Kiemtailieu.com Etylbenzen

7/24/2019 Kiemtailieu.com Etylbenzen

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11/09/15 1

BO CO CHUYN BO CO CHUYN

MN: CNG NGH TNG HPMN: CNG NGH TNG HP

HU C HA DUHU C HA DU


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11/09/15 2

ETHYLBENZENEETHYLBENZENE

!"# !"#

G$HD: T%& P'() T'*+' H,-+G$HD: T%& P'() T'*+' H,-+

N'.) /0:N'.) /0:

/&/& H,1+' A+' $#2!H,1+' A+' $#2!3&3& N4,-5+ H6"+4 $#2!N4,-5+ H6"+4 $#2!

7&7& T89+ ; $#+'T89+ ; $#+'

& B?# @,*+4 $+4B?# @,*+4 $+4


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E!'-++ " '#F86;*;6+ !') IJ; +4 FK+4 8+4 8# !86+4;+4 +4'2 !+4 'J '.* F9,&E!'-++Q '+-!'*+Q CRH>CH3CH7 " 'J ;'=! AS- !')+ +4Q ;. V +4'W* X,*+ !8+4 !86+4 ;+4 +4'#2 !+4 'J ', ;

'.* F9,& P'9+ + [ \ ]] ^ _ IJ; à FK+4 ") +4,-b+ #2, ;'6 X,c!8d+' è+ f,=! %!-8+ )6+6)8 CRH>CHgCH3& >h ^ ;i* X,c !8d+'è+ f,=! ++ !8b+ !'j 4##& C+ (# k! '+ / ^ !'-++ IJ;à FK+4 ") F,+4 )# ;'6 `+Q '6l; +4,-b+ #2, ;'6 X,c !8d+' è+

f,=! F#!'-++&H9, +'I !=! ;e E!'-++ !#+' S'#j! IJ; à FK+4 ")6-`!-8+ m è+ f,=! +'n* " ;*6 `, +4,-b+ #2,&RQ< !8#2, !=+ o +p) ;i* E!'-++ IJ; è+ f,=! !(# Mq [`r#2, 3hh/_& s EUQ S'6e+4 >Q0 !8#2, !=+ IJ; è+ f,=! "6 +p) /]]]&


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11/09/15 4

T l EB trn th gii gim trong nm 2008, l kt qu c! "# "u$ tho%ikinh t th gii, &'n ti nhu c(u )* +t$rn c-ng &(n ./ thu h1 li3 4%cnh "n 5u6t 7 9, T:u ;u, i )ic tng gi% ngu$n liu,

&'n ti lm gim nng "u6t , h?nh thnh c%c c@ng t$ lin hA13 hu )#cTrung C@ng ) Trung Du>c, nng "u6t EB +t$rn ti1 tc tng nhF o%n &o nhu c(u tng3 Trong khi Trung ) c


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11/09/15 5

QRSR TRUV TW


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11/09/15 6

eh(n Reh(n R

CY


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11/09/15 7

t D*+' 'c uUPAC: !-++t Tb+ S'c; " : !-+6Q'+-!*+QEB

t C+4 !'; '.* ';: CvH/h

O3 C/nh nghs!O3 C/nh nghs!::


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11/09/15 8

4@ng thKc 1h:n tG4@ng thKc 1h:n tG.
http://vi.wikipedia.org/wiki/T%E1%BA%ADp_tin:Ethylbenzene-2D-skeletal.pn


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11/09/15 9

46u trc46u trc
http://vi.wikipedia.org/wiki/T%E1%BA%ADp_tin:Ethylbenzene-3d.pn


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11/09/15 10

33& Tk+' ;'=! w! V& Tk+' ;'=! w! Vx i*u kin thFHng, Eth$l.nvn l ch6t

lwng trong "u>t, kh@ng mu )i mxi thymzc trFng3

x Eth$l.nvn c{ k|ch Kng cho &! ) m}t3

x TFyng >i ~c hi khi u>ng 1hi, h|t th7 )h61 1h qu! &!3


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11/09/15 11

Di y l mt viDi y l mt vitnh chttnh chtvt l ca Ethylbenzene:vt l ca Ethylbenzene:

Khi lng ring :- 15hC : 0.87139 g/cm3

- 200C : 0.867g/cm3

- 250C : 0.86262 g/cm3

Nhi! "# n$ng ch%& : -94. 9490C


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11/09/15 12

DI# y- " )! "#DI# y- " )! "#!k+' ;'=! w! V!k+' ;'=! w! V;i* E!'-++:;i* E!'-++:[!!_[!!_

N'#2! `# `#z /h/&7 SP*z /h/&7 SP*:: /7R&3/7R&3 hhCC

C'{ `r S'|; f(C'{ `r S'|; f( } z 3h} z 3h hhC :C : /&vv/&vv

} z 3>} z 3> hhC :C : /&


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11/09/15 13

Fi :$ l m~t )iFi :$ l m~t )it|nh ch6t )=t lt|nh ch6t )=t lc! Eth$l.nvn c! Eth$l.nvn tttt

N'#2! ;' ;'c-:N'#2! ;' ;'c-: />/> hhCC

N'#2! !n r; ;'c-N'#2! !n r; ;'c-:: o4


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11/09/15 14

Fi :$ l m~t )iFi :$ l m~t )it|nh ch6t )=t lt|nh ch6t )=t lc! Eth$l.nvnc! Eth$l.nvntttt

+'! +4 '; +'! +4 ';} z 70&v} z 70&vhh

C : h&R


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11/09/15 15

DI# y- " )! "#DI# y- " )! "#!k+' ;'=! w! V ;i*!k+' ;'=! w! V ;i*E!'-++: [!!_E!'-++: [!!_

N'#2! IJ+4 8#b+4:N'#2! IJ+4 8#b+4:} S'k V !Iz+4Q 3>} S'k V !Iz+4Q 3> hhC : //R] S4t/t/C : //R] S4t/t/

} +4Q 3>} +4Q 3> hhC : /0>3 S4t/t/C : /0>3 S4t/t/

G## '(+ ++G## '(+ ++:: h&3R7h&3R7

'* !*+ !86+4 +I; z 3h '* !*+ !86+4 +I; z 3h hhC : hQh/>4 o /hh)C : hQh/>4 o /hh)

T{ !8+4 '# [S'+4 S'k g/_ :7Q0T{ !8+4 '# [S'+4 S'k g/_ :7Q0

#m) r; ;'c- :/>t3h#m) r; ;'c- :/>t3h hhCC


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11/09/15 16

Phn IIPhn II

T^


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Trng th%i @5i h{!E!- ++ "6 X,c !8d+' 6f- '.* !86+4 ;c; !c; +'y+ 6f- '.* S'c; +'*,;'6 ;c; `e+ ') S'c; +'*, +'I '-F8686f#F E!'-++Q*;!6'+6+ " !'w) ;'k *;#F +6#;&


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T=! ;e +'+4 'e+ +4 !8b+ " 'e+ +4 6f- '.* ;i*!'- ++ # +'+4 ;'=! 'e+ +4 S'c; +'*, +'I:}P'e+ +4 / '.* ;'=! IJ; `a FK+4 " N*C83O0}P'e+ +4 3 '.* ;'=! IJ; `a FK+4 " C8O7}P'e+ +4 7 ;. !c; +'y+ 6f- '.* " M4[CH7COO_3}P'e+ +4 < ;. !c; +'y+ 6f- '.* " 6f- !86+4 S'+4 S'k

Trng th%i @5i h{!tt


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11/09/15 19

khG hir@ c! Eth$l.nvn

a s styrene c sn xut trong cng nghip t qu trnhkh hir ca !thy"#en$ene

CH3

CH7

C87O7QAB3O7

Rhh6C

CH CH3


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11/09/15 20

ehn Kng t$l.nvn )i Br2


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ehn Kng c~ng 2

CH3 CH7

} 7H3N#

//h *!)Q/3>6

C

CH3 CH7


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11/09/15 22

ehn Kng h!logn h{! nh{m !nk$l

CH3 CH7

} CB3

3 CH7CH

CB}

CH3 CH3CB


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11/09/15 23

Phn :

P!"#$% P!&P '($ )*+,


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11/09/15 24

4%c 1hFyng 1h%1 "n 5u6t Et$l.nvn4%c 1hFyng 1h%1 "n 5u6t Et$l.nvn

C. 3 'I+4 'c `e+ f,=! !-++:

tC'I+4 '+ 'J '# H-F86;*;6+ !') Cv

tA+S- '.* ++ +4 !-+


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11/09/15 25

Du% tr?nh chFng t%ch tN hn hA1 48Du% tr?nh chFng t%ch tN hn hA1 48

x '6e+4 /^ !-++ IJ; è+ f,=! ! X,c !8d+'+"-Q!'I+4 Sj! 'J # è+ f,=! f-+ ! è+ ') ;i* X,c!8d+' 68)#+4

x %e+ f,=! !-++ ! +4,+ +"- !#j+ '"+' '9+ + +4;'I+4 ;=!QX,c !8d+' !c;' 8=! S'. S'p+Q;+4 +4'2 !#j+ '"+'

;'I+4 !86+4 S'6e+4 ' [`#b, ;'I+4 'y+ 6(+_x C+4 +4'2 9, !#b+ ;i* '+4 C6`F+ O# *+F C')#;*

C6)*+- 8* # +p) /]>0Q#b+ Sj! # B*F48 C6)*+-&x @,c !8d+' !c;' -b, ;9, 7 !'c ;'I+4Q)# !'c '+ /hh

W*&N'#, +'" )c- IJ; fy- Fn+4 z MqQ;'y, ,QN'w!!86+4 +'+4 +p) RhQ!,- +'#b+ F6 r+ 9, !I " 4#c +p+4IJ+4 !p+4 +b+ 'I+4 'c +"- S'+4 ;. !k+' ;(+' !8*+'&


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IJ; !#j+ '"+' ;'i -j, !'6 3 'I+4 'c:

tT#j+ '"+' !86+4 '* +4

tT#j+ '"+' !86+4 '* '# # f|; !c; 8+ !9+4 ;r +'

Du% tr?nh !nk$l h{! .ng Et$lnDu% tr?nh !nk$l h{! .ng Et$ln


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11/09/15 27

Du% tr?nh 1h! lwngDu% tr?nh 1h! lwng@,c !8d+' *S- '.* # f|; !c; *f#! L#`QS'+4 `a FK+4

Z6#!

@,c !8d+' *S- '.* !8b+ f|; !c; Z6#! !86+4 '* +4

Du% tr?nh !nk$l h{! .ng Et$ln ttDu% tr?nh !nk$l h{! .ng Et$ln tt


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Du% tr?nh !lk$l h{! trn 5c t%c olit trong1h! lwngC+4 +4'2 '* +4 `a FK+4 f|; !c; Z6#! ! 9, IJ;

!'I+4 )(# '.* ! +p) /]]hQ+'" )c- 9, !#b+ w+ '"+' z#N#6+ %M ;i* N'w! Fn* !8b+ ;+4 +4'2 ;i* '+4 ABBL,)),` G6* *+F U+6;*Q;+4 +4'2 +"- `a FK+4 f|; !c;Z6#! Y " 49+ y- " Z6#! `#b, + +'

C+4 +4'2 EBM*f ;i* M6#tB*F48 Fn* !8b+ f|; !c;M6# MCMt33

Du% tr?nh !nk$l h{! .ng Et$ln ttDu% tr?nh !nk$l h{! .ng Et$ln tt

% ;+4 +4'2 ;i* 3 ;+4 +4'2 +"- !I+4 r# 4#r+4 +'*,:


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% ;+4 +4'2 ;i* 3 ;+4 +4'2 +"- !I+4 r# 4#r+4 +'*,:

igur 23aummu"Ve th$l.nvn 1roc""*_AS-*!#6+ 8*;!68 _ T8*+`*S-*!#6+ 8*;!68 ;_ B++ ;6,)+ F_ E!'-++;6,)+ _ P6-!'-++ ;6,)+& igurP3o.il B!&gr EB!5 1roc""*_ AS-*!#6+ 8*;!68 _ T8*+`*S-*!#6+ 8*;!68 ;_ B++ ;6,)+ F_ $+!t4*`;6,)+ _ E!'-++ ;6,)+ _ P6-!'-++ ;6,)+


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Du% tr?nh 1h! hyi

G) '*# X,c !8d+':

Du% tr?nh !lk$l h{! 5c t%c !5it ai",kh@ng"G &ng olit

Du% tr?nh !lk$l h{! 1h! hyi trn olit


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Du% tr?nh !lk$l h{! 5c t%c !5it ai",kh@ng"G &ng olit

Np) /]Rh ;. X,- !8d+' IJ; 'c! !8#m+ z# UOP Fn*!8b+ f|; !c; B7&

#, S#2+ w+ '"+':t N4,-b+ #2,:++ S'Q!-+ " B7t `,=! ;*6:3Q> 7Q> M*t N'#2! !'#j! 'e+ +4 !'=:/hh />h 6C

t N'#2! !'#j! ;',-m+ *S-: /vh 37h 6Cj! X,e !', IJ; !-++ ;. ++4 ]]Q]^


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11/09/15 32

Du% tr?nh !lk$l h{! 1h! hyi trn olit

Np) /]0hQ;+4 +4'2 ;i* M6#tB*F48 f,=! '#2+ "IJ; ;+4 +'w+ " ;+4 +4'2 *S- '.* !86+4 '* '#!'"+' ;+4 +'=! # f|; !c; Z6#! !+4 'J Z%Mt>, S#2+ w+ '"+':

tN4,-b+ #2, k! !-+ [/>^_t|; !c; Z%Mt> '6(! !k+' ;*6t `,=! : /t7 M*tN'#2! :


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11/09/15 33

Du% tr?nh !lk$l h{! 1h! hyi trn olit'( ") c*ng ngh:

igur 3Thir&gnr!tion o.il B!&gr th$l.nvn 1roc""*_*;!68tF '*!8 _ AS-*!#6+ 8*;!68 ;_ B++ 8;68- ;6,)+ F_E!'-++8;68- ;6,)+ _ P6-!'-+++ 8;68- ;6,)+ _ %;6+F*8- 8*;!68 4_ %!*##8


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11/09/15 34

4@ng ngh "n 5u6t Et$l.nvn mi hin n!$

C+4 +4'2 `e+ f,=! !-++ !86+4 '* '+'J IJ; I* 8* z# CD T;'Q" ;+4 !- #b+ 'J;i* ABB L,)),` G6* " C')#;* `*8;'

*+F L#;+`#+4&N'" )c- 9, !#b+ 8* # +p)/]]< " !# +p) /]]] ;. 7 'y+ fIz+4 # "6w+ '"+'

4@ h 6t Et l. i hi


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4@ng ngh "n 5u6t Et$l.nvn mi hin n!$% ;+4 +4'2

igur 34Tch th$l.nvn 1roc""*_ #+#`'#+4 8*;!68 _ T8*+`*S-*!68 ;_ AS-*!68 F_ B++ `!8#8 _E!'-++;6,)+ _ P6-!'-++ ;6,)+B g 6#8 F *!8Q PEB g 6-!'-++


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11/09/15 36

eh(n eh(n

jng &ng ) ch6t lFAng


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jng &ngjng &ng

x E!'-++ 49+ +'I ; X,-+ [\ ]]^_à FK+4 m è+ f,=! `!-8+ )6+6)8CA% N: /hhtQ CRH>CH g CH3

x H9, 'j! )6+6) `!-8+ [T` g /Q3hC_IJ; è+ f,=! +4 'I+4 'c F'-F86'.* !-++ '6l; " +4 è+ ') ;i*X,c !8d+' è+ f,=! 86-+ 6f-!


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jng &ng

xHg/3>o)6xP'e+ +4 " 'e+ +4 !',w+ +4';'Q!', +'#2! )(+'Q!p+4 !'m !k;'Q!'k;''J !#j+ '"+' z +'2! ;*6 c `,=! !'=

C ;'j 'e+ +4:


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jng &ng ttjng &ng tt

u! '+ /^ ;i* E!'-++ è+ f,=! IJ; à FK+4u! '+ /^ ;i* E!'-++ è+ f,=! IJ; à FK+4+'I )! !8,+4 4#*+ m è+ f,=! F#!'-++Q+'I )! !8,+4 4#*+ m è+ f,=! F#!'-++Q*;!6'+6+ " !'-*+!'8*X,#+6+Q +'I " )!*;!6'+6+ " !'-*+!'8*X,#+6+Q +'I " )!

!'"+' '9+ ;i* +'n* I+4 " +*'!'*Q " +'I )!!'"+' '9+ ;i* +'n* I+4 " +*'!'*Q " +'I )!;'=! ;'r+4 Sk;' + ;'=! 'K 4#* +'#b+ #2, ";'=! ;'r+4 Sk;' + ;'=! 'K 4#* +'#b+ #2, "4*`6#+`&4*`6#+`&

T86+4 +'+4 +4 FK+4 +'Q X,*+ !8+4 +'=! " !86+4T86+4 +'+4 +4 FK+4 +'Q X,*+ !8+4 +'=! " !86+4+4"+' ;+4 +4'#2 `+ 'i +'I " )! [-+ '++4"+' ;+4 +4'#2 `+ 'i +'I " )! [-+ '+'J_ F,+4 )# ;'6 `+Q S6 f!Q " ;+#&'J_ F,+4 )# ;'6 `+Q S6 f!Q " ;+#&


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11/09/15 40

4h6t lFAng4h6t lFAng

x * `r ;c; +'" `e+ f,=! fc; +' l; #m) Sq !',w!c+ '"+4 ;i* ' !'6 !#b, ;',+ Mq " !'a +4'#2)'I+4 'c A%TM D7/]7 T#b, ;',+ Sq !',w! r# #E!'-++ &

x Cc; !'+4 `r ;'k+' ;i* )! l; #m) Sq !',w! c+ '"+4!'+4 !'I+4 ": !r# !'#m, !#+' S'#j! ;i* ]]Q> !& ^$" !r# * )", `; ;i* /h !8b+ ;c;tC6*! @,- )

P*!#+,)!86+4 S'# ;c; !( ;'=! X,- +' " ++4 ;i*' 'K !',; "6 !8d+' `e+ f,=! ") #2;Q ;?+4 # ;c;l; !k+' '#2, `,=! ;y- !8+4&


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11/09/15 41

4%c kh|! cnh kinh t

C. ]]^ E!'-++ IJ; à FK+4 m IJ; è+ f,=!`!-8+ )6+6)8 !8b+ !6"+ !'j 4##&

N'+4 +p) /]Rh " 9, +'+4 +p) /]0h ! 2 !p+4!8Iz+4 '"+4 +p) ;i* `!-8+ " E!'-++ !8,+4

d+' /h^&'6e+4 />^ ;i* E!'-++ IJ; !#b, !'K !86+4 è+f,=! 'J !c; ;i* `!-8+ " 6f#! 86-+& Cc; +'" )c-

+"- ;,+4 ;= )! J# !'j S#+' !j d 4#c !8 ;i* è+ ')86-+ 6f#! +4&%e+ f,=! +'#, !(# ;c; +'" )c- z H" L*+Q Ty- B*+ N'*Q

N'w! Be+Q %#+4*68Q H"+ @,r; " H6* 1&

4%c kh|! cnh kinh t


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4%c kh|! cnh kinh tNp) /]]] !8b+ !6"+ !'j 4## ;+4`,=! [!86+4 /h7 ! o *_ !'6 ?+4 +'I `*,:

N68!' A)8#;* 00hh%6,!' A)8#;* 77h

`!8+ E,86 >]hh

E*`!8+ E,86 /7hh68*oT*#*+oC'#+* 7vhh

**+ 7>hh

M#FF E*`! *+F A8#;* Rvh%6,!'*`! A`#*oA,`!8*#* >hh

%ota" 3< 0hh


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11/09/15 43

Phn -:Phn -:

.n t/n m0i t12n3


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O3@i trFHngO3@i trFHng

x E!'-++ 4#e) +'*+' ;'.+4 !86+4)# !8I+4 S'+4 ;. V +4'W* `#+' ';

!k;' -& N. +# !8b+ )l! +I; " +'*+';'.+4 *- '#&

x T'6 ;'{ !' EU E!'-++ '#2+

S'+4 'y+ 6(# " +4,- '(# ;'6 )#!8I+4&


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11/09/15 45

234on ngFHi234on ngFHi

x T'6 ;'{ !' EU ;c; ;'=! +4,- '#m) e+' 'Iz+4 j+`; S' !'d E!'-++ IJ; 'y+ 6(# " S'k ;. '(#S'# 'k!& Nj, 'k! '# E!'-++ ++4 ;*6 !86+4!'# 4#*+ F"# ;. !'m 4y- 8* ;'.+4 )l!) +'; 9,Q ,+

+4iQ ,+ ++ " )=! 'r# 'J&x $ !d+' p+ 'e# S'+4 4y- !'I+4 !k;' +'I+4 +j, +,r!

)! I+4 + ;. !'m 4y- !a 6+4&

xE!-++ ;. !'m 4y- Sk;' +4 +' j+ !8,+4 d+'j+ F* " )!& T'I+4 f,-b+ !#j f|; ` F+ j+ S'F* " #b) F*&


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11/09/15 46

eh(n eh(n

G l ) .o qun


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O3G lO3G l

x T8c+' !#j f|; # F*Q )! " X,9+ c6& C'{ `aFK+4 +# !'+4 4#. !r!&

x E!'-++ '# ;. !'m !(6 !'"+' '+ 'J + #S'+4 S'k& Cc; 4## '(+ + !86+4 S'+4 S'k [ z c`,=! S'k X,-m+ Q 6 !(# /


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11/09/15 48

O3G l ttO3G l tt

x E!'-++ " )! ;'=! +4 F5 ;'c-;*6Q +'#2! ;' ;'c- /> 3h 6C dw- 'e# fa V +'#2! )# !8I+4 f,+4

X,*+'Q !8c+' f* c+' ++4 )l! !8# !8n;!#j " ;c; +4,+ +'#2!&x E!'-++ ;. !'m !k;' !K !W+' #2+ F6

. 'e# ;'| V j+ ;c; #2+ 'c ;'r+4 (#!W+' f [ !#* a* 4y- +4,- '#m)_&


49/50

11/09/15 49

23Bo qun23Bo qun

x Be6 X,e+ !86+4 !'?+4 ;'* `a FK+4 !'S'+4 4{Q S) f##;*!Q +'n* 6f-&

x '+4 '? 'J # +4,-b+ w! #2, ,!-Q;*6 `, N68+ '6l; +#!8# !n +'#b+ "'9, 'j! ;c; `e+ ') +'n*&


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XIN CHN THNH CM N!

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