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VSEPRVSEPR
What shape are your molecules in?What shape are your molecules in?
Background you need… Background you need…
Lewis structuresLewis structures How many bonds do each element make?How many bonds do each element make? What can expand?What can expand?
Bonding (covalent)Bonding (covalent) PolarityPolarity
Electronegativity and determining bond typeElectronegativity and determining bond type Resonance v. IsomersResonance v. Isomers Formal chargeFormal charge
Let’s review Let’s review now…..now…..
Lewis StructuresLewis Structures
Remember that Lewis structures want a Remember that Lewis structures want a full outer shellfull outer shell
Remember that for a given Lewis Remember that for a given Lewis structure, the number of electrons around structure, the number of electrons around the atoms must equal the total number of the atoms must equal the total number of electrons individually assigned. electrons individually assigned. Ex: C has 4, H has 1, so CHEx: C has 4, H has 1, so CH44 must have 8 must have 8
total total
IsomersIsomers
Same formula, different arrangement of Same formula, different arrangement of atomsatoms
Physically break bonds and MOVE Physically break bonds and MOVE atomsatoms
Resonance StructuresResonance Structures
Have the same Have the same alignment of alignment of atoms, but atoms, but different bonding different bonding (electrons ONLY (electrons ONLY are moved, both are moved, both in bonds and in bonds and lone pairs)lone pairs)
Determining formal Determining formal chargecharge
Formal charge can be determined by:
Normal number of electrons in outer shell
-[(1/2 the number of bonded electrons)
+ lone electrons]
_____________________________________= formal charge
Example: N in NH4
FC =5- [(1/2 of 8)+ 0]= +1
Formal charge and Formal charge and stabilitystability
The most “happy” molecules tend to have The most “happy” molecules tend to have no formal chargesno formal charges
However, molecules may be “happy” if However, molecules may be “happy” if they have not NET charge on them (if they have not NET charge on them (if there is 1+ and 1-, so a net of +1 + (-1)=0)there is 1+ and 1-, so a net of +1 + (-1)=0)
Resonance structures that are the best Resonance structures that are the best have a minimal formal charge and a full have a minimal formal charge and a full octet around each atomoctet around each atom
What is VSEPR?What is VSEPR?
ValenceValence ShellShell ElectronElectron PairPair RepulsionRepulsion TheoryTheory
Why?Why?
The shape of molecules influences their The shape of molecules influences their characteristics:characteristics: Things like polarity which influence things Things like polarity which influence things
likelike boiling point, melting point, which dictate their boiling point, melting point, which dictate their
nature (solid, liquid or gas at room temperature)nature (solid, liquid or gas at room temperature)
The parent geometries: all others come from these
Steric NumberSteric Number
The number of “things” sprouting off of an The number of “things” sprouting off of an atomatom These can be eitherThese can be either
Bonds Bonds Of any order (1, 2, or 3)Of any order (1, 2, or 3)
OrOr
Lone pairs of electronsLone pairs of electrons
Steric Number ExamplesSteric Number Examples Ex #1: CHEx #1: CH44
There are 4 H’s branching There are 4 H’s branching off , so the steric number off , so the steric number is 4is 4
SN=4SN=4
Ex #2: HEx #2: H22OO SN= 4SN= 4
Explain why Explain why
Ex #3: COEx #3: CO22
SN= 2SN= 2 Explain whyExplain why
General FormulasGeneral Formulas All molecules with a shared general All molecules with a shared general
formula have a shared geometryformula have a shared geometry we use them to help note shapewe use them to help note shape
Formulas are typically written with A’s, Formulas are typically written with A’s, X’s, and E’s X’s, and E’s
The letters stand for:The letters stand for: A= the central atomA= the central atom X *= the number of atoms attached to the central X *= the number of atoms attached to the central
atomatom E= the number of lone pairs of electrons attached E= the number of lone pairs of electrons attached
to the central atomto the central atom
*Some sources use A’s, B’s, and E’s*Some sources use A’s, B’s, and E’s
General Formula ExamplesGeneral Formula Examples Ex #1: CHEx #1: CH44
AXAX44
Ex #2: HEx #2: H22OO AXAX22EE22
Ex #3: COEx #3: CO22
AXAX22
LinearLinear
AXAX22
Trigonal planarTrigonal planar
AXAX33
TetrahedralTetrahedral
AXAX44
Pyramidal (Trigonal or Pyramidal (Trigonal or tetrahedral)tetrahedral)
Tetrahedral parent Tetrahedral parent shapeshape
1 lone pair of 1 lone pair of electronselectrons
AXAX33EE
BentBent
Tetrahedral Tetrahedral parent shapeparent shape
2 lone pair of 2 lone pair of electronselectrons
AXAX22EE22
When determining When determining polarity it is polarity it is important to look at important to look at the dipole moments- do the dipole moments- do they cancel out?they cancel out?
Trigonal bipyramidalTrigonal bipyramidal
AXAX55
Seesaw Seesaw a.k.a.a.k.a. Teeter- Teeter-tottertotter
Trigonal bipyramidal Trigonal bipyramidal parent shapeparent shape
1 lone pair of 1 lone pair of electronselectrons
AXAX44EE
T-shapedT-shaped
Trigonal bipyramidal Trigonal bipyramidal parent shapeparent shape
2 lone pair of 2 lone pair of electronselectrons
AXAX33EE22
LinearLinear
Trigonal bipyramidal Trigonal bipyramidal parent shapeparent shape
3 lone pair of 3 lone pair of electronselectrons
AXAX22EE33
OctahedralOctahedral
AXAX66
Square pyramidalSquare pyramidal
Octahedral parent Octahedral parent shapeshape
1 lone pair of 1 lone pair of electronselectrons
AXAX55EE
Square planarSquare planar
Octahedral parent Octahedral parent shapeshape
2 lone pair of 2 lone pair of electronselectrons
AXAX44EE22
T-shapedT-shaped
Octahedral parent Octahedral parent shapeshape
1 lone pair of 1 lone pair of electronselectrons
AXAX33EE33
Summary of shapesSummary of shapes
ID these VSEPR shapes…ID these VSEPR shapes…
Sweet drill and practice Sweet drill and practice web siteweb site
Given generic shapes to ID:Given generic shapes to ID: http://www.chemistry-drills.com/VSEPR-1.php?http://www.chemistry-drills.com/VSEPR-1.php?
q=1q=1
Given molecules to draw out:Given molecules to draw out: Basic: http://www.chemistry-drills.com/VSEPR-Basic: http://www.chemistry-drills.com/VSEPR-
1.php?q=21.php?q=2 Advanced: Advanced:
http://www.chemistry-drills.com/VSEPR-1.php?http://www.chemistry-drills.com/VSEPR-1.php?q=3q=3