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    1

    !"#$%&'( *+&,,&"',-"'./"%, 0"/ 1--2 *'(&'$,

    3&.4%5 6/&78"#7"9 :8&+&'( ;4"9

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    FA.%&'$

    Background, Objective, Approach

    Steady-state experimental measurements of RCCI engine-outemissions from a light-duty, multi-cylinder engine

    Drive-cycle simulations of engine-out exhaust from an RCCI-

    enabled vehicle Preliminary experimental measurements of oxidation catalyst

    performance with RCCI exhaust

    Summary

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    3

    U4=7(/"A'#

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    1$4=HS&.5 ="'./"%%$# ="+O/$,,&"' &('&H"' V1--2W4%%"C, O/$=&,$ /$4=H"' 4'# 8$4.J/$%$4,$ ="'./"%

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    C&.8 4&/@

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    +

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    ;%"D4% 0A$% /$4=HS&.5 VO84,&'(W

    [A$% /$4=HS&.5 (/4#&$'., VO/$,,A/$ /&,$W

    *\A&S4%$'=$ /4H" ,./4H]=4H"'

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    1--2 "_$/, D".8 D$'$]., 4'# =84%%$'($, ."&+O%$+$'.4H"' "0 I^-

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    I"C GFY 4'# ,"".

    -"'./"%, 4'# $+&,,&"', =84%%$'($,

    !"#$%&'( )

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    !"#$%&'(

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    )&(#(%

    6773 2773

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    8$9 ! #$%&%'() *+(,-./'0(0,' 6&:5 ! #$,1,(%) *+(,-./'0(0,'

    Adapted from Hanson, UW-M Engine Research Center

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    FDZ$=HS$ 4'# XOO/"4=8

    FDZ$=HS$

    R'#$/,.4'# .8$ $+&,,&"', D$'$]., 4'# =84%%$'($, "0 1--2J$'4D%$# +A%HJ=5%&'#$/

    $'(&'$ "S$/ ./4',&$'. =&.5 4'# 8&(8C45 #/&S$ =5=%$,

    XOO/"4=8

    + -84/4=.$/&a$ $YO$/&+$'.4% 1--2 $'(&'$J"A. $+&,,&"', 0/"+ 4 %&(8.J#A.5 +A%HJ

    =5%&'#$/ $'(&'$

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    RH%&a$ #/&S$J=5=%$ ,&+A%4H"', ." $'H05 &+O"/.4'. #&_$/$'=$, &' $'(&'$J"A.$+&,,&"', 0"/ 1--2 ="+O4/$# ." ="'S$'H"'4% #&$,$% ="+DA,H"'

    +

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    2#$'H05 O".$'H4% 4b$/./$4.+$'. =84%%$'($, O",$# D5 1--2

    Emissions Constraints

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    !A%HJ=5%&'#$/ $YO$/&+$'.4% ,$.AO 0"/ 1--2 $Y84A,. +$4,A/$+$'.,

    KLLT ;! M@cJI dJ=5%&'#$/ #&$,$% $'(&'$

    F*! #&$,$% 0A$% ,5,.$+ C&.8 B2 &'Z$=."/,

    BA4%J0A$% ,5,.$+ C&.8 6[2 &'Z$=."/,

    F*! S4/&4D%$ ($"+$./5 .A/D"=84/($/ F/&(&'4% ,."=7 O&,."' +"#&]$# 0"/ 1--2 &' /$=$'. ,.A#&$,

    !&=/"O/"=$,,"/JD4,$# ="'./"% ,5,.$+ VB1233*GW

    [A%% ="'./"% "0 B2 e 6[2 0A$% ,5,.$+, e $'(&'$ O4/4+$.$/,

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    -5%&'#$/J."J=5%&'#$/ D4%4'=&'( V2!*69 -XPL9 !611W

    [A$%,f R^;gRI

    See Curran et al, Int. J. Engine Res., 13(3), 216 , 2012 and Prikhodko et al,

    SAE 2013-01-0515.

    -2B2 D4,$

    ="'](A/4H"'

    GA+D$/ "0 =5%&'#$/, d

    U"/$ V++W hK@L

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    1--2 ="A%# '". D$ ,A==$,,0A%%5 &+O%$+$'.$# 4. 4%% $'(&'$ ="'#&H"',9/$\A&/&'( #A4%J+"#$ "O$/4H"'i

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    1--2 84# #/4+4H= $_$=., "' $Y84A,. .$+O$/4.A/$

    CDC only CDC/RCCI

    CDC/RCCI

    T

    exhaust(C)

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    ^8$ =84/4=.$/&,H=, "0 $'(&'$J"A. 6! C$/$ (/$4.%5 4%.$/$# #A/&'(1--2 "O$/4H"'

    X%.8"A(8 ,+"7$ 'A+D$/ #$=/$4,$# ,&('&]=4'.%5 #A/&'( 1--29 6! +4,, 4=.A4%%5&'=/$4,$# ="+O4/$# ." 6--2

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    CDC

    0.137

    PCCI RCCI

    0.0400.025PM mass(mg/min)*

    Engine Condition: 2300 rpm, 4.2 bar BMEP (Prikhodko et. al., SAE 2010-01-2266)

    i

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    1--2 l- ,O$=&$, C$/$ 4%," \A&.$ #&_$/$'. ="+O4/$# ." -B-

    4'# 6--2

    SAE 2010-01-2266

    Higher carbonyl emissions

    More mono-aromatics (*)reflects gasoline vs. diesel PICs

    Engine Condition: 2300 rpm, 4.2 bar BMEP*

    *

    **

    As gasoline-to-diesel ratio changes over the speed/load map, HC composition shiftsbetween diesel-like and gasoline-like

    i1$,A%., 0"/ R^;JcQgRI

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    B/&S$J=5=%$ ,&+A%4H"', "0 4' 1--2J$'4D%$# IB S$8&=%$

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    ^" A'#$/,.4'# .8$ &+O4=. "0 #/&S$ =5=%$ ./4',&$'., "' $'(&'$J"A.$Y84A,. =84/4=.$/&,H=,9 C$ ,&+A%4.$# 4 S$8&=%$ C&.8 XA."'"+&$i

    XA."'"+&$ &, 4 O%A(J4'#JO%45 O"C$/./4&' 4'# S$8&=%$+"#$% 4/=8&.$=.A/$ 4'# #$S$%"O+$'. $'S&/"'+$'.

    0A'#$# D5 BF* ." ,AOO"/. .8$ /4O $S4%A4H"' "0'$C O"C$/./4&'gO/"OA%,&"' .$=8'"%"(&$, C&.8,.$4#5J,.4.$ +4O, VHHHI$"(4%42/'I%'(W

    E$ 4%," A,$# 4 ,&+O%&]$# %"CJ"/#$/ ="//$=H"'+$.8"#"%"(5 ." $,H+4.$ ./4',&$'. $Y84A,.O/"O$/H$, 0/"+ ,.$4#5J,.4.$ $'(&'$ +4O, JK$4'(I$)I* :%(I LI ,%7/%' 9'3I* DDJBM* BCDCM

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    E$ 0"A'# .84. 1--2 "O$/4H"' &, O",,&D%$ 0"/ 4 %4/($ 0/4=H"' "0 $4=8#/&S$ =5=%$

    1--2J$'4D%$# $'(&'$

    &'=/$4,$, 0A$% $="'"+5"S$/ =&.5 4'# 8&(8C45#/&S$ =5=%$,

    RCCIresults

    Fueleconomybenefit

    (relative %)

    Drive cycleby distance

    (%)

    Drivecycle by

    time

    (%)

    Totaldieselfuel

    (%)

    DieselduringRCCI

    (%)

    UDDS +14 72 55 56 41

    HWFET +15 88 86 44 37

    US06 +8 66 56 66 31

    NYCC +13 69 36 65 43

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    ^8$ 0A$% $`=&$'=5 D$'$]., "0 1--2 C$/$ =%$4/ V$Y4+O%$ /$,A%.,D$%"C 0"/ ,&+A%4.$# 8".J,.4/. RBB

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    X, $YO$=.$# 0/"+ .8$ ,.$4#5J,.4.$ $YO$/&+$'.,9 $'(&'$J"A. GFY 4'#,+"7$ #/"OO$# #/4+4H=4%%59 DA. -F 4'# l- C$/$ +A=8 (/$4.$/

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    GFY e

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    6/$%&+&'4/5 =84/4=.$/&a4H"' "0 "YH"' =4.4%5,.O$/0"/+4'=$ C&.8 1--2 $'(&'$J"A. $Y84A,.

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    *YO$/&+$'.4% BF- +$4,A/$+$'., C&.8 $'(&'$ $Y84A,.

    Modified 2007 GM 1.9-L multi-cylinder dieselengine as before

    UTG-96 Gasoline/ULSD fuels

    Dual-fuel system with PFI injectors forgasoline

    OEM diesel fuel system

    OEM variable geometry turbocharger

    Measurements at 5 speeds and loads

    2300 rpm, 4.2 Bar BMEP (mid RCCI range)

    2000 rpm, 6.0/2.0 Bar BMEP

    1250 rpm, 5.0/2.0 Bar BMEP

    Comparison of CDC, PCCI, and RCCI

    Exhaust aftertreatment

    1.25-liter model DOC

    Supplied by Emerachem

    300 csi, 100 g/ft3Pt, 0 g/ft3 Pd

    3 hrs degreening in engine exhaust at 730C

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    RCCI PM mass was highly reduced in the DOC

    Engine-out PCCI andRCCI mass were similarin magnitude but"

    The DOC reduced PMmass by 50% withRCCI vs. 30% withCDC and 10% withPCCI

    DOC was effective forRCCI despite lowerexhaust temperature

    CDC: 411C

    PCCI: 408C

    RCCI: 247C

    0 1 2 3 4 5 6 7ParticleMassEmissions(g/hp-hr)

    0.00

    0.02

    0.04

    0.06

    0.08

    0.10

    0.12

    0.14

    Conventional Diesel

    PostDOC

    EngineOut

    Diesel PCCI

    PostDOC

    EngineOut

    Dual-Fuel RCCI

    PostDOC

    EngineOut

    Reduction by DOC

    Conventional Diesel: 30 6%

    Diesel PCCI: 9 18%

    Dual-Fuel RCCI: 47 9%

    RCCI post-DOC emissions 0.014 0.001 g/hp-hr

    Engine Condition: 2300 rpm, 4.2 bar BMEP*

    iB4.4 ,8"C' 0"/ R^;JcQgRI

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    The fraction of very small particles (nuclei mode) was reduced~35% by the DOC

    Number of RCCI particles >30 nm ~100times less than CDC and PCCI

    Enhanced fuel and air mixing

    High HC concentration with lack ofsoot surface area for adsorption

    dp(nm)

    1 10 100

    dN/dlogd

    p

    (#/cm

    3)

    1e+4

    1e+5

    1e+6

    1e+7

    1e+8

    1e+9

    Conv: Engine Out

    Conv: Post DOC

    PCCI: Engine Out

    PCCI: Post DOC

    Dual: Engine Out

    Dual: Post DOC

    Engine Condition: 2300 rpm, 4.2 bar BMEP*

    Small RCCI PM appears to be moresusceptible to vaporization and

    oxidation at 250 C

    iB4.4 ,8"C' 0"/ R^;JcQgRI

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    ^8$ %&(8.J"_ .$+O$/4.A/$ 0"/ l- 4'# -F "YH"' 4OO$4/$# ." D$8&(8$/ 0"/ 1--2 $Y84A,.i

    Speed/Load(rpm/bar)

    !Exhaust T(C )

    1250/2.0 8

    1250/5.0 35

    2000/2.0 34

    2000/6.0 49

    0

    10

    20

    30

    40

    50

    60

    70

    80

    90

    100

    100 150 200 250 300 350

    Conv

    ersion(%)

    Inlet Exhaust Temperature (C)

    HC (RCCI)

    CO (RCCI)

    HC (CDC)

    CO (CDC)

    iB4.4 ,8"C' 0"/ R^;JcQgRI

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    X=7'"C%$#($+$'.,

    Gurpreet Singh

    Ken Howden

    Office of Vehicle Technologies

    US Department of Energy

    -"'.4=.,

    Scott Curran(865) [email protected]

    Vitaly Prikhodko(865) [email protected]

    Zhiming Gao(865) [email protected]

    Stuart Daw(865) [email protected]

    Fuels, Engines and Emissions Research CenterOak Ridge National Laboratory

    Robert Wagner(865) [email protected]

    James Parks(865) 946-1283

    [email protected]