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    Mathematical Modeling of a Contact Lens and Tear Layer at Equilibrium

    by

    Bhagya U.A. Athukorallage, B.Sc.

    A Thesis

    in

    Mathematics

    Submitted to the Graduate Facultyof Texas Tech University in

    Partial Fulfillment of

    the Requirements for the Degree of

    Master of Science

    Approved

    Dr. Ram IyerChair of Committee

    Dr. Magdalena Toda

    Dr. Eugenio Aulisa

    Peggy Gordon Miller

    Dean of the Graduate School

    August, 2012

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    ACKNOWLEDGMENTS

    It is with great pleasure that I express my gratitude and appreciation to myadvisor Dr. Ram Iyer for his encouragement, guidance and patience throughout

    this endeavor. Furthermore, his guidance helped enormously for me to succeed as a

    graduate student. My sincere gratitude goes to Dr. Magdalena Toda and Dr. Eugenio

    Aulisa for their support, suggestions and encouragement. They were always willing

    to help me in every way.

    I am grateful to Dr. Pantaleon Perera who guided and helped me in every

    possible way throughout my academic career. Moreover, I take this opportunity to

    express my gratitude to all my teachers during my student life.

    I would like to thank all my Texas Tech University friends and Lubbock Sri

    Lankan community for their support provided from the day I arrived here. My special

    thanks go to Janitha Gunatilake and Josh Engwer for their suggestions and help in

    writing the thesis.

    Last but not least, I would like to thank my loving parents, sisters and wife for

    being with me in every moment in my life.

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    TABLE OF CONTENTS

    ACKNOWLEDGMENTS . . . . . . . . . . . . . . . . . . . . . . . . . . . iiABSTRACT . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . v

    LIST OF TABLES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . vi

    LIST OF FIGURES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . vii

    1. INTRODUCTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1

    2. CAPILLARY SURFACES . . . . . . . . . . . . . . . . . . . . . . . . . 5

    2.1 Preliminaries . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5

    2.1.1 Surface tension . . . . . . . . . . . . . . . . . . . . . . . . 5

    2.1.2 Youngs equation . . . . . . . . . . . . . . . . . . . . . . . 6

    2.1.3 Contact angle hysteresis . . . . . . . . . . . . . . . . . . . 7

    2.1.4 Young-Laplace Equation . . . . . . . . . . . . . . . . . . . 9

    2.1.5 Curvature of a curve and a surface . . . . . . . . . . . . . 10

    2.2 Profile of a capillary surface at a vertical flat wall . . . . . . . 13

    2.2.1 Modeling the capillary surface at a vertical wall . . . . . . 13

    2.2.2 Boundary conditions . . . . . . . . . . . . . . . . . . . . . 15

    2.2.3 Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16

    2.3 Forces acting on a contact lens . . . . . . . . . . . . . . . . . . 19

    2.3.1 Static equilibrium of a contact lens . . . . . . . . . . . . . 203. TEAR MENISCUS AROUND A CONTACT LENS . . . . . . . . . . . 27

    3.1 Modeling the tear meniscus around a contact lens . . . . . . . 27

    3.2 Two-dimensional analysis of tear meniscus . . . . . . . . . . . 31

    3.2.1 Necessary conditions for the equilibrium of the contact lens 34

    3.2.2 Numerical results . . . . . . . . . . . . . . . . . . . . . . . 36

    3.3 Two-dimensional analysis of a tear meniscus when the disk is

    supported by the lower eyelid . . . . . . . . . . . . . . . . . . . 38

    3.3.1 Numerical results . . . . . . . . . . . . . . . . . . . . . . . 40

    3.4 Two-dimensional analysis of a tear meniscus with cylindrical

    shell type contact lens . . . . . . . . . . . . . . . . . . . . . . . 42

    3.4.1 Numerical results . . . . . . . . . . . . . . . . . . . . . . . 46

    3.4.2 Lower tear meniscus . . . . . . . . . . . . . . . . . . . . . 48

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    3.4.2.1 Numerical results . . . . . . . . . . . . . . . . . . . . 48

    3.5 Three-dimensional analysis of a tear meniscus with a spherical

    cap type contact lens . . . . . . . . . . . . . . . . . . . . . . . 503.5.1 Numerical Results . . . . . . . . . . . . . . . . . . . . . . . 55

    3.6 Comparison with observations . . . . . . . . . . . . . . . . . . 58

    4. CONCLUSIONS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61

    BIBLIOGRAPHY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 62

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    ABSTRACT

    In this thesis, we study the capillary surface at a vertical wall, and a tear meniscusaround a symmetric, spherical cap lens. We propose a mathematical model of a

    tear meniscus around a contact lens that is at static equilibrium using a calculus of

    variations approach. As the lens is in static equilibrium all the forces and moments

    sum to zero. The forces acting on the lens are its weight, force due to hydrostatic

    and atmospheric pressures and surface tension on the periphery of the lens due to

    the tear meniscus. We consider the two cases of presence or absence of a force due to

    the lower eyelid. The fixed parameters in the model are weight of the lens, coefficient

    of surface tension, magnitude of gravitational acceleration, density of the tear liquid

    and physical parameters of the lens such as the diameter and base curve radius. The

    adjustable parameters in the model are contact angles of the tear meniscus with

    the cornea and contact lens respectively and the position of the lens on the cornea.

    Numerical experiments suggest that there exist range of values for the adjustable

    parameters that lead to physically reasonable solutions, for lens position; extent of

    overlap of the lower lid on the lens; pressure due to the lid on the lens; and contact

    angles between the tear meniscus and the cornea and contact lens respectively.

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    LIST OF FIGURES

    1.1 Capillary surface at a vertical wall . . . . . . . . . . . . . . . . . . . . 12.1 Attractive interaction of a molecule at the surface and in the middle

    of a liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5

    2.2 Equilibrium contact angle of a liquid drop on a solid surface . . . . . 6

    2.3 Interfacial tensions at a contact point of a liquid drop . . . . . . . . . 7

    2.4 Advancing and receding contact angles of a liquid drop . . . . . . . . 7

    2.5 Sectional view of a liquid column in a capillary tube . . . . . . . . . . 8

    2.6 Liquid-gas interface Swith principal radii ofR1 andR2 . . . . . . . . 9

    2.7 Normal curvaturee of a surface in R3 . . . . . . . . . . . . . . . . . . 11

    2.8 Sectional view of a capillary surface at a vertical wall . . . . . . . . . 14

    2.9 The directions of the forces on a section of a capillary surface and

    meniscus . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15

    2.10 Variation of the meniscus heightz(x) from the vertical wall . . . . . . 17

    2.11 Image of contact lens resting on the inside of the lower eyelid . . . . . 20

    2.12 Case 1: Tear film over a disk . . . . . . . . . . . . . . . . . . . . . . . 21

    2.13 Case 2: Contact angle between the tear meniscus and the contact

    lens is less than 90 . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22

    2.14 Case 3: Contact angle between the tear meniscus and the contactlens is equal to 90 . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23

    2.15 Case 4: Contact angle between the tear meniscus and the contact

    lens is greater than 90 . . . . . . . . . . . . . . . . . . . . . . . . . . 25

    2.16 Case 5: Contact angle between the tear meniscus and the contact

    lens is greater than 90 . . . . . . . . . . . . . . . . . . . . . . . . . . 26

    3.1 Contact lens on a flat cornea . . . . . . . . . . . . . . . . . . . . . . . 27

    3.2 Upper and lower tear menisci on a rectangular contact lens . . . . . . 31

    3.3 Upper tear meniscus on a rectangular contact lens . . . . . . . . . . . 33

    3.4 Forces on a section of a rectangular contact lens . . . . . . . . . . . . 35

    3.5 Force components in the zdirection . . . . . . . . . . . . . . . . . . . 37

    3.6 Images of contact lens resting on the inside of the lower eyelid . . . . 38

    3.7 Forces on the lens due to the upper tear meniscus and the lower eyelid 39

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    3.8 Variation ofL1, a, b and the reaction forces FL and FR with respect

    to the distance x1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41

    3.9 A cylindrical shell type lens . . . . . . . . . . . . . . . . . . . . . . . 423.10 Forces on the cylindrical shell type lens due to the upper tear meniscus

    and the lower eyelid . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44

    3.11 Variation of FL, FR and the moment difference with respect to the

    distancex1. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47

    3.12 Variation of lower contact angle values withx1 and Variation of the

    force components in the x direction . . . . . . . . . . . . . . . . . . . 49

    3.13 Spherical cap type contact lens . . . . . . . . . . . . . . . . . . . . . 50

    3.14 Forces acting on the spherical cap . . . . . . . . . . . . . . . . . . . . 52

    3.15 Variation of the force due to fluid pressureFR, surface tensionFTand

    the lid force FL in the x,y andzdirections . . . . . . . . . . . . . . 56

    3.16 Variation ofL for different corneal contact angles . . . . . . . . . . . 57

    3.17 Contact angles between the tear meniscus with the flat vertical wall

    and corneal surface . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59

    3.18 Meniscus profiles z(x) and their slopes z(x) for the contact angles

    E= 33 and EC= 14.5 . . . . . . . . . . . . . . . . . . . . . . . . 60

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    energy is [3]

    J =dA pdV. (1.2)In equation (1.2),is the surface energy per unit area and p is the pressure difference

    between the liquid-gas interface. dAanddVare the surface area and volume elements

    of the liquid respectively. The potential energy functional is

    J =

    J =

    dA

    pdV, (1.3)

    where is the region occupied by the liquid and is the boundary of . Both

    methods result in the same equation for the capillary surface at a vertical wall asshown in section 2.2.

    The potential energy functional approach is used to model the tear meniscus

    around a symmetric, spherical cap lens in Section 3.1. We analyze the static equi-

    librium of the lens by considering all the forces and moments that act on the lens.

    Mainly, there are four types of forces. They are lens weight, forces due to hydrostatic

    and atmospheric pressure, surface tension forces on the periphery of the lens due to

    the tear meniscus and the force due to the lower eyelid. Lens weight acts through its

    center of mass, parallel to the direction of gravitational acceleration g. Forces result

    from hydrostatic pressure and atmospheric pressure acting perpendicular to the pos-

    terior and anterior sides of the lens respectively. Thus, due to the spherical shape of

    the contact lens, all these pressure forces and their resultant force have the direction

    of the outward normal vector to the sphere. Furthermore, surface tension forces act

    on the lens at the contact line and directed tangentially to the tear meniscus. Since

    tear film is at equilibrium, its velocity is u and, hence, viscous stress 1 are zero.

    Therefore, in our model, we neglect the force on the posterior side of the lens due to

    the viscous stress.

    We use the lens weight, coefficient of surface tension, density of the tear liquid,

    1=

    u+ uT2

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    magnitude of gravitational acceleration, lens diameter and its base curve radius as

    the fixed parameters. The adjustable parameters in our model are the position of the

    lens on the cornea, contact angle of the tear meniscus with the cornea and contactlens respectively. The contact angle hysteresis phenomenon (refer to Section 2.1.3)

    explains that these contact angles may have a range of values. Our mathematical

    model for the tear meniscus is valid for rigid gas permeable RGP lenses as well as

    for the soft contact lenses. However, numerical simulations are done only for the

    RGP type lenses. Our numerical calculations show that the pressure change due

    to gravity significantly affect the equilibrium equations. In particular, force resultant

    due to hydrostatic pressure is greater than the surface tension force in the zdirection.

    In addition to ignoring the change in hydrostatic pressure due to gravity, capil-

    lary effect is also ignored in [1] and in [18]. These forces are significant and cannot

    be ignored as shown in this thesis. The net force due to hydrostatic pressure has the

    largest magnitude amongst all the forces acting on a lens and the capillary effect re-

    duces the magnitude of the lid (or other) forces needed to maintain static equilibrium.

    In the literature [1], the contact lens and tear meniscus are considered to be in

    a quasi-static equilibrium state. The author assumes the shape of the contact lens

    to be a cylindrical shell type with a unit width. Reaction force due to the posteriortear film, upper and lower contact angles are calculated by considering the quasi-

    static equilibrium of the lens in two-dimensions. However, calculation of the reaction

    force due to the posterior tear film completely neglects hydrostatic pressure variation

    due to gravity. But, our numerical simulations show that the force due to hydrostatic

    pressure significantly affects the static equilibrium of the lens. The literature [2] mod-

    els the contact lens and the cornea as flat surfaces with infinite width. Lubrication

    approximation theory is used to model quasi-steady motion of the tear film under

    the contact lens and away from the lens. In the analysis of the the latter tear film,

    its attachment to the cornea is incorrectly modeled. As a result, gravitational force

    acting on the fluid is neglected in the analysis. In [18], the contact lens considered is

    a porous, planar, circular disk, and the authors model the dynamics of the contact

    lens during blinking. They use a version of Darcys law to model constitutive relation

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    of tear, in which gravity is neglected. For the no blink or quasi-static blink case, this

    constitutive relation yields a constant pressure distribution in the tear layer, which is

    unphysical.

    In our analysis, we consider the static equilibrium of a spherical lens in three-

    dimensions by introducing an additional force that results from the lower eyelid.

    Effect of hydrostatic pressure includes in the equilibrium equations of the lens. We

    assume the pressure variation of the tear film is linear with the distance x and also

    assume linear variations of the contact angles of the tear meniscus with the lens.

    Ranges of values for the adjustable parameters are obtained through the numerical

    simulations for the static equilibrium of the lens.

    Chapter 2 consists of the basic theories involving a study of capillary surfaces and

    model the capillary surface at a vertical wall by applying the Young-Laplace equation

    and a calculus of variations approach. This chapter also contains an analysis for the

    stability of a unit width plate that the axis of symmetry is parallel to the direction

    of gravitational acceleration g. In chapter 3, we mathematically model the tear

    meniscus around a contact lens. We initially consider the static equilibrium of a flat

    plate and cylindrical shell that yield to gain a better understanding of the stability of

    a spherical cap type lens. Finally, for the equilibrium of the spherical cap type lens,numerical simulations are carried out to obtain the feasible values for the adjustable

    parameters. Simulation results suggest that there exist a range of values for the

    adjustable parameters that lead to the physically reasonable solutions.

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    CHAPTER 2

    CAPILLARY SURFACES

    In this chapter, the basic definitions and theorems that we used to analyze menis-

    cus profiles at a flat vertical wall and around a disk are described. In particular, we

    derive an equation for a meniscus profile at a vertical wall using the Laplace theorem.

    2.1 Preliminaries

    2.1.1 Surface tension

    Surface tension of a liquid is defined as the energy that must be required to

    increase the surface by one unit[3].

    Figure 2.1: Attractive interaction of a molecule at the surface and in the middle of aliquid.

    The unit of surface tension is either J/m2 or N/m. Surface tension of liquids

    vary from 0.02 to 0.08N/mand, therefore, they are usually expressed inmN/m. The

    following table contains surface tension of a few liquids at different temperatures [9].

    Table 2.1: Surface tension of some liquids at different temperatures [9].

    Liquid Temperature (C) (mNm1)

    Water 20 73100 58

    Tear - 45

    Mercury 20 485Acetone 20 24Water/oil 20 50

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    2.1.2 Youngs equation

    Consider a static equilibrium of a liquid drop that is deposited on an ideal1 solid

    surface. LetO be a point on the contact line that forms in the solid, liquid and airinterface. Let Mbe a plane perpendicular to the solid surface and parallel to the

    Y Zplane through the point O. Then, the liquid drop forms a profile curve OC on

    the plane Mas shown in Figure 2.2. Line OB represents a tangent line to the curve

    OC at the point O. The AOB that forms at the point O through the liquid is

    denoted byE. This angle is referred to as an equilibrium contact angleand its value

    is determined by the Youngs equation.

    Figure 2.2: Equilibrium contact angle of a liquid drop on a solid surface. Mis a planeparallel to the Y Zplane. AOB is the equilibrium contact angle E.

    Figure 2.3 depicts the directions of interfacial tensions between the solid-vapor,

    solid-liquid and liquid-vapor interfaces on the plane M. Those interfacial tensions are

    assumed to have the values ofSG , SL and LG (per unit length) respectively.

    The equilibrium of forces in the Y direction results in the following equation

    (2.1) and the value ofEis found from the equation(2.2).

    LGcos E+SL = SG , (2.1)

    LGcos E = SG SL,E = cos

    1

    SG SLLG

    . (2.2)

    1An ideal solid surface is one that is flat, rigid, perfectly smooth, inert, non-porous and chemicallyhomogeneous with zero contact angle hysteresis [10].

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    Figure 2.3: Interfacial tensions at a contact point of a liquid drop.

    2.1.3 Contact angle hysteresis

    The equilibrium contact angle Ethat is defined by the Youngs formula is not

    unique for a non-ideal surface.

    Figure 2.4: Advancing and receding contact angles of a liquid drop.

    Consider a small liquid drop on a solid surface with a contact angle of (Con-

    figuration of the contact angle is similar to that used in the previous analysis).

    Experiments show that if liquid is carefully removed from a droplet with a syringe,

    volume and contact angle of droplet decrease without changing its initial contact area.

    Continuing this process results in a receding of the contact area at a contact angle

    ofR. Similarly, if liquid is added to the droplet, the volume and contact angle of

    the droplet will increase, but retain the same contact area. Further increasing of its

    volume results in a motion of the contact area at contact angle of A. These two

    limiting values, R and A, are referred to as receding and advancing angles. The

    difference betweenA andR is termed ascontact angle hysteresis.

    The following example indicates the contact angle hysteresis phenomenon that

    occurs in a capillary tube.

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    Consider a liquid column trapped in a capillary tube [3] that is parallel to the Z

    direction as shown in the figure 2.5. Magnitude of the gravitational acceleration is

    denoted by g and it is directed to theZ direction. The liquid column has heighth and radius R with liquid density of . Its upper and lower lines of contact2 are

    denoted byC1 andC2 respectively. On the lines C1 andC2, the contact angles are 1

    and2 and it is assumed that each contact angle is constant along the corresponding

    contact line.

    Figure 2.5: Sectional view of a liquid column in a capillary tube. 1 and 2 denote

    the upper and lower contact angles respectively. Gravity g acts in theZdirection.

    Under this configuration, surface tension acts tangentially to the upper and

    lower capillary surfaces of the liquid column. Let A and B be arbitrary points on

    the contact lines C1 and C2 respectively. Thus at the point A, surface tension force

    acts tangentially to the upper liquid meniscus. Hence, its vertical component is

    cos 1 inZdirection. Similarly, at the point B, there is a force component cos 2,

    that acts in theZ direction. Therefore, the total forces in Z andZ directionsdue to the upper and lower contact lines are 2Rcos 1and 2Rcos 2respectively.

    Moreover, the weight of the liquid column, R2hg acts inZdirection.

    Thus, the following equations can be derived for static equilibrium of the liquid

    2In three dimensions, these lines are circles with radius R.

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    column in the Zdirection:

    2R(cos 1 cos 2) R2

    hg = 0,2(cos 1 cos 2) = Rgh. (2.3)

    Thus, at the equilibrium of the liquid column, the upper and the lower contact

    angles satisfy the condition,

    R 1 < 2 A. (2.4)

    2.1.4 Young-Laplace Equation

    Consider a liquid-gas interface (capillary surface3) that is in equilibrium. Supposethere is a pressure difference across the liquid-gas interface. Then, the interface is

    curved due to that pressure difference. The aforementioned pressure difference is

    related to curvature and surface tension of the interface, and this relationship is given

    by the Young-Laplace equation.

    Figure 2.6: Liquid-gas interfaceSwith principal radii ofR1 andR2.

    3The term capillary surface is used to describe a free interface that occurs when one of thematerials is a liquid and the other is a liquid or a gas [11].

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    Young-Laplace equation:

    Let Sbe a fluid interface as described above with surface tension and pressure

    difference across a point A on the surface,p. Then,

    p =

    1

    R1+

    1

    R2

    =(1+2) (2.5)

    whereR1 andR2 represent the two principal radii of curvature at the point A. Note

    that we define the pressure difference p to be pliquid pgas.

    One of the important implications of the Young-Laplace equation is that one can

    use it with appropriate boundary conditions to calculate the geometry of a capillary

    surface. In the next section, the principal radii of curvature of a surface are discussed

    in detail.

    2.1.5 Curvature of a curve and a surface

    Curvature of a curve in R3

    LetCbe a curve, parametrized byr(t) in R3 such thatr(t) = 0 fort (a, b) R.We define its arc length parameter (s) by the equation,

    s(t) =

    t

    a

    r()d. (2.6)

    Thus, unit tangent vector (T) of the curve C is defined in terms of the arc length

    parameters:

    T : =dr

    ds, (2.7)

    which leads to

    T= dr

    dtdtds

    = r(t)r(t) . (2.8)

    Note thatT = 1.Therefore, we can show that T dT

    ds= 0. Hence,

    dT

    ds is orthogonal to T.

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    The curvature (s), of a curve Cis defined by [12],

    dT

    ds =(s)n(s). (2.9)

    In the above equation, n(s) is the principal unit normalto the curve C. The radius

    of curvature R is the reciprocal of(s). The plane spanned by Tand nis called the

    osculating plane.

    Furthermore, may be expressed in terms of the original parameter t as given in the

    equation:

    =r(t) r(t)

    r(t)

    3

    . (2.10)

    Curvature of a surface in R3

    LetSbe a curved surface in three dimensions and Nbe the unit surface normal

    through a pointAonS. Consider a tangent plane,TASthrough the pointA. We con-

    sider all the planes perpendicular toTASthrough the surface normal N. Intersections

    of these planes with the surface Sresult in a family of curves,{Ci}.

    Figure 2.7: Normal curvaturee of a surface in R3. 1 and 2 denote the principal

    curvatures at the point A. N represents the surface normal at A.

    Note that the each tangent direction corresponds to one of the {Ci} at the pointA. The curvature of each such curve corresponding to the direction u in the tangent

    plane is called the normal curvature, n(u) in the direction u. The value of the

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    normal curvature is

    n= n N, (2.11)and nis defined by the equation (2.9).

    The maximum and minimum values of the normal curvature are called the principal

    curvaturesand are denoted by 1 and 2 respectively. The corresponding directions

    of1 and 2 are the principal directions e1 and e2. Furthermore, reciprocals of the

    1 and2 are the principal radii of curvaturesand denoted byR1 and R2.

    Subsequently, the product and the average of 1 and 2 are defined as the Gauss

    curvature (K) and the Mean curvature (H) of a surface. Thus,

    H = 1+2

    2 ,

    K = 12. (2.12)

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    2.2 Profile of a capillary surface at a vertical flat wall

    2.2.1 Modeling the capillary surface at a vertical wall

    The following analysis of the capillary surface at a vertical wall may be found in[3]. We consider a liquid in static equilibrium that is uniform in the y direction. The

    Xaxis of the coordinate system is configured so that the meniscus has zero curvature

    at z= 0 as x . For simplicity, we have placed the Zaxis on the vertical wall.LetMbe a plane parallel to the X Zplane andA be a point on the capillary surface

    as depicted in the figure 2.8. Outer pressure and internal pressure at the point A

    are denoted by po and piA. We assume that the point A has coordinates (x, z(x))

    with respect to the given coordinate system. T and n represent the tangent plane

    and the normal at the point A respectively. Let M2 be a plane through the normal

    n perpendicular to both M and T. Radii of curvature for the meniscus are defined

    using the lines of intersection that result from intersection of the planes M and M2

    through the meniscus. These lines of intersections are denoted by C1 and C2. In

    particular, C2 is a straight line and, therefore, its curvature is zero. Note that the

    curve C1 coincides with the capillary surface that is given by the equation z=z(x).

    We represent the the curve C1 as a parametrization,

    r(x) = (x, y0, z(x)), (2.13)

    wherey0 is a constant.

    By using equations (2.10) and (2.13), we determine the curvature of the curve

    C1. Thus,

    r(x) = (1, 0, z(x)),

    r(x) = (0, 0, z(x)),

    C1 = z(x)

    [1 +z(x)2]3

    2

    . (2.14)

    We apply the Young-Laplace equation to the point A to determine the geometry

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    Figure 2.8: Sectional view of a capillary surface at a vertical wall. Gravity g acts intheZdirection.

    of the capillary surface (meniscus profile), which results in the following equation,

    piA po =

    1

    R1+

    1

    R2

    , (2.15)

    = z(x)

    (1 +z(x)2)3

    2

    . (2.16)

    Curvature of the meniscus at infinity is zero as mentioned above. Then, the Young-Laplace equation implies that the internal pressure is equal to the outer pressure (po)

    at a point at infinity. Thus, the liquid on the Xaxis has a pressure po. We derive

    an equation for hydrostatic pressure at point B (piB) that has the coordinates (x, 0).

    Then,

    piA+gz(x) =piB =po. (2.17)

    Use equations (2.16) and (2.17) to determine the equation for the meniscus profile,

    gz(x) =

    z(x)

    [1 +z(x)2] 32 . (2.18)

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    angle E.

    z =

    2(1 sin )g ,

    z|x=0 =

    2(1 sin E)g

    . (2.21)

    Furthermore, the boundary condition for z|x=0 is obtained from the slope of thetangent line that is drawn to the meniscus at x= 0,

    z|x=0 = cot E. (2.22)

    2.2.3 Results

    In this section, we numerically solve the meniscus profile equation (2.18) with

    the boundary conditions that are derived in equations (2.21) and (2.22).

    Consequently, we have the following initial value problem:

    gz(x) = z(x)

    [1 +z(x)2]3

    2

    , (2.23)

    with the initial conditions

    z(0) =

    2(1 sin E)

    g , z(0) = cot E. (2.24)

    We obtain a corresponding system of first order differential equations by introducing

    new variables,

    y1 = z, y2= z.

    Which leads to

    y1 = y2

    y2 = g

    y1(1 +y

    22)

    3

    2 , (2.25)

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    with

    y1(0) =2(1 sin E)g , y2(0) = cot E. (2.26)

    The system of equations (2.25) are solved using the fourth-order Runge-Kutta

    method. Parameter values that use for the numerical calculations are given in the

    following table.

    Table 2.2: Fixed parameter values [17].

    Parameter Value CGS units

    1 g/cm3

    g 981 cm/s2

    45 dyn cmE 25 deg

    0 1 2 3 4 50

    0.05

    0.1

    0.15

    0.2

    0.25

    Distance from the vertical wall (cm)

    Meniscusheight(cm)

    Figure 2.10: Variation of the meniscus height z(x) from the vertical wall.

    Next, we model the same capillary surface that was depicted in Figure 2.8, byusing a calculus of variations approach. Consider the differential form of the potential

    energy [3] that is given by the equation,

    J =dA pdV . (2.27)

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    the vertical wall,

    z(x)

    [1 +z(x)2]3

    2

    =gz(x). (2.34)

    Thus, we obtain the same equation for the capillary surface using the Young-Laplace

    equationand using a calculus of variations approach.

    We use the latter method to derive an equation for the tear meniscus around a

    contact lens.

    2.3 Forces acting on a contact lens

    There are three types of forces that mainly act on a contact lens to hold it on

    the cornea. They are: weight of the lens, fluid forces, and force due to the eye lids.

    Lens weight: Lens weight has become a critical factor since the magnitude of thegravitational force is proportional to its weight. The following table contains the

    different types of materials and their specific gravities that are used to design

    contact lenses.

    Table 2.3: Contact lens materials and their specific gravities [8].

    Material Density (g/cm3) Material Density (g/cm3)

    PMMA 1.18 Polycon 1.15Boston RxD 1.27 Boston II 1.13Airlens 0.99 Equalens 1.19

    Fluid forces: When a contact lens is placed on the cornea, the tear meniscusformed on the peripheral of the lens and the thin layer of tear is present in

    between the cornea and posterior side of the lens. Due to the previously men-

    tioned peripheral tear meniscus, surface tension forces act on the lens at the

    contact line and directed tangentially to the meniscus surface. Moreover, pres-sure reaction forces act perpendicular to the posterior and anterior sides of the

    lens due to the build-up pressure in the tear and atmospheric pressure, patm.

    Force due to the eyelid: In this research, we analyze the static equilibrium of acontact lens. Hence, we consider only the force due to the lower eyelid (refer to

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    Figure 2.11).

    Figure 2.11: Image of contact lens resting on the inside of the lower eyelid.

    2.3.1 Static equilibrium of a contact lens

    In the literature [1], the contact lens and tear meniscus are considered to be in

    a quasi-static equilibrium state. The author assumes the shape of the contact lens

    to be a cylindrical shell type with a unit width. Reaction force due to the posterior

    tear film, upper and lower contact angles are calculated by considering the quasi-

    static equilibrium of the lens in two-dimensions. However, calculation of the reaction

    force due to the posterior tear film completely neglects hydrostatic pressure variationdue to gravity. But, our numerical simulations show that the force due to hydrostatic

    pressure significantly affects the static equilibrium of the lens. The literature [2] mod-

    els the contact lens and the cornea as flat surfaces with infinite width. Lubrication

    approximation theory is used to model quasi-steady motion of the tear film under

    the contact lens and away from the lens. In the analysis of the the latter tear film,

    its attachment to the cornea is incorrectly modeled. As a result, gravitational force

    acting on the fluid is neglected in the analysis. In [18], the contact lens considered is

    a porous, planar, circular disk, and the authors model the dynamics of the contact

    lens during blinking. They use a version of Darcys law to model constitutive relation

    of tear, in which gravity is neglected. For the no blink or quasi-static blink case, this

    constitutive relation yields a constant pressure distribution in the tear layer, which is

    unphysical.

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    point B implies piB < patm. Thus, piA > piB.

    However, hydrostatic pressure at the point B is given by,

    piB =piA+ghAB,

    which implies piB > piA and this contradicts the previous conclusion. Hence, there

    cannot be a film over the disk.

    Static equilibrium inZdirection of the disk is analyzed with respect to the value

    of contact angle . In particular, we consider 90.

    Case 2: Liquid meniscus with a contact angle

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    which simplifies to

    2cos +dhllg = (piCpo)d. (2.36)In equation (2.35), m and piC represent mass of the disk and pressure at the point

    C. Thus, stability inZdirection can be achieved only ifpiC > po and, hence, this

    condition is necessary for existence of a liquid film under the disk.

    However, according to the configuration of the X axis, meniscus has a zero

    curvature on it. From the Young-Laplace equation, fluid pressure on the Xaxis is

    equal to the outer pressure po. We derive a formula for hydrostatic pressure at point

    C:

    po = piC+tgh. (2.37)

    Equation (2.37) implies piC < po and, therefore, stability in the Zdirection is

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    Static equilibrium of forces on the disk in the Z direction results in an equa-

    tion similar to (2.36). Since = 90, the surface tension force component of the

    aforementioned equation becomes zero. We obtain,

    lhldg = (piCpo)d (2.38)

    where piCdenotes pressure at the point Cand is expressed in terms of hydrostatic

    pressure,

    piC=po+tgh. (2.39)

    piCachieves its maximum value at max{h} =hl, which leads topiC|max= po+tghl. (2.40)

    Substituting equation (2.40) into equation (2.38) yields

    lhldg = thldg,

    which turns out to be

    l = t. (2.41)

    The above equation (2.41) implies that ift l then liquid film exists in betweenthe disk and the surface.

    Case 4: Liquid meniscus with a contact angle >90.

    Consider the case in which contact angle >90. Configuration of the coordinate

    system is similar to that of the preceding case. Furthermore, the Z axis intersects

    the bottom edge of the disk at a point C, (0, h).

    Thus, we can formulate a static equilibrium equation in Zdirection:

    2cos( ) + (piCpo)dmg = 0 2cos( ) + (piCpo)d = mg, (2.42)

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    Figure 2.15: Case 4: Contact angle between the tear meniscus and the contact lensis greater than 90. Gravityg acts along the Zdirection.

    which simplifies to

    2cos( ) + (piCpo)d = dhllg. (2.43)

    We obtain a formula for piCusing hydrostatic pressure that turns out to be

    piC=po+tgh. (2.44)

    Combine equations (2.43) and (2.44) to formulate the following equation

    2cos( ) +tghd = dhllg, (2.45)

    which simplifies to

    2cos( ) = (lhl th)dg. (2.46)

    Equation (2.46) shows that stability in the Z direction may be possible for a lens

    made out of hydrophobic material. However, the literature [22] shows that lens ma-

    terials always have the hydrophilic property.

    Case 5: Liquid meniscus with a contact angle >90 and gravity g acts along the

    Xdirection.

    We consider a disk that has a contact angle > 90 in a vertical position as

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    depicted in the Figure 2.16. Since >90 around the lens, curvature of the meniscus

    is positive. Thus,

    pi(x)> po x x1.

    Hence, force due to hydrostatic pressure acts in the zdirection as well as the surface

    tension forces. Due to this reason, stability in the zdirection cannot be achieved with

    this configuration.

    Figure 2.16: Case 5: Contact angle between the tear meniscus and the contact lensis greater than 90. Gravity g acts along the Xdirection.

    Contact angle less than 90 with gravity g acting perpendicular to the axis of

    symmetry is considered in chapter 3.

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    CHAPTER 3

    TEAR MENISCUS AROUND A CONTACT LENS

    3.1 Modeling the tear meniscus around a contact lens

    In this endeavor, tear meniscus is considered that forms between the cornea

    and a contact lens. In the Cartesian coordinate system shown in Figure 3.1, the

    domains bounded by the contact lens and tear meniscus are 1 and 2 respectively.

    Furthermore, the contact line formed between the lens and the meniscus is denoted

    by12. Inner and outer profiles of a contact lens have the equations Fi(x, y) and

    Fo(x, y) respectively. Moreover, we introduce a rotational motion of the contact lens

    around the y axis by adding a linear function, z(x) = mx+ b. Let the pressure

    developed inside the tear meniscus be pi(x,y,z) and the profile of the tear meniscus

    bez= f(x, y). Finally, atmospheric (outer) pressure,patmis assumed to be a constant

    throughout the domains.

    Figure 3.1: Contact lens on a cornea. g acts along the X direction. Tear pressureand atmospheric pressure are pi and po respectively. Domain of the lens is 1 andthe domain of the tear meniscus is 2.

    We consider the differential form of the energy functional, Jthat is given by

    J =dA pdV, (3.1)

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    where is the surface energy per unit area of liquid, p is the pressure difference

    between inside and outside of medium, dA and dV are surface area and volume

    elements of a liquid respectively. Surface energy per unit area is taken to be a constantin a given domain. Consider the potential function which is defined by equation (3.1).

    Then total energy of the system is given by

    J =2

    dA 2

    p2(x,y,z)dVt 1

    p1(x,y,z)dVt 1

    cgxdVl, (3.2)

    where subscripts t and l refer to the quantities involving tear and lens. c is the

    density of the lens and g is the magnitude of gravitational acceleration. The term

    1 cgxdVl in equation (3.2) is the potential energy of the contact lens.Consider the Cauchy momentum equation [7]:

    Du

    Dt =g p+ , (3.3)

    where=

    u +uT2

    .

    In equation (3.3) and denote the density and the viscosity of the fluid. Further-

    more, u and are the velocity of the fluid and its viscous stress. g is the vector

    (g, 0, 0)T whereg represents the magnitude of the gravitational acceleration. is thegradiant operator in three-dimensions and DDt is the operator

    t + u .

    For a static Newtonian fluid, the above equation can be simplified to

    p(x,y,z) =g. (3.4)

    Solutions of equation (3.4) for p(x,y,z) yields a function p(x) that is dependent on

    x alone:

    p(x) =gx +pi0, (3.5)

    whereg is the gravitational constant and pi0 = p|x=0.

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    Thus, pressure difference between inside and outside of the medium is

    p = p(x)patm,= tgx+pi0 patm. (3.6)

    According to the given configuration of the coordinate system, any point on the

    capillary surface can be described by the parameterization,

    r(x, y) = (x,y,f(x, y)). (3.7)

    Then, surface area, A of a given domain is

    A =

    rxrydxdy,

    =

    1 +f2x + f

    2y dxdy. (3.8)

    Substitute equations (3.6) and (3.8) into equation (3.2) leads to

    J(f, m) = 2

    1 +f2x + f

    2y dxdy

    2

    [(tgx+p0 patm)f(x, y)]dxdy

    1

    (tgx+pi0 patm)(Fi(x, y) +mx+b)dxdy

    1

    cgx[Fo(x, y) Fi(x, y)]dxdy, (3.9)

    subject to the constraint

    f(x, y) =Fi(x, y) +mx+b (x, y) 12. (3.10)

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    Thus, the modified functional:

    J(f,m,) = 1

    (tgx+pi0 patm)(Fi+mx+b) +cgx(Fo Fi) dxdy(f(x, y) Fi(x, y)mx b)+

    2

    1 +f2x + f2y (tgx+pi0 patm)f(x, y)

    dxdy, (3.11)

    whererepresents the Lagrange multiplier.

    Equation (3.11) has the form

    J(f,m,) = 1

    L1(x,y,m)dxdy+ 2

    L2(x, y, f , f x, fy)dxdy. (3.12)

    For simplicity of analysis, we consider m and b to be fixed. These are the cases we

    consider in the rest of the thesis.

    Thus, associated Euler - Lagrange equation of equation (3.12) results,

    L2f

    x

    L2fx

    y

    L2fy

    = 0, (3.13)

    Simplifying the equations (3.13) yields,

    patm p0 tgx

    = (1 +fy

    2)fxx+ (1 +fx2)fyy 2fxfyfxy

    (1 +fx2 +fy

    2)3

    2

    . (3.14)

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    3.2 Two-dimensional analysis of tear meniscus

    We begin our study by considering the idealized case of a flat and rectangular

    contact lens of unit width, and a flat corneal wall. Consider equation (3.14) that isderived in the previous section for the meniscus profile. The meniscus profile depends

    on the x variable only.

    Let z= f(x). Then, equation (3.14) is reduced to

    patm pi(0) tgx

    = fxx

    (1 +fx2)

    3

    2

    (3.15)

    Figure 3.2: The upper and lower tear menisci on a section of a contact lens for the

    idealized case when the cornea and the contact lens are flat, and the contact lensis rectangular. The angle of tilt of the lens is . C1 and C2 denote the contactangle on the upper and lower cornea respectively. L1 and L2 represent the upperand the lower contact angle between the tear meniscus and the contact lens. FR isthe resultant force due to the fluid pressure on the posterior and anterior sides of thelens.

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    Upper meniscus profileEquation for the upper meniscus profile is,

    patm pi(0) tgx

    = fxx

    (1 +fx2)

    3

    2

    , (3.16)

    with the boundary conditions,f(0) = 0 andfx(0) = tan C1.

    Convert the equation (3.16) in to a first order system of ODE results,

    y

    1 = y2, (3.17)

    y

    2 = (1 +y22)

    3/2

    patm pi(0) gx

    . (3.18)

    Moreover, equation (3.18) has the form

    y

    2 = (1 + y22)

    3/2(k cx) (3.19)

    wherek =patm pi(0)

    and c =

    g

    ,

    which leads to

    dy2

    (1 +y22)3/2

    = (k cx)dx. (3.20)Use the substitutiony2= tan . Then equation (3.20) simplifies to

    cos d =

    (k cx)dx (3.21)

    and has the solution

    sin(tan1 y2) =kx cx2

    2 +C0. (3.22)

    The value ofC0 in equation (3.22) is determined using the boundary condition,y2(0) =fx(0) = tan C1.

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    Thus,

    y2(x) = tan

    sin1

    kx cx2

    2 + sin C1

    , (3.23)

    y1(x) =

    tan

    sin1

    kx cx

    2

    2 + sin C1

    dx (3.24)

    Recall that k = patm pi0

    , c =

    g

    and y2(x) = fx = tan where is the

    angle depicted in figure 3.3 and its value is given by

    = tan1 y2= sin1

    kx cx

    2

    2 + sin C1

    . (3.25)

    Figure 3.3: Upper tear meniscus profile, z = f(x), on the rectangular contact lens

    when the cornea and the contact lens are flat. Gravity g acts in the x direction.h1 is the angle between the tear meniscus and an axis parallel to the z axis, andh1=

    2 .

    Since [0, 2

    ], equation (3.25) implies

    0 kx cx2

    2 + sin C1 1

    0 cx2 2kx+ 2(1 sin C1) 2. (3.26)

    Consider the compound inequality in equation (3.26).

    1.

    cx2 2kx + 2(1 sin C1) 0 x 0 0

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    k2 2c(1 sin C1) 0

    k

    2g(1 sin C1)

    x 0, pi(0) patm

    2g(1 sin C1). (3.27)

    2.

    2 cx2 2kx + 2(1 sin C1)0 cx2 2kx 2sin C1= g(x) (3.28)

    Since c > 0, graph ofg(x) is convex. Thus, in order to satisfy equation

    (3.28), x [x1, x2].

    x1=k k2 + 2 sin C1

    c and x2 =

    k+

    k2 + 2 sin C1c

    . (3.29)

    Sincex1 < 0 andx2> 0 from [0, x2] we have the required inequality.

    3.2.1 Necessary conditions for the equilibrium of the contact lens

    We consider a contact lens that has a weight ofWand diameter ofd units. Let

    the resulted force due to hydrostatic pressure be denoted by FR, and it acts on theposterior side of the lens with an distance ofb units from the upper edge of the lens.

    Angle is the tilting angle of the lens with respect to the x axis. Upper and lower

    contact angles are denoted by L1 and L2 respectively. Moreover, we assume that

    distance from the posterior surface of the disk to the contact points of the upper and

    lower tear menisci have same value.

    For the equilibrium of the lens, we study the force balance in the x and zdirec-

    tions and the moment balance about the point A.

    Force balance equation in the x direction:(sin h1 sin h2) +FRsin = W. (3.30)

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    Figure 3.4: This figure illustrates the forces on a section of a contact lens for theidealized case when the cornea and the contact lens are flat, and the contact lens isrectangular. Surface tension is the force per unit length. The upper and the lowercontact angles are L1 and L2 respectively. Resultant force due to the fluid pressureis FR and it acts on the posterior side of the lens at distance a from the bottomsurface of the lens. Height of the lens is d.

    Thus,

    h2 = sin1sin h1+FRsin W . (3.31)

    Hence,L2 (refer to Figure 3.4) may be found using equation (3.31).

    Force balance equation in the zdirection:

    (cos h1+ cos h2) =FRcos (3.32)

    where

    FR = 1

    cos

    x2x1

    (pi(x) patm)dx

    = d

    2[2(pi(0)patm) +tg(2x1+d cos )]. (3.33)

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    Moment balance equation with respect to point B:

    FRa = x2x1

    (x2

    x)[pi(x)

    patm]

    cos2 dx

    a = d(pi(0)patm) + tgd3 (3x1+d cos )

    2(pi(0)patm) +tg(2x1+d cos ) (3.34)

    Moment balance equation with respect to point A:

    W d sin

    2 +cos L2d= FRb (3.35)

    3.2.2 Numerical results

    Values ofh1 are numerically calculated using equation (3.25) and the condition

    h1 = 2 . Corresponding h2 values are obtained using the equation (3.31) with

    the conditions that are derived in equations (3.27) and (3.29). Parameter values that

    are used in the numerical calculation are given in Table 3 .1.

    Table 3.1: Fixed parameter values for the idealized case when the cornea and the con-tact lens are flat, and the contact lens has a rectangular shape. The values of{,g,},{C1},{d, W}and{min, max}may be found in [1], [16], [17], and [22] respectively.

    Parameter Value CGS units Parameter Value CGS units 1 g/cm3 d 0.9 cmg 981 cm/s2 W 0.02g dyn 45 dyn cm patm 10

    6 dyn/cm2

    C1 25 deg [min, max] [10, 50] deg

    Finally, in order to the verify the necessary condition given in equation (3.32),

    we calculate the difference, e = FRcos (cos h1+ cos h2).As shown in Figure 3.5, the e increases with the x values. That is, the force

    component due to hydrostatic pressure dominates the surface tension forces. Hence,it is not feasible to achieve the equilibrium in the z direction with the configuration

    shown in Figure 3.2.

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    0.045 0.05 0.055 0.06 0.065 0.07 0.075 0.08 0.085 0.09 0.09550

    100

    150

    200

    250

    300

    Distance,x1 (cm)

    Forcecomponentsinthezfirection

    (dyn)

    FRz

    (cos h1+ cos h2)

    Difference

    Figure 3.5: Force components in the zdirection. FRz is the resultant force componentin the zdirection due to the liquid pressure on the lens. (cos h1+ cos h2) denotesthe only force component in thez direction. This force component results fromthe surface tension forces on the lens. The difference between the above mentionedcomponents is positive for all feasible x1 values.

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    3.3 Two-dimensional analysis of a tear meniscus when the disk is supported by the

    lower eyelid

    In this section, we continue our analysis of the idealized case of a flat, rectangularlens on a flat cornea with the additional caveat that the lens is resting on the inside

    of the lower eyelid. Our hypothesis is verified by Figure 3.6 which shows images of

    rigid gas permeable (RGP) lens on a cornea.

    As a consequence, a force acts on the lens due to the lower eyelid. The magnitude of

    Figure 3.6: Images of contact lens resting on the inside of the lower eyelid. The headsof the wearers are in the upright position in the images.

    this force isFL and it makes and angle with respect to the axis as shown in Figure

    (3.7). We assume the location ofFL acting on the lens has distance l from the upperedge of the lens. Let FR be the resultant force due to the liquid pressure on the lens.

    h1 is the angle between the upper tear meniscus and an axis parallel to the zaxis.

    Weight of the unit width plate is W.

    In order to find the location, magnitude and the angle that FL acts, we analyze the

    force balance in the x and y directions and the moment balance with respect to the

    point A.

    Those equations are given by,

    sin h1+FRsin +FLcos = W , (3.36)

    cos h1+FLsin = FRcos , (3.37)

    W d sin

    2 +FLsin l cos = FR(d a) +FLcos l sin , (3.38)

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    Figure 3.7: Forces on the lens due to the upper tear meniscus and the lower eyelid.Magnitude of the lower eyelid force is FL and gravity g acts along thex direction. ais the distance to the FR from the lower edge of the lens. Angle between FL and anaxis parallel to the xaxis is .

    and the expression for FR is given by equation (3.33).

    We calculate the distance a using the moment of the disk due to hydrostatic pressure

    force with its resultant force FR about point B that yields,

    FRa =

    x2x1

    (x2 x)[pi(x)patm]cos2

    dx

    a = d(pi(0)patm) + tgd3 (3x1+d cos )

    2(pi(0)patm) +tg(2x1+d cos ) (3.39)

    Moreover, the following expressions are found using the equations (3.36), (3.37) and

    (3.38) for FL, andl respectively.

    FL = (FRcos cos h1)2 + (W

    sin h1

    FRsin )2. (3.40)

    = tan1

    FRcos cos h1W sin h1 FRsin

    . (3.41)

    l =Wd sin

    2 FRb

    Wsin +cos L1 FR . (3.42)

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    3.3.1 Numerical results

    Possible contact angles for the upper tear meniscus are numerically calculated

    using equation (3.25) with the conditions, h1 = 2 and L1 =h1+ where L1

    denotes the contact angle between the upper tear meniscus and the lens. Maximum

    possible overlap distance for the lower eyelid is obtained by measuring from Figure

    1(E)[14]. It has an approximate value of 0.27mm. According to this criteria, we have

    selected feasible l values and corresponding L1, FL,FR and a values.

    Parameter values that are used in this numerical calculation are given in Table 3 .2.

    Figure 3.8 that follows depicts the variation ofL1,a,dl= b,FLandFRwith respect

    Table 3.2: Fixed parameter values.

    Parameter Value CGS units Parameter Value CGS units

    1 g/cm3 d 0.9 cmg 981 cm/s2 W 0.02g dyn 62 dyn cm patm 10

    6 dyn/cm2

    0 deg [min, max] [10, 50] deg

    to the distance x1 for the corneal contact angle of 25. Figure 3.8(a) indicates the

    possible contact angles for the upper tear meniscus. Since the values ofFR depend

    on hydrostatic pressure, as x1 increases the corresponding FR value also increases.

    Thus, in order to balance the effect ofFR, force FL increases with x1.

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    0.06 0.065 0.07 0.075 0.08 0 .085 0 .090

    0.005

    0.01

    0.015

    0.02

    0.025

    0.03

    Distance,x1 (cm)

    b (cm)

    (c)

    0.06 0.065 0.07 0.075 0.08 0.085 0.09170

    180

    190

    200

    210

    220

    230

    240

    Distance,x1 (cm)

    F (dyn)

    (d)

    0.06 0.065 0.07 0.075 0.08 0 .085 0 .0943

    44

    45

    46

    47

    48

    49

    Distance,x1 (cm)

    L (deg)

    (a)

    0.06 0.065 0.07 0.075 0.08 0.085 0.090.17

    0.175

    0.18

    0.185

    0.19

    0.195

    0.2

    Distance,x1 (cm)

    a(cm)

    (b)

    FL

    FR

    Figure 3.8: Variation ofL1,a,band the reaction forcesFLandFRwith respect to thedistance x1. (a) Possible contact angles for the upper tear meniscus with differentx1 values. (b) Increasing the length of the upper tear meniscus x1 yields the disktoward the lower eyelid and, hence, the distance b also increases with x1. (d) For

    all x1 values, the lower eyelid force FL is less than the resultant force FR due to theliquid pressure.

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    3.4 Two-dimensional analysis of a tear meniscus with cylindrical shell type contact

    lens

    In this section, lens geometry is assumed to be a cylindrical shell that has a unitwidth. First, we model the lens and upper tear meniscus system with a lower eyelid

    force,FL. Then, analysis is extended to the system that has a lower tear meniscus.

    The radius and thickness of the cylindrical shell are assumed to be R and t respec-

    tively. Moreover, the open angle of the shell has a value of 2. The center of the

    circular cylindrical shell is denoted byO (refer to Figure 3.9).

    Figure 3.9: A cylindrical shell type lens. The radius and thickness of the circularshell are R and t respectively. Shell has weightW and coordinates of the centroidare (Rc, c). Apex angle of the cylindrical shell is 2.

    Next, the centroid of the shell is located based on its moment about the x axis

    and the axis of symmetry of the shell. Let us assume that the centroid has the

    coordinates (Rc, c, ) with respect to the axis of symmetry of the shell. We consider

    a circular sector on the shell that has an angle from the axis of symmetry of the

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    shell. The circular sector has an angle d . Thus,

    Rc= 1

    W R+tR

    xrddr= 1

    W R+tR

    r2 cos ddr (3.43)

    c = 1

    W

    R+tR

    yrddr= 1

    W

    R+tR

    r2 sin ddr (3.44)

    where, denotes the material density of the shell andW(weight of the shell) is given

    by,

    W =

    R+tR

    rddr. (3.45)

    Use the fact that R >> t, equations (3.43) and (3.44) yield to be,

    Rc sin

    c = 0

    Now, we consider the shell has tilting angle of with respect to the x axis. By

    using geometric analysis, a point, x (x > x1) on the x axis is represented by

    x

    =x1+R sin(+) R sin(+), (3.46)

    where represents the angle that makes the corresponding point ofx on the shell

    with its axis of symmetry.

    Furthermore, force due to hydrostatic pressure acts normal to a surface and our lens

    has a circular profile, hence, the aforementioned force acts radially in the outward

    direction. The total resultant force due to hydrostatic pressure (FR) is found by

    considering a sector element on the shell (refer to Figure 3.10).

    FR(R, ) =

    (pi(r, )patm)R d r (3.47)

    where r is the unit vector in the radial direction and it relates to the Cartesian

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    Figure 3.10: Forces on the lens due to the upper tear meniscus and the lower eyelid.Gravityg acts in the x direction. Diameter and the tilting angle of the lens ared and. rdenotes the unit vector in the radial direction. Angle between the tear meniscus

    and an axis parallel to the y axis is h1.

    coordinate vectors as follows:

    r= sin(+)x+ cos(+)y. (3.48)

    Thus, using equations (3.46), (3.47), and (3.48)

    FR =

    (pi(0) +tgx1+tgR sin(+)

    tgR sin(+)

    patm) rR d

    FRx = R(2c0sin sin+tgR( sin cos cos2))FRy = 2R(c0sin cos tgR sin2 sin2), (3.49)

    wherec0= pi(0)patm+tgx1+tgR sin(+).

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    Let (FLx, FLy) be the lower eyelid force components in the xandy direction re-

    spectively andT denote the surface tension that results from the upper tear meniscussuch that T= (sin h1,cos h1).Then, the force equilibrium of the lens yields,

    FL+ FR+ W+ T = 0

    (FLx, FLy) = (FRx, FRy) (W, 0) +(sin h1, cos h1) (3.50)

    Next, we consider the moment of FR, T, W and FL about the point O. Use the

    convention that counter-clockwise moment of a force is positive. Since the resultant

    force due to hydrostatic pressure acts normal to the surface, the moment ofFRis zero

    about the point O. Thus, the moment ofTand W result,

    MT = [( cos h1, sin h1) ( sin(+), cos(+))]R= R sin(++h1),

    MW = W R cos sin

    . (3.51)

    Lower eyelid force, FL, acts on the outer surface of the lens. We assume it has the

    coordinates (x,y) with respect to the Cartesian coordinate system and using equation(3.46),

    (x,y) =

    x1+R sin(+) R sin(L+), R cos(L+)

    (3.52)

    whereL = +sin1

    sin() bR

    andb denotes the maximum possible overlap

    distance for the lower eyelid.

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    The moment due to FL is

    MFL = ||(x,y) FL||= ||(x,y) (FLx, FLy)||= (FRy+cos h1)(R sin(L+))

    (FRx W+sin h1)R cos(L+) (3.53)

    Thus, for the equilibrium of the lens

    MT+MW+MFL = 0. (3.54)

    3.4.1 Numerical results

    We numerically calculate the possible contact angles for the upper tear meniscus.

    Thus, FR and FL values are calculated for the possible contact angles that were

    mentioned earlier. Finally, the total moment is computed using equation (3.54).

    Parameter values that are used in this computation are given in Table 3.3.

    Table 3.3: Fixed parameter values for the case when the cornea is flat, and the contactlens has a cylindrical shell shape. The values of{, g},{d, W} and{min, max}maybe found [1], [17], and [22] respectively.

    Parameter Value CGS units Parameter Value CGS units

    1 g/cm3 d 0.9 cmg 981 cm/s2 W 0.02g dyn 62 dyn cm patm 10

    6 dyn/cm2

    0 deg [min, max] [10, 50] degR 0.65 cm b 0.1 cm

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    0.05 0.1 0.15 0.2 0.25 0.3200

    250

    300

    350

    400

    450

    Distance,x1 (cm)

    FL, FR(dyn)

    (a)

    FL

    FR

    0.05 0.1 0.15 0.2 0.25 0.360

    50

    40

    30

    20

    10

    0

    10

    X: 0.0773Y: 0.005001

    Distance,x1 (cm)

    (b)

    Moment diff.(dyn.cm)

    Figure 3.11: Variation of FL, FR and the moment difference with respect to thedistance x1. For all the possible distances x1, FR is greater than the FL. Moreover,Figure 3.11(b) indicates that the equilibrium is possible for the particular distance,x1 0.077cm.

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    3.4.2 Lower tear meniscus

    Finally, we extend the above analysis to a lens with upper and lower tear menisci.

    Hence, all the equations derived previously are valid except the equations that containthe lower lid force. The moment due to surface tension of lower tear meniscus yields,

    MTL = R[(cos h2, sin h2) (sin( ), cos( ))]= Rsin( +h2) (3.55)

    whereh2= L2+.

    By using equations (3.51) and (3.55), we derive a formula for the total momentum,

    R sin(++h1) R sin( +h2)W R cos sin

    = 0. (3.56)

    Moreover, the following two equations are derived for the force equilibrium in the x

    and y directions, and an equation is derived for the lower contact angle L2.

    sin h1+W+FRx+sin h2 = 0, (3.57)FRy cos h1 cos h2 = 0, (3.58)

    h2 = tan1

    sin h1 W FRx

    FRy

    cos h1 . (3.59)3.4.2.1 Numerical results

    We numerically compute the values ofh2 for the lower tear meniscus using the

    equations (3.56) and (3.59) separately. Moreover, contact angle at the lower meniscus,

    L2 are obtained using h2 that we obtained by solving the equation (3.56). We use

    the same parameter values that was given in Table 3.3 except [min, max] = [30, 70].

    Variations of the lower contact angles with respect to a horizontal axis, is shown

    in Figure 3.12(a). h2M and H2Fdenote the angles that are obtained by solving the

    equations (3.56) and (3.59) respectively. Furthermore, in Figure 3.12(b), (FRx+W)

    is the vertical component of the resultant force due to hydrostatic pressure and the

    weight of the lens. Stupdenotes the surface tension force that acts in the xdirection.Note that, as depicts in the equation (3.57), the equilibrium in the x direction is

    achieved ifS tup > FRx+W. However, according to Figure 3.12(b),Stup < FRx+W

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    0 0.02 0.04 0.06 0.08 0.1 0.12 0.14 0.16

    40

    60

    80

    Distance,x1 (cm)

    (FRx+ W),Stup(dyn)

    (b)

    FRx

    +W

    Stup

    0 0.02 0.04 0.06 0.08 0.1 0.12 0.14 0.1660

    40

    20

    0

    20

    40

    60

    Distance,x1 (cm)

    h2M, H2F(deg)

    (a)

    h2M

    H2F

    Figure 3.12: (a) Variation of lower contact angle values with x1. h2M and H2F

    denote the lower contact angle values that are obtained by solving the momentumbalance equation and the force balance equations respectively. (b) Variation of theforce components in the x direction (FRx+ W) and the force component in thexdirection (Stup sin h1).

    for all the possible values ofx1. Thus, it is not feasible to achieve the equilibrium in

    the x direction with a lower tear meniscus.

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    3.5 Three-dimensional analysis of a tear meniscus with a spherical cap type

    contact lens

    In this section, we consider a lens that has a shape of a spherical cap. Forsimplicity, tilting angle, of the cap is assumed to be 0. The lens and the upper tear

    meniscus are modeled with a lower eyelid force, FL.

    The radius and a uniform thickness of the spherical cap are assumed to have the

    values ofR and t respectively. The center of the cap is denoted by O and the origin

    of the spherical coordinate system is placed at that point as shown in Figure 3.13.

    The apex angle of the cap is symbolized by 2.

    Figure 3.13: Spherical cap type contact lens. The radius and apex angle of thespherical cap are R and 2 respectively. n is the unit normal in the radial direction.

    g acts in the x direction. The width and apex angle of the spherical frustum are dzand 2.

    In the following analysis, the centroid of the cap is located based on its moment

    about the xy, xz and yz planes. However, since the cap is symmetric about the x

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    and y axis, the centroid has the coordinates of the form (0, 0, zc), where zc denotes

    the zcoordinate of the centroid. As shown in Figure 3.13, we consider a spherical

    frustum on the cap that has an angle from the zaxis with a width ofdz. Let thematerial density of the lens be . Thus, the moment about xy plane results

    zc= 1

    W

    0

    2R3t sin2 cos d (3.60)

    and

    W =

    0

    2R2t sin2 d. (3.61)

    By using the equations (3.60) and (3.61), the zcoordinate of the centroid yields to

    be

    zc= 2R sin3

    3

    sin 2

    2

    . (3.62)

    Let the unit vector in the radial direction be n and it is denoted by

    n= (sin cos , sin sin , cos ). (3.63)

    Next, we consider the forces that act on the lens. Since our lens has a spherical

    profile, forces due to hydrostatic pressure act radially in the outward direction, that is,

    in the direction ofn. Therefore, the liquid force dFRon an area element,R2 sin dd

    on the spherical cap (refer to Figure 3.14) is given by

    dFR= (pi(x)patm)R2 sin dd n (3.64)

    where

    pi(x) =pi(0) +gx1+gR sin+gR sin cos . (3.65)

    Thus, the total force resultant due to the liquid pressure FR, on the spherical cap is

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    Figure 3.14: Forces acting on the spherical cap. FL and rL denote the lower eyelidforce and its position vector with respect to the coordinate system. Gravity g actsin the x direction. Contact anglel is the angle between the tear meniscus and thelens at distance x1. dFR is the force acting on an area element dAdue to the liquidpressure.

    found using the equations (3.64) and (3.65).

    FR=

    0

    20

    (pi(x)patm)R2 sin n d d. (3.66)

    Hence, its components in the x, y andzdirections are

    FRx = gR3

    2

    3 cos+cos

    3

    3

    ,

    FRy = 0,

    FRz = c1R

    2

    2 (1

    cos2) (3.67)

    respectively andc1 = pi(0) +gx1+gR sin patm.

    Surface tension forces act along the circumference of the spherical cap in the

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    direction of the tear meniscus. Let v be a vector pointing tangent to the tear meniscus

    from a point, C, on the circumference of the spherical cap. An orthonormal basis for

    the plane described by the span ofk and n isk, n k(k n)||n k(k n)||

    . (3.68)

    The vector v in this orthonormal basis is given by

    v= cos lk + sin l

    n k(k n)||n k(k n)||

    . (3.69)

    As n= (sin cos , sin sin , cos )T

    = sin cos i +sin sin j +cos k, the coordi-nates for the vector v are:

    v= (sin lcos , sin lsin , cos l) (3.70)

    wherel denotes the contact angle at the pointC(refer to Figure 3.14) and note that

    l l(). Thus, the total force due to surface tension (S) is given by the followingequation,

    S= 20

    vd (3.71)

    Then, force equilibrium of the lens yields,

    FR+ W+ S + FL= 0. (3.72)

    Finally, we consider the moment of the forces, FR, FL, S and W about the point

    O. Since the resultant force, FR acts normal to the spherical cap, its moment about

    point O is zero.

    Let the position vector of the centroid be denoted by rW. Thus, the moment due to

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    the weight (MW) is defined by the equation,

    MW = rW W

    =

    0

    2RWsin3

    3

    sin 2

    2

    0

    . (3.73)

    Next, the moment resulted due to the surface tension is considered about the point

    O. We denote the vector, rc of a point C, on the base circle of the spherical cap by,

    rc= (R sin cos , R sin sin , R cos). (3.74)

    Hence, using the equations (3.70) and (3.74), the moment of the surface tension at

    the point Cis expressed as

    MSc = rc v and then, the total momentum of surface tension yields to beMS =

    20

    (r v) d

    = R 20

    sin(+l()) sin

    cos

    0

    d. (3.75)Now, assume the lid force FL has the componentsFLx,FLy andFLz in the directions

    ofx, y and z respectively. Let rL be a vector corresponding to the point L, where

    the force FL acts on the surface of the spherical cap. Hence, moment of FL about

    the point O is,

    ML = rL FL

    = R

    FLzsin sin FLycos FLxcos FLzsin cos FLysin cos FLxsin sin

    . (3.76)

    Furthermore, using the facts that FRy = 0 and Sy 0, we conclude that FLy 0.

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    Thus, applying the aforementioned facts with the help of equation (3.76), we obtain

    the following two results at the point L.

    = 0

    = tan1

    FLxFLy

    . (3.77)

    Finally, for the equilibrium of the lens,

    MW+ MS+ ML = 0. (3.78)

    3.5.1 Numerical Results

    We numerically calculate all the forces and the moments in the x,y andzdirec-

    tion for all the possible contact angles at the point (R,,). Possible overlap distances

    L for the lower eyelid are numerically calculated by considering the equilibrium of

    the lens.

    For the numerical calculation, we consider a linear variation ofl with respect

    to the angle . Maximum value of the contact angle, which occurs at (R,,), is

    computed from equation (3.25) according to as explained in Figure 3.3. This is an

    approximation as it neglects the curvature in the direction. The minimum value of

    the contact angle, which occurs at (R, 0,) is set at 10

    . Equations (3.71) and (3.75)are numerically integrated using the Simpsons 1/3rd rule. Parameter values that are

    used in this calculation are given in Table 3.4.

    Table 3.4: Fixed parameter values for the case when the cornea is flat and the contactlens has a spherical cap shape. The values of{, g},{c} and{min, max} may befound [1], [16], and [22] respectively.

    Parameter Value CGS units Parameter Value CGS units

    1 g/cm3 d 0.98 cm

    g 981 cm/s

    2

    W 0.0152g dyn 62 dyn cm patm 106 dyn/cm2

    R 0.65 cm [min, max] [10, 50] degc [30, 35] deg

    Figure 3.15 shows the variation of forces that act on the lens with respect to

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    the x1 values for the corneal contact angle of 32. As depicted in Figure 3.15(a), (b)

    and (c), the eyelid force FL is necessary for the equilibrium of the lens. Note that

    hydrostatic force component in theydirection is zero as derived in the equation (3.67).Variation of the moment due to the eyelid force FL is shown in Figure 3.15(d).

    0.145 0.1452 0.1454 0.1456 0.1458 0.146 0.1462 0.146460

    40

    20

    0

    20

    40

    60

    80

    100

    Distance, x1 (cm)

    Fx (dyn)

    (a)

    FLx

    FRx

    FTx

    0.145 0.1452 0.1454 0.1456 0.1458 0.146 0.1462 0.14644

    3

    2

    1

    0

    1

    2

    3

    4x 10

    3

    Distance, x1 (cm)

    Fy (dyn)

    (b)

    FLy

    FRy

    FTy

    0.145 0.1452 0.1454 0.1456 0.1458 0.146 0.1462 0.1464400

    300

    200

    100

    0

    100

    200

    300

    400

    Distance, x1 (cm)

    Fz (dyn)

    (c)

    FLz

    FRz

    FTz

    0.145 0.1452 0.1454 0.1456 0.1458 0.146 0.1462 0.14642.0252

    2.0254

    2.0256

    2.0258

    2.026

    2.0262

    2.0264x 10

    3

    Distance, x1 (cm)

    ML

    (dyn cm)

    (d)

    Figure 3.15: Variation of the force due to fluid pressure FR, surface tension FT andthe lid force FL in the x,y andzdirections. Bottom right corner figure indicates themoment due the eyelid force FL.

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    0.145 0.1452 0.1454 0.1456 0.1458 0.146 0.1462 0.14642.5

    3

    3.5

    4

    4.5

    5

    5.5

    6

    6.5x 10

    3

    Distance, x1 (cm)

    L (cm)

    0.15 0.155 0.16 0.1650

    0.01

    0.02

    0.03

    0.04

    0.05

    0.06

    0.07

    Distance, x1 (cm)

    L (cm)

    0.145 0.15 0.155 0.16 0.165 0.17 0.175 0.180

    0.02

    0.04

    0.06

    0.08

    0.1

    0.12

    Distance, x1 (cm)

    L (cm)

    0 .1 45 0 .1 5 0 .1 55 0 .1 6 0 .1 65 0 .1 7 0 .1 75 0 .1 8 0 .1 850

    0.02

    0.04

    0.06

    0.08

    0.1

    0.12

    0.14

    Distance, x1 (cm)

    L (cm)

    Figure 3.16: Variation ofL for different corneal contact angles. From left to right,top to bottom: c = 32, c = 33, c = 34, c = 35. According to the figures, wesee that the values ofL increase as c increases from 32 to 35.

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    3.6 Comparison with observations

    In the literature[16], the value of the corneal contact angle Eis reported to be in

    the interval [20

    , 49

    ]. In our analysis so far, we had assumed a flat and vertical cornea.The numerical results reported in Section 3.5 were obtained with this assumption.

    The analysis of Section 3.5 shows that there are no feasible solutions when the corneal

    contact angle is less than 32. Can the discrepancy between the theoretical results

    and experimental observations be satisfactorily explained? In this section, we show

    that there is a satisfactory explanation by considering a curved corneal wall that is

    inclined at an angle with respect to the vertical at the point of attachment of the

    tear meniscus. In Figure 3.17, the origin is this point of attachment of the meniscus

    with the curved cornea. We show that the meniscus profiles for the two cases of

    flat, vertical cornea, and curved cornea are virtually identical from the point of view

    of the contact lens. The two relevant factors, (i) distance from the origin to the

    point of attachment of the tear meniscus with the lens, and (ii) the contact angle of

    the meniscus with the lens, have virtually identical numerical values. Thus one can

    conclude static stability even with much smaller contact angles at the corneal wall

    than those predicted by the analysis of Section 3.5.

    We denote the contact angles of the tear meniscus with the flat vertical wall and

    curved corneal surface byEand EC respectively (refer to Figure 3.17).

    We numerically calculate the meniscus profiles and the corresponding slopes forthe contact angles E= 33 andEC= 14.5 using Equation 2.18. For the numerical

    analysis, the same parameter values are used as in Table 2 .2. As depicted in Figure

    3.18, it is possible to obtain the same contact angle between the tear meniscus and

    contact lens for the same tear meniscus height( 0.15 cm) for the contact angles Eand EC. Therefore, the numerical results hold for the same range of values for x1

    even when the cornea is not flat.

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    Figure 3.17: Contact angles between the tear meniscus with the flat vertical walland corneal surface. Gravity g acts in the x direction. E and EC denote thecontact angles between the tear meniscus with the flat vertical wall and corneal surfacerespectively. x1 is the upper tear meniscus height.

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    0 0.05 0.1 0.15 0.2 0.25 0.3 0.350

    0.05

    0.1

    0.15

    0.2

    0.25

    Distance along the vertical wall, x (cm)

    z(x) (cm)

    (a)

    0 0.05 0.1 0.15 0.2 0.25 0.3 0.354

    3

    2

    1

    0

    Distance along the vertical wall, x (cm)

    z(x)

    (b)

    E

    EC

    E

    EC

    Figure 3.18: Meniscus profiles z(x) and their slopes z(x) for the contact anglesE = 33 and EC = 14.5. (a) Variations of the meniscus height with the distancefrom the vertical wall. Note that the two meniscus profiles become identical at theheight,z(x) 0.05 cmand their corresponding slopes z(x) (refer to Figure 3.18(b)).

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    CHAPTER 4

    CONCLUSIONS

    In this research, we mathematically modeled a tear meniscus around a symmet-

    ric, spherical cap lens that was at static equilibrium, using a calculus of variations

    approach. Static equilibrium was analyzed by taking the net force and net moment

    to be zero. The results discussed below assume a flat cornea. However, as shown in

    Section 3.6 the results held (that is, static equilibrium can be archived) for the same

    range of values for x1 even when the cornea is not flat.

    We obtained a range of values for the adjustable parameters, the corneal contact

    angleE, upper contact angle L1and lens positionx1through numerical simulations.

    There were no solutions for E in the range [0, 31]. For E = 32, our numerical

    analysis showed that the static equilibrium may be achieved for x1 in the interval

    [0.145, 0.146]. The analysis further showed that pressure force dominated surface

    tension and the weight of the lens. Hence, for the equilibrium of the lens, it was

    necessary to introduce the lower lid force FL. When we increased the value of E

    from 32 to 35, ranges ofx1 and lid overlap distance Lbecame [1.45, 1.84] mmand

    [0.025, 1.25] mmrespectively. At this particular corneal contact angle, the magnitude

    of the lower eyelid forceFLwas approximately 75.2 dyn. The pressure due to the lower

    lid when the lid overlap is between 0.1 mm 0.27 mm is in the range 3.1 mmHg 13.7 mmHg, with lesser value for lid overlap corresponding to higher lid pressure.

    This compares well with the intraocular pressure of 10 mmHg 20 mmHg [21]. Lidoverlap values up to 0.27 mmare physically reasonable [14]. Therefore, we have shown

    that there exists physically reasonable solutions for a contact lens in static equilibrium

    for a adjustable parameter values.

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    BIBLIOGRAPHY

    [1] Hayashi, T.T., (1977), Mechanics of Contact Lens Motion, Ph.D Dissertation,University of California.

    [2] Moriarty, J.A., Terrill, E.L, (1996), Mathematical Modeling of the Motion ofHard Contact Lenses, Euro. J. Appl. Math, Vol 7, pp575-594.

    [3] de Gennes, P-G., Quere, D., (2004), Capillary and Wetting Phenomena,Springer, New York.

    [4] de Gennes, P-G., (1985), Wetting: Statics and Dynamics, Reviews of ModernPhysics, Vol 57, pp827-863.

    [5] Gao, L., McCarthy T.J., (2006), Contact Angle Hysteresis Explained,AmericanChemical Society, Vol 14, pp6234-6237.

    [6] Joanny, J.F., de Gennes, P-G., (1984), A model for contact angle hysteresis,American Institute of Physics, Vol 81, pp552-562.

    [7] Deen W.M., (1998), Analysis of Transport Phenomena, Oxford University Press,New York.

    [8] Bennett, E.S., Weissman, B.A., (2004). Clinical Contact Lens Practice, Lippin-cott Williams & Wilkins, Philadelphia.

    [9] Butt, H.J., Graf, K., Kappl, M., (2006), Physics and Chemistry of Interfaces,John Wiley & Sons, Weinheim.

    [10] Choi, C., Kim, M., (2011), Wettability Effects on Heat Transfer, Two PhaseFlow, Phase Change and Numerical Modeling,Amimul Ahsan (Ed.), ISBN: 978-953-307-584-6, InTech, Available from: http://www.intechopen.com/books/two-phase-flow-phase-change-and-numerical-modeling/wettability-effects-on-heat-transfer.

    [11] Finn R., (1999), Capillary Surface Interfaces,Notices Amer. Math. Soc., Vol 46,pp770.

    [12] Frankel, T., (2004), The Geometry of Physics: An Introduction, CambridgeUniversity Press, New York.

    [13] Schulz, E., Simon, F., (1984), Contact lens fitting for binocular micromovementrecording, Graefes Archive for Clinical and Experimental Ophthalmology, Vol221, pp282-285.

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    [14] Wang J., Cox I., Reindel W.T., (2009), Upper and Lower Tear Menisci on Con-tact Lenses, Investigative Ophthalmology and Visual Science, Vol 50, pp1106-1111.

    [15] Gelfand, I.M., Fomin, S.V., Silverman, R.A., (2000), Calculus of Variations,Dover Publications, New York.

    [16] Lemp, M.A., Holly, F.J., Iwata, S., Dohlman, C.H., (1970), The precorneal tearfilm: I. factors in spreading and