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2007 Carbohydrates U 0500 Addition of Difluoromethyl Radicals to Glycals: A New Route to α-CF2-D-Glyco- sides. — Most of the products are obtained as single diastereomers. The presence of the ester group allows further functionalization [cf. (VIII)]. — (MORENO, B.; QUEHEN, C.; ROSE-HELENE, M.; LECLERC*, E.; QUIRION, J.-C.; Org. Lett. 9 (2007) 13, 2477-2480; Lab. Heterochim. Org., Inst. Rech. Chim. Org. Fine, Univ. Rouen, F-76821 Mont-Saint-Aignan, Fr.; Eng.) — R. Steudel 42- 183

Addition of Difluoromethyl Radicals to Glycals: A New Route to α-CF2-D-Glycosides

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2007

CarbohydratesU 0500 Addition of Difluoromethyl Radicals to Glycals: A New Route to α-CF2-D-Glyco-

sides. — Most of the products are obtained as single diastereomers. The presence of the ester group allows further functionalization [cf. (VIII)]. — (MORENO, B.; QUEHEN, C.; ROSE-HELENE, M.; LECLERC*, E.; QUIRION, J.-C.; Org. Lett. 9 (2007) 13, 2477-2480; Lab. Heterochim. Org., Inst. Rech. Chim. Org. Fine, Univ. Rouen, F-76821 Mont-Saint-Aignan, Fr.; Eng.) — R. Steudel

42- 183