2001 furan derivatives

furan derivativesR 0060

29 - 116Cobaloxime-Mediated Intramolecular Radical Addition onto OximeFunctions in the Electrolysis Media: Formation of Mannich BaseAnalogues. — Electrolysis of α-bromoacetals under the conditions showngenerates carbon radicals which cyclize onto the O-alkyloxime moiety to affordMannich base analogues (II), (IV), and (VI). In some cases, the cyclizationproceeds stereoselectively. — (INOKUCHI, TSUTOMU; KAWAFUCHI,HIROYUKI; Synlett (2001) 3, 421-423; Dep. Biosci. Biotechnol., Fac. Eng.,Okayama Univ., Okayama 700, Japan; EN)

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