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Page 1: NIST  SWCNTs

10 100 1000 100000.1

1

10

100

1000

10000

SMPS

APS

OPS

Particle diameter (Dp) [nm]

dN/d

logD

p [#

/cm

3]

10 100 1000 1000010

100

1000

10000

SMPS

APS

OPS

Particle diameter (Dp) [nm]

dV/d

logD

p [1

0-12

m3/

m3]

Fig. S1 Number-based size distribution of aerosolized CNTs measured by a scanning mobility particle sizer (SMPS), an aerodynamic particle sizer (APS), and an optical particle

sizer (OPS) (left) and calculated volume-based size distribution (right).

NIST SWCNTs NIST SWCNTs

Page 2: NIST  SWCNTs

10 100 1000 100001

10

100

1000

10000

SMPS

APS

OPS

Particle diameter (Dp) [nm]

dN/d

logD

p [#

/cm

3]

10 100 1000 1000010

100

1000

10000

SMPS

APS

OPS

Particle diameter (Dp) [nm]

dV/d

logD

p [1

0-12

m3/

m3]

Aldrich SWCNTs Aldrich SWCNTs

Fig. S1. continued

Page 3: NIST  SWCNTs

10 100 1000 100001

10

100

1000

SMPS

APS

OPS

Particle diameter (Dp) [nm]

dV/d

logD

p [1

0-12

m3/

m3]

10 100 1000 100001

10

100

1000

10000

SMPS

APS

OPS

Particle diameter (Dp) [nm]

dN/d

logD

p [#

/cm

3]

NanoIntegris SWCNTs NanoIntegris SWCNTs

Fig. S1. continued

Page 4: NIST  SWCNTs

10 100 1000 100000.01

0.1

1

10

100

1000

SMPS

APS

OPS

Particle diameter (Dp) [nm]

dN/d

logD

p [#

/cm

3]

10 100 1000 100000.1

1

10

100

1000

10000

SMPS

APS

OPS

Particle diameter (Dp) [nm]

dV/d

logD

p [1

0-12

m3/

m3]

Nanocyl SWCNTs Nanocyl SWCNTs

Fig. S1. continued

Page 5: NIST  SWCNTs

10 100 1000 100001

10

100

1000

SMPS

APS

OPS

Particle diameter (Dp) [nm]

dN/d

logD

p [#

/cm

3]

10 100 1000 100001

10

100

1000

10000

SMPS

APS

OPS

Particle diameter (Dp) [nm]

dV/d

logD

p [1

0-12

m3/

m3]

AIST SWCNTs AIST SWCNTs

Fig. S1. continued

Page 6: NIST  SWCNTs

10 100 1000 100000.01

0.1

1

10

100

SMPS

APS

OPS

Particle diameter (Dp) [nm]

dN/d

logD

p [#

/cm

3]

10 100 1000 100000.01

0.1

1

10

100

1000

SMPS

APS

OPS

Particle diameter (Dp) [nm]

dV/d

logD

p [1

0-12

m3/

m3]

Aldrich MWCNTs Aldrich MWCNTs

Fig. S1. continued

Page 7: NIST  SWCNTs

10 100 1000 100000.001

0.01

0.1

1

10

100

SMPS

APS

OPS

Particle diameter (Dp) [nm]

dN/d

logD

p [#

/cm

3]

10 100 1000 100000.1

1

10

100

SMPS

APS

OPS

Particle diameter (Dp) [nm]

dV/d

logD

p [1

0-12

m3/

m3]

Nanocyl MWCNTs Nanocyl MWCNTs

Fig. S1. continued

Page 8: NIST  SWCNTs

10 100 1000 100000.1

1

10

100

1000

SMPS

APS

OPS

Particle diameter (Dp) [nm]

dN/d

logD

p [#

/cm

3]

10 100 1000 100000.1

1

10

100

1000

10000

SMPS

APS

OPS

Particle diameter (Dp) [nm]

dV/d

logD

p [1

0-12

m3/

m3]

Company A MWCNTsCompany-A MWCNTs Company-A MWCNTs

Fig. S1. continued

Page 9: NIST  SWCNTs

10 100 1000 100001

10

100

1000

10000

SMPS

APS

OPS

Particle diameter (Dp) [nm]

dN/d

logD

p [#

/cm

3]

10 100 1000 100001

10

100

SMPS

APS

OPS

Particle diameter (Dp) [nm]

dV/d

logD

p [1

0-12

m3/

m3]

Nikkiso MWCNTs Nikkiso MWCNTs

Fig. S1. continued

Page 10: NIST  SWCNTs

10 100 1000 100000.001

0.01

0.1

1

10

100

1000

10000

SMPS

APS

OPS

Particle diameter (Dp) [nm]

dN/d

logD

p [#

/cm

3]

10 100 1000 100001

10

100

1000

SMPS

APS

OPS

Particle diameter (Dp) [nm]

dV/d

logD

p [1

0-12

m3/

m3]

Mitsui MWCNTs Mitsui MWCNTs

Fig. S1. continued

Page 11: NIST  SWCNTs

NIST SWCNTs Aldrich SWCNTs NanoIntegris SWCNTs

AIST SWCNTs

0 50 1001502002503003504004505000

20

40

60

80

100

120

f(x) = 0.173491397245675 xR² = 0.941295265667804

f(x) = 0.256275390142078 xR² = 0.992404498544144

Concentrations of EC measured by thermal carbon analysis [µg/m3]

Con

cent

ratio

ns m

easu

red

by

port

able

inst

rum

ents

[µg

/m3]

0 20 40 60 80 100 120 140 160 1800

20

40

60

80

100

120

140

f(x) = 0.359118410840181 xR² = 0.923553033796122

f(x) = 0.781592419744647 xR² = 0.967051008723515

Concentrations of EC measured by thermal carbon analysis [µg/m3]

Con

cent

ratio

ns m

easu

red

by

port

able

inst

rum

ents

[µg

/m3]

0

50

100

150

200

250f(x) = 0.133822831564629 xR² = 0.996689582928117

f(x) = NaN xR² = 0

Concentrations of EC measured by thermal carbon analysis [µg/m3]

Con

cent

ratio

ns m

easu

red

by

port

able

inst

rum

ents

[µg

/m3]

0 10 20 30 40 50 60 700

10

20

30

40

50

60

70

80

90

100

f(x) = 0.32175587980843 xR² = 0.970547745530704

f(x) = 1.52934669694219 xR² = 0.994313629512667

Concentrations of EC measured by thermal carbon analysis [µg/m3]

Con

cent

ratio

ns m

easu

red

by

port

able

inst

rum

ents

[µg

/m3]

Fig. S2 Responses of the black carbon monitor (BCM) and the photometer to airborne carbon nanotubes (CNTs) compared to the CNT mass concentrations measured by thermal carbon analysis.

Page 12: NIST  SWCNTs

0 50 100 150 200 2500

10

20

30

40

50

60

70

80f(x) = 0.337240372740915 xR² = 0.987906977620206

f(x) = 0.160576835176537 xR² = 0.994423613993458

Concentrations of EC measured by thermal carbon analysis [µg/m3]

Con

cent

ratio

ns m

easu

red

by

port

able

inst

rum

ents

[µg

/m3]

Aldrich MWCNTs Nanocyl MWCNTs Company-A MWCNTs

Nikkiso MWCNTs Mitsui MWCNTs

0 2 4 6 8 10 12 14 16 18 200

10

20

30

40

50

60

70

80

f(x) = 0.892510333261659 xR² = 0.826561975834519

f(x) = 4.69503330469416 xR² = 0.989650080564394

Concentrations of EC measured by thermal carbon analysis [µg/m3]

Con

cent

ratio

ns m

easu

red

by

port

able

inst

rum

ents

[µg

/m3]

0 50 100 150 200 250 3000

100

200

300

400

500

600

f(x) = 0.500664596152053 xR² = 0.995637527538933

f(x) = 1.75212011736042 xR² = 0.997934628977739

Concentrations of EC measured by thermal carbon analysis [µg/m3]

Con

cent

ratio

ns m

easu

red

by

port

able

inst

rum

ents

[µg

/m3]

0 200 400 600 8000

20

40

60

80

100

120

140

160

180

f(x) = 0.19531897774911 xR² = 0.983279761783688

f(x) = 0.138931764570809 xR² = 0.998900954261082

Concentrations of EC measured by thermal carbon analysis [µg/m3]

Con

cent

ratio

ns m

easu

red

by

port

able

inst

rum

ents

[µg

/m3]

0 20 40 60 80 100 1200

5

10

15

20

f(x) = 0.120645032003345 xR² = 0.985513004022709

f(x) = 0.0666275843159122 xR² = 0.981859806219885

Concentrations of EC measured by thermal carbon analysis [µg/m3]

Con

cent

ratio

ns m

easu

red

by

port

able

inst

rum

ents

[µg

/m3]

Fig. S2. continued