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Kamil B. Varınca, M. Talha Gönüllü (2014). Ham veya İşlenmiş Atıklardan Kirletici Taşınımının Tespiti: Özütleme Testleri, 2nd International Symposium on Environment and Morality (ISEM 2014), Proceedings, Volume 2, pp:1081-1087, Adıyaman Üniversitesi Yayınları No:12, ISBN: 978-605-60221-8-0, Adiyaman University, Adiyaman, 24-26 October 2014.
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2. ULUSLARARASI
EVRE VE AHLAK
SEMPOZYUMU
BLDRLER KTABI
2. Cilt
24-26 EKM 2014
ADIYAMAN
EDTRLER
Prof. Dr. Ahmet PINARBAI
Prof. Dr. Murat PALA
EDTR YARIMCILARI
Do. Dr. Tanju TEKER
rt. Gr. Faruk KRKER
rt. Gr. Hseyin KUTLU
ORGANZASYON
ADIYAMAN NVERSTES
TRKYE
2ND
INTERNATIONAL SYMPOSIUM
ON ENVIRONMENT AND MORALITY
PROCEEDINGS
Volume 2
24-26 OCTOBER 2014
ADIYAMAN
EDITORS
Prof. Dr. Ahmet PINARBAI
Prof. Dr. Murat PALA
Co-EDITOR
Assoc. Prof. Dr. Tanju TEKER
Instructor Faruk KRKER
Instructor Hseyin KUTLU
ORGANIZATION
ADIYAMAN UNIVERSITY
TURKEY
ISBN: 978-605-60221-8-0
EDTRLER
Prof. Dr. Ahmet PINARBAI
Prof. Dr. Murat PALA
EDTR YARIMCILARI
Do. Dr. Tanju TEKER
rt. Gr. Faruk KRKER
rt. Gr. Hseyin KUTLU
YAYINCI
Adyaman niversitesi Yaynlar
Telefon: 0 416 2233800
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BASKI
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ADIYAMAN
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Dr. Evangelos GIDARAKOS (Technical University of Crete, Greece)
Dr. Fazlun KHALID (Islamic Foundation for Ecology and Environ. Sci., UK)
Dr. Ferit YUSUPOV (Kazan Federal University, Tataristan)
Dr. Harun TRKMENLER (Adiyaman University, Turkey)
Dr. Ibrahim DEMIR (Istanbul Technical University, Turkey)
Dr. Ibrahim OZDEMIR (Gaziantep University, Turkey)
Dr. Ismail KOYUNCU (Istanbul Technical University, Turkey)
Dr. Ismail TORZ (Istanbul Technical University, Turkey)
Dr. Izzet ZTRK (Istanbul Technical University, Turkey)
Dr. zzetullah NUREDDNOV (Uzbekistan Academy of Sciences)
Dr. Jame SCHAEFER (Marquette University, USA)
Dr. John MUTTER (Columbia University, USA)
Dr. Kadir OZKOSE (Gaziosmanpasa University, Turkey)
Dr. Lisa SIDERIS (Indiana University, USA)
Dr. M. Doan KARACOKUN (Kilis 7 Aralk University, Turkey)
Dr. Mawil Izzi DIEN (University of Wales, UK)
Dr. Mehmet Emin AYDIN (Necmettin Erbakan University, Konya)
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Dr. Mufeed BATARSEH (Abu Dhabi Polytechnic, UAE)
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Dr. Mustafa SEKKELI (Kahramanmaras Sutcu Imam University, Turkey)
Dr. Nadirhan HASANOV (Fatih University, Turkey)
Dr. Necdet YILMAZ (MEC Research and Training Center, Turkey)
Dr. Nedim VARDAR (Universidad Interamericana de Puerto Rico, Puerto Rico)
Dr. Noor MOHAMMAD (The National University Of Malaysia, Malaysia)
Dr. Osman BAKAR (Universiti Brunei Darussalam, Brunei Darussalam)
Dr. Qilin LEE (Rice University, USA)
Dr. Richard FOLTZ (Concordia University, Canada)
Dr. S. Parvez MANZOOR (Swedish Writer, Swedish)
Dr. Seyyed Hossein NASR (George Washington University, USA)
Dr. Sherzodhon Yu. MAHMODOV (Academy of Sciences of The Republic of Uzbekistan
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Dr. Tanju KARANFIL (Clemson University, USA)
Dr. Teoman DURALI (Krklareli University, Turkey)
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Dr. Timothy G. ELLIS (Iowa State University, USA)
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SEKRETERLER/ SECRETARIES
Research Assist. Mustafa OZSAGIR (Sakarya University)
Research Assist. Halil Ibrahim UZUN (Cevre Foundation)
Lecturer Faruk Krker (Adiyaman University)
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Res. Assist. Mehmet Faruk YAREN (Sakarya University)
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2nd
International Symposium on Environment and Morality
24-26 October 2014, Adyaman - TURKEY
*Corresponding author: Address: Faculty of Engineering, Department of Environmental Engineering, Adiyaman
University, 02040, Adiyaman, TURKEY. E-mail address: [email protected], Phone: +904162233808, Fax:
+904162233809
Determination of Convection of Pollutants from Raw or Treated Waste:
Extraction Tests
*1Kamil B. Varnca,
1Mustafa Talha Gnll
1Faculty of Engineering Department of Environmental Engineering, Adiyaman University
02040, Adiyaman, Turkey
Abstract
One of the most important issues in waste disposal is to prevent the transport of pollutants. Especially
in environments where solvents such as water, disperse of pollutants from waste or material into the
liquid medium the environment are the unwanted event in terms of the protection of the environment
and human health.
Various extraction tests have been developed for the detection of pollutants passage from raw or
treated wastes/materials into liquid environment. These tests are used to determine pass degree of
pollutants into liquid environment under model situations of natural environment.
In this paper, the present extraction tests examined and these tests compared with each other in terms
of the model conditions of environment.
Key words: Waste, solidification/stabilization, convection, extraction, TCLP
Ham veya lenmi Atklardan Kirletici Tanmnn Tespiti:
ztleme Testleri
zet
Atk bertarafnda en nemli konulardan biri kirleticilerin tanmnn engellenmesidir. zellikle su gibi
zclerin olduu ortamlarda kirleticilerin atk veya malzemeden sv ortama geerek evrede
dalmalar evre ve insan salnn korunmas asndan istenmeyen hadiselerdendir.
Kirleticilerin ham veya ilenmi atk/malzemelerden sv ortama geiinin tespit edilebilmesi iin
eitli ztleme testleri gelitirilmitir. Bu testler atk veya malzemenin doal hayatta karlaabilecei
ortam artlarna gre modellenmi artlar altnda kirleticinin sv ortama gei derecesini tespit etmek
maksadyla kullanlmaktadr.
Bu almada, mevcut ztleme testleri incelenerek bu testler kendi aralarnda modelledikleri ortam
artlar bakmndan mukayeseye tabi tutulmutur.
Anahtar kelimeler: Atk, katlatrma/kararllatrma, tanm, ztleme, TCLP
K.B. VARINCA, M.T. GNLL / ISEM2014 Adiyaman - TURKEY
1082
1. Giri
Atklar ham veya ilenmi olarak kontrolsz olarak doaya brakldklarnda zamanla evresel
artlar (rzgr, yamur, scak, souk vb. gibi) sonucunda ilerindeki kirleticileri evreye
salabilirler. Kirleticilerin evreye salnmas neticesinde de bu kirleticiler tanm yoluyla su ve
besin zincirine girerek evre ve insan sal zerine tehlike olutururlar. Bu sebeple atklar
kontrolsz bir ekilde doaya braklmaz, gerekli ilemler geirildikten sonra kontroll bir ekilde
bertaraflar, depolanmalar salanr.
ztleme (eng: extraction); toprak, kirlenmi toprak, amur, kelti, kompost, atk veya inaat
malzemeleri gibi kat maddeler iindeki bileenlerin fiziksel, kimyasal veya biyolojik ilemlerle
su fazna geirilmesi olarak tanmlanmakta [1] olup birok ztleme testi bulunmaktadr.
2. ztleme Testleri
Kirleticilerin tanm ve evreden izole edilmesi amaland iin ztleme testi, bir ham veya
ilenmi atn szma derecesini lmek iin kullanlan en yaygn test yntemleridir. ztleme
artlar farkllk arz ettii iin zaman ierisinde ok eitli test yntemleri gelitirilmi ve
kullanlmtr. Kullanlm olan bu ztleme testleri izelge 1de, ztleme test yntemleri
kaynaka listesi izelge 2de ve ztleme testlerine ait test artlar ise izelge 3de derlenmitir.
izelge 1. Uygulanabilir ztleme testleri [2, 3, 4, 5, 6, 7, 8]
Test Yntem
Malzeme
Uygulama(a)
Ama
U S L
alkalamal ztleme Testleri
Toxicity Characteristic Leaching
Procedure (TCLP) (tur: Zehirlilik
zellikleri Szma lemi)
USEPA SW-846
1311(b)
X X X Zehirlilik verilerini yasal deerler ile
karlatrmak iin (ABDde RCRA
gereksinimidir.)
Extraction Procedure Toxicity (EP
Tox) Test (tur: Zehirlilik ztleme
lemi)
USEPA SW-846
1310B(b)
X X X Sznt suyu konsantrasyonlarn
deerlendirmek iin (ABDde RCRA
gereksinimidir.)
TCLP Cage Modification (tur:
Deitirilmi TCLP Kafes)
USFR(c)
X TCLP testinin deerlendirilmesine
niteliksel katk.
California Waste Extraction Test (Cal
WET) (tur: Kaliforniya Atk
ztleme Deneyi)
California Code()
X X X Metaller iin TCLPden daha gl
szma testi salamak iin (ABD
Kaliforniyada yasal gerekliliktir.)
Synthetic Precipitation Leach Test
(SPLP) (tur: Sentetik Ya Szdrma
Deneyi)
USEPA SW-846
1312(b)
X X Asit yamurlarna maruz atklar iin
(ABDde RCRA gereksinimidir.)
Agitated Powder Leach Test (tur:
alkalamal Toz Szdrma Deneyi)
MCC-3S(d)
X X alkantl ak iindeki btn
numunenin szma direncini
deerlendirmek iin
Shake Extraction Test (tur: Sallamal
ztleme Deneyi)
TS 9394(e)
ASTM D3987(f)
X X Hzl bir ekilde bir sulu ektrakt elde
etmeyi salamak iin
K.B. VARINCA, M.T. GNLL / ISEM2014 Adiyaman - TURKEY
1083
Test Yntem
Malzeme
Uygulama(a)
Ama
U S L
Acid Neutralization Capacity (ANC)
Test (tur: Asit Ntralizasyon
Kapasitesi Deneyi)
WTC-ANC(g)
X X X Bir malzemenin asidi ntralize
edebilme yeteneinin llmesi iin
alkalamasz ztleme Testleri
Static Leach Test (tur: Duraan
Szdrma Deneyi)
ASTM C1220(f)
X Statik ak iindeki btn numunenin
szma direncini deerlendirmek iin
Static Leach Test (tur: Duraan
Szdrma Deneyi)
MCC-1P(d)
X Statik ak iindeki btn numunenin
szma direncini deerlendirmek iin
High Temperature Static Leach Test
(tur: Yksek Scaklkl Duraan
Szdrma Deneyi)
MCC-2P(d)
X Statik ak iindeki btn numunenin
szma direncini deerlendirmek iin
Monofilled Waste Extraction
Procedure (MWEP) (tur: Tekdolgulu
Atk ztleme lemi)
USEPA SW-924()
X Dk hzl doygun blgede atk
bertaraf iin
Equilibrium Leach Test (ELT) (tur:
Dengesel Szdrma Deneyi)
WTC-ELT(g)
X X En fazla sznt suyu salamak iin
Ardk Kimyasal ztleme Testleri
Sequential Batch Extraction Test (tur:
Ardk ztleme Deneyi)
ASTM D5284(f)
X X ztleme kapasitesini deerlendirmek
iin
Sequential Extraction Test (SET)
(tur: Ardk ztleme Deneyi)
Bishop(h)
X X oklu ztleme ile tamponlama
kapasitesini deerlendirmek iin
Sequential Chemical Extraction Test
(SCET) (tur: Ardk Kimyasal
ztleme Deneyi)
WTC-SCET(g)
X X K/K ilemi grm atklarda metal ve
organiklerin tutunmasn
deerlendirmek iin
Dinamik Testler, Seri
Multiple Extraction Procedure (MEP)
(tur: oklu ztleme lemi)
USEPA SW-846
1320(b)
X X X Asidik artlar altnda atk szmasn
deerlendirmek iin
Leaching Test (tur: Szma Deneyi) EN 12457-(1-4) ()
TS EN 12457-(1-4) (e)
X X ztleme kapasitesini deerlendirmek
iin
Availability Test (tur: Ulalabilirlik
Testi)
NEN 7341(i)
X
Dinamik Testler, Ak-etrafndan
American Nuclear Society (ANS)
Leach Test (tur: Amerikan Nkleer
Cemiyeti Szdrma Deneyi)
ANSI/ANS/16.1(j)
X K/K ilemi grm atklarn
mukayesesinde bir difzyon katsays
oluturmak iin
Monolithic Diffusion Test (tur:
Yekpare Difzyon Deneyi)
NEN 7345(i)
X Yekpare parann ztleme
kapasitesinin belirlenmesi iin
Leach Test (tur: Szdrma Deneyi) ISO 6961(k)
X ztleme snrnn belirlenmesi iin
Dinamik Testler, Ak-iinden
Dynamic Leach Test (DLT) (tur:
Dinamik Szdrma Deneyi)
WTC-DLT(g)
X K/K ilemi grm bir ata has
difzyon katsays tahmin etmek iin
Column Leach Test (tur: Kolon
Szdrma Deneyi)
ASTM D4874(f)
X Kolon eklinde szdrma kapasitesinin
belirlenmesi iin
Column Test (tur: Kolon Deneyi) NEN 7374(i)
X Szma kapasitesinin belirlenmesi iin
K.B. VARINCA, M.T. GNLL / ISEM2014 Adiyaman - TURKEY
1084
Test Yntem
Malzeme
Uygulama(a)
Ama
U S L
Dinamik Testler, Soklet
Soxhlet Leach Test (tur: Soklet
Szdrma Deneyi)
MCC-5S(d)
X Srekli yenilenen saf szdrma suyunda
btn numunenin szma direncini
deerlendirmek iin
izelge 2. ztleme test yntemleri kaynaka listesi
Yntem Kaynak Yaymc
ANSI/ANS/16.1 ANSI/ANS/16.1-2003:R2008, Measurement of the Leachability of
Solidified Low-Level Radioactive Wastes by a Short-Term Test
Procedure http://www.ans.org/store/i_240249
American Nuclear
Society (ANS)
http://www.ans.org/
ASTM C1220 ASTM C1220-10, Standard Test Method for Static Leaching of
Monolithic Waste Forms for Disposal of Radioactive Waste
http://www.astm.org/Standards/C1220.htm
ASTM International.
http://www.astm.org/
ASTM D3987 ASTM D3987-12, Standard Practice for Shake Extraction of Solid
Waste with Water http://www.astm.org/Standards/D3987.htm
ASTM D4874 ASTM D4874-95(2014), Standard Test Method for Leaching
Solid Material in a Column Apparatus
http://www.astm.org/Standards/D4874.htm
ASTM D5284 ASTM D5284-09, Standard Test Method for Sequential Batch
Extraction of Waste with Acidic Extraction Fluid
http://www.astm.org/Standards/D5284.htm
Bishop Bishop, P.L., Prediction of Heavy Metal Leaching Rates from
Stabilization/Solidification Hazardous Wastes, Toxic and
Hazardous Wastes: Proceedings of the Eighteenth Mid-Atlantic
Industrial Waste Conference, Technomic Publishing, USA, 1986.
California Code California Code Title 22, Article 11, pp. 1800.75-1800.82.
EN 12457-(1-4) EN 12457-(1-4), Characterisation of waste - Leaching -
Compliance test for leaching of granular waste materials and
sludges
European Committee for
Standardization (CEN)
http://standards.cen.eu/
ISO 6961 ISO 6961:1982, Long-term leach testing of solidified radioactive
waste forms
http://www.iso.org/iso/home/store/catalogue_tc/catalogue_detail.h
tm?csnumber=13511
International
Organization for
Standardization
http://www.iso.org/
MCC-1P MCC, Materials Characterization Center, Pacific Northwest
Laboratory (PNL), Nuclear Waste Materials Handbook: Test
Methods, USDOE, DOE/TIC-11400, 1981.
http://www.worldcat.org/oclc/9285773
Materials
Characterization Center
(MCC)
MCC-2P
MCC-3S
MCC-5S
NEN 7341 NEN 7341:1995, http://www.nen.nl/NEN-Shop/Norm/NEN-
73411995-nl.htm
Netherlands
Standardization Institute
(NEN)
http://www.nen.nl/
NEN 7374 NEN 7374:2004, http://www.nen.nl/NEN-Shop/Norm/NEN-
73742004-nl.htm
NEN 7345 NEN 7345:1995, http://www.nen.nl/NEN-Shop/Norm/NEN-
73451995-nl.htm
USEPA SW-846 1310B USEPA SW-846 On Line, Test Methods for Evaluating Solid
Waste, Physical/Chemical Methods.
http://www.epa.gov/epawaste/hazard/testmethods/sw846/online/
United States
Environmental
Protection Agency
(USEPA)
USEPA SW-846 1311
USEPA SW-846 1312
USEPA SW-846 1320
http://www.ans.org/store/i_240249http://www.ans.org/http://www.astm.org/Standards/C1220.htmhttp://www.astm.org/http://www.astm.org/Standards/D3987.htmhttp://www.astm.org/Standards/D4874.htmhttp://www.astm.org/Standards/D5284.htmhttp://standards.cen.eu/http://www.iso.org/iso/home/store/catalogue_tc/catalogue_detail.htm?csnumber=13511http://www.iso.org/iso/home/store/catalogue_tc/catalogue_detail.htm?csnumber=13511http://www.iso.org/http://www.worldcat.org/oclc/9285773http://www.nen.nl/NEN-Shop/Norm/NEN-73411995-nl.htmhttp://www.nen.nl/NEN-Shop/Norm/NEN-73411995-nl.htmhttp://www.nen.nl/http://www.nen.nl/NEN-Shop/Norm/NEN-73742004-nl.htmhttp://www.nen.nl/NEN-Shop/Norm/NEN-73742004-nl.htmhttp://www.nen.nl/NEN-Shop/Norm/NEN-73451995-nl.htmhttp://www.nen.nl/NEN-Shop/Norm/NEN-73451995-nl.htmhttp://www.epa.gov/epawaste/hazard/testmethods/sw846/online/
K.B. VARINCA, M.T. GNLL / ISEM2014 Adiyaman - TURKEY
1085
Yntem Kaynak Yaymc
USEPA SW-924 USEPA, SW-924, Solid Waste Leaching Procedure, 1984.
http://nepis.epa.gov/Exe/ZyPURL.cgi?Dockey=2000OL4A.txt
USFR USFR, 53 FR 18792, May 24, 1988.
http://nepis.epa.gov/Exe/ZyPURL.cgi?Dockey=10003P0J.txt
TS 9394 TS 9394:1991, Atklar-Kat atklarn su ile alkalanarak
ekstraksiyon metodu
Trk Standartlar
Enstits (TSE)
https://intweb.tse.org.tr/
Standard/Standard/Stand
ardAra.aspx
TS EN 12457-(1-4) TS EN 12457-(1-4), Atklarn nitelendirilmesi - Katdan ztleme
analizi - Granl kat atklarn ve amurlarn kat ztlemesi iin
uygunluk deneyi
WTC-ANC WTC, Wastewater Technology Centre, Environment Canada,
Investigation of Test Methods for Solidified Waste Evaluation -
A Cooperative Program, Report: EPS 3/HA/8, 1991.
http://www.worldcat.org/oclc/23220612
Wastewater Technology
Centre, Environment
Canada (WTC)
WTC-DLT
WTC-ELT
WTC-SCET
izelge 3. Uygulanabilir ztleme testlerinin test artlar [2, 3, 4, 5, 6, 7, 8]
Test Yntemi Szma Ortam Sv:Kat
Oran Parack Boyutu
ztleme
Says ztleme Sresi
TCLP Asetat tamponu(a)
20:1 < 9,5 mm 1 182 saat
EP Tox 0,04 M asetik asit (pH 5,0) 16:1-20:1 < 9,5 mm 1 24 saat
TCLP cage Asetat tamponu(a)
20:1 (b)
1 18 saat
Cal WET 0,2 M sodyum sitrat (pH
5,0) veya Cr6+
l su
10:1 < 2,0 mm 1 48 saat
SPLP (c)
20:1 < 9,5 mm 1 18 saat
MCC-3S ()
10:1 Yars
K.B. VARINCA, M.T. GNLL / ISEM2014 Adiyaman - TURKEY
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Test Yntemi Szma Ortam Sv:Kat
Oran Parack Boyutu
ztleme
Says ztleme Sresi
ANSI/ANS/16.1 Deiyonize su (e)
Btn uzunluk-
ap oran 0,2-5,0
aras
10-12 Szdrma suyu 2,7 saatte
yenilenir; 1, 2, 3, 4, 5, 14,
28, 43 ve 90 gn
DLT Deiyonize su (f)
Btn uzunluk-
ap oran 0,2-5,0
aras
(f) Szdrma suyu 0, 1, 4, 7,
24, 31, 48, 72, 79 ve 100
satte veya 0, 4, 24, 31,
72, 104, 168 ve 196
saatte yenilenir
MCC-5S Deiyonize su Yeniden
damtlm
suyun
srekli
ak
Yekpare 1 Her bir numune iin 3, 7
ve 14 gn
(a) Asetat tampon zeltisi (pH 5,0) veya asetik asit (pH 3,0)
(b) TCLP tipi ztleme esnasnda tel kafes iinde yuvarlanan para
(c) Arlka 60:40 slfrik asit nitrik asit karm. pH deiyonize su ile 4,2 veya 5,0a ayarlanr.
() Silikatl su, deiyonize su veya tuzlu su
(d) Szdrma suyunun hacmi numunenin llen geometrik yzey alanna baldr. Hacmin yzeye oran 10 il 200
cm arasnda olmaldr. (e)
Szdrma suyu hacminin numune yzey alanna oran 10 cm (f)
Yenileme frekanslar bilinen difzyon katsaysna gre seilir. Yzey hacim oran kirleticinin tespitini salamak
zere seilmelidir. Yenileme frekans dengesiz artlara da hkim olacak ekilde seilmelidir.
Grld zere uygulamada birok farkl ztleme testi bulunmaktadr. Temel amalar ayn
olsa da uygulama artlar farkl olduu iin bu testlerden farkl sonular elde edilmesi tabiidir.
nemli olan mukayese ve muhakeme asndan ayn olmasa bile benzer nitelikteki ztleme
testlerinin kullanlmasdr. Bu ztleme testlerinin seiminde kanuni zorunluluun bulunmasnn
yannda uygulama kolayl, ksa srede sonu elde edilmesi ve ekonomiklik tercih sebebidir.
ztleme testleri ierisinde en ok kullanlanlardan biri Toxicity Characteristic Leaching
Procedure (TCLP)dir.
2.1. Toxicity Characteristic Leaching Procedure (TCLP)
USEPA SW-846 1311 Toxicity Characteristics Leaching Procedure (TCLP) (tur: Zehirlilik
zellikleri Szma lemi), United States Environmental Protection Agency (tur: Amerika Birleik
Devletleri evre Koruma Ajans) tarafndan yaymlanm olan SW-846: Test Methods for
Evaluating Solid Waste, Physical/Chemical Methods deney yntemleri ierisinde yer alan bir
yntem olup ABDde tehlikeli atk ve katlatrlm malzeme zelliklerinin belirlenmesi iin
uygulanmas zorunlu olan deney yntemlerinden biridir.
Deney, yntem uyarnca malzemenin 9,5 mmden daha kk hale getirilmesinin ardndan 20:1
oranndaki sv asidik ortamda 18 saat alkalanmas sonucu zeltide kirletici tayini yaplmas
eklinde uygulanr [8]. Bylece atk malzemenin uzun vadede tabii artlar altnda gsterecei
davran, 18 saatlik bir srede asidik ortamda hzlandrlm olarak gerekletirilmekte ve uzun
sreler sonunda elde edilebilecek sonular nceden tahmin edilebilmektedir.
K.B. VARINCA, M.T. GNLL / ISEM2014 Adiyaman - TURKEY
1087
Deerlendirme
Atklar ham veya ilenmi olarak kontrolsz olarak doaya brakldklarnda zamanla evresel
artlar (rzgr, yamur, scak, souk vb. gibi) sonucunda ilerindeki kirleticileri evreye
salabilirler. Kirleticilerin evreye salnmas neticesinde de bu kirleticiler tanm yoluyla su ve
besin zincirine girerek evre ve insan sal zerine tehlike olutururlar. Bu sebeple atklar
kontrolsz bir ekilde doaya braklmaz, gerekli ilemler geirildikten sonra kontroll bir ekilde
bertaraflar, depolanmalar salanr.
ztleme (eng: extraction), atn ierisindeki kirleticinin darya salnmas derecesini gsteren
bir kavram olup birok ztleme testi bulunmaktadr. Bu testlerden en ok kullanlan, United
States Environmental Protection Agency (tur: Amerika Birleik Devletleri evre Koruma Ajans)
tarafndan yaymlanm olan SW-846: Test Methods for Evaluating Solid Waste,
Physical/Chemical Methods deney yntemleri ierisinde yer alan USEPA SW-846 1311 Toxicity
Characteristics Leaching Procedure (TCLP) (tur: Zehirlilik zellikleri Szma lemi) deney
yntemidir. Yntem, ABDde tehlikeli atk ve katlatrlm malzeme zelliklerinin belirlenmesi
iin uygulanmas zorunlu olan deney yntemlerinden biridir.
Bu testler sonucunda ham atn veya ilenmi atn ierisindeki kirleticilerin szmas
belirlenerek evre ve insan sal zerinde oluabilecek olumsuz etkiler nceden grlerek
tedbirinin alnmas salanmaktadr.
Kaynaklar
[1] T.C. evre ve Orman Bakanl. Atklarn Dzenli Depolanmasna Dair Ynetmelik.
Resm Gazete: 26/03/2010-27533. (Yaymlanan hli: http://goo.gl/CkXFII Gncel hli:
http://goo.gl/5ZXIJG)
[2] U.S. EPA. Stabilization/Solidification of CERCLA and RCRA Wastes: Physical Tests,
Chemical Testing Procedures, Technology Screening, and Field Activities. EPA/625/6-
89/022. USEPA, 1989. http://nepis.epa.gov/Exe/ZyPURL.cgi?Dockey=30004CB5.txt
[3] Barth EF. et al. Stabilization and Solidification of Hazardous Wastes. Noyes Data
Corporation, 1990. ISBN: 0-8155-1245-7. http://www.worldcat.org/oclc/21761182
[4] Means JL. et al. The Application of Solidification/Stabilization to Waste Materials. Lewis
Publisher, 1995. ISBN: 0-56670-080-9. http://www.worldcat.org/oclc/31045421
[5] LaGrega MD, Buckingham PL, Evans JC. Hazardous Waste Management. 2.ed. McGraw-
Hill, 2001. ISBN: 978-0-07118-170-9. http://www.worldcat.org/oclc/843948430
[6] Spence RD, Shi C. Stabilization and Solidification of Hazardous, Radioactive, and Mixed
Wastes. CRC Press, 2004. ISBN: 978-1-56670-444-1.
http://www.crcnetbase.com/isbn/978-1-56670-444-1
[7] Suthersan SS. Remediation Engineering - Design Concepts. CRC Press, 1996. ISBN: 978-
1-56670-137-2. http://dx.doi.org/10.1201/9781420050585
[8] U.S. EPA. USEPA SW-846 1311: Toxicity Characteristics Leaching Procedure (TCLP).
1992. SW-846: Test Methods for Evaluating Solid Waste, Physical/Chemical Methods.
http://www.epa.gov/epawaste/hazard/testmethods/sw846/pdfs/1311.pdf
http://goo.gl/CkXFIIhttp://goo.gl/5ZXIJGhttp://nepis.epa.gov/Exe/ZyPURL.cgi?Dockey=30004CB5.txthttp://www.worldcat.org/oclc/21761182http://www.worldcat.org/oclc/31045421http://www.worldcat.org/oclc/843948430http://www.crcnetbase.com/isbn/978-1-56670-444-1http://dx.doi.org/10.1201/9781420050585http://www.epa.gov/epawaste/hazard/testmethods/sw846/pdfs/1311.pdf
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