ChE Syllabus

7/30/2019 ChE Syllabus

1/30

Name Of Course: B.Tech.(Chem.Engg.)

Harcourt Butler Technological Institute, Kanpur

Study and Evaluation Scheme

[Effective from the Session 2009-10]

B. Tech. (Chem. Engg) Year 2nd, Semester -III

S.

N

o.

CourseCode

SubjectPeriods

Evaluation SchemeSubjectTotal

Credits

Sessional Exam.ESE

L T P CT TA Total

Theory Subjects

1 CY 301 Applied chemistry

&instrumental analysis

3 1 0 30 20 50 100 150 4

2 CH301 Material &Energy balance 3 1 0 30 20 50 100 150 4

3 MA 301 Mathematics III 3 1 0 30 20 50 100 150 4

4 CH302 Transport Phenomena 3 1 0 30 20 50 100 150 4

5 CH 303 Engineering Thermodynamics 3 1 0 30 20 50 100 150 4

Practical/Design

6 CY 351 Chemistry Lab 0 1 3 30 20 50 50 100 4

7 CH 351 Flow Sheeting Lab 0 1 3 30 20 50 50 100 48 General Proficiency 50

B. Tech. (Chem. Engg) Year 2nd, Semester -IV

S.No

.

Course

CodeSubject

PeriodsEvaluation Scheme

Subject

Total

Credi

tsSessional Exam.

ESEL T P CT TA Total

Theory Subjects

1 CH 401 Fluid Mechanics 3 1 0 30 20 50 100 150 4

2 CH 402 Mechanical Operation 3 1 0 30 20 50 100 150 4

3 CH 403 Heat Transfer Operation 3 1 0 30 20 50 100 150 4

4 CH 404 Chemical EngineeringThermodynamics

3 1 0 30 20 50 100 150 4

5 CH 405 Chemical Reaction

engineering-1

3 1 0 30 20 50 100 150 4

Practical/Design

6 CH 451 Fluid Mechanics Lab 0 0 3 15 10 25 25 50 2

CH 452 Mechanical operation lab 0 0 3 15 10 25 25 50 2

7 CH 453 Heat Transfer Operation Lab 0 1 3 30 20 50 50 100 4

8 General Proficiency 50


2/30

B. Tech. (Chem. Engg) Year 3rd, Semester -V

S.

No.

Course

CodeSubject


Subject

Total

Credit

sSessional Exam.

ESE

L T P CT TA TotalTheory Subjects

1 CH 501 Instrumentation and ProcessControl

3 1 0 30 20 50 100 150 4

2 CH 502 Chemical Reaction Engineering

-II

3 1 0 30 20 50 100 150 4

3 CH 503 Mass Transfer Operation-I 3 1 0 30 20 50 100 150 4

4 CH 504 Bio system processes 3 1 0 30 20 50 100 150 4

5 CH 505 Chemical Technology-I 3 1 0 30 20 50 100 150 4

Practical/Design

6 CH 551 Instrumentation and ProcessControl Lab

0 1 3 30 20 50 50 100 4

7 CH 552 Chemical reaction engineering

Lab

0 1 3 30 20 50 50 100 4


B. Tech. (Chem. Engg) Year 3rd, SemesterVI

S.No.

CourseCode

SubjectPeriods

Evaluation SchemeSubjectTotal

Credits

Sessional Exam.ESE

L T P CT TA Total

Theory Subjects

1 CH 601 Mass transfer operation -II 3 1 0 30 20 50 100 150 4

2 MA CONM 3 1 0 30 20 50 100 150 43 CH 602 Process Equipment Design 3 1 0 30 20 50 100 150 4

4 CH 603 Process Optimization 3 1 0 30 20 50 100 150 4

5 CH 604 Chemical Technology-II 3 1 0 30 20 50 100 150 4

Practical/Design

7 CH 651 Mass Transfer Lab 0 0 3 15 10 25 25 50 2

8 MA CONM Lab 0 0 3 15 10 25 25 50 2

9 CH 652 Seminar 0 0 6 15 10 25 25 50 2



3/30

B. Tech. (Chem. Engg) Year 4th, Semester -VII

S.N

o.

Course

CodeSubject


Subject

Total

Credit

sSessional Exam.


Theory Subjects

1 CH OE Open Elective 3 1 0 30 20 50 100 150 42 CH 701 Process Modeling and

Simulation

3 1 0 30 20 50 100 150 4

3 CH 702 Material Technology 3 1 0 30 20 50 100 150 4

4 CH 703 Process design and poject

engineering

3 1 0 30 20 50 100 150 4

5 Elective-I 3 1 0 30 20 50 100 150 4

Practical/Design

6 CH 751 Computer Application and

Design lab

0 0 3 15 10 25 25 50 2

7 CH 752 Project 0 0 6 100 4

8 CH 753 Industrial/practical training and

report presentation

0 0 3 - 50 50 50 2


B. Tech. (Chem. Engg) Year 4th, Semester -VIII

S.

No.Course Code Subject


Subject

Total

Cre

sSessional Exam.


Theory Subjects

1 Engineering Economics and

Management

3 1 0 30 20 50 100 150 4

2 Elective-II 3 1 0 30 20 50 100 150 4

3 Elective -III 3 1 0 30 20 50 100 150 4

4 Energy Resources and

Management

3 1 0 30 20 50 100 150 4

Practical/Design

6 CH751 Energy & Environmental lab 0 0 3 30 20 50 50 100 4

7 CH752 Project 0 0 10 250


Open Elective: Energy resources utilization and management

Elective-I 1.Advance separation process

2. Process Integration

3. Interface and surface sciences

Elective-II 1. Heterogeneous catalysis

2. Advanced process control3. Molecular Simulation

Elective-III

1. Nanotechnology

2. Standardization in Chemical engineering

3. Industrial Safety & Hazard Management


4/30

THIRD SEMESTER

CH 301 MATERIAL &ENERGY BALANCE (3:1:0)

UNIT 1

Basic and derived units, use of model units in calculations, Methods of expression, compositions of mixture andsolutions, Ideal and real gas laws - Gas constant - calculations of pressure, volume and temperature using ideal

gas law, Use of partial pressure and pure component volume in gas calculations, applications of real gas

relationship in gas calculation.

UNIT2

Stoichiometric principles, application of material balance to unit operations like distillation, evaporation,

crystallization, drying etc., Material balance with chemical reaction, Limiting and excess reactants, recycle,

bypass and purging

UNIT 3

Unsteady state material balances, calculation of absolute humidity, molal humidity, relative humidity and

percentage humidity, use of humidity in condensation and drying, Humidity chart, dew point.

UNIT 4

Determination of Composition by Orsat analysis of products of combustion of solid, liquid and gas fuels,

calculation of excess air from orsat technique and problems, heat capacity of solids, liquids, gases and solutions,use of mean heat capacity in heat calculations, problems involving sensible heat and latent heats, evaluation of

enthalpy.

UNIT5

Standard heat of reaction, heats of formation, combustion, solution, mixing etc., calculation of standard heat of

reaction, effect of pressure and temperature on heat of reaction, Energy balance for systems with and without

chemical reaction, unsteady state energy balances. Introduction to Computer aided calculations-steady state

material and energy balances.

BOOKS:

1. Bhatt, B.L., VORA, S.M., Stoichiomentry ", Tata McGraw-Hill, 1976.

2. Hougen, O.A., Watson, K.M and Ragatz, R.A., " Chemical Process Principles Part-I ",John Wileyand Asia Publishing, 1970.

3. Himmelblau, D.M., Basic Principles and Calculations in Chemical Engineering ",Fourth Edition,

Prentice Hall Inc., 1982.

4. Whitwell, J.C., Tone, R.K. Conservation of Mass and Energy ", McGraw-Hill, 1973.5. Process Calculation for Chemical Engineering, Second Revised Edition, Chemical Engineering

Education Development Centre, I.I.T., Madras, 1981.


5/30

CH 302 TRANSPORT PHENOMENA (3:1:0)

UNIT 1

Vectors/Tensors, Newtons law of viscosity, Temperature, pressure and composition dependence of viscosity,

Kinetic theory of viscosity, Fouriers law of heat conduction, Temperature, pressure and composition

dependence of thermal conductivity, Kinetic theory of thermal conductivity, Ficks law of diffusion,

Temperature, pressure and composition dependence of diffusivity, Kinetic theory of diffusivity.

UNIT 2

Shell Momentum balances, velocity profiles, average velocity, momentum flux at the surfaces, Equations of

Change (Isothermal), equation of continuity, equation of motion, equation of energy (isothermal).

UNIT 3

Shell energy balances, temperature profiles, average temperature, energy fluxes at surfaces, Equations of change

(non-isothermal), equation of continuity, equation of motion for forced and free convection, equation of energy

(non-isothermal).

UNIT 4

Shell mass balances, concentration profiles, average concentration, mass flux at surfaces, Equations of change

(multi-component), equations of continuity for each species, equation of energy (multi-component).

UNIT 5

Introduction to the concept of heat and mass transfer coefficients. Interphase mass transfer, various coefficient ofmass transfer and their determination, resistance concept, controlling phase concept, Mass transfer in turbulent

flow, Analogies of mass transfer, Empirical equations.Theories of mass transfer, two film theory, Higbies

penetration theory, Derivation of flux equation, surface renewal theory.

BOOKS:

1. Byron, R. B., Stewart, W. E., Lightfoot, E. N., Transport Phenomena, John Wiley & Sons, 1960.


6/30

CH 303ENGINEERING THERMODYNAMICS (3:1:0)

UNIT 1Fundamental concepts in thermodynamics: heat and work, the first law of thermodynamics, joule's experiment,

Internal energy, state functions, enthalpy, steady-state steady-flow processes, equilibrium and the phase rule,

reversible processes, processes at constant volume and constant pressure, heat capacities, thermodynamics

analysis of control volume, unsteady flow processes, charging and discharging of vessel.

UNIT 2

Volumetric properties of pure fluids, P-V-T diagrams, Ideal gas, virial equation and its applications, cubic

equations of state, generalized correlations for gases and liquids.

UNIT 3

THERMAL EFFECTS: Sensible heat and latent heat. Standard heat of formation, heat of reaction and heat of

combustion, effect of the temperature on the heat of reaction, the second law of thermodynamics, statement ofthe second law, heat engines, carnot cycle, thermodynamic scale of temperatures, entropy, the third law of

thermodynamics.

UNIT 4

Thermodynamic properties of pure fluids, maxwell's equations, helmholtz and gibbs functions. residual

properties. two-phase systems, tables and diagrams of thermodynamic properties of gases and liquids.

UNIT 5

Cycles for conversion of heat into power, refrigeration and liquefaction, thermodynamic analysis of processes.

BOOKS1. Smith, J. M.; Introduction to chemical engineering thermodynamics Tata McGraw Hill, New

Delhi

CH 351 FLOW SHEETING LAB(0:1:3)

Problems will be solved using CHEMCAD Software

FOURTH SEMESTER


7/30

CH 401 FLUID MECHANICS (3:1:0)

UNIT 1

Properties of fluids, fluid statics, Forces on fluids, pressure depth relationship for compressible and

incompressible fluids, Forces on submerged bodies, Rigid body motion, pressure measurements, Eulers

equation, Bernoullis theorem.

UNIT 2

Kinematics of flow, Description of velocity field, Stream functions, Angular velocity, Fluids in circulation,

Irrotational flow, Dimensional analysis, Buckingham Pi Theorem, Dimensionless numbers and their physical

significance, Similitude Criteria.

UNIT 3

Fluid flow: Laminar and turbulent flows, Pressure drop in pipes, pipe fittings and pipe network, friction factor,Conservation of mass, momentum and energy, Mechanical engineering Bernoullis equation .

UNIT 4

Flow measuring devices for chemical plants, venturimeter, orifice meter, nozzle, Rota meter, pitots tube and v-notch.

UNIT 5

Pumping and compressing of chemicals and gases, reciprocating pumps, rotary pumps, centrifugal pumps and

blowers, NPSH and calibrations, mixing and agitation, types of mixers and their selection, power requirement,

compressible fluid flow, introductory concepts of two-phase flow.

BOOKS

1. Gupta, Vijay and S. K. Gupta, Fluid Mechanics and its Applications, Wiley Eastern, New Delhi

(1984).

2. Rajput, R. K., Text Book of Fluid Mechanics, S. Chand and Co., New Delhi (1998).

3. Jain, A. K., Fluid Mechanics including Hydraulic Machines, Khanna Publishers, Delhi (2007).

4. Bansal, R. K., Fluid Mechanics and Hydraulic Machines, Laxmi Publications (P) Ltd., New Delhi(2005).

5. Gupta, S. K., Momentum Transfer Operations, Tata McGraw Hill, New Delhi (1982).


8/30

CH 402 MECHANICAL OPERATIONS (3:1:0)

UNIT I

Particle Technology: Particle shape, particle size, different ways of expression of particle size, shape factor,sphericity, mixed particles size analysis, screens ideal and actual screens, differential and cumulative size

analysis, effectiveness of screen, specific surface of mixture of particles, number of particles in a mixture,

standard screens industrial screening equipment, motion of screen, grizzly, gyratory screen, vibrating screen,

trommels, sub sieve analysis Air permeability method, sedimentation and elutriation methods.

UNIT 2

Size Reduction: Introduction types of forces used for communition, criteria for communition, characteristics

of communited products, laws of size reduction, work index, energy utilization, methods of operating crushers

free crushing, choke feeding, open circuit grinding, closed circuit grinding, wet and dry grinding, equipment for

size reduction Blake jaw crusher, gyratory crusher, smooth roll crusher, tooth roll crusher, imp actor, attrition

mill, ball mill, critical speed of ball mill, ultra fine grinders, fluid energy mill, colloid mill, cutters knife cutter

UNIT 3

Flow of Fluid Past Immersed Bodies: Drag, drag coefficient, pressure drop Kozeny Carman equation,

Blake- Plummer, Ergun equation, fluidization, conditions for fluidization, minimum fluidization velocity, types

of fluidization, application of fluidization, slurry transport, pneumatic conveying.

Motion of Particles Through Fluids: Mechanics of particle motion, equation for one dimensional motion of

particles through a fluid in gravitational and centrifugal field, terminal velocity, drag coefficient, motion of

spherical particles in Stokes region, Newtons region and intermediate region, criterion for settling regime,

hindered settling, modification of equation for hindered settling, centrifugal separators, cyclones and hydro

cyclones.

UNIT 4

Sedimentation: Batch settling test, application of batch settling test to design of continuous thickener, Coe andClevenger theory, Kynch theory, thickener design, determination of thickener area.

Filtration: Introduction, classification of filtration, cake filtration, clarification, batch and continuous filtration,

pressure and vacuum filtration constant rate filtration and cake filtration, characteristics of filter media, industrial

filters, sand filter, filter press, leaf filter, rotary drum filter, horizontal belt filter, bag filter, centrifugal filtration

suspended batch centrifuge, filter aids, application of filter aids, principles of cake filtration, modification of

Kozeny Carman for filtration

UNIT 5

Agitation And Mixing: Application of agitation, Agitation equipment, Types of impellers Propellers, Paddles

and Turbines, Flow patterns in agitated vessels, Prevention of swirling, Standard turbine design, Powercorrelation and Power calculation, Mixing of solids, Types of mixers- change can mixers, Muller mixers, Mixing

index, Ribbon blender, Internal screw mixer, Tumbling mixer.Sampling, Storage and Conveying of Solids: Sampling of solids, storage of solids, Open and closed storage,

Bulk and bin storage, Conveyors Belt conveyors, Chain conveyor, Apron conveyor, Bucket conveyor, Bucket

elevators, Screw conveyor.

BOOKS:

1. Momentum transfer operation: S.K.Gupta, TMC, 1979.

2. Unit Operations of Chemical Engineering: McCabe and Smith,.TMC


9/30

3. Chemical Engineering Vol. I: Coulson & Richardson, Pergamon, 1979

CH 403 HEAT TRANSFER OPEARATIONS(3:1:0)

UNIT 1

Introduction to heat transfer and general concepts of heat transfer by conduction, convection and radiation,

Conduction: Basic concepts of conduction in solids, liquids, gases, steady state temperature fields and one

dimensional conduction without heat generation e.g. through plain walls, cylindrical and spherical surfaces,

composite layers, etc. Insulation materials, critical and optimum insulation thickness. Extended surfaces, fins

and their applications. Introduction to unsteady state heat transfer.

UNIT 2

Convection: Fundamentals of convection, Basic concepts and definitions, natural and forced convection,

hydrodynamic and thermal boundary layers, laminar and turbulent heat transfer inside and outside tubes.

Dimensional analysis, determination of individual and overall heat transfer coefficients, heat transfer in molten

metals.

UNIT 3

Radiation: Basic laws of heat transfer by radiation, black body and gray body concepts, view factors, Kirchhoffs

law, solar radiations, combined heat transfer coefficients by convection and radiation.

UNIT 4

Heat transfer with phase change: Condensation of pure vapours, film wise and drop wise condensation, loading

in condensers and basic calculation on condensers. Heat transfer in boiling liquids, boiling heat transfer

coefficients. Evaporation: Elementary principles, types of evaporators, Single and multiple effect evaporatorsand their calculations.

UNIT 5

Heat transfer equipment: Classification, principles and design criteria, types of exchangers, viz. double pipe,shell and tube, extended surface. Furnaces and their classification and application.

BOOKS

1. Holman, J. P., Heat Transfer, 9th ed. McGraw Hill (1989).

2 Coulson, J. M. & Richardson, J. F., Chemical Engineering:Vol-1, 6th ed. Butterworth-Heinemann

3 McAdams, W. H., Heat Transmission, 3rd ed., McGraw-Hill (1954).

4 Kern, D. Q., Process Heat Transfer, McGraw Hill Book (1950).

5 Badger, W. L. & Bancharo, J. T., Introduction to Chemical Engineering, Tata McGraw Hill.


10/30

CH 404 CHEMICAL ENGINEERING THERMODYNAMICS (3:1:0)

UNIT 1.

An Introduction to vapour-Liquid Equilibria, qualitative behaviour of the vapour-liquid equilibria (VLE),

Simple models for vapourliquid, equilibria:Raoult's and henrys laws, dewpoint and bubblepoint calculations,

VLE by modified raoults law and K-value correlations. Flash calculations.

UNIT 2

Solution Thermodynamics, theory fundamental property relation. The chemical potential and phase equilibria.

Partial properties, equations relating molar and partial molar properties, partial properties in binary solutions,

relations among partial properties, ideal gas mixtures, fugacity and

fugacity coefficient for pure species, VLE for pure species, fugacity of a pure liquid, fugacity and fugacity

coefficient for species in solution, the fundamental residual property relation, fugacity coefficients from the

virial equation of state and generalized correlations, the ideal solution, the Lewis/Randall rule, excess properties.The excess Gibbs energy and the activity coefficient, The nature of excess properties.

UNIT 3.

Solution Thermodynamics, Applications Liquid phase properties from VLE data. Fugacity. Activity coefficient.Excess Gibbs energy. Data reduction. Thermodynamic consistency. Models for the excess Gibbs energy. Local

composition models. Property changes of mixing. Heat effects of mixing processes. Heats of solution. Enthalpy-

Concentration diagrams.

UNIT 4.

Chemical Reaction Equilibria, The reaction coordinate. Multireaction stoichiometry. Application of equlibrium

criteria to chemical reactions. The standard Gibbs energy change and equilibrium constant. Effect of temperature

on the equilibrium constant. Evaluation of equilibrium constants. Relation of equilibrium constants tocomposition. Gas-phase and liquid-phase reactions. Equilibrium conversions for single reactions. Single phase

reactions. Reactions in heterogeneous systems. Multireaction equilibria. Fuel cells.

UNIT 5

Topics in Phase Equilibria The gamma/phi formulation of VLE. VLE from cubic equations of state. Equilibrium

and stability. Liquid-liquid equilibrium. Vapour-liquid-liquid equilibrium. Solid-liquid equilibrium. Osmoticequilibrium and osmotic pressure.

BOOKS

1. Smith, J. M.; Introduction to chemical engineering thermodynamics .

CH 405 CHEMICAL REACTION ENGINEERING-I(3:1:0)

UNIT 1

Rate of Reaction, Elementary and non-elementary homogeneous reactions, Molecularity and order of reaction,

Mechanism of reaction, temperature dependency from thermodynamics, collision and activated complex

theories. Integral and differential methods for analyzing kinetic data, interpretation of constant volume reactor,


11/30

zero, first, second and third order reactions, half life period, irreversible reaction in parallel and series, catalytic

reaction, auto catalytic reaction, reversible reactions.

UNIT 2

Interpretation of variable volume batch reactions for zero, first and second order reactions, design equation forbatch, continuous stirred tank, plug flow reactors for isothermal reaction.

UNIT 3

OPTIMUM REACTOR SIZE, PLUG FLOW/MIXED FLOW REACTORS IN SERIES AND PARALLEL,

RECYCLE REACTOR.

UNIT 4

Design of reactors for multiple reactions, parallel and series reactions. Temperature and pressure effects for

single reaction.

UNIT 5

Residence time distribution of fluids in vessels, E, F and C curves, Dispersion model, Tank in series model.

BOOKS

1. Levenspiel, O., Chemical Reaction Engineering, 3rd edition, John Wiley (1998).

CH 451 FLUID MECHANICS LAB(0:0:3)1. To find the cake and filter medium resistance of Plate and Frame Filter press.

2. To find the filter medium resistance of a Vacuum Leaf Filters.

3. To find the flow rate using a V notch

4. To find the friction losses in a Straight pipe

5. To find the friction losses in a Bend pipe

6. Study of Pipe fittings and Valves

7. To study the principle of a hydro-cyclone and find out the efficiency of separation.

8. To study the Reynolds apparatus and verify experimentally

9. To study the working principle of a reciprocating pump and to determine the percentage of slip.

10. To study the working principle of a centrifugal pump and determine its efficiency experimentally.

11. To determine the cake resistance of a batch basket centrifuge.12. To find out the flow profile of water from hooks gauge and determination of coefficient of velocity,

coefficient of discharge, coefficient of resistance, coefficient of contraction

13. To determine the pressure drop in a packed bed by Levas and Erguns equation and verify

experimentally.

14. To determine the minimum fluidization velocity in a fluidized bed and verify experimentally.

15. To determine the minimum fluidization velocity and pressure drop in a tapered fluidized bed.

16. Determination of discharge coefficient with Reynolds Number in case of an orifice meter and a venturi

meter.


12/30

17. Determination of the minimum fluidization velocity and pressure drop in a square bed.

18. Study of De laval Centrifuge and to find out its efficiency using it as a Clarifier and Purifier.

19. Study and verification of the flow pattern in a Bernoullis apparatus.

20. Determination of the mixing and segregation index of the given sample of bed materials in a fluidized

bed.

21. Determination of the fluidization index of the given sample of bed materials in a fluidized bed.

CH 452 MECHANICAL OPERATION LABS(0:0:3)

1. Determination of average particle size of a mixture of particles by sieve analysis.

2. Study and operation of Jaw crusher and thereby verification of Ritingers constant.

3. Determination of reduction ratio, maximum feed size and theoretical capacity of crushing rolls.

4. Determination of the effect of no. of balls on grinding in a Ball mill and comparison of its critical speed

with the operating speed.

5. To find out the effect of time on grinding and amount of undersize at zero time of grinding in a ball mill

and to compare its operating speed with the critical speed.

6. To find out enrichment of the coal sample using a froth flotation cell.

7. Determination of the effectiveness of a vibrating screen.

8. To find the efficiency of Wilfley Table and the effect of water flow rate on efficiency of separation.

9. Study and operation of a Hammer mill thereby finding its reduction ratio.10. Study and operation of a Pulverizer and thereby finding its reduction ratio.

11. Study and operation of a cyclone separator and thereby finding its efficiency of separation.

12. Study and operation of a Magnetic separator and thereby finding its efficiency of separation.

13. Study and operation of a Gyratory Crusher and thereby finding its reduction ratio

CH 453 HEAT TRANSFER LAB (0:1:3)

1. To find out the thermal conductivity of liquids.

2. To find out the thermal conductivity of a metal rod.

3. Find out the Heat Transfer Coefficient during drop wise and film wise condensation.

4. Find out the Heat Transfer Coefficient in a vertical and a horizontal condenser.

5. To find out the emissivity of a surface.

6. To find out the overall thermal conductance and plot the temperature distribution in case of a composite

wall.

7. To find out the average heat transfer co-efficient of vertical cylinder in natural convection.

8. To find out the Stefan Boltzmans constant and compare with the theoretical value.

9. To find out the relation between insulation thickness and heat loss.

10. To find out the overall heat transfer co-efficient of a double pipe heat exchanger.

11. To find out the overall heat transfer co-efficient of 1-2 shell & tube heat exchanger.

12. Study and operation of a long tube evaporator.

FIFTH SEMESTER


13/30

CH 501 INSTRUMENTATION & PROCES CONTROL(3:1:0)

UNIT 1

Introduction to Process control systems, Use of Laplace & Inverse Laplace Transformation in study of Process

Dynamics & Control .Dynamic Modeling of a Process, Dynamic behavior of First order system, First ordersystems in series & second & higher order systems for various kind of inputs, Linearization of nonlinear

systems, Transportation & Transfer Lag.

UNIT 2

Classification of control systems ,Regulator & Servo control, Feed Forward & Feed backward control, Negative

& Positive Feed back Control, Variables & Physical Elements of a Control system, Modes of control action,

Controllers & Final control Elements, Reduction of Block & Signal Flow Diagrams, Closed loop transfer

function

UNIT 3

Response of closed loop control system for various type of control actions.Stability analysis, Rouths criterion,UNIT 4

Principles of measurements and classification of process control instruments,Static & Dynamic Chracterstics of

instruments, Error analysis, Measurement of temperature,

UNIT 5

Measurement of pressure, Vacuum, flow rate, liquid level and viscosity.

BOOKS

1. Coughnowr and Koppel, " Process Systems Analysis and Control ", McGraw-Hill, New

York, 1986.2. George Stephanopolous, " Chemical Process Control ", Prentice-Hall of India Pvt-Ltd.,

New Delhi, 1990.

3. Emenule, S.Savas, " Computer Control of Industrial Processes ", McGraw-Hill, London, 1965.

4. Eckman, D.P., " Industrial Instrumentation ", Wiley, 1978.

CH 502 CHEMICAL REACTION ENGINEERING II (3:1:0)

UNIT 1

Introduction to heterogeneous reactions, Fluid-fluid reactions: kinetics and design.

UNIT 2

Fluid-solid reactions: kinetic and design, Design of packed bed and fluidized bed reactors.

UNIT 3


14/30

Nature of catalysis, Adsorption isotherms, Physical properties of catalysts, preparation, testing and

characterization of solid catalysts, catalyst selection, catalyst poisoning and mechanisms of catalytic reactions.

UNIT 4

Reaction and diffusion within porous catalysts, effectiveness factor, design of solid catalytic reactors.

UNIT 5

Biochemical reactors, polymerization reactors.

BOOKS

1. Levenspiel, O., Chemical Reaction Engineering, 3rd edition, John Wiley, (1998).

2. Smith, J, M, Chemical Engineering Kinetics, 3rd edition, McGraw-Hill (1990).

CH 503 MASS TRANSFER -1 (3:1:0)

UNIT 1

Distillation

Pressure-composition, Temperature-concentration, Enthalpy-concentration diagrams for ideal and non-ideal

solutions, Raoults law and its application, Maximum and minimum boiling mixtures, concept of relative

volatility, Single Stage Distillation Differential distillation, Flash vaporization, Vacuum, molecular and steam

distillation.

UNIT 2

Continuous Distillation of Binary Mixtures

Multistage contact operations, Characteristics of multistage tower, McCabe Thiele method, Ponchon Savarit

method, Reflux, maximum, min. and optimum reflux, Use of open steam, Tray efficiency, Determination of

height and column diameter, Multistage batch distillation; Principles of azeotropic and extractive distillation,

Introduction to multicomponent distillation system.

UNIT 3

Liquid-Liquid Extraction

Ternary liquid equilibria, Triangular graphical representation concept of theoretical or ideal stage, Equipmentused for single stage and multistage continuous operation; Analytical and graphical solution of single and

multistage operation Super critical fluid extraction.

UNIT 4

Solid /Liquid Extraction

Leaching, Solid liquid equilibrium, Equipment used in solid-liquid extraction,Single and multistage cross current

contact and counter current operations. Concept of an ideal stage, Overall stage efficiency, Determination of

number of stages.

UNIT 5


15/30

Adsorption

Description of adsorption processes and their application, Types of adsorption, Nature of adsorbents adsorption

equilibrium and adsorption hysterises, Stage wise and continuous contact adsorption operations, Determination

of number of stages, Equipments; Ion exchange, Equilibrium relationship, Principle of ion-exchange, techniques

and applications, Principles and application of dialysis, osmosis reverse osmosis, thermal diffusion, sweepdiffusion.

BOOKS

1. Treybal, R Mass Transfer Operations, 3rd ed. New York: McGraw-Hill, (1980).

2. Sherwood T. K., Pigford R. L. and Wilke P. Mass Transfer McGraw Hill (1975).

3. Foust A. S. et.al., Principles of Unit Operations John Wiley (1980).

4. Geankoplis, C.J.. Transport Processes and Unit Operations, 3rd ed. Prentice Hall.

CH 505 CHEMICAL TECHNOLOGY--I (3:1:0)

Introduction of CPT with reference to Indian resources, industries, trade and export potential, small scale

industries and rural development. Preparation of process flow diagrams, Instrumentation diagrams and Process

symbols. ; Introduction to the following industries lying emphasis on process flow sheet, material requirements,

process conditions, material of construction and design aspects.

UNIT 1

CARBOHYDRATES

Introduction - Mono and Disaccharides - Important reactions - Polysaccharides - Starch and Cellulose -

Derivatives of Cellulose - Carboxy Methyl Cellulose and gun cotton - Structural aspects of cellulose.

UNIT 2

Sugar, Glucose, Starch, Fermentation products such as Alcohol , Acetic acid, Citric acidand antibiotics

UNIT 3

Soap and Surfactants, Glycerin, Fatty acids, Hydrogenation of edible oils , paper and pulp [6]

UNIT 4

Synthetic and natural fibers: Nylon, Dacron, Terylyne, Polyester and other new products, Viscose rayon, acetate

rayon , synthetic rubber with special reference to manufacture, vulcanization and reclaiming of rubber, SBR,Plastics, Thermosetting and Thermo Plastics(PVC, Polyethylene, Polyurethane, Teflon )

UNIT 5

Crude oil distillation, Thermal conversion processes(visbreaking ,coking), Catalytic conversion processes(fluid

catalytic cracking, catalytic reforming, hydro cracking, alkylation, isomerisation, polymerization) Finishingprocesses, sulphur removal process, lub oil manufacture; Petrochemicals(ethylene, propylene, formaldehyde,

methanol, ethylene oxide , ethanolamine, cumene, ethylene glycol, ethyl benzene)

BOOKS

1. Dryden, C. E. Outlines of Chemical Technology (Edited and Revised by M.Gopal Rao and Sittig

.M) East West Press.Pvt Ltd,New Delhi,3 rd Edition(1997).

2. Austin G. T Shreves Chemical Process Industries, 5th ed., McGraw Hill.(1984).


16/30

CH 551 INSTRUMENTATION & PROCES CONTROL LAB (0:1:3)

1. Transient response to single tank system with storage & Flow to (a) step change (b) impulse change in

put.

2. Transient response of non interacting system in series.

3. Transient response of interacting system in series.

4. Study the operation of ON-OFF electronic temperature controller & determination of its performance tocontrol the temperature of a system having capacity to store thermal energy.

5. Study the principle of operation & working of pneumatic servo system with various input functions.

6. Transient response of a CSTR System to step change.

7. Controlling a batch reactor using digital PID controller.

8. Study the dynamics of parallel & counter flow shell & tube heat exchanger.

9. Controlling of Parallel Flow & counter flow STHE using digital PI controller to have desired output.

10. Dynamics characteristics of mercury & water manometers.

11. Study of control value characteristics.

12. Study the performance of cascade control system & to maintain desired level in a tank, with flow.

13. Study the dynamics of bubble cap distillation column.

14. Control of a bubble cap distillation column using digital PID controller.15. Study of effect of PID controller on pressure process trainer.

16 Calibration of thermocouple/Bimetallic thermocouple/Resistance thermocouple.

17. Calibration of Pressure gauge/ Pnuematic pressure recorder/ Differential pressure recorder.

18. Calibration of Orificemeter/ Venturimeter / Rotameter/ Gas flow meter.

19. Estimation of viscosity by Redwood/ Saybolt/ Ostwald viscometer.20. Calibration of pH meter.

21. Calibration of Conductivity meter.

CH 552 CHEMICAL REACTION LABORATORY

(0:1:3)

1. Study and operation of a packed bed reactor

2. Study and operation of a batch reactor3. Study and operation of a CSTR

4. Study and operation of a plug flow reactor

5. Study and operation of a cascade CSTR

6. Study and operation of an adiabatic batch reactor

7. Study and operation Trickle bed reactor

8. Study and operation Condensation polymerization reactor

9. Study and operation Emulsion polymerization reactor

10. RTD study in a CSTR

11. RTD study in a plug flow reactor

12. Study and operation of a coiled tubular reactor

SIXTH SEMESTER


17/30

CH 601 MASS TRANSFER OPERATIONS - II (3:1:0)

UNIT 1

Absorption and Stripping: Equipments, Gas-liquid equilibrium, Henrys law, Selection of solvent, Absorption

in traycolumn, Graphical and analytical methods, Absorption in packed columns, HTU, NTU &HETP concepts,Design equations for packed column, Absorption with chemical reactionand mass transfer.

UNIT 2

Humidification and Dehumidification:Vapour liquid equilibrium and enthalpy for a pure substance, vapour

pressure temperature curve, Vapour gas mixtures, Definition and derivations of relationships related with

humidity Fundamental concept of humidification, Dehumidification and water cooling, Wet bulb temperature,

Adiabatic and non-adiabatic operations,Evaporative cooling ,Classification and design of cooling towers.

UNIT 3

Drying: Solid-gas equilibrium, Different modes of drying operations, Definitions of moisture

contents, Types of batch and continuous dryers, Rate of batch drying, Time of drying,

Mechanism of batch drying, Continuous drying,

UNIT 4

Crystallization: Equilibrium yield of crystallization ,Heat and mass transfer rates in crystallization, Theories of

crystallization, Factors governing nucleation and crystal growth rates, Controlled growth of crystal.,Classification and design of crystallizers.

UNIT 5

Membrane separation process, Types of membrane, separation of gases, separation of liquids, Dialysis, Reverse

Osmosis, pervaporisation, Desalination.Recent Developments in Mass Transfer Operation.

BOOKS1. Trey bal, R Mass Transfer Operations, 3rd ed. New York: McGraw-Hill, (1980).

2. Sherwood T. K., Pig ford R. L. and wilke P. Mass Transfer McGraw Hill (1975).

3. Foust A. S. et.al., Principles of Unit Operations John Wiley (1980).

4. Geankoplis, C.J.. Transport Processes and Unit Operations, 3rd ed. Prentice Hall.

(1993)

CH 602 PROCESS EQUIPMENT DESIGN (3:1:0)

Process Design: Heat exchangers concentric tube, shell and tube types, Condensers condenser coolers andsuperheater condensers for single vapour only, Evaporators single and multi effects, Absorbers for binary

systems without reactions, Distillation columns for binary mixtures along with tray hydraulics, dryers; Multi-

component Distillation Column Design.

Mechanical Design.:Storage tank,Supports. unfired pressure vessel subjected to internal and external pressure,

Tall vessel,


18/30

BOOKS

1 D. Q. Kern, Process Heat Transfer.

2 J. H. Perry, Chemical Engineers Handbook.

3 R. E. Treybal, Mass Transfer Operations

4 I.S.Code for Unfired Pressure: IS No. 2825 -1969 pressure vessel.5 B. E. Brownell & E M Young, Process Equipment Design

CH 603 PROCESS OPTIMIZATION (3:1:0)

UNIT-1

Introduction to process optimization; formulation of various process optimization problems and

their classification. Basic concepts of optimization-convex and concave functions, necessary and sufficientconditions for stationary points.

UNIT-2

Optimization of one dimensional functions, unconstrained multivariable optimization- direct search methods.

Bracketing methods: Exhaustive search method, Bounding phase method Region elimination methods: Interval

halving method, Fibonacci search method, Golden section search method. Point-Estimation method: Successive

quadratic estimation method. Indirect first order and second order method. Gradient-based methods: Newton-

Raphson method, Bisection method, Secant method, Cubic search method. Root-finding using optimization

techniques.

UNIT-3

Multivariable Optimization Algorithms: Optimality criteria, Unidirectional search, direct search

methods: Evolutionary optimization method, simplex search method, Powells conjugate direction method.

Gradient-based methods: Cauchys (steepest descent) method, Newtons method.

UNIT-4

Constrained Optimization Algorithms: Kuhn-Tucker conditions, Transformation methods:

Penalty function method, method of multipliers, Sensitivity analysis, Direct search for constraint

minimization: Variable elimination method, complex search method.

UNIT 5

Successive linear and quadratic programming, optimization of staged and discrete processes.

Specialized & Non-traditional Algorithms: Integer Programming: Penalty function method, Nontraditional

Optimization Algorithms

Books

1. Kalyanmoy Deb ,Optimization for engineering design, , Prentice Hall of India

2. T.F.Edgar and D.M.Himmelblau, optimization of chemical processes, Mc Graw Hill,


19/30

3. International editions, chemical engineering series, 1989.

4. G.S. Beveridge and R.S. Schechter, Optimization theory and practice, Mc Graw Hill,

Newyork, 1970.

5. Rekllitis, G.V., Ravindran, A., and Ragdell, K.M., Engineering Optimization- Methods

and Applications, John Wiley, New York, 1983.6. SS Rao, Optimization Theory and Applications

CH 604 CHEMICAL TECHNOLOGY II (3:1:0)

Introduction of CPT with reference to Indian resources, industries, trade and export potential, small scale

industries and rural development. Preparation of process flow diagrams, Instrumentation diagrams and Process

symbols. ; Introduction to the following industries lying emphasis on process flow sheet, material requirements,

process conditions, material of construction and design aspects.

UNIT 1

Chlor-alkali industry: Common salt, Caustic soda and Chlorine, Soda Ash, Hydrochloric acid.

UNIT 2Sulfur Industry: Sulfur and sulfuric acid,Oleum Phosphorus Industry: Phosphorus, Phosphoric acid and super

phosphates

UNIT 3

Nitrogen Industry: Ammonia, Nitric acid, Urea and other nitrogen fertilisers, Mixed fertilisers (SSP, TSP,

NPK ,KAP ,DAP, Nitrophosphate) Bio fertilizers.

Unit 4

Industrial Gases: Oxygen, Nitrogen, Hydrogen Inert gases, Syngas, Cement.

UNIT 5

Electrothermal industries, Aluminium, Magnesium, Litfium Titanium etc., Electro-chemical sources of energyand storage.

BOOKS

1 Dryden, C. E. Outlines of Chemical Technology (Edited and Revised by M.Gopal

Rao and Sittig .M) East West Press. ,New Delhi,3 rd Edition(1997).

2 Austin G. T Shreves Chemical Process Industries, 5th ed., McGraw Hill.(1984).3 Faith, W. L., Keyes, D. B. and Clark, R. L., Industrial Chemicals John Wiley.(1975).

4 Kirk and Othmer, "Encyclopaedia of Chemical Technology" Wiley (2004).

5 Pandey G.N & Shukla.S.D, Chemical Technology Vol - I Vikas publication.

CH 651 MASS TRANSFER LAB (0: 0:3)

1. Determination of diffusivity of acetone in air.

2. Determination of mass transfer coefficient in an agitated vessel.

3. Determination of mass transfer coefficient for steady state surface evaporation of water at different

temperature.

4. Determination of mass transfer coefficient in a wetted wall column.

5. Determination of T-x-y diagram for a binary batch distillation.

6. Verification ofRayleigh equation in a binary batch distillation process.

7. Verification of steam distillation equations.


20/30

8. Determination of ternary curve for the system acetic acid-water-carbon tetrachloride.

9. Determination of distribution coefficient of a solute in two immiscible liquids.

10. Solid-Liquid extraction Soxhlets experiment.

11. Liquid - liquid extraction in packed bed.

12. Determination of adsorption kinetics and isotherm at solid-liquid interface.

13. Determination of the rate of drying in a tray dryer.

14. Estimation of efficiency of the fluidized bed dryer

MA 651 CONM LAB (0: :3)

CH 651 SEMINAR (0:0 :6)

SEVENTH SEMESTER

OPEN ELECTIVE

ENERGY RESOURCES UTILIZATION & MANAGEMENT (3:1:0)

Unit I

Energy Scenario

Indian and global, energy crisis, Classification of various energy sources, Renewable and

Non-renewable energy sources, Remedial measures to some energy crisis.

Energy Conservation

Energy: Biogas plants and their operation, Biomass and its conversion routes to gaseous

and liquid fuels. Wind energy, its potential and generation by wind mills.

Unit II

Alternative Sources of Energy

Fuel cell ,Solar Energy : Photo thermal and photovoltaic conversion and utilization methods , solar

water heating , cooking , drying and its use for other industrial processes , solar cells their material andmode of operation . direct and indirect methods solar energy storage , sensible heat and latent heat

storage materials Solar ponds, Bio energy, biogas plants and their operation , biomass and its

conversion roots to gaseous and liquid fuels ,wind energy , its potential and generation by wind mills.

Unit III

Hydroelectric potential, its utilization & production, Geothermal energy its potential

Status and production, Nuclear energy: Status, nuclear raw materials, nuclear reactors

And other classification, Generation of Nuclear power, Nuclear installations in India andTheir capacity of generation, Limitations of nuclear energy, Reprocessing of spent nuclear

Fuel, Cogeneration of fuel and power, Energy from tidal and ocean thermal sources,

MHD systems.

Unit IV

Fossil and Processed Fuel

Coal its origin and formation, Coal analysis, Coal classification, Coal preparation, Coalwashing and coal blending, Coal carbonization, Treatment of coal gas and recovery of


21/30

chemical from coal tar, Coal gasification, liquid fuel synthesis from coal, CBM.

Unit V

Petroleum crude, Types of crude, emergence of petroleum products as energy, GaseousFuels: Natural gas, Water gas, producer gas, L.P.G., biogas, coke oven gas, blast

Furnace gas, LNG ,CNG,Gas hydrates ,GTL Technology (gas to liquid), Bio diesel.

Text Books

1. Brame J.S.S. and King J.G., Edward Arnold Fuel Solid, Liquid and Gases EdwardArnold (1967).

2. Sukhatme S.P, "Solar Energy - Principles of Thermal Collection and Storage",2nd Ed.,

Tata McGraw- Hill.,(1996).

CH 701 PROCESS MODELLING AND SIMULATION (3:1:0)

Unit I

Introduction to mathematical modeling; Advantages and limitations of models and applications of processmodels of stand-alone unit operations and unit processes; Classification of models Simple vs. rigorous, Lumpedparameter vs. distributed parameter; Steady state vs. dynamic, Transport phenomena based vs. Statistical;

Concept of degree of freedom analysis.

Unit II

Simple examples of process models; Models giving rise to nonlinear algebraic equation (NAE) systems, - steady

state models of flash vessels, equilibrium staged processes distillation columns, absorbers, strippers, CSTR, heat

exchangers, etc.; Review of solution procedures and available numerical software libraries.

Unit III

Steady state models giving rise to differential algebraic equation (DAE) systems; Rate based approaches for

staged processes; Modeling of differential contactors distributed parameter models of packed beds; Packed bedreactors; Modeling of reactive separation processes; Review of solution strategies for Differential Algebraic

Equations (DAEs), Partial Differential Equations (PDEs), and available numerical software libraries.

Unit IV

Unsteady state (time dependent) models and their applications; Simple dynamic models of Batch reactors,

Adsorption columns, Multistage separation systems; Model reduction through orthogonal collocation; Review ofsolution techniques and available numerical software libraries.

Unit V

Introduction to flow sheet simulation; Sequential modular approach; Equation oriented approach; artitioning andtearing; Recycle convergence methods; Review of thermodynamic procedures and physical property data banks.

Text Books

1. Luyben W.L., Process Modeling, Simulation, and Control for Chemical Engineering, Wiley.

2. M.M. Denn, Process Modelling, Wiley, New York, (1990).

3. Hussain Asghar, Chemical Process Simulation, Wiley Eastern Ltd., New Delhi, (1986)


22/30

4. C.D. Holland and A.I. Liapis, Computer Methods for Solving Dynamic Separation Problems, McGraw

Hill, (1983).

5. C.D. Holland, Fundamentals of Modelling Separation Processes, Prentice Hall, (1975)

6. S.M. Walas, Modelling with Differential Equations in Chemical Engineering, Butterworth, (1991)

CH 702 MATERIAL TECHNOLOGY (3:1:0)

Unit I

Introduction: Introduction to material science, Classification of engineering materials, Levels of

Structure, Structure-Property relationship in materials.

Crystal Geometry and Structure Determination: Geometry of crystals- the Bravais lattices, Crystal directions

and Planes- Miller indices, Structure determination-X ray diffraction- Braggs Law, the power method.

Unit II

Atomic Structure, Chemical Bonding And Structure Of Solids: Structure of atom, Periodic table,Crystal Imperfections: Point Imperfections, Line imperfections- edge and screw dislocations, Surface

imperfections.

Unit III

Phase Diagram And Phase Transformations: Phase rule, Single component systems, Binary Phase Diagrams,

Lever rule, Typical Phase diagrams for Magnesia-Alumina, Copper-Zinc, Iron-carbon system, Nucleation and

growth, Solidification, Allotropic transformation, Cooling curves for pure iron, Iron-carbon equilibrium diagram,

Isothermal transformations (TTT curves).

Deformation Of Materials- Fracture: Elastic deformation, Plastic deformation, Creep, Visco-elastic

deformation, Different types of fracture.

Unit IVHeat Treatment: Annealing, Normalizing, Hardening, Martempering, Austempering, Hardenability,

Quenching, Tempering, Carburising, Cyaniding, Nitriding, Flame hardening.

Corrosion And Prevention: Direct Corrosion, electro-chemical corrosion, Galvanic cells, High

temperature corrosion, Passivity, factor influencing corrosion rate, Control and of corrosion-modification of

corrosive environment, Inhibitors, Cathodic protection, protective coatings. Corrosion charts.

Unit V

Typical Engineering Materials: Ferrous metals, Non ferrous metals and alloys- Aluminum and its alloys,

Copper and its alloys, Lead and its alloys, Tin, Zinc and its alloys, Alloys for high temperature service, Ceramicmaterials- Structure of ceramic, Polymorphism, mechanical, electrical and thermal properties of ceramic phase.

Smart materials, biomaterials, nanomaterials.

Books:

1. Material Science and Processes Hajra Choudhary S. K., Indian Book Distributing Co., 1982.

2. Material Science and Engineering- A First Course, Raghavan V., 3rd Edition, Prentice Hall

of India Pvt. Ltd., New Delhi, 1996.

3. William D Callister, Material Science

4. Elements of Materials Science, Van Vlack, H.L., 2nd Edition, Addision-Wesly Publishing

Company, NY, 1964.


23/30

CH 703 PLANT DESIGN AND PROJECT ENGINEERING (3:1:0)

Unit I

Basic considerations in Chemical Engineering Piant Design. Project identification, preliminary teachno-

economic feasibility. Process design aspects-process selection, factors affecting. Importance of laboratory

development, pilot plant, scale-up methods, safety factor's, flow diagrams.

Unit II

Selection of process equipments-standard Vs special equipments, selection Criteria, specification sheet, Processauxiliaries - piping design, layout, process control and instrumentation, Process utilities-process water, boiierfeea

water, wasts treatment & disposal, Oil heating system, chilling plant., compressed air v accum.

Unit III

Interest-types & calculations.Cost estimation-factors involved in project cost estimation, total capital

investment, fixed capital and working capital, Methods if estimation of investment. Cost index and scaling for

equipment cost. Estimation of total product cost-factors involved.

Unit IV

Depreciation-types & methods of determination. Profitability - alternative investment and replacement methods,practical factors in alternative & replacement investment.

Unit V

Inventory control, scheduling a project using CPM/PERT. Project management. Optimum conditions-optimum

production rates in plant operations, optimum conditions in cyclic operations. Design reports. Plant location and

layout principles, factors affecting, use of scale methods, case studies.

BOOKS

1) Plant design and Economics for Chemical Engineers - Max S.Peters S.KIausD.Timmerhaus, Fourth

Edition, McGraw Hill (1991).

2) Chemical Engineering Plant Design - F.C.Vibrandt & C.E.Dryden, MuGraw Hill (1954) Note :Industrial visits and case studies are expected.

ELECTIVE-I

ADVANCE SEPARATION PROCESS(3:1:0)


24/30


25/30

James M. Douglas Conceptual Design of Chemical Process, McGraw Hill, New York,

1988.

Linnhoff, B. Townsend D.W., Boland D., Hewitt G.F., Thomas, B.E.A., Guy, A.R. andMarsland, R.H., A Users guide on process integration for the efficient use of energy,

Inst. Of Chemical Engineers, London (1982).

Smith, R., Chemical Process Design, McGraw Hill (1995).

INTERFACE AND SURFACE SCIENCES (3:1:0)

General introduction of colloids, interfaces, surfactants, and micellization. Intermolecular

forces, Van der Waals forces, Brownian motion and Brownian flocculation, Surface and

interfacial tension and surface free energy, Surface tension for curved interfaces, Surface

excess and Gibbs equation, Thermodynamics of interfaces, Thermodynamics of micelleformation, Electrical phenomena at interfaces(Electrokinetic phenomena, Electrical

double layer), Colloidal systems and colloidal stability, Emulsion and micro-emulsion.Application : General applications, Enhanced petroleum recovery, Novel fabrication of

nanostructured particles, Engineering surfaces and interfaces, Self-assembled &

nanostructured biomimetic interfaces. Measurement techniques of surface tension,zetapotential, particle size.

BOOKS

Hiemenz, P. C. and Rajagopalan, R., Principles of Colloid and Surface Chemistry, 3rd

Edition, Marcel Dekker, N.Y., 1997.M. J. Rosen, Surfactants and Interfacial Phenomena, Wiley-Interscience Publication,New York, 1978.

EIGHTH SEMESTER

ELECTIVE-II

1.HETEROGENEOUS CATALYSIS (3:1:0)

Basic Data and Principles of Design, Interpretation of Data from Laboratory Batch, CSTR & Tubular Flow

Reactors, Differential Reactor, Accuracy of Kinetic measurements, Thermodynamic Aspects of Chemical


26/30

Reactions, Catalyst Preparation Methods, Common Operations used During Catalyst Preparation and their

Significant Variables, Catalyst Characterization, Mechanism of Catalytic Reactions, Various Resistances in

Multiphase Reactions stablishing Global Rates in Various Situations, Design of Real Reactors Considering

Actual Concentration and Temperature Profile

2.ADVANCED PROCESS CONTROL(3:1:0)

Complex control system: Multiple loop control systems; Cascade control; Ratio control;

Feed forward control, Multivariable process control: Design of controllers for interactions, Loop interaction,

Decoupling of interacting loops. Tuning of feed back controllers Quarter Decay Ratio Response, Minimumerror Integral Criterion, IAE, ISE, ITAE, ITSE,Design strategies for common industrial processes such

distillation, heat exchangers,etc.Batch Process: Introduction to advanced control strategies, use of

microprocessors in process control.

BOOKS :

1. Industrial Instrumentation, Eckman. D.P,Wiley Eastern Ltd.

2. Process Instrumentation and Controls Handbook, Considine,D.N., McGraw Hill.3. Process System Analysis and Control, Coughanowr, D.R. and Koppel, L.B.,McGraw Hill.

4. Chemical Process Control- An introduction theory and practice, Stephanopolous, G.,

Prentice Hall of India.

5. Principals and Practice of Automatic Process Control, Carlos A. Smith and Armando B.Corripio, John Willy & Sons, 2nd Ed.

3.MOLECULAR SIMULATION (3:1:0)

Introduction, ensembles, Fluctuations, Boltzmann statistics Gases, classical statistical mechanics, distributionfunctions. Imperfect gases, perturbation theories of liquids Monte Carlo methods, sampling, Markov chains,

Monte Carlo simulation, Molecular dynamics, ensemble averaging, error estimation, periodic boundaries

Equilibrium molecular dynamics simulations of continuous potentials, integration algorithms Modeling of

molecules, including hard potentials, soft potentials, and multiatomic models, Free energy calculations

Phase equilibrium calculations, Advanced molecular dynamic methods, Complex Fluids and biased-sampling

techniques Introduction to commercial simulation software

BOOKS:

1. Understanding Molecular Simulation by Frenkel and Smit, Academic Press, SanDiego, CA, 1996.

2. Statistical Mechanics by D. A. McQuarrie, Harper and Row, 1976.3. Computer Simulation of Liquids by Allen and Tildesley, Oxford University Press, 1987.

4. The Theory of Simple Fluids by Hansen and McDonald, Academic Press, 2nd edition, 1986.5. The Theory of Molecular Fluids by Gray and Gubbins, Oxford University Press, 1985

6.

ELECTIVE-III

1.NANOTECHNOLOGY (3:1:0)

Introduction to Nanotechnology History of nano-revolution, nano scale materialsand their applications, Carbon

nano tubes, organic and inorganic nano structures.Future of the nanotechnology. Materials used in


27/30

Nanotechnology An overview of the physical (mechanical, electrical) and chemical properties of different

classes of solid materials such asmetals, semiconductors, insulators and polymers. Examples of size effects of

properties observed in thin films, colloids and nanocrystals.Conventional Fabrication Techniques Top down

and bottom up process, techniques used in conventional micro fabrication including thin film deposition

(e.g.CVD, PVD(, lithography, chemical etching and electrodeposition.Analytical Techniques Analyticaltechniques such as Electron Microscopy, Electron and X-ray Diffraction, Ellipsometry, Photoelectron, Optical

and Ion spectroscopy and Probe Microscopy. Applications Examples of applications in Micro and Nanotechnology including, Micro fluidics, Micro Electron Mechanical Systems (MEMS) membrane technology, and

catalyst and coatings

BOOKS:

1. M. Wilson, K. K. G. Smith, M. Simmons and B, Raguse; Nanotechnology, Chapman

& Hall/CRC press 2002

2. M. Meyyappan; Carbon Nanotubes, Science and application; CRC Press, 2005

3. Alexei Nabok; Organic and Inorganic Nanostructures; Publisher Artech House,

London, 2005

4. H. Watarai, N. Teramae and T Sawada; Interfacial Nanochemistry; Kluwer

2.STANDARDIZATION IN CHEMICAL ENGINEERING(3:1:0)

Utility of standard, Standards for material consumption, Standards for equipment, Standards for manual

work, Standards for financial returns, Qualitative standards.

Approach to standardization, Objective of the system, Idealized model for national standard system,case studies of national standards systems. Objective of Inspection and Quality Control, Function of

inspection, Elements of quality, Objective of statistical quality control, Function of statistical quality

control, Control charts, Concept of sampling, Concept of zero defects, Study of different standardsfollowed by the chemical industry, Role of technology transfer in standardization; Modern trends in

standardization.

BOOKS

1. Ali Mansoor & Dalela S., A text Book of Industrial Engineering. 2nd Ed., Standard Publishers,Delhi (1972) pp. 264 - 334 Phone: 011 23285798: Agrawal & Co. Phone 011 23916376.

3.INDUSTRIAL SAFETY & HAZARD MANAGEMENT(3:1:0)

Unit IIndustrial safety, Industrial hygiene and safety aspects related to toxicity, noise, pressure, temperature,

vibrations, radiation etc. Explosions including dust , vapor, cloud and mist explosion.

Unit II

Elements of safety, safety aspects related to site, plant layout, process development and design stages,

identification of hazards and its estimation, risk, risk analysis and assessment methods; fault free

method,event free method, scope of risk assessment, controlling toxic chemicals and flammable materials.


28/30

Unit III

Toxic substances and degree of toxicity, its estimation, their entry routes into human system, their

doses and responses, control techniques for toxic substances exposure, use of respirators, ventilationsystems.

Unit IV

Prevention of losses, pressure relief, provision for fire fighting, release of hazardous materials fromtanks,

pipes through holes and cracks , relief systems : types and location of reliefs.

Unit V

Handling, transportation and storage of of flammable liquids, gases, and toxic materials and wastes,

regulation and legislation, government role, risk management routines, emergency preparedness,

disaster planning and management.

BOOKS:1. H. H. Tawcatt & W S Wood, Safety and Accident Prevention in Chemical Operations.

2. R. V. Betrabet and T. P. S. Rajan in CHEMTECH-I, Safety in Chemical Industry, Chemical Engineering

3. Wells, Safety in Process Plant Design.

4. Less, P. Frank, Loss Prevention in Process Industries.

5. J. Lolb & S. Roy Sterm, Product Safety and Liability.

CH 801 ENERGY RESOURCES AND MANAGEMENT(3:1:0)

UNIT 1

Renewable energy sources. Prospects of Renewable energy sources; Solar energy fundamentals and application;

Geothermal energy: Introduction, Utilization of Geothermal energy, Geothermal energy resources, geothermal

gradient, Different types of Geothermal Electric power plant and their operations for Geothermal Energy

systems in India;

UNIT II

Wind energy: Fundamentals and application, Basic principles of Wind Energy Conversion, Wind Energy

conversion system, Performance of wind machines, Electric generation for wind; Biomass Energy Resources:Introduction, Biomass Conversion Process. Biogas from plant wastes, communities bio-gas plants. Biochemical

conversion, Fermentation, liquid fuels for biomass; Urban Waste: A source of Energy. Urban solid waste, waste

incineration process. Environmental consideration, Fluidized bed combustion boilers for burning solid waste andfossil fuels; Energy from the oceans:

UNIT III


29/30

Introduction Ocean Energy conversion Technologies. Types of Ocean Thermal Electric Power Generation

system and their operation. Tidal power plant; Hydro Energy: Introduction, types hyd ro-electric plants and

energy conversion scheme, Impulse turbine and Reaction turbine.

UNIT IV

Solid fuels: Coal origin, Chemical composition, Calorific value, Classifications, Characteristics and

Distribution of Indian coals, Storage and spontaneous combustion of coal, Coal washing and blending,Petographic constituents of coal, Carbonization of coal, Manufacture and properties of metallurgical coke,

Recovery of byproducts;

Liquid fuels: Origin and composition of crude oil, Crude oil distillation and its products with special reference

to gasoline, kerosene and diesel oil, Cracking and reforming, Coal tar distillation products, Shale oil; Testing of

oils, viscosity, flash point, pour point, aniline point, carbon residue, Diesel index, octane and cetane number

,moisture content.

UNIT V

Gaseous fuels: Natural gas, Coal gas, Coke oven and blast furnace gas, Manufacture of water gas and producer

gas, Carbureted water gas; Synthetic fuels: Hydrogenation of coal, Fischer Tropsch synthesis; Introduction to

nuclear fuels and nuclear reactors, fuels, Moderators and structural materials, Combustion: Combustion of solid

fuels, Pulverized coal, Calculation of volumes and weights of air necessary for combustion of fuels, Gas

analysis.

Books:

1. S. Rao and Dr. B.B. Parulekar, Energy Technology, Non convential, Renewable and

Conventional, Khanna Publishers.2. G.D. Rai, Non-conventional Energy Sources, Khanna Publishers.

3. S. Sarkar, Fuels and Combustion. Sangam books Ltd (Imported)

4. Himus, Elements of Fuel technology.

5. J. Brame and King, Fuels: Solid, liquid and gaseous fuels, Kessinger Publishing, LLC, 2007.

6. O. P. Gupta, Elements of Fuels, Furnaces and Refractories.

CH 851 ENERGY LAB & ENVIRONMENTAL LAB (0:0:3)

1. 1 Determination of composting of the supplied sample of Coal by Proximate Analysis.

3. Determination of Caking Index of the supplied sample of Coal by Grey campredon method.

4. To determine the washability characteristics of the supplied sample of Coal using Float and Sink

test.

5. To find the effect of temperature on viscosity of the supplied samples of liquid fuel using Red wood

viscometer.

6. To find the effect of temperature on viscosity of the supplied samples of lubricating oil using

Englers viscometer.7. To find the Flash and Fire point of the supplied samples of liquid fuel using

(i.) Penslery Martein closed cup apparatus

(ii.) Abel open cup apparatus.

8. To find the Aniline point of the supplied samples of liquid fuels using Aniline point apparatus and

hence find out the Diesel Index Number of the Diesel oil.

9. To find the Carbon Residue of the supplied sample of lubricating oil / oil mixture using Conradson

apparatus.


30/30

10. To find the moisture content of the supplied samples of liquid fuel / Crude oil using Dean and Stark

apparatus.

11. To find the Pour point and Solidfication point of the supplied samples of liquid fuels.

12. To find the Calorific value of LPG using

(i.) Boy.s Gas calorimeter

(ii.) Junker s Gas calorimeter.

13. To find the composition of the gas using Gas Chromatograph and hence determine the percent of

excess air used for combustion of the fuel used.

14. To determine the ultimate analysis of the supplied sample of coal and hence find the theoretical

GCU of given coal.

15. To determine the Swelling Index of the supplied sample of coal and ascertain the agglomerating

characteristics of the coal sample.

16. To determine the Gross calorific value of the supplied sample of coal using Bomb Calorimeter (on

ash free basis).

17. To determine the Smoke Point of kerosene oil using Smoke Point Apparatus

Documents

ChE Syllabus