Aiga Kala ELLE-ADMS Odour 20120202

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    Odour modelling using

    ADMS software

    Presentation by

    Dr David Carruthers

    Cambridge Environmental Research Consultants(CERC)

    Aiga Kla

    Estonian, Latvian & Lithuanian Environment

    (ELLE)

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    Overview

    Odour units

    Odour modelling and legal requirements

    Practical examples

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    Odour units

    Two types of odour units available inADMS:

    ouA value in ou is aratio. The ou strength is the number oftimes the mixture must be diluted (at standard temperature

    and pressure) to reach the detection limit

    ouE(European odour unit)A value in ouEis amassmeasurement. One ouEis the mass of pollutant that, when

    evaporated into 1m3 of odourless gas (at standard conditions)

    results in a mixture with concentration equal to the detection

    threshold for that pollutant

    European odour units (ouE) are morecommonly used and olfactometry

    measurements give odour concentrations in

    ouE/m3

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    Odour units (II)

    The odour concentration of a compound can beestimated by:

    D = C/T

    Where:

    D is the odour concentration of a compound

    (dimensionless, odour units ouEm -3)

    C is the chemical concentration of a

    compound in mg m -3

    Ta is the published odour threshold value of a

    compound in mg m -3

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    How strong is an odour

    unit?

    According to generalised assumptions based

    upon laboratory-based experiments on

    perceived intensity: 1 ouE

    m -3 is the point of detection

    5 ouEm -3 is a faint odour

    10 ouEm -3 is a distinct odour

    The recognition threshold is often about

    three odour units

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    Lithuania User Group Meeting 2012

    Modelling odours

    Many types of installation have the potential for being the cause of

    an odour nuisance problem

    Waste water

    treatment works

    Landfill sitesLivestock farming

    Paint spray

    workshops

    Fuel storage

    ADMS-Urban and ADMS-Roads 3.1

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    Lithuania User Group Meeting 2012

    Modelling odours

    ouE - The massof pollutant,

    which when evaporated into

    1m3of odourless gas at

    standard conditions (STP)results in a mixture with

    concentration equal to the

    detection threshold for that

    pollutant

    Detection threshold - the point at which an increasing concentration of

    an odour sample becomes strong enough to produce a first sensation

    of odour in 50% of people to whom the sample is presented

    ADMS-Urban and ADMS-Roads 3.1

    Odours

    appears as

    new option in

    Setup screen

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    Lithuania User Group Meeting 2012

    Modelling odours

    Offensiveness

    category

    Indicative criterion(below which there is no

    reasonable cause for

    annoyance)

    Examples of installation types

    High 1.5 ouE/m3 Waste water treatment, brickworks, oil

    refining

    Medium 3 ouE/m3 Sugar beet processing, intensive

    livestock rearing

    Low 6 ouE/m3 Brewery, chocolate manufacture

    Horizontal Guidance for Odour Management (H4)(Environment

    Agency, April 2011): Classifies relative offensiveness of odours arising from different

    types of process as High, Medium or Low

    Odour exposure criteria expressed in terms of 98thpercentile of

    hourly mean (equivalent to 175 exceedences per year)

    ADMS-Urban and ADMS-Roads 3.1

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    Lithuania User Group Meeting 2012

    Modelling odours

    Odours are not

    included in the

    default pollutants list,

    so must be added to

    the palette of

    pollutants

    ADMS-Urban and ADMS-Roads 3.1

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    Lithuania User Group Meeting 2012

    Modelling odours

    This will produceoutput for direct

    comparison with

    the indicative

    odour exposure

    criteria.

    The .gltoutput file contains thelong-term average

    odour concentrations and percentiles of hourly

    averageodour concentrations for all grid points.

    ADMS-Urban and ADMS-Roads 3.1

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    Lithuania User Group Meeting 2012

    Modelling odours

    Example- Odour release from a group of 5 vents:

    Olfactometry 125 ouE/m3(STP) from each vent

    Source characteristics:

    Vent height: 1.75 m

    Vent diameter: 1 m

    Exit flow rate: 2 m3/s

    Temperature: 15 C

    Emission rate: 2 m3/s x 125 ouE/m3

    = 250 ouE/s

    ADMS-Urban and ADMS-Roads 3.1

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    Lithuania User Group Meeting 2012

    Modelling odours

    Offensiveness category Indicative criterion

    High 1.5 ouE/m3

    Medium 3 ouE/m3

    Low 6 ouE/m3

    Contour Plotter used to plot

    98thpercentile of hourlyaverage odour concentrations

    Comparing predicted odour

    concentrations to indicative

    odour exposure criteria:

    No area of exceedence

    for Low or Medium

    offensiveness categories

    Small area of

    exceedence for High

    offensiveness category

    ADMS-Urban and ADMS-Roads 3.1

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    Legal requirements in Latvia

    Cabinet of Ministers Regulations No 626adopted on July 27, 2004 Regulation on

    the methods for determination of odour, as

    well order of limitation of odours from

    polluting activities

    Odour target

    value, ouEm -3

    Percentile of

    hourly averages

    Source of odour

    5 98.08th Not specified

    8 98.08th Agricultural

    activities

    10 98.08th Permitted industrial

    activities

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    Examples emission rate

    Emission factors from literature

    pig farms (Environmental Protection Agency of

    Ireland - Odour Impacts and Odour Emission

    Control Measures for Intensive Agriculture, 2001)

    Measurements the laboratory of LatvianEnvironment, Geology and Meteorology

    Centre determine odour by means of

    olfactometry

    uploading oil products

    pig farms

    Calculated results based on odour threshold

    values

    uploading liquefied gas (methyl mercaptan)

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    Measurements

    Analytical techniques (chemical analysis)

    Sensory methods (ie relating to the human

    response) provides information on the

    likely population response

    Selection of a particular method will dependupon:

    the purpose of the measurement

    the frequency (once off or frequent/continuous) etc

    the location at which the odour is sampled

    whether a point source or surface/area source

    the complexity of the emission - a single compound

    or a complex mixture.

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    Case study fish processing

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    Case study fish processing (II)

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    Case study

    fish processing (III)

    Main production parameters:

    Fish for drying - 7260 t/a

    Fish for cooking 2324 t/a

    Source characteristics:

    Height: 23 and 11 m

    Diameter: 400 and 500 mm

    Exit flow rate:1200-1800 m3/h and 800

    m3/h

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    Emission factors for fish

    processing

    Activity

    Hydrogen

    Sulfide (H2S),

    kg/t

    Trimethylamine((CH3)3N), kg/t

    Fish cooking:

    Fresh fish 0.005 0.15

    Stale fish 0.1 1.75

    Fish drying 0.05 n/d

    AP 42, Fifth Edition, Volume I

    Chapter 9: Food and Agricultural Industries

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    Odour emissions

    Odour tresholds:

    For Hydrogen Sulfide 0.003 ppm(0.0042 mg/m3)

    For Trimethylamine 0.48 ppm (1.16

    mg/m3)

    Activity

    Odour

    concentration,

    (ouE/m3)

    Odour

    emission,

    (ouE/s)

    Fish drying 4690.48 1547.86Fish cooking,

    H2S4773.81 1050.24

    Fish cooking,

    (CH3)3N

    310.73 68.36

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    Legend

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    Odour assessment:

    Oil product terminal,

    Emission rate based on measurement results and information aboutodour treshold values

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    Odour assessment:

    pig farm;

    emission rate

    calculated from EF

    (odour units peranimal)