Marking Sbp Mid Year 08

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    SULIT 4541/1/2/34541ChemistryMarking SchemeMei

    2008

    BA A!IA" S#$%LA$#M#"T#&IA" '#LA(A&A" MALA)SIA

    ********************************************** '#'#&I$SAA" '#&T#"!A A" TA U" 2008

    +%&M 5 C #MIST&)

    MA&$I"! SC #M# +%& 'A'#& 1, 2 A"- 'A'#& 3

    Peraturan pemarkahan ini mengandungi halaman bercetak.

    1

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    'A'#& 1

    1 B 21 D 41 D2 C 22 D 42 B

    3 B 23 B 43 D4 C 24 A 44 C5 D 25 C 45 B. A 2. A 4. A

    B 2 D 4 B8 A 28 A 48 D

    D 2 C 4 C10 D 30 A 50 B11 D 31 A12 C 32 B

    13 A 33 D14 A 34 A15 C 35 C1. B 3. A1 C 3 D18 C 38 B1 C 3 B20 C 40 D

    2

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    'A'#& 2 S#CTI%" A

    " & ric Mark

    1 a

    b (i)

    (ii)

    c

    d

    e (i)

    (ii)

    (iii)

    GHas stable / ctet electr n arrangement//! "alence electr n

    2A # 2H 2$ 2A$H # H 2

    %se a small pieces//use a & rcep// use a g gle

    G' 'D' A' '*

    Has same "alence electr n// "alence electr n is 1

    D 2 r + 2D

    ,can dra- the diagram & electr n arrangement c rrectl

    0 C rrect structure & at ms

    0 C rrect rati & at ms 1+2

    Has (neutral ) m leculeT%TAL

    11

    1

    1

    1

    1

    1

    2

    1

    102 a

    b(i)

    (ii)

    c

    d

    e (i)

    (ii)

    (iii)

    1

    P3+ s lid # li4uid

    56+ li4uid

    Heat energ abs rbed

    is used t "erc me the & rces & attracti n bet-een particles

    // Heat is abs rbed t "erc me the interm lecular & rces

    r+ i n/at m

    (1#1)

    he particles / m lecules m "e &aster

    7 dine/7 2//napthalene/C 18H !

    C pper/ Cu

    7 n

    Di&&usi n

    T%TAL

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    103 a (i) 9H 2 # : 2 2:H 9 1

    9

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    (ii)

    b (i)

    (ii)

    (iii)

    c (i)

    (ii)

    d

    ( ;tract &r m ) air

    :eutraliertili

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    c (i) (ii)

    d

    (An de )+Cu Cu 2# # 2e

    (Cath de )+ Cu 2# # 2e Cu

    lectr plating & metals/ ;tracti n & reacti"e metals

    T%TAL

    1

    1

    1

    10

    5 a

    b

    c 6i

    6ii

    9

    2H 2$ 2 $ 2 # 2H 2$

    :umber & m le & H 2$ 2 28 ; 2/1888 8.8=

    2 m l & H 2$ 2 pr duce 1 m l & $ 2 //

    :umber & m le & $ 2 8.8=/2 8.82

    @ lume' $ 2 8.2 ; 2=dm 9 =.! dm 9

    5ate & reacti n in e;periment 77 is higher than e;periment 7

    he c ncentrati n/number & m lecule per unit " lume &

    h dr gen per ;ide in 77 is higher

    he &re4uenc & c llisi n bet-een H 2$ 2 m lecule is higher

    he &re4uenc & e&&ecti"e c llisi n is higher

    @ lume & gas/cm 9

    ime(s)

    *abel a;es and a;esC rrect cur"e and label 7 and 77

    T%TAL

    1

    1

    1

    1

    1

    1

    1

    1

    11

    10

    . a A c mp und that c ntain element & carb n and deri"e &r m li"ing

    rganisms.

    1

    77

    7

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    6i

    6ii

    6iii

    c 6i

    6ii

    6iii

    9 6i

    6ii

    6iii

    C2H=

    ethene

    d uble b nd bet-een carb n at ms

    (a+ C C )

    Acidi&ied p tassium manganat (@77) // Acidi&ied p tassium

    dicr mate (@7)

    $;idati n

    Purple t c l urless // range t green

    C2H= # H 2$ C2H $H

    Alc h l

    emperature 988 C // Pressure 8 atm sphere // c ncentrated

    ph sph ric acid

    T%TAL

    1

    1

    1

    1

    1

    1

    1

    1

    1

    10

    S#CTI%" B

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    " & ric Mark

    a 6i

    6ii

    6ii

    C mp und that & rm -hen n n metal at m gain/recei"e/accept

    electr n that release/l se/d nate b metal at m t achie"e stable

    / ctet/duplet electr n arrangemen

    C mp und that & rm bet-een n n metal at m b sharing their

    "alence electr n t achie"e stable/ ctet /duplet electr n

    arrangement

    Bet-een P and 3

    At m has 1 "alence electr n

    At m l ses/d nates/trans&ers 1 electr ns t & rm # i n //

    # # e0 and attain stable ctet electr n arrangement

    At m has E "alence electr ns At m gains/recei"es/accept 1 electr n t & rm 0i n//

    # e0 0

    attain the stable / ctet electr n arrangement

    he t- pp sitel 0charged i ns// the # and 0 i n are

    b nded t gether b a str ng electr static & rce

    & rm a i nic c mp und -ith the & rmula //

    diagramn

    Fa; E

    Bet-een and

    At m has = "alence electr ns and at m has 1 "alence

    electr ns

    $ne at m c ntributes = electr ns and (each) at m

    c ntributes ne electr n & r sharing .

    At m shared = pairs & electr n -ith = at ms

    t attain a ctet /stable electr n arrangement respecti"el

    1

    1

    1

    1

    11

    1

    11

    1

    1

    111

    E

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    8 a

    c6i

    mpirical & rmula0 + rm :a sh -s simplest rati & at ms & each

    element in the c mp und

    F lecular & rmula0 + rm :a sh -s actual number & at ms &

    each element in the c mp und

    F lecular > rmula ( mpirical & rmula )n ( CH 2 )n

    5elati"e F lecular Fass ( CH 2 )n E8 12n # 2n E8

    1=n E8 n

    F lecular > rmula C H18

    1. Fetal is cleaned using sand paper

    2. A crucible and its lid are -eighed and the mass is rec ded

    9. Fetal is palced in the crucible. he crucible'lid and its

    c ntent is -eighed and the mass is rec rded.

    =. he crucible -ith its c ntent is heated str ng:y -ith ut

    lid.

    . hen metal start burn' the crucible is c "ered b its

    lid

    . the c "ered is raise a little at inter"als

    E. hen there is n m re reacti n' the lid is rem "ed and the

    crucible is heated str ngl & r a &e- minutes.

    !. C l the crucible and -eigh the crucible'its lid and its

    C ntent and rec rd the mass.

    I. he pr cess & heating' c ling and -eighing is repeated

    until c nstant is btained.

    18. (Precauti n step )J

    Cl se the crucible immediatel t pre"ent l ss &

    1

    1

    1

    11

    11

    1

    1

    1

    1

    1

    1

    1

    1

    !

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    lement $

    Fass(g) 1.98 8.92

    m l 1.98/ 8.82 8.92/1 8.82

    6implestrati

    1 1

    mpirical > rmula $

    $ A*

    1

    1

    1

    1

    1

    20

    I

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    'A'#&2 ;S#CTI%" C

    " 5ubric Mark

    a

    6i

    6ii

    c6i

    6ample ans-er +

    n # H:$ 9 n(:$ 9)2 # H 2$

    nC$ 9 # H:$ 9 n(:$ 9)2 # H 2$ # C$ 2

    n$ # H:$ 9 n(:$ 9)2 # H 2$

    An t-

    Fethan ic acid partial i ni

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    6ii

    9

    nC$ 9 # H 26$ = n6$ = # H 2$ # C$ 2

    :umber & m le ' H 26$ = 8.1( 188 )/1888

    8.81

    1 m l & H 26$ = pr duce 1 m l & n6$ =

    F le & n6$ = 8.81

    Fass & n6$ = 8.81 1 1

    1 .1 g

    6ample ans-er +

    1 amm nium chl ride as a &ertili

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    6i

    6ii

    Bacteria -ill pr duce lactic acid/H # i ns -hich neutrali

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    $ A*PAP 5 9

    1 (a) KK8 89 ? Feasuring and using numbers

    P*A:A 7$: 6C$5[Able to write all the times with units accurately]6uggested ans-er+

    t 1 .8 s' t 2 48.0 s , t 3 42.0 s , t 4 37.0 s , t 5 33.0 s

    9

    [Able to record all the times accurately but without units no decimal !lace]t1 .8 ' t 2 =!.8 ' t 9 =2.8 ' t = 9E.8 ' t 99.8 //// t 1 s ' t 2 =!.8 s ' t 9 =2 s' t = 9Es' t 99s

    2

    [Able to write at least 3 readin"s o# the times accurately] 1

    $o res!onse "i%en wron" res!onse 8

    1 (b) KK8 810 $bser"ati nP*A:A 7$: 6C$5

    [Able to state the colour o# sul!hur and the rate o# it is #ormed]6uggested ans-er+

    Pale / light ell - precipitate is sl -l & rmed

    9

    [Able to state the colour o# sul!hur]

    Pale / light ell - precipitate is & rmed.

    2

    [Able to state the #ormation o# !reci!itate]A precipitate is & rmed.

    1

    $o res !onse "i%en wron" res!onse 8

    1 (c) KK8 8 ? C mmunicatingP*A:A 7$: 6C$5

    [Able to construct a table correctly containin" three labeled columns withcorrect units and record all the time and 1 time accurately ]

    6uggested ans-er+

    emperature' C

    98 9 =8 = 8

    ime ' s .8 =!.8 =2.8 9E.8 99.81 / time ' s 01 8.81! 8.821 8.82= 8.82E 8.898

    9

    [Able to construct a table correctly containin" three labeled columns withcorrect units and record all the time and 1 time but not accurately]

    2

    [Able to write at least 3 readin"s o# the times accurately] 1

    $o res!onse "i%en wron" res!onse 8

    19

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    1 (d) (i) KK8 8 C mmunicatingP*A:A 7$: 6C$5

    [Able to draw a "ra!h accurately that consists o# the #ollowin" as!ects]6uggested ans-er+

    1. B th a;es labeled and units( a;is 0 temperature ' a;is ? 1/ time )

    2. All p ints trans&erred c rrectl9. %ni& rm scale' graph si

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    1

    30

    35

    40

    45

    50

    0.015 0.020 0.025 0.030X

    X

    X

    X

    X

    emperature / C

    1/time ' s 01

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    1(e) KK8 18 0 6tate "ariables

    P*A:A 7$: 6C$5[Able to state three %ariables and three action to be ta&en]6uggested ans-er+

    @ariable Acti n t be takenFanipulated+emperature

    Heat the s dium thi sulphates luti n at di&&erent temperature //%se di&&erent temperature.

    5esp nding+5ate & reacti n / time taken & r L Mmarks t disappear &r m "ie-.

    5ec rd the time taken & r L M markt disappear &r m "ie-.

    C ntr lled +C ncentrati n and " lume & H 26$ ='c ncentrati n and " lume & s diumthi sulphate s luti n' si

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    2(b) KK 8 8 0 Predicting

    P*A:A 7$: 6C$5[Able to state the %olta"e %alue]8. @

    9

    8. 9 ? 8. = @ // 8. ? 8. E @ 2N 8. = @ // O 8. E @ 1

    $o res!onse "i%en wron" res!onse 8

    2(c)KK 8 8! ? 7nterpreting DataP*A:A 7$: 6C$5

    [Able to arran"e the !osition o# all metals in an ascending order based ontendency to release electrons correctly]C pper O *ead O 7r n O inc O Fagnesium

    9

    [Able to arran"e the !osition o# all metals in descending order based ontendency to release electrons]Fagnesium O inc O 7r n O *ead O c pper

    2

    [Able to arran"e the !osition o# at least #our metals in ascendin" order basedon tendency to release electrons correctly]

    1

    $o res!onse "i%en wron" res!onse 8

    2(d) KK8 8I ? $perati nal de&initi nP*A:A 7$: 6C$5

    [Able to state the correct and com!lete o!erational de#inition]6uggested ans-er+

    he &urther the metal is =r m c >>er in the electr chemical series' the greateris their " ltage reading. //

    9

    [Able to "i%e incom!lete relationshi!]6uggested ans-er+

    he &urther apart the metal is in the electr chemical series' the greater the p tential di&&erence / " ltage reading.

    2

    [Able to state an idea]6uggested ans-er+

    he p siti n & metal in&luence the " ltage reading //pe & metal in&luence the " ltage reading.

    1

    $o res!onse "i%en wron" res!onse 8

    1E

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    9.(a) KK8 1821 ? 6tatement & pr blem

    P*A:A 7$: 6C$5[Able to ma&e a suitable statement o# !roblem]6uggested ans-er+

    H - t di&&erentiate bet-een magnesium nitrate s luti n and calcium nitrates luti n // H - t di&&erentiate bet-een magnesium i n and calcium i n

    9

    [Able to ma&e a suitable aim]6uggested ans-er+

    di&&erentiate the presence & magnesium i n and calcium i n b usinga4ue us amm nia s luti n.

    2

    [Able to state an idea o# statement o# !roblem or aim] 1

    $o res!onse "i%en wron" res!onse 8 9(b) KK8 1282 ? 6tating h p thesis

    P*A:A 7$: 6C$5[Able to state the relationshi! between mani!ulated %ariable and res!ondin"%ariable correctly]6uggested ans-er+

    7& the additi n & a4ue us amm nia s luti n & rms -hite precipitate -hich isins luble in e;cess amm nia a4ue us s luti n' then the s luti n tested ismagnesium nitrate. // 7& a4ue us amm nia s luti n is added and n changeccur then the s luti n tested is calcium nitrate.

    9

    [Able to state the relationshi! between mani!ulated %ariable and res!ondin"%ariable]

    2

    [Able to state an idea o# the hy!othesis] 1

    $o res!onse "i%en wron" res!onse 8

    9 (c) KK8 1282 ? 6tating "ariables

    P*A:A 7$: 6C$5[Able to state all the three %ariables correctly]6uggested ans-er+

    Fanipulated "ariable + magnesium nitrate and calcium nitrate // Fg 2# and Ca 2#

    5esp nding "ariable+ & rmati n & -hite precipitateC ntr lled "ariable + a4ue us amm nia s luti n[Able to state any two o# the %ariables correctly]

    [Able to state one o# the %ariables correctly or state idea re"ardin" %ariable]

    $o res!onse "i%en wron" res!onse

    1!

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    9(d) KK8 128 ? *ist & substances and apparatus

    P*A:A 7$: 6C$5[Able to state the list o# substances and a!!aratus correctly and com!letely]6uggested ans-er+

    est tube' dr pper' test tube rack8. m l dm 09 magnesium nitrate s luti n' 8. m l dm 09 calcium nitrate s luti n'a4ue us amm nia s luti n.

    9

    [Able to state the list o# substances and a!!aratus correctly but notcom!letely]6uggested ans-er+

    est tube8. m l dm 09 magnesium nitrate s luti n' 8. m l dm 09 calcium nitrate s luti n'a4ue us amm nia s luti n.

    2

    [Able to state an idea about the list o# substances and a!!aratus]6uggested ans-er+

    est tubemagnesium nitrate' calcium nitrate

    1

    $o res!onse "i%en wron" res!onse 8

    9(e) KK8 128= ? echni4ue /Precedure

    P*A:A 7$: 6C$5[Able to state a com!lete e(!erimental !rocedure]6uggested ans-er+

    1. 2 cm 9 & s luti n A is p ured int a test tube.2. A &e- dr ps & a4ue us amm nia s luti n are added int the test tube

    using a dr pper and the test tube is shaken -ell.9. 7& the precipitate is & rmed' a4ue us amm nia s luti n is added

    c ntinu usl until n &urther change ccurred / until e;cess=. he mi;ture is shaken -ell.

    . he changes ccur is rec rded in a table.

    . 6teps 1 t = are repeated using s luti n B.

    9

    [Able to state a com!lete e(!erimental !rocedure]1'2'9'='

    2

    [Able to state a com!lete e(!erimental !rocedure]1'2'9'

    1

    $o res!onse "i%en wron" res!onse 8

    1I

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    9(&) abulati n & data

    P*A:A 7$: 6C$5[Able to e(hibit the tabulation o# data correctly ]

    5eagent $bser"ati nest tube/6 luti n A est tube/6 luti n B

    A4ue usamm nia s luti n 9

    [Able to e(hibit the tabulation o# data less accurately ]

    5eagent est tube /6 luti n A est tube/6 luti n BA4ue usamm nia s luti n

    2

    [Able state an idea about the tabulation o# data] 1

    $o res!onse "i%en wron" res!onse 8

    #"- %+ MA&$I"! SC #M#

    28

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