materials for a Geological Disposal