SPE-0101-0057-JPT

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    Reservoir-Engineering

    Analysis of Microbial

    Enhanced Oil Recovery

    Reservoir-Engineering

    Analysis of Microbial

    Enhanced Oil Recovery

    Generally, microbial enhanced oilrecovery (MEOR) recovers less of

    the remaining oil in place thanother chemical EOR processes, bothin the laboratory and the field.Efforts to explain this difference arelimited by the lack of quantitativemeasures of microbial performance(e.g., reaction rates, stoichiometry,and required product concentra-tions). However, it is possible todemonstrate quantitative relation-ships between microbial perform-ance, reservoir characteristics, andoperating conditions (e.g., well

    spacing, injection rates, and resid-ual-oil saturation).

    IntroductionLow oil prices led to a marked shift infocus from EOR to improved-oil-recovery processes that use well tech-nology (i.e., completions, well stimu-lation, or water shutoff). However,interest in developing MEOR methodspersisted, largely because of the per-ceived potential to provide incremen-tal oil production at low cost.

    The full-length paper details a studythat adopted a reservoir-engineeringperspective, focusing on issues such asscaling up laboratory results, processdesign, and field implementation andoperation. This approach provides aconsistent framework for comparingMEOR with other EOR processes. Thestudy focuses on enhanced recoveryprocesses that induce or promotemicrobial activity that, in turn, gener-ates appropriate chemicals in thereservoir that enhance recovery.

    MEOR as a Chemical EORTable 1 shows the wide range ofmicrobial-reaction products common-

    ly cited as relevantto EOR. Except

    for biomass, allthe microbialproducts corre-spond to familiesof chemicals al-ready used or pro-posed for use inEOR processes.The claimed ef-fects of biomasscorrespond toeffects achievableby use of other

    chemicals. Cur-rent MEOR proc-esses propose nofundamental lynovel mechanismof oil recovery.Hence, MEORdiffers from otherEOR processesonly in the way that chemicals areintroduced into the reservoir (i.e., in-situ generation) and, therefore, shouldbe evaluated on the same basis as otherEOR processes. Therefore, any advan-tage of MEOR will result from beingmore efficient than other EORprocesses. In-situ generation has apotential logistics advantage, especial-ly if residual oil can be used as anin-situ carbon source. This logisticsadvantage is the most important, andpossibly the only, advantage overother processes. However, in-situ gen-eration introduces a new set of techni-cal difficulties.

    In addition to challenges associatedwith in-situ chemical generation,

    MEOR must overcome similar techni-cal problems and difficulties as otherEOR processes, particularly the place-ment and propagation of recovery-enhancing chemicals. Previous studieson chemical EOR underscore theimportance of chemical dissipationthrough dispersion and diffusion, andconsumption or retention by means ofinteractions with the rock and oil.Similarly, propagation cannot be takenfor granted in microbial treatments;injection of chemicals generated out-

    side the reservoir recovered little or nooil, even though the same chemicalsdid lead to oil recovery when generat-ed in the reservoir. Reservoir hetero-geneity may severely reduce contact ofthe chemical slug with the oil-contain-ing reservoir rock, and fingering intothe mobilized oil bank must be sup-pressed. Also, the presence of recovery-enhancing chemicals in the producedoil may create processing problems.

    An EOR process moves fluids froman injection to a production well, andphysical and chemical interactionsoccur as those fluids encounter differ-ent rock and fluid compositions.Theories that account for this move-ment are established for steam, poly-

    mer, surfactant, miscible gas, andalkali-surfactant-polymer flooding.These theories account for the behav-ior of MEOR also, insofar as MEORoperates by means of microbially gen-erated chemicals. However, an exten-sion of existing theory is required toaccount for the time required to gen-erate these species in-situ and thefeedback loop that arises when gener-ated species (e.g., polymers) alter theflow field. The full-length paperdetails this extension.

    This article is a synopsis of paperSPE 63229, Reservoir-EngineeringAnalysis of Microbial Enhanced OilRecovery, bySteven L. Bryant, U. ofTexas, and Thomas P. Lockhart,SPE,Enitecnologie, originally presented atthe 2000 SPE Annual TechnicalConference and Exhibition, Dallas,14 October.

    Product Effect

    Acids Increased rock porosity and permeability.Production of CO2 by reaction withcarbonate minerals.

    Biomass Selective and nonselective plugging.Emulsification through adhesion to oil.Changing wettability of mineral surfaces.Reduction of oil viscosity and pour point.Desulfurization of oil.

    Gases Reservoir repressurization.Oil swelling.Viscosity reduction.Increased permeability by dissolving

    carbonate rocks.

    Solvents Dissolution of oil.

    Surfactants Lowering interfacial tension.Emulsification.

    Polymers Mobility control.Selective or nonselective plugging.

    TABLE 1MICROBIAL REACTION PRODUCTS AND

    THEIR CLAIMED EFFECTS FOR EOR

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    Base-Case ImplementationIn essence, MEOR introduces reactionengineering into reservoir engineering,accompanied by concepts such as theresidence time in the reaction zone,reaction kinetics and selectivity, andlimiting reactants. The current under-standing of microbial reactions is inad-equate for quantifying these conceptsin a reservoir setting. However, it is

    possible to delineate some microbialperformance constraints imposed byengineering considerations. Theirderivation assumes that the most likelyimplementation of MEOR will entailinoculation of injection wells withmicrobes, a suitable shut-in period forincubation, then resumption of water-flooding with water containing appro-priate nutrients.

    The incubation period establishesbioreactors in the reservoir. It isassumed that microbes remain station-ary once established. This assumptionis convenient, but not crucial to theconstraints. When waterfloodingresumes, the microbes within eachbioreactor convert the injected nutri-ents and the carbon source into chem-icals that move with the aqueousphase into the reservoir and displacethe target oil.

    This implementation implies contin-uous bioreactor operation, rather thanthe batch operation commonly used inmicrobial well stimulations. Typically,the bioreactor volume is a small frac-

    tion of the reservoir volume; therefore,production of recovery-enhancingchemicals during the incubation peri-od will make a negligible contributionto the overall process. However, pub-lished laboratory studies of MEORreport on batch microbial reactions,highlighting one of the gaps hinderinga reservoir-engineering assessment ofthe technologys potential.

    Table 2 summarizes the designoptions for the base-case implementa-tion. The carbon source may be ex situ

    (included in the injected stream) orin situ (residual oil in the bioreactor).The economic and logistic advantagesare greatest for an in-situ carbonsource and the discussion will proceedon that premise. Use of indigenousmicrobes (i.e., microbes native to thereservoir) also circumvents some con-straints. Generally, achieving thedesired reactions with such microbes

    is more difficult. Some applicationsthat use indigenous microbes appearto rely only on microbe growth, ratherthan on reaction products.

    Reaction-Engineering ConstraintsThe effective reactor size is limited bythe distance to which exogenousmicrobes can be placed and by the dis-tance dictated by nutrient solubility.This limit imposes constraints on themicrobial performance and on slugvolume. The constraints are nontrivialfor reasonable values of reservoirparameters. Moreover, in-situ genera-tion of viscous fluids appears to beintrinsically unreliable.

    MEOR ExperienceTo date, laboratory work on MEORhas not demonstrated recovery ofresidual oil from cores at levels com-parable with those of other EORprocesses. There are insufficient dataand inadequate mechanistic under-standing to determine whether thislack of recovery is caused by unfavor-

    able kinetics, insufficient concentra-tion of reaction products, or low effi-cacy of microbial-reaction productsfor oil mobilization. Most field appli-cations of microbial technology arewell stimulations rather thanenhanced-recovery processes. Theapplications are intended to increaseoil-production rates rather than tomobilize incremental oil. Significantincremental oil recovery by means ofincreased displacement efficiency hasnot been demonstrated in the field.

    Increasing volumetric efficiency bypromotion of biomass growth is tech-nically simpler and appears to have abetter chance of success. However,mechanistic explanations of laborato-ry and field results are lacking.

    ConclusionsThe use of microbes introduces reac-tion engineering into reservoir engi-

    neering, with associated conceptsincluding bioreactor volume, nutrient-reaction kinetics and selectivity, andminimum required level of conver-sion. These concepts enable quantita-tive relationships between reservoircharacteristics, operating conditions,and microbial performance. Unfor-tunately, the current state of knowl-edge does not allow direct use of theseconstraints to assess MEOR field-implementation feasibility.

    Analysis with plausible values ofreservoir and microbial parametersindicates an MEOR process that usesin-situ carbon must overcome severeperformance constraints. Use of anex-situ carbon source circumvents orrelaxes some of the technical con-straints, but the logistical and costadvantages of an in-situ sourceare lost.

    Microbial gas production con-tributes to oil recovery. Analysis showsthat it is unlikely that gases such asCO2 and CH4 could be producedin situ in quantities needed for effec-

    tive oil displacement.In-situ generation of viscosifying

    agents is intrinsically unstable. Thus,robust mobility control of MEOR islikely to require an ex-situ polymer,reducing the potential logisticaladvantage of the process.

    Please read the full-length paper foradditional detail, illustrations, and ref-erences. The paper from which thesynopsis has been taken has not beenpeer reviewed.

    Design Feature Design Options Comments

    Reactor Type Fixed Microbes extend a finite, constant distance from wellbore.Growing Extent of microbes from wellbore increases as biomass is created.Mobile Microbes suspended in aqueous phase and propagate without retention.

    Carbon source In situ Residual oil.Ex situ Added to injected water; molasses is an example.

    Microbe provenance Indigenous Bacteria native and hence specific to individual reservoir; use for MEORmust be determined case by case.

    Exogenous Bacteria cultivated for use in MEOR; must adapt to reservoir conditions.

    TABLE 2KEY OPTIONS FOR MEOR-PROCESS IMPLEMENTATION

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