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Large Air SeparationLarge Air Separationfor Gasificationfor Gasification
大型空分设备用于煤气化大型空分设备用于煤气化
Presented by: Stephen Mogck, Director of ASU Sales-Asia
演讲人：Stephen Mogck, 亚太区空分装置销售总监[email protected]
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简要介绍简要介绍 APCI FactsAPCI Facts
成立于1940年 Founded in 1940
位于美国宾夕法尼亚州的艾伦城USA H.Q. in Allentown, PA USA
500强财富排名281 Fortune 500: # 281
年销售额超过82亿美元 Sales of > US$ 8,200,000,000
是世界唯一将气体工业与化工工业巧妙结合的设备供应商The world’s only combined Gases and Chemicals Company
全世界拥有超过20000名员工 > 20,000 employees worldwide
安全业绩在空分行业居世界领先 Chemical industry safety leader Worlds largest manufacturer of hydrogen at more than 450,000,000 SCF/day
产品涉及地区非常广泛，50%以上的业绩产生在美国本土以外, 遍及30多个国家Geographically diversified with more than half of our salesoutside of the U.S. with operations in more than 30 countries
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世界唯一综合气体和化工业务的公司世界唯一综合气体和化工业务的公司APCI Corporate Business MixAPCI Corporate Business Mix ––the Worldthe World’’s Onlys OnlyIntegrated Gases/Chemicals CompanyIntegrated Gases/Chemicals Company
Cryogenic Air Separation 低温空气分离设备
Non-cryo Air Separation 非低温空气分离设备
Cogeneration Facilities 联合电站设备
Pipeline Systems 管网供气系统
Chemicals 化工
Hydrogen 氢气
HyCO Supply Capabilities 合成气的杰出供应能力
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APCIAPCI 在亚洲在亚洲 Air Products AsiaAir Products Asia
销售气体的王者 (Leader in Gas Sales)#1 韩国 (Korea)#1 天津/北京 (Tianjin/ Beijing)#2 上海/南京 (Shanghai/Nanjing)#1 台湾 (Taiwan)#1 南中国/广东 (S. China / Guangdong)#2 泰国 (Thailand)#2 马来西亚 (Malaysia)
ChinaChina
新加坡
韩国
广东
泰国
马来西亚
台湾
天津/北京
上海/南京
AP 亚洲 (AP in Asia (2005)销售 (Revenue): $17 亿/年 ($1.7BBN)资产 (Assets)： $20 亿 ($2.0BBN)雇员 (Employees): 4,800
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空分装置设计制造中心Engineering + Manufacturing Locations
中国上海，设计中心，中国总部Shanghai, PRCEngineeringChina HQ
中国上海，设计中心，中国总部Shanghai, PRCEngineeringChina HQ
上海漕泾，中国制造中心Caojing, PRCManufacturing
上海漕泾，中国制造中心Caojing, PRCManufacturing
美国艾伦镇，设计中心，全球总部
Allentown, PA, USAEngineeringGlobal HQ
美国艾伦镇，设计中心，全球总部
Allentown, PA, USAEngineeringGlobal HQ
美国韦克斯 芭利，制造中心Wilkes Barre, PA, USA
Manufacturing
美国韦克斯 芭利，制造中心Wilkes Barre, PA, USA
Manufacturing
英国阿科发尔，制造中心Acrefair, UK
Manufacturing
英国阿科发尔，制造中心Acrefair, UK
Manufacturing
英国赫山，英国设计中心，欧洲总部
Hersham, UKEngineering
European HQ
英国赫山，英国设计中心，欧洲总部
Hersham, UKEngineering
European HQ
离纽约100公里
100 kM from N.Y.C.
离伦敦90公里90 kM from London
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IGCC 等其他煤气化项目供应中的领先地位Leadership in Supplying IGCC + Gasification
APPLICATION EXPERIENCE: Experience with all major gasifiers—GE Energy(Texaco), Shell, Lurgi, ConocoPhillips
丰富的运用经验：具备所有主要煤气化工艺的经验-包括GE能源(德士古), 壳牌，鲁齐和ConocoPhillips
MEGA-TRAIN EXPERIENCE: Manufacturer/operator of very large single train airseparation plant since 1997 in Rozenburg, Netherlands (95,000nm3/hr); Now have 2x 3,500 mTPD (105,000nm3/hr) units for GTL in operation on Qatar.
大型空分设备经验：1997年在荷兰的玫瑰堡建造和运行了大型单套空分装置（制氧能力达95,000Nm3/hr ）；现在卡塔尔的两套3,500 MTPD (105,000nm3/hrGOX) 用于天然气液化的大型空分装置已投入运行。
RELIABILITY: First company to supply high-reliability tonnage oxygen withoutoxygen backup (Atlas 82,000nm3/hr ASU)可靠性：第一个做到提供高可靠性氧气管网供气, 而不设置液氧后备系统 （Atlas的82,000nm3/hr 空分装置）
VERY HIGH PRESSURE OXYGEN EXPERIENCE: Lead the industry in operatingexperience supplying tonnage oxygen at 1000 psig
具有超高压氧气的供气经验：氧气供气压力1000 psig的装置运营经验占行业领先地位
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APCIAPCI 大型空分装置经验大型空分装置经验Examples of Large Capacity ASUs by APCIExamples of Large Capacity ASUs by APCI
15,00025,00035,00045,00055,00065,00075,00085,00095,000
105,000
1987 1996 1997 1999 2001 2004 2008
PlaqueminePlaquemine
Demkolec
Demkolec
TECOTECOSaso
lSaso
l
AP/ExxonAP/Exxon
AP/ShellAP/Shell
GASGAS
NanjingChem.
NanjingChem.
AP/MethanexAP/Methanex
投产年份 On-Stream Year
氧气 Oxygen(NM3/hr)
Qatarx 2
Qatarx 2
MethanexMethanex
BaosteelBaosteel
Nigeriax 2
Nigeriax 2
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煤气化/POX项目中的空分装置ASUs For Gasification/POX
SyngasResid31,2503,000LaPorte, TX1979
ChemicalsCoal31,2501,230Kingsport, TN1983
H2Resid21,1501,500Convent, LA1984
IGCCCoal16501,500Plaquemine, LA1987
IGCCCoal14801,960Netherlands1994
H2/COGasPipelineHouston, TX1996
IGCCCoal15802,020Polk County, FL1996
H2/IGCCResid11,1003,500Netherlands1997
ChemicalsCoal14652,100South Africa1998
H2/COResid11,1002,600Baytown, TX1999
FertilizerNaptha11,5001,510China2000
MeOHGas16103,100Trinidad2004
MeOHGas15951,780Chile2005
Gas-to-LiquidsGas25207,720Qatar2005
MeOH/COCoal11,0901,760Nanjing PRC2006
Gas-to-LiquidsGas25207,720Nigeria2008
End UseFeedstockTrainsO2, psigO2, sT/DLocationOn-stream
43,000 sTPD
Up to /压力达1500 psig
IGCC /联合供电装置
GTL /天然气液化
H2 /氢气
Chemicals /化工
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中国南京化工Nanjing
ChemicalNANJING, PRC
业绩：中国,南京化工, 48,200 立方米/小时Experience: 48,200 Nm3/hr, Nanjing, PRC
Air Products Confidential Information 保密信息
GE Gasifier GE公司煤气化器Full Pump LOX 液氧泵内压缩10 MPa GOX Pressure 气氧压力99.6 % Purity Oxygen 氧气纯度Merchant LOX/LIN 液氧/液氮产品2001 Start-up 2001年开车成功
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业绩：空气化工Texas 工厂，80,000 Nm3/hrExperience: 80,000 Nm3/hr, Texas USA
Air Products Confidential Information 保密信息
GE/Texaco Gasifier 气化器7.7 MPa (77 Bar) 压力99.6 % Purity 氧气纯度Pump LOX Cycle 液氧泵内压缩循环Argon Production 氩气生产Liquids Facility 液体输送设施1999 Start-up 1999 年开车
>99.8% On-stream 投产可靠性大于99.8%
Air Products USAfor ExxonMobil
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业绩：特里尼达，82,000 立方米/小时Experience: 82,000 Nm3/hr, Trinidad
特立尼达AP (CIG) / MethanexPt. Lisas, Trinidad
Lurgi Methanol Process 鲁齐工艺Single Train ASU 单套空分Pumped LOX Cycle 液氧泵内压缩循环4.25 MPa GOX / 99.6 % 气氧压力/纯度No LOX Storage 不含液氧储罐2003 Start-up 2003年开车成功
>99.5% ASU On-stream 投产可靠性大于99.5%
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业绩：荷兰，玫瑰堡，业绩：荷兰，玫瑰堡，95,00095,000 立方米立方米//小时小时Experience: 95,000 NmExperience: 95,000 Nm33/hr, Netherlands/hr, Netherlands
荷兰Air Products
NETHERLANDS
Shell Gasification 壳牌煤气化炉
Elevated Pressure Cycle 高压循环
Single Train ASU 单套空分
7.7 MPa at 99.6% GOX 压力/纯度
GOX/LOX Storage 气/液氧储罐
Merchant LOXLIN/LAR 液体氧氮氩
1997 Start-up 1997年开车
> 99% On-Stream 投产可靠性大于99%
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业绩：卡塔尔，2 X102,200 立方米/小时Experience: 2 X 102,200 Nm3/hr, Qatar
卡塔尔Chevron Sasol
QatarSteam Driven MAC / BAC蒸汽驱动主空压机/增压机
Two Train ASU 两套空分装置
Pump LOX Cycle 液氧泵内压缩循环
4.25 MPa GOX 气氧压力
99.6 % Purity 纯度
2006 Start-up 2006年开车
现已投入运行现已投入运行NOW in OPERATIONNOW in OPERATION
ITM Oxygen离子传输膜制氧
Gasification /煤气化
High efficiency oxygen production withlower capital and operating costs /制氧效率高，可降低投资和操作成本
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什么是离子传输膜制氧？What is ITM Oxygen?
Uses ceramic membrane to separate O2 from air
通过使用陶瓷膜将O2从空气中分离出来
100% selective to O2 and extremely high flux (pure, very compact)
对氧气100%的选择性，非常高的流量（纯度高而且非常紧凑）
Feed air must be heated (800 –900 C) and compressed (200 –300 psig)
进料空气需加热(800 –900 C)，并加压(200 –300 psig)– Energy recovered from depleted air, typically through power
generation cycle通常经过发电循环来回收空气中的能量
– Integrates well with high temperature and pressure processes可以与高温高压流程进行很好的整合
Step-change savings compared to state-of-the-art cryogenic technology
与目前发展的深冷技术所带来的益处相比较
– 35% less capital + 35-60% less power节省35%资金+35-60%的能耗
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Single-stage air separation leads tocompact designs
单级空气压缩带来紧凑的设计
Low pressure drop on the high-pressure side 高压段的压降较小
High-temperature process has bettersynergy with power generationsystems
高温流程与电力生产系统之间具有更好的整合效果
Extraordinary flux enables largetonnage production economics
超凡的大流量带来大型制氧的经济效益
陶瓷膜：氧气供应技术的变革Ceramic Membranes: Revolutionary Technologyfor Tonnage Oxygen Supply
压缩空气压缩空气CompressedCompressed
AirAir
氧产品氧产品OxygenOxygenProductProduct
0.5 TPD 模块（大规模生产）0.5 TPD module(commercial-scale)
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ITM制氧的核心技术-平面薄膜片箱The Heart of ITM Oxygen Technology
空气Air
800-900°C200-300 psig
纯氧Pure Oxygen
ABC
薄膜Thinmembrane
多孔型薄膜支撑Porousmembranesupport
稠密的槽形中枢Dense, slottedbackbone
产品提取管道ProductWithdrawalTube
薄膜片间的间隔物Spacerbetween wafers
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离子传输膜制氧与电力生产系统的良好整合ITM Oxygen integrates well with power generation
空气AIR氧气OXYGEN
燃料FUEL
换热器HEAT
EXCHANGE
离子传输膜ION
TRANSPORTMEMBRANE
HRSG
蒸汽STEAM
氧气吹风机OXYGENBLOWER
电力ELECTRIC
POWER
氧气 OXYGEN
‘空气 AIR’
ITM Oxygen requires 35% less capital and 35-60% less energy离子传输膜制氧可节省35%成本和35-60%的能耗
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能力为5 TPD的试验性工厂正在测试过程中Testing is underway in 5 TPD Pilot Plant
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大规模生产的ITM模块是大型工业装置的简单组成部分Commercial-scale ITM modules are simplebuilding blocks for large tonnage units
往模块里插入平面膜片，然后添加模块以提高生产量Insert planar wafers into modules,Add modules to increase production
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相对比低温分离装置2000TPD ITM制氧容器的尺寸2000 TPD ITM Oxygen Vessel Size Compared toCryogenic Separation Unit
超高氧流量将带来更为紧凑的设计，并降低成本
The very highoxygen fluxleads to verycompact designsand drives downcost
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ITM O2, Possible DOE Proposal
0
2
4
6
8
10
2000 2005 2010 2015 2020
Year Onstream
Cap
acit
y(T
/D)
5
150
2000
第2阶段 Phase 2
第3阶段 Phase 3
FutureGen
ITM制氧的发展计划是和美国能源部一起开发的ITM Oxygen Development Plan Being DevelopedWith The U.S. DOE 与能源部2012年未来能源计划安
排一致 Consistent with currentDOE FutureGen timing of 2012
500
23
A significant portion of this report was prepared by Air Products and Chemicals, Inc. pursuant to aCooperative Agreement partially funded by the United States Department of Energy, and neither AirProducts and Chemicals, Inc. nor any of its contractors or subcontractors nor the United StatesDepartment of Energy, nor any person acting on behalf of either:
1. Makes any warranty or representation, express or implied, with respect to the accuracy,completeness, or usefulness of the information contained in this report, or that the use of anyinformation, apparatus, method, or process disclosed in this report may not infringe privatelyowned rights; or
2. Assumes any liabilities with respect to the use of, or for damages resulting from the use of, anyinformation, apparatus, method, or process disclosed in this report. Reference herein to anyspecific commercial products, process, or service by trade name, trademark, manufacturer, orotherwise, does not necessarily constitute or imply its endorsement, recommendation, or favoringby the United States Department of Energy. The views and opinions of authors expressed herein donot necessarily state or reflect those of the United States Department of Energy.
This paper was written with support of the U.S. Department of Energy underContract No. DE-FC26-98FT40343 and Contract No. DE-FC26-97FT96052.The Government reserves for itself and others acting on its behalf a royalty-free, nonexclusive, irrevocable, worldwide license for Governmentalpurposes to publish, distribute, translate, duplicate, exhibit and perform thiscopyrighted paper.
Disclaimer
Acknowledgment: DOE/NETL
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