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8/10/2019 Phn xng parex UOP
1/19
Opportunities andOpportunities andDevelo ments inDevelo ments in araara--X leneX lene
ProductionProductionGuangdong Qu
2014 China PX Development ForumApril 10-11, 2014
2014 UOP LLC. All rights reserved. UOP 6123-1
,
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Aromatics Technology Innovation
Latest UOP technologies enable the lowestcost of production of aromatics
UOP 6044P-2
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Polyester chain drivers continue tobe strong
ACT FRCST
Key demand factors:
Global economy Regional Middle Class Growth Substitut ion (container applications) Recycle & Renewable Raws
PCI
Fundamentals remain good
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Global pX demand will increase by75% in 10 years
Current View Q1 2014
~30 M~30 M
~ -
~~
Source: UOP (SBA-CCI & PCI)
New pX capacity needed to match demand growth
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Chinas growing economydrives global pX demand
35 M
40 M
-
China
Other Asia Pacific
30 M
India
N AmericaME
Europe 19 M
20 M
tric
Tons
10 M
15 MM
M
5 M
Almost 20 million tons of p-X demand growth in china alone
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China will not be able to meet itspara-Xylene demand alone
To
ns
Metri
Deficit in China met via imports from Middle East andAsia Pacific regions
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Para-Xylene margins have been atattractive levels
PX naphtha marginshave begun to decline &expec e o con nue n
2014 2015
2011-2013 s reads haveexceeded most every prioryear average
was a goo year ornaphtha based producers;mixed xylenes based
roducers have been
squeezed by MX suppliers
Naphtha based
advantage
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p-Xylene Cost of Production impacted byregional utility costs
$1,065 $1,044 $1,041$1,000 $988
1,000
1,200
800
PX
Capital Charges
Fixed COPCat & Chems
Utilities
$888 $870 $896$803
$859
400$/M
NCOP
CCOP
0
200
East
Basis Assumed:Energy Values, /mm btu: AP = $5.50 USGC = $3.9 China = $6.00 India = $4.20 ME = $1.25Location Factors: AP = 1.02 USGC = 1.00 China = 0.80 India = 0.77 ME = 1.08
Reducing COP drives profitabil ity UOP 6044P-8
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Latest technology advances drive COPreduction
COP ContributorsCOP ContributorsAdvanced CatalystsAdvanced Catalysts
and Adsorbentsand AdsorbentsEfficient Designs,Efficient Designs,
World Class ServiceWorld Class Service
FeedstockFeedstock Reduced byproduct formation,Reduced byproduct formation,enhanced recoveriesenhanced recoveriesMaximizing productMaximizing product
recoveries drives feedstockrecoveries drives feedstockutilizationutilization
Utilities
High activity for reduced energyinput; High recoveries and
maximum yields for reduced
recycles
Advanced processintegration maximizes
energy efficiency
Capital High activities and capacity forsmaller equipmentDesigns optimized for minimal
capital overall
Operations(Contributes to Fixed Costs)
High activity and capacity extendintervals between turnarounds
Designs reduce maintenanceneeds; high on-streamavailability
UOP technology minimizes COP UOP 6044P-9
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Latest Generation UOP AromaticsTechnologies Product Portfolio
RaffinateBenzene
EDSulfolane
Unit
EDSulfolane
Unit
PlatformingUnitPlatformingUnit
B T
ReformateSplitter Heavy
AromaticsTA-32
NHTNHTA10+
UnitUnit
ADS-47
I-500
Naphthap-Xylene
Light EndsIsomarUnit
IsomarUnit
ParexUnit
ParexUnit
XyleneColumn Deheptanizer
Column
UOPs innovation delivers new products for key processes!
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Continuous innovation at UOP drivestechnical leadership in aromatics
Next Gen Aromatics Complex Design ImpX Rx System for Platforming Unit UOP I-600 Isomar EB Isom Catalyst
- somar ea a a ys Low xy lenes losses 3 operating units
UOP Tatoray PTD Process Low xylenes losses
UOP R-284 Platforming Catalyst Improved aromatics yields
UOP ADS-47 Parex Adsorbent Over 25% extra throughput 7 operating units
Recently Commercialized
UOP R-334 PlatformingTM
Catalyst Maximizes aromatics yields
UOP TA-32 Tatoray Catalyst Improved activity & yields
rs un s u n rs un s u n
Energy Efficient Aromatics Complex First unit s/u in 2014
UOP TA-30 Tatoray Catalyst
2004 2005 2006 2007 2008 2009 2010 2014+20122011
3 operating units
2013
+22% ROI+15% ROIBase ROI +30% ROINet Energy Required
Reduced by 1/3 vs.
Best 2009 Designs
Addit ional 14%+Energy
Reduction vs.
+45% ROI
CAPEX and OPEXReductions vs.
Best 2012 Design
Best 2010 Design
Substantial CAPEX/OPEX reductions over last 4 years
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ADS-47 Adsorbent Developmentand Commercialization
Drop-in replacement for existingadsorbent resulting in low capital costsfor ca acit additions
-ADSADS--47 Adsorbent47 Adsorbent is theis theresult ofresult of improvingimproving massmass
transfer and capacitytransfer and capacity
Up to 50% capacity increase in existingunits
-
same proven chemistrysame proven chemistry
(~ $2-5 / ton of pX benefit over ADS-37)
Significantly lower capital per ton of pX(less adsorbent, smaller chambers) -
-
Fast revamp execution; implementacross a standard turnaround
Seven commercial units successfull
1990 ADS-27
loaded with ADS-47 Adsorbent since2011
Five new unit designs have been based1971 ADS-3
1980 ADS-7
on ADS-47 Adsorbent
UOPs Parex technology leads innovation and value
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UOP TA-32 Tatoray catalyst setsnew standard for activity & stability
Twice the catalyst li fe Hi her activit b 30C
TA-32 BenefitsNovel & proprietaryNovel & proprietaryzeolitezeolite structure atstructure at
--
Novel & proprietaryNovel & proprietaryzeolitezeolite structure atstructure at
-- Lower heater firing: $1/MT pX IRR Improvement by +1 to 3%
Higher xylenes yield-
More than 1% higher xylene selectivity Value improved by > $3/MT pX
Lower feed requirementerature,
C
Up to 50% lower ring loss
Broad range of operating parameters Designs optimized to maximize value
Temp
TA-32
More Stable
Commercially Proven Nearing two year of stable performanceCatalyst L ife
Improved profitabili ty through selectivity and catalyst life
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UOP I-500 Isomar catalyst sets newstandard for isomerization
Improved Xylene Selectivity ~0.5 % better Xylene Retention
High Paraxylene Selectivi ty ~24% pX/X at high WHSV
Higher EB Conversion Activity 8 10C better than I-300
High Benzene Selectivity > 98% compared to 90% Bz Sel
High Benzene Purity > 99.8% Benzene Purity
I-500 catalyst improves COP by ~ $3-9 / ton pX
UOP 5892B-14
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Latest products improve yields andcapital investment effectiveness
BaseBase LatestLatest COP ReductionCOP Reduction
For new aromatics complex designed with the latest products:
CCR Platforming R-264 R-284 $3+ /MT pXIsomar I-300/350 I-500 $1-8* / MT pX
- -
Parex ADS-37 ADS-47 $3 / MT pX
Total COP Reduction Over $10 / MTOver $10 / MT ppXX
* For complexes without transalkylation
d Cos
ts
Latest products substantiallyreduce production costs
Re
du
c
Pro
duction
UOP 6044P-15
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Integrated process design reduces energycosts by over 53%
Total EnergyRequirement(MMBtu/hr)
Energy Savings(MMBtu/hr)
Energy Savings@ $6 / mm Btu
(MM$/year)*
UOP Design 2009 1150 Base Base
UOP Design 2011 455 (40%) $22.9
Energy Benefit / MT pX 4.2 MMBtu / MT pX $26/ MT pX
ADS-47 Energy Benefit /MT pX $5 / MT pX
TA-32 Energy Benefit / MT pX $1 / MT pX
I-500 Energy Benefit / MT pX $3 / MT pX
Addit ional Energy Benefitfrom Upgraded Products
1.2+ MMBtu / MT pX $9 / MT pX
*Aromatics Complex pX Capacity = 900,000 tonne pX / year
Total Energy Benefit / MT pX 5.6+ MMBTU / MT pX $35 / MT pX
UOP 5625E-16
Latest products and integrated design substantially improveenergy efficiency
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UOP technology advances enablelarger scale plants
Parex Adsorbent Train Size Increases Over Time
1800
1200
1400
KMTA
600
800
1000
-Xylene,
0
200
400
1970 1975 1980 1985 1990 1995 2000 2005 2010 2015 2020
Commissioned In Design / Construction
UOP continues to lead the market in all size pX complexes
Source: UOP licensed uni t data
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Summary
Since 2009, UOP has achieved $45+ per ton reductionin COP of pX
Catalyst and adsorbent advancements have improved yields
and selectivities, but also improve energy efficiency
Latest technolo develo ments have enabled sin le traincomplex designs in excess of 1.5 MM TPA pX
Our development pipeline is loaded with projects that
UOPs Parex/Isomar/Tatoray portfolio is the clearleader in highest margin pX in the market
OFITABILIT
P
to address diverse challenges
UOP 6044P-18
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UOP 6123-19