kpfu.rukpfu.ru/staff_files/F1120146825/sbornik.pdfРоссийское химическое общество им. Д. И. Менделеева Российская академия

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, . , , , , . : 1. S. Cosnier, A. Le Goff, M. Holzinger // Electrochemistry Communications 38 (2014) 19-23 2. .. , .. , .. . // . 1986. . 22. . 742. 3. M.R. Tarasevich //Bioelectrochemistry and Bioenergetics 6 (1979) 587-597 4. M.R. Tarasevich, Yu.G. Chirkov, V.A. Bogdanovskaya, A.V. Kapustin//Electrochimica Acta 51 (2005) 418426

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Ni . // . ., 2010, 18, 3. C. 41-47.

2. .., .., .. - . // . . ., 2010. 8 . 545-510.

3. .., .., .., .. - . // . . ., 2011. 4 . 18-24.

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1 High-performance Cu/MgONa catalyst for methanol synthesis via

ethyl formate / Baoshan Hu, Kaoru Fujimoto // Appl Catal A-Gen. 346. 2008. . 174178

2 Application of water vapor-permselective aluminasilica composite membrane in methanol synthesis process to enhance CO2 hydrogenation and catalyst life time / Farsi M., Jahanmiri A. // Ind Eng Chem Res. 18. 2012. . 10881095

3 Liquid-phase methanol synthesis in apolar (squalane) and polar (tetraethylene glycol dimethylether) solvents / Gerard P. van der Laan, Antonie A.C.M. Beenackers, Baiquan Ding, Johan C. Strikwerda // Catal Today. 48. 1999. . 93-100

5 R. Quinn, T.A. Dahl, B.A. Toseland An evaluation of synthesis gas contaminants as methanol synthesis catalyst poisons // Appl Catal A-Gen - 272. - 2004 - . 6168

19

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5. . ., . ., . ., . ., . . // , 2014. 7. . 37-40.

23

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.. , 119991, , ., . 65, . 1, . 84995078157, e-mail [email protected],

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3StrasbourgUniversity, 25 RueBecquerel 67087 Strasbourg, France

() Nd1-xCaxCoO4 La1-xSrxCoO4 (x=1; 0.75), [1-5]. . NdCaCoO3.96, - 100% 85-90%.

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25

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, 1422,

5.1661.2014/K, 13-03-12406, 13-03-00381 14-13-01007.

. 1. .., .., .., ..,

.., .., .., .. - : , , . // . 2013. 12. . 716-722.

2. . . , . . , . . , . . , .. , . . , . . . NdCaCoO4 -. // . 2013. . 87. 12. . 20092015

3. O.A. Shlyakhtin, G.N. Mazo, S.A. Malyshev, L.N. Kolchina, A.V. Knotko, A.S. Loktev, A.G. Dedov. Cryogel synthesis and solid state reactivity of NdCaCoO4 // Materials Research Bulletin. 2013. V. 48. 1. P. 245249.

4. O.A. Shlyakhtin, G.N. Mazo, M.S. Kaluzhskikh, D.A. Komissarenko, A.S. Loktev, A.G. Dedov. Compositional boundaries of Nd2 xCaxCoO4 at 9001200 C // Materials Letters. 2012. V. 75. P. 20-22.

5. .. , .. , .. , .. , .. , .. , .. , .. , .. , .. , .. . -.// . 2011. . 441. 5. . 635-638.

6. R. Lago, G. Bini, M.A. Pena, J.L.G. Fierro, J. Catal. 167 (1997) 198-209.

26

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28

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30

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31

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, . , . , . :

1. Olthuis W. Chemical and Physical FET - based Sensors or variations on an equation. Actuator B105, 2005. P. 96-103.

2. .., .., .., .. . VIII ... , . : . 2011. .414-422.

3. Bidisa Sengupta and Pradeep K. Sengupta The interraction of quersitin with human serum albumin: fluorescence spectroscopic studies. Biochemical and Biophysical Research Comunications 299(2002) 400-403.

32

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33

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36

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2. .., .., .., .., .. . 2470004, . .. 35 20.12.2012 .

, % . . . ,

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38

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[1]. [1]:

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))/1(ln())(ln( fN = : ))/1(ln(/))((ln( dNd . -

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39

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1. .., .., .., ... . .: , 1992. 544.

40

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42

. , , . , , , , , [8].

- () . , , , , , .

1. .. . .: . 2013.

248 . 2. .., ..

. .: . 1978. 312 . 3. Atomic Spectroscopy in Elemental Analysis. /Ed.: M. Cullen. Blackwell

Sheffield Academic Press. 2003. 310 p. 4. . . . I.

/. .. . , 2002. 964 . 5. .., .. /

// .2011. . 19. 4. . 4753; 2012. . 20. 1. . 3954.

6. - / . ... 2 . .: . 2012. .1. 352 . .2. 416 .

7. http://www.fgosvo.ru ( : 14.05.2014).

8. .. // . 2014. . XXVIII.

http://www.kalahari.co.ke/page_templates/searchresults.aspx?qs=MHxFbnRpdHlfRW5nbGlzaHxNaWNoYWVsIEN1bGxlbiB8fDB8MHwxfDI1fHx8TWFya2V0UGxhY2VBdmFpbGFiaWxpdHlUeXBlfEZvcm1hdF9FbmdfRmFjZXR8RGVsaXZlcnlEYXlzfFByaWNlfHx8&displayShop=home&navigationid=1http://www.fgosvo.ru/

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. .

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q1a1.1a1.2a1.3a1.4a1.5a1.6a1.7a1.8a1.9a1.10a1.11a1.12a1.13q2a2.1a2.2a2.3a2.4q3a3.1a3.2a3.3a3.4q4a4.1a4.2a4.3a4.4

q1a1.1a1.2a1.3a1.4a1.5

n

55

, - (. 1.) - : ; ; , IDEF0, CALS . - . 4.

. 4. - - : ; - ; ; ; ; .

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: ; 1995, - 345 . 2. .., ..

// , 2014, 1. .64-73.

3. .., .. // , 2014, 48, 6.

4. .. // , 2013, 6. .24-44.

5. .. // , 2014, 5. .32-43. 3 ... ..

58

662.99

.. 1,2, .. 1,3, .. 1, .. 1*

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2) . ; 3)

125047, , . 9, : (499) 978-89-23, e-mail: [email protected]

() , , .

[1] , - . () , , , - , :

; ; j- (, , , ) i- ti; , ; , , = const.

() , , . .

[1, 2] , , .

https://www.google.ru/url?sa=t&rct=j&q=&esrc=s&source=web&cd=3&cad=rja&uact=8&ved=0CCgQFjAC&url=http%3A%2F%2Fwww.gazprom.ru%2Fabout%2Fsubsidiaries%2Flist-items%2Fgazprom-transgaz-kazan%2F&ei=jTQpVPHFNILzoAT0poL4DQ&usg=AFQjCNFRcN61damqhouHZs5Kx257TSPq0Q&bvm=bv.76247554,d.cGUmailto:[email protected]

59

-.

[3].

1. . (N) , , (Q..) QT/N, QT , . N , QT. N, QT, Q..

2. , QT Q.. - , .

3. , . , - ().

[4] - (). . .

[5] . .

[13]. 0 1 , . .

[5 - 8]

60

(1)

; ;

; n; , .

, , (1) (2)

; ( ).

, , (1), (2)

(3) ,

( ), , , (2) :

(4) ,

(CT = const), (2) [7]

. . i-ro j- :

(5) ; ;

(6)

; z ; kT (kT, = const);

, Q ;

(7) ; ; - ; .

61

, - .

[8] , . .

[9]

(8) Ci ; ; n- .

( ) , . . , . , .

[10, 11] . [11] [12]. .

[11, 13, 14] .

[11] : 1) ; 2) . : . .

[13] , ,

62

. .

. - , , S . S- (Q1,Q2,,Q8) R8, , Q1>Q2>>Q8.

[7] . , : 1) , ; 2) .

ij- . ij- i- j- , , j- i- . ij - i- (j - ) , () . [16, 17], . . . .

1. Hwa C.S. mathematical formulation and optimization of heat exchanger networks using separable programming // AiChE Chem. E. Symposium Series. 1965. 4. P. 101-105.

2. Kesler M.G., Parker R.O. Optimal networks of heat exchange // Chem. Eng. Progr. Symp. Ser. 1969. Vol. 65. 92. P 111 120.

63

3. Kobayashi S., Umdea F. Ichikawa A. Synthesis of optimal heat exchange systems an approach by the optimal assignment problem in linear programming// Chem. Eng. Sci. 1971. Vol. 26. 9. P. 1367 -1380.

4. .. - : . . . . . ., 1974.

5. El-Sayed Y.M., Evans R.B. Thermoecomics and the design of heat systems // Transaction of the ASME. Journal of Engineering for Power. 1970. Janary. P. 27-35.

6. El-Sayed Y.M., Aplenc A.J. Application of the thermoeconomics approach to the analysis and optimization of vapour-compression desalting System // Transaction of the ASME. Journal of Engineering for Power. 1970. Janary. 1. P. 17-27.

7. .. : . . . . . ., 1978.

8. .., .. .. - - // . . . . . 1983. .2.. 3- 103.

9. .. .., .. // . . . . 1979 2. . 87-92.

10. .., .. // . . . 1981. . 15. 1. . 1-3.

11. Sophas A., Rotstein E., Stephanopoulos G. Therodynamic bounds and selection of technologies in petrochemical industry // Chem. Eng. Sci. 1980. Vol. 35. 5 P. 1049-1065.

12. .., .., .. . .: , 1988.

13. . - : . . . . . ., 1981.

14. .., ., - . . .: , 1984.

15. Umeda F., Shingo A., Ichikawa A. Process synthesis task assignment // Chem. Eng. Sci. 1974. Vol. 29. 10. P. 2033 -2051.

16. .. : . . . . . . . ., 1981.

17. Lothar R., Klaus H. Optimal Dimisionierung von Warmeubertragungssystemen mit belibig vielen Hiz- und kublsomen // Chem. Tech. 1975. Bd 27. 8. P 439-442.

64

.695; 546.85; 502.55; 661.63

.. 1*, .. 2, .. 2, . 2 , .. . 1, .. 2, .. 1,

.. 1, .. 1, .. 2, .. 1

1 . .. , 420088,. 8, . , . -mail: [email protected]

2 () , 420008, . , . , .18.

4

[1]. , , , , . , . , . , . , .

() . . 0.1% , , , . , . 4 0.01% , , , 23 , , . P4 0.01% () 31 35 . , . , 35 P4 . 63 . , 4. ,


65

63 0.01% [2, 3].

0.01% 4 . . Streptomyces [3, 4]. , , , . , , , , . , 0.1% 4 Bacillus (Bacillus subtilis, B. subtilis var. mesentericus, B. cereus B. macerans) [5].

, [6] , , . , , . . , : , . 240 . 223 , - . , . .

31 , , . , , , , , .., . , , , [5, 7]. , .

, .

66

, , . . . . , , , ! .

. , . , P4, . .

( 14-08-31091 -).

1). .., .., .. : // . 2013. . 33. 2. . 117. 2). .., .., .., .., ., .., .., .., .. // .. . -. . . . 2011. .153. .2. .110-119. 3). .., .., .., ., .., .., .., .., .. // . 2013. .33. 1. .22-34. 4). ., .., .., .. , // . 2014. . 38. 4. . 5). .., .., .., .., .., .., .., .., .. 0.1% // . - 2014. - . 37. - 3. . 67-78. 6). .., .., .., .., .., .. // . 2013..36. 10. . 1-12. 7). .., .., .., ., .., .., .., .., .. // . 2013. .36. 12. . 34-52.

67

.006.1

. . , ..

- ...

125047 , ., 9, .+7(499)9734792 , e-mail: [email protected]

, , . , . , , , , . , -, . ().

, ( (), (), (), ()) .

, , .

, , , ..

,


68

, .. , , .

, , , , .

() (, , ; ). () (, , , ), -. 1 2014 . 2 2, (NACE Rev.2 CPA 2008). ( 1 2015 . ). 1 2015 . (. 1.), (. 1.1.), , , (), () ().

2014 . 2 2001 2007 .

2 (, , ) . . 1.1, , . () () .

, , , , , .

2 , . ,

69

. , 20.15 , 20.15 - . , , .

2 2 , , - .

, , .

70

541.11 -

*. . 1, . . 1, . . 2,3

1 , 199106, -, , . 15 , .(812)322-39-33, (812)322-39-22, , e-mail: [email protected];

2- , 191186, -, , 18;

3- . .. (),197376,

-, . , 5.

. , , .

, (>6), , . >9 , .. . , . , (6) (pKb>6) ; 4) () .

71

, 10-4 . - ( ). , .

Ka (KBH+), A- (BH+) , X. CO2 , , , .

. : NaOH, Na2CO3 + HCl; Na2CO3 + HCl; NaOH + HCl; NaOH + HCl ; Na2CO3 + AcOH ; Et3N + HCl ; Et3N + AcOH, 210-5 .

. L , (Y Na2CO3 , C HA), (1 2) (X) :

Kw, K1, K2 i, A-

. . (1) .

(H++OH-), (H++Cl-), (Na++Cl-), (H+-Na+), (H++HCO3-), (H++CO3--), (H++Ac-), (Et3N++Cl-) (KEt3N+, KAcOH), (Kc1 Kc2).

, , , , , , , ( 1).

72

1. ,

(-)

100/,

K100K/K, (pKa)

(0, pKa)

Na2CO3 (H++PhO-) KPhOH

368.30.43% 1.1510-101.1% (9.94)

9.99 [1] 9.99 [2]

Na2CO3 3- (H++PhO-) K3NO2PhOH

379.00.15% 4.8510-91.2% (8.31)

8.36 [1] 8.36 [2]

HCl (An++Cl-) KAn+ 111.34.0% 2.5410-52.4% (4.60)

4.87 [1] 4.60 [2]

HCl (Qn++Cl-) KQn+ 109.52.0% 1.2910-51.6% (4.89)

4.90 [1] 4.80 [2]

NaOH + HCl

(Gly++Cl-) KGly+ (H++Gly-) KGly

8527% 3.410-318% (2.47) 392.43.8% 1.9710-102.8% (9.71)

2.34 [1] 2.34 [2]

9.78 [1] 9.60 [2]

NaOH + L- HCl

(Trp++Cl-) KTrp+ (H++Trp-) Trp

9430% 3.310-316% (2.48) 361.50.26% 2.8910-101.6% (9.54)

2.46 [1] 2.38 [2]

9.41 [1] 9.39 [2]

NaOH + 4--

HCl

(Aba++Cl-) KAba+ (H++Aba-) KAba

11128% 4.510-321% (2.35) 374.90.35% 1.4110-51.3% (4.85)

2.50 [1] 2.41 [2]

4.87 [1] 4.85 [2]

( 50% ) , .

[1] CRC handbook of chemistry and physics. / Ed. by Lide D.R. - 85 th. Ed. - Boca Raton: CRC Press, 2005. - 2664 p. [2] Lange's Handbook of Chemistry. / Ed. by Dean J.A. - 15th. Ed. - McGrawHill, 1999. - 1424 p.

73

544.723:66.065.2 -

.. *, .. , ..

. .. 119991, -1, , , 31; .: (495)9547138,

:(495)9541279, E-mail: [email protected]

. . , . , , [1]. [2].

.

V = 300 ( ) 100 ( ). 10 400 /. . 1 40 /. , , . , 15 , . 2 ( ) ( ). , .

. , - .

.


74

. , , , . , -- , . . ( pH), . , () Ce qe ( ). 1-3 , . 4 . ( ) , 1 3. . , .

Ce/qe () Ce : 1 m = 12 , 2 1.5, 3 m = 0.3 ; 4 0 = 100 /, m = var = 0.3 12 . C -

E. , E

75

10 14 /. , ( , ).

, 0 = 100400 / m/V 1 /, ( 16.8 /), ( 28.7 /, 22 /) ( 8.2 /).

[2]. . , [3]. . , ( ) 100 7 /. , , 1.5 /. , . (0.5-1 ) 300 / 1 /.

: 1. Fu Fenglian. Removal of heavy metal ions from wastewaters: A review / Fenglian Fu, Qi Wang // Journal of Environmental Management, 2011. V. 92. P. 407418. 2. Sevil Veli. Adsorption of copper and zinc from aqueous solution by using natural clay / Sevil Veli, Bilge Alyz // Journal of Hazardous Materials, 2007. V 149. P. 226-233. 3. .. / .., .., .. // 4- . .. , . 1., 2012. , . .. . . 99101.

76

534-8

.. , .. *, .. , ..

()

. .. , 659305, ., . , 27,

/ (3854) 43-25-70, e-mail: [email protected]

() . (, , , , , , , ..), 0,0012 [1-4].

, [3-5].

( 30 ) [3-7].

, (, , .) ( 2 ), , ( ), [1, 3, 8]. , :

.

, ( 5 ).

,

77

, . , ( ) (, , ) [8-9].

, - , , .

, [3, 4, 10], , ( ). 7 [3, 5] : 1) , ; 2) , , ; , .

, [4,8,9], , , , [9].

, [4, 9] (, , , , . .), , , , .

, , ,

78

, .

, , , , .

14-08-31521

1. , .. [] / .. , .. , .. // . . 2005. 2.

2. [ ] / Dow Europe GmbH. : http://msdssearch.dow.com/PublishedLiteratureDOWCOM/dh_04d9/0901b803804d9c23.pdf?filepath=/296-01841.pdf&fromPage=GetDoc.

3. , .. [] / .. [ .] // 3/2010/ ... -. : - . . . -, 2010. . 321-325.

4. [] / . .. . .:, 1968. 268 .

5. , .. , [] / .. [ .] : - . . . -, 2007. 400 .

6. [ ]. : http://www.utinlab.ru/.

7. Hielscher - Ultrasound Technology [ ]. : www.hielscher.com.

8. , .. / .. [ .] // . 2010. 4. . 58-62.

9. Khmelev, S.S. The influence of viscosity on the formation of cavitation zone in liquid media / S.S. Khmelev, V.N. Khmelev, R.N. Golykh // Archives des sciences. Switzerland, Geneva, 2013. Vol. 66(2). pp. 471-481.

10. , .. [] / .. . .: , 1986. 300 .

http://kias.rfbr.ru/Application.aspx?id=5705613

79

2.

,

546.72:669.17/669.181.2

.. *, .. , .. , .. ,

..

. .. ,, Az-1143, . . 113, .: 012-596-24-82, : 012-510-85-93, e-mail: [email protected]

. , , , . : Fe 13-15%, TiO2 2,3-3,0%, V 0,6% Mn 0,7%. , 54% Fe , 7% TiO2, 1%V 0,8% Mn , , , . , 5-7 . 875-9000 97-98% . : -, (II), ,


80

., : Fe34+Na23 = 2NaFeO2 + FeO + CO2 2NaFeO2 + CH4 = Fe + FeO + Na23 + 2H2 2NaFeO2 + CH4 = 2Fe + Na23+ H2 + H2 , , , , .

-, , , , , , , . , , , , , , - .

-, , .

, , .

.

, 0,1 Na2CO3 . 875 9000 . 60 700 (:=1:4), , 85 900 1 . 1000 - . 500 .

81

, 98%. F 98%, TiO2 38-40%.

TiO2 98% V2O5 - .

82

621.785.533 -

.. *, .. , .. , ..

. .. , 156961, , . 1 , 14. (4942) 391601, (4942) 311322,

E-mail: [email protected]

- () / , ( , , ). , , , , , , . , , . , , . , , , () . , : , . , . , , .

. , , . , ( ) .

,


83

. , , , , , . 1. , , . , 15% , . 2. , , .

. 1. (1), (2) (3) 5 850 , 10 .%

EDX- (0,50,9 .%) , . . ,

84

. , 4050 , , , .

, , , . , , . Ra = 0,11 5 750 , 10% .

.

- -

.

. 2. (1), (2) (3) 5 850 , 10 .%

85

666.11.016.2

.. 1, .. 1*, .. 2

1 , . , 13, 220006, . , , +375 17 327 43 08;

[email protected] 1

.. , - , 48, 246746, . ,

. . , , , . , , . , , .

, , . . . .

:

450 530 ;

600 650 ;

( (80 100)10-7 -1); 3- . 1,6 ( ).

(Bi2O3B2O3), .

86

622,646, 648 696 , 675, 722 708 . , Bi2O3 . . Bi2O3B2O3ZnO, Bi2O3B2O3O Bi2O3B2O3ZnO K2O. .

Bi2O3B2O3ZnO Bi2O3B2O3O Bi2O3B2O3ZnO

, 10001100 9501000 9501050 , 460500 460480

485

, 630650 590630

635

, . 107 1 8690 9398 96 () 1,641,68 1,721,735

1,727

, ( 10134.0) III III III

Bi2O3B2O3O, , , , .

, -. - , YAG: d0~ 5060 Bi2O3B2O3O : 70: 30; 75 : 25; 80 : 20; 85 :15. . . 600650 30 . , ,

87

. - , . , - (=450 , W =1 ) - -; , -, ( 2 ) .

- . , Foryard, = 470 ( : = 0,151; = 0,114) - ( : = 0,3024; = 0,334). 9 . , , ().

, , 30 %.

.

, 1

88

Fe (III)

.. 1*, .. 2

1 , , 8104, .

e-mail: [email protected] 2

, 7200, . , 47 e-mail: [email protected]

Fe (III)

, . - . 5 (5) . Cl- C2Cl4 (). Cl- - . .1, .1.

1. , , , , .

m3/h HCl ppm

H2O ppm

H2S ppm

CH3OH* ppm

** t%

100 0.9 8 0.4 4 0.4 100 0.8 8 0.2 4 0.4 100 1 8 0.3 4 0.4 95 0.5 8 0.2 4 0.4 95 0.9 8 0.4 6 0.4 95 0.8 8 0.2 7 0.4 95 0.9 8 0.3 8 0.4 95 1 8 0.4 8 0.4 95 0.8 9 0.3 8 0.4 95 1 9 0.4 8 0.4 95 0.7 9 0.2 5 0.5 95 1.2 10 0.3 5 0.5 95 0.5 9 0.2 5 0.5

* ** .


89

. 1. .

CH3OH 5 . . .2 , .3 - . .4 .

. 2. : ;

3. : ; - -

4.

90

9, 10 3 (.1 .1). Cl- , FeCl2 CCln. 3 . FeCCl2+n. . . 45 , 650 . , .

, Fe (III) Fe2O3, . (.2). (d, nm): 0,369(8) - 0,335(10) - 0,168(8) - 0,123(9) - 0,115(9) , .

.

91

621.785.533

-

.. *, .. , .. , ..

. .. , 156961, , . 1 , 14. (4942) 391601, (4942) 311322,

E-mail: [email protected]

- , , , . .

- () , .

/ , . , , , () . , : , . , . , , .

, , , , . .

,


92

.

, (5%), (12%) (15%) 850, , , , . , , .

, (. 1).

. 1. (I) (II) 850 , (5%), (12%) (15%)

( ), . . , , . , , .

- . ,

93

, . . .

. , , . CO2 CO. , , .

, , , :

CH3CH=O + NH3 CH3CH=NH + H2O (1) CH3CH=NH CH3CN + H2 (2)

. -

20 , (. 2).

. 2. 20 850 5 , (5%), (12%) (15%) : 1 , 2 , 3 , 4 -

.- -

.

94

621.039.7.14325:543.544-414

(IV)

.. , .. , .. *

. .. , , ., 184209, , 26, . (81555)79549,

(81555)61658, e-mail [email protected]

(), , 134,137Cs, 90Sr, 60. . , .

(IV) P:Ti(IV)1 TiO(1+x)()2(1-x-y)(HPO4)ynH2O, , -, , - , .

(IV) () (). , (IV) - , Fe(III) Zr(IV), (K) , RH + 1/zMz+ H+ + 1/zMRz (R , Mz+ ), .


95

(IV)

, --1 -lgK()

Na+ Cs+ Sr2+ Na+ Cs+ Sr2+ 2+

TiOHPO46.30H2O 3.59 3.68 3.62 2.94 1.80 2.39

TiOHPO43.17H2O 4.62 4.64 4.57 3.14 1.60 2.60 2.74

TiO(OH)0.24(HPO4)0.881.89H2O 3.10 3.49 2.36 2.26 1.48 1.76

Fe0.07(TiO)1.035(OH)0.14(HPO4)2.88H2O 3.98 4.05 3.76 2.46 1.75 2.24

Fe0.1(TiO)(OH)0.3(HPO4)2.25H2O 4.34 4.46 4.22 2.32 1.52 1.94

Zr0.25(TiO1.25)(OH)0.5(HPO4)1.33H2O 4.11 4.10 3.94 2.20 1.28 1.65

Zr0.1(TiO)(OH)0.4(HPO4)1.76H2O 4.63 4.82 4.48 2.36 1.34 1.72 1.80

TiOHPO4nH2O 200C , 660C (IV) . , MITiOPO4 (MI ) (. 1). , , (. 2).

I, .. I, ..

d, d,

. 1. Na+ () Cs+ () TiOHPO43.17H2O

96

I, ..

d, . 2. Co2+ Zr0.1(TiO)(OH)0.4(HPO4)1.76H2O 300C

, , , 7 pH 4 8 . , .

, (IV) , .

( 12-08-00944-), 8 ,

, (-487.2014.3).

97

: 616.71; 548.5 -

.. *, ..

, 690022, . , . 100- , 159, . (423) 2-215-288, -mail: [email protected]

,

, . . . - , .

- . , , [1]. pH, - , [2]. , , . , in vivo [3]. . , . , , .

() () : 3(4)2 + C(24)22 + 72 4422.


98

Ca/P , .

, : = 1:1() 24 422 (); : = 1,5:1() : 422 + 10(4)6()2 ( + ). , , . 30% (). , , , , 6,3 ( : = 1,5:1). Si , , , [4], .

. , () . . 2.

2. - .

.

, %

, %

/, /

.

(25, 80% ..),

,

1 64.87 35.13 90 10 0.8 180 11.7 2 64.87 35.13 90 10 1.2 15 16.1 3 64.87 35.13 90 10 1.6 2 6.1 4 64.87 35.13 95 5 1.4 5 14 5 64.87 35.13 80 20 1.2 25 6.2

6 * 64.87 35.13 100 - 1.2 2 2 * .

pH

, pH, , .. 6,0-6,7. , / 5 20 . 3-4 , 6-16 . ,

99

2-12 [5], , . 6, , 2 . .

- , . , , , . 2 . . 5 -10% . , , , [6].

1. Apelt D., Theiss F., El-Warrak A.O. et al. In vivo behavior of three different injectable hydraulic calcium phosphate cements. // Biomaterials. 2004. V. 25. P. 1439-1451.

2. .., .. : . // : , , . 2013. .4. 1. .24-47.

3. .., .., .. . // . . . 2004. . XLVIII. 4. . 52-64.

4. .., .., .., .., .. . // . 2007. . 52. 10. . 1594-1599.

5. .. . // . 2010. .79. 1. . 15-31.

6. Li Y., Li Q., Zhu S., Luo E., Li J. The effect of strontium-substituted hydroxyapatite coating on implant fixation in ovariectomized rats. // Biomaterials. 2010. V. 31. 34. P. 9006-9014.

100

669.162.28

.. *, .. , .. , ..

. .. ,

119991, -1, , ., 49, 8-499-135-71-70, [email protected], [email protected]

. , , - . , . , , , . , , , . , 50 % TiO2 50% SiO2. , .

, 45% TiO2, 45% SiO2 10% , >2000 : TiO2 , SiO . 100 , . , : 100 , 77 , 40 . 150 3 , -1601 150 . , .

101

-300 . 40 , 30. . , , , . 6104 /, , .

1 53,3 % TiO2, 40,2 % SiO2 Fe2O3 Al2O3. 293 . 38,6 , 90 5 . . 15 8 10 . . .

0,5 . .

. , , 200 25 8 . 400 60 2 . 1 . , -, , . . , , .

: = 1 . px = 0,7 . , 30 .3 1,25

102

. , , 35 .

206,8 , 2 40,5 . 20 .. 55,0 . . 5 . 29,0 , 72,67 2/. , , , 5,8 ( 2 %).

(Ti3O5); , , . , SiO2 Si. , .

, , 81 %.

1. ..

. . .. 75 , ., , 2013, . 37 59.

2. .., . ., .. . ., , 1978, 560 .

3. .. - . . ., . .. , 2005, 47 .

4. .., .., .. . 2513327 17.02.2014, 7 .

5. .., .., .., .., .. - - . , 2011, 5, . 21 27.

103

621.357

.. , .. *, ..

- .., , 125047 , ., 9, . +7-499-978-85-03,

[email protected]

. , , () . .

, .

, . , (. 1). , , , .

. , . .

104

. 1. .

1. l/h = 2,35; 2. l/h = 1,8; 3. l/h = 1,3; 4. l/h = 1,1; 5. l/h = 0,7 .

/ , 1 2. ( 20-30%) , b=a1+a2. , , , 10%. , , . . , , , , .

.

( 13_03_00451).

105

. . *, .. , ..

, 7200, . , 47


(H4Al2Si2O9) - 75 %. Al2O3 - 39.50%, SiO2 - 46.54% H2O - 13.96%. .

, , 1-2, 2,5 g/cm3. (K2O.Al2O3.6SiO2) , (Na2O.Al2O3.6SiO2) :

2(KAlSi3O8) + 2H2O + CO2 Al2O3.2SiO2.2H2O + 4SiO2 + K2CO3

2(NaAlSi3O8) + 2H2O + CO2 Al2O3.2SiO2.2H2O + 4SiO2 + Na2CO3 : 550-600 Al2O3.2SiO2.2H2O Al2O3.2SiO2 + 22 1100-1250 3(Al2O3.2SiO2) 3Al2O3.2SiO2 + 4SiO2

: Al2O3.2SiO2.2H2O

550-600 Al2O3.2SiO2

950-1000 2Al2O3.3SiO2/./ SiO2 +-Al2O3

1000-1100 3Al2O3.2SiO2

1200-1350

3Al2O3.2SiO2 SiO2 .

,

106

80-90% 15% (, , Fe. Ti, Ca, Mg ) 900-1000 (). . .

: 1000, 1100, 1200, 1250, 1300, 1350 .1. . 1 , .

.

1000

1100

1200

1250

1300

1350

1..% SiO2 Al2O3 Fe2O3 TiO2 CaO MgO K2O Na2O L.o.i

51.80 33.41 1.00 0.26 0.14 0.26 1.08 0.16 11.87

58.76 37.60 1.12 0.28 0.16 0.28 1.20 0.18 0.40

58.76 37.65 1.12 0.28 0.16 0.28 1.20 0.18 0.35

58.74 37.65 1.13 0.29 0.16 0.28 1.21 0.18 0.31

58.75 37.65 1.13 0.29 0.16 0.28 1.22 0.18 0.27

58.76 37.73 1.13 0.29 0.17 0.29 1.22 0.18 0.25

58.75 37.76 1.13 0.29 0.17 0.29 1.22 0.18 0.20

2.- ,%

31.65 26.70 12.37 8.00 5.75 2.75

3.

K80% I 8% Q 9 % O 3%

Q-30% -70%

Q-25 * -52% -23%

Q-16% -9% -31% -44%

Q-11 -19% -25% -45%

Q-8% -21% -25% -46%

3. TAlpha 10-6K-1,500-600

7.76

6.51

6.23

6.06

- - O - Q - - //

C - - I - / C*-

:

1000 / 70 % + 30 %/;

1100 / 23 % + / 52 % + 25 %/;

107

1200 / 44 % + / 9 % + 31 % + 16 %/;

1250 / 45 % + / 19 % + 25% + / 11 %/;

1300 / 46 % + % / 21 %/ + 25 % + / 8 %/ - .

, .1.

.1

,

30200 .

, 6 22%. 6 %, 30200 9,010-6, 14 % - 10,510-6.

, 14 %.

30200 = 10,511,010-6 ( ) .

108

:546.830.055(02)7

. . *, . . , . , ... , . . , . .

- . . . ;

125047, . , ., . 9; / +7 495 495-21-26; e-mail:[email protected]

, , . , , , . , [1].

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, (30% .) , , .

[3]. . . . . . .


109

() . , .

. 5 12 , .

40000 , - (. 1). 1 , .

. 1. , - ,

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2.

.

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110

15 (5 , 10 ).

. 3.

,

300 . , , , , , , , .

, . (30%) . .

14-19-00522.

. . . .

1. Keshri A.K., Huang J., Singh V., Choi W., Seal S., Agarwal A., // Carbon,

2010, 48, 431442. 2. Inam F., Peijs T., Reece M.J., // Journal of the European Ceramic Society

2011, 31, 15, 2853-2859. 3. .., .., .., ..,

.., .., . // . 2011 3. . 12-16.

111

546.830.055(02)7 ,

: , ,

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, , . , () , . , , , . , .

Al2O3-, -Al2O3 8 2/ - . , , . ( 5% ) . 8-27, 10-30 . .

: , Al2O3-, [1].

, . 0 24%. 10-4 ... 1700-1750 8-10 . 3%.


112

3-5 , , . 350-400 . 3%. . : , . , .

[2]. 6 : , , , , , 5 : , , , , . , . 0.058, 6 %. . 0.3% (), 4.2% ( ), 0.4% ( ) 2.9% (), 11.8% ( ).

(20-50%.) . . [3]. HPD25. 200 380/, 15001600.

,

113

1-2 , , . . , 1%. , 1-2 . , . 50%. 8,9 *, 550 .

Z-:

;0=

+

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11

11

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,

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114

// . 2014. 4. . 2227 2. . ., . . // - -26: . XXVI . . . 6, 7, 8, 9. : . . . -, 2013. . 114116.

115

.. *, ..

. .. , . , , 15-66, +79167419066

e-mail:[email protected]

( ). , , , .. 1 , , , . , - . , %

Al2O3 16,55 K2O 0,92 SiO2 52,30 Na2O 1,92 TiO2 0,95 P2O5 0,12 CaO 5,49 MgO 3,03

Fe2O3 5,2 S 0,36 , , . , , 15-17 . , - . : ( )

, ; ,

; .

, -, , -,


116

. () . Na2CO3 . 85% 15% ( ). , , . , . ( ) , , , , . , , . :

1. .. / .. , 2. .. , .. , .: , 1989, 211 . 3. . , ,

5, 1979. 4. .. , ,

, 2010.

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117

3.

,

546.273:535.37:66.040.2: 666.1.056.64 (8-)

.. , .. , .. ,

.. , .. , .. *

- .. , , 125047 , ., .9, . (495)-496-6177,

(495)-496-6781, e-mail: [email protected]

[1] , () 8- Mq3-B2O3 ( = Al, Ga, In) . (8-) (Bq3) :

Alq3+B2O3 Bq3+Al2O3, (1)

Bq3, , Inq3Gaq3Alq3 [2], , Bq3, .

(8-) (Bq3) >99,995 .% (2) , .

9H7NO + H3BO3 = (9H6NO)3B + 3H2O (2) .

, , , , . ++ ++ Bq3. (.2).

118

, Bq3, (. 1).

() , . , . , =463 -Bq3 ,

=494 - -Bq3 , =538 - -Bq3 , =522 - -Bq3 .

1. Bq3

-Bq3 -Bq3 -Bq3 -Bq3

a () 8.4919(11) 13.6226(10) 11.093(12) 13.659(25)

b () 17.2525(12) 16.0576(12) 12.833(14) 16.064(36)

c () 18.0096(14) 18.6320(15) 12.033(12) 18.639(33)

() 85.6849(25) 95.4565(22) 84.535(93) 95.37(13)

() 95.3873(35) 108.9245(46) 96.167(55) 108.98(12)

() 86.658(29) 144.6136(52) 126.450(61) 144.70(13)

Z 4 2 2 6

(3) 2613(12) 1684.321 1368(2) 3385(13)

H3BO3

-Bq3 (.2), .

Bq3 , .. , Bq3 4 , Mq3 2 . Bq3 .

OLED Bq3 , .

119

(1) Alq3 / B2O3 , . , , .

2. Bq3, (ext=365 293 K) H3BO3:

Hq, /

,

,

,

FWHM,

,

, %

X Y

1 1:2 110 3 514.3 112.0 463/494/ 538 16 / 36 /

48 0.2726 0.4648

2 1:1 110 20 508.1 106.3 463/494/ 538 8 / 46 /

46 0.2644 0.4673

3 1:3 110 22 515.8 113.5 463/494/ 538 5 / 40 /

55 0.2837 0.4809

4 2:1 190 2.5 486.4 95.5 463/494/ 538 33 / 40 /

27 0.2075 0.3597

5 1:1 200 2 497.2 96.3 463/494/ 538 21 / 45 /

34 0.2277 0.4143

6 1:2 200 2 512.7 102.3 463/494/538 4 / 41 /

55 0.2851 0.5102

7 1:1 170 16 513.5 102.3 463/494/ 538 3 / 41 /

56 0.2847 0.5074

8 1:2 170 16 517.6 108.6 494/522/ 538 27 / 17 /

56 0.3050 0.5439

,

14-13-01074.

[1] Avetisov R., Petrova O., Khomyakov A., Mushkalo O., Akkuzina A., Cherednichenko A., Avetissov I. // J. Crystal Growth (2014), V. 401, P.449452

[2] . ., . ., . ., . ., . . // 2014. . 454 2. . 178.

120

551.463 NUCLEATION IN THE BIOCOMPARTIBLE MATERIAL

PRODUCTION

1M.P. Anisimov* and 2M. Tanaka

1 Technological Design Institute of Scientific Instrument Engineering SB RAS, 41, Russkaya Str. 630058 Novosibirsk,Russia. Phone: +383-3066213; Fax: +383- 3065869; E-mail: [email protected]

2 Graduate School of Science and Engineering, Yamagata University, 4-3-16 Joan, Yonezawa, Yamagata, 992-8510, Japan. Phone/Fax: +81-238-263116; E-mail: [email protected]

The design of biocompatible 2D surfaces and 3D nano/micro

topographies based on self-organization inspired by biology has a variety of potential applications in medical devices and tissue engineering. Many polymers have been studied to obtain biocompatible surfaces [T. Tsuruta, J. Biomat. Sci. Polym. Ed, 21, 1831 (2010)]. Self-organization of materials which is inspired by biology is actual nowadays problem. The blood compatible polymers have been widely used for medical applications including artificial heart, lungs and drug delivery carriers. To provide the blood compatibility for polymeric materials, the adhesion and activation of platelets in blood-contact condition must be prevented on polymer surface. We have reported poly(2-methoxyethyl acrylate) (PMEA) possesses excellent blood compatibility and PMEA have a distinctive hydration water structure, so-called intermediate water [M. Tanaka et al. Biomaterials, 21, 1471 (2000); M. Tanaka et al., Biomacromolecules, 3, 36 (2002); I. Javakhishvili, M. Tanaka, K. Jankova and S. Hvilsted , Macromol. Rapid Commun., 33, 319 (2012)]. The intermediate water possesses moderate molecular mobility between that of non-freezing and free water. The molecular mobility of intermediate water or polymer is related to the blood compatibility such as production of thrombin-antithrombin III complex. Therefore, we consider that the intermediate water plays a key role in blood compatibility of polymers. However, the relationship between intermediate water content and blood compatibility has not yet been explained. Additionally, controlling the intermediate water content at bio-interface still cannot be performed well. The Japanese-Russian research team is demonstrating the controlling intermediate water content and blood compatibility of polymer through altering the chemical structure of polymers. The intermediate water is only found in hydrated biopolymers (proteins, polysaccharides and nucleic acid; DNA and RNA) and biocompatible synthetic polymers. Therefore, it can be proposed the intermediate water concept for directional design of functional polymeric biomaterials. It is needed for the quantitative and precise description of biocompatibility driven


121

by novel interface-sensitive approaches, We have found that biocompatible 2D surface can be created using poly(2-methoxyethyl acrylate) (PMEA) as well as honeycomb-patterned 3D films with regular interconnected pores which are formed by self-organization [M. Tanaka, Biochimica et Biophysica Acta, 1810, 251 (2011); M. Birch, M. Tanaka, G. Kirmizidis, Tissue Engineering, 19(17,18), 1 (2013)]. Surfaces made of biocompatible polymers profoundly influence cell behavior at all hierarchical levels. The interaction of polymers with cells is managed by cooperation of primary structure including backbone and functional groups at the side chain to tune the chemical functions and higher order structure forming specific shape to restrict or expand the chemical function as biological system generally adopts. Using principles of intermediate water, which is common in hydrated biopolymers and only biocompatible synthetic polymers, we hope to find the synthetic methodology to create novel biocompatible polymers moves toward a more high-throughput way. Such well-defined polymeric biomaterials could find application in the age of personalized medicine. We focused on the role of self-organized water molecules at the biointerfaces at all hierarchical levels, from sub-cellular dimensions to the whole organ of some biological object. Water molecules serve as a medium for adhesion, and play a key role in sell morphology and other cellular functions. The structure of water absorbed onto polymer surfaces greatly affects on a blood compatibility of the medical devices [M. Ide, M. Tanaka et al. Langmuir, 19, 429 (2003)]. Water phase transformations play the important role on the blood-polymer surface interaction. We are constructing semiempirically the nucleation rate surfaces over the diagram of water phase equilibria.

We are collecting the up-to-date ideas and data for the areas of water metastable states [O. Mishima and H. E. Stanley, "The Relationship between Liquid, Supercooled and Glassy Water," Nature 396, 329-335 (1998); P. Debenedetti, J. Phys.Condens. Matter 15, R1669-R1726 (2003); F. Starr, M.-C. Bellissent-Funel, H. Stanley, Phys. Rev. E 60, 1084 (1999); M. Elsaesser et al., PhysChemChem.Phys. 12, 708 (2010); V.Novikov, A.Sokolov PhysRevLett 110(6), 065701 (2013); C. Angel, Annu.Rev. Phys Chem 55, 559 (2004); K. Winkel at al., J.Chem Phys 128(4), 044510 (2008); P.Handle, et.al., Phys Rev Lett 108(22), 225901 (2012), V. Holten at al., J Chem Phys, 136, 094507 (2012); M. Anisimov, et al., J Phys Chem (Russian), 84(3), 71-77 (2010); etc] in the frame of the current project. The area topologies for the metastable states of substances [M. Anisimov, E. Fominykh, et al., Elements of the metastable area topologies for the binary solutions of vapor] J Phys Chem (Russian), 84(3), 71-77 (2010)] under investigation is designed and considered. The impact of the semiempirical construction of the nucleation rate surfaces over diagram of phase equilibria on nucleation researches is summarized in several reviews [M. P. Anisimov (2003) Nucleation: Theory and Experiment. Russian Chemical Reviews, 72(7) 591-628; Michael P. Anisimov, Elena G. Fominykh, Sergey V. Akimov, Philip K. Hopke. Vapor-Gas/Liquid Nucleation Experiments: A Review of the Challenges. J. Aerosol Sci. 40, 733-746, 2009; . Anisimov M. P., Fominykh E. G., and Petrova-Bogdanova O. O. Examples of a Semiempirical Design of Nucleation Rate Surfaces for

122

Systems with Monotropic Polymorphous Phase Transitions. Russian Journal of Physical Chemistry A, 2013, Vol. 87, No. 2, p. 252256] et cetera.

The experience of the heterogeneous nucleation rate surfaces design [M.P. Anisimov, Hopke P.K., Terry J., Rasmussen D.H.,Shandakov S.D. Pinaev V. A. Surface topology of ion-induced nucleation rates of single systems. (1998). Aerosol Science and Technology (1998) V, 29, 547-556; Michael P. Anisimov, Koropchak J.A., Nasibulin A.G., Timoshina L.V. Critical embryo phase transitions in the nucleated binary glycerin - carbon dioxide system. (1998) J. Chem. Phys. 1998, V.109(22): 10004-10010; Michael P. Anisimov, A.G. Nasibulin, and S.D. Shandakov. Experimental detection of nucleation rate surface singularity. Journal of Chem. Phys. (2000) V.112(5) P.2348-2354] is used. The homogeneous and heterogeneous nucleation rate surfaces is designed over diagram of water phase equilibria and areas of metastable states. Idea of that design was published in several articles [M. P. Anisimov, Hopke P.K., Rasmussen D.H., Shandakov S.D. Pinaev V. A. Relation of phase state diagrams and surfaces of new phase nucleation rates. (1998) J. Phys. Chem. V. 109(4) P.1435-1444; M. P. Anisimov and P. K. Hopke. Nucleation rate surface topologies for binary systems. J. Phys. Chem. B. V. 105(47) P.11817-11822 (2001)] etc. The first algorithm and the water nucleation rate surface design was developed in 2005 [L. Anisimova, M. Anisimov, G. Semin, P. Turner, and P.K. Hopke. An Algorithm for Semi-Empirical Design of Nucleation Rate Surface. Journal of Colloid and Interface Science, 290, 107-116 (2005)]. Several ideas, which should be taken in to account for real water and water based systems, are taken from the scientific literature. For example, the multilayer topologies of the nucleation rate surfaces was discussed in the article by M. Anisimov, et al. [M. Anisimov, E. Fominykh, O. Petrova-Bogdanova. Examples of the multilayer topologies of the nucleation rate surfaces. Russian J Phys Chem A, 87(2), 252256 (2013)].

The diagram of water phase equilibria is reconstructed using the new ideas for design of the water metastable state areas in the whole temperature interval from critical conditions to zero temperature limitation [M. Anisimov, et al. The multilayer topologies of the nucleation rate surfaces. Russian J Phys Chem A, 87(2), 252256 (2013)]. The nucleation rate surfaces for water phase transitions are designed semi-empirically over diagram of water phase equilibria using published idea [M. P. Anisimov, Hopke P.K., Rasmussen D.H., Shandakov S.D. Pinaev V. A. Relation of phase state diagrams and surfaces of new phase nucleation rates. (1998) J. Phys. Chem. V. 109(4) P.1435-1444]. The critical water supercooling we are going to measure quantitatively for some experimentally available conditions. The relation of the nucleation rate surfaces and the adhesion in cell morphology and other cellular functions will be found empirically.

Experimental detection of nucleation rate surface singularities is used to describe the singularities of the nucleation rate surfaces of the tested systems [M. P. Anisimov, A. Nasibulin, and S.D. Shandakov. Experimental detection of nucleation rate surface singularity. Journal of Chem. Phys. (2000) V.112(5) P.2348-2354]. To normalize the slopes of the nucleation rate surfaces for the water freezing the nucleation experiment will be provided in the neares future. The line of the critical supercooling for heterogeneous water freezing will be measured

123

using the well known electrical effects which are rising when the water freezing takes place. The freezing water is producing the voltage up to several hundred volts per interface boundary [Ribeira J.C., Ann. Acad. Brasil. Sci. (1950) V. 22(3), P.547-556; Workman E.A., Reynold S.E., Phys. Rev. (1956) V. 94(4), P.1073-1075]. That electrical field can cause the various effects.

124

547. (534.2'021+52/.59'032+539.3):547.584 Cr2O3

V-Sb-Bi/-Al2O3

- 4-

.. 1*, .. 2

1 . .. , Az1143, , . .,29, .:(+99455)8602194

e-mail:[email protected] 2 , Az1022, ,

. , 98,

-

, [1]. - . - 4-- 4- V-Sb-Bi/-Al2O3 - , [1].

, V-Sb-Bi V5+ V4+ - [2]. , , [3,4].

, - 4-- 4- V-Sb-Bi , (V5+), .. . , . ,

125

, , [5-7].

, - [5,8] 4-- 4- V-Sb-Bi/-Al2O3 , .

- . , , , [5-7]. . , , , , [5].

, - 4-- 4- V-Sb-Bi/-Al2O3 . V-Sb-Bi/-Al2O3 , 4- Cr/V [9] , , : 633 , ::=1.0:4.06.3:12.015.0, 2927 -1, . Ni ( /2) , [10] 323-843 =10-20 / [11].

, () [9]. , -Al2O3 H2 783-803, 813-873, 908-923 938-958 , [9,10], V6O13, VO2, V2O3 , -

126

, . [12] - (90%H2+10%N2), 125-250 -1-1, 25-50 /. V-Sb-Bi/-Al2O3 (V5+) (V4+) , [3]. , r ( r/V=0,15) , V-Sb-Bi/-Al2O3 , [9,10].

, , V-Sb-Bi-r/-Al2O3 . : 1. .., .., .., .. // . . . 2000. 1. .60-63. 2. .. . . . : , 1993. 37 . 3. Sembaev D.Kh., Suvorov B.V., Kolodina J.S., Kim S.M., Stepanova L.A. and Chukhno N.J. // React. Kinet. and Catal. Lett. 1980. V.13. 4. P.431-436. 4. .. // . . . 2010. 1. .166-170. 5. .. 1728240 . .. 1992. 15. 6. .., .., .. // .. I . . .. - . .: . .., 2009. .94-95. 7. .. // .. II . . .. . .: . .., 2010. .197-198. 8. .., .., .., .., .. // . 1986. . 26. 5. .654-660. 9. .. // . . . 2009. 4. .163-166. 10. .., .. // . . V . . .. - . .: . .., 2013. .56-58. 11. .. // . 1984. .22. .63-66. 12. Huang Y.-J., Xue J., Schwarz J.A. // J.Catal. 1988. V.111. 1. P.59-66.

127

665.71:665.7.038.3:543.068.8:543.067.5 -

N-

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- [1]. , , - [2-4]. - .

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: Al2O3, SiO2 ( ) . . . - . N- () (t - 150). , i1Pro (GretagMacbeth) CanoScan LIDE 500F (Canon) .


128

Al2O3, . [5]. (, , ) .

Al2O3 . N- . 0.01-0.5% .

1. .., .., .. - ./ .: , 2002. 304 .

2. .., .. // . . . 2008. .63. 6. .581.

3. .., .., .., .., .. // . 2. . 2004. .45. 2. .131-138.

4. Apyari V.V., Dmitrienko S.G., Zolotov Y.A. // Sensors and Actuators B: Chemical. - 2013.- Vol. 188.- P.1109-1115.

5. .., .., .., .. 2013155205 12.12.2013

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131

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132

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133

, , .

1. , . V. . . , 1971. . . . . .. . , 1975, 488 .

2. Methoden der Organischen Chemie (Houben-Weyl) ed. E. Muller, Thieme Verlag, Stuttgard, 1976.

3. Patai S. Rappoport Z. The chemistry of the quinonoid compounds. John Wiley&Sons, 1988.

4. J. A. VanAllan, G. A. Reynolds, R. E. Adel, J. Org. Chem., 1963, 28, 520.

5. K. Fries, K. Billig, Berichte d. D. Chem. Gesellschaft, 1923, 58, 1128. 6. .., .., .., ..,

.., .. . 2013, 49, 9, 1369. 7. . ., . ., . ., .

., . ., . . . . . . 2014, 3, 739. 8. .., .., .. . 2013, 12, 1972. 9. .., .. . 2013,

33, 3, 88.

134

678.083:661.183.55 -

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- , , 4, -, 198095. (812)786-57-44; (812)786-86-00, [email protected], [email protected]

. , - . , , , , - . , , - , , , . - , - , - .

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,

mailto:[email protected]:[email protected]

135

Zetatrac . , [1]. (.1) - 10-4 /3, [2] 5.81() 6.01() .

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136

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1. .. .., .., .. // , 2007..69. 2 .261-264. 2. .., .. // . 6. 112-117. 3. .. . ; , 2004, c. 269. ISBN 5-7691-1458-4

137

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