ISOBUTYRALDEHYDE(1) - n-heptane(2)ISOTÉRMICO

45°C

Isobutyraldehyde(1) n-heptane(2)VP_A -7.53679 -7.67468VP_B 1.08548 1.37068VP_C -1.52929 -3.53616 T (K)=VP_D -8.48589 -2.70794 R=Pc 41.5 27.4Tc 513 540.3 Pvp1=x 0.379824561403509 0.4111604664 Pvp2=z= 10

Grupos funcionalesn-Heptane CH3(2) y CH2(5)

Isobutyraldehyde CH3(2) CH(1)

SUBGRUPO k Rk Qk vk1CH3 1 0.9011 0.848 2CH2 2 0.6744 0.54 5CH 3 0.4469 0.228 0CHO 4 0.998 0.948 0

PARAMETROS DE INTERACCION BINARIA ajkk

j (SUBGRUPO) CH3 (1) CH2 (1) CH (1) CHO (10)CH3 (1) 0 0 0 618.8CH2 (1) 0 0 0 618.8CH (1) 0 0 0 618.8CHO (10) 2261 2261 2261 0

x2 Φ1 Φ2 Ѳ10.001 0.999 0.0015925383 0.998407462 0.0015298290.05 0.95 0.0773780416 0.922621958 0.0745539650.1 0.9 0.1504210988 0.849578901 0.1453511440.15 0.85 0.2194835365 0.780516463 0.2126685160.2 0.8 0.2848821204 0.71511788 0.2767564850.25 0.75 0.3469008749 0.653099125 0.337841992

CH3(CH2)5CH3

(CH3)2CHCHO

x1

0.3 0.7 0.4057952071 0.594204793 0.3961312030.35 0.65 0.461795422 0.538204578 0.4518118280.4 0.6 0.5151097328 0.484890267 0.5050551470.45 0.55 0.5659268477 0.434073152 0.5560177640.5 0.5 0.6144182015 0.385581799 0.6048431480.55 0.45 0.6607398877 0.339260112 0.6516629830.6 0.4 0.7050343374 0.294965663 0.6965983520.65 0.35 0.7474317818 0.252568218 0.7397607830.7 0.3 0.788051531 0.211948469 0.7812531740.75 0.25 0.8270030954 0.172996905 0.821170610.8 0.2 0.8643871717 0.135612828 0.8596010950.85 0.15 0.9002965118 0.099703488 0.8966261940.9 0.1 0.9348166914 0.065183309 0.9323216140.95 0.05 0.9680267909 0.031973209 0.966757720.999 0.001 0.9993722102 0.00062779 0.999346452

Datos ExperimentalesP, mmHg P,Bar x1 y1

114.33 0.1524521952 0 0149.37 0.1991759328 0.0348 0.255187.03 0.2493932832 0.0846 0.4292225.09 0.3001440096 0.1583 0.5523257.76 0.3437074944 0.242 0.6344285.02 0.3800570688 0.3312 0.6924303.06 0.4041123264 0.4073 0.7266310.53 0.4140731232 0.4373 0.7426315.63 0.4208736672 0.4669 0.7499328.98 0.4386750912 0.5319 0.7786336.25 0.4483692 0.5843 0.7938

345.1 0.460170144 0.6284 0.8116356.43 0.4752780192 0.7043 0.8404364.64 0.4862255616 0.7636 0.8626371.13 0.4948795872 0.8167 0.8842377.06 0.5027868864 0.8616 0.9074381.41 0.5085873504 0.902 0.9301386.36 0.5151878784 0.9562 0.9641388.68 0.5182814592 0.9833 0.9839389.97 0.5200015968 1 1

ISOBUTYRALDEHYDE(1) - n-heptane(2) ALUMNO: SÁNCHEZ OCHOA JORGE LUISISOTÉRMICO

45°C

318.158.314

0.5185690940.153465581

Parámetros calculados

r1= 5.1742 L1=

CHO(1) r2= 3.2471 L2=q1= 4.396

vk2 q2= 2.87220 X11= 0.285714286 X12= 0.51 X21= 0.714285714 X22= 01 X31= 0 X32= 0.25

X41= 0 X42= 0.25

ᴪ11= 1 ᴪ12= 1ᴪ21= 1 ᴪ22= 1ᴪ31= 1 ᴪ32= 1ᴪ41= 0.000819586 ᴪ42= 0.000819586

lnᴦ11= 0 lnᴦ12= 0.245729981lnᴦ21= 0 lnᴦ22= 0.156478997lnᴦ31= 0 lnᴦ32= 0.06606891lnᴦ41= 2.791077818 lnᴦ42= 1.021678008

Ѳ2 lnϒC1 lnϒC2 X1 X2 X3 X40.998470171 -0.109232558 -1.476491E-07 0.499625281 0.001249063 0.249562828 0.2495628280.925446035 -0.095498857 -0.0003564243 0.481927711 0.060240964 0.228915663 0.2289156630.854648856 -0.082874349 -0.0013768281 0.465116279 0.11627907 0.209302326 0.2093023260.787331484 -0.07153147 -0.0029941025 0.449438202 0.168539326 0.191011236 0.1910112360.723243515 -0.061360291 -0.0051485396 0.434782609 0.217391304 0.173913043 0.1739130430.662158008 -0.052262126 -0.0077868899 0.421052632 0.263157895 0.157894737 0.157894737

0.603868797 -0.044148175 -0.0108615578 0.408163265 0.306122449 0.142857143 0.1428571430.548188172 -0.036938354 -0.014329911 0.396039604 0.346534653 0.128712871 0.1287128710.494944853 -0.030560281 -0.0181536868 0.384615385 0.384615385 0.115384615 0.1153846150.443982236 -0.024948401 -0.0222984788 0.373831776 0.420560748 0.102803738 0.1028037380.395156852 -0.020043227 -0.0267332928 0.363636364 0.454545455 0.090909091 0.0909090910.348337017 -0.015790678 -0.0314301608 0.353982301 0.486725664 0.079646018 0.0796460180.303401648 -0.012141498 -0.036363805 0.344827586 0.517241379 0.068965517 0.0689655170.260239217 -0.009050747 -0.0415113439 0.336134454 0.546218487 0.058823529 0.0588235290.218746826 -0.006477361 -0.0468520354 0.327868852 0.573770492 0.049180328 0.049180328

0.17882939 -0.004383755 -0.0523670507 0.32 0.6 0.04 0.040.140398905 -0.002735475 -0.058039276 0.3125 0.625 0.03125 0.031250.103373806 -0.001500896 -0.0638531369 0.305343511 0.648854962 0.022900763 0.0229007630.067678386 -0.000650947 -0.0697944436 0.298507463 0.671641791 0.014925373 0.014925373

0.03324228 -0.000158869 -0.0758502535 0.291970803 0.693430657 0.00729927 0.007299270.000653548 -6.20907E-08 -0.0818846447 0.285836787 0.713877376 0.000142918 0.000142918

ALUMNO: SÁNCHEZ OCHOA JORGE LUIS

Parámetros calculados

-0.2832

-0.3716

Ɵ11= 0.385805278 Ɵ12= 0.590529248Ɵ21= 0.614194722 Ɵ22= 0Ɵ31= 0 Ɵ32= 0.079387187Ɵ41= 0 Ɵ42= 0.330083565

ᴪ13= 1 ᴪ14= 0.14298801ᴪ23= 1 ᴪ24= 0.14298801ᴪ33= 1 ᴪ34= 0.14298801ᴪ43= 0.000819586 ᴪ44= 1

Diagonalx y0 01 1

O1 O2 O3 O4 lnᴦ10.590216055 0.000939613 0.079265737819 0.329578594 0.245139335866 0.1561028789720.575266264 0.045790652 0.073468557086 0.305474527 0.21761272945 0.1385741437540.560772385 0.089273906 0.067848168232 0.282105542 0.192150781806 0.122360167660.546990905 0.13061988 0.062504031478 0.259885184 0.169039324689 0.1076429661930.533870562 0.169982372 0.057416267943 0.238730798 0.148026578805 0.0942622082010.521364894 0.207500769 0.052566861359 0.218567476 0.128903361476 0.082084687732

lnᴦ2

0.509431695 0.243301694 0.047939444912 0.199327166 0.111495214066 0.0709993108440.498032537 0.27750044 0.043519116697 0.180947906 0.095656404743 0.0609132766050.487132353 0.310202206 0.039292279412 0.163373162 0.081265330019 0.0517491488330.476699084 0.341503176 0.035246500646 0.14655124 0.068220981168 0.0434426059320.466703357 0.371491469 0.031370390754 0.130434783 0.05644023958 0.0359407186010.457118215 0.400247965 0.027653495768 0.114980325 0.04585583416 0.0292006491110.447918868 0.427847031 0.024086203254 0.100147898 0.036414844106 0.0231886978980.439082483 0.454357169 0.020659659297 0.085900689 0.02807766838 0.0178796473180.430587996 0.479841576 0.017365695136 0.072204732 0.020817413466 0.013256371783

0.42241594 0.504358655 0.014196762142 0.059028643 0.014619677011 0.0093096999830.414548299 0.527962456 0.011145874071 0.046343371 0.009482729311 0.0060385304580.406968374 0.550703076 0.008206555646 0.034121995 0.005418119875 0.0034502178450.399660665 0.572627015 0.005372796682 0.022339523 0.002451765213 0.0015612655840.392610769 0.59377749 0.002639011065 0.01097273 0.000625609852 0.0003983836320.385939074 0.613793317 5.188331897E-05 0.000215725 2.559589292E-07 1.629927143E-07

lnᴦ3 lnϒR1 lnϒR2 lnϒ1 lnϒ2 ϒ10.065910104455 1.023019635 1.270793067 1.53144E-06 1.161560509 1.383791E-06 3.1949150820.058509082918 1.089178263 1.128096178 0.0037059251 1.032597321 0.0033495008 2.8083505570.051663181901 1.157622093 0.996102402 0.0143799586 0.913228053 0.0130031306 2.4923550160.045449252393 1.22714924 0.87629348 0.0314702619 0.80476201 0.0284761594 2.2361642510.039799599018 1.297907951 0.767364199 0.0545538273 0.706003908 0.0494052877 2.0258794610.034657979265 1.370056616 0.668230162 0.0833144384 0.615968036 0.0755275485 1.851448001

lnᴦ4

0.029977486801 1.443765624 0.577986982 0.1175266593 0.533838807 0.1066651016 1.7054667160.025718939011 1.51921947 0.495879193 0.1570443384 0.458940838 0.1427144274 1.5823970830.021849640618 1.596619187 0.421276404 0.2017926073 0.390716123 0.1836389205 1.4780388730.018342433616 1.676185175 0.353654992 0.2517626915 0.328706591 0.2294642128 1.3891702010.015174970076 1.758160522 0.292584072 0.3070090909 0.272540845 0.2802757981 1.3132970990.012329162958 1.842814914 0.237714914 0.3676488656 0.221924236 0.3362187048 1.2484767840.009790783557 1.930449319 0.188773178 0.4338629113 0.17663168 0.3974991063 1.1931915360.007549184423 2.021401589 0.145553573 0.5058992307 0.136502826 0.4643878868 1.1462581170.005597134753 2.11605325 0.107916686 0.5840783316 0.101439325 0.5372262962 1.1067627630.003930762215 2.214837778 0.075787854 0.6688010141 0.071404099 0.6164339634 1.0740151470.002549601749 2.318250779 0.049158111 0.7605589592 0.046422636 0.7025196832 1.0475170360.001456758646 2.426862606 0.028087329 0.8599487249 0.026586433 0.796095588 1.0269430050.000659201024 2.541334152 0.012709858 0.9676900031 0.012058911 0.8978955595 1.0121319130.000168206422 2.662436787 0.003243138 1.0846493328 0.003084269 1.0087990793 1.00308903

6.881914605E-08 2.788424477 1.326881E-06 1.2092181779 1.264791E-06 1.1273335332 1.000001265

ϒ2 P,bar y1 y2 y1+y21.00000138 0.15496911 0.01069106 0.98930894 11.00335512 0.21909764 0.33234584 0.66765416 11.01308804 0.26917256 0.48015975 0.51984025 11.02888548 0.30815458 0.56445972 0.43554028 11.05064608 0.3391021 0.61961189 0.38038811 11.07845294 0.36415498 0.65913125 0.34086875 1

1.1125616 0.38483864 0.68943363 0.31056637 11.15340038 0.4022585 0.71397815 0.28602185 11.20158188 0.41722699 0.7348185 0.2651815 11.25792585 0.43034791 0.75327735 0.24672265 11.32349478 0.44207309 0.77027453 0.22972547 1

1.3996451 0.45274062 0.7865029 0.2134971 11.48809846 0.46260011 0.80253191 0.19746809 11.59103999 0.47182858 0.81887605 0.18112395 11.71125376 0.48053864 0.83604739 0.16395261 11.85231084 0.48877979 0.85460428 0.14539572 12.01883312 0.49653225 0.87520593 0.12479407 12.21686844 0.50369172 0.89868416 0.10131584 12.45443247 0.51004139 0.92614895 0.07385105 12.74230574 0.5152049 0.95915707 0.04084293 13.08741303 0.51852499 0.99908623 0.00091377 1

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 10

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

Isobutyraldehyde(1)-n-Heptane(2) UNIFAC ( X vs Y )

X vs Y (CALCULADO) DIAGONAL X vs Y (EXP)

X

Y

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 10

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

Isobutyraldehyde(1)-n-Heptane(2) UNIFAC ( X vs Y )

X vs Y (CALCULADO) DIAGONAL X vs Y (EXP)

X

Y

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 10

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

Isobutyraldehyde(1)-n-Heptane(2) UNIFAC ( X vs Y )

X vs Y (CALCULADO) DIAGONAL X vs Y (EXP)

X

Y

DIAGONALX Y

0 0.152521951 0.5200016

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 10

0.1

0.2

0.3

0.4

0.5

0.6

Isobutyraldehyde(1)-n-Heptane(2) UNIFAC (X Y vs P)

X vs P (CALC) Y vs P (CALC) X vs P (EXP) Y vs P (EXP) DIAGONAL

X Y

P (B

ar)

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 10

0.1

0.2

0.3

0.4

0.5

0.6

Isobutyraldehyde(1)-n-Heptane(2) UNIFAC (X Y vs P)

X vs P (CALC) Y vs P (CALC) X vs P (EXP) Y vs P (EXP) DIAGONAL

X Y

P (B

ar)

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 10

0.1

0.2

0.3

0.4

0.5

0.6

Isobutyraldehyde(1)-n-Heptane(2) UNIFAC (X Y vs P)

X vs P (CALC) Y vs P (CALC) X vs P (EXP) Y vs P (EXP) DIAGONAL

X Y

P (B

ar)