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GERAGHTY & MILLER, INC.

J

PZ - WELL SERIESBORING LOGS

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& MILLER, INC.Ground- Water Consultants

SAMPLE/CORE LOGBoring/Well_Z2li_Pro)ect/No. M0679FR6 ____________ Pflgfl

Avtex Fibers, Front Royal £gS 6/17/87 SS««i- 6/22/87Type of Sample/

Total Depth Drilled __35_ feet Mote Diameter _!_ inches CoringDevfce Air cuttingsLength and Diameter _ , • ,Of Coring Device ____________________________________ Sampling Interval Z CO 5

Land-Surface Bev. _____ feet D Surveyed O Estimated Datum __________ ; •Drilling Fluid Used M P*> ___________________ Drilling Method Air rotaryDrillingContractor Pennsylvania Drilling Co. _____ Driller Bryan Adams Helper Bryan KrausePrepared Hammer HammerBy ——————— J- Moore ———————————————————— Weight _____ Drop ____ Inches

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brown, tjdamp.

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minerals (calcite) , filling fractures, dark

grey, wet

Lime mud stone, massive, medium grey

Same

\Same to friable, weathered shale

Same

RRsaiaa:

1/86

•TGERAGHTY.'& MILLER. INC.Ground- Water Consultants

SAMPLE/CORE LOGBoring/We«_EZrJ2_ Project/No. M0679FR6 _______________ Pay 1 of 1Site . m Drilling Drilling „ _ _„Location Avtex Fibers. Front Royal Started ______ Compfatad 6/23/87

Type of Sample/Total Depth Drilled JLiLJL feet Hote Diameter __!__ inches CoringDevtee Air CuttingsLength and Diameterof Coring Device _______________________________ Sampling Interval 2' to 5*

Land-Surface Etev. _____ feet DSurveyed DEstlmated DatumDrilling Fluid Used __________________________ Drilling Mathod Air Rotary

Contractor Penn Drilling _______ ____ Priiter Adams Haiaf KrausePrepared , M Hammer HammerBy _____ J. Moore ______ , ________________ Weight _____ Drop ____ InchesSampWCora Depot Thnafftydra o

(teal betow Und urtm) Con Pmsun orRecomy Btawsporl

Frwn To (tocO bwheo SanpWCon D«crtptai

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10'

121

51

10 '

12*

161

Silt, some sand, fine to medium, and organics,

dark brown, damp

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brown, very moist

Shale, lime mud stone, dark grey, wet

Shale, lime mud stone, friable, greenish grey,

little calcite void filling, wet

flR3Q!58!

—————————— aa — 3, —— _ ——————————————————————————————————— .1/86

& MILLER, INC.round- Water Consultants . '-', . .

SAMPLE/CORE LOGBoring/Well _£Zz3 Project/No. M0679FR6 _______________ Page Jt___of_iSite r ? -"• •"=Location Avtex Fibers• Front Royal it tiS Completed 6/23/87

..« , - Type of Sample/ _. _, _ ^^.Total Depth Drilled_2J_feet Hole Diameter«JL_lnches CoringDevice Air Rotary CuttingsLength and Diameter ~ofCoring Device •___;__________________Sampling interval ContinuousLand-SurfaceElev._____feet DSurveyed OEstimated ' Datum________ o^Drilling Fluid Used ____Mono _________________ Drilling Mathod Air RotaryDrillingContractor Penn Drilling - _______Driller Adams Helper KraugePrepared Hammer HammerBy————J, Moore——;————————————————————Weignt_____Drop____InchesSampfe/Cori DepOi TbnoAfyilnulic

(tt« baJov (and turtia) ton fnaunttRocowry Itom itr I

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61

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131

51

6*

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13 '

18'

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Sand, fine to course, some silt and organics.

medium brown, moist

Same, dark brown to black, wet (weatheredi

bedrock)

:

Shale, lime muds tone, fissil, dark grey.

Same

' .. -."!•;.- ._-,: * • - • ' . . . . : • 'Same

•

; ,AR30I585

E-4

^GERAGHTY'& MILLER. INC.tround- Water Consultants

SAMPLE/TORE LOGBering/Well __E2rA_ Project/No. M0679FR6________________PageJ___ofJLSite Drilling Drilling V-Location Avtex Fibers. Front Royal Started__________Completed fi/3S/B7

Type of Sample/Total Depth Drilled _3JU3 feet Hote Diameter __4__ inches Coring Device Air cuttingsLength and Diameterof Coring Device ___________________________ Sampling Interval continuous feetLand-Surface Elev. _____feet D Surveyed D Estimated Datum ________________Drilling Fluid Used Nftn*» _________________________ Prilling Method Air RotaryDrillingContractor Ponn n-rj 1 1 tng ________________ Drilter__adaffla ____ HelperPrepared Hammer HammerBy ______ .T Mrv»y«a ______________________ Weight _____ Drop ____ inches

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17.

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3'

2'

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Rock at 10.5'

Shale, weathered, black to grey, abundant

calcite

Shale, grey, some calcite filling

Same

BR3Q1590~

F-S . .. . .. . ————————— 11/86

# MILLER, INC.round- Water Consultants

SAMPLE/CORE LOGBoring/Well P2-5 Prnjart/Ma, MQ679FR6___________________Pay* 1 of 1Site Drilling DrillingLocation Avtex Fibers. Front Royal started_________Conyfeted 6/an/P7

„ „ Type of Sample/Total Depth Drilled 25.5 feat Hole Diameter __1__ inches Coring Device a-lrLength and Diameterof Coring Device ___________________________ Sampling Interval,Land-Surface Etey._____feet D Surveyed D Estimated Datum _____Drilling Fluid Used None _______ : ___________ Drilling Method Air rotaryDrilling _ _ . _ _ .Contractor Penn Drilling _____________ pniter Adams HelperPrepared _ M «--m Hammer HammerBy —————— J. Moore

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0

51

7.51

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51

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10.6

25.5

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Silty Clay, wet

Bedrock - shale, weathered, black to grey, -

calcite veins

Shale, grey, some calcite filling

flR30!-S3-U

E-6

GERAGHTY& MILLER, INC

Ground-Water Consultants . ,.

SAMPLE/CORE LOGBoring/Well _££T£_ Project/No. M0679FR6Site Drilling DrillingLocation atH-gv P*hoT-er P-rortt- Royal Started___________Compteted 6/30/87

Type of Sample/ •.Total Depth Drilled _23__ feet Hole Diameter __4___ inches Coring Device Air cuttingsLength and Diameterof Coring Device _____________- ••-____________ Sampling Interval continuous feetLand-Surface Etev._____ feet D Surveyed D Estimated Datum ________;_______Drilling Fluid Used None ______ - ____________ Drilling Mflttwi Air rotary

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12'

17'

5'

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12'

17 '

23'

Silt, some sand and gravel, medium to coarse.

dark brown, organics, damp

Silt, some sand, medium, organics, some

friable lime mud stone, moist

'Lime muds tone, some weathering, light to

dark grey

Lime mud stone, friable, fissil, dark grey,

some weathering

Same

BR30159?H n w w • —

e ja ————————————————————————————~ /

•TGERAGHTY& MILLER, INC.Ground- Water Consultants

SAMPLE/CORE LOG£Zz2__ Project/No, M0679FR6 __________________ Pag«_JL_of

Site , Drilling Drilling „ .„ .„Location Rvt-px Fibers - Front Roval Started __________ ComrJeted 7/2/87

Type of Sample/ . ^ _Total Depth Drilled __2i_ feet Hote Diameter ____ Inches CoringDevtee Air cuttingsLength and Diameterof Coring Device ____________________________ Sampling Interval continuous

Land-Surface Etev. _____ feet D Surveyed D Estimated DatumDrilling Fluid Used None________________________ Drilling Method Air rotary

cStor Penn Drilling_____________M, Mams Hfllfw Krausepr8Pared -r «~~— Hammer HammerBy J. Moore_______________________Weight_____Drop____inchesSampleAefO Depth TkneVHydrsufle

(feel betov lane* surface) Core PresmreorRecovery Blow per IFrom To (MO Inches Sample£ofO Dwerlption

0

51

10'

11'

13'

5

18'

51

10'

II1

13'

18'

23'

Sand, fine to coarse, and silt, medium brown,

damp

Same•

Shale, dark grey, weathered

Shale, lime mudstone, dark grey, weathered

Shale, lime mudstone, grey, weathered, some

calcite filling

Same

n D o n t————————————————————————————— Mn JU j

E-S AR30I5931/86

^GERAGHTY'<sr MILLER, INC'Ground. Water Consultants

SAMPLE/CORE LOGBoring/Well _£Zrfl_ Project/No. M0679FR6 ________ ,. . v _____ PJ B 1 of 1

V J Site . ... Drilling " Drilling _,-,«,-^ x Location Avtex Fibers - Front Roval Started __________ Ct -feted 7/7/87

f Sample/ , . _ .Total Depth Drilled __!£_ feet Hole Diameter _J_ Inches CoringDevice Air cuttingsLength and Diameterof Coring Device ____________________________ Sampling Interval continuousLand-Surface Etev. _____ feet O Surveyed DEstimated Datum ___________ -*.•:Drilling Fluid Used None __________ . ___________ Drining Method Air

Penn Drilling p,, Adams ^ KrausePrepared _ ..._ Hammer HammerBy——————J- Moore——————,————_——————————Weight_____Drop____InchesSample&ore Depth Tkna/Hydraullc

(feet below land surface) Con Pressure orRecovery Uovsperl

From Te (feet) todies Sample/Con Description

0

5'

81

13 '

51

81

131

18'

Silt, sand, medium to coarse, and organics.

medium red brown, damp

Same to dark grey friable, lime mudstone,

moist-wet•

Lime mudstone, fissil, dark grey, wet

Lime muds tone fissil, dark grey, wet

QP90 I 59(4H n o w i w «/ -T

p.d —— -- —————— i1/86

.INC.Ground-Water Consultants

SAMPLE/CORE LOGBoring/Wen _EZ=a_ Project/No. M0679FR6 _____________Pay 1 nf__1.Site ,,_ , Drilling Drilling „ .„ /(1B1Location Avtex Fibers - Front Royal started________Completed_ZZ2Z§Z_

Type of Sample/ m. .. .Total Depth Drilled__2iL feet Hole Diameter _JL_ inches CoringDevtee Air cuttingsLength and Diameterof Coring Device ___________________________ Sampling Interval continuousLand-Surface EJev. _____feet D Surveyed D Estimated Datum ______________Drilling Fluid Used None______________________Drilling Method_f £_ fEL.

Penn Drilling_____________pniiar- Afla"18 Heioflr KrausePrepared T Wrtrt-- Hammer Hammer

J-By——————J- flooi:e—————————————————————Weight_____Drop____inchesSample/Core Dep* Tkne/HydrauOc

(rest betov land surface) Core PressureerRecovery Blow per §

From To (toeO todies Sampte/Cote DescrfpOM

0

5'

8'

13 •

18'

• •

5'

8'

13 '

18'

28'

Silt, sand/ medium to coarse, and organics,medium brown, damp

Same to dark grey friable lime mudstone,

moist- wet•

Lime mudstone, dark grey to medium grey, wet

Same, some weathering

Same

________________ |\R3ni59^

E-10

^GERAGHTYf& MILLER, INC.'Ground- Water Consultants

SAMPLE/CORE LOG rBoring/Well _E2L=JJ3 Project/No. MQfi7QFPfi________ :' '•____Page_J __of.

™Location Atex Fibers » Front Roval startiS _________ Crvnptoted 7/30/87*- - , Type of Sample/

Total Depth Drilted __£2_._5 feet Hole Diameter 4 Inches CoringDevtee AirLength and Diameterof Coring Device • ___ : ______________________ Sampling Interval continuous feetLand-Surface Etev. _____ feet OSurveyed DEsHmated Datum ___________ Drilling Fluid Used None ______ ; __________________ Drilling Method Air rotaryDrillingContractor Penn Drilling ______________ Driller Adams HelperPrepared Hammer HammerBy ————— r r*?oge ——————————————————————— Weight _____ Drop ____ InchesSample/Core Depth Ttau/rfydrsuflc

fleet below lend surface) Core Pressure erRecovery Itovsperl

From To (reef) todies Sampte ore Description

0

51

91

13 '

51

91

13 '

22.5

Silt and sand, medium to coarse, oraanics.

medium red brown, damn\ • '• •

Same to dark arev weathered limestone, damp

Lime mudstone, dark qrev

Lime mudstone fissil, dark arey, wet

- ;• ,.„, , ,

ARÔ!596- -

B-ll _j1/86

>l«rGERAGHTY£f& MILLER, INC

'Ground- Water ConsultantsSAMPLE/CORE LOG

Boring/WellJi£ i_ Project/No. M0679FR6_________________Pflqft * of 1

Location Avtex Fibers - Front Royal started________Completed 7/30/87Type of Sample/ ,. J_J_,

Total Depth Drilled __80^5 feet Hote Diameter __!_ inches CoringDevtee Air cuttingsLength and Diameter J_,of Coring Devtee ___________________________ Sampling Interval continuousLand-Surface Etev. _____ feet D Surveyed D Estimated Datum _____________Drilling Ruid Used y n* _____________________ Drilling Method Air RotaryDrilling .... , Contractor Penn Drilling _____________ r>iiier Adams Hfliar KrausePrepared „ , Hammer HammerBy _____ Wesselman _____________________ Weight _____ Drop ____ inchesSample/Core Depth Ttme/HydrauBc

(feel betov land surface) Core PressureorRecovery Blow per I

From To (heO todies SampWCore DescrtptkM

0

9'

13'

181

28*

331

50'

77'

9

13'

18 '

28'

33'

50'

77'

80.5'

Silty sand with dobbles; light brown to grey.

wet.

Lime mudstone, dark grey to medium grey, wet

Same, some weathering

Same

Same, little H,O yield 'for section

Same, frequent zones of calcite filling

Limestone, light grey to dark grey, dense.no fractures, no ground water

Lime mudstone, dark grey, calcite veins.

ground water ~ 5 gpm

A R 3 Q 1 5971 1 1 V v w l \J 1

E-121/86

GERAGHTY & MILLER, INC

MW - WELL SERIESBORING LOGS

ftR3Q 15.98

E-13

•TGERAGHTY£& MILLER, INC

Ground- Water ConsultantsSAMPLE/CORE LOG

swing/well MW-9 Pmfrrt/Mo. M0679FR6_______________Page_J__ofSite , _._ ^ Drilling DrillingLocation Avtex Fibers - Front Royal Started_________Completad 7/22/R7

Type of Sample/Total Depth Drilled ___45_ feet Hole Diameter__A_ Inches CoringDevtee Split spoonLength and Diameterof Coring Device ____18" spoon________________ Sampling intan/ai continuousLand-Surface Etev. _____ feet D Surveyed D Estimated Datum ______________Drilling Fluid Used None_____________________ Drilling Method AugercXactor Penn Drilling_____________p^ Adams Hfllftf Krause.Helper.

T M~**-A Hammer HammerBy:—————J' Moore——————————————————————Weight_____Drop____inchesSampWCoro Depth Tbne/HvdrsuKs

{Test below land surface) Core PressureorRecovery Btotn per e

From To (heO todwe SampWCoit Oetcripdw

1.0

1.5

3.0

5.0

7.5

10.0

1.5

3.0

5.0

7.5

ijt

, 10.

<:

12.

t

i

D'

i1

>-3-4

>-10-9

3-3-5-5

2-4-3-3

5-6-8-4

L-4-3-4

Silt, clay, some sand, fine to medium, mottled

light grey and medium brown, dry

Same, some coarse gravel, red brown, dry

Silt, some clay, some sand, medium, yellow

brown to red brown, red and grey stringers.

damp

Silt, some clay, sand medium to fine, mottled,

medium brown to olive, odor, damp

Clay, silt and sand, fine to medium, some

gravel, coarse, slightly cohesive, medium

brown, damp

Clay and silty sand, fine to coarse^ rae££umqq

brown to black, damp, slightly cohesive

E-14 SR30I599 _ ,1/86

GERAGHTY'& MILLER, INC.'•round- Water Consultants

SAMPLE/CORE LOG (Cont.d)MW-9

Prepared By,

Cample/Cora Depth TIme/HydrauOc(feet betow lend surface) Cora Pressure or

Recovery Wows per •From T« (feet) Inches Sample/Cora Description

12. 51

15. 01

17.5'

20. 01

22.5'

25. 01

27.5'

15.0'

17. 51

20. 01

22.5'

25. 01

27.5'

30. 01- -

-

-

. .

1-2-2-1

1-1-3-3

2-4-6-6

.

1-3-4-4

2-4-7-6. ._

,- f i •

- f

' . . H

5-5-6-K

. r .

r

i

Same, moist

Same, saturated

Same, mottled, light grey to red

brown, saturated..

Same

• •

• Silt, clay, and sand, fine to

v medium, redish brown, saturated

Silt, clay, sand and gravel, fine

to coarse, medium brown to black,

5 saturated

Silt and clay, some sand and grave

find to medium, dark greenish blac

wet odor ;

flRan !£nnii

-15

-\

• t

tf

1/86

•TGERAGHTYMg MILLER, INC

Ground- Water Consultants

SAMPLE/CORE LOG (Cont.d)PWinj/WeH MW-9 Page 3 of 3

Prepared By

Sample/Cora Depth Time/Hydraulic(feet below land surface) Cor* Pressure or

Recovery Stamper*From To (fe«Q Inche* Sample/Cor* Description

30.0'

32. 51

35. 01

37.5'

•f.•**

40.0'

42.5'

32. 5'

35. O1

37. 51

40.0'

42.5'

45. 01

1

1-3-5-6

2-3-6-10

4-20-20-

11-21-12

5-15-21-

15-15-22

E

Same

Same to silt and clay, some sand

and gravel, fine to coarse, coheslv

medium brown with olive mottle.

moist

.

21 Silt and clay, some sand and

gravel, fine -to coarse, cohesive,

medium brown with olive mottle,

moist

•12 Silt and Sand, fine to coarse,

little gravel, dark red brown.

moist, cohesive

.5 Same

-17 Silt and sand, medium, red browx

and grey, wet ^ p 3 fj 1 6 0 I

-16

e,

1/JM

^GERAGHTY' MILLER, INC.Ground- Water Consultants

SAMPLE/CORE LOG*i Boring/Well _J5tifi_ Project/No. M0679FR6_______________Page__l_of

Site m ^ _L _ Drilling DrillingLocation AV.tex Fibers - Front Royal Started___________Completed 7/71/P7

Type of Sample/Total Depth Drilled 53.5 feat Hnto Diameter 4 inches CoringDevtee fipl < -h gpnXn_____Length and DiameterOf Coring Device _______18 M Spoon____________________ Sampling interval r»rtrTMTi»rme teet

Land-Surface Etev. _____ feet D Surveyed D Estimated Datum ________________Drilling Fluid Used None_______________________ Drilling Method auger '_____Drilling _ _ ., _ . *Contractor Penn Drilling_________ ^; Driller Adams Helper KraqgePrepared - „ Hammer HammerBy_____J. Moore ____ ""'_________Weight_____Drop____InchesSample/Core Depth Time/Hydraulic

(feet betow tend surface) Con Pressure erRecovery Horn per I

From To fleet) todies SampteAore Description

0

2.5

5.0

7.5

10.0

12.5

15.0

2-5

5.0

7.5

10.0

12.5

15.0

17.5

,

LO-12-K

i-4-5-5

X-l-3-4

6-5-6-4

4-8-9-1:

5-6-4-6

3-6-8-8

Silt, sand, gravel and organics. fine to coars

medium brown, drvSilt, clay, mottled grey and red brown.

r . ;

soft, cohesive, damp

Silt and sand, fine to medium, little gravel,

coarse, medium brown, damp

Silt and sand, some gravel, fine to medium,,• •-.

cohesive, -dark red brown, damp'•""• 3 ". • -

Same, some gravel to sand, fine to medium.

some silt, olive, damp:

Silt, some clay, some sand and gravel, fine

to medium, dark red brown, damp cohesive

flR30!6(Same, more clay, darker brown. . ..... _,

l ——————————— ,p__,i ia_ ————————————————————————————————— —————————— ——

,INC'<round- Water Consultants

SAMPLE/CORE LOG (Cont.d)Boring/Well_ &S-JJ) Page_2__of_3.

Prepared By ________________

Sample/Core Depth Ttme/HydrauOe(feet below land surface) Cora Pressure or

Recovery Blow* pertFrom To (feel) toche* Sample/Cora Description

17. 5'

20. O1

2*2.5'

25. 01

27. 51

30. tf5•T

32.5'

35.0'

20. 01

22. 51

25. 01

27. 5'

30. 01

32.5'

35. 01

37. 51•

L-3-3-5

3-4-7-6

5-5-9-7

5-4-7-4

6-10-8-7

3-5-6-7

6-5-5-9

Same with black stringers

Same

Silt and clay/ light grey to red

brown, some fine sand, trace mica,

damp

Same, light brown and grey to

medium brown

Silt and clay, little sand, fine

to medium, dark brown, damp,

cohesive

Same

Same, mottled light grey to dark

brown

AR30I60!ft 1 l W w »

Silty clay, olive,

fine, some medium brown to black

mottle, cohesiveE-18 i/a«

GERAGHTY& MILLER, INC >

Ground- Water Consultants

SAMPLE/CORE LOG (Cont.d)Boring/Well _ HHr ID Page——3.

Prepared By ________________.

Sample/Cora Depth TUm/Hydrauflc(feet below lend surface) Core Pressure or .

Recovery Wows pertFrom To (feet) Inches Sample/Core Description

37. 51

40. 01

42. 5'

45. O1

47. 5'

40.0*

42.5'

45.0'

47. 51

50. 01

1-7-10-1

4-9-12-2

7-12-27-. .- ,

. ' /

L2-10-15

2-6-10-1

r. -

. ,

- ' r*

. Same

. Clay and silt, medium to dark brown

damp, cohesive

15 Silt, some sand and gravel, fine

to coarse, medium red brown,, moist.

cohesive,

•17 Same

! Silt, sand and gravel, medium to

-coarse, medium grey to brown, wet•

t_

f "

AR30I601)

1-1 O

•TGERAGHTY£&& MILLER, INCGround- Water Consultants

SAMPLE/CORE LOGBnring/WoH MW-11 Pmjart/Nto M0679FR6______________________Pag* 1 of

Site Drilling Drilling „ _ ,„„Location Avtex Fibers - Front Roval started_________Compfatad 7/28/87Type of Sample/

Total Depth Drilled_1Q_ feet Hote Diameter_J__Inches CoringDevtee Split spoonLength and Diameterof Coring Device Ifl" spoon_________________ Sampling Interval continuous feetLand-Surface Elev. _____ feet D Surveyed D Estimated DatumDrilling Fluid Used ______ Nona __________________ Drilling Method. AuaerDrillingContractor P«»nn niMTUngr _____________ Priiiar Adama ___ Halpar KrausePrepared Hammer HammerBy ———— J — Mnnrp ——————————————————————— Weight ————— Drop ____ inches

SampleXofo Destrtpfai

0

2.5

5.0

7.5

10.0

12.5

15.0

• s

17.5

20.0

2.5

5.0

7.5

10.0

12.5

15.0

17.5

:20.0

22.5

1

10

13

7-

-12-12-]

2-2-4-7

5-9-11-:

L-5-13-:

L-4-H-:-12-22-;

4-12-23-

-21-21-;

14-24-|{

0 Silt and sand, fine, some clay, medium brown

dry to damp

Clay, little silt, mottled red brown, light

grey and yellow brown, damp, cohesive

2 Same, more silt

3 Clay, some silt, medium red brown, light

grey stringers, damp, cohesive

3 Same, stiff clay

4 Very stiff clay, medium red brown, trace

light grey stringers

6 Same with some silt, black organic

inclusions

1 Sand and silt, fine to medium, variegated

(red brown, buff, yellow brown, light grey

and black), moist, odor

Silt and sand, fine, buff to sand and gravel.

coarse, organics, unknown sheet- l a rfat fi '

moist, wet

=-20 AR30I605

^GERAGHTY'& MILLER, INC'round-Water Consultants

SAMPLE/CORE LOG (Cont.d)Bnring/Well MW-11 ' Page 2 of 2

Prepared By ________________,-•. '" " '"- •

Sample/Cor* Depth Time/Hydraulic(feet below land aurfsce) Core Pressure or .„

Recoveiy WowaperCFrom To (feet) Inches SamcXe/Core Deccrlptkxi

22.5'

25.0'

27.5'

25.0'

27. 51

30.0'

>0/5"

50/6"

50/3"

_ f. .

,

Same

Same with maroon colored flakes

of shale

Lime mudstone, fissil, broken,

dark grey

§

————————————— AR30I60

-21

^kWGERAGHTY& MILLER, INC


Boring/We«_ilHkl2 Project/No. Mn<i7QPBfi ______________ Pag* i nfAvtex Fibers - Front Royal 553 ________ n 7/29/87

-, . Type of Sample/Total Depth Drilled _±£__ feet Hole Diameter J ___ inches CoringDevice Split spoonLength and Diameter .AHof Coring Device _____ 18 spoon ________________ Sampling Interval continuousLand-Surface Etev. _____ feet Q Surveyed D Estimated DatumDrilling Fluid Used _____ None ______________________ DrilHng Method AM gar ________DrillingContractor Penn Drilling ______________ Driiiar Adams Hetpar KrausePrepared , Hammer HammerBy Jt Moore _______________________ Weight _____ Drop ____ inchesSample/Core Depdi Tbne/HydrsuRc

(feel below land surface) Core Pressure orRecoverf Blows pert

From To (tool) Inches Sampte£on Oescrtpttoii

0

2.5

5.0

7.5

2.5

5.0

7.5

10.0

1-7-10-9

r-40-50/

>-18-27-

J-50/5

Silt, some sand, fine to medium, medium brown

organic, dry

5 Stiff, friable clav and silt, dark reddish

brown, dry.

50/5 Same

Silt, buff, some fine sand to shale at

9.0' (dark black)

flR3QI607E-22 - - - . -

1/80

GERAGHTY & MILLER, INC

VB - PIEZOMETER SERIES

BEDROCK CORE LOGS

E-23 HR30i608

•TGERAGHTY£f& MILLER, INC


VB-l Project/No. M0679FR6___________________Pag«_l___of_i.Site Drilling _ ... .__ Drilling . .„„ ,„Location Avtex - Viscose Basin 1________Started 8/31/87 Cnmnfatftd 8/31/87

Type of Sample/Total Depth Drilled 10 feet Hole Diameter 3 inches Coring Device NX coring______Length and Diameterof Coring Device _______in ft-_________________ Sampling Interval continuous feetLand-Surface Elev. _____ feet D Surveyed D Estimated Datum _________Drilling Fluid Used City water__________________ Drilling Method NICDrillingContractor Pennsylvania Drilling PaiT^y____Driller_2dams____Helper _I£rause___Prepared . „ * Hammer HammerBy _____M. Gairtette_____________________Weight_____Drop____inchesSample/Core Depth TkneAfydraulle

(feat below tanf surface) Cora PressureorRecovery Blows per I

From To (Iwfl (ncfm SampleCon DeserHrtkM

26

-

•~

28

29

•-

28

29

36

—

—

10

•

mudstone, fine grain, light brown to tan, iron staining

present, snail fractures present particularly at

between 27.5' and 28', fracture orientation 45°to 50°.

nudstone, tan to light grey, fine grain.

,

mudstone, light grey, fine grain, rust stained fron

30' to 33' 10".

Unconformities present at 30* 4" (nudstone/silstone

contact); 32* (nudstone/siltstone) ; 32.5', 33',Vertical fractures appear to be present between 32'

and 33'; rock discoloration present, iron stained at32.5'.

AR30I601

E-24

1/86

^GERAGHTY'# MILLER, INC/round- Water Consultants , , .,....= ,.,=

SAMPLE/CORE LOG ,Bering/Well _J2ll_ Project/No. M0679FR6 - •- _______ '_ _______ Page

Location Avtex - Viscose Basin 2 8A1/87 tad 8/12/87^ r

Total Depth Drilled _I9__ feet Hole Diameter _JL_ inches C ngDevice NX CoringLength and Diameter ,A f. _ L.of Coring Device ___ L±±: ____ - -- -•• "-•• " - • • _____ Samniir interval ContinuousLand-Surface Etev. _____ .feet D Surveyed D Estimated Qstum . ___ ' "'Drilling Fluid Used Citv Water -.- _______ Prilling Methnd N?c ^

Pennsylvania Drilling Ooipany p adams ^ KrauJePrepared M «...,•_«« Hammer HammerBy M- Gauoette ______ ' Wa ht _____ Drop ____ Inches

SampfeCore Descrlptloft

25 35

'

10

•

mudstone, fine grain, light to ned grey, iron stained

throughout some fracturing (pcss vertical) in through-

out Core, other small fractures present at 30', thin.

verticle calcite seams at 27.5' and between 29' and 31f .„., . ".-.-. . .

nudstone/siltstone contact present between 27*5*

and 31'. -

, . , . . . , - . . . -

. . „.„.,„. . -. - - -- - - - • --

. . ... .. ._- ,.., ..,-.._.-

. . . _.,„_ .. , . .

. _ _ „ „ . . . . _ . , .

_...._. , ... .

flR3Q!6in

,....-.,-_-

E-25

•TGERAGHTY£fQ MILLER, INC

ground- Water ConsultantsSAMPLE/CORE LOG

Boring/Well _Xffl=l__ Project/No. M0479FR6________________Pag* 1 niSite „ , . Drilling Drilling \J

**„ , .

Location Avtgy - iscos& Basin 3 _______ Started 8A5/87 Comfetfld 8/2Q/87.. , Type of Sample/

Total Depth Drilled _±2_ feet Hole Diameter J ___ inches Coring Device NXLength and Diameterof Coring Device in f+_. _________________ _ Sampling Interval ranHnitntm feetLand-Surf ace Etev. _____ feet DSurveyed D Estimated Datum ________________Drilling Fluid Used rH+y «a<-f»r-_________________ Drilling Method__Hx.Con'trictor Pennsylvania Drilling Oanpany _____ Pniior Mams HAI KrausePrepared „ -..j .- Hammer HammerBy M. Gaudette ___________________ Weight

SampleVCon Depn TlmeArydnuae(feel betow tantf surface) Con Pressursor

Recovery Blows per IFrom To (reel) Inches SampteCore DescrlprjM

29 38

•-

9 Core consists of fine grey nudstone with medium grained

material between 36 and 37.5*.

Thin calcite seams are present through the entire core.

Iron staining present at 37.3', 38.6* and 39'.

Shall 45° fractures present at 29.7', 30.6', 31', 31.5*

32.2', 32.8', 33. 4', 341, 35.', 36.5', 371, 37.6', and

38.3'.

AR30I6I

E-261/86

A*& MILLER, INCGround- Water Consultants

SAMPLE/CORE LOGBoring/Well _Y?lZ__ Project/No. MnfiTQi pfi ________ _ _£. ____ Pay* 1 ofSite . _,_ , „. _ . _ Drilling „ „ DrillingLocation Avtex - Viscose Basin 7 ________ Started 9/1/87 Comrzfetad 9/1/87

Type of Sample/Total Depth Drilled «_1Q_ feet Hole Diameter __3_ Inches Coring Device ______ EX _____Length and Diameterof Coring Device _____ lQ_ft* ____________________ Sampling Interval Continuous teatLand-Surface Etev. _____ feet D Surveyed D Estimated Datum ________________Drilling Fluid Used rt ty Mitw _________________ Drilling Method__I&DrillingContractor gnnsyly nia Prilling f o., ______ Priitor a ams ____ HelperPrepared M fiai o4-*-e Hammer Hammer

"'By ' ____________________ Weight _____ Drop ____ Inchestonpte/Core Depth Ttme/Hydrsulk

ffeet ketow lend surface) Core Fnsnn orRecovery Blows eerft

From To fleet) fetches Sample/Core Description

30'

33'

33'

40'

.

•

Mudstone, fine grained, It. to medium brown, crumbly.Iron-stained seams present throughout, highly

fractured throughout - most fractures appear to be at

45° angle - Major 45° fractures at 30 '7", 30 '10", 31',31'7"

toristone, fine grained, mod. to dark grey, iron stained

throughout, small fractures present between 33 and 35 ft

most appear to vary between 45° and 50° . Fractures

at 33'4", 33'10", 341, 34'5", 35'.

Between 37' and 39.5', poss. fine grain siltstone/tedcontact present; vertical fracturing also present

fron 37' to 39'.

—————————————————— flR3QI6i:'•

E-27

• r

>»

o

i-O

I

AR30I6I

Pumping Test 12Drawdown Analyses

Explanation for Plots:T - coefficient of transmissivity, ft2/minS - coefficient of storage, dimensionless

drawdown in feettime in minutes

HR30I6H*

1-1

Olcf-lQ.3a

CM

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Pumping Test |2Recovery Analyses

Explanation for Plots;T «• coefficient of transmissivity,

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time * time since pumping began to time since pumping stopped

AR30I630

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Pumping Test 13Drawdown Analyses

Explanation for Plots:T - coefficient of transmissivity, ft2/»inS - coefficient of storage, dimensionless

drawdown in feettime in minutes

AR301636

1-25

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time » time since pumping began to time since pumping stopped

c_03

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AR30I6149

EPA REGION IIISUPERFUND DOCUMENT MANAGEMENT SYSTEM

DOC IDPAGE *_

IMAGERY COVER SHEETUN8CANNABLE ITEM

SITE NAME

OPERABLE UNIT

ADMINISTRATIVE RECORDS- SECTION VOLUME &

REPORT OR DOCUMENT TITLE.

DATE OF DOCUMENT.

DESCRIPTON OF IMAGERY XA3\ y-\cA

NUMBER AND TYPE OF IMAGERY ITEM(S)

zoX

AR3GI65!

• MANNERS *

CERTIFICATE OF ANALYSIS

CLIENT: Geraghty & Miller. Inc. DATE REPORTED: 10/09/87844 West StreetAnnapolis MO 21401 REPORT NO: 8710479-001

DATE SAMPLED: 08/24/87

SAMPLE TYPE: Soil DATE RECEIVED: 08/25/87

SAMPLED BY: Wesselman PURCHASE NO.:

SAMPLE IDENTIFICATION: So1l~V1$cose Basin Material ORDER NO.:Front Royal Project - M0679FR6V8-11 Surface

II. CHEMICAL ANALYSIS

AS RECEIVED DRY BASIS

Total Moisture % . 7.21Volatile Matter % 85.4 92.0Fixed Carbon % 5.67 6.15Ash % 1.72 1.85

Heating Value " Btu/lb 6720 7240

Sulfur % 0.18 6.19Carbon % 39.1 42.1Hydrogen (Excluding H in moisture) % 5.04 5.44Hydrogen (Including H in moisture) % 5.85Nitrogen % 0.02 0.02Chlorine % 0.01 0.01

•K-:orm No. L11a

RR30I652

R6PCT TO:

OHOUC office QMOUSTHAL OCHEMSTRT OL&MH VALLEY OFFICE*4$HWyomlMlngBtod. HVOICfC lASOKATOmr U6OIMTORY

lteiO-0307

Geraghty & Miller, Inc. 'Report No. 8710479-1October 9. 1987Page 2

II. REACTIVITY ;

A. The sample was stable and did not undergo violent changes.B. No reaction was noted when mixed with water.C* No potential explosive mixtures were formed when mixed with water.D. No toxic gases, vapors or fumes were generated when mixed with water.

• ^ 4 -. - . "

E. No Sulfide (<Z9.0 tig/Kg) or Cyanide (<0.29 mg/Kg) was detected whenexposed to pH conditions between 2 and 12.

F. The sample did not detonate* explosively decompose or react atstandard temperatures and pressures*

III. IGNITABILITY

The sample ignited at Ambient temperature. The sample burned slowly,but was entirely consumed by the flame. The same observations were

. made when the temperature was Increased to 60 Degrees Celsius.

mi tted,

R. M. LARGEProgram SupervisorChemistry Laboratory

PRN

cc: Michele RuthRichard Smith

RR301653

K-3

SPOTTUIEVENS mi M*COMNCENCmCERS • PLANNERS • SOtMIO*


CLIENT: Geraghty & Miller. Inc. DATE REPORTED: 10/09/87844 West StreetAnnapolis MD 21401 REPORT NO: 8710479-002

DATE SAMPLED: 08/24/87•.•/•r

SAK»LE TYPE: Soil DATE RECEIVED: 08/25/87

SAMPLED BY: Wesselman PURCHASE NO.:SAH>LE IDENTIFICATION: Soil-Viscose Basin Material ORDER NO.:

Front Royal Project - M0679FR6VB-11-0-0



Total Moisture % . 8.00Volatile Matter % 84.0 • 91.3Fixed Carbon % 4.79 5.21Ash % 3.21 3.49

Heating Value - Btu/lb 6580 7150

Sulfur % 0.13 0.14Carbon % 39.1 42.5Hydrogen (Excluding H In moisture) % 5.28 5.74Hydrogen (Including H in moisture) % 6.17Nitrogen % < 0.01 < 0.01Chlorine I 0.01 0.01

RR30165U,rm No. L11« Rev. 1/87

REPLY TO:

™,__ aCHEMunw OLCHOH VALLEY OFFICEHYGIENELASOWTOW LABOMTOKV WKA/twrOffto.**»SdM401MSH.W|u» <noeM. MNOMSVMI araur-ohsw* s«tt«iaa

M 194KMW07 PXXBwMOT __ PAOMSSST. WMHM M 1«OS2«M TowMn MO »1»4JSrtHistS7s-«ssi n,i*ft9 M mio-oaor mmr^ PAIWM-OSZT pist4»-4tas

SSMGeraghty & Miller, Inc.Report No. 8710479-2October 9, 1987Page 2

II. REACTIVITY

A. The sample was stable and did not undergo violent changes.B. No reaction was noted when mixed with water.C. No potential explosive mixtures were formed when mixed with water.D. No toxic gases» vapors or fumes were generated when mixed with water.E. No Sulfide (<27.8 mg/Kg) or Cyanide (<0.28 ing/Kg) was detected when

exposed to pH conditions between 2 and 12.F. The sample did not detonate, explosively decompose or react at

standard temperatures and pressures.III. IGNITABILITY

The sample Ignited at Ambient temperature. The sample burned slowly,but was entirely consumed by the flame. The same observations weremade when the temperatures was increased to 60 Degrees Celsius.

R.M. LARGEProgram Supervisor

PRN


AR301655

SfOnS.SIEVENS «4 MrCOr, WeENGINEERS * RANNERS • SCBflOT


CLIENT: Geraghty * Miller, Inc. DATE REPORTED: 10/09/87$44 West Street „,,«,,« ««*Annapolis MD 21401 REPORT NO: 8710479-003

DATE SAMPLED: 08/24/87A


SAf-PLED BY: Wesselman PURCHASE NO.:

SAMPLE IDENTIFICATION: Soil-Viscose Basin Material ORDER NO.:Front Royal Project M0679FR6VB-11-0-1



Total Moisture % . 88.6Volatile Matter X 9.21 • 80.6Fixed Carbon % 1.35 11.8Ash % 0.84 7.36

Heating Value • " Btu/lb 770 6740

Sulfur % 0.09 0.79Carbon % 4.64 40.6Hydrogen (Excluding H In moisture) % 0.58 5.12Hydrogen (Including H In moisture) % 10.5Nitrogen % < 0.01 < 0.01Chlorine % < 0.01 0.02

orm No. L11« R«v. 1/87

AR301656K-5

Q HOME Of fCt Q MOUSTMAL OCHEMttTRV OUMKJM VALLEY OFHCf O BAUIUOM OFFICEHYGIENE LABORATORY LASOftATORY ItacArtiur OMet fU» SuM 401 6SS F«lmwwnt Avtnu*

3722 Uhigh S*MtIMI04307 PjQ.R««C307 PjO.S««S>7. WNWWi PA iaOU443S • TowMH MO f1»4Jilt

FA 1M10-OJ07 MMA j PA1M11-OS27

SSMGeraghty & Miller, Inc.Report No. 8710479-3October 9, 1987Page 2

II. REACTIVITY

A. The sample was stable and did not undergo violent changes.B. No reaction was noted when mixed with water.C. No potential explosive mixtures were formed when mixed with water.D. No toxic gases, vapors or fumes were generated when mixed with water*

'; ii . ' ' ' .

E. No Sulfide (<26.8 mg/Kg) or Cyanide (<0.27 mg/Kg) was detected whenexposed to pH conditions between 2 and 12.

F. The sample did not detonate, explosively decompose or react atstandard temperatures and pressures.

III. IGNITABILITY

The sample does not exhibit the characteristic of ignltabllity as describedIn Section 2.1.1 of EPA SW-846.


PRN

cc: Mlchele RuthRichard Smith

AR301657K-6

EXGWfOS • RANHESS • SOEKTBIS v J


CLIENT: Geraghty & Miller, Inc. DATE REPORTED: 10/09/87844 West StreetAnnapolis MD 21401 REPORT NO: 8710479-004

DATE SAMPLED: 08/24/87SAMPLE TYPE: Soil DATE RECEIVED: 08/25/87

SAMPLED BY: Uesselman PURCHASE NO.:

SAMPLE IDENTIFICATION: Soil-Viscose Basin Material ORDER NO.:Front Royal Project - M0679FR6VB-1M-2



• "Total Moisture % . 83.3Volatile Matter % 13.7 81.8Fixed Carbon % 2.38 14.2Ash % 0.62 3.70

Heating Value Btu/lb 1160 6930

Sulfur % 0.05 0.30Carbon % 7.00 41.8Hydrogen (Excluding H In moisture) % 0.86 5.14Hydrogen (Including H in moisture) % 10.2Nitrogen % < 0.01 0.01Chlorine % < 0.01 < 0.01

AR30I658rorm No. Lilt R«v. 1/87 K-7REPLY TO:

O HOMC Off CE Q INDUSTOAL ___ O CHEMISTRY OLEMQH VALLEY OFFICE O SALTIMWC OFFlCI94*N.<*.««iuMtBfe«. tmUENE LABORATORY LABORATORY tteArtwr OMai Ptaafiuta 401 MS f*m**M A****

PA iMw-0307 pjasainov PJO. *» tsar. WMWIMPA taou js Towwn MO»i30*-auHM«n|PA 1M10430T f«M«nf PA1M114S2T (115) 433-.1* (301)4944900(215) J7«-«Si1

Geraghty & Miller, Inc.Report No. 8710479-4October 9, 1987Page 2

II. REACTIVITY

A. The sample was stable and did not undergo violent changes.B. No reaction was noted when mixed with water.C. No potential explosive mixtures were formed when mixed with water.D. No toxic gases, vapors or fumes were generated when mixed with water.E. No Sulfide (<21.9 mg/Kg) or Cyanide (<0.22 mg/Kg) was detected when



The sample does not exhibit the characteristic of ignitabllity as describedin Section 2.1.1 of EPA SW-846.


PRN

cc: Michele Ruth, Richard Smith

AR30I659

.'.».* > v0JGWEERS • RANNERS • SCENTOn , V





SAILED BY: Uesselman PURCHASE NO.:

SAM>LE IDENTIFICATION: Soil-Viscose Basin Material ORDER NO.:Front Royal Project - M0679FR6VB-11-2-3


AS RECEIVED DRY BASIS*

Total Moisture X .83.4Volatile Matter % 11.4 6.86Fixed Carbon % 1.67 10.1Ash % 3.53 21.2


Sulfur % 0.51 3.07Carbon % 5.20 31.3Hydrogen (Excluding H in moisture) % 0.56 3.37Hydrogen (Including H In moisture) % 9.89Nitrogen % < 0.01 < 0.01Chlorine % 0.01 0.06

AR30I660rorm No. L11* R»v. 1/87 K-9REPLY TO:

Q HOME OFFICE O MOUSTRUL . OCHEMSTRV *4o»a722L«hWiS> • SulM 10ft

«, WW--F* iaOtM43l T«w««-OS»y (Z1S)4a4iM 001)4944500

SSMGeraghty & Miller, Inc.Report No. 8710479-5October 9, 1987Page.2

II. .REACTIVITY




The sample does not exhibit the characteristic of ignitablllty as describedin Section 2.1.1 of EPA SW-846.

c tfu lly/ suBftjl tted,

IK.R. M. LARGEProgram SupervisorChemistry Laboratory

PRN


AR30I66I

K-10

SfOfB.SHVENSivdMc03V.INeCNGWIERS • RANNERS * SOEHItHS


CLIENT: Geraghty & Miller, Inc. DATE REPORTED: 10/09/87844 West StreetAnnapolis MO 21401 REPORT NO: 8710479-006



SAf-PLED BY: Wesselman PURCHASE NO.:

SAWLE IDENTIFICATION: Soil-Viscose Basin Material ORDER NO.:Front Royal Project - M0679FR6VB-11-3-4



Total Moisture % - 83.8Volatile Matter % 11.5 70.9Fixed Carbon % 1.12 6.91Ash % 3.58 22.1

Heating Value " Btu/lb 860 5310Sulfur % 0.50 3.08Carbon % 5.38 33.2Hydrogen (Excluding H in moisture) % 0.43 2.64Hydrogen (Including H in moisture) % 9.80Nitrogen % < 0.01 < 0.01Chlorine % 0.01 0.06

HR301&62orm No. L11« Rev. 1/87 K-ll

REPLY TO:

OHOMEOFFCC QMOUSTRUL QCHEMISTRY OLEMQH VALLEY OFFCE a BALTIMORE OFFC*MYCtEHE LABORATORY LABORATORY M«Artwr Offin Plat &*• 401 69S FalmMuM AwMM

RMding PA 1M104M7 PASMU07 PjO.BoK<S17. WhlwtM M tMS2-443i TowMH MOS1204-3S1SaiS)»T*-*301 RMdtaoPA 1M104307 tteMng PA1M11-OS27 (»S)43»41M (30t)4M4$00

(IIS) 37i-«5*l , (21S)S7<-4StS

SSMGeraghty & Miller, Inc. ' rReport No. 8710479-6October 9, 1987Page 2

II; REACTIVITY

A. The sample was stable and did not undergo violent changes.B. No reaction was noted when mixed with water*C. No potential explosive mixtures were formed when mixed with water.D. No toxic gases, vapors or fumes were generated when mixed with water.

; ' . * • ' • " •

E. No Sulfide (<24.8 mg/Kg) or Cyanide (<0.25 mg/Kg) was detected whenexposed to pH conditions between 2 and 12.


III. IGNITABILITY

The sample does not exhibit the characteristic of Ignitablllty as describedin Section 2.1.1 of EPA SW-846.

. Respectfully


PRN


AR301663

K-12

''**B4GMEEIS • RANNERS * KOtOOt

CERTIFICATE OF ANALYSIS 28198?

CLIENT: Geraghty 4 Miller, Inc. DATE REPORTED: 9/23/87844 West StreetAnnapolis MD ~21401 REPORT NO: 8710429-001

DATE SAMPLED: 8/21/87SAMPLE TYPE: Soil DATE RECEIVED:

SAMPLED BY: Client PURCHASE NO.:

SAMPLE IDENTIFICATION: Soil Sample - ORDER NO.:Viscose Basin Sub Surface WasteVB 10-18-20


Total Moisture - % 71.8Volatile Moisture % 17.6 62,3Ash % 8.20 29.0

Heating Value Btu/lb • 1260 4460

Sulfur % 0.95 3.36Carbon % 7.54 26.7Hydrogen (Excluding H in moisture) % 0.89 3.16Hydrogen (Including H In moisture) % 8.92Nitrogen - % 0.02 0.09Chlorine - % 0.03 0.03Oxygen (Excluding 0 in moisture) % 10.6 37.6Oxygen (Including 0 in moisture) % 74.3

Respectfu

JdHN M. MEHOLICK, ChemistChemistry Laboratory

PRNcc: Michele Ruth

Richard SmithaR30!66U

form No. L11« R«v. 1/87REPLY TO:

QHOUtOFFCE QMNJSTRML OCHEMSTRV OUMOM VALLEY ORBCE O BALT1MOW OFFICEVSRWyortMingBto*. HVQENE LABORATORY LABORATORY MKArftyrO«MPlMiS<*401 *» FHnnou* A«MwtPABM007 >4SN.W,8.lMl«iB*«. SONeMtSVMi >mU(iMSMI MM 10S

PA ittto-0307 fAmamtan pABoicsir. WMMM PA ta»MO» TMMH MOH»«s»tPA1M11-09ZT 01943M1M O01)4»«OSOB^«w^w» »-

.INCSNGWf Ett * RANNERS • SOEHTOTS


CLIENT: Geraghty & Miller, Inc. DATE REPORTED: 9/23/87„ 844 West Street

Annapolis MD 21401 REPORT NO: . 8710429-001

DATE SAMPLED: 8/21/87SATC»LE TYPE: Soil DATE RECEIVED:

SAILED BY: Client . PURCHASE NO.:

SAWLE IDENTIFICATION: Soil Sample - ORDER NO.:Viscose Basin Sub Surface WasteVB 10 - 18 - 20

REACTIVITY

A. The sample was stable and did not undergo violent changes.B. No reaction was noted when mixed with water.C. No potential explosive mixtures were forced-when mixed with water.D* No toxic gases, vapors or fumes were generated when mixed with water.

E. No Sulfide (<24.0 mg/Kg) or Cyanide (<0.25 mg/Kg) was detected when exposedto pH conditions between 2 and 12.

F. The sample did not detonate, explosively decompose or react at standardtemperatures and pressures.

The sample does not exhibit the characteristic of reactivity as described inSection 2,1.3 of EPA SW-846.

IGNITABILITY

The sample did not exhibit any signs of combustibility at Ambient or 60°C.Respectful ly-stibniitte/L

Q-y——• l S*" f ~~ V—— **"

,dOHN M. MEHOLICK, Chemist,. 0 n l C C CPRN Chemistry Laboratory AR3'UlbDJ

^~s n No. tllb R«v. 8/86-• - . . _ . . - - - - - ___———- - - — - «\™i 4

REPLY TO:OHOME OFFICE QNOUSTRWL cpteumtrr

lASORlTOIir.

RMding.PA 1S010-OM7 PABo>tM7 PARWSS27. UMghion, PA 1U35-I751 TowMn. MD tl204-2S1*HM««.PA ^ ^fl(ij »TC-f5*t

SEP 28 W87

CERTIFICATE OF. ANALYSIS

spom.srtvo« «J MCCOT. me• RANNEBX • SOEKTOIS I


DATE SAMPLED: 8/19/87'?SAMPLE TYPE: Soils DATE RECEIVED: 8/20/87

SAILED BY: Wesselman PURCHASE NO.:

SAW>LE IDENTIFICATION: Soil - Project M0679FR6 ORDER NO.:Front Royal-Viscose Basin

SamplesVB-10 - Surface

I. CHEMICAL ANALYSIS


Total Moisture % 18.0;Volatile Matter % 67.3 82.0Fixed Carbon % ' 7.09 8.72Ash X 7.61 9.28


Sulfur - % 0.23 0.28Carbon % 32.4 39.5Hydrogen (Excluding H in moisture) % 4.35 5.30Hydrogen (Including H in moisture) % 6.36Nitrogen % 0.07 0.08Chlorine % 0.01 0.01

II. IGNITABILITY

The sample does not exhibit the characteristic of ignitabillty as describedin Section 2.1.1 of ERA SW-846.

. orm No. Lit* R«v. 1/87

RR30I666K-15

REPLY TO;

OHOUC OFFICE OMOUSTRML o CHEMISTRY QLEMQH VALLEY OFFICE n BALTIMORE OFFICEMSKWywriMinf 8M«. HYGIENE LABORATORY LABORATORY MKArffMrOHbtPtattSidM40l MS FclRiMuM AtomicPABMUOT . »4»N.W|romiuf««SML. MNottoSMM. vn UNgh S»MI SuR« 10SRM«IM PA 1MW4307 P.O. BM HOT PjaBM«2T. WhMMi M ia«*443* • TewMM MO Iia04-2S1t

RM«n|PA IM10 307 fWMng PAlMII-OStr OIBJ43M10B p01)4»4«900(21S) 37»-«M1 (21$) 3TC-4MS

SSMGeraghty & Miller. Inc.Report No. 8710394-001September 24, 1987Page 2

III. REACTIVITY

A. The sample was stable and did not undergo violent changes.B. No reaction was noted when mixed with water.C. No potential explosive mixtures were formed when mixed with water.

t,; ' ~ ' i

D. No toxic gases, vapors or fumes were generated when mixed with water.E* No Sulfide (<23.6 mg/Kg) or Cyanide (<0.25 mg/Kg) was detected when

exposed to pH conditions between 2 and 12.F. The sample did not detonate, explosively decompose or react at standard

temperatures and pressures.The sample does not exhibit the characteristic of reactivity as describedIn Section 2.1.3 of EPA SW-846.

ctfully

R. H. LARGE, Program SupervisorChemistry Laboratory

PRN


K-16

*n;.t 'i _____ _____ _"l' •. .-/ i ^ ^ - M MI w *mSfrl. / worn. JTIVD* «pJ MeOT. weV/ENGiNKlS • RANNERS • SOENIKrS


CLIENT: Geraghty & Miller.Inc. DATE REPORTED: 9/24/87844 West StreetAnnapolis MD 21401 REPORT NO: 8710394-002


SAMPLE TYPE: Soils DATE RECEIVED: 8/20/87

SAT-PLED BY: Wesselman PURCHASE NO.:

SAMPLE IDENTIFICATION: Soil - Project M0679FR6 ORDER NO.:Front Royal-Viscose Basin

SamplesVB-10 - 2-0'- 8-0'

.1. CHEMICAL ANALYSIS


Total Moisture % 87.7Volatile Matter % 8.55 69.4Fixed Carbon % ' 0.39 * 3.30Ash % 3.36 27.3


Sulfur " % 0.38 3.09Carbon % 3.70 30.1Hydrogen (Excluding H In moisture) % 0.44 3.56Hydrogen (Including H In moisture) % 10.2Nitrogen % 0.01 0.10Chlorine % 0.01 0.04

II. IGNITABILITY

The sample does not exhibit the characteristic of ignitability as describedin Section 2.1.1 of EPA SW-846.

AR30I668orm No. L11« R«v. 1/87 K-17

REPLY TO:

QHOMEOFFICE QWOUSTRIAL__ __ OCHCMSTRV OLCMQM VALLEY OFFICE Q BALTIMORt OPPICtMMWVMiuiivS**. MYGCNE LABORATORY LABORATORY MMAf«ur OMo* Pirn &** 401 68S FcMnwM AMIMMPABwdOr MSHWiKMiMinoBM. MNoW«SM«. STBUNgliSM* Soil* 10SRufiiS PA 1M104307 PABMB30T pjO.BMUXT. WNMWI PA 100SM43* Towvon MO*l2044BtSaiSta7«-«M1 RiiflHi PA 19*10-0307 RM«nf PA 1M11-OSZ7 (t1S)43M1M POt)«t4OSOO

B19|37«-45M

SSMGeraghty & Miller, Inc,Report No. 6710394-002September 24, 1987Page 2

III. REACTIVITY


exposed to pH conditions between 2 and 12.

F. The sample did not detonate, explosively decompose or react at standardtemperatures and pressures.1 ' • .

The sample does not exhibit the characteristic of reactivity as describedIn Section 2.1.3 of EPA SW-846.

tted,

R. M. LARGE, Program SupervisorChemistry Laboratory

PRN


AR30I669

K-18

SPOTB.STCVEHS md McCOT.INC• RANNEKS * SOBflBIS


CLIENT: Geraghty & Miller, Inc. DATE REPORTED: 9/17/37844 West StreetAnnapolis, MD 21401 REPORT NO: 8710265-001


SAMPLE TYPE: soil DATE RECEIVED: 8/17/1?

SAfPLEO BY: K. Wesselman PURCHASE NO.:

SW-PLE IDENTIFICATION: VBI-2-6 ORDER NO.:Front Royal Project M0679FR6

I. CHEMICAt ANALYSIS OP MHJABtE FRACTION*

AS RECEIVED DRV BASIS

Total Moisture % 41.4Volatile Matter Z 14.9 25.4Fixed Carbon X 2.20 3.80Ash t . 41.5 70.8


Sulfur Z S 2.00 3.41Carbon • Z C 6.67 11.4Hydrogen (Excluding H in moisture) Z H 0.65 1.10Hydrogen (Including H in moisture) Z H 5.28Nitrogen Z N 0.10 0.17Chlorine Z Cl <0.01 <0.01

II. IGNITABILITYThe sample does not exhibit the characteristic of ignitability as describedin Section 2.1.1 of EPA SW-846.

* NOTE:Analysis performed on ml 11 able portion only. Approximately 38Z of thesample consisted of dense hard plastic-like circular plugs which couldnot be blended into the analysis sample. This material was removed he-fore analysis as per instructions from Richard Smith 8/25/87.

AR301670,rm No. L11a Rev. t/87 R-13

RgPLVTOi "~

OHOMCOFFICt QWOOSTMAL__ _^ QCHCMSTMV QtEMOHVALLEVOFFICf Q BALTIMOWOFFICfMSM.Wy«*iM*9»*«, HYGlEMlLAeOWATOrW LABOflATCMV MMAffwr OffiM Ptan S»W 401 «• Fklrmount AWHM

OOr MMWywniuingaM. MNoWtSMM. 3722 UMgd SffMt SiriW 10SPA 1M10-OM7 PA8»««30T __ fA9MWV. WNMuft PA 1WS2-3O* Tow»en MO 212044819

RMtfn,PA IMIO-OaOf R.i*n, FA 1MH-OS3T <21S|43»41M p01|4»44>900C21«37«-iS»l

SSMGeraghty & Miller, Inc.Report No. 8710265September 17, 1987Page 2

III. REACTIVITY

A. The sample vas stable and did not undergo violent changes. »

B. No reaction vas noted when nixed with vater.

C. No potential explosive mixtures vere formed when mixed withvater.

D. No toxic gases, vapors or fumes vere generated when mixed withvater.

E. No Sulfide (<44.3 mg/fcg) or Cuanide (<0,50 mg/kg) vas detectedwhen exposed to pH conditions between 2 and 12,

F. The sample did not detonate, explosively decompose or react atstandard temperatures and pressures*

The sample does not exhibit the characteristic of reactivity as describedin Section 2.1.3 of EPA SW-846.

t fully submitted,

R. M. Large - Program SupervisorChemistry Laboratory

OMDcc: Michelc Ruth

Richard Smith

AR30167I

JC-rfcO

• RANNOIS • SOWTOT ,


CLIENT: Geraghty & Miller, Inc. DATE REPORTED: 9/17/87844 West StreetAnnapolis, MD 21401 REPORT NO: 8710221-003

SAMPLE TYPE: Solid Hast* DATE RECEIVED: 8/13/87

SAILED BY: Vesselmaa/Sarrientes PURCHASE NO.:

SAWLE IDENTIFICATION: VB2-17-22 ORDER NO.:Porject M0679FR6

I. CHEMICAL ANALYSIS OF MILLABLE FRACTION*


Total Moisture Z 64.0Volatile Matter Z 14.6 40.6Fixed Carbon Z <0.01 <0.01Ash Z . 27.2 75.7


Sulfur Z S 0.15' 0.42Carbon • ZC 2.06 5.72Hydrogen (Excluding R in moisture) Z R 0.22 0.60Hydrogen (Including R in moisture) Z H 7.38Nitrogen Z N 0.04 0.10Chlorine Z Cl <0.01 <0.01

II. IGNITABIHTYThe sample does not exhibit the characteristic of ignitability as describedin Section 2.1.1 of EPA SW-846.

* NOTE:Analysis performed on mi11able portion only. Approximately 15.6Z of thesample consisted of dense hard plastic-like circular plugs which couldnot be blended into the analysis sample. This material was removed be-fore analysis as per instructions from Richard Smith 8/25/87.

flR30!672>rm No. Llla Rev. 1/87 K-21

REPLY TO:

O HOMf OFFCC D MOUSTNAL OCHEMtSTMV Q LEMOH VALLEY OfKX Q BALTIMORE OfftC€MSHWyonriuiAgaM, HrOCNC iABOflATOW LA80MTORV WMAfffmr OffiM Pua SuMt 401 6M PclrmetHrt A««nu,PO.BMU07 145MWy«miUin08MH MNOMfSMM. JTBUhignSVMI StHW IDSAM«nfl PA 1««10-0»T P&aMCW PJ».BM«S2r. WhiMfMl M 1*052.10, Towton M0»l204.2t1tai|ia7t-«Ml AMdiiif PA 1MIO-OMT A*«din§ PA 1M11-O92T (21 S»439-tlH O01)4»4«SOO

12131 JT«-f HI R1S) 3?ft-4$9$

SSMGeraghty & Miller, Inc.Report No. 8710221-003September 17, 1987Page.2

III. ' REACTIVITY

A. The sample vas stable and did not undergo violent changes.

B. No reaction vas noted when mixed with vater.

C. No potential explosive mixtures vere formed when mixed withvater.

D. No toxic gases, vapors or fumes vere generated when mixed withvater. _ „ .. ,.

C. No Sulfide <<24.4 mg/kg) or Cyanide (<0.25 mg/kg) vas detectedwhen exposed to pH conditions between 2 and 12.


The sample does not exhibit the characteristic of reactivity as de-scribed in Section 2.1.3 of EPA SW-846.


OMD ,cc: Michele Ruth

Richard Smith

RR30I673

K-22

^•A •ts~fzr srons.srcvcNS «W MCCOT.INCf£ XaiCINCEIS • RANNCtS * SOENTOT ,

^CERTIFICATE OF ANALYSIS

CLIENT: Geraghty & Miller, Inc. DATE REPORTED: 9/17/87844 Vest StreetAnnapolis, MD 21401 REPORT NO: 8710221-001

DATE SAMPLED: Unknown*SAMPLE TYPE: Solid Waste DATE RECEIVED: 8/13/87

SAM>LED BY: Wesselmaa/Barrientes • PURCHASE NO.:

SAMPLE IDENTIFICATION: VB3-4-7 ORDER NO.:Project M0679FR6



Total Moisture Z 41.3Volatile Matter X 5.49 9.36Fixed Carbon X <0.01* <0.01Ash X • 54.9 93.6


Sulfur X S 0.22 0.37Carbon Z C 0.69 1.18Hydrogen (Excluding H in moisture) X H <0.01 <0.01Hydrogen (Including H in moisture) X H 4.62Nitrogen X N 0.02 0.04Chlorine Z Cl 0.02 0.03

II. IGNITABILITY

The sample does not exhibit the characteristic of ignitabillty as describedin Section 2.1.1 of EPA SW-846.

rm No. L11a R«v. 1/87 K-23 ft K O U IREPLY TO;

SSSr—

Geraghty & Miller, Inc.Report No. 8710221-001September 17, 1987Page 2

III. REACTIVITY

A. The sample vas stable and did not undergo violent changes.

B. No reaction vas noted when mixed with vater.

C* No potential explosive mixtures vere formed when mixed withvater.

D. Ho toxic gases, vapors or fumes vere generated when mixed withvater. .

E. No Sulfide (<24.2 mg/kg) or Cuanide (<0.25 mg/kg) vas detectedwhen exposed to pH conditions between 2 and 12.

F. the sample did not detonate, explosively decompose or react atstandard temperatures and pressures.

The sample does not exhibit the characteristic of reactivity as de-scribed in Section 2.1.3 of EPA SW-846.

itted,


OMDcc: Mlchele Ruthf

Richard Smith

AR30I675

K-24

srom.srcva« «w MCCOT.INCENCMCEIS * RANNBB * SOCNTBIS


CLIENT: Geraghty & Miller, Inc. DATE REPORTED: 9/17/87844 West StreetAnnapolis, MD 21401 REPORT NO: " 8710221-002

DATE SAMPLED: Unknown

SAMPLE TYPE: solid Waste DATE RECEIVED: 8/13/67

SAMPLED BY: Wesselman/Barrientes PURCHASE NO.:

SAMPLE IDENTIFICATION: VB2-5-7 ORDER NO.:Project M0679FR6



Total Moisture Z 13.2Volatile Matter Z 2.37 2.73Fixed Carbon X <0.01~ <0.01A«h Z • 85.2 98.1

Heating Value Btu/lb <50 <50

Sulfur Z S 0.26 0.30Carbon - Z C <0.01 <0.01Hydrogen (Excluding H in moisture) Z H 0.01 0.01Hydrogen (Including H in moisture Z R 1.48Nitrogen Z N 0.02 0.02Chlorine Z Cl <0.01 <0.01

II. IGNITABILITY

The sample does not exhibit the characteristic of Ignitability as describedin Section 2.2.1 of EPA SW-846.

K-25 AR30I676•m No. Llla Rev. 1/87

HEPLYTO:

O HOMf OFFId Q MOUSTMAL 0 CHEMSTHV

S2«30PA

1M10430T ftadMf PA IM11-OS2T<?1HJ7«-4S»

OCT191987•ewttts • RANNEIS • KXNreis


CLIENT: Geraghty & Miller DATE REPORTED: 10/13/87844 West Street -Annapolis MD 21401 REPORT NO: 8710541-001


SAMPLE TYPE: Solid Waste DATE RECEIVED: 08/27/87


SAWLE IDENTIFICATION: Solid Waste - Front Royal ORDER NO.:Project

Project M0679FR6Sample VB - 9 Surface


AS RECEIVED - DRY BASIS

Total Moisture % 27 9*Volatile Matter* % . ss.e 81.3Fixed Carbon % 9.15 12.7Ash X 4.35 6.04Heating Value Btu/lb 5000 6940

Sulfur - ' * 0.16 0.22Carbon 3t 29 4 40 8Hydrogen (Excluding H In moisture) % 3.*90 5*41Hydrogen (Including H In moisture) % 7.03Nitrogen % < 0.01 < 0.01Chlorine % 0.02 0.02

* 12 Minute Volatile

irm No. Llla Rev. 1/87 K»26REPLY TO:

— gjr— SSSr- ss— ss—

IMOT.MC

Geraghty & MillerReport 8710541-001October 13. 1987Page 2

II. REACTIVITY

A. The sample was stable and did not undergo violent changes.B. No reaction was noted when mixed with water. *C. No potential explosive mixtures were formed when mixed with water.D. No toxic gases, vapors or fumes were generated when mixed with

water.E. No Sulflde (<24.3 mg/Kg) or Cyanide (<0.25 mg/Kg) was detected

when exposed to pH conditions between 2 and 12.F. The sample did not detonate* explosively decompose or react at



Respectfully submitted.


PRN


K-27

W srom.ntvENS mi jtiueor.MCHGffrtSB • RANNOS * tCEHRSR


CLIENT: Geraghty & Miller DATE REPORTED: 10/13/87844 West StreetAnnapolis MD 21401 ~ REPORT NO: 8710541-002


SAMPLE TYPE: Solid Waste ; DATE RECEIVED: 08/27/87


SAMPLE IDENTIFICATION: Solid Waste - Front Royal ORDER NO.:Project

Project M0679FR6Sample VB - 9 - 0 - 2

.1. CHEMICAL ANALYSIS


Total Moisture % 90.2'Volatile Matter X - 8.05 81.7Fixed Carbon % 1.03 ' 13.2Ash . .tX 0.45 4.57


Sulfur % 0.05 0.51Carbon , X','.., 4.06 41.2Hydrogen (Excluding H In moisture) ,t; 0,55 5.27Hydrogen (Including H 1n moisture) X 10.6Nitrogen X < 0,01 0.01Chlorine X < 0.01 0.03

AR30167SNo. L11a R«». 1/87 K-28

REPLY TO:Q HOW* OFFICE QMOUSTRMI. OCHEWSTftr QLEHM3H VALLEY OFFICE Q BALTIMORE OFFICE

HVOKNE LABORATORY UBOAATORV M Arttur Oflto> Ptoa **• 401 9M Fahmeuni *«WHM

PA ItilO-OMT Pfl,«M«»r PABMCSXT. WNWtM PA 1MS2 4» T«w«O«PA 1KW4307 RMdM» PA 1»611-M3? (n» 433-41M (301) 4944500

SSIVIGeraghty & MillerReport 8710541-002October 13, 1987Page 2

II. REACTIVITY

A. The sample was stable and did not undergo violent changes.J«ta-

B. No reaction was noted when mixed with water.C. No potential explosive mixtures were formed when mixed with water.D. No toxic gases* vapors or fumes were generated when mixed with

water.

E. No Sulflde (<20.1 mg/Kg) or Cyanide (<0.20 mg/Kg) was detectedwhen exposed to pH conditions between 2 and 12.

F. The sample did not detonate* explosively decompose or react atstandard temperatures and pressures.

III. -IGNITABILITY

The sample does not exhibit the characteristic of reactivity as describedIn Section 2.1.3 of EPA SU-846.

Respectfully submitted,


PRN


RR301680

K-29

RAHNBtS «


CLIENT: Geraghty & Miller DATE REPORTED: 10/13/87844 West StreetAnnapolis MD 21401 REPORT NO: 8710541-003


SAMPLE TYPE: Solid Waste : DATE RECEIVED: 08/27/87

SAMPLED BY: Wesselman : - PURCHASE NO.:

SAMPLE IDENTIFICATION: Solid Waste-^Front Royal ORDER NO.:Project

Project M0679FR6Sample VB - 9 - 2 - 4


-ir"i;- AS RECEIVED DRY BASIS

Total Moisture X 84.8'Volatile Matter . X • 11.7 77.1Fixed Carbon J-"l 1.51 9.95Ash X 1.99 13.1


Sulfur - X 0.29 1.91Carbon ., . X 6.97 45.9Hydrogen (Excluding H 1n moisture)4 :X 0.50 3.28Hydrogen (including H In moisture) % 9.99Nitrogen ! r fX 0.01 0.04Chlorine X 0.01 0.06

AR30168Iarm No. L11a R«v. 1/87 K-30

REPLY TO:

O HOME OFFICE O MOUSTRML QCHEMOTRY QLEHOH VALLEY OFFICE O BALTIMORE OFFICE»43N.Wyw~*H«flBNd_ HVOJENC LABORATORY IABORATORY MKArftur OMn Pton Soft, 401 •« Mnwunl AVWNMP.O.fc»MOr »45HWiwliilnBBML aONeWcfttMt 3T72UN*SVM SwIM W*RM«AO PA 1M1O-O30T PABwCWT Pja*M<UT. WNtahM PA WU-3430 TCWMA WO tl204-2*1*

1t6W-030T Rllffnfl PA 1t611-OS2T

Geraghty & MillerReport 8710541-003October 13. 1987Page 2

II. REACTIVITY

.A. The sample was stable and did not undergo violent changes.B. No reaction was noted when mixed with water.C. No potential explosive mixtures were formed when mixed with water.D. No toxic gases* vapors or fumes were generated when mixed with

water.E. No Sulfide (<24.0 mg/Kg) or Cyanide (<0.25 mg/Kg) was detected

when exposed to pH conditions between 2 and 12.


III. IGNITABILITY




PRN

cc: Mfchele RuthRichard Smith

AR30I682

K-31

SPOTTMTSVENS mi McCOY.INCENONCOtS • RANNERS • fOENTSlS


CLIENT: Geraghty & Miller DATE REPORTED: 10/13/87844 West StreetAnnapolis MD 21401 REPORT NO: 8710566-001


SAMPLE TYPE: Solid Waste , DATE RECEIVED: 08/28/87

SAWLEO BY: Wesselman PURCHASE NO,:

SAMPLE IDENTIFICATION: Solid Waste - Front Royal ORDER NO.:Project

Project M0679FR6Sample VB.-.9 r 16 - 18

•I. CHEMICAL ANALYSIS


Total Moisture X 79.0 *Volatile Matter X • 15.0 71.4Fixed Carbon X 1.02 * 4.85Asn ; : * 4-98 23-7Heating Value Btu/lb 1170 5570

Sulfur fX 0.78 3.71Carbon * 8.22 39.1Hydrogen (Excluding H In moisture) _X 0.25 1.18Hydrogen (Including H In moisture) X 9.09Nitrogen % 0.05 0.21Chlorine % <0.01 <0.01

AR30I683arm No. L11« R«v. 1/87 K-32

REPLY TO:

Q HOME OFFCE Q MOUSTRML QCHEMSTRYLABORATORYRMdingPA 1MI04W7 P.O.B<w«07 PABMCS27. WhMMl PA 1MS2-MM ToMen HD 212044019

IK 1 0-030 7 ^

SSMGeraghty & MillerReport 8710566-001October 13, 1987Page 2

II. REACTIVITY

A. The sample was stable and did not undergo violent changes. sB. No reaction was noted when mixed with water.C. No potential explosive mixtures were formed when mixed with water.D. No toxic gases* vapors or fumes were generated when mixed with

water.

E. No Sulfide (147 mg/Kg) or Cyanide (<0.25 mg/Kg) was detectedwhen exposed to pH conditions between 2 and 12.


III. IGNITABILITY




PRN


K-33

SfOTTLfTCVCNS mi McO3T.lNCVONEEKS • RANNCtS • KENTSB


CLIENT: Geraghty & Miller DATE REPORTED: 10/13/87844 West StreetAnnapolis MD 21401 REP«T NO: 8710747-001

: DATE SAMPLED: 09/01/87

SAMPLE TYPE: Solid Waste DATE RECEIVED: 09/03/87

SAWLED BY: Wesselman * PURCHASE NO.:

SAMPLE IDENTIFICATION: Solid Waste•* Front Royal ORDER NO,:Project

Project M0679FR6Sample VB - 7 - 14-15

J. CHEMICAL ANALYSIS


I j Total Moisture X • 71.8 '^ Volatile Matter* X - 16.0 56.7

Fixed Carbon X 1.80 ' 6.38Ash % 10.4 36.9


Sulfur % 1.20 4.25Carbon % 8.61 30.5Hydrogen (Excluding H in moisture) X 0.99 3.50Hydrogen (Including H in moisture) X 9.02Nitrogen % , 0.04 0.13Chlorine J;, 0.02 0.08

* 12 Minute Volatile

AR30I685No. L11« R«v. 1/87

REPLY TO:O HOME OFFICE O INDUSTRIAL OCHEuaTRv

tABORATORY

1M104WT °7 PJ0.»0.«W. WNMtf M HOSZ-MM TowtOA MO *l20*2*1tQ01)4»44600

SSMGeraghty & MillerReport 8710747-001October 13, 1987Page 2

II. REACTIVITY

A. The sample was stable and did not undergo violent changes.B. No reaction was noted when mixed with water.C. No potential explosive mixtures were formed when mixed with water.D. No toxic gases, vapors or fumes were generated when mixed with

water.E. Sulfide (65.7 mg/Kg S*) was detected when exposed to pH condi-

tions between 2 and 12.

F. No Cyanide (<0.25 mg/Kg CN) was detected when exposed to pH condi-tions between 2 and 12.

G. The sample did not detonate* explosively decompose or react atstandard .temperatures and pressures.

III. IGNITABILITY

The sample does not exhibit the characteristic of reactivity as describedin Section 2.1.3 of EPA SW-846.



PRN


RR301636

K-35

ISo

AR30I687

CERAGHTY ft MILLER, INC

AVTEX FIBERS, INC. • LABORATORY TESTS " '.' * J « ' •

UET NATURAL ATTERBER6 LIMITS UHCONFINED ONEUNIT MOISTURE ***••••*****•****•••**•••••*•«******* COHPRESS1VC DIMENSIONAL

SPECIFIC WIGHT CONTENT GRAIN-SIZE LIQUID PLASTICITY SHRINKAGE STRENGTH CONSOLIDATIONGRAVITY (PCF) (X) DISTRIBUTION LIMIT INDEX (R) (J) (PSF) TEST

2VB-1-1-4 2.32 82.1 67.6 NT(1) 54 17 1.86 15.51 1&9 . SEC GRAPHSILT, SOME FIBEROUS ^MATERIAL AND FIHC TO —

MEDIUM SAND

II

2VS-1-10-12 2.69 . 121.5 27.6 C.SAHD*O.OX (6 25 1.87 14.99 18(2 SEC CXAPNLIGHT CRAY AND YELLOU M.SANO*0.5XBROUN CUV,UITN TRACE : F.SAM»4.6X

SAND AND FIBERS *' JEP«00«94.9X

V9-7-15-17 1.80 79.1 455.4 NT(3) NT (3) NT<3) NT (3) KT<3> 372 NT(2)BLACK RUBBERY MATERIAL

VB2-2-4 NT 63.5 508.4 NT(1) NT{1) NT(1) NT (3) NT (3) 557 SEE CftAPNSANDY CLAY WITH BLACK. . RUBBER MATERIAL

V83-2-* ,S-1 2.70 118.1 25.7 f. GRAVEL-0. 7X 22 5 1.82 14.34 125 SEC GRAPH

SILTV CLAY, LITTLE C.SAND-1.0XFINE TO MEDIUM SAND M. SAND -3. OX

F.SANO»11.7XXP*200z83.6X

VB3-2-4S-2 2.70 113.3 29.8 C.SAND*2.7X NT(1) NT(1) NT(3) NT(3) NT(2) SEE GRAPH

BLACK RUBBER MATERIAL M.SAHOO.1X| MIXED WITH GRAY BROUN F.SAHO-10.9X: SILTY CLAY .. .i*.., . -- ' XP*200«83.3X . - - .' ;.

, 1. Test was attempttd but failed because of the material| . (material was rubbery and would not «(x with water).t

2. Proper test sample could not be obtained (rubbery of fibrous materialI • could not be cut or would not hold Its shape).

3. Test was not performed because material was evaluated to bt sfmtlar; to material that failed because of reason 1.

AR30I688

L-l

GERAGHTY t KILLER, IKC (

AVTEX FIBERS, INC. » LABORATORY TESTS

VET NATURAL ATTCR8ERG LIMITS UNCOKFINED ONE( U N I T MOISTURE «•••••*••****••••«******••«••*«••**•** OPPRESSIVE DIMENSIONAL

SPECIFIC WEIGHT CONTENT 6RAIN-SIZC LIQUID PLASTICITY SHRINKAGE STRENGTH CONSOLIDATIONGRAVITY (PCF) <X) DISTRIBUTION LIMIT INDEX (R) (S) (PSF) TEST

VB10-0-2 1.53 63.0 971.3 NT(3) NT(3) NT(3) NT(3) NT(3) 69 SEE GRAPH•LACK AND GRAY . . _ . _ . - . *RUBBERY MATERIAL

VB10-12-14 1.62 59.9 351.4 NT(3) NT(3) NT(3) NT(3) NT(3) 8051 SEC GRAPHCRAY AND WHITE

RU8BERY MATERIAL,GREEN RUBBERY MATERIAL

IVB-9-0-2 1.61 60.4 928.9 NT(1) N7(1) NT(1) NT(3) NT(3) 1113 SEE GRAPH

GRAY AND WHITERUBBERY MATERIAL

VS-9-10-12 1.91 98.6 300.0 *T<3) «T(3) NT(3) NT(3) HT(3) NT(2) NT(2 IGk ri,BLACK AND WHITE

RUBBERY MATERIAL

VB-11-11-13 2.35 57.2 412.8 NT(3) NT(3) NT(3) NT(3) NT<3) NT(2) SEE GRAPHGRAY AND WHITERUBBERY MATERIAL

VB-lt-1-2 1.61 61.2 482.6 NT(3> NT(3) NT(3) NT(3) NU3) NT(2) IfEC GRAPHWHITE AND GRAYRUBBERY MATERIAL•;

1. Test was attempted but failed because of the material^material was rubbery and would not m\x with water).

.?y2. Proper test sample could not be obtained (rubbery or fibrous material

could not be cut or would not hold Its shape).

3. Test Mas not performed because material was evaluated to be similarto material that faded because of reason 1.

AR30I689

1-2

RR301690

ENVXRONMENTAL .LABORAIDRIESINC

««t_. -

STUDY TO DETERMINE RIVER CONTAMINATION

FROM CONTAMINATED AQUIFER AT

AVTEX FIBERS

August 31, 1984

W. Burton BlacKburnInstrumental Analysis/Quality Assurance

Donna L. Wirick " T~ ~~ A R 3 0 1 6 9 1General Chemical Analysis "

INTRODUCTION

On 19 and 20 June/ 1984, samples were collected on the Shenandoah Riverin compliance with a SWCB request to investigate the possibility ofcontaminated groundwater leaching through faults into the river. Thesegeologic faults run under the Shenandoah River in a diagonal fashion.

METHODS

1) Sampling

A cord calibrated in 1 meter increments was attached at eachbank running parallel to geologic faults. The upstream (control)station was located about 25 meters downstream from the gaugingstation located just upstream from the Avtex Fibers plant. Down-stream samples were collected about 10 meters downstream of a drain-age discharge area. At this station, a substance resembling ash •was floating on top of the water from the bank to about 3 metersout. Photographs are enclosed-ofeach sampling location.

Sampling at the upstream (control) station began 1 meter fromthe bank and progressed in 2 meter increments from the east bankto the west bank. Sampling began at 0900 EDT on 20 June and wasfinished by 1130 EDT the same day.

Sampling at the downstream station began 3 meters from the bank(due to shallow, silty conditions) and progressed in 1 meter in-crements from the east bank to the west bank. Sampling began on19 June at 1030 EDT and was finished by 1730 EDT the same day.

All samples were grab samples taken at mid-water depth. Sampleswere iced and preserved (where appropriate) on site and deliveredto Environmental Laboratories, Inc. for analysis. Sampling methods

&R30I692M-2

ENVIRONMENTAL .LABORATORIES INC

conformed to "Handbook for Sampling and Preservation of Hater andWastewater, "U.S.E.P.A. (EPA-600/4-82-029), September 1982.

2) Analytical

Analytical methodology conformed to "Methods of Analysis forWater and Wastes," U.S.E.P.A. (EPA-600/4-79-02) Rev. March 1983.

DATA

Data is presented in tabular form by transect. Sample locationsprogress along the transect aS indicated.

AR30i&93M-3

ENVIRONMENTAL .LABORATORIES INC

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Geraghty & Ml HOP, Inc.

SURFRCE WflTER CHEMICRL SURVEYSOUTH FORK OF THE SHENRNDORH

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Geraghty & Mfllcr, Inc

SURFRCE WRTER CHEMICRL SURVEYSOUTH FORK OF THE SHENRNDORH

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SURFRCE NRTER CHEMICRL SURVEYSOUTH FORK OF THE SHENRNDORH

SUMMRRY STRTISTICS9/24/84

M-33 AR30I723

Gcraghty & Miller, Inc.

Significance Testing

Two river water quality samples were collected upstream

and downstream from the AVTEX site in June 1984* Summary

statistics for these water quality samples are presented in

Table 1 . The two samples were compared to detect statis-

tically significant differences in upstream and downstream

water quality.

The number of observations for each water quality

variable differed for the upstream and downstream samples.

In addition/ the variance for a water quality variable was

not always constant between the sampling locations. The

equality of variances for two samples can be tested by an

F-test. The form of a hypothesis test for ecjsality of

variances is shown in Table 2.

In order to detect differences between the seans of

two samples, the pooled t test is employed for the following

cases:

1) equal sample sizes and equal populationvariances

2) unequal sample sizes and equal populationvariances

3) equal sample sizes and unequal populationvariances

The form of the pooled t hypothesis test is given ij» Table3.

M-34 IS3QI72!*

Geraghty & Miller, Inc

TABLE 1.

Downstream Sampleno. of observations (nj) • 126

water QualityVariable

Sodium

IDS

(Hardness

Conductivity

Sulfate

Chloride

Sulfide

Alkalinity

Mean*1

9.0

188

147.7

271

16

10.15

<1

141.21

StandardDeviation, Si

1.03

47.2

17.3

17.4

3.0

1.67—

8.26

VarianceS12

1.06

2225

298.8

301.2

8.93

2.81

—

68.21

MaximumValue

11.9

330

245.3

290

30

20.99—

159.77

MinimumValue

2.7

84

91

205

11

6.08

78.5

M-35

AR30I725

Geraghcy & Miller, Inc

TABLE 1., cont

Upstream Sampleno. of observations (n> * 47

Water QualityVariable

Sodium

IDS

Hardness

Conductivity

Sulfate

Chloride

Sulfide

Alkalinity

Mean StandardXi Deviation, $2

8.8

197

150.3

272

15

9.97

<1

143.50

0.39

51.8

13.1

16.4

1.4

1.47

—

9.80

VarianceS22

0.15

2687

172.2

269.2

2.02

2.17

—

96.06

MaximumValue

9.5

316

173.0

310

18

12.62

—

169.00

MinimumValue

7.7

72

122.5

230

12

7.17

—

96.04

M'36 AR30I726 v .N.—X


CTABLE 2

Equality of variences hypothesis test .

1. null hypothesis (Ho): "'&J'1 ' <*2*

2. alternate hypothesis (H ): *2 > 0z2

3. test statistic: P - Sj2 (S^2 < S22)

dfj-nj-1

4. rejection rule: reject Ho if F > F

where: ai. population variance for Sample 1si82

2 population variance for Sample 2f sample variance of Sample 12 sample variance of Sample 2

number of observations in Sample 1number of observations in Sample 2

AR301727tt-37


TABLE 3.

Pooled t hypothesis test (one-tailed test)

1. null hypothesis (Ho): Vi a H*

2. alternate hypothesis (HA) : Vi > Vz

3. test statistic: t*« X1 - »2

*2

V*2= v *l+12 2 oS = (n,-l) (S. ) + (n.-l) (S. )i 1 »"~2 * * 5

4. rejection rule: reject Ho if t" > t(apdf)a & level of significance

where: Ui « population mean for Sample 1IU = population mean for Sample 2KI 3 mean of Sample 1*2 ~ mean of Sample 2n^ s size of Sample 1n2 = size of Sample 2s.,2 = variance of Sample 12s- = variance of Sample 2

flR30I723

M-38


For the case when sample sizes and variances are

not equal, Welch's approximate t statistic can be substitued

for the t * calculated in the pooled t test. Welch's ap-«r» f. •

proximate t is calculated as follows:

V •• Vxl X2•v S 2 S 2Sl + S2nl n2

The number of degrees of freedom are calculated by:

Sl2/nldf - (n,-l) (n--l) where c« x "L1____z _________ ~T5—— 2S-* — *

^ ^ 1 2(n2-l) C" +--{n1-l) (l-c)41 __ + __2 x n, + n-1 2

A summary of the tests for equality of variances and

equality of means are listed in Table 4. Only a significantf "increase in sulfate was detected in the downstream sample.

M-39


TABLE 4.

* significant at a * 0.01** significant at a - 0.01

Water QualityVariable

Sodium

TDS

Hardness

Conductivity

Sulfate

Chloride

Alkalinity

CalculatedF Statistic

7.07*

1.21

1.74

1.12

4.42*

1.29

1.41

Calculatedt Statistic

1.86

-1.09

-0.94

-0.34

2.96**

0.65

-1.54

AR30I730M-40

IgAR30I73I*

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*&4' Y/.T G.F. - Superfund Records Collections | US ... 00 ^,^0^ J.65H "I..3A M.II2. 2.93.6 1.^?-0.9* l.Oto I'M; .63 J.3I AV/X.45385 • I5J.og5r.O'HS".O 4017. v"3 '"^0... I'DIS"

&4' Y/.T G.F. - Superfund Records Collections | US ... 00 ^,^0^ J.65H "I..3A M.II2. 2.93.6 1.^?-0.9 l.Oto I'M; .63 J.3I AV/X.45385 • I5J.og5r.O'HS".O 4017. v"3 '"^0... I'DIS"