Diagrama de Solubilidad Actualiz. 290915

7/24/2019 Diagrama de Solubilidad Actualiz. 290915

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273.15

H2S(a)= HS(-a) + H(+

T T 1/T deltaH deltaS deltaG K1

C K kJ J/K kJ

0 273.15 0.0036609921 31.076 -28.823 38.949 3.557E-008

5 278.15 0.0035951825 28.984 -36.413 39.113 4.511E-00810 283.15 0.003531697 27.131 -43.019 39.312 5.589E-008

15 288.15 0.0034704147 25.458 -48.876 39.542 6.784E-008

20 293.15 0.0034112229 23.922 -54.160 39.799 8.087E-008

25 298.15 0.0033540164 22.492 -59.000 40.082 9.487E-008

30 303.15 0.003298697 21.141 -63.494 40.389 1.097E-007

35 308.15 0.0032451728 19.849 -67.719 40.717 1.252E-007

40 313.15 0.0031933578 18.603 -71.731 41.066 1.411E-007

45 318.15 0.0031431715 17.391 -75.572 41.434 1.573E-007

50 323.15 0.0030945381 16.205 -79.269 41.821 1.735E-007

55 328.15 0.0030473869 15.042 -82.841 42.226 1.896E-00760 333.15 0.0030016509 13.899 -86.297 42.649 2.053E-007

65 338.15 0.0029572675 12.770 -89.663 43.089 2.205E-007

70 343.15 0.0029141775 11.647 -92.958 43.546 2.349E-007

75 348.15 0.0028723251 10.529 -96.194 44.019 2.484E-007

80 353.15 0.0028316579 9.412 -99.380 44.508 2.608E-007

85 358.15 0.0027921262 8.293 -102.524 45.012 2.720E-007

90 363.15 0.0027536831 7.171 -105.636 45.533 2.819E-007

95 368.15 0.0027162841 6.043 -108.723 46.069 2.904E-007

100 373.15 0.0026798874 4.905 -111.791 46.620 2.975E-007

HS(-a) = S(-2a) + H(+


C K kJ J/K kJ

0 273.15 0.0036609921 48.631 -83.707 71.496 2.122E-014

5 278.15 0.0035951825 49.081 -82.074 71.910 3.124E-014

10 283.15 0.003531697 49.334 -81.171 72.318 4.549E-014

15 288.15 0.0034704147 49.421 -80.864 72.722 6.547E-014

20 293.15 0.0034112229 49.370 -81.039 73.127 9.308E-014

25 298.15 0.0033540164 49.204 -81.602 73.533 1.307E-013

30 303.15 0.003298697 48.941 -82.476 73.944 1.811E-013

35 308.15 0.0032451728 48.598 -83.599 74.359 2.480E-013

40 313.15 0.0031933578 48.187 -84.921 74.780 3.353E-013

45 318.15 0.0031431715 47.718 -86.405 75.208 4.478E-013

50 323.15 0.0030945381 47.200 -88.022 75.644 5.911E-013

55 328.15 0.0030473869 46.636 -89.753 76.089 7.714E-013

60 333.15 0.0030016509 46.030 -91.587 76.542 9.954E-013


2/26

65 338.15 0.0029572675 45.389 -93.496 77.004 1.270E-012

70 343.15 0.0029141775 44.721 -95.457 77.477 1.605E-012

75 348.15 0.0028723251 44.030 -97.456 77.959 2.006E-012

80 353.15 0.0028316579 43.319 -99.482 78.451 2.484E-012

85 358.15 0.0027921262 42.593 -101.523 78.954 3.047E-012

90 363.15 0.0027536831 41.855 -103.570 79.467 3.705E-012

95 368.15 0.0027162841 41.109 -105.612 79.990 4.465E-012100 373.15 0.0026798874 40.357 -107.641 80.523 5.336E-012

H2CO3(a) = HCO3(-a) +

T T 1/T deltaH deltaS deltaG K1C K kJ J/K kJ

0 273.15 0.0036609921 11.234 -83.931 34.159 2.93E-007

5 278.15 0.0035951825 10.816 -85.448 34.583 3.20E-007

10 283.15 0.003531697 10.480 -86.643 35.013 3.47E-007

15 288.15 0.0034704147 10.209 -87.593 35.449 3.74E-007

20 293.15 0.0034112229 9.986 -88.360 35.889 4.02E-007

25 298.15 0.0033540164 9.799 -88.994 36.332 4.31E-007

30 303.15 0.003298697 9.637 -89.534 36.779 4.59E-007

35 308.15 0.0032451728 9.491 -90.011 37.228 4.89E-007

40 313.15 0.0031933578 9.356 -90.446 37.679 5.18E-007

45 318.15 0.0031431715 9.227 -90.855 38.132 5.48E-007

50 323.15 0.0030945381 9.101 -91.246 38.587 5.78E-007

55 328.15 0.0030473869 8.979 -91.622 39.044 6.09E-007

60 333.15 0.0030016509 8.860 -91.982 39.504 6.39E-007

65 338.15 0.0029572675 8.740 -92.337 39.964 6.70E-007

70 343.15 0.0029141775 8.617 -92.699 40.427 7.01E-007

75 348.15 0.0028723251 8.489 -93.069 40.891 7.32E-007

80 353.15 0.0028316579 8.356 -93.450 41.358 7.63E-007

85 358.15 0.0027921262 8.215 -93.846 41.826 7.93E-007

90 363.15 0.0027536831 8.066 -94.260 42.296 8.24E-007

95 368.15 0.0027162841 7.907 -94.694 42.768 8.54E-007

100 373.15 0.0026798874 7.737 -95.151 43.243 8.83E-007

HCO3(-a) = CO3(-2a) +


C K kJ J/K kJ


3/26

0 273.15 0.0036609921 22.535 -120.902 55.559 2.369E-011

5 278.15 0.0035951825 20.630 -127.812 56.181 2.810E-011

10 283.15 0.003531697 18.936 -133.849 56.836 3.268E-011

15 288.15 0.0034704147 17.407 -139.202 57.519 3.736E-011

20 293.15 0.0034112229 16.005 -144.027 58.227 4.208E-011

25

298.15 0.0033540164 14.698 -148.448 58.958 4.676E-011

30 303.15 0.003298697 13.461 -152.564 59.711 5.135E-011

35 308.15 0.0032451728 12.273 -156.451 60.483 5.579E-011

40 313.15 0.0031933578 11.120 -160.164 61.275 6.001E-011

45 318.15 0.0031431715 9.990 -163.743 62.085 6.396E-011

50 323.15 0.0030945381 8.879 -167.209 62.912 6.759E-011

55 328.15 0.0030473869 7.783 -170.573 63.757 7.086E-011

60 333.15 0.0030016509 6.706 -173.832 64.618 7.374E-011

65 338.15 0.0029572675 5.636 -177.020 65.495 7.621E-011

70 343.15 0.0029141775 4.566 -180.161 66.388 7.825E-011

75 348.15 0.0028723251 3.494 -183.262 67.297 7.986E-011

80 353.15 0.0028316579 2.418 -186.332 68.221 8.102E-011

85 358.15 0.0027921262 1.334 -189.377 69.160 8.175E-011

90 363.15 0.0027536831 0.242 -192.407 70.114 8.205E-011

95 368.15 0.0027162841 -0.863 -195.428 71.084 8.194E-011

100 373.15 0.0026798874 -1.982 -198.447 72.069 8.143E-011


4/26

)

Log(K) LogK estimada ESTIMCIO!

B' A'

-7.4488773 -7.338 -921.1241253267 -3.9655764753

-7.3456941 -7.277 40.1620113227 0.1259522448-7.2526825 -7.219 "#$%&13$13'$ 0.0544100317

-7.1685322 -7.162 526.0238139061 19

-7.0922044 -7.108 1.5572680134 0.0562485794

-7.0228634 -7.055

-6.959824 -7.004

-6.902521 -6.955

-6.8504802 -6.907

-6.8032963 -6.861 42.2264081009

-6.7606173 -6.816

-6.7221311 -6.773-6.6875549 -6.730

-6.6566332 -6.690

-6.6291467 -6.650

-6.6048991 -6.611

-6.5837123 -6.574

-6.5654251 -6.537

-6.549891 -6.502

-6.5369771 -6.468

-6.5265629 -6.434

)


B' A'

-13.673 -13.645 -2460.101020793 -4.6381305902

-13.505 -13.48315.0749508865 0.047276614

-13.342 -13.326 "#$$$2'"%&2 0.020422995

-13.184 -13.176 26631.404470126 19

-13.031 -13.030 11.1079248096 0.0079248757

-12.884 -12.889

-12.742 -12.753

-12.606 -12.622

-12.475 -12.494

-12.349 -12.371

-12.228 -12.251

-12.113 -12.135

-12.002 -12.022


5/26

-11.896 -11.913

-11.795 -11.807

-11.698 -11.704

-11.605 -11.604

-11.516 -11.507

-11.431 -11.412

-11.350 -11.320-11.273 -11.231

(+a)

Log(K) LogK estimada ESTIMCIO!B' A'

-6.533 -6.519 -484.9748040838 -4.7433399795

-6.495 -6.487 4.7458786997 0.0148835692

-6.460 -6.456 "#$$131$ 0.0064295438

-6.427 -6.426 10442.5144482 19

-6.395 -6.398 0.4316834526 0.0007854416

-6.366 -6.370

-6.338 -6.343

-6.311 -6.317

-6.285 -6.292

-6.261 -6.268

-6.238 -6.244

-6.216 -6.221

-6.194 -6.199

-6.174 -6.178

-6.154 -6.157

-6.136 -6.136

-6.118 -6.117

-6.101 -6.097

-6.084 -6.079

-6.069 -6.061

-6.054 -6.043

(+a)


B' A'


6/26

-10.625 -10.523 -530.4797638709 -8.5804263298

-10.551 -10.488 37.504278406 0.117617318

-10.486 -10.454 "#$132%%' 0.0508094318

-10.428 -10.421 200.0672558535 19

-10.376 -10.390 0.5164932999 0.0490503689

-10.330

-10.360-10.289 -10.330

-10.253 -10.302

-10.222 -10.274

-10.194 -10.248

-10.170 -10.222

-10.150 -10.197

-10.132 -10.173

-10.118 -10.149

-10.106 -10.126

-10.098 -10.104

-10.091 -10.083

-10.088 -10.062

-10.086 -10.041

-10.087 -10.021

-10.089 -10.002


7/26

dH (kJ/mol) dS (J/(mol*K)) d (kJ/mol) 273.15

H2S -39.544 122.807 -75.545 T

HS- -16.108 67.000 -36.084 273.15

S2- 33.095 -14.602 37.449 278.15

H+ 0.000 0.000 0.000 283.15

dS (J/(mol*K)) -55.807 288.15

d (kJ/mol) 39.460 293.15298.15

303.15

308.15

313.15

318.15

323.15

328.15

333.15

338.15

343.15348.15

353.15

358.15

363.15

368.15

373.15

!" 5

T= 2'#1&

K1= E-"

K2= 3#2$E-1

*E,OMI!!CI

H+. H

1.00E#00 0 5.28E-08 1.00E#00

1.00E-01 1 5.28E-07 1.00E#00

1.00E-02 2 5.28E-06 1.00E#00

1.00E-03 3 5.28E-05 1.00E#00

1.00E-04 4 5.28E-04 9.99E-01

1.00E-05 5 5.25E-03 9.95E-01

1.00E-06 6 5.02E-02 9.50E-01

1.00E-07 7 3.46E-01 6.54E-01

1.00E-08 8 8.41E-01 1.59E-01

1.00E-09 9 9.81E-01 1.86E-02

1.00E-10 10 9.98E-01 1.89E-03

HS-.0S2-

H2S.0S2-


8/26

1.00E-11 11 9.97E-01 1.89E-04

1.00E-12 12 9.68E-01 1.83E-05

1.00E-13 13 7.52E-01 1.42E-06

1.00E-14 14 2.33E-01 4.41E-08

1.00E-15 15 2.95E-02 5.58E-10

1.00E-16 16 3.03E-03 5.73E-12

1.00E-17 17 3.04E-04 5.75E-141.00E-18 18 3.04E-05 5.75E-16

T &

K1 3#2%E-"'K2 3#2&E-11

*E,OMI!!CI

H+. H

1.00E#00 0 3.26E-07 1.00E#00

1.00E-01 1 3.26E-06 1.00E#00

1.00E-02 2 3.26E-05 1.00E#00

1.00E-03 3 3.26E-04 1.00E#00

1.00E-04 4 3.25E-03 9.97E-01

1.00E-05 5 3.16E-02 9.68E-01

1.00E-06 6 2.46E-01 7.54E-01

1.00E-07 7 7.65E-01 2.35E-01

1.00E-08 8 9.67E-01 2.97E-02

1.00E-09 9 9.66E-01 2.96E-03

1.00E-10 10 7.54E-01 2.31E-04

1.00E-11 11 2.35E-01 7.21E-06

1.00E-12 12 2.98E-02 9.15E-08

1.00E-13 13 3.06E-03 9.40E-10

1.00E-14 14 3.07E-04 9.43E-12

1.00E-15 15 3.07E-05 9.43E-14

1.00E-16 16 3.07E-06 9.43E-16

1.00E-17 17 3.07E-07 9.43E-18

1.00E-18 18 3.07E-08 9.43E-20

T 2&

K1 #2'E-"'

K2 #3'E-11

HCO3(-a).0CO32-

H2CO3(a).0CO32-


9/26

*E,OMI!!CI

H+. H

1.00E#00 0 4.27E-07 1.00E#00

1.00E-01 1 4.27E-06 1.00E#00

1.00E-02 2 4.27E-05 1.00E#00

1.00E-03 3 4.26E-04 1.00E#001.00E-04 4 4.25E-03 9.96E-01

1.00E-05 5 4.09E-02 9.59E-01

1.00E-06 6 2.99E-01 7.01E-01

1.00E-07 7 8.10E-01 1.90E-01

1.00E-08 8 9.73E-01 2.28E-02

1.00E-09 9 9.56E-01 2.24E-03

1.00E-10 10 6.96E-01 1.63E-04

1.00E-11 11 1.86E-01 4.37E-06

1.00E-12 12 2.24E-02 5.25E-08

1.00E-13 13 2.28E-03 5.35E-10

1.00E-14 14 2.29E-04 5.36E-12

1.00E-15 15 2.29E-05 5.37E-14

1.00E-16 16 2.29E-06 5.37E-16

1.00E-17 17 2.29E-07 5.37E-18

1.00E-18 18 2.29E-08 5.37E-20

HCO3(-a).0CO32-

H2CO3(a).0CO32-


10/26

1/T deltaG LogK

0.003661 38.065 -'#2'%&2231

0.003595 38.344 -'#2"$11'$2'%

0.003532 38.623 -'#1333&13'2

0.003470 38.902 -'#"%"213&

0.003411 39.181 -%#$$&'2130.003354 39.460 -%#$212$$2$&

0.003299 39.739 -%#&&2'&&&

0.003245 40.018 -%#'$1""2

0.003193 40.297 -%#'2$&%1$33

0.003143 40.576 -%#%%$%%'1'

0.003095 40.855 -%#%11%2&$"%

0.003047 41.135 -%#&&&3&33'

0.003002 41.414 -%#&""''""3$1

0.002957 41.693 -%#'""1'&

0.002914 41.972 -%#3$%3'&2130.002872 42.251 -%#3%2%'1$1

0.002832 42.530 -%#2$'$2&$&%

0.002792 42.809 -%#2&"'13%"%2

0.002754 43.088 -%#2"33''%%

0.002716 43.367 -%#1%"2""1'3&

0.002680 43.646 -%#11%'%2'""'

EM

LOG(H2S./0S2-)

1.74E-21 -1.03E#01 -3.00E#00

1.74E-19 -9.28E#00 -3.00E#00

1.74E-17 -8.28E#00 -3.00E#00

1.74E-15 -7.28E#00 -3.00E#00

1.74E-13 -6.28E#00 -3.00E#00

1.73E-11 -5.28E#00 -3.00E#00

1.65E-09 -4.30E#00 -3.02E#00

1.14E-07 -3.46E#00 -3.18E#00

2.77E-06 -3.08E#00 -3.80E#00

3.23E-05 -3.01E#00 -4.73E#00

3.28E-04 -3.00E#00 -5.72E#00

S2-.0S2- LOG(HS-./0S2-)


11/26

3.28E-03 -3.00E#00 -6.72E#00

3.19E-02 -3.01E#00 -7.74E#00

2.48E-01 -3.12E#00 -8.85E#00

7.67E-01 -3.63E#00 -1.04E#01

9.71E-01 -4.53E#00 -1.23E#01

9.97E-01 -5.52E#00 -1.42E#01

1.00E#00 -6.52E#00 -1.62E#011.00E#00 -7.52E#00 -1.82E#01

EM

LOG(HCO3(-a)./0CO32-) LOG(H2CO3(a)./0CO32-)

1.06E-17 -6.49E#00 -1.42E-07

1.06E-15 -5.49E#00 -1.42E-06

1.06E-13 -4.49E#00 -1.42E-05

1.06E-11 -3.49E#00 -1.42E-04

1.06E-09 -2.49E#00 -1.41E-03

1.03E-07 -1.50E#00 -1.39E-02

8.00E-06 -6.09E-01 -1.23E-01

2.49E-04 -1.16E-01 -6.29E-01

3.15E-03 -1.45E-02 -1.53E#00

3.14E-02 -1.52E-02 -2.53E#00

2.45E-01 -1.22E-01 -3.64E#00

7.65E-01 -6.29E-01 -5.14E#00

9.70E-01 -1.53E#00 -7.04E#00

9.97E-01 -2.51E#00 -9.03E#00

1.00E#00 -3.51E#00 -1.10E#01

1.00E#00 -4.51E#00 -1.30E#01

1.00E#00 -5.51E#00 -1.50E#01

1.00E#00 -6.51E#00 -1.70E#01

1.00E#00 -7.51E#00 -1.90E#01

CO3(-2a).0CO32-


12/26

EM

LOG(HCO3(-a)./0CO32-) LOG(H2CO3(a)./0CO32-)

1.86E-17 -6.37E#00 -1.85E-07

1.86E-15 -5.37E#00 -1.85E-06

1.86E-13 -4.37E#00 -1.85E-05

1.86E-11 -3.37E#00 -1.85E-041.86E-09 -2.37E#00 -1.85E-03

1.79E-07 -1.39E#00 -1.81E-02

1.31E-05 -5.24E-01 -1.54E-01

3.54E-04 -9.16E-02 -7.22E-01

4.25E-03 -1.19E-02 -1.64E#00

4.18E-02 -1.95E-02 -2.65E#00

3.04E-01 -1.57E-01 -3.79E#00

8.14E-01 -7.30E-01 -5.36E#00

9.78E-01 -1.65E#00 -7.28E#00

9.98E-01 -2.64E#00 -9.27E#00

1.00E#00 -3.64E#00 -1.13E#01

1.00E#00 -4.64E#00 -1.33E#01

1.00E#00 -5.64E#00 -1.53E#01

1.00E#00 -6.64E#00 -1.73E#01

1.00E#00 -7.64E#00 -1.93E#01

CO3(-2a).0CO32-


13/26

LOG(S2-./0S2-)

-2.38E#01

-2.18E#01

-1.98E#01

-1.78E#01

-1.58E#01

-1.38E#01

-1.18E#01

-9.94E#00

-8.56E#00

-7.49E#00

-6.48E#00

0 2 4 6 8 10

0.00$

10.00$20.00$

30.00$

40.00$

50.00$

60.00$

70.00$

80.00$

90.00$

100.00$

0 2 4 6 8 10

0.00E#00

1.00E#00


14/26

-5.48E#00

-4.50E#00

-3.61E#00

-3.12E#00

-3.01E#00

-3.00E#00

-3.00E#00-3.00E#00

LOG(CO3(-2a)./0CO32-)

-1.70E#01

-1.50E#01

-1.30E#01

-1.10E#01

-8.98E#00

-6.99E#00

-5.10E#00

-3.60E#00

-2.50E#00

-1.50E#00

-6.10E-01

-1.16E-01

-1.31E-02

-1.33E-03

-1.33E-04

-1.33E-05

-1.33E-06

-1.33E-07

-1.33E-08

-5.00E#00

-4.00E#00

-3.00E#00

-2.00E#00

-1.00E#00

0 2 4 6 8

0.00$10.00$

20.00$

30.00$

40.00$

50.00$

60.00$

70.00$

80.00$

90.00$

100.00$

0 2 4 6 8

-5.00E#00

-4.00E#00

-3.00E#00

-2.00E#00

-1.00E#00

0.00E#00

1.00E#00


15/26

LOG(CO3(-2a)./0CO32-)

-1.67E#01

-1.47E#01

-1.27E#01

-1.07E#01-8.73E#00

-6.75E#00

-4.88E#00

-3.45E#00

-2.37E#00

-1.38E#00

-5.17E-01

-8.95E-02

-9.83E-03

-9.93E-04

-9.94E-05

-9.94E-06

-9.94E-07

-9.94E-08

-9.94E-09

0 2 4 6 8

0.00$

10.00$

20.00$

30.00$40.00$

50.00$

60.00$

70.00$

80.00$

90.00$

100.00$

0 2 4 6 8

-5.00E#00

-4.00E#00

-3.00E#00

-2.00E#00

-1.00E#00

0.00E#00

1.00E#00


16/26

12 14 16 18 20

%ol&m

%ol&m

%ol&m S

12 14 16 18 20


17/26

%ol&m

10 12 14 16 18 20

%ol&m

%ol&m

%ol&m S

10 12 14 16 18 20

%ol&m !

%ol&m


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10 12 14 16 18 20

%ol&m

%ol&m

%ol&m S

10 12 14 16 18 20

%ol&m !%ol&m


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H2CO3(a) = CO2(g) + H2O

T deltaH deltaS deltaG K4o2 Log(K) T

C 54al 4al/K 54al C

0 2.772 15.418 -1.439 14.18 1.152 0

5 4.341 21.156 -1.544 16.33 1.213 5

10 4.474 21.63 -1.651 18.80 1.274 10

15 4.607 22.097 -1.76 21.63 1.335 15

20 4.741 22.557 -1.872 24.86 1.395 20

25 4.875 23.01 -1.986 28.55 1.456 25

30 5.009 23.458 -2.102 32.76 1.515 30

35 5.144 23.899 -2.22 37.56 1.575 35

40 5.279 24.334 -2.341 43.03 1.634 40

45 5.415 24.763 -2.463 49.25 1.692 45

50 5.551 25.186 -2.588 56.32 1.751 50

55 5.687 25.604 -2.715 64.35 1.809 55

60 5.823 26.016 -2.844 73.47 1.866 60

65 5.96 26.423 -2.975 83.80 1.923 6570 6.097 26.826 -3.109 95.50 1.98 70

75 6.234 27.223 -3.244 108.70 2.036 75

80 6.371 27.615 -3.381 123.70 2.092 80

85 6.509 28.003 -3.52 140.60 2.148 85

90 6.648 28.386 -3.661 159.70 2.203 90

95 6.786 28.765 -3.804 181.20 2.258 95

100 6.925 29.14 -3.948 205.50 2.313 100

HCO3(-a) = CO3(-2a) + H(+a)

T deltaH deltaS deltaG K2 Log(K) TC 54al 4al/K 54al C

0 5.386 -28.896 13.279 2.37E-11 -10.625 0

5 4.931 -30.548 13.428 2.81E-11 -10.551 5

10 4.526 -31.991 13.584 3.27E-11 -10.486 10

15 4.16 -33.27 13.747 3.74E-11 -10.428 15

20 3.825 -34.423 13.917 4.21E-11 -10.376 20

25 3.513 -35.48 14.091 4.68E-11 -10.33 25

30 3.217 -36.464 14.271 5.14E-11 -10.289 30

35 2.933 -37.393 14.456 5.58E-11 -10.253 35

40 2.658 -38.28 14.645 6.00E-11 -10.222 4045 2.388 -39.135 14.839 6.40E-11 -10.194 45

50 2.122 -39.964 15.036 6.76E-11 -10.17 50

55 1.86 -40.768 15.238 7.09E-11 -10.15 55

60 1.603 -41.547 15.444 7.37E-11 -10.132 60

65 1.347 -42.309 15.654 7.62E-11 -10.118 65

70 1.091 -43.06 15.867 7.83E-11 -10.106 70

75 0.835 -43.801 16.084 7.99E-11 -10.098 75

80 0.578 -44.534 16.305 8.10E-11 -10.091 80


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85 0.319 -45.262 16.53 8.18E-11 -10.088 85

90 0.058 -45.986 16.758 8.21E-11 -10.086 90

95 -0.206 -46.708 16.989 8.19E-11 -10.087 95

100 -0.474 -47.43 17.225 8.14E-11 -10.089 100


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H2CO3(a) = HCO3(-a) + H(+a) +%,2

deltaH deltaS deltaG K1 Log(K)

54al 4al/K 54al

2.685 -20.06 8.164 2.932E-07 -6.533 +H(#)

2.585 -20.423 8.266 3.199E-07 -6.495 1.00E#00

2.505 -20.708 8.368 3.470E-07 -6.46 1.00E-01

2.44 -20.935 8.473 3.745E-07 -6.427 1.00E-02

2.387 -21.119 8.578 4.024E-07 -6.395 1.00E-03

2.342 -21.27 8.684 4.307E-07 -6.366 1.00E-04

2.303 -21.399 8.79 4.595E-07 -6.338 1.00E-05

2.268 -21.513 8.898 4.886E-07 -6.311 1.00E-06

2.236 -21.617 9.005 5.182E-07 -6.285 1.00E-07

2.205 -21.715 9.114 5.481E-07 -6.261 1.00E-08

2.175 -21.808 9.223 5.783E-07 -6.238 1.00E-09

2.146 -21.898 9.332 6.087E-07 -6.216 1.00E-10

2.118 -21.984 9.442 6.393E-07 -6.194 1.00E-11

2.089 -22.069 9.552 6.701E-07 -6.174 1.00E-122.06 -22.156 9.662 7.009E-07 -6.154 1.00E-13

2.029 -22.244 9.773 7.317E-07 -6.136 1.00E-14

1.997 -22.335 9.885 7.625E-07 -6.118 1.00E-15

1.963 -22.43 9.997 7.932E-07 -6.101 1.00E-16

1.928 -22.529 10.109 8.236E-07 -6.084 1.00E-17

1.89 -22.632 10.222 8.537E-07 -6.069 1.00E-18

1.849 -22.742 10.335 8.835E-07 -6.054

H2O = H(+a) + OH(-a)

deltaH deltaS deltaG K6 Log(K)54al 4al/K 54al

16.33 -8.552 18.666 1.16E-15 -14.936

14.516 -15.18 18.738 1.89E-15 -14.725

14.18 -16.378 18.817 2.98E-15 -14.525

13.876 -17.442 18.902 4.60E-15 -14.338

13.598 -18.4 18.992 6.92E-15 -14.16

13.338 -19.278 19.086 1.02E-14 -13.991

13.092 -20.096 19.184 1.47E-14 -13.832

12.856 -20.869 19.287 2.09E-14 -13.68

12.627 -21.606 19.393 2.91E-14 -13.53612.403 -22.317 19.503 4.00E-14 -13.398

12.182 -23.006 19.616 5.40E-14 -13.268

11.964 -23.674 19.733 7.19E-14 -13.143

11.75 -24.321 19.853 9.45E-14 -13.025

11.538 -24.954 19.976 1.23E-13 -12.912

11.325 -25.578 20.102 1.57E-13 -12.804

11.113 -26.193 20.232 1.99E-13 -12.701

10.899 -26.803 20.364 2.49E-13 -12.604 -1

-1

-

-

-

-

logCT


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10.684 -27.407 20.5 3.09E-13 -12.51

10.467 -28.008 20.638 3.79E-13 -12.422

10.248 -28.608 20.78 4.60E-13 -12.337

10.026 -29.207 20.924 5.54E-13 -12.256


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3.16E-04 Ko2" 28.55 k1 4.307E-007

+H2%,3"

H +%,2/K%,2 K1/+H# lo%!

0 1.10763E-005 0.0000004307 2.0139532E-017 -4.9556059255

1 1.10763E-005 0.000004307 2.0139532E-015 -4.9556042421

2 1.10763E-005 0.00004307 2.0139532E-013 -4.9555874079

3 1.10763E-005 0.0004307 2.0139532E-011 -4.9554191022

4 1.10763E-005 0.004307 0.000000002 -4.953739622

5 1.10763E-005 0.04307 2.0139532E-007 -4.937292574

6 1.10763E-005 0.4307 2.0139532E-005 -4.800051422

7 1.10763E-005 4.307 0.0020139532 -4.2305922458

8 1.10763E-005 43.07 0.20139532 -3.3094829025

9 1.10763E-005 430.7 20.139532 -2.3006218874

10 1.10763E-005 4307 2013.9532 -1.1547548361

11 1.10763E-005 43070 201395.32 0.4326129225

12 1.10763E-005 430700 20139532 2.357633098413 1.10763E-005 4307000 2013953200 4.3493710437

14 1.10763E-005 43070000 201395320000 6.3485361291

15 1.10763E-005 430700000 20139532000000 8.3484525493

16 1.10763E-005 4307000000 2013953200000000 10.34844419

17 1.10763E-005 43070000000 2.0139532000E#017 12.348443355

18 1.10763E-005 430700000000 2.0139532000E#019 14.348443271

+H%,3- /+H2%,3" +%,3 2- /+H2%,3"

(K1*K2)/+H#2

0 2 4 6 8

2

0

8

6

4

2

0

2

4

,iag7ama de Sol89il


24/26

H


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k2 4.676E-011 k 1.02E-014

lo+H2%,3 lo+H%,3(-) lo+%,3(2-) lo+,H(-) lo+H(#)

-4.9556061126 -11.321431241 -21.651556738 -13.991399828 0

-4.9556061126 -10.321431241 -19.651556738 -12.991399828 -1

-4.9556061126 -9.3214312408 -17.651556738 -11.991399828 -2

-4.9556061126 -8.3214312408 -15.651556738 -10.991399828 -3

-4.9556061126 -7.3214312408 -13.651556738 -9.9913998282 -4

-4.9556061126 -6.3214312408 -11.651556738 -8.9913998282 -5

-4.9556061126 -5.3214312408 -9.6515567383 -7.9913998282 -6

-4.9556061126 -4.3214312408 -7.6515567383 -6.9913998282 -7

-4.9556061126 -3.3214312408 -5.6515567383 -5.9913998282 -8

-4.9556061126 -2.3214312408 -3.6515567383 -4.9913998282 -9

-4.9556061126 -1.3214312408 -1.6515567383 -3.9913998282 -10

-4.9556061126 -0.3214312408 0.3484432617 -2.9913998282 -11

-4.9556061126 0.6785687592 2.3484432617 -1.9913998282 -12-4.9556061126 1.6785687592 4.3484432617 -0.9913998282 -13

-4.9556061126 2.6785687592 6.3484432617 0.0086001718 -14

-4.9556061126 3.6785687592 8.3484432617 1.0086001718 -15

-4.9556061126 4.6785687592 10.348443262 2.0086001718 -16

-4.9556061126 5.6785687592 12.348443262 3.0086001718 -17

-4.9556061126 6.6785687592 14.348443262 4.0086001718 -18

10 12 14

idad

lo%!

lo+H2%,3

lo+H%,3

lo+%,3

lo+H

lo+,H


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Documents

Diagrama de Solubilidad Actualiz. 290915