9
201 41 2 1389 * 29 11 1387 22 3 1389 cm 30 0 (CCE) (ACCE) NACCE XRD BET N 2 . CCE 38 228 1 105 ACCE mm 1 (ACCE1) 9 9 6 90 7 32 ACCE (ACCE2) 4 13 8 99 37 ACCE1 32 ACCE2 34 75 19 2 103 * 46 0 r CCE ** 52 0 r CCE XRD MgxCa1-xCO3 7 (CCE) Ghranjikie ( 1999 250 81 Karimian and Moafpouryan 1999 180 460 25 321 Maftoun et al. 2000 274 703 * [email protected] DelCampillo et al.1992 (Morris et al.1990) (Barrow,1986) Samadi and Gilikes 1999 Sayers et al. 1972 Oustan 2004 Lajtha and Schlesiger 1988 Yasrebi et al. 1994 Reyhanitabar et al. 2007

PardeesJournalsPT12 - دانشگاه تهران · 1389 2 41 206 10 6 3 5 17 18 r2 066** 1992 CCE r2 062 SSA= 23/6-7/04log CCE Abedi and 1975 Holford and Mattingly 1974 Talibudeen

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Page 1: PardeesJournalsPT12 - دانشگاه تهران · 1389 2 41 206 10 6 3 5 17 18 r2 066** 1992 CCE r2 062 SSA= 23/6-7/04log CCE Abedi and 1975 Holford and Mattingly 1974 Talibudeen

2014121389

*

291113872231389

cm300

(CCE)

(ACCE)NACCE XRD

BETN2.CCE382281105

ACCEmm1(ACCE1)99690

732ACCE(ACCE2)413899

37ACCE132ACCE234

7519

2103

*460rCCE**520r

CCEXRD

MgxCa1-xCO37

(CCE)Ghranjikie( 1999

250

81Karimian and

Moafpouryan1999

18046025321

Maftoun et al.2000

274703

*[email protected]

DelCampillo et al.1992

(Morris et

al.1990)

(Barrow,1986)

Samadi and

Gilikes1999Sayers et al.1972

Oustan2004Lajtha and Schlesiger1988

Yasrebi et al.1994

Reyhanitabar et al.2007

Page 2: PardeesJournalsPT12 - دانشگاه تهران · 1389 2 41 206 10 6 3 5 17 18 r2 066** 1992 CCE r2 062 SSA= 23/6-7/04log CCE Abedi and 1975 Holford and Mattingly 1974 Talibudeen

2024121389

Holford and Mattingly, 1975

Drouinea,1942

Ca45

Talibudeen & Arambarri,1964;

Abedi & Talibudeen, 1974; Mattingly, & Holford;

1975

(DelCampillo et al.1992Borrero

1988

N2

Samadi and Gilkes1999

50

Oustan2004

**900r

cm300

mm2

Klute and Dirksen,

1986Nelson and

Sommers, 1986

Chapman,1965

(pH)

01015

Richards,1954

(CCE)

(HC1)

Allison and Moodie,1965

10

754pH

XRD

(ACCE)mm1

mm2

M11252

50

2

(Dronio, 1942)

12C105

(BET) N205030p/p0

)1oo

CCEor %ACCEB(1ASSA

SSA(m2g

-1)

AB

Page 3: PardeesJournalsPT12 - دانشگاه تهران · 1389 2 41 206 10 6 3 5 17 18 r2 066** 1992 CCE r2 062 SSA= 23/6-7/04log CCE Abedi and 1975 Holford and Mattingly 1974 Talibudeen

203

DelCampillo et

al.,1992

1

CCE382281105

mm1(ACCE1)413899

g.kg-1371(BET)

5839-1m

2.g7519

Samadi and Gilkes1999

(BET)370-1

m2.g232

XRD

Brindley, and Brown, 1980 )

11

10

23814

VChSm

2

15

18

25

K251410

30014

14

10

17

550

2–

1–XRD34Q

FC

2X-ray

1 ch==VSm

=

2X-ray

125

123

20

Page 4: PardeesJournalsPT12 - دانشگاه تهران · 1389 2 41 206 10 6 3 5 17 18 r2 066** 1992 CCE r2 062 SSA= 23/6-7/04log CCE Abedi and 1975 Holford and Mattingly 1974 Talibudeen

2044121389

mm132CCEACCE

32CCE

mm134

3

2X-ray

1300550

y = 0.32x - 0.42

R2 = 0.60

0

20

40

60

80

100

0 100 200 300

CCE(g/kg)

AC

CE

1(g

/kg

)

y = 0.34x + 1.31

R2 = 0.62

0

20

40

60

80

100

120

0 100 200 300

CCE(g/kg)

AC

CE

2(g

/kg

)

312

3

(r2) 12

6062

CCE

ACCE

Samadi and Gilkes1999

540r2

50

Oustan2004

810r2

CCEACCE

2

612kg-1

g80

6

1612gkg-141

CCE

XRD

MgxCa1-xCO37

XRD

CEC

21403-1m

2.g103

ACCE12

Page 5: PardeesJournalsPT12 - دانشگاه تهران · 1389 2 41 206 10 6 3 5 17 18 r2 066** 1992 CCE r2 062 SSA= 23/6-7/04log CCE Abedi and 1975 Holford and Mattingly 1974 Talibudeen

205

ACCE1136821122

1

pH(*) pH(**)

SSA.Soil

m2g

-1

g kg-1

g kg-1

g kg-1

CEC

[cmolckg-1

]

1 Entisols 407 637 26 325 325 38 416

2 Entisols 557 707 10 106 238 39 412

3 Aridisols 657 707 20 226 185 38 219

4 Aridisols 627 807 618 308 308 211 316

5 Entisols 907 507 218 253 210 919 717

6 Entisols 607 207 58 215 225 322 315

7 Entisols 107 317 915 188 272 29 624

8 Entisols 807 567 320 134 287 113 030

9 Entisols 507 667 21 200 300 44 214

10 Entisols 357 777 39 307 330 515 220

11 Aridisols 507 537 914 305 375 918 925

12 Entisols 777 47 18 203 385 724 819

13 Aridisols 507 667 512 165 371 37 814

14 Entisols 607 607 638 410 340 29 219

15 Entisols 407 517 811 134 283 36 032

16 Aridisols 507 527 17 200 100 112 308

17 Entisols 307 367 618 363 406 37 619

18 Entisols 96 76 127 403 323 23 030

19 Entisols 777 667 421 142 265 36 017

20 Aridisols 907 957 817 160 156 5 116

507 547 7519 236 284 512 519

pH(*)pH(**)51010SSA.Soil

Holford and Mattingly1975m2/g500

CCE

CCE

DelCampilo et al1992CCE

CCE

18403-1

m2.g500

10

1848

345

CCE

CCE

4

Page 6: PardeesJournalsPT12 - دانشگاه تهران · 1389 2 41 206 10 6 3 5 17 18 r2 066** 1992 CCE r2 062 SSA= 23/6-7/04log CCE Abedi and 1975 Holford and Mattingly 1974 Talibudeen

2064121389

53610

1817

**660r2

1992

CCE

SSA= 23/6-7/04log CCE620r2

Holford and Mattingly1975Abedi and

Talibudeen1974

DelCampillo et al1992

4

718

ACCECCECCE52

CCECCE

ACCE

7

CCE

ACCE

CCE

NACCEACCENACCE

5

2

CCE

(g/kg)

ACCE(1)

(g/kg)

ACCE(2)

(g/kg) CCE

ACCE1%

CCE

ACCE 2%

SSA.CCE

(m2/g)

SSA.ACCE1

(m2/g)

SSAN.ACCE1

(m2/g)

1 80 237 438 546 48 00157 0099 00208

2 046 914 219 432 741 00111 0044 00143

3 72 026 227 136 837 0083 00124 0061

4 0136 6460 662 644 46 0050 0028 0068

5 062 343 544 70 871 00151 0020 00450

6 088 215 0816 317 318 0028 0036 0026

7 098 211 413 411 713 00127 00682 0055

8 125 232 533 825 826 0094 00197 0058

9 108 819 827 318 725 0074 00141 0059

10 228 690 899 739 843 0079 0026 00114

11 95 417 222 318 423 0088 0088 0088

12 82 639 840 348 849 00124 0013 00228

13 38 215 327 40 871 00140 00110 0159

14 94 935 840 238 443 00102 00132 0084

15 194 852 558 227 130 0021 0025 0019

16 170 250 65 529 238 0045 0094 0025

17 90 521 523 923 126 0084 0039 098

18 48 99 614 620 430 00403 00279 00436

19 108 930 634 628 32 0049 00110 0025

20 140 528 431 320 422 0054 00155 0028

1105 6532 0637 931 34 2103 1122 6121

CCEACCE (2)ACCE (1)SSA.CCE

SSA. NACCE (1)SSA.ACCE (1)1

Page 7: PardeesJournalsPT12 - دانشگاه تهران · 1389 2 41 206 10 6 3 5 17 18 r2 066** 1992 CCE r2 062 SSA= 23/6-7/04log CCE Abedi and 1975 Holford and Mattingly 1974 Talibudeen

207

3(r)20n

Silt SSA ACCE(2) ACCE(1) CCE CEC OC Clay

pH(2)

1 clay

1 0.368 OC

1 0.34 0.34 CEC

1 0.128 -0.23 -0.13 CCE

1 0.777** -0.01 -0.05 0.1 ACCE(1)

1 0.985** 0.722** -0.1 -0.08 0.07 ACCE(2)

1 0.460* 0.470* 0.725 0.105 0.056 0.7** SSA.Soil

1 0.252 -0.07 -0.05 -0.194 0.3 0.152 0.201 Silt

4(r).

SSA.Non.ACCE SSA.CCE SSA.ACCE(1) CCE Clay

1 Clay

1 -0.134 CCE

1 -0.139 -0.031 SSA.ACCE

1 0.362 -0.522** 0.461* SSA. CCE

1 0.811** -0.045 -0.497* 0.395 SSA.NACCE

***51

y = 0.055x + 6.66

R2 = 0.49

0

10

20

30

40

50

0 100 200 300 400 500

Clay(g/kg)

SS

A.S

oil(m

2/g

)

R2 = 0.022

0

5

10

15

20

25

30

35

40

45

0 10 20 30

OC(g/kg)

SS

A.S

oil(m

2/g

)

4

Soil no=17

y = -0.78x + 171.65

R2 = 0.66

0

40

80

120

160

200

0 50 100 150 200 250

CCE(g./kg)

SS

A.C

CE

(m

2/g

)

Soil No=20

y = -0.86x + 193.59

R2 = 0.27

0

100

200

300

400

500

0 100 200 300CCE(g.kg-1)

SS

A.C

CE

(m

2/g

)

5

61018

Soil No=18

y = 187.03x + 13.18

R2 = 0.52

0

50

100

150

200

0.00 0.20 0.40 0.60 0.80

ACCE/CCE

SS

A.C

CE

Soil No=20

y = 100.47x + 66.1

R2 = 0.037

0

100

200

300

400

500

0 0.2 0.4 0.6 0.8

ACCE/CCE

SS

A.C

CE

Page 8: PardeesJournalsPT12 - دانشگاه تهران · 1389 2 41 206 10 6 3 5 17 18 r2 066** 1992 CCE r2 062 SSA= 23/6-7/04log CCE Abedi and 1975 Holford and Mattingly 1974 Talibudeen

2084121389

6CCE

718

Soil No=18

y = -289.7x + 273.2

R2 = 0.45

0

100

200

300

0.00 0.20 0.40 0.60 0.80 1.00

NACCE/CCE

SS

A.N

AC

CE

y = -419.89x + 276.99

R2 = 0.20

0

100

200

300

400

500

600

700

800

0 0.2 0.4 0.6 0.8

ACCE / CCE

SS

A.A

CC

E

Soil No=18

y = -289.7x + 273.2

R2 = 0.45

0

100

200

300

0.00 0.20 0.40 0.60 0.80 1.00

NACCE/CCE

SS

A.N

AC

CE

7

518

Ca45

R.Gilkes

REFERENCES Allison,L.E. and Moodie,C.D.,(1965). Carbonat. In

Methods of Soil Analysis, Part 2, Black, C.A.(ed),

American Society of Agronomy:Madison

,Wisc,1379-1396.

Abedi ,M.J. and Talibudeen,O.,(1974).The calcareous

soils of Azerbaijan .I.Catena development related

to distribution and surface properties of soil

carbonate.J.Soil Sci.,25:357-372.

Borrero,C., Pena,F. and Torrent,J.,(1988).Phosphate

sorption by calcium carbonate in some soils of

the Mediterreanean part of

Spain.Geoderma,42:261-269.

Brindley, G. W., and Brown, G.,(1980). Crystal

structures of clay minerals and their X-ray

Identification. Mineralogical society, London.

Brummer, G., K. G. Tiller, U. Herms, and P. M.

Clayton.( 1983). Adsorption desorption and / or

precipitation dissolution processes of zinc in

Soils. Geoderma. 31: 337-354.

Barrow, N. J. and A. S. Ellis., (1986). Testing a

mechanistic model. V. The points of Zero salt

effect for phosphate retention, for Zinc retention

and for acid/alkali titration of a soil. J. soil sci.

37: 303-310.

Chapman,H.D.,(1965). Cation exchange capacity.In

Methods of Soil Analysis, Part 2, Black, C.A.(ed),

American Society of Agronomy:Madison

,Wisc,1379-1396

Drouineau ,G.,(1942).Dossage rapide du calcaire actif

du sol:nouvelles donnees sur la separation et la

nature des fractions calcaires.Ann.Agron.,12:441-

450

DelCampillo, M.C., J. Torrent and R. H. Looppert.(

1992). The reactivity of carbonates in selected

soils of southern Spain. Geoderma, 52: 149-160.

Gharenjikie.A., (1999).Zinc surface adsorption

characteristics in paddy soils from North of Iran.

Ms.S.dissertation .University of Tehran,Karaj.

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Holford I.C.R. and G.E.G. Mattingly.,(1975). Surface

areas of calcium carbonate in soils.

Geoderma,13:247-255.

Karimian,N. and Moafpouryan, G.R.(1999).Zinc

adsorption characteristics of selected soils if Iran

and their relationship with soil

properties.Communication in Soil Science and

Plant Analysis,30:1722-1731

Klute,A., and Dirksen,C.(1986). Laboratoary

methods.ch.28 In : A.Klute (Ed).Methods of soil

analysis,part 1:Physical and mineralogical

methods, 2 nd Edition.ASA and SSSSA,

Madison, WI.

Lajtha, K., and Schlesiger, W. H. (1988). The

biogeochemistry of phophorus cycling and

phosphorus availability along a desert

chronoseqence.Ecology 69:24-39

Maftoun,M.,Haghighat Nia,H., and

Karimian,N.(2000).Characterization of zinc

adsorption in some calcareous paddy soils from

Fars province.Journal of Science and Technology

of Agriculture and Natural Resources,4:71-84 (In

Farsi).

Morris, D.R.,Loeppert,R.H. and Moore,T.J. , (1990).

Indigenous soil factors influencing iron chlorosis

of soybean in calcareous soils.Soil Sci. Soc. Am.

J., 54: 1329-1336.

Nelson, D. W. and L. E. Sommers. (1986). Total

carbon, organic carbon, and organic matter. P.

539-579. In A.L. Page et al (ed). Methods of soil

analysis, part 2,2nd

ed. ASA, SSSA,Madison,W. I.

Oustan,S.,(2004).Kinetics and equilibrium studies on

phosphorus in some soils of Iran.Ph.D.

dissertation.University of Tehran.Karaj.

Richards,L.A.(1954). pH reading of saturated soil

paste.USDA Agriculture Hand book.

Reyhanitabar, A., N. Karimian, M. Ardalan,

G.Savaghebi and M. Ghannadha. (2007).

Comparison of five adsorption isotherms for

prediction of zinc retention in calcareous soils

and relationship of their coefficients with soil

characteristics. Commun Soil Sci. Plant Anal.,

38(1&2)147-159

Samadi, A., and R. J. Gilkes. (1999). Phosphorus

transformations and their relationships with

calcareous soil properties of south western

Australa. Soil Sci. Soc. Am. J. 63: 809-815.

Talibudeen, O. And De Arambarri, P., (1964). The

influence of the amount and the origin of calcium

carbonate on the isotopically exchangeable

phosphate in calcareous soils.J.Agric.Sci.,62:93-

97.

Yasrebi, J., N. Karimian, M. Maftoun, A. Abtahi, and

A. M. Sameni. (1994). Distribution of zinc forms

in highly calcareous soils as influenced by soils

physical and chamical properties and application

of zinc sulfate commun. Soil Sci. Plant Anal., 25

(11&12), 2133-2145.