MSDS Cesium.doc

7/24/2019 MSDS Cesium.doc

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Cesium

SAFETY DATA SHEET

1 PRODUCT AND SUPPLIER IDENTIFICATION

Product Name: Cesium Metal

Formula: Cs

Supplier: ESPI Metals

1050 Benson Way

Ashland, OR 95!0

Telephoe: "00#$%"#!5"1

Fa!: 5&1#&""#"%1%

Email: sales'es(imetals)*om

Emer"ec#: In+ota* "00#5%5#505% -.S/ o %5!#%!%#%500 -!& hou/

Recommeded U$e$: S*ienti+i* Resea*h

% HA&ARDS IDENTIFICATION

'HS Cla$$i(icatio )%* CFR 1*1+,1%++-: Sustan*es and mitues 2hi*h, in *onta*t 2ith 2ate, emit

+lammale 3ases, *ate3oy 1, S4in *oosioniitation, *ate3oy 1B, Eye dama3eiitation, *ate3oy 1)

'HS La.el Elemet$:

Si"al /ord: 6an3e

Ha0ard Statemet$: 7!$0 In *onta*t 2ith 2ate eleases +lammale 3ases 2hi*h may i3nite s(ontaneously,

7%1& Causes se8ee s4in uns and eye dama3e)

Precautioar# Statemet$: P!!% ee( a2ay +om any (ossile *onta*t 2ith 2ate, e*ause o+ 8iolent ea*tion

and (ossile +lash +ie, P!%1P!%! 7andle unde inet 3as) Pote*t +om moistue, P!$0 6o not eath dust o+ume, P!$& Wash s4in thoou3hly a+te handlin3, P!"0 Wea (ote*ti8e 3lo8es(ote*ti8e *lothin3eye

(ote*tion+a*e (ote*tion, P%01P%%0P%%1 I; SWAa4e o++ immediately all *ontaminated *lothin3) Rinse SI=

2ith 2atesho2e, P%%5P%%& Bush o++ loose (ati*les +om s4in and immese in *ool 2ate2a( in 2et

anda3es, P%0&P%&0 I; I=7A


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attention immediately)

S7IN: Remo8e *ontaminated *lothin3 i+ ne*essay) Bush o++ any 8isile solids) Wash the a++e*ted aea 2ith

2ate +o at least 15 minutes) See4 medi*al attention)

EYES: Immediately +lush eyes 2ith *o(ious amounts o+ 2ate, in*ludin3 unde eyelids +o at least 10#15

minutes) A 8i*tim may need assistan*e in 4ee(in3 thei eyelids o(en) A 5 solution o+ oi* a*id may e used

to neutali@e any emainin3 *austi*) See4 immediate medi*al attention)

2o$t Importat S#mptom$3E((ect$8 Acute ad Dela#ed: May *ause se8ee iitation and uns) See

se*tion 11 +o moe in+omation)

Idicatio o( Immediate 2edical Attetio ad Special Treatmet: >his (odu*t is *oosi8e and ea*ts

8iolently 2ith 2ate) >eatment should +ist emo8e as mu*h o+ the mateial as (ossile as ui*4ly as (ossile

and then +lush 2ith 8ey la3e uantities o+ 2ate) In3estion (esents a sin3ula (olem as emesis may

(odu*e eso(ha3eal dama3e ando as(iation dama3eD dilution 2ith 2ate o othe 2ate#*ontainin3 mateials

may (odu*e a ea*tion that ea*eates the *oosi8e a*ti8ity) Consideation may e 3i8en to 3asti* la8a3e

2ith a la3e diamete tue +o emo8al o+ mateial and then dilution 2ith la3e amounts o+ 2ate)

Eso(ha3os*o(y may e o+ assistan*e in this (o*edue and to assess etent o+ dama3e) >eatment is othe2ise

sym(tomati* and su((oti8e)

9 FIREFI'HTIN' 2EASURES

E!ti"ui$hi" 2edia: .se *lass 6 metal etin3uishin3 a3ent su*h as Met#


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a*ids, oidi@es and halo3ens) See se*tion 10 +o moe in+omation on in*om(atile mateials)

> E?POSURE CONTROLS AND PERSONAL PROTECTION

E!po$ure Limit$: Cesium

OSHA3PEL: =o e(osue limit estalished

AC'IH3TL@: =o e(osue limit estalished

Appropriate E"ieeri" Cotrol$: 7andle in an inet 3as su*h as a3on) 7andle in an en*losed, *ontolled

(o*ess) .se lo*al ehaust to maintain e(osue at lo2 le8els) Whene8e (ossile the use o+ lo*al ehaust

8entilation o othe en3ineein3 *ontols is the (e+eed method o+ *ontollin3 e(osue to aione dust and

+ume to meet estalished o**u(ational e(osue limits) 6o not use toa**o o +ood in 2o4 aea) Wash

thoou3hly e+oe eatin3 o smo4in3) 6o not lo2 dust o++ *lothin3 o s4in 2ith *om(essed ai) Pe(ae +o the

(ossiility o+ a +ie) ee( etin3uishin3 a3ents, tools +o handlin3 and (ote*ti8e *lothin3 eadily a8ailale)

Idi:idual Protectio 2ea$ure$8 Such a$ Per$oal Protecti:e E;uipmet:

Re$pirator# Protectio: Wea a =IOS7MS7A a((o8ed es(iato 2hen hi3h *on*entations ae (esent)

E#e Protectio: Al2ays 2ea a((o8ed *hemi*al s(lash (oo+ 3o33les)

Si Protectio: Rue 3lo8es, +lame etadant (ote*ti8e 2o4 *lothin3)

* PHYSICAL AND CHE2ICAL PROPERTIES

Appearace:

Form: Solid

Color: Fold#tinted sil8e metalli*

Odor: =ot detemined

Odor Thre$hold: =ot detemined

pH: =A

2elti" Poit: !")& oC

Boili" Poit: $$9)% oC

Fla$h Poit: =A

E:aporatio Rate: =A

Flamma.ilit#: ;lammale solid

Upper Flamma.le Limit: =o data

Loer Flamma.le Limit: =o data

@apor Pre$$ure: 1 mm at !9 oC

@apor De$it#: =A

Relati:e De$it# )Speci(ic 'ra:it#-: 1)""5 3** at 15 oC

Solu.ilit# i H%O: 6e*om(oses

Partitio Coe((iciet )octaol3ater-: =ot detemined

Autoi"itio Temperature: =o data

Decompo$itio Temperature: =o data

@i$co$it#: =A

1+ STABILITY AND REACTI@ITY

Reacti:it#: =o data

Chemical Sta.ilit#: Stale unde e*ommended stoa3e *onditions)

Po$$i.ilit# o( Ha0ardou$ Reactio$: Cesium ea*ts e(losi8ely 2ith 2ate eleasin3 +lammale hydo3en

3as)

Coditio$ to A:oid: E(osue to 2ate o ai) 7eat, s(a4s, +lame)

Icompati.le 2aterial$: Wate, al*ohols, oidi@es, halo3ens, oy3en, *aon dioide, halo3enated

halo*aons, sul+u, (hos(hous, and mineal a*ids)

Ha0ardou$ Decompo$itio Product$: Cesium oides, *esium hydoides, hydo3en 3as)

11 TO?ICOLO'ICAL INFOR2ATION

Liel# Route$ o( E!po$ure: Podu*t as shi((ed does not (esent an inhalation o *onta*t ha@ad) 7o2e8esuseuent o(eations may *eate dusts o +umes o deis 2hi*h *ould e inhaled o *ome into *onta*t 2ith

s4in o eyes)


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S#mptom$ o( E!po$ure: Inhalation o+ dust o +umes 2ill se8eely iitate the nasal *a8ity and es(iatoy

ta*t) In3estion 2ill *ause uns and (e+oations o+ the 3astointestinal ta*t) Se8ee themal uns, *oosion

and ul*eation o+ the s4in any eyes may o**u on die*t *onta*t)

Acute ad Chroic E((ect$: Cesium is hi3hly ea*ti8e, es(e*ially 2ith moistue and thee+oe etemely

*oosi8e to tissue) I+ *esium i3nites, it 2ill *ause themal uns) >he metal a(idly +oms *austi* and hi3hly

*oosi8e al4ali hydoide 2ith e8olution o+ heat) Se8ee themal and *hemi*al uns 2ill esult at e8ey (oint o+

human *onta*t) Choni* in3estion o+ *esium has een +atal to laoatoy animals, (ossily due to the

e(la*ement o+ (otassium) Choni* e(osue also *an ha8e lood and neuomus*ula e++e*ts)

Acute To!icit#:


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Prepared .#: ESPI Metals

Re:i$ed3Re:ieed: Guly !015

Cesium

LE2BAR DATA 7ESELA2ATAN

1 PRODU7 DAN PE2ASO7 IDENTIFI7ASI

Nama Produ Cesium


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CAS 4 &&0#&$#!

5 100

EC 4 !%1#155#&

6 TINDA7AN PERTOLON'AN PERTA2AI(orma$i umum6ianHu4an untu4 memili4i (enHe(it, (inset, (en*a4a atau eea(a Henis menea(4an di

tan3an untu4 men3ha(us (oton3an lo3am dai 4ulit atau (a4aian dalam (eisti2a 4e*ela4aan) SeHumlah esaai haus di3una4an untu4 memilas atau memanHii daeah 4onta4 sea3ai Humlah 4e*il ai da(at mela4u4an

leih eahaya dai(ada ai4)

TERHISAP7a(us 4oan 4e udaa se3a)Men*ai (ehatian medis se3ea)

TertelaCe(at men3ha(us matei dai mulut dan ilas den3an ai)Gan3an mema4sa4an muntah)Men*ai(ehatian medis se3ea)

7ULIT


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menutu( tum(ahan 4e*il yan3 teHadi)Menya(u atau meau()>em(at4an dalam 2adah lo3am 4ein3 dilen34a(i

den3an tutu( dan men33anti tutu( se3ea)7al ini da(at dila4u4an ah4an Hi4a lo3am tea4a)6en3an tutu(di tem(at o4si3en a4an di4elua4an dan a(i a4an 4elua)

Tidaa pece"aha li"u"aGan3an diia4an masu4 4e saluan atau dile(as 4e lin34un3an)

= PENAN'ANAN DAN PENYI2PANAN

Pece"aha utu Pea"aa AmaSan3at disaan4an ah2a setida4nya dua oan3 teliat dalam

(enan3anan dan (en33unaan ahan ini)Cesium sehausnya hanya ditan3ani oleh tena3a telatih men3ena4an(a4aian (elindun3 yan3 te(at dan (ealatan yan3 dinyata4an dalam (asal ") 7andle dalam, (oses

di4endali4an tetutu( di a2ah 3as (elindun3 4ein3 se(eti a3on) Pasti4an ah2a semua (elen34a(an dan

(ealatan yan3 a4an di3una4an dalam (enan3anan yan3 ena#ena 4ein3)Melindun3i dai udaa dan

4elemaan)Melindun3i dai (anas, a(i dan sume a(i)6ianHu4an untu4 menHa3a 2adah (asi atau soda au

4ein3 tesedia di aea 4eHa)Gauh4an ahan yan3 mudah tea4a dai aea 4eHa)7indai 4onta4 den3an 4ulit

dan mata)7indai men*i(ta4an deu)7indai men3hiu( deu atau asa()Cu*i sam(ai esih seelum ma4anatau meo4o4)

7odi$i Pe#impaa #a" Ama8 terma$u ada#a iompati.ilita$

Melindun3i dai o4si3en dan

ai)Melindun3i dai ua( ai 4elemaan)Menyim(an di a2ah 3as inet 4ein3 se(eti a3on)Menyim(an

dalam 2adah tetutu()Wadah (enyim(anan haus diei lael untu4 menunHu44an isinya)Wadah haus

di(ei4sa se*aa e4ala untu4 memei4sa inte3itas 2adah)Aea (enyim(anan haus eas dai mudah

tea4a dan sume (en3a(ian)Gan3an sim(an esama#sama den3an asam, o4sidasi dan halo3en) 7ONTROL PAPARAN DAN PERLINDUN'AN PRIBADI

Bata$ ter.ua Cesium

OSHA 3 PEL >ida4 ada atas (a(aan didii4an

AC'IH 3 TL@ >ida4 ada atas (a(aan didii4an

7otrol Tei #a" $e$uai>an3ani 3as inet se(eti a3on)Menan3ani dalam, (oses di4endali4an

tetutu()Funa4an (emuan3an lo4al untu4 mem(etahan4an e4s(osu (ada tin34at endah) Bila mun34in(en33unaan 8entilasi (emuan3an lo4al atau 4ontol te4ni4 lainnya adalah metode yan3 disu4ai

men3endali4an (a(aan deu di udaa dan asa( memenuhi didii4an atas (a(aan)Gan3an 3una4an

tema4au atau ma4anan di aea 4eHa)Cu*i sam(ai esih seelum ma4an atau meo4o4)Gan3an meniu( deu

dai (a4aian atau 4ulit den3an udaa te4om(esi)Mem(esia(4an 4emun34inan 4ea4aan)Gauh4an(emadam a3en, alat untu4 (enan3anan dan (a4aian (elindun3 tesedia)

Tidaa Perlidu"a idi:idu8 Seperti Alat Pelidu" Pri.adi

Perlidu"a perapa$aPa4ai =IOS7 MS7A disetuHui es(iato 4eti4a 4onsentasi tin33i yan3 hadi)

Perlidu"a mataSelalu mema4ai disetuHui (e*i4an 4imia 4a*amata u4ti)

Perlidu"a ulitSaun3 tan3an 4aet, tahan a(i (a4aian 4eHa (elindun3)

* SIFAT FISI7 DAN 7I2IAPeampila

Form Padat

/ara Emas#(ea4 e2ana metali4

Bau >ida4 ditentu4an

Bau Thre$hold >ida4 ditentu4an

pH = A

2ecair Titi !")& oC

Titi didih $$9,% oC

Titi N#ala = ATi"at Pe"uapa = A


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2udah ter.aar Mudah tea4a (adat

Bata$ Ata$ mudah ter.aar >ida4 ada data

Bata$ mudah ter.aar le.ih redah >ida4 ada data

Teaa uap 1 mm di !9 oC

De$ita$ Uap = A

Relati( De$it# )Speci(ic 'ra:it#- 1,""5 3 ** (ada 15o

C7elaruta dalam H%O >euai

7oe(i$ie parti$i )otaol 3 air- >ida4 ditentu4an

Suhu N#ala >ida4 ada data

Suhu pe"uraia >ida4 ada data

@i$o$ita$ = A

1+ STABILITAS DAN REA7TI@ITASReati:ita$>ida4 ada data

7imia Sta.ilita$Stail di a2ah 4ondisi (enyim(anan yan3 disaan4an)

7emu"ia Rea$i Ber.aha#aCesium eea4si e4s(losi+ den3an ai mele(as4an 3as hido3en yan3mudah tea4a)

7odi$i #a" dihidariPa(aan ai atau udaa)Panas, (e*i4an, a(i)

Baha #a" tida ompati.elAi, al4ohol, o4sidasi, halo3en, o4si3en, 4aon dio4sida, halo*aonstehalo3enasi, sul+u, +os+o, dan asam mineal)

Pe"uraia Produo4sida Cesium, hido4sida *esium, 3as hido3en)

11 INFOR2ASI TO7SI7OLO'I

Rute emu"ia E!po$urePodu4 sea3ai di4iim4an tida4 menyaHi4an inhalasi atau 4onta4

ahaya)=amun o(easi ei4utnya da(at memuat deu atau asa( atau (uin3#(uin3 yan3 isa tehiu( atauesentuhan den3an 4ulit atau mata)

'eala PaparaMen3hiu( deu atau asa( san3at a4an men3iitasi on33a hidun3 dan saluan

(ena(asan)>etelan a4an menyea4an lu4a a4a dan (e+oasi dai saluan (en*enaan)ida4 ada data

Peumpua .iolo"i$ Pote$i>ida4 ada data

2o.ilita$ di Taah>ida4 ada data

E(e $ampi" lai#aGan3an ia4an ahan yan3 a4an dile(as4an 4e lin34un3an)>ida4 ada in+omasi yan3ele8an lanHut tesedia)

1 PERTI2BAN'AN PE2BUAN'AN


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Lim.ah 2etode Pem.ua"a

ProduBuan3 sesuai den3an ;edeal, =e3aa dan (eatuan lo4al)

7ema$aBuan3 sesuai den3an ;edeal, =e3aa dan (eatuan lo4al)

16 INFOR2ASI AN'7UTAN

Nomor UN .=1&0

PBB Pe"irima Proper Nama Cesium -Cesium/

Tra$porta$i 7ela$ Baha#a &)%

Paci" 'rup A4u

7elauta Poluta >ida4

Tidaa pece"aha hu$u$ Pein3atan, @at yan3, dalam 4onta4 den3an ai men3elua4an 3asyan3 mudah tea4a)

19 INFOR2ASI PERATURAN

TSCA Terda(tarSemua 4om(onen teda+ta)Peratura )EC- No 1%=%3%++> )CLP-Bahan dan *am(uan yan3, dalam 4onta4 den3an ai men3elua4an3as yan3 mudah tea4a, 4ate3oi 1, 4oosi+ (ada 4ulit iitasi, 4ate3oi 1B, 4eusa4an mata iitasi, 4ate3oi

1)

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MSDS Cesium.doc