JDF6/16/2015XRoofing Submittals€¦ · · 2015-06-16PVA Section SDS 07554 SBS Modified ... Celvol® Polyvinyl alcohol, copolymer ... 528 PV ALCOHOL; 530 PV ALCOHOL; 540 PV ALCOHOL;

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6/16/2015

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Roofing Submittals

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Atlas Apex Roofing, Inc.

1065

PROJECT: Uptown of Delray 190 S. E.

5th Ave., Delray Beach, FL DATE

6-15-15

Architect: Slatter & Associates

2060 NW Boca Raton Blvd. Suite 2, Boca Raton, FL

CONTRACTOR: LandSouth Construction

1680 The Greens Way, Suite 100

Jacksonville Bch, FL

Spec.

SectionTitle/Description Date Sent ACTION

Date

ReturnedComments

035216 Lightweight Insulating Concrete

Lightweight System

PVA

Section SDS

07554 SBS Modified Bituminous Membrane

Base Sheet Modified Sopra G

Mid-Ply (Sopralene Flam 180)

Cap Sheet (Soprema Sopralene Flam 180 FR GR)

Base Sheet Fasteners 1.75

Section SDS

07620 Metal Flashings

Aluminum

Section SDS

07700 Roof Accessories

Galvanized G90

Uplift Engineering Calculations

Project Number:

SUBMITTAL RECORD

Submittal

No.

Action Code

(checklist / log)

APP - Approved A/C - Approved with Comments

R/R - Revise and Re-submit REJ - Not Approved

Revised Jan02 Page 1 of 1 Printed 6/15/2015

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Section 3. HAZARDS IDENTIFICATION

Potential Health Effects

InhalationVapors are minimal at room temperature. If product is heated or sprayed as an aerosol, airbornematerial may cause respiratory irritation.

Skin ContactContact with liquid may cause moderate irritation or dermatitis due toremoval of oils from theskin.

Eye ContactProduct is an eye irritant.

Ingestion

Not a hazard in normal industrial use. Small amounts swallowed during normal handlingoperations are not likely to cause injury; swallowing large amounts may cause injury or irritation

Additional Health Effects

Existing eye or skin sensitivity may be aggravated by exposure.

Carcinogenicity Information

No data available.

Section 4. FIRST AID MEASURES

InhalationNo specific treatment is necessary since this material is not likely to be hazardous by inhalation.If exposed to excessive levels of airborne mists, remove to fresh air. Seek medical attention ifeffects occur.

Skin ContactIn case of skin contact, immediately flush skin with copious amounts of water for at least 15minutes. Launder clothing before re-use. If irritation occurs, obtain medical attention.

Eye ContactIn case of eye contact, immediately flush eyes with copious amountsof water for 15 minutes.Retract eyelids often to ensure thorough rinsing. Contact a physician if irritation persists.

IngestionIf swallowed, give victim plenty of milk or water to drink. Do not induce vomiting. Neveradminister anything by mouth to an unconscious person. Seek medical attention.

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Section 5. FIRE FIGHTING MEASURES

Flammable PropertiesFlash Point – Not applicable

Fire and Explosion HazardsNot Applicable

Extinguishing MediaNot Applicable.

Special Fire Fighting InstructionsNot Applicable.

Section 6. ACCIDENTAL RELEASE MEASURES

Safeguards (Personnel)NOTE: Use appropriate Personal Protective Equipment during clean-up.

Accidental Release Measures

ConcentrateStop flow if possible. Use appropriate protective equipment during clean up. For small volumereleases, collect spilled concentrate with absorbent material; place in approved container. Forlarge volume releases, contain and collect for use where possible.Flush area with water until itno longer foams. Exercise caution, surfaces may be slippery. Prevent discharge of concentrate towaterways. Disposal should be made in accordance with federal, state and local regulations.

Foam/Foam Solution

See above. Flush with water. Prevent discharge of foam/foam solution to waterways. Do notdischarge into biological sewer treatment systems without prior approval. Disposal should bemade in accordance with federal, state and local regulations.

Section 7. HANDLING AND STORAGE

Handling (Personnel)Avoid contact with eyes, skin or clothing. Avoid ingestion or inhalation. Rinse skin and eyesthoroughly in case of contact. Review HAZARDS and FIRST AID sections.

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StorageRecommended storage environment is between 35°F (2°C) and 120°F(49°C). Store product inoriginal shipping container or tanks designed for product storage.

Section 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering ControlsSpecial ventilation is not required.

Personal Protective Equipment

RespiratoryRecommended exposure limits (OSHA-PEL and ACGIH-TLV) have not been determined forthis material. A qualified health specialist should evaluate the need for respiratory protection.

Protective ClothingRubber or PVC gloves recommended.

Eye ProtectionSafety glasses, face shield or chemical splash goggles must be worn when possibility exists foreye contact. Contact lenses should not be worn. Eye wash facilitiesare recommended.

Other Hygienic PracticesUse good personal hygiene practices. Wash hands before eating, drinking, smoking, or usingtoilet facilities. Promptly remove soiled clothing and wash thoroughly before re-use.

Exposure Guidelines

Exposure Limits

Component CAS Number PEL (OSHA) TLV(ACGIH)

Ferrous Sulfate 7720-78-7 1.0 mg/m3 1.0 mg/m3

Ethylene Glycol 107-21-1 50 ppm 50 ppm

Hexylene Glycol 107-41-5 25 ppm 25 ppm

Zinc Chloride 7646-85-7 1.0 mg/m3 1.0 mg/m3

Ferrous Chloride 7758-94-3 1.0 mg/m3 1.0 mg/m3

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Section 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical Data

Boiling Point: Not applicable

Vapor Pressure: Not applicable

Vapor Density: Not applicable

Melting Point: Not applicable

Evaporation Rate: <1 (Butyl Acetate = 1.0)

Solubility in Water: 100%

pH: 7.2

Specific Gravity: 1.162 @ 15°C

Odor: Organic

Form: Liquid

Color: Dark Brown

Section 10. STABILITY AND REACTIVITY

Chemical StabilityStable.

Incompatibility, Materials to AvoidAvoid use of product on burning metals, electrically energized equipment and contact withwater- reactive materials.

PolymerizationWill not occur.

Section 11. TOXICOLOGICAL INFORMATION

This product has not been tested as a whole for acute oral and inhalation toxicity, primary eyeirritation, or primary skin irritation.

Section 12. ECOLOGICAL INFORMATION

Ecotoxicological Information

Aquatic Toxicity

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No data available.

Environmental Fate

BOD5 No data available

COD No data available

Section 13. DISPOSAL CONSIDERATIONS

Do not discharge into biological sewer treatment systems without priorapproval. Specificconcerns may be high BOD load and foaming tendency. Dilution will reduce BOD and CODfactors proportionately. Low dosage flow rate or antifoaming agents acceptable to the treatmentplant may be helpful. Do not flush to waterways. Disposal should be made in accordance withfederal, state and local regulations.

Section 14. TRANSPORTATION INFORMATION

Shipping InformationProper Shipping Name: Fire Extinguisher Charges or Compounds N.O.I., Class 70National Motor Freight Code: 69160 Sub 0Hazard Class: NoneUN Number: None

Section 15. REGULATORY INFORMATION

U.S. Federal Regulations

Toxic Substances Control Act (TSCA)All components of this product are listed in the TSCA inventory.

Superfund Amendments and Reauthorization Act of 1986 (SARA), Title III

Section 302/304There are no components of this material with known CAS numbers that are on theExtremely Hazardous Substances (EHS) list.

Section 311 & 312There are no components of this material with known CAS numbers that are classified ashealth and/or physical hazards according to Section 311 & 312.

Ferrous Chloride (7758-94-3)

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Section 313Based on available information, this material contains the followingcomponents subjectto the reporting requirements of Section 313.

Ferrous Sulfate 7720-78-7 less than 2% by weight

Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA)Based on available information, this material contains the followingcomponents subject to thereporting requirements of CERCLA.

Ferrous Sulfate 7720-78-7 less than 2% by weight

Ferrous Chloride 7758-94-3 less than 3% by weight

OTHER REGULATORY INFORMATIONCanadian Environmental Protection Act (CEPA)

All ingredients are listed on the Domestic Substance List (DSL).

STATE REGULATIONS

PENNSYLVANIA RIGHT-TO-KNOW HAZARDOUS SUBSTANCES LIST

PA Hazardous Substances present at levels greater than 1%:

Ferrous Sulfate 7720-78-7Ferrous Chloride 7758-94-3

Section 16. OTHER INFORMATION

NFPA Rating WHMIS Rating

Health 0 D2BFlammability 0Reactivity 0

ADDITIONAL INFORMATION

Revision Summary

8-12-10 Temporary Issue

The information contained herein is furnished without warranty either expressed orimplied. This data sheet is not a part of any contract of sale. The information containedherein is believed to be correct or is obtained from sources believed to be generally reliable.However, it is the responsibility of the user of these materials to investigate, understand

Page 8 of 8 8/12/2010

and comply with federal, state and local guidelines and procedures for safe handling anduse of these materials. National Foam, Inc. shall not be liable for any loss or damage arisingdirectly or indirectly from the use of this product and National Foam, Inc. assumes noobligation or liabilities for reliance on the information contained herein or omissionsherefrom.

November 13, 2008

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Product name

Revision Date Nov.07.2005

Celvol® Polyvinyl alcohol, copolymer

Revision Number 0.03

Material Safety Data Sheet

Issuing date Aug.22.2006***

NA/EN

MSDS number 80524

1. Product and company identification

Transportation emergency phone numbers:In USA, call 800 424 9300 Outside USA, call 703 527 3887, collect calls accepted

End use:Chemical intermediate (including monomers), Auxiliary for leather, Auxiliary for textil, packaging, Surfactant, Adhesives industry, Food industry 2. Hazards identification Emergency Overview

CAUTION!May cause eye irritation.Dust from this product can form an explosive organic dust cloud. Product Description Appearance Form Powder Odour odourless Colour white Potential health effects Routes of exposureSkin, eyes, inhalation, ingestion. Immediate effects Inhalation

May cause respiratory tract irritation Symptoms of exposure may include: Nasal discharge, hoarseness, coughing, chest pain and breathing difficulty

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Manufacturer, importer, supplierCelanese Ltd. 1601 W. LBJ Freeway P.O. Box 819005 Dallas, TX 75381-9005 United States Phone: 972 443 4000 Internet: www.celanese.com

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Product name






NA/EN

MSDS number 80524

SkinEssentially non-irritating.

Eyes

May cause eye irritation Symptoms of exposure may include: Eye irritation or burning sensation. Ingestion

Essentially non-toxic based on components. Symptoms of exposure may include: Inflammation of mouth, throat, esophagus and/or stomach.

Target organ effectsOverexposure (prolonged or repeated exposure) may cause: Irritation of the respiratory tract Irritation of the digestive tract Local irritation at the site of exposure

Medical conditions which may be aggravated by exposure: Significant exposure to this chemical may adversely affect people with acute or chronic disease of the: Respiratory Tract Eyes Digestive tract

3. Composition/information on ingredients Components CAS-No Percent % Acetic acid ethenyl ester, polymer with ethenol 25213-24-5 92 - 95

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in vitro Mutagenicity Ames test - negative

in vivo MutagenicityMouse micronucleus - negative

Acetic acid ethenyl ester, polymer with ethenol Carcinogenic effects

No evidence of carcinogenicity respiratory tract epithelium

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Product name






NA/EN

MSDS number 80524

The following specific grades of Celvol are covered by this MSDS:

203 PV ALCOHOL; 203S PV ALCOHOL;205 PV ALCOHOL; 205S PV ALCOHOL; 403 PV ALCOHOL; 418 PV ALCOHOL; 425 PV ALCOHOL; 423 PV ALCOHOL; 430 PV ALCOHOL; 443 PV ALCOHOL; 502 PV ALCOHOL; 502S PV ALCOHOL; 504 PV ALCOHOL; 508 PV ALCOHOL; 508S PV ALCOHOL; 513 PV ALCOHOL; 513S PV ALCOHOL; 518 PV ALCOHOL; 523 PV ALCOHOL; 523S PV ALCOHOL; 528 PV ALCOHOL; 530 PV ALCOHOL; 540 PV ALCOHOL; 540S PV ALCOHOL; 540TV PV ALCOHOL; 603 PV ALCOHOL; 6107 PV ALCOHOL; 640 PV ALCOHOL; 640S PV ALCOHOL; 704 PV ALCOHOL; 711 PV ALCOHOL; 804 PV ALCOHOL; 805 PV ALCOHOL; 818 PV ALCOHOL; 823 PV ALCOHOL; 830 PV ALCOHOL; 831 PV ALCOHOL; 840 PV ALCOHOL; 50-42NS PV ALCOHOL; 50-42N PV ALCOHOL; 51-05N PV ALCOHOL; WS-53NF PV ALCOHOL; WS-724 PV ALCOHOL

Specific technical information on a Celvol grade should be obtained from the sales specification sheet available at www.celvol.com*** 4. First aid measures General InformationWash contaminated clothing before re-use. Inhalation Move to fresh air in case of accidental inhalation of vapours. If symptoms persist, call a physician. Skin Wash off immediately with plenty of water for at least 15 minutes. If symptoms persist, call a physician. Eyes Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Immediate medical attention is required. Ingestion If swallowed, seek medical advice immediately and show this container or label. Do not induce vomiting without medical advice. Call a physician immediately. 5. Fire-fighting measures

Suitable extinguishing mediaalcohol-resistant foam, carbon dioxide (CO2), Dry chemical Extinguishing media which must not be used for safety reasonsDo not use a solid water stream as it may scatter and spread fire. Special exposure hazards arising from the substance or preparation itself, its combustion products, or released gasesUnder conditions giving incomplete combustion, hazardous gases produced may consist of carbon monoxide carbon dioxide (CO2) Combustion gases of organic materials must in principle be graded as inhalation poisons

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Flammability: 1 Instability: 0NFPA: Health: 1

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NA/EN

MSDS number 80524

Special protective equipment for firefightersflame retardant protective clothing. Self-contained breathing apparatus. Other InformationCool containers / tanks with water spray. Thoroughly decontaminate bunker gear and other fire-fighting equipment before re-use. 6. Accidental release measures Personal precautionsAvoid contact with the skin and the eyes. Do not breathe dust. Forms slippery surfaces with water. Keep unnecessary people away; isolate hazard area and deny entry. Environmental precautionsPrevent further leakage or spillage. Do not discharge into the drains/surface waters/groundwater. Methods for cleaning UpShovel or sweep up. Keep in suitable, closed containers for disposal. Dispose of in accordance with local regulations. Avoid dust formation. 7. Handling and storage Handling Advice on safe handling

Ensure adequate ventilation. Keep containers tightly closed in a dry, cool and well-ventilated place. Avoid dust formation.

Protection - fire and explosion:

The powder can explode if mixed in air and ignited in a confined space. If unconfined, ignition will give rise to a Class A fire. Care should be taken to prevent the accumulation of dust. Dust is an explosion hazard. However, the explosive hazard is highly dependent on particle size; the finer the particles, the higher the explosion strength. Emptying of bags of powder directly into vessels where flammable vapors exist should be strictly prohibited because static discharges can be generated of sufficient strength to produce an explosion.

Storage Technical measures/Storage conditions

Keep container tightly closed in a dry and well-ventilated place. Material storage

Store at room temperature in the original container. Keep away from reactive metals (sodium, zinc, copper, calcium, etc.).

Incompatible products

Keep away from:concentrated peroxidesperchloratesstrong oxidizing agents

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NA/EN

MSDS number 80524

8. Exposure controls / personal protection OSHA Exposure Limits Components TWARespirable Dust 5 mg/m³Total Dust 15 mg/m³ ACGIH Exposure Limits

Components TWARespirable Dust 3 mg/m³Total Dust 10 mg/m³ Exposure controls Engineering measuresGeneral or dilution ventilation is frequently insufficient as the sole means of controlling employee exposure. Local ventilation is usually preferred Protective EquipmentA safety shower and eyebath should be readily available. General advice Avoid contact with skin and eyes. Do not breathe dust. Use only in an area equipped with a safety shower. Hold eye wash fountain available.

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NA/EN

MSDS number 80524

Respiratory protectionBased on workplace contaminant level and working limits of the respirator, use a respirator approved by NIOSH. The following is the minimum recommended equipment for an occupational exposure level. To estimate an occupational exposure level see Section 8 and Section 11.

For concentrations > 1 and < 10 times the occupational exposure level: Use air-purifying respirator with full facepiece and organic vapor cartridge(s) or air-purifying full facepiece respirator with an organic vapor canister or a full facepiece powered air-purifying respirator fitted with organic vapor cartridge(s). The air purifying element must have an end of service life indicator, or a documented change out schedule must be established. Otherwise, use supplied air.

For concentrations more than 10 times the occupational exposure level and less than the lower of either 100 times the occupational exposure level or the IDLH: Use Type C full facepiece supplied-air respirator operated in positive-pressure or continuous-flow mode.

For concentrations > 100 times the occupational exposure level or greater than the IDLH level or unknown concentrations (such as in emergencies): Use self-contained breathing apparatus with full facepiece in positive-pressure mode or Type C positive-pressure full facepiece supplied-air respirator with an auxiliary positive-pressure self-contained breathing apparatus escape system.

For escape: Use self-contained breathing apparatus with full facepiece or any respirator specifically approved for escape. Skin protection:Wear impervious clothing and gloves to prevent contact. Neoprene is recommended. Other protective material may be used, depending on the situation, if adequate degradation and permeation data is available. If other chemicals are used in conjunction with this chemical, material selection should be based on protection for all chemicals present Eye/face protection:Wear chemical goggles when there is a reasonable chance of eye contact. 9. Physical and chemical properties Appearance Form Powder Colour white Odour odourlessMelting point/range 230°C -240°C Bulk density 0.61-0.67 g/cm³ @20 °CpH NeutralWater solubility hot water 10. Stability and reactivity StabilityStable

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NA/EN

MSDS number 80524

Conditions to avoidAvoid dust formation Materials to avoid Keep away from:, oxygen, peroxides, perchlorates, nitrates, oxidizing agents, Keep away from reactive metals (sodium, zinc, copper, calcium, etc.) Hazardous Combustion or Decomposition Products:Thermal decomposition products may include oxides of carbon. Hazardous reactionsHazardous polymerisation does not occur 11. Toxicological information

12. Ecological information

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Carcinogenic effects No evidence of carcinogenicity respiratory tract epithelium

Inhalation

Study inhalation study (28 months)

LC50: > 20 mg/m³, rat, 1h

in vitro Mutagenicity Ames test - negative in vivo Mutagenicity Mouse micronucleus - negative

Skin irritation No skin irritation Species rabbit

Acetic acid ethenyl ester, polymer with ethenol Toxicity to fish LC50: 10 mg/l (96h)

Skin Sensitization

Species Lepomis macrochirus (Bluegill sunfish)

nonsensitizer

LC50: 40 mg/l (96h)

Acetic acid ethenyl ester, polymer with ethenol

Species Pimephales promelas (Fathead minnow)

Species guinea pig

Toxicity to daphnia EC50: 8.3 mg/l (48h) EC50: 8.3 mg/l (96h) Species Daphnia magna

Toxicity to bacteria EC50: 50 mg/l (17h)

Method Maximization

Method DIN 38412 T.8

Biodegradation 90 %

Eye Irritation

Method OECD 302 B (Zahn-Wellens Test)

Mild eye irritation

Oral LD50: > 5000 mg/kg, rat

Species rabbit eye

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NA/EN

MSDS number 80524

13. Disposal considerations Disposal Considerations:Dispose of spilled material in accordance with state and local regulations for waste that is non-hazardous by Federal definition. Note that this information applies to the material as manufactured; processing, use, or contamination may make this information inappropriate, inaccurate, or incomplete.

Note that this handling and disposal information may also apply to empty containers, liners and rinsate. State or local regulations or restrictions are complex and may differ from federal regulations. This information is intended as an aid to proper handling and disposal; the final responsibility for handling and disposal is with the owner of the waste. 14. Transport information US Department of Transportation Not regulated TDG Not regulated ICAO/IATA Not restricted IMDG Not regulated 15. Regulatory information U.S. STATE REGULATIONSChemicals associated with the product which are subject to the state right-to-know regulations are listed along with the applicable state(s):none U.S. FEDERAL REGULATIONS TSCA Inventory:We certify that all components are either on the TSCA inventory or qualify for an exemption.dummy header Environmental Regulations: SARA 311: Acute health: Yes Chronic health: No

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Chemical Oxygen Demand 1640 mg/l

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NA/EN

MSDS number 80524

Fire: No Sudden release of pressure: No Reactive: No INTERNATIONAL REGULATIONS International Chemical InventoryListed on the chemical inventories of the following countries or qualifies for an exemption:AUSTRALIA,CHINA,CANADA,EUROPE,KOREA,PHILIPPINES, JAPAN

16. Other information Prepared ByProduct Stewardship Department Celanese

For more information, other material safety data sheets or technical data sheets please consult the Celanese homepage (www.celanese.com) Sources of key data used to compile the datasheetInformation contained in this safety data sheet is based on Celanese owned data and public sources deemed valid or acceptable. The absence of data elements required by ANSI or 2001/58/EC indicates, that no data meeting these requirements is available. Changes against the previous version are marked by *** For industrial use only. The information contained herein is accurate to the best of our knowledge. We do not suggest or guarantee that any hazards listed herein are the only ones which exist. Celanese makes no warranty of any kind, express or implied, concerning the safe use of this material in your process or in combination with other substances. Effects can be aggravated by other materials and/or this material may aggravate or add to the effects of other materials. This material may be released from gas, liquid, or solid materials made directly or indirectly from it. User has the sole responsibility to determine the suitability of the materials for any use and the manner of use contemplated. User must meet all applicable safety and health standards. Material safety data sheets are provided on the Internet by Celanese as a service to its customers. Possession of an Internet MSDS does not indicate that the possessor of the MSDS was a purchaser or user of the subject product.

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Health: 1 Flammability: 1 Physical hazard: 0

NFPA: Health: 1 Flammability: 1 Instability: 0

HMIS:

MODIFIED SOPRA-GMODIFIED SOPRA-G (03) Order No. 00107*

*Contact Customer Service for additional order numbers.

310 QUADRAL DRIVE • WADSWORTH, OHIO 44281 • TEL.: (330) 334-0066 • TOLL FREE: (800) 356-3521 • FAX: (330) 334-4289General product information is provided on this Product Data Sheet. The physical property values reported here are based on testing conducted under controlled laboratory conditions according to accepted test standards.

PRODUCT DATA SHEET PDS-101 Rev 05/11

COMPOSITION, PACkAGING & PROPERTIES

Modified Sopra G (modified with SBS) is a ASTM 4601, Type II and G2 fiberglass base sheets. The Modified Sopra G base sheet is used as an anchor sheet for hot mopped, cold adhesive or heat welded roof assemblies. This base sheet is suitable for use to form BUR roof assemblies or is used in combination with SBS membranes when they are completely adhered either by hot mopping or cold adhesive. The Modified Sopra-G sheet may be used as an anchor sheet for waterproofing assemblies or as a seperation sheet over approved Colphene H waterproofing systems. See published Specifications and Approved Details.

DESCRIPTION

WARRANTYContact your local SOPREMA representative for project warranty offerings.

APPROvAlSSee Underwriters Laboratories Inc. File #R11436, FM Approvals, ICC/ES, Miami-Dade County or Florida Building Code Product Approval Listings for current Approved Roof Assembly combinations. Soprema is ISO-9001:2000.

Product/Properties per ASTM D 4601-04

Modified Sopra-G

Net Dry Mass (lb. 100 ft2) 28.4Moisture (% max @ time of mfg.) <1Mass of desaturated glass mat (lb. 100 ft2) 1.70Asphalt (min. lb./100 ft2) 10Parting agent & stabilizer (max. lb./100 ft2) NALoad strain properties @ 77° F (25° C) Breaking Strength

60 MD 44 XD

Pliability (½ in. radius failures) No Cracking

Minimum values before and after Heat Conditioning. Test results for manufacturing plant in Wadsworth, OH7/24/03

Product/Property Modified Sopra-GReinforcement FiberglassBitumen SBS ModifiedTopside SandedUnderside SandedApprox. Nominal Thickness 1.2 mm (48 mils)Approximate Roll Coverage 28 m2 (300 ft2)Side Lap 76 mm (3”)End Lap 152 mm (6”)Roll Length 33 m (108’)Roll Width 0.9 m (3’)Approximate Roll Weight 41.7 kg (92 lbs.)Rolls per Pallet* 20*Rolls stocked upright on pallet

SOPRALENE FLAM 180SOPRALENE FLAM 180 (32) Order No. 00410

Sopralene Flam 180 base ply is composed of selected SBS modified bitumen applied onto a non-woven polyester reinforcement with a film on both the underside and topside surfaces.

The Sopralene field and flashing base membrane plies is adhered to a properly prepared, clean, dry and/or primed (where required) substrate by using the heat welding application method. Optional inner ply(s) or the field cap membrane ply is bonded to the properly prepared, clean, dry and/or primed (where required) Sopralene Flam 180 top surface with the heat welding application method.

Sopralene Flam 180 may also be used as a base and/or innerply ply membrane and also as a flashing base ply or inner ply membrane in approved waterproofing assemblies.

See published Specifications and Approved Details.

DESCRIPTION & APPLICATION



COMPOSITION & PACKAGING

Product/Property

SOPRALENE FLAM 180

Reinforcement polyesterElastomeric Bitumen selected blend of bitumen and SBS thermoplastic polymersTopside filmUnderside filmApproximate Nominal Thickness 120 mils (3.0 mm)Approximate Roll Coverage 97.5 ft² (9.1m²)Side Lap 3” (76 mm)End Lap 6” (152 mm)Roll Length 33 ft (10 m)Roll Width 39” (1 m)Approximate Roll Weight 81 lbs (37 kg)Rolls per Pallet* 30* Rolls stocked upright on pallets

WARRANTY

Contact your local SOPREMA representative for project warranty offerings.


SOPRALENE FLAM 180PAGE 2

Physical Property per ASTM D 6164, Type I, Grade S

MD XD

Tensile - Max Load at 0 ± 3.6°F lbf/in 117 83Elongation at 0 ± 3.6°F % 29 22Tensile - Max Load at 73.4 ± 3.6°F lbf/in 70 70Elongation at 73.4 ± 3.6°F % 56 61Tear Strength at 73.4 ± 3.6°F lbf 120 87Low Temperature Flex °F max -15 -15Dimensional Stability % max <0.5 <0.5Compound Stability Temp F 250 250Granule Embedment g/max NA NA

Minimum values before and after Heat ConditioningTest results for manufacturing plant in Wadsworth, OH

PHYSICAL PROPERTIES

SOPREMA is a Certified ISO 9001:2000 worldwide producer of bituminous membranes with factories in Europe and North America. Waterproofing sheets have been produced by SOPREMA since 1908. Today, through a special mixture of components, SOPREMA membranes redefine the qualities indispensable to a high performance roof membrane: elasticity, flexibility, heat & fatigue resistance.

SOPREMA SBS modified bitumen membrane assemblies typically consist of base and top ply membranes that have specific type reinforcements in order to meet specific ASTM Standards. The two ply system provides a resistance to punctures and tears, as well as ensuring an effective distribution of stress points. The two ply system operates in a homogeneous fashion. The bitumen in each layer moves uniformly to offer continuous protection.

GENERAL

APPROvALS

See Underwriters Laboratories Inc. File #R11436, FM Approvals, ICC/ES, Miami-Dade County or Florida Building Code Product Approval Listings for current Approved Roof Assembly combinations. Soprema is ISO-9001:2000 Certified.

PDS-357 Rev 07/10

SOPRALENE 180 FR GRSOPRALENE 180 FR GR (44) Order No. 01366**Cap sheet order numbers are for WHITE CAP SHEETS ONLY. Contact Customer Service or your Sales Representative for other available cap sheet colors and special order requirements.



Sopralene 180 FR GR cap ply is composed of selected SBS modified bitumen applied onto a non-woven polyester reinforcement with sand on the underside and a colored granule topside surface.

The Sopralene 180 FR GR field and flashing cap membrane ply is adhered to a properly prepared, clean, dry and/or primed (where required) base or ply membrane by using the hot asphalt or cold adhesive application methods. See published Specifications and Approved Details.

DESCRIPTION & APPLICATION

COMPOSITION & PACKAGING

Product/Property

SOPRALENE 180 FR GR

Reinforcement polyesterElastomeric Bitumen selected blend of bitumen and SBS thermoplastic polymersTopside colored granulesUnderside sandedApproximate Nominal Thickness 160 mils (4.0 mm)Approximate Roll Coverage 97.5 ft² (9.1 m²)Side Lap 3” (76 mm)End Lap 6” (152 mm)Roll Length 33 ft (10 m)Roll Width 39” (1 m)Approximate Roll Weight 113 lbs (51.3 kg)Rolls per Pallet* 25* Rolls stocked upright on pallets

WARRANTYContact your local SOPREMA representative for project warranty offerings.

APPROvALSSee Underwriters Laboratories Inc. File #R11436, FM Approvals, ICC/ES, Miami-Dade County or Florida Building Code Product Approval Listings for current Approved Roof Assembly combinations. Soprema is ISO-9001:2008 Certified.


SOPRALENE 180 FR GRPAGE 2

Physical Property per ASTM D 6164, Type I, Grade G

MD XD

Tensile - Max Load at 0 ± 3.6°F lbf/in 117 83Elongation at 0 ± 3.6°F % 29 22Tensile - Max Load at 73.4 ± 3.6°F lbf/in 70 70Elongation at 73.4 ± 3.6°F % 56 61Tear Strength at 73.4 ± 3.6°F lbf 120 87Low Temperature Flex °F max -15 -15Dimensional Stability % max <0.5 <0.5Compound Stability Temp F 230 230Granule Embedment g/max 0.8 0.8

Minimum values before and after Heat ConditioningTest results for manufacturing plant in Wadsworth, OH

PHYSICAL PROPERTIES

PDS-376 Rev 03/13

PRODUCTSOLAR REFLECTANCE(1) THERMAL EMITTANCE(2) SRI(3)

INITIAL 3 YEAR INITIAL 3 YEAR INITIAL 3 YEARSOPRALENE 180 FR GR (WH)[Standard white granules]*

0.27 0.24 0.87 0.90 27 24

SOPRALENE 180 FR GR (SG)[Highly reflective white granules]**

0.70 PENDING 0.89 PENDING 86 PENDING

* CRRC Rated Product ID Number: 0772-0005** CRRC Rated Product ID Number: 0772-0049 Initial reporting, results pending

(1) ASTM C1549(2) ASTM C1371(3) ASTM E1980

Sopralene 180 FR GR includes the standard white granules. Contact Soprema Customer Service or your Sales Representative for other available granule color options and special order requirements.

Sopralene 180 FR GR (WH) white granules: Order No. 01366Sopralene 180 FR GR (SG) highly reflective white granules: Order No. 01305

SURFACE CHARACTERISTICS

MADE IN USAFASTENERS ADHES IVES DRAINS P IPE SUPPORTS

KEY:

S Steel

W Wood

G Gypsum

P Purlins

SC Structural Concrete

LC Lightweight Concrete

LWIC Lightweight Insulating Concrete

CWF Cementitious Wood Fiber

CR-Base Sheet Fastener

PRODUCT DESCRIPTIONThe OMG Assembled CR-Base Sheet Fasteners are one-piece, precision formed from G-90 galvanized steel, coated with CR-10 and assembled with a 2.75-in. diameter Galvalume® plate. These fasteners are designed to secure base sheets to poured lightweight insulating concrete or various gypsums*.

The OMG Assembled CR-Base Sheet Fastener is Factory Mutual and Miami-Dade County approved and is installed with an OMG MultiPogo Stick or wooden mallet.

*Caution: Only the CR 1.2 Base Sheet Fastener can be installed in some gypsum decks. A pull test is required to determine suitability.

FEATURES & BENEFITSOMG Assembled CR-Base Sheet •Fasteners are F.M. and Miami-Dade County approved.

Assembled fasteners greatly reduce •installation time and labor cost.

CR-Base Sheet Fasteners are packaged •for easy handling on the roof.

Entire fastener “legs” are CR-10 coated •to prevent in-place corrosion.

COATINgOMG CR-10 corrosion resistant coating exceeds F.M. Approval Standard 4470.

APPLICATIONSurfaces must be surface dry and reason-ably smooth prior to roofing. For best performance, the fastener should always be installed perpendicular to the substrate.

CR 1.2 BSF – Are designed for use on minimum 1.25-in. thick poured lightweight insulating concreted and some gypsum decks. A pull test is required to determine suitability.

CR (1.75) BSF – Are designed for use on minimum 2-in. thick poured lightweight insulating concreted decks only. Not to be used on poured gypsum decks.

OMG Assembled CR-Base Sheet Fasteners are FM approved and rated to 1-150 with certain fastener, base sheet and insulating concrete combinations. Consult the roofing system manufacturer for specific wind ratings.

Note: Prior to job start, contact roof cover manufacturer to determine the correct fastening pattern. On re-roofing applications, prior to job start, roof should be inspected and pull tests should be completed to determine the pullout values.

ACCESSORIESUse an OMG MultiPogo Stick to install the fastener. See Accessories section.

APPROvALS

PHYSICAL DATAThe data below is constant for each OMG CR-Base Sheet Fastener.

HEAD lEgS

1.125" x 1" 1.2 " 1.75"

MATERIAl PlATE

g-90 galvanized CR-10 Coated Fastener

.014" (nominal) Thickness

2.75" Diameter galvalume

ORDERINg INFORMATION

CAT. NO. lENgTH PKg WEIgHT

CRBSA134 1.75" 500 21 lbs.

CRBSA120 1.20" 1000 37 lbs.

MUlTIPOgO 39.5" 1 25 lbs.

RP09

123W

USE WITH

LWICGDECK

TYPES

P R O D U C T D A T A S P E C I F I C A T I O N S

*

P R O D U C T D A T A S P E C I F I C A T I O N S

153 BOwlES ROAD , AgAwAm, mA 01001800 .633 .3800 www.OlyFAST. cOm INFO @OlyFAST. cOmCopyright © 2009 OMG, Inc. All rights reserved.

SPECIFICATIONThe fastener will be an OMG Assembled CR-Base Sheet Fastener (or CR 1.2 Base Sheet Fastener). The fastener comes assembled with a 2.75-in. diameter Galvalume plate. The fastener head and legs must be CR-10 coated. The fastener must be Factory Mutual approved and made in America.

COATINg REqUIREMENTThe fastener will be coated with the OMG CR-10 corrosion resistant coating. Fastener must meet Factory Mutual Approval Standard 4470. The plate must be Galvalume® and also meet Factory Mutual Approval Standard 4470.

APPLICATIONOMG 1.75 CR-Base Sheet Fastener will be embedded into a minimum of 2-in. of poured lightweight insulating concrete. The OMG CR 1.2 Base Sheet Fastener will be embedded into a minimum of 1¼-in. of poured lightweight insulating concrete or various gypsums. Substrates must be surface dry. For best performance, the fastener should always be installed perpendicular to the substrate. Installation of fasteners too far apart to too close together can result in interaction of forces on the substrate and lead to a reduction of fastener performance.

Note: On re-roofing applications, prior to job bid, roof deck should be inspected or tested to determine the pullout values.

PHYSICAL DATAThe data below is constant for each OMG CR-Base Sheet Fastener.

HEAD lEgS

1.125" x 1" 1.2" 1.75"

MATERIAl PlATE

g-90 galvanized CR-10 Coated Fastener

.014" (nominal) Thickness

2.75" Diameter galvalume

PACKAgINg

1000 500

CR-Base Sheet Fastener

FM APPROvED FASTENINg PATTERNSDue to frequent changes in Factory Mutual requirements for securing base sheets to various lightweight concrete and gypsum decks, please contact the roof cover manufacturer for up to date information on approved fastening patterns.

SBS Modified Bitumen Waterproofing Membrane Revision date: April 30, 2015 Page 1 of 4

SAFETY DATA SHEET

SBS MODIFIED BITUMEN WATERPROOFING MEMBRANE Offerte en français

GHS PROTECTIVE CLOTHING TRANSPORT OF DANGEROUS GOODS

Not regulated

Not regulated

SECTION I: IDENTIFICATION Trade names: Elastophene Sanded 3.0, Elastophene Flam, Elastophene PS 3.0, Elastophene SP 3.0, Elastophene Flam Stick, Elastophene Stick, Colphene Sanded, Elastophene PS 2.2,

Elastophene SP 2.2, Elastophene Flam 2.2, Elastophene Sanded, Colvent Flam SA, Colvent SA, Colvent TG, Colvent Flam TG, Colphene Stick GR, Elastophene Stick

FR GR, Elastophene FR+GR, Elastophene Flam LS FR GR, Elastophene Flam FR+ GR, Elastophene Flam FR GR, Elastophene FR GR, Elastophene LS FR GR, Elastophene HR Sanded 2.2, Elastophene HR Sanded 3.0, Elastophene Flam HR 3.0, Elastophene HR 2.2, Elastophene HE FR GR (WHT), Elastophene Stick HE FR

GR (WHT), Elastophene Flam HR FR GR (WHT), Colply membranes, Lastobond, Lastoflex, Modified Sopra G, Perimet’R, Sopra G, Sopragrip F, Sopralap, Sopraply,

Soprasolin, Sopravap’R, Unilay.

Use: Membranes are used for all types of roofing needs, air barrier and waterproofing protection. Manufacturers SOPREMA Canada SOPREMA Inc. SOPREMA USA SOPREMA Gulfport

and distributors: 1675 Haggerty Street 44955 Yale Road West 310 Quadral Drive 12251 Seaway Road

Drummondville (Quebec) J2C 5P7 Chilliwack (B.C.) V2R 4H3 Wadsworth (Ohio) 44281 Gulfport (Mississippi) 39503

CANADA CANADA UNITED STATES UNITED STATES

Tel.: 819 478-8163 Tel.: 604 793-7100 Tel.: 1 800 356-3521 Tel.: 228 701-1900

In case of emergency:

SOPREMA (8:00am to 5:00pm): 1 800 567-1492 CANUTEC (Canada) (24h.): 613 996-6666 CHEMTREC (USA) (24h.): 1 800 424-9300

SECTION II: HAZARD(S) IDENTIFICATION

Bitumen membrane. Asphalt odor. Under normal use, this product is not expected to create any health or environmental hazard. Inhalation of dust or of

asphalt fumes can cause a slight respiratory irritation and/or congestion.

SECTION III: COMPOSITION AND INFORMATION ON HAZARDOUS INGREDIENTS

NAME CAS # % WEIGHT EXPOSURE LIMIT (ACGIH)

TLV-TWA TLV-STEL

BITUMINOUS BLEND

Bitumen 8052-42-4 30-70 0.5 mg/m³

Asphalt fumes Not established

Self-adhesive membranes contain:

Highly hydrotreated naphthenic oil1 64742-52-5 0-30 Not established Not established

Calcium Carbonate1 471-34-1 0-60 10 mg/m³ Not established

Styrene butadiene copolymer1 9003-55-8 0-15 10 mg/m³ Not established

FR products contain:

Calcium borate1 FR Plus products contain:

Fire retardant1

1318-33-8

Proprietary

7-15

1-5

10 mg/m³

2 mg/m³

Not established

Not established

REINFORCEMENT

Some products may contain fibre glass, polyester or a mix of glass grid and polyester.

Polyester mat1 N/A 1-7 Not established Not established

Fibre glass mat1

Contains: Fibre glass filament1

N/A

65997-17-3

1-7

0,5-7

Not established

1f/cc

Not established

Not established

UNDERFACE AND SURFACE

Some membranes are protected by sand, talc, mineral granule, silicone paper, polyethylene or polypropylene film, aluminium, copper or

stainless steel foil.


Silicone paper N/A 6-20 Not established Not established

Polypropylene film N/A 2-10 Not established Not established

Polyethylene film 9002-88-4 2-10 Not established Not established

Aluminium, copper or stainless steel foil N/A 4-15 Not established Not established

Sand

Contains: Crystalline silica2

N/A

14808-60-7

7-13

7-13

0.1 mg/m³

0.025 mg/m³

Not established

Not established

Talc 14807-96-6 7-13 Not established Not established

Coloured granules

Contains: Crystalline silica2

N/A

14808-60-7

15-40

< 12

Not established

0.025 mg/m³

Not established

Not established

1. The exposure to the substance above the limits of exposure is not likely to occur considering its form (incorporated in the mixture) and/or the

provided use. The limit of exposure is given for reference only.

2. A proportion of crystalline silica can be present in the sand sprinkled on the top of some membranes. The crystalline silica contained in the sand

is not likely to be found in the ambient air in concentration above the limit of exposure since the sand adheres to the surface of the membrane.

SECTION III: POTENTIAL HEALTH EFFECTS

Effects of short term (acute) exposure SKIN CONTACT The product can cause a mechanical irritation of the skin because of its

rough surface. If the membrane is torch-applied, asphalt fumes can

cause skin irritation. The asphalt fumes can cause an irritation of the

skin. The contact with this product at high temperature can cause

thermal burns. EYE CONTACT The product is not likely to cause effects to the eyes. If the membrane is

torch-applied, asphalt fumes can be emitted of the product and cause

irritations, redness and conjunctivitis to the eyes. The contact with this

product at high temperature can cause thermal burns. INHALATION The product is not likely to cause effects on the respiratory system. If

the membrane is torch-applied, asphalt fumes can be emitted of the

product and cause irritations to the nose, the throat and the respiratory

tracts, tiredness, headaches, dizziness, nauseas and insomnia. INGESTION Exposure is not likely to occur by this route of entry under normal use

of the product.

Effects of long term (chronic) exposure SKIN CONTACT The repeated or prolonged contact can cause irritation. If the membrane

is torch-applied, asphalt fumes can be emitted. The long-term exposure

to the asphalt fumes can cause changes of the pigmentation of the skin

which can be worsened by the exposure to the sun. (1) INHALATION If the membrane is torch-applied, asphalt fumes can be inhaled. No data

on chronic effects of the exposure to asphalt fumes on the lungs. CARCINOGENICITY Due to the product form, exposure to hazardous dusts or fumes is not

expected to occur. Information on carcinogenicity is given for reference

only. This product is not classifiable as a carcinogen. Bitumen: According to the International Agency for Research on

Cancer (IARC): not classifiable as to its carcinogenicity to humans.

Epidemiological studies of roofers have generally demonstrated an

excess of lung cancer in these workers. However, it is unclear to what

extent these cancers may be attributable to asphalt exposures during

roofing operations, since in the past, roofers have been exposed to coal

tar and asbestos, which are known human lung carcinogens. Trace

amounts of polynuclear aromatic hydrocarbons (PAHs) may be present

in some asphalts and can be released upon excessive heating. Some of

these PAHs have been identified as having the potential to induce

carcinogenic and reproductive health effects. (2) Crystalline Silica: Breathable crystalline silica from sand is not

expected to be released, sand is adhered to product. According to

IARC, crystalline silica is carcinogenic for human by inhalation. (3)

Fibreglass Filament: Fibreglass is not expected to be released. In

2001, IARC classified fibreglass as Group 3 “not classifiable as to its

carcinogenicity to humans”. The American Conference of

Governmental Industrial Hygienists (ACGIH) and the National

Toxicology Program (NTP) classify the substance in Group 2B

(possibly carcinogenic to humans) based on studies in which animals

were injected with large quantities of fibreglass. The other ingredients were not found to be carcinogenic or no

information is available on that matter. TERATOGENICITY, EMBRIOTOXICITY, FETOTOXICITY No information available. REPRODUCTIVE TOXICITY No information available.

MUTAGENICITY No information available. TOXICOLOGICALLY SYNERGISTIC MATERIALS No information available. POTENTIAL ACCUMULATION No information available.

SECTION IV: FIRST-AID MEASURES SKIN CONTACT If there is presence of dust on the skin, wash gently with water and

soap. In the event of contact with the product melted, do not try to

remove the product of the affected area and rinse the area affected in

cold water. Obtain immediate medical attention. At the end of each

working day, clean all the parts of the body which came into contact

with asphalt fumes. Clean the clothing contaminated by the asphalt

fumes. EYE CONTACT Flush eyes with water for at least 15 minutes while holding eyelids

open. Do not attempt to remove material from affected area without

medical assistance. Obtain immediate medical attention. INHALATION

Remove victim from contaminated place and restore breathing, if

required. INGESTION

The ingestion of this product is not very likely to occur.

SECTION V: FIRE-FIGHTING MEASURES FLAMMABILITY: Not applicable

EXPLOSION DATA: Not applicable

FLASH POINT: Not applicable

AUTO-IGNITION TEMPERATURE: Not applicable

FLAMMABILITY LIMITS IN AIR: (% in volume) Not applicable FIRE AND EXPLOSION HAZARDS


Asphalt fumes are flammable. Torch, used to weld waterproofing

membranes, can produce temperatures beyond 1100°C (2000°F). Avoid

all contact with materials sensitive to these temperatures, as lead or

plastic materials. Never work in an enclosed area where gas can

accumulate. Shield air conditioning units and other protrusions on the

roof with perlite panels or similar material when using the torch around

them. Never use torch (es):

- When substrate(s) have been recently covered by solvent-based

products (wait until it is dry).

- Near any combustible materials.

- Close to containers containing flammable liquids or materials (keep

open flame at least 3 m [10'] away).

- Directly on combustible substrate or insulation.

Voids, holes or gaps in substrate or located nearby the welding zone

can be protected against flame penetration. Particular precautions must

be taken to keep combustible or heat sensitive insulation away from the

torch flame. If wood fibre panels must be installed, use fireproof

panels. Avoid presence of combustible materials near open flame. At

all times and especially when leaving job site, make sure that there is

no smouldering or concealed fire. In that case, strictly follow the safety

measures. Job planning must allow for employee presence on the roof

at least one hour after torch application. At the end of every day, use a

heat detector gun to discover any unusually hot surface. Always have

one ABC fire extinguisher on hand, filled and in perfect working order

near each torch. COMBUSTION PRODUCTS

Burning of this material will produce thick black smoke. Irritating

and/or toxic gases including Hydrogen Sulphide and Sulphur Dioxide,

traces of metallic fumes may be generated by thermal decomposition or

combustion. FIRE FIGHTING INSTRUCTIONS Evacuate the area. Wear self-contained breathing apparatus and

appropriate protective clothing in accordance with standards. Approach

fire from upwind and fight fire from maximum distance or use

unmanned hose holders or monitor nozzles. Always stay away from the

containers at the time of the fire considering the high risk of explosion.

Move the rolls of membrane from fire area if it can be done without

risk. Cool the rolls of membrane with flooding quantities of water until

well after fire is out. EXTINGUISHING MEDIA: Foam, CO2, sand, chemical powder.

SECTION VI: ACCIDENTAL RELEASE MEASURES RELEASE OR SPILL If hot material is spilled, allow enough time to cool completely and

remove to a container for disposal. Wear appropriate breathing

apparatus (if applicable) and protective clothing. Notify appropriate

environmental agencies. Wash spill area with soap and water. Dispose

of this material according to local environmental regulations.

SECTION VII: HANDLING AND STORAGE HANDLING SOPREMA's products must be applied by qualified applicators who

have received an adequate training, for the prevention and the

protection (in particular for the use of the extinguishers) against

accidents caused by use of combustible or flammable materials, of

liquefied propane gas, open flame, and their material of installation.

The present recommendations must be imperatively related to the

knowledge of the employees before the application of the products to

the building site. Check the construction and the composition of the

systems of roof and the walls before welding. Ensure of the cleanliness

of the places (debris). Precautions of the use of the torch: Use only proper torching

equipment in perfect working order, C.S.A. certified. Never modify

torching equipment. Use only proper hoses suited for propane gas of

less than 15 m (50'). Verify and tighten all the connections before the

use of the equipment. Do not light the torch if a propane odor is

present. Never seek a leak with a flame. Use a torch whose gas output

is adjustable with stopping device. Follow the specifications, notices

and documentations of the manufacturers. STORAGE Flashings must be stored in such a way to prevent any creasing,

twisting, scratches and other damages of the roof. The materials must

be protected adequately and stored permanently away from flames or

welding sparks, protected from bad weather and any harmful

substances. Store self-adhesive membranes away from the sun.

SECTION VIII: EXPOSURE CONTROLS / PERSONAL

PROTECTION HANDS: Wear resistant gloves.

RESPIRATORY: If the TLV for dust is exceeded, if use is performed

in a poorly ventilated confined area, use an approved respirator in

accordance with standards.

EYES: Wear safety goggles in accordance with standards.

BODY: Wear adequate protective clothes. Do not wear synthetic

fabric. Remove clothing contaminated with solvents.

OTHERS: Eye bath and safety shower.

SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Solid

ODOR AND APPEARANCE: Black membrane with asphalt odor

ODOR THRESHOLD: Not available

VAPOR PRESSURE (20C): Not applicable

VAPOR DENSITY (air = 1): Not applicable

EVAPORATION RATE (Butyl acetate = 1): Not applicable

BOILING POINT (760 mm Hg): Not applicable

FREEZING POINT: Not applicable

SPECIFIC GRAVITY (H2O = 1): Variable

SOLUBILITY IN WATER (20C): None

VOLATILE ORGANIC COMPOUND CONTENT (V.O.C.): Not measurable (0 g/L)

VISCOSITY: Not applicable

SECTION X: STABILITY AND REACTIVITY STABILITY: This material is stable.

CONDITIONS OF REACTIVITY: Avoid excessive heat.

INCOMPATIBILITY: Acid and strong basis and organic solvents

and greasy substances.

HAZARDOUS DECOMPOSITION PRODUCTS: None identified.

HAZARDOUS POLYMERISATION: None.

SECTION XI: TOXICOLOGICAL INFORMATION

Effects of Short-Term (Acute) Exposure No information available.

Effects of Long-Term (Chronic) Exposure CARCINOGENICITY

Bitumen: Data from experimental studies in animals and cultured

mammalian cells indicate that laboratory-generated roofing asphalt

fume condensates are genotoxic and cause skin tumours. (2) Crystalline Silica: Several studies have shown an increased incidence

of lung tumours in rats exposed to quartz by inhalation for up to 2

years. IARC has determined that there is sufficient evidence that quartz

is carcinogenic to experimental animals. (3) The other ingredients were not found to be carcinogenic or no

information is available on that matter. REPRODUCTIVE EFFECTS No information available.


TERATOGENICITY, EMBRYOTOXICITY, FETOTOXICITY

No information available. MUTAGENICITY

Crystalline Silica: None according to the available information. No information available about the other ingredients. SYNERGISTIC MATERIALS Tobacco smoke increases the effects of silica dust on respiratory

system. Simultaneous exposure to known carcinogens as benzo (a),

pyrene, can increase the carcinogenicity of crystalline silica.

SECTION XII: ECOLOGICAL INFORMATION ENVIRONMENTAL EFFECTS

No data. BIODEGRADABILITY This product is not biodegradable. No possible bioaccumulation and

unlikely bioconcentration in the food chain.

SECTION XIII: DISPOSAL CONSIDERATIONS WASTE DISPOSAL

This product is not hazardous waste. Consult local, provincial, territory

or state authorities to know disposal methods. This material is not listed

by the EPA as hazardous waste according to the Resource Conservation

and Recovery Act (RCRA) of the United States. No Environmental

Protection Agency (EPA) waste numbers are applicable for this

product.

SECTION XIV: TRANSPORT INFORMATION This product is not regulated by Department of Transportation (DOT)

and Transportation Dangerous Goods (TDG).

SECTION XV: REGULATORY INFORMATION DSL: All constituents of this product are included in the

Domestic Substances List (Canada).

TSCA: All constituents of this product are listed on the Toxic

Substances Control Act Inventory (TSCA – United

States).

Prop. 65: This product contains chemicals known to the State of

California to cause cancer or reproductive toxicity.

SECTION XVI: OTHER INFORMATION GLOSSARY

ACGIH: American Conference of Governmental Industrial

Hygienists (United States)

ANSI: American National Standards Institute (United States)

ASTM: American Society for Testing and Materials (United

States)

CAS: Chemical Abstract Services

CFR: Code of Federal Regulations (United States)

CSA: Canadian Standardization Association

DOT: Department of Transportation (United States)

DSL: Domestic Substances List (Canada)

EPA: Environmental Protection Agency (United States)

GHS Globally Harmonized System

IARC: International Agency for Research on Cancer

LD50/LC50: Less high lethal dose and lethal concentration published

NFPA: National Fire Protection Association (United States)

NIOSH: National Institute for Occupational Safety and Health

(United States)

NTP: National Toxicology Program (United States)

OSHA: Occupational Safety & Health Administration (United

States)

RCRA: Resource Conservation and Recovery Act (United

States)

TDG: Transportation of Dangerous Goods (Canada)

TLV-TWA: Threshold Limit Value – Time-Weighted Average

TSCA: Toxic Substances Control Act (United States)

References: (1) Safety Data Sheet from the supplier

(2) WHO (2013) Bitumens and bitumen emissions, and some N- and

S- heterocyclic polycyclic aromatic hydrocarbons. Volume 103.

IARC monographs on the evaluation of carcinogenic risks to

humans.

(3) CHEMINFO (2015) Canadian Centre of Occupational Health and

Safety, Hamilton (Ontario) Canada

Code of SDS: CA U DRU SS FS 044

For information: 1-800-356-3521 (U.S.A.)

1 800 567-1492 (Canada)

The Safety Data Sheets of SOPREMA are available on Internet at the

following site: www.soprema.us and www.soprema.ca

Update justification:

GHS Format

To the best of our knowledge, the information contained herein is accurate.

However, neither the above named supplier nor any of its subsidiaries

assumes any liability whatsoever for the accuracy or completeness of the

information contained herein. Final determination of suitability of any

material is the sole responsibility of the user. All materials may present

unknown hazards and should be used with caution. Although certain

hazards are described herein, we cannot guarantee that these are the only

hazards that exist.

http://www.soprema.us/

http://www.soprema.ca/

SBS Modified Bitumen Waterproofing Membrane Revision date: August 27, 2014 Page 1 of 4

MATERIAL SAFETY DATA SHEET

SBS MODIFIED BITUMEN WATERPROOFING MEMBRANE Offerte en français

WHMIS PROTECTIVE CLOTHING TRANSPORT OF DANGEROUS GOODS

Not regulated

Not regulated

SECTION I: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Trade names: Aerisol, Antirock, Baral, Colphene, Colply, Colvent, Dryseal, Elasto, Elastobase, Elastophene, Environap, EPS Flam Stick, G-Vent, Lastobond,

Lastoflex, M-Express, M-SBase, Modified Sopra G, Perimet’R, Sopraeshavent, Soprafix, Sopraflash, Sopra G, Sopra G2, Sopraglass, Sopragrip F, Sopraguard, Sopra IV, Soprajoint, Sopralap, Sopralast, Sopralene, Sopraply, Soprasaf'T, Sopraseal, Soprasolin, Soprastar, Soprastick, Sopratape, Sopravap’R, Sopra VI, Soprawalk, Sopremium, Starter Stick GR, Stickson, Unilay.

Use: Membranes are used for all types of roofing needs, air barrier and waterproofing protection. Manufacturers Soprema Canada Soprema Inc. Soprema USA Soprema Gulfport and distributors: 1675 Haggerty Street 44955 Yale Road West 310 Quadral Drive 12251 Seaway Road Drummondville (Quebec) J2C 5P7 Chilliwack (B.-C.) V2R 4H3 Wadsworth (Ohio) 44281 Gulfport (Mississippi) 39503 CANADA CANADA UNITED STATES UNITED STATES Tel.: 819 478-8163 Tel.: 604 793-7100 Tel.: 1 800 356-3521 Tel.: 228 701-1900

In case of emergency:

SOPREMA (8:00am to 5:00pm): 1 800 567-1492 CANUTEC (Canada) (24h.): 613 996-6666 CHEMTREC (USA) (24h.): 1 800 424-9300

EMERGENCY OVERVIEW Bitumen membrane. Asphalt odour. Under normal use, this product is not expected to create any health or environmental hazard. Inhalation of dust or of

asphalt fumes can cause a respiratory irritation and/or congestion. WARNING! This product may contain substances known by the State of California that could cause cancer (asphalt, crystalline silica, fibreglass).

SECTION II: COMPOSITION AND INFORMATION ON DANGEROUS INGREDIENTS NAME CAS # % WEIGHT EXPOSURE LIMIT (ACGIH)

TLV-TWA TLV-STEL BITUMINOUS BLEND

Bitumen 8052-42-4 30-70 0.5 mg/m³ Asphalt fumes Not established

Self-adhesive membranes contain: Highly hydrotreated naphthenic oil1 64742-52-5 0-30 Not established Not established

Calcium Carbonate1 471-34-1 0-60 10 mg/m³ Not established Styrene butadiene copolymer1 9003-55-8 0-15 10 mg/m³ Not established

FR products contain: Calcium borate1

FR Plus products contain: Natural graphite1

1318-33-8

7782-42-5

7-15

1-5

10 mg/m³

2 mg/m³

Not established

Not established

REINFORCEMENT Some products may contain fibre glass, polyester or a mix of glass grid and polyester.

Polyester mat1 N/A 1-7 Not established Not established Fibre glass mat1

Contains: Fibre glass filament1 N/A

65997-17-3 1-7

0,5-7 Not established

1f/cc Not established Not established

UNDERFACE AND SURFACE Some membranes are protected by sand, talc, mineral granule, silicone paper, polyethylene or polypropylene film, aluminium, copper or

stainless steel foil. Silicone paper N/A 6-20 Not established Not established

Polypropylene film N/A 2-10 Not established Not established Polyethylene film 9002-88-4 2-10 Not established Not established

Aluminium, copper or stainless steel foil N/A 4-15 Not established Not established Sand

Contains: Crystalline silica2 N/A

14808-60-7 7-13 7-13

0.1 mg/m³ 0.025 mg/m³

Not established Not established

Talc 14807-96-6 7-13 Not established Not established Coloured granules

Contains: Crystalline silica2 N/A

14808-60-7 15-40 < 12

Not established 0.025 mg/m³

Not established Not established

1. The exposure to the substance above the limits of exposure is not likely to occur considering its form (incorporated in the mixture) and the provided use. The limit of exposure is given for reference only.

2. A proportion of crystalline silica can be present in the sand sprinkled on the top of some membranes. The crystalline silica contained in the sand is not likely to be found in the ambient air in concentration above the limit of exposure since the sand adheres to the surface of the membrane.


SECTION III: POTENTIAL HEALTH EFFECTS

Effects of short term (acute) exposure SKIN CONTACT The product can cause a mechanical irritation of the skin because of its rough surface. If the membrane is torch-applied, asphalt fumes can cause skin irritation. The asphalt fumes can cause an irritation of the skin. The contact with this product at high temperature can cause thermal burns. EYE CONTACT The product is not likely to cause effects to the eyes. If the membrane is torch-applied, asphalt fumes can be emitted of the product and cause irritations, redness and conjunctivitis to the eyes. The contact with this product at high temperature can cause thermal burns. INHALATION The product is not likely to cause effects on the respiratory system. If the membrane is torch-applied, asphalt fumes can be emitted of the product and cause irritations to the nose, the throat and the respiratory tracts, tiredness, headaches, dizziness, nauseas and insomnia. INGESTION Exposure is not likely to occur by this route of entry under normal use of the product.

Effects of long term (chronic) exposure SKIN CONTACT The repeated or prolonged contact can cause irritation. If the membrane is torch-applied, asphalt fumes can be emitted. The long-term exposure to the asphalt fumes can cause changes of the pigmentation of the skin which can be worsened by the exposure to the sun. (1) INHALATION If the membrane is torch-applied, asphalt fumes can be inhaled. No data on chronic effects of the exposure to asphalt fumes on the lungs. CARCINOGENICITY Due to the product form, exposure to hazardous dusts or fumes is not expected to occur. Information on carcinogenicity is given for reference only. This product is not classifiable as a carcinogen. Asphalt: According to the International Agency for Research on Cancer (IARC): not classifiable as to its carcinogenicity to humans. Epidemiological studies of roofers have generally demonstrated an excess of lung cancer in these workers. However, it is unclear to what extent these cancers may be attributable to asphalt exposures during roofing operations, since in the past, roofers have been exposed to coal tar and asbestos, which are known human lung carcinogens. Trace amounts of polynuclear aromatic hydrocarbons (PAHs) may be present in some asphalts and can be released upon excessive heating. Some of these PAHs have been identified as having the potential to induce carcinogenic and reproductive health effects. (2) Crystalline Silica: Breathable crystalline silica from sand is not expected to be released, sand is adhered to product. According to IARC, crystalline silica is carcinogenic for human by inhalation. (3) Fibreglass Filament: Fibreglass is not expected to be released. In 2001, IARC classified fibreglass as Group 3 “not classifiable as to its carcinogenicity to humans”. The American Conference of Governmental Industrial Hygienists (ACGIH) and the National Toxicology Program (NTP) classify the substance in Group 2B (possibly carcinogenic to humans) based on studies in which animals were injected with large quantities of fibreglass. The other ingredients were not found to be carcinogenic or no information is available on that matter. TERATOGENICITY, EMBRIOTOXICITY, FETOTOXICITY No information available. REPRODUCTIVE TOXICITY No information available.

MUTAGENICITY No information available. TOXICOLOGICALLY SYNERGISTIC MATERIALS No information available. POTENTIAL ACCUMULATION No information available.

SECTION IV: FIRST AID MEASURES

SKIN CONTACT If there is presence of dust on the skin, wash gently with water and soap. In the event of contact with the product melted, do not try to remove the product of the affected area and rinse the area affected in cold water. Obtain immediate medical attention. At the end of each working day, clean all the parts of the body which came into contact with asphalt fumes. Clean the clothing contaminated by the asphalt fumes. EYE CONTACT Flush eyes with water for at least 15 minutes while holding eyelids open. Do not attempt to remove material from affected area without medical assistance. Obtain immediate medical attention. INHALATION Remove victim from contaminated place and restore breathing, if required. INGESTION The ingestion of this product is not very likely to occur.

SECTION V: FIRE-FIGHTING MEASURES FLAMMABILITY: Not applicable EXPLOSION DATA: Not applicable FLASH POINT: Not applicable AUTO-IGNITION TEMPERATURE: Not applicable FLAMMABILITY LIMITS IN AIR: (% in volume) Not applicable FIRE AND EXPLOSION HAZARDS Asphalt fumes are flammable. Torch, used to weld waterproofing membranes, can produce temperatures beyond 1100°C (2000°F). Avoid all contact with materials sensitive to these temperatures, as lead or plastic materials. Never work in an enclosed area where gas can accumulate. Shield air conditioning units and other protrusions on the roof with perlite panels or similar material when using the torch around them. Never use torch (es): - When substrate(s) have been recently covered by solvent-based

products (wait until it is dry). - Near any combustible materials. - Close to containers containing flammable liquids or materials (keep

open flame at least 3 m [10'] away). - Directly on combustible substrate or insulation. Voids, holes or gaps in substrate or located nearby the welding zone can be protected against flame penetration. Particular precautions must be taken to keep combustible or heat sensitive insulation away from the torch flame. If wood fibre panels must be installed, use fireproof panels. Avoid presence of combustible materials near open flame. At all times and especially when leaving job site, make sure that there is no smouldering or concealed fire. In that case, strictly follow the safety measures. Job planning must allow for employee presence on the roof at least one hour after torch application. At the end of every day, use a heat detector gun to discover any unusually hot surface. Always have one ABC fire extinguisher on hand, filled and in perfect working order near each torch. COMBUSTION PRODUCTS Burning of this material will produce thick black smoke. Irritating and/or toxic gases including Hydrogen Sulphide and Sulphur Dioxide, traces of metallic fumes may be generated by thermal decomposition or combustion.


FIRE FIGHTING INSTRUCTIONS Evacuate the area. Wear self-contained breathing apparatus and appropriate protective clothing in accordance with standards. Approach fire from upwind and fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Always stay away from the containers at the time of the fire considering the high risk of explosion. Move the rolls of membrane from fire area if it can be done without risk. Cool the rolls of membrane with flooding quantities of water until well after fire is out. EXTINGUISHING MEDIA: Foam, CO2, sand, chemical powder.

SECTION VI: ACCIDENTAL RELEASE MEASURES

RELEASE OR SPILL If hot material is spilled, allow enough time to cool completely and remove to a container for disposal. Wear appropriate breathing apparatus (if applicable) and protective clothing. Notify appropriate environmental agencies. Wash spill area with soap and water. Dispose of this material according to local environmental regulations.

SECTION VII: HANDLING AND STORAGE HANDLING Soprema's products must be applied by qualified applicators who have received an adequate training, for the prevention and the protection (in particular for the use of the extinguishers) against accidents caused by use of combustible or flammable materials, of liquefied propane gas, open flame, and their material of installation. The present recommendations must be imperatively related to the knowledge of the employees before the application of the products to the building site. Check the construction and the composition of the systems of roof and the walls before welding. Ensure of the cleanliness of the places (debris). Precautions of the use of the torch: Use only proper torching equipment in perfect working order, C.S.A. certified. Never modify torching equipment. Use only proper hoses suited for propane gas of less than 15 m (50'). Verify and tighten all the connections before the use of the equipment. Do not light the torch if a propane odour is present. Never seek a leak with a flame. Use a torch whose gas output is adjustable with stopping device. Follow the specifications, notices and documentations of the manufacturers. STORAGE Flashings must be stored in such a way to prevent any creasing, twisting, scratches and other damages of the roof. The materials must be protected adequately and stored permanently away from flames or welding sparks, protected from bad weather and any harmful substances. Store self-adhesive membranes away from the sun.

SECTION VIII: EXPOSURE CONTROLS / PERSONAL PROTECTION

HANDS: Wear resistant gloves. RESPIRATORY: If the TLV for dust is exceeded, if use is performed in a poorly ventilated confined area, use an approved respirator in accordance with standards. EYES: Wear safety goggles in accordance with standards. BODY: Wear adequate protective clothes. Do not wear synthetic fabric. Remove clothing contaminated with solvents. OTHERS: Eye bath and safety shower.

SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Solid ODOUR AND APPEARANCE: Black membrane with asphalt odour ODOUR THRESHOLD: Not available VAPOUR PRESSURE (20°C): Not applicable VAPOUR DENSITY (air = 1): Not applicable EVAPORATION RATE (Butyl acetate = 1): Not applicable BOILING POINT (760 mm Hg): Not applicable

FREEZING POINT: Not applicable SPECIFIC GRAVITY (H2O = 1): Variable SOLUBILITY IN WATER (20°C): None VOLATIL ORGANIC COMPOUND CONTENT (V.O.C.): Not measurable (0 g/L) VISCOSITY: Not applicable

SECTION X: STABILITY AND REACTIVITY STABILITY: This material is stable. CONDITIONS OF REACTIVITY: Avoid excessive heat. INCOMPATIBILITY: Acid and strong basis and organic solvents and greasy substances. HAZARDOUS DECOMPOSITION PRODUCTS: None identified. HAZARDOUS POLYMERISATION: None.

SECTION XI: TOXICOLOGICAL INFORMATION TOXICOLOGICAL DATA Natural graphite: (3) LC50 (rat): > 64 400 mg/kg LD50 (oral, rat): > 10 000 mg/kg No information available on the other ingredients.

Effects of Short-Term (Acute) Exposure No information available.

Effects of Long-Term (Chronic) Exposure CARCINOGENICITY Asphalt: Data from experimental studies in animals and cultured mammalian cells indicate that laboratory-generated roofing asphalt fume condensates are genotoxic and cause skin tumours. (2) Crystalline Silica: Several studies have shown an increased incidence of lung tumours in rats exposed to quartz by inhalation for up to 2 years. IARC has determined that there is sufficient evidence that quartz is carcinogenic to experimental animals. (3) The other ingredients were not found to be carcinogenic or no information is available on that matter. REPRODUCTIVE EFFECTS No information available. TERATOGENICITY, EMBRYOTOXICITY, FETOTOXICITY No information available. MUTAGENICITY Crystalline Silica: None according to the available information. No information available about the other ingredients. SYNERGISTIC MATERIALS Tobacco smoke increases the effects of silica dust on respiratory system. Simultaneous exposure to known carcinogens as benzo (a), pyrene, can increase the carcinogenicity of crystalline silica.

SECTION XII: ECOLOGICAL INFORMATION ENVIRONMENTAL EFFECTS No data. BIODEGRADABILITY This product is not biodegradable. No possible bioaccumulation and unlikely bioconcentration in the food chain.

SECTION XIII: DISPOSAL CONSIDERATIONS WASTE DISPOSAL This product is not hazardous waste. Consult local, provincial, territory or state authorities to know disposal methods. This material is not listed by the EPA as hazardous waste according to the Resource Conservation and Recovery Act (RCRA) of the United States. No Environmental Protection Agency (EPA) waste numbers are applicable for this product.


SECTION XIV: TRANSPORT INFORMATION This product is not regulated by Department of Transportation (DOT) and Transportation Dangerous Goods (TDG).

SECTION XV: REGULATORY INFORMATION WHMIS: This product is not regulated by WHMIS. DSL: All constituents of this product are included in the

Domestic Substances List (Canada). TSCA: All constituents of this product are listed on the Toxic

Substances Control Act Inventory (TSCA – United States).

HMIS (USA): NFPA (USA): Health 0 Health 0 Flammability 1 Flammability 1 Physical hazard 0 Instability 0 Protective equipment B Specific hazard 0

SECTION XVI: OTHER INFORMATION GLOSSARY ANSI: American National Standards Institute CAS: Chemical Abstract Services CFR: Code of Federal Regulations LD50/CL50: Less high lethal dose and lethal concentration published HMIS: Hazardous Material Information System IARC: International Agency for Research on Cancer NIOSH: National Institute for Occupational Safety and Health NFPA: National Fire Protection Association OSHA: Occupational Safety & Health Administration SARA: Superfund Amendments and Reorganization Act TLV: Threshold Limit Value TWA: Time-weighted average WHMIS: Workplace Hazardous Materials Information System

References: (1) Material Safety Data Sheet from the supplier (2) NIOSH (2001) Hazard Review, Health Effects of Occupational

Exposure to Asphalt. U.S. Department of Health and Human Service, Centers for Disease Control and Prevention, National Institute for Occupational Safety and Health, DHHS (NIOSH) Publication No. 2001-110.

(3) CHEMINFO (2014) Canadian Centre of Occupational Health and Safety, Hamilton (Ontario) Canada

Code of MSDS: CA U DRU SS FS 044 For information: 1 800 567-1492 The Material Safety Data Sheets of SOPREMA are available on Internet at the following site: www.soprema.ca Update justification: Modification of the list of ingredients. (Section II) This MSDS contains all the information required by ANSI Z-400.1-1998 standard (United States), by regulation 29 CFR Part 1910.1200 of the Hazard Communication Standard of OSHA, and is in accordance with standard DORS/88-66 OF WHMIS Canada. To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

http://www.soprema.ca/

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