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Ce$ificate l{o. 02402itBAPACDate: I'Jay 28, :003
PRiNCiPIiL
SUtsJFCT
T[STER FOR
TES]"TD idETHOD
DATE OF RECEIVING
DA-TE CF ANALYSiS
SAfu'iPLE NAME
FsEsEi
**p*g;3[si.ri,..;r:r.,ffiffiffiW#PW""'4%' &liWJ*+i$$slL;r,;;''lii* f;;...*1 %:{j.
i:'i lq4 "'' i:l:n'r-" !r
issuing Ciflce:
SuCCf il,lDO l3ulidirig. ii. Raden Pata:"r I'jo. S.1 , Baloi Batam isiand 29432, lndcnesiaPnone/Facs: +62 77 I 1,5657 51456?92
Ema!i: jurn. [email protected]:.!d
RffiP#RT *F ,S'gUALYSf;$
CV. TNB Chemicals Ind*nesiaKonrp. Guciang $eiu Blok A i\c.7 i.- .
Batarn Centre - Batam
Said to be Chemicai
Lead, Cadmium, ,Vercury, and Chicnnium Vl Anaiysls'1. Refe:-ence ta US EFA 305$ B, lor Leai Conteir'i
Analysis was pei'formed by Atomic Absorption Spectronreter
2, iteference to BS EhJ 1 122 :2AA1, Method B fos" Caclrnium CcntentAnalysis was perl'ortneci by Atornic Abscrption Spectlcnieier
3. Reference to US S?A74718, fcr lr/iercury CcntentAilalysis vras pertoffried lly Atomic Abs':r^pticn Spectioi-nei*r
4. Reference tc US EpA 30G0A - Meti":oci 7195, for l-lexavaie;:l Chrc;';':iuni
Analysis was perfo*-,led by $pectrcpirci'irneteI
26i05i2009
26/0512009 to 28/0512009
lPA, l-{exane, Devesgi 1425, Methano}, De - l"latured Ethyl Alccirc'i, Etirartoi
99.5%, Ethanol 99.9%, lV'lethylene Chioride , D - 1 131
Fana;Treters
I Cadmiunr (CC
- Mercury (Hg)
ThiSCefi{icatel|epoiiisiSsu€dunneiourGenelaiTeintsaldConoi|ions,Copyci'.ihjCiisavaiiableup0ireqUes|orr,aybeaccessecat./vt1'su00f:f00'oo':d
ETh,i. LJ U.0SC]"3.200 g
Sn* Cqelpq,al Seririces
1l'ri
f1u'''l\''s$qan*;
[."lrrit i Results
ppm l < C.CC01
ppm | ' 0.01- Ch;"onnium l--lexavalent (Cr6*)
Chctnlcalt
I iSiiii illii liiHi iiilllii! iiiit Ellii liii iili
I'IATERIAL SAFETY DATA SHSET ExxonHobil Chenical
PRODUCT NAME: EXXSOL DSP 80/100 FTUID(novssol 1425)
{,- . PAGE 1 OF LLMSDS NUMBERI ITDHP-C-60260REVISIOiiI: 12 llarch 2004
1 CHE!TCAL PRODUCT AND COMPANY TDENIIFICATION
IDENTIFICATION OP THE SUBSTANCE: EXXSCL DSP 8O/1OO PLUTDThis is a petroler-lh-rJetiued r:ompler sr.rb.5ta$ce
CIIEMICAL FAIIILY: Alj.phatlc. cycloparaffinie hydrocarbons
PRODUC? DSSCRIPTION'Clear col.ourless J-iquid
SUPPLIER:Exxonltobil cbemical Asia Pacific (Regn. No. 52893?2qc)(A division of ExxoDMobil Asia Pacific Pte Ltd - Regn- No. 196800312N)Internediates1 HarbourFront Place, #06-00 HarbourFront ?ower One
singapore 098633Telephone: 65-6885 8005Facei-niIe: 65-6885 8233
EHERGENCY TEI,EPI'ONE }IUMEER:65-6885 8005 (office hours)65-966 50900 (outside of,fice hours)
2 COI4POSIT]ON/INFORHATION ON INGREDIENTS
CAS NUUBER: 6{?42-49-0
HAZARDOUS COMFONENTS SYMBOL/R-PHRASE Wtttand/or c[s NUMBERS) OR OEt
N-HEXANE 15.0-20.0110-5{-3 F,Xn,xi,H,R11'R38'R{8/?0,R51153rR62,R65,R6?
HEpTANE AND ISOIIERS 32.0-36-0F, Xn, Xi, N, R11, R38, R50/53, R65, R67
cycLoHExANs 25.0-27.0110*82-? F,Xn,Xi,N,R11,R38.R50/53,R65'R67
Sxxon UoLit Corporation includes Exxontlobil Chemical Company and the ExxonllobilChenical Affiliates-
@nNHCV. TNB CHEMICALSINDONESIA
PR1NT DAIE: 16 Apcil 2004 Cont.
MATERIAL SAFETY DA?A SHEET ExxonMobil Chemical
PRODUCT NAI'IE: EXXSOT DsP 801100 FTUID PAGE 2 OF ].1MSDS NUUBtnt fiDHP-C-60260REVISION: 12 March 2004
METHYTCYCTOI{EXANE108-8?-2
3.0- ?.0Xn, Xi,N. R38, R51/53, R65, R5?
3 I{AZARDS IDENTIFICATION
HEALfII HAZARDSIrrj-tating to skinIlarmful : danger of serious danrage to health by prolonged exposure throughinhal ation.Possible risk of impaired fert.ility.Harmful : may cause lung damage if swallowed-Vapours may cause drowsiness and dizziness
ENVIRONMENTAI, HASARDSToxic to aquatic organisms, may cause long-term adverse effects in theaquatic environrneot.
P}IYSICAI A}ID CHEUICAL ITAZARDS / FIRE AND EXPLOSION HAZARDSg Extreme hazard. Leaks of gas or spills of liquid can readily form
flanntnable mixtures at temperatures at or above the flash poirt.o static Discharge, Product can accumufat€ static charqes which can
cause an incendiary el-ectrica] discharge.
4 FIRST AID MEASORES
INHALATION:o lJsing proper respiratory protection, innrediatery remove the affected
victim from exposure. Administ,er artificial respirati.on if br€athingis stopped. Keep at re$t, Call for prompt medical attention.
SKIN CONTACT:o Flush with large amounts of rrater; use soap if availabLe.o Remove grossly contaminated clothing, including shoes, and launder
before reuse.EYE CONTACT:
o Flush eyes with large amounts of r.rater until irritatj.on subsides. ff
PRINT DATE: I-6 April 2004
MATERIAL SAEE?Y DA?A SIiEET
Cont.
ExxonMobil Cherarcal
ffiu*
PRODUCT NAME: EXXSOL DsP 801100 F'LUID PAGE 3 OF 11
MSDS NUMBER: HDHP-C-60260REVISION: t2 March 2004
irritation Persists, get medical attention'1NGESTION:
o If snallowed, DO NOT induce voniting'rnedlcal attention'
Keep at rest. Get ProftPt
--l--llT:lTT:::-Yi::Y:------FIRE FIGHTING PROCEDURES:
oUse$ater=p'aytocoolfireexposedsutfacesandLoProtectpersonnel. Sfrut off "fuel" to fire' If a leak or spj-ll has not
igniled, ,r""-t"a,*t sptay to disperse the vapors and to prolect men
aitenPting to stop a leak'oEltherallowfire.toburaundercontrol}edconditionsorextinguish
with foam ot aiy chernical' Try to cover liquid spilLs wiLh foam'
SPECIAL FIRE PRECAUTIONS:o Al'oict "pr-yiig-"uter
ditectly into storage contalners due to danget of
boilover.o see also Section 4 trPIRST AID MEAsuREs" as He1} as Section 10 "STABILITY
AND REACTIVITY".
HEZARDOUS COMBUSTION PRODUCTS:
No unusual
- -: - -l::i::::i:-::::i:: -Yi::Y: - -
I,AND SPIIL:o Elirninate sources of ignition' l{arn occupants of downwind areas of
fireandexplosionhazird.Preventliguidfromenteringsewers,ratercourses, or low areas'
o Keep public ttiy' sftut off source if possible to do so t'ithout hazard'
Advise authorities if substance has entered a watercourse or sewer or
haseontaminatedsoilorvegetation.Takenreasurestominimizetheeffect on the ground nater'
o Contain spilled liguid with sand or earth'o Recover uV p"*pins'irr" "n explosion proof or hand putnP) or with a
suiLable .u"oiteni_ If liquid is too viscous for purnping, scraPe uP
uithst,o.,ers-o'pallsandplaeeinsuitablecontainersforrecycleordisPosal -
oconsul|anexPertondisposalofrecoverednaterialandensureconformity to loeal disposal regulaiions'
ExxonMobil Chemicaf
TNBChemicols
MATER]hL SAFEIY D}JA SIiEEf
CV. TNB CHEMICALS INDONESIA
PRODUCT NAME: EXxsoL DSP 80/100 l"tulD PAGE 4 OF 11
l.tSDS NUI4BER: llDltP-C-60260REVISION: 12 March 200t1
o See Section 4 "FIRST AID MEASURES" as wellREACTIVITY" -
as SeCtiON 10 DSTABILITY AND
I{AIER SPILL:o Eliminate aources of ignition. ?ilarn occupants and shipping in downwind
.areas of fire anal explosion hazard and request them to stay clear'o Notify port or relevant authority and keep Public away. shut off source
ifpossibletodosowit'houthazard.Confineifpossible.o Renove fron surface by skimming or nith suitable absorbent$' If allowed
by local authorities and environmentai agencies sinking ancllor suiEabledispersaats nay be used in non-conEined waters'
o Consult an expert on dispOSal Of any recovered material arrd ensure
conformity to ]ocal disposal regulationso See atso section 4 "flRST AID I{EASURES" and Section 10 'STAEILITY AND
REACTIVITY".
? IIANDLTNG AND STORAGE
STORAGE TEMPERATURE (DegC) : AmbientTRAIISPORT TEMPERATURE tDeqc) : AnbientLOADING/UNI,OADING TEIIPERATURE (DeSC} : ANbiENt
VISCOSITY (cst) I 0.56STORAGE/TRANSPORT PRESSTIRE (KPA} : AIMOSPhETiC
ELBCTROSTATIC ACCUMUTArION HAZARD? Yes, use proPer grounding procedure
UST'AL SHIPPING CONTAINERS:
Rail wagons, barges or drums
HA?ERIALS AND COATINGS SUITABTE:
Carbon Stee]StainlesE SteelPolyethYlenePolyproPyleneTelfon
MATERIALS AND COATINGS UNSUITABLE:Natural RubberButy1 RubberEPDUPolYstYrene
ExxonMobil Chenical!.{A?ERIAL S}FETY DAT} SIIEET
ffinu*
PRODUCT NAME: EXXSOL DSP 80/100 FLUID PAGE 5 OF 11MSDS NUMBER: ttDtlP-C-50260REVISION: 12 l.{arch 2004
Cornpatibility with Plastic !{aterials ean vaty; we t.herefore tcconmendthat compatlbility is tested prior to use.
STORAGE I HENDLING, GEI{ERAI NOTES
o Keep concainer closed. Handle containers with care. Open slowly inorder to cont.rol possible pressure release- Store in a cool,well-ventilated place away from inconpatible materials.
o DO NOT handle, store or open neax an open flame. sources of beat orsources of igniti.on. Protecb materi,al from direct sunlight'
o l{ateria} r.rill accumulate static eharges trhich may cause an electricalspark (ignition sourcel, Use proper bonding and./or grounding procedures.
o D0 NOT pressurize, cut, heat' or weld containers. EmPty Productcontainers may contain product residue. Do Nof reuse empty containers*ithout cornmercial cleaning or reconditioning-
ADDITIObIAL $ARNINGSContainer remains hazardous uhen etnpty. Continue to observe allprecautions.
8 EXPOSURE CONTROI,S/PERSONAL PROTECTION
SNGINEERING CONTROL MEASURES / VEIITILATIONThe use of local exhaust ventilation is recorunended to control processemj.ssions nea! f,he source. Laboratory sarnples should be handled in a labhsod- Provide rnechanical venti.lation of confined spaces. Useexplosion-proof ventj.]ation equiplent'
OCCUPR?IONAL EXPOSURE L1I4IT5
Exxonuotil recorsnends, for t.otal hydrocafbons, based on composition andusing the Reciprocal Calculation Procedure {RCP):
Naphtha {Petroleunl, hydrotreated light;tlIA: 600 rng/n3 (159 ppm), ExxonMobil (2000) .
This product is a complex substance wbicb contains Ehe followingeonponent(s) nith a recognised or recornmended oEL value:
Cyclohexane;TwA: 100 ppn {344 ng/m3), ACGIH {2002) .
PRINT DATE: 16 April 2004
YIA"ERIAL SAFETY DAA SHEET
Cont.
ExxonMobil Chemical
PRODUCT I'IAHE: EXxsoL DSP 80,/100 FLUID PAGS 6 OF 11
@rNB\-/ chemicotsCV. TNB CHEMICALS INDONESIA
MSDS NUMBER: IIDHP-C-60260REVISION: 1? March 2004
Heptane;TwA: 400 pprr (1640 mq/mi) StEL: 500 ppn t2050 ftS/m3), €qr n-lleptane'ACGIH (2002).
n-Ilexane;TWA: 50 pptn (1?6 mg/n3) {SKIN} , ACGIH {2002't .
PERSONAL PROTECTION
GENERAT ADVICEThe use and choice o: Fersonal ?rotection equipment is reialed to thehazard of the product, the uorkplace, and the way the product is handled.In general, $e recoflunend as a nininum safety precaution that safetyglasses with slde-shields and workclothes proteeting arns, legs and bodybe used, In addigion, any person visiting an area r*here this product is'handled or processed slrould at f,east wear safety glassee uithside-shields.
SPECIAL ADVICEBased on and linrited to ExxonMobil's experience of this product as such.the fo]louing special advi.ce is belj.eved to provide satisfactoryprotection for the industrial user or handler-
F€SPIRATORY PROTECTIONWhele concentrations in air may exceed the limiEs given in this sectioo,it j:s reconnended to use a half face filtet ltask to plotect fromoverexposure by inbalation. Suitable filter material depends on theamount aod type of chemicaLs be5.ng handled in the worhplace, but filtermaterial of type trArt or sirnilar may be considered for use.
H}ND PROTECTIONWhen handling this product, it is recornrnended to *ear chernical resistantgloves. The choice of suitable protective glgves depends on uorkconditions and ehat chemicals are handled, but we have positive experiencewlth gloves made of Nitrile. Gloves should be replaced immediately ifsign of degradation is observed.
EYE PROTECTIONSee general advice.
SRIN/BODY PROTECTIONSee general advice.
MATERIAL SEFETY DATA SitEEI Exxon!1obil Chernical
16 Apri
PRCDUCT NArrlE: EXXSOL DSP 801100 FLUID PAGE 7 OF }1
.ffi\{f'w}TNBV chemicols
CV, TNB CHEMICALS INDONEsIA
MSDS NUIIBER: HDHP-C-60260REVISION: 12 Harch 2004
_-:-_:i:::::_i::_:i:::i:-:i::::::::-_--_-__ -----&3---
These are indicatirre values only. Please refer also to the productspecification sheet.
9.1 General Information
PHYSICAL STATE: LiqUidFOR}1,/COIOUR:ODOR:
Clear colourless liquidMild odour
FRuEZ./MELT/Potxr: <0 DegC
BoILING POINT RANGE: between 75 and 115 DegCVAPOR PRESSURE {20 DegC}: 8.65 kPaVAPOR PRESSURE (38 DeqC): 19.44 kPaVAPOR PRESSURE {50 DegC}: 31.4? kPaDENSITY (15 Deqc): 0.?20 kg/dm3VAPOR DENSI?Y t101.3 kPa/air=l):
EVAPORATISN RATE (n-Bu Acetate= 1): 6.000
9.2 Health, Safety 6 Environrnental Information
FLAST{POINT {): -15 DegC
AUTOIGNITION TEMPERAfURE: ) 200 DegCSXPLOSM IIUITS (in air): betreen 1 and ? VoltSoIUBIIITY IN WATER (20 DegC): 0'00 l{tt
VISCOSITY (25 DegC):{40 DegC}:
9.3 Otber Inforrnation
I4OI,ECUIAR 9JEIGIIT:COEFF. OF THERHAL EXPANSION (L'q.}:IS MATERIAL HYGROSCOPIC:
0.56 cSt0.43 cst
940.00126 DegC
NO
ASTM D{052Not ava.ilable
ASTM D445Approxinate
Estimated
PRINT DATE: 16 April 2004
XE.TERT,AL SAFETY DATA SHEET
Con!.
ExxonMobil Cheni.ca1
PRODUCT NAI{E: EXXSOT DSP 80/100 FIUID PAGE 8 OF 11MSDS NUMBER: HDHP-C-60250REVISION: !.2 !4arch 2004
10 S"EBII,ITY AND REACTTVITY
@rhrnCV TNB CHEMICALS TNDONESIA
TIAZARDOUS POTYMERIZATTON?CONDITIONS TO AVOID POLYMERTZATION:
Not Applicable.
STABTTITY:CONDITIONS TO AVOID INSTABITITY:
Not Applicable.
No
StabLe
MATERIALS AND CONDITIONS TO AVOID (INCOMPATTBILITY):Serong oxidizing agents.
HAZARDOUS DECOMPOSITIQN PRODUCTS :Non€
11 TOXICOISGICAT INFONMETION
ACUTE:INHALATTON:
o Vapor concentrations above recommended exposure levels nay be irritatingto the eyes and the respiratory tract, may cause headaches anddizziness, could be anesthetic and may have other central nerv$us systemeffects.
SKIN CONTACT:o Low order of toxiciby.o Frequent or prolonged contact. may defat and dry the skin, Ieadlng to
discomfort and dermatitis.EYE CONTACT:
o Will eause eye discomfort, but will not injure eye tissue.1NGESTION:
o Minirnal toxicity.o Small amounts of liquid aspirated into the respiratory systen during
ingestion or from vonit,ing may cause bronchopneumonia or pul.nonaryedema.
CHRONIC:This product contains n-hexane. Overexposure to n-hexane may causeprogressive and potentlally irreversi.bl.e damage to the peripheral nervoussystem, particularly in the arms aod 1egs.
PRINT DATE: 16 Apri.l 2004
I4ATERIAL SAFETY DATA SEEET
Cont.
Exxont'tobiL Chemica-L
FRODUC1 NAHE: BXX9or DSP 80,/100 FtUlD PA6E 9 OF 11MSDS NUMBER: HDHP-C-60260REVISfON: 12 !{arch 2004
Additional. info:mation is a'.'ailable on speclal request.
@R'rHCV. TNB CHEMICALSINDONESIA
L2 ECOI.OGICAT INFORN'ATION
ENVI RONI.IENTAI MOB I LITYThis producL ie highly volatile and will rapidly evaporatb*to tlte air ifreleased into the nater-
EWIRONMENIEL DEGRADAB]TITYThis product can degrade rapidly in air.this substance is expected to be removed in a $astei{ater treatmentfacility-Sased upon data for a simifar component or preparation, or estirnated data.This product is exp€cEed to biodegrade raFidly and be "readily"biodegradable according to oEcD guidelines.
ECO?OXICITY AND BIOACCUHUIAT]ONBased upon daba for a sinilar component or preparation, or estinated data-Expected to be toxic to aquatic organisms.Long Lerrn adverse effects to aguatie organisns are possible if continuousexposure is maintained.
13 DISPOSAL CONSIDSRATIONS
The following advice only appliee to the product as supplied.Codbination pith other materials may well indicate another route ofdisposal- If in doubt' contact the local Exxon}lobil affiliateor local AuthoriEies.Bnpty packaging should be taken for recycling, recovery or disposal througha euitably gualified or licensed contractor.Care should in any case be taken to ensure eompliance ritb nati'onaland local regulations.
This producE is NOT suitable for disposal hy either landfill or vianunicipal seuers, drains, natural st,reams or rj"vers.This produet is ashless and can be burned directly in aPptoprlateequipment.
I'{ATERIAI SATEfY DATA SHEET ExxonMobil Chenica]
PRODUCT NAME: EXXSOT DSP g0/100 Ftur,D PAGB 10 OF 11ttSDS F.IMBERT HDHP-C-60260REVISIoN: 12 }larch 2006
14 TRANSPOR! INFORMATION
@IHHCV. TNB CHEMICALS INDONESIA
tANDCLASS: 3 PG: II UN .NUHBER: 3295
. HAZCHEM CODE: 3eIE SUBSIDIARY RISK:TRANSPORT DOCUF1ENT NAME:
IIYDROCARBONS, IIQUID, N.O-S. (n-hexane), CLASS 3, UN 3295. PG Ir '(-15 DegC c-c.) \*r'
SEA - II.IDG {PACKAGED GOODS AND BLCs)CTASS: 3 PG: fI UN NUMBER: 3295I,IARINE POI,LUTANT: NO E!,S HUMBER: F-E, S-DRISK TABEL: 3 SUBSIDIARY RISK:TRANSPORI DOCUMENT NAME:
HYDROCARBONS, LIQUID, N.O.S. (n-hexane), 3, UN 3295' PG II, (-15 DegCc.c. )
AIR {1UA0/rAIA}CTASS: 3 PG: fI UN NU!{BER: 3295
PROPER SHIPPING NAF1E:
IIYDROCARBONS, IIQUID, l,l .O.S. (n-hexane)
15 REGULATORY INFORT"{ATION
CI,ASSIT'TCATION AI{D LABELLINC ACCORDING TO EUROPEAN DIRECTIVESCLASSTTICATTON/ sYMEoL : HIGHLY FI"AI"TMABLE /FCLASSIFICATION/SYMBOL: HARHFUL./XnCLASSIFICATIONISYMBOL: DANGEROUS FOR rHE ENVIRONMENT/NGOVERNTNG DIRECTIVE:
Dangerous Substances Directive 67l548lEC' as modified.
NATURE OT SPECIAT RISKR11 Highly flanrnableR38 Irritating to skinR48/20Harnful : danger of serious danage to health by prolonged exposure throughinhalation.
PBINT DATE: 16 Apt1l 200{
MATER]AI SAFETY DATA SHEET
Cont.
ExxonMobil Chenical
PRODUCT NAHE: EXXSOL DSP 80/100 FTUID PAGE 11 OF 11MSDS NUMBER: !IDHP-C-60260REVISION: 12 llarch 2004
R51 /53Toxj.c to aquatic organisms. may eause long-term adverse effects in theaguatic environnenE.
".62 PossibLe risk of :npaired fertility.
@n*{HCV. TNB CHEMICALS INDONESIA
R65R6?
Harmful : may cause lung damage if swallowed.vapours may cause drowsiness and dizziness
SAFETY ADVICES09 Keep containeE in a rell ventilated place516 Keep away from sources of ignition-No SnokingS23 Do not breathe gas,/furnes/vapour,/spray \'-iS24 Avoid contact Hith skinS43A In case of f,ire use sand, earth, chemical powder or foams5?Use appropriate contain€r to avoid environmental contamination.s60This naterial and/or its container must be disposed of as hazardous waste.s62If, swal.Iowed, do not induce vomitinq : seek medieal advice innediatelyand shor* this container or label.
15 OTI{ER INFORI,IATION
RSVISION SUMMARY:
Since 2{ December 2003, this MSDS has been revi.sed in Section(s):9
This information relat€s only to the specific material designated and may notbe valid for such material. used in combination uith any other materials or in'any process. Such infornration is to the best of ExxonMobil Chemical Cornpany'sknowledge and believed accurate and reliable as of the date indicated.Honever, no representation, parfanty or guarantee is nade as to its accoFdclrreliability or completeness. It is the user's responsibiliCy to satisfyhimself as to the suitabiliEy and corryleteness of such j.nformation for his onnparticular use.
PRMT Df,,TE: 1.6 April 2004
ffin,ur'
