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Vanessa ArrudaGerente de Marketing Técnico LatamMarzo 2012
Sinergia e Incompatibilidad entreFiltros Solares
Page 11
Agenda• Sol y piel – porque necesitamos la protección UV?
• Cambios Regulatórios y Retos
• Eligiendo filtros UV y sinérgia entre ellos
• Fotoestabilidad y desempeño de PARSOL® 1789
• Tendencias de Mercado Europa
Page 22
Agenda
• Cambios Regulatórios y Retos
• Eligiendo filtros UV y sinérgia entre ellos
• Fotoestabilidad y desempeño de PARSOL® 1789
• Tendencias de Mercado Europa
•Sol y piel – porque necesitamos la protección UV?
Page
UVC UVB UVA
ULTRAVIOLETA VISÍVEL INFRAVERMELHO
100 280 320 400 800 1700
Efeitos
Bioquímicos
Efeitos
Bioquímicos*
Efeitos
Luminosos
UVA-1 (longo): 340-400
UVA-2 (curto): 320-340
*Arch Dermatol Res 1982;272:229-38; Photodermatol Photoimmunol Photomed 1992/1993;9:275-8
UVC UVB UVA
ULTRAVIOLETA VISÍVEL INFRAVERMELHO
100 280 320 400 800 1700
Efeitos
Bioquímicos
Efeitos
Bioquímicos*
Efeitos
Luminosos
UVA-1 (longo): 340-400
UVA-2 (curto): 320-340
*Arch Dermatol Res 1982;272:229-38; Photodermatol Photoimmunol Photomed 1992/1993;9:275-8
Radiación UVB y UVA
Page 44
Rayos UV son losresponsables por unos
90% delfotoenvejecimiento
prematuro!
Radiación UVB y UVA: daños en la piel• Rayos UVB
• Alta energía pero no penetra en la piel muyprofundo – principalmente afecta laepidermis
• Primera causa de quemaduras solares• Causa daños en el DNA y contribuye al
cancer de piel en un 65%• Actua como inmunosupresor• Contribuye al fotoenvejecimiento
• Rayos UVA• Penetra mais profundamente en la dermis,
dañando el colágeno y afectando laproducción de elastina que lleva a lasarrugas
• El daño en la piel es cumulativo y la mayorcausa de fotoenvejecimiento
• Estimula la producción de melanina ypuede causar la pigmentación
• Causa danõ en el DNA y contribuye alcancer de piel en un 35%
Page 66
Cual es la edad de la piel?
Factores intrínsicos de la edadvs.Factores externos(ej. fotoenvejecimiento)
Page 77
• Las estaciones – más alta en verano y menor en invierno.• Hora del día – más alta al medio día• Latitud – más alta en Ecuador• Altitud – alta radiación UVB
La radiación UVB depende de vários factores
Radiación UVA es mas constante durante el año y horas del día
102030405060708090
100
Page 88 *Sources: The Skin Cancer Foundation, Mayoclinic.com, AAD.org
Y porque la protección UVA?
• Prevención del cancer de piel: UVAcontribuye en un 35% de todos los canceresde piel
• Prevención de daños en la piel, daños alDNA, mutaciones p53
• Prevención de la actividad inmunosupresora
• Prevención de manchas de edad y otraspigmentaciones
• Prevención del fotoenvejecimiento yarrugas
• Prevención del 90% de todos los sintomasdel envejecimiento prematuro!
Page 99
Agenda• Sol y piel – porque necesitamos la protección UV?
• Cambios Regulatórios y Retos
• Eligiendo filtros UV y sinérgia entre ellos
• Fotoestabilidad y desempeño de PARSOL® 1789
• Tendencias de Mercado Europa
•Cambios Regulatórios y Retos
Page 1010
CategoryLabeled SunProtection
Factor
Measured SunProtection
Factor
Recommendedminimum UVA
ProtectionFactor
Recommendedminimumcritical
wavelength
Very High Protection 50+ > 601/3 of labeled SPF
370nm
High Protection50 50 - 59.9
30 30 - 49.9
Medium Protection
25 25 - 29.9
20 20 - 24.9
15 15 - 19.9
Low Protection10 10 - 14.9
6 6 - 9.9
Threshold: go / no go criteria
Recomendación Europea 2006
UVA
Page 1313
Agenda• Sol y piel – porque necesitamos la protección UV?
• Cambios Regulatórios y Retos
• Eligiendo filtros UV y sinérgia entre ellos
• Fotoestabilidad y desempeño de PARSOL® 1789
• Tendencias de Mercado Europa
Eligiendo filtros UV y sinérgia entre ellos
Page
Alto desempeño en SPFUV A contribution to SPF
0,000
0,001
0,010
0,100
1,000
10,000
290 300 310 320 330 340 350 360 370 380 390 400
rela
tive
Ene
rgy
nm
Erythema Action Spectrum
0
0,2
0,4
0,6
0,8
1
1,2
290 300 310 320 330 340 350 360 370 380 390 400
W/q
m*n
m
nm
UV-SSR Source Spectrum
Erythema Action Spectrum
0,00
0,01
0,01
0,02
0,02
0,03
0,03
0,04
0
0,2
0,4
0,6
0,8
1
1,2
290 300 310 320 330 340 350 360 370 380 390 400
W/q
m*n
m
nm
UV-SSR Source Spectrum
Erythema Action Spectrum
Effective Erythemal Radiation during SPF test
90 %95 % 98 %Erythemal
Energy
14
Page
Absorptance - 2.9 % -3.5 % -2.9 % -1.9 %
UVA Contribution - Experimental Data
Una buena protección UVA entrega 2 – 4 % Absorbancia:también colabora para un alto SPF!
Avobenzone concentration
SPF
in v
ivo
16
Alto desempeño en SPF
Page
Productos de mercado con nivelesde estabilización 100% contienen:
• Octocrileno
y/o
• Uso de estabilizantesadicionales, comoMethilbenzelideno canfora(MBC)
70%
75%
80%
85%
90%
95%
100%
3.0% 4.0% 5.0% 6.0% 7.0% 8.0% 9.0%
Octocrylene use level
% HPLC Recovery Avobenzoneafter Radiation
La estabilización de la Avobenzona esnecesaria
17
Alto desempeño en SPF
Dose-Response for a O/W system
Page 2020
Overview de los Filtros Solares DSMButhyl Methoxydibenzoylmethane (BMDBM) UVA filter
Ethylhexyl Methoxycinnamate (OMC) UVB filter
Octocrylene UVB filter
4-Methylbenzylidene Camphor approved UVB filter outside US
Ethylhexyl Salicylate UVB filter
Homosalate UVB filter
Phenylbenzimidazole Sulfonic Acid UVB filter (water soluble)
Titanium Dioxide UVB filter (inorganic)
Titanium Dioxide TX50 AB UVB filter (inorganic)Polysilicone-15 approved UVB filter outside
US (polymeric) (permitted inhair care applications and as afoto stabilizer in US)
Page 2121
INCI name: Buthyl Methoxydibenzoylmethane (BMDBM)USAN: Avobenzone E1
1 = 1100 - 1180 (Ethanol)max: 357 nm (UVA absorber)
PARSOL 1789
• Uso de solventes para mantener el producto ensolución
• Calentar hasta 80 - 85 °C : solución clara
• Uso de agentes quelantes para evitar complejoscon metales de transición
• Seleccionar con cuidado sistema de preservación(no formaldehyde y sus donantes)
• Impurezas de hierro pueden llevar a cambio decolor
Avobenzona (PARSOL® 1789) es 100% fotoestable cuando esformulada junto con Octocrileno (PARSOL® 340) y/o 4- methylbenzilidenocanfora (PARSOL® 5000)
Page 2222
INCI name: OctocryleneUSAN: Octocrylene
E11 = 340 - 370 (Ethanol)max: 303 nm (UVB absorber)PARSOL 340
•PARSOL® 340 es fácil de manejar. Puede ser facilmente disuelto en la fasegrasosa de la formulación.
•PARSOL® 340 es compatible con la gran mayoría de los ingredientescosméticos
•PARSOL® 340 es un excelente fotoestabilizador de la Avobenzona
•PARSOL® 340 es un óptimo solvente de la Avobenzone (25%)
Benefícios 3 en 1:- Filtro UVB- Estabilizante para Avobenzone- Solvente para otros filtros UV
Page 2323
Nuevas oportunidades para el OctocrilenoLista de filtros UV permitidos y su concentración máxima de uso
Calculado como Esther 14%:
Page 2424
INCI name: 4-Methylbenzylidene Camphor
E11 = 930 - 990 (Ethanol)max: 299 nm (UVB absorber)PARSOL 5000
• Se recomienda usar solventes para mantener el producto en
solución
• Calentar hasta 80 - 85 °C para obtención de una solución clara
• MBC es un excelente estabilizante para Avobenzone
Page 2525
INCI name: Ethylhexyl Methoxycinnamate (OMC)
PARSOL MCXE1
1 = 835 - 865 (Ethanol)max: 308 nm (UVB absorber)
• PARSOL® MCX es facil de manejar. Se mantiene liquido y nocristaliza en la formulacion.Puede ser facilmente disuelto en la fase oleosa de la formulación
• PARSOL® MCX es un excelente solvente paras otros filtros UV
Page 2626
INCI name: Phenylbenzimidazole Sulfonic Acid
E11 = 920 - 1000 (Water)max: 306 nm (UVB absorber)PARSOL HS
• Filtro UVB soluble en água. Necesita neutralización, con las bases: (para 1gde PARSOL® HS)– KOH 100% 0.20 g– NaOH 100% 0.15 g– TEA 100% 0.65 g– AMP 100% 0.35 g– Tromethamine 100% 0.50 g
• Usando AMP o TEA como neutralizante no disminuye la viscosidad de laemulsión
• Formular siempre en pH mayor que 7,0 para evitar cristalización
Page 2727
INCI name: Ethylhexyl Salicylate
PARSOL EHSE1
1 = 168 - 182 (Ethanol)max: 306 nm (UVB absorber)
• EHS es facil de manejar. Se mantiene liquido y no cristaliza enla formulacion.Puede ser facilmente disuelto en la fase oleosa de laformulación
• EHS es un optimo solubilizante para PARSOL® 1789
Page 2828
INCI name: Homosalate
PARSOL HMSE1
1 = 170 - 180 (Ethanol)max: 305 nm (UVB absorber)
• HMS es facil de manejar. Se mantiene liquido y no cristaliza enla formulacion.Puede ser facilmente disuelto en la fase oleosa de laformulación
• EHS es un optimo solubilizante para PARSOL® 1789
Page 2929
INCI name: Titanium Dioxide, Silica, Dimethicone• Primary particle size: 17-23*nm (mean value)
max: 316 nm (UVB absorber)
Rutile Titanium Dioxide Core,
Silica, Dimethicone,
PARSOL TX
Page 3030
PARSOL TX
• TX es fácil de dispersar. Puede ser añadido directamente en lafase oleosa de la formulación.
• TX es compatible con la Avobenzone y la gran mayoría delosingredientes cosméticos, especialmente espesores deacrilato
• TX50 AB es la dispersion del PARSOL TX en Alkyl Benzoate
Page 3131
INCI name: Polysilicone-15
E11 = 160 - 190max: 312 nm (UVB absorber)PARSOL SLX
• PARSOL® SLX es estable en pH del 4-9. puede ser añadido enla fase oleosa y calentado hasta 80°C por 6 hs sin perderactividad.
• PARSOL® SLX es compatible con filtros organicos einorganicos, emolientes y emulsificantes mas usados
• PARSOL® SLX es aprobado en EU con máxima concentraciónde uso permitida de 10% en formulaciones cosméticas
Page 3232
PARSOL SLXAplicaciones
Sun Care/ Skin Care
• PARSOL® SLX contribuye para la obtención de alta protecciónsolar
• Para productos Sun Care y Daily Care, para productos parapieles sensitivas
Hair Care
• Protege el color de los cabellos teñidos
• Mejora la peinabilidad del cabello después de la radiación UVcuando es comparado con el placebo
• Silicon base product: efecto condicionante, aumento delbrillo, …
Page
Argentina
The Natura Plant Verano range is enriched with coconut lipids andUV filter and claimed to hydrate and restore damaged hairstrands, preparing them for sun exposure while providing aprotective anti-UV layer to provide long-lasting protection.Available as part of the range are: Crema para Peinar (SummerCombing Cream), retailed in a 170ml pack; and Mascaril…
33
Natura Plant Verano Summer Combing Cream
1736314
Natura Cosmeticos
Feb 2012
Aqua, Cetearyl Alcohol, PPG-15 Stearyl Ether, Dimethicone, Dimethiconol, TEA-dodecylbenzenesulfonate, Elaeis Guineensis Oil, parfum, Polysilicone-15, BehentrimoniumChloride, Cetrimonium Chloride…
Hair Treatments
Seasonal, Damaged Hair, Botanical/Herbal, Ethical - Environmentally Friendly Package, UVProtection, Long-Lasting*, Moisturising / Hydrating
Country:
Company:
Date Published:
Sub-Category:
Ingredients:
Claims:
ARS56.0$13.14 / €9.91
Price (local):Price (majorcurrencies):
Page
Israel
Schwarzkopf Gliss Hair Repair Color Protection 30 Reflex-ShineTreatment repairs coloured, dyed hair from inside out. The leave-in treatment protects the colour from fading, and gives up to90% colour retention after 30 applications. The product repairsthe hair structure and smoothes the hair surface for animmediate, shimmering shine. It offers tangibly no…
34
Schwarzkopf Gliss Hair Repair Color Protection 30 Refle…
1141687
Schwarzkopf & Henkel
Jul 2009
Aqua, Alcohol Denat. (Denatured), Polyquaternium-37, Trisiloxane, Dimethicone, Mica,Amodimethicone, Polyquaternium-11, parfum (fragrance), Prunus Armeniaca Kernel Oil, Panthenol,Propylene Glycol, dicaprylate/dicaprate, Polysilicone-15, Glycerin, Laurdimonium HydroxypropylHydrolyzed Wheat Protein (Hydrolyzed), Polyquaternium-10, Linalool, Hexyl Cinnamal, Lactic Acid,PPG-1 Trideceth-6, Cetrimonium Chloride, Cyclomethicone, Hydrolyzed Keratin (Hydrolyzed),Trideceth-12, Butylphenyl Methylpropional, Benzyl Alcohol, L-limonene, Coumarin, CI 77891
Hair Treatments
Brightening / Illuminating*, Time/Speed, Damaged Hair
Country:
Company:
Date Published:
Sub-Category:
Ingredients:
Claims:
ILS39.99$10.19 / €7.34
Price (local):Price (majorcurrencies):
Page
Photostability tests have been done in film:Photostability tests have been done in film:
70% ethanol / 30% Finsolv TN + Myritol 31870% ethanol / 30% Finsolv TN + Myritol 318
Filtros UV
1.PARSOL® 340 Octocrylene
2. PARSOL® 5000 4-MethylbenzylideneCamphor
3.Eusolex 4360 Benzophenone-3
4.PARSOL® SLX Benzophenone-3
5.Tinosorb S Bis-EthylhexyloxyphenolMethoxyphenyl Triazine
Estabilizantes6.Tinogard Q Tris(tetramethylhydoxypiperi-
dinol) citrate7.Tinogard TL Benzotriazolyl Dodecyl
p-Cresol
8. Corapan TQ Diethylhexyl 2,6-Naphthalate
9.Hallbrite BHB Butyloctyl Salicylate
10. Polycrylene Polyester-8
11. Oxynex ST Diethylhexyl SyringylideneMalonate
Fotoestabilizantes para Avobenzona
Page 3939
Dissolving inDissolving in 50ml Ethanol
Glass plate 10cmGlass plate 10cm22
layerlayer 2mg/cm2 irradiationirradiation25 MED
~~ 70% evaporationevaporation
dryingdrying
analysis of solution :analysis of solution :- spectrofotometric- chromatographic
(e.g. HPLC)
light
Método de análisis de la fotoestabilidad
Page
Butyl MethoxydibenzoylMethane 4.0% 4.0% 4.0% 4.0% 4.0% 4.0% 4.0% 4.0% 4.0% 4.0% 4.0% 4.0%
Octocrylene 2.0%
Bis EthylhexyloxyphenolMethoxyphenyl Triazine 2.0%
4-MethylbenzylideneCamphor 2.0%
Benzophenone-3 2.0%
Benzotriazolyl Dodecyl p-Cresol 2.0%
Tris(tetramethylhydroxypiperidinol)citrate
2.0%
Polysilicone-15 2.0%
Butyloctyl Salicylate 2.0%
DiethylhexylSyringylidenemalonat 2.0%
Polyester-8 2.0%
Diethylhexyl-2,6-Naphthalate 2.0%
Content of BMDBM after25 MED 23% 77% 70% 69% 58% 53% 53% 45% 44% 43% 42% 34%
2% stabilizer
Butyl Methoxydibenzoyl Methane 4.0% 4.0% 4.0% 4.0% 4.0% 4.0% 4.0% 4.0% 4.0% 4.0% 4.0% 4.0%
Octocrylene 3.6%
4-Methylbenzylidene Camphor 4.0%
Diethylhexyl Syringylidene-malonat 4.0%
Bis EthylhexyloxyphenolMethoxyphenyl Triazine 4.0%
Benzophenone-3 5.0%
Polysilicone-15 4.0%
Benzotriazolyl Dodecyl p-Cresol 2.0%
Tris(tetramethylhydroxy-piperidinol)citrate 2.0%
Polyester-8 3.0%
Butyloctyl Salicylate 5.0%
Diethylhexyl-2,6-Naphthalate 5.0%
Content of BMDBM after 25 MED 23% 90% 87% 82% 81% 80% 53% 53% 53% 50% 50% 47%
2-5% stabilizer
Eficácia de los fotoestabilizantes
Page 4141
Butyl MethoxydibenzoylMethane
4,0% 4,0% 4,0% 4,0% 4,0%
Octocrylene 4,0% 4,0% 4,0% 4,0% 4,0%
Bis EthylhexyloxyphenolMethoxyphenyl Triazine
4,0%
4-MethylbenzylideneCamphor
2,0% 4,0%
Polysilicone-15 4,0%
Content* BMDBM after25MED 90% 100% 95% 100% 95%
* deviation ±5%
100% de estabilización de la Avobenzona es posible !!
Mezclas de estabilizantes
Page 44
Rutile or Anatas core
Silica, or Al2O3, Stearic Acidbetween 3% and 30% coatingmaterial
Dimethicone, Simethicone
INCI of ingredient CAS No. EINECS
Titanium Dioxide 13463-67-7 236-675-5
Silica 7631-86-9 262-373-8
Dimethicone(C2H6OSi)xC4H12Si
9016-00-6 polymer exempt
Recubrimiento del TiO2
Coated TiO2
PARSOL TX
Page 47
• BMDBM and TiO2 is a common combinationin sun-care and day-care in Europe and Asia Pacific.
• Al2O3 is one of the most commonly used coatingmaterial for TiO2.
• As a result, BMDBM - Al 3+ complex is formed
• Reduced amount of BMDBM is detectedif a formulation is analyzed, leading to potentialproblems in UVA protection, but more importantis the risk of crystal formation do to the lowersolubility of this complex.
• Solubility of 1789/Al complex 2% in Finsolv TN
• Problems with customers and authorities(reduced content of used and eventually charged Parsol 1789)
Estabilidad del desempeño de Avobenzonay TiO2
Page 48
400x 400x
• Formulation 3 months at 43°C,formulated with 10% Al coatedTiO2
• Same formulation, same storagetime with 10% of Parsol TX doesn’thave any crystals
Estabilidad del desempeño de Avobenzonay TiO2
Page
49
%
• 4% BMDBM
• 10% TiO2 /Aluminium Hydroxide /Stearic Acid
• HPLC Method
Formation of Al - BMDBM complex
An Al - BMDBM complex appears already after 2 weeks
Estabilidad del desempeño de Avobenzonay TiO2
Page 5656
Agenda• Sol y piel – porque necesitamos la protección UV?
• Cambios Regulatórios y Retos
• Eligiendo filtros UV y sinérgia entre ellos
• Fotoestabilidad y desempeño de PARSOL® 1789
•Tendencias de Mercado Europa
Page 5858
• More than sunburn prevention—it's balanced sundamage protection.
The truth is, most sunscreens don't protect againstboth UVB and UVA rays. But, now from Neutrogena,comes a complete line of Sun Protection productsfeaturing breakthrough Helioplex™ technology. Neverbefore has skin protection against the sun's rays beenso complete—or balanced.
"Helioplex™ delivers unbeatable UVAprotection. It works better to helpprevent damaging UVA rays frompenetrating deep under skin's surface.Dry-Touch technology absorbs excesssunscreen oils, leaving a clean,lightweight, non-shiny finish."
Enfasis en alto SPF, protección UVA, yConveniencia
Page 5959
Anti-edad, Protección UVA y UVB
New ultralight formula to hydrate the skin.WaterproofProtects DNA cells against damage caused by the
sunInnovative system of protective UVA and UVB
filters with folic acid to provide betterprotection from marks, lines and sun damage.
Page 6060
PIZ BUIN® IN SUN LOTIONHelioplex™ technology provides photostable UVA/UVB broadspectrumprotection while Vitamin E helps neutralise free radicals which causepremature skin ageing. A rich hydration complex helps your skinremain moisturised all day, leaving it smooth and silky soft. Sweatand water-resistant.AVAILABLE SPF's: 200ml - SPF 6, 10, 15, 20, 30, 50+
PIZ BUIN® ACTIVE FRESH COOLINGThe ACTIVE Fresh Cooling Spray cools the skincontinuous spray system is easy to applynon-greasy formula dries within secondsenriches the skin with moisture and essential vitaminsHelioplex™, a breakthrough technology newlydeveloped by PIZ BUIN®, provides photostable,efficient protection against harmful UVA/UVB raysSweat -and very water- resistant.AVAILABLE SPF's: 20, 30
Helioplex- Protección UVA/UVB avanzada
Page
Combinaciones de Filtros UV en productosBDF lanzados a partir de octubre 2011:
Butyl Methoxydibenzoylmethane (25),Octocrylene (17), Bis-ethylhexyloxyphenolMethoxyphenyl Triazine (14), EthylhexylMethoxycinnamate (11), Homosalate (9), SodiumPhenylbenzimidazole Sulfonate (8), EthylhexylSalicylate (7), CI 77891 (5) Titanium Dioxide,Ethylhexyl Triazone (4), Diethylhexyl ButamidoTriazone
Page
New Product Launches BDF since 11.2011• Nivea Sun Kids Caring Sun Spray SPF 50 + offers very high and
immediate protection for children's delicate skin. The product isvery water resistant and has a non-sticky, easily absorbed formulathat offers deep and long lasting moisture for smooth skin. It isformulated to help reduce the risk of sun allergies and has beenskin compatibility dermatologically tested and approved. Theproduct retails in a value size 300ml pack.
•aqua, glycerin, octocrylene, butylene glycol dicaprylate/dicaprate,alcohol denat., butyl methoxydibenzoylmethane, bis-ethylhexyloxyphenol methoxyphenyl triazine, homosalate,titanium dioxide, sodium phenylbenzimidazole sulfonate,ceteareth-20, methyl propanediol, C18-36 acid triglyceride,tocopheryl acetate, diethylhexyl butamido triazone, ethylhexylmethoxycinnamate, VP/hexadecene copolymer, acrylates/C10-30alkyl acrylate crosspolymer, trimethoxycaprylylsilane, trisodiumEDTA, ethylhexyl glycerin, methylparaben, ethylparaben,phenoxyethanol, BHT, limonene, linalool, benzyl benzoate,hydroxyisohexyl 3-cyclohexene carboxaldehyde, hexyl cinnamal,benzyl salicylate, butylphenyl methylpropional, alpha-isomethylionone, eugenol, citronellol, coumarin, parfum
Page
Nivea Sun Alpin Cream & Stick SPF 30Nivea Sun Alpin Cream & Stick SPF 30 is claimed to combine twoproducts in one: a cream and a stick; offering immediate protectionof the face and lips under extreme conditions, protecting the skinagainst the winter sun, cold, and wind. The cream is designed toprotect the face, while the stick is for the lips.
Aqua (water), butylene glycol dicaprylate/dicaprate, C12-15 alkylbenzoate, butylene glycol, glycerin, PEG-30 dipolyhydroxystearate,titanium dioxide, butyl methoxydibenzoylmethane, ethylhexyltriazone, isopropyl stearate, cera microcristallina, alcohol denat.,paraffinum liquidum, bis-ethylhexyloxyphenol methoxyphenyltriazine, panthenol, tocopheryl acetate, glycine, C18-36 acidtriglyceride, cetyl dimethicone, sodium starch octenylsuccinate,trimethoxycaprylylsilane, magnesium sulfate, trisodium EDTA,ethylhexylglycerin, phenoxyethanol, methylparaben,propylparaben, limonene, linalool, benzyl benzoate,hydroxyisohexyl 3-cyclohexene carboxaldehyde, hexyl cinnamal,benzyl salicylate, butylphenyl methylpropional, alpha-isomethylionone, eugenol, citronellol, coumarin, parfum
Page
Nivea Sun Baby Bloqueador Solar(Baby Sunblock SPF 60)
Nivea Sun Baby Bloqueador Solar (Baby Sunblock SPF 60) is nowavailable in a newly designed 115g pack. It features adermatologically tested, water-resistant formula, designed toprotect baby's delicate skin against UVA and UVB sun rays, helpingto prevent sunburn. Free of fragrance, alcohol and colourants,the product retails in a 115ml pack.
aqua, butylene glycol dicaprylate/dicaprate, C12-15 alkylbenzoate, titanium dioxide, butyl methoxydibenzoylmethane,alcohol, glycerin, bis-ethylhexyloxyphenol methoxyphenyltriazine, dicaprylyl carbonate, ethylhexyl triazone,phenylbenzimidazole sulfonic acid, cetearyl alcohol, cetylalcohol, glycine, C18-36 acid triglyceride, glyceryl stearate SE,hydrogenated coco-glycerides, tocopheryl acetate,VP/hexadecene copolymer, xanthan gum, PEG-40 castor oil,trisodium EDTA, sodium cetearyl sulfate, triethoxycaprylylsilane,zinc sulphate, magnesium sulphate, ethylhexyl glycerin,phenoxyethanol, methylparaben, propylparaben, sodiumhydroxide
Page
Combinaciones de Filtros UV en productosL'Oreal lanzados a partir de octubre 2011
Butyl Methoxydibenzoylmethane (378), Octocrylene(367), Drometrizole Trisiloxane (292), EthylhexylTriazone (239), Terephthalylidene Dicamphor SulfonicAcid (238), Ethylhexyl Salicylate (101), Bis-ethylhexyloxyphenol Methoxyphenyl Triazine (96),Ethylhexyl Methoxycinnamate (46), Titanium Dioxide(25), Phenylbenzimidazole Sulfonic Acid (13),Diethylhexyl Butamido Triazone (11), Benzophenone-3(9), 4-methylbenzylidene Camphor (8), Homosalate (3
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Vichy Laboratoires Capital Soleil Ansigt SolcremeVichy Laboratoires Capital Soleil Ansigt Solcreme (FacialSun Crème SPF 25) is suitable for normal to dry skin and isformulated without parabens. It is foto-stable and madewith Mexoryl-XL and DHC for cellular protection.
Aqua (water), octocrylene, glycerin, alcohol denat.,propylene glycol, C12-15 alkyl benzoate,cyclohexasiloxane, ethylhexyl salicylate, butylmethoxydibenzoylmethane, ethylhexyl triazone, bisethylhexyloxyphenol methoxyphenyl triazine, talc,drometrizole trisiloxane, acrylates/C10-30 alkyl acrylatecrosspolymer, aluminum hydroxide, aluminum starchoctenylsuccinate, ascorbyl glycoside, citric acid,ethylhexylglycerin, isohexadecane, methylsilanol/silicatecrosspolymer, neohesperidin dihydrochalcone, parfum(fragrance), pentasodium ethylenediamine tetramethylenephosphonate, phenoxyethanol, polysorbate 60, polysorbate80, sodium hyaluronate, sodium polyacryloyldimethyltaurate, sorbitan oleate, stearic acid, titanium dioxide,tocopherol, triethanolamine
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Ambre Solaire UV-Ski ExtremeConditions Protection FSP 50+
Ambre Solaire UV Ski Extreme Conditions Protection CreamSPF 50+ is claimed to offer a superior level of UVAprotection, and is suitable for sun intolerant skin.
Aqua (water), C12-15 alkyl benzoate, cyclohexasiloxane,cyclopentasiloxane, alcohol denat., isohexadecane,ethylhexyl salicylate, propylene glycol, titanium dioxide,bis-ethylhexyloxyphenol methoxyphenyl triazine,octocrylene, butyl methoxydibenzoylmethane, PEG-30dipolyhydroxystearate, glycerin, terephthalylidenedicamphor sulfonic acid, lauryl PEG/PPG-18/18 methicone,ethylhexyl triazone, tocopherol, dodecene,phenoxyethanol, ethylparaben, triethanolamine,poloxamer 407, dimethicone, pentasodiumethylenediamine tetramethylene phosphonate,drometrizole trisiloxane, propylparaben, isobutylparaben,sorbitol, methylparaben, butylparaben, opuntiacoccinellifera flower extract, glycine soja (soybean oil),
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Ice Effect Moisturising Sun Milk SPF 30L'Oréal Solar Expertise Icy Protection Leche SolarHidratación Efecto Hielo (Ice Effect Moisturising Sun MilkSPF 30) features a non-greasy, non-sticky, water- andsweat-resistant, moisturising formula with SPF 30 sunprotection against UVA/UVB rays and a blend of watermicro-drops with hydrating milk.
aqua (water), glycerin, alcohol denat., octocrylene,ethylhexyl salicylate, butyl methoxydibenzoylmethane,butylene glycol, ethylhexyl triazone, titanium dioxide,dimethicone, phenoxyethanol, sodium acrylatescrosspolymer, drometrizole trisiloxane, glyceryl stearate,behenyl alcohol, triethanolamine, terephthalylidenedicamphor sulfonic acid, methylparaben, caprylyl glycol,menthol, glyceryl stearate citrate, disodium ethylenedicocamide PEG-15 disulfate, ethylparaben, ammoniumpolyacryldimethyltauramide, ammoniumpolyacryloyldimethyl taurate, acrylates copolymer,disodium EDTA, aluminium hydroxide, stearic acid,tocopherol, sodium hyaluronate, linalool, silica, CI 42090(blue 1), parfum (fragrance)
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Delial Ambre Solaire Resisto Niños SPF 50Garnier Delial Ambre Solaire Resisto Niños SPF 50 LecheHidratante Muy Alta Proteción (SPF 50 Childrens HighProtection Moisturising Sun Milk) features a patented Mexoplexfilter system to protect kids sensitive skin against UVA andUVB rays. Enriched with vegetable wax, it is claimed to be twotimes more resistant to water than other suncreams.
Aqua (water), C12-15 alkyl benzoate, alcohol denat.,isohexadecane, ethylhexyl salicylate, propylene glycol,titanium dioxide, cyclohexasiloxane, butylmethoxydibenzoylmethane, PEG-30 dipolyhydroxystearate,bis-ethylhexyloxyphenol methoxyphenyl triazine, octocrylene,glycerin, cyclopentasiloxane, lauryl PEG/PPG-18/18methicone, terephthalylidene dicamphor sulfonic acid,synthetic wax, ethylhexyl triazone, tocopherol, dodecene,triethanolamine, silica, poloxamer 407, dimethicone,ammonium polyacryldimethyltauramide, ammoniumpolyacryloyldimethyl taurate, simmondsia chinensis (jojobaseed) oil, pentasodium ethylenediamine tetramethylenephosphonate, drometrizole trisiloxane, isopropyl lauroylsarcosinate, isostearyl alcohol, caprylyl glycol,disteardimonium hectorite,
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Eau Thermale Avène Sol Lotion(Sun Lotion SPF 50+)
Eau Thermale Avène Sol Lotion (Sun Lotion SPF 50+) is suitablefor babies' sensitive skin and is very water resistant with veryhigh UVA and UVB protection. The hypoallergenic and non-comedogenic product is fragrance- and paraben-free. It retailsin a 100ml pack
avene aqua, octocrylene, cyclomethicone, dicaprylyl ether,methylene bis-benzotriazolyl tetramethylbutylphenol, aqua,butyl methoxydibenzoylmethane, cetearyl isononanoate,glycerin, titanium dioxide, bis-ethylhexyloxyphenolmethoxyphenyl triazine, C12-15 alkyl benzoate, diisopropyladipate, potassium cetyl phosphate, stearyl alcohol,PVP/eicosene copolymer, caprylic/capric triglyceride, caprylylglycol, decyl glucoside, dimethicone, disodium EDTA, glycerylbehenate, glyceryl dibehenate, propylene glycol, silica, sorbicacid, tocopheryl glucoside, tribehenin, xanthan gum,tocopherol
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Eau Thermale Avène Crema para ZonasSensibles
Eau Thermale Avène Crema para Zonas Sensibles (Cream forSensitive Areas) is now available in a newly designed 15mlpack. This water resistant product features SPF 50+ providingUVA and UVB protection, is designed for intolerant skin, ishypoallergenic, fragrance- and paraben-free and non-comedogenic. It can be used on sensitive areas such as nose,cheeks, lips and scars
Avene thermal water (Avene aqua), titanium dioxide, isodecylneopentanoate, triethylhexanoin, C12-15 alkyl benzoate,cyclomethicone, glycerin, polyglyceryl-4 isostearate, C30-45alkyl methicone, cetyl PEG/PPG-10/1 dimethicone, hexyllaurate, alumina, water (aqua), stearic acid, hydrogenatedcastor oil, caprylic/capric triglyceride, disodium EDTA, ironoxides (CI 77492), iron oxides (CI 77491), octyldodecanol,silica dimethyl silylate, sodium chloride, sodium myristoylglutamate, sorbic acid, tocopheryl glucoside,triethoxycaprylylsilane, xanthan gum, tetradibutylpentaerithrityl hydroxyhydrocinnamate
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