Upload
others
View
8
Download
1
Embed Size (px)
Citation preview
1
DEGRADATION AND STABILIZATION OF POLYOLEFINSتخریب و پایدارسازی پلی اولفین ها
O. Dadgari, M. Jamali, A. Bashir, R. Bagheri
Presenter: Omid Dadgari
Paper Code: imbpa15-00180005
March 2016
Parsa Polymer Sharif
Leading manufacturer of advanced polymeric compounds in Iran
15 years of academic research experience prior to its establishment
Active professional R&D team in continuous collaboration with academic atmospheres
Innovative and Knowledge-based
Wide variety of products
2
Contents
3
Polymer degradation and oxidation
Stabilization strategies and mechanisms
Thermal stabilization
Light stabilization
UV radiation and measuring its effects on polymer degradation
Thermal degradation
• Happens in the absence of Oxygen
• Most polymers are thermally stable. So why degradation?
• Nature of long chains in polymers
• Structural defects
4
IcosaneMP = 38 °C BP = 343.1 °C
Thermal degradation mechanisms
• Reactions including chain scission and radical formation
• Reactions including molecular rearrangements
5
Oxidative Degradation
• A complex radical reaction
Termination
• Neutral products formation (may not be happened)
Propagation
• An autacceleratingchain reaction which reproduce its initiator
Initiation
• Free radical formation by light or heat
6
Initiation reaction
Light
• Chromophores: Light absorbing groups
Thermal
• Polymer structure, an important parameter in controlling the relative stability
7
Oxidation chain reaction in polymers
8
ROOH RH
R. ROO.
O2RH
ROO. + .OH
Heat
Light
Metal ions
chain scission and
carbonyl products
hν
Δ
Bolland-Gee Mechanism
Strategies in stabilizing polymers against oxidation
ROOH RH
R. ROO.
O2RH
ROO. + .OH
Heat
Light
Metal ions
chain scission and
carbonyl products
hν
Δ
HALSHindered PhenolsAromatic Amines
Quinones
ThioethersTrialkyl Phosphites
BenzophenonesBenzotriazoles
Nickel Quenchers
9
Primary antioxidants
Hindered phenols
• Mechanism: CB-A
• Wide range of temperatures
• Improvement in long-term thermal stability
• Non-regenerating mechanism:
10
Secondary antioxidants
Phosphites
• Mechanism: PD
• Process stabilizer
• Stable to hydrolyze
• Stabilization byproducts are colorless
Thioethers
• Mechanism: PD
• Works in high temperatures
• Designed to protect polymers from aging in high temperatures
11
UV Absorbers
Hydroxy Phenyl
Benzophenone
BP
Hydroxy Phenyl
Benzotriazolw
BTZ
12
Nickel Quenchers
• Quenchers transform the radiant energy absorbed by chromophores in the polymer and prevent degradation.
• Energy absorbed by quenchers can be dissipated in the form of heat or fluorescent /phosphorescent radiation.
13
Hindered Amine Light Stabilizers
• Strategy: Free radical scavenger
• Edge of polymer stabilization science
• Cyclic structure:
2,2,6,6-tetramethyl piperidine
Denisoff Cycle
14
Different generations of HALS
ChimassorbTuinuvin
Cyassorb Hostavin Lowilite
• Monomeric HALS
1st generation
• Polymeric HALS
2nd generation• Non-
reactive HALS
3rd generation
• Synergistic blend of HALS & UVA
4th generation
15
Solar irradiance
Solar irradiance is the power per unit area produced by the Sun in theform of electromagnetic radiation
Florida
Arizona
Bandar Abbas
Shiraz
16
Outdoor Exposure
17
Accelerated Weathering Testing
Fluorescent UV lamps
18
Xenon Arc
What properties to measure?
Mechanical Properties
• Tensile Strength
• Elongation
• Impact Strength
Aesthetics
• Yellow Index
• Chalking
Oxidation
• Carbonyl and Hydroxyl Absorption
• Hydro-peroxide evaluation
EnEnergy for n% reduction in properties
TnTime for n% reduction in properties
19