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ChemInform 2010, 41, issue 19 © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.cheminform.wiley-vch.de Azetidine derivatives R 0045 DOI: 10.1002/chin.201019088 Stereoselective Synthesis of trans-β-Lactams by Palladium-Catalyzed Carbonyla- tion of Vinyl Aziridines. — The π-allyl Pd intermediates undergo isomerization prior to β-lactam formation, and thus allow a significant control of the product distribution by carefully adjusting the reaction parameters. — (FONTANA, F.; TRON, G. C.; BARBERO, N.; FERRINI, S.; THOMAS, S. P.; AGGARWAL*, V. K.; Chem. Commun. (Cambridge) 46 (2010) 2, 267-269; Sch. Chem., Univ. Bristol, Cantock's Close, Bristol BS8 1TS, UK; Eng.) — D. Singer 19- 088

ChemInform Abstract: Stereoselective Synthesis of trans-β-Lactams by Palladium-Catalyzed Carbonylation of Vinyl Aziridines

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Page 1: ChemInform Abstract: Stereoselective Synthesis of trans-β-Lactams by Palladium-Catalyzed Carbonylation of Vinyl Aziridines

www.cheminform.wiley-vch.de

Azetidine derivativesR 0045 DOI: 10.1002/chin.201019088

Stereoselective Synthesis of trans-β-Lactams by Palladium-Catalyzed Carbonyla-tion of Vinyl Aziridines. — The π-allyl Pd intermediates undergo isomerization prior to β-lactam formation, and thus allow a significant control of the product distribution by carefully adjusting the reaction parameters. — (FONTANA, F.; TRON, G. C.; BARBERO, N.; FERRINI, S.; THOMAS, S. P.; AGGARWAL*, V. K.; Chem. Commun. (Cambridge) 46 (2010) 2, 267-269; Sch. Chem., Univ. Bristol, Cantock's Close, Bristol BS8 1TS, UK; Eng.) — D. Singer

19- 088

ChemInform 2010, 41, issue 19 © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Page 2: ChemInform Abstract: Stereoselective Synthesis of trans-β-Lactams by Palladium-Catalyzed Carbonylation of Vinyl Aziridines

www.cheminform.wiley-vch.de

ChemInform 2010, 41, issue 19 © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

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