COBRECu(+2a) + 2e- = Cu

T deltaH deltaS deltaG KK kJ J/K kJ

298.150 -64.900 0.471 -65.040 2.488E+011303.150 -64.889 0.507 -65.043 1.615E+011308.150 -64.892 0.498 -65.045 1.064E+011313.150 -64.902 0.465 -65.048 7.098E+010318.150 -64.916 0.422 -65.050 4.797E+010323.150 -64.930 0.377 -65.052 3.281E+010328.150 -64.945 0.333 -65.054 2.270E+010333.150 -64.960 0.286 -65.055 1.588E+010338.150 -64.973 0.249 -65.057 1.123E+010343.150 -64.979 0.230 -65.058 8.017E+009348.150 -64.978 0.233 -65.059 5.780E+009353.150 -64.968 0.261 -65.060 4.206E+009358.150 -64.949 0.315 -65.062 3.089E+009363.150 -64.919 0.399 -65.064 2.288E+009368.150 -64.876 0.515 -65.066 1.708E+009

Formula FM Conc. Amount Amountg/mol wt-% mol g

Cu(+2a) 63.546 99.998 1.000 63.546e- 0.001 0.002 2.000 0.001

g/mol wt-% mol gCu 63.546 100.000 1.000 63.546

ZINC m ,||||||||||

Zn(+2a) + 2e- = ZnT deltaH deltaS deltaG KK kJ J/K kJ

298.150 153.385 20.572 147.252 1.585E-026303.150 153.486 20.908 147.148 4.399E-026308.150 153.574 21.194 147.043 1.182E-025313.150 153.654 21.453 146.936 3.079E-025318.150 153.731 21.697 146.828 7.787E-025323.150 153.807 21.934 146.719 1.914E-024

328.150 153.883 22.167 146.609 4.581E-024333.150 153.959 22.395 146.498 1.068E-023338.150 154.036 22.627 146.385 2.431E-023343.150 154.121 22.874 146.271 5.402E-023348.150 154.212 23.138 146.156 1.174E-022353.150 154.312 23.423 146.040 2.497E-022358.150 154.421 23.731 145.922 5.201E-022363.150 154.541 24.064 145.803 1.063E-021368.150 154.674 24.426 145.681 2.130E-021

Formula FM Conc. Amount Amountg/mol wt-% mol g

Zn(+2a) 65.380 99.998 1.000 65.380e- 0.001 0.002 2.000 0.001

g/mol wt-% mol gZn 65.380 100.000 1.000 65.380

TOTAL

Cu(+2a) + Zn = Zn(+2a) + CuT deltaH deltaS deltaG KK kJ J/K kJ

298.150 -218.285 -20.101 -212.292 1.570E+037303.150 -218.376 -20.401 -212.191 3.672E+036308.150 -218.466 -20.696 -212.088 8.999E+035313.150 -218.556 -20.988 -211.984 2.305E+035318.150 -218.647 -21.274 -211.879 6.161E+034323.150 -218.737 -21.557 -211.771 1.714E+034328.150 -218.828 -21.835 -211.663 4.956E+033333.150 -218.919 -22.109 -211.553 1.487E+033338.150 -219.009 -22.378 -211.442 4.619E+032343.150 -219.100 -22.644 -211.329 1.484E+032348.150 -219.190 -22.905 -211.215 4.924E+031353.150 -219.280 -23.163 -211.100 1.685E+031358.150 -219.370 -23.416 -210.984 5.938E+030363.150 -219.460 -23.665 -210.866 2.153E+030368.150 -219.550 -23.911 -210.747 8.020E+029

Formula FM Conc. Amount Amountg/mol wt-% mol g

Cu(+2a) 63.546 49.289 1.000 63.546

Zn 65.380 50.711 1.000 65.380g/mol wt-% mol g

Zn(+2a) 65.380 50.711 1.000 65.380Cu 63.546 49.289 1.000 63.546

E vs. SHEV logK 1/T

0.34 11.4135301 0.00335401640.34 11.2257073 0.0032986970.34 11.0439893 0.0032451728 r20.34 10.8680557 0.00319335780.34 10.6976203 0.00314317150.34 10.532423 0.00309453810.34 10.3722242 0.00304738690.34 10.2167985 0.00300165090.34 10.0659353 0.00295726750.34 9.91944681 0.0029141775 r20.34 9.77716007 0.00287232510.34 9.63891355 0.00283165790.34 9.50455668 0.00279212620.34 9.37394911 0.00275368310.34 9.24696018 0.0027162841

Volumel or ml0.000 ml0.000 ml

l or ml7.092 ml

,||||||||||

E vs. SHEV logK 1/T

-0.76 -25.8402842 0.0033540164-0.76 -25.3961861 0.003298697-0.76 -24.9662374 0.0032451728 r2-0.76 -24.5497918 0.0031933578-0.76 -24.1462301 0.0031431715-0.76 -23.7549622 0.0030945381

-0.76 -23.3754303 0.0030473869-0.76 -23.0071094 0.0030016509-0.76 -22.6495043 0.0029572675-0.76 -22.3021382 0.0029141775 r2-0.76 -21.9645574 0.0028723251-0.76 -21.6363325 0.0028316579-0.76 -21.3170559 0.0027921262-0.76 -21.0063405 0.0027536831-0.76 -20.7038182 0.0027162841

Volumel or ml 0.000 ml0.000 ml

l or ml9.157 ml

Log(K)logK 1/T

37.196 37.2538142 0.003354016436.565 36.6218934 0.00329869735.954 36.0102267 0.0032451728 r235.363 35.4178476 0.003193357834.790 34.8438503 0.003143171534.234 34.2873853 0.003094538133.695 33.7476545 0.003047386933.172 33.2239079 0.003001650932.665 32.7154396 0.002957267532.171 32.221585 0.0029141775 r231.692 31.7417175 0.002872325131.227 31.2752461 0.002831657930.774 30.8216126 0.002792126230.333 30.3802897 0.002753683129.904 29.9507783 0.0027162841

Volumel or ml0.000 ml

9.157 mll or ml0.000 ml7.092 ml

G = A + BT-0.00033808 -64.94159461.2391E-005 0.00413687

0.9828354 0.00103674744.372652 130.00080007 1.3973E-005

logK = A + B(1/T)3397.693 0.01792406

0.222 0.000669171.000 0.00016854

235250520.997 136.682 3.6927E-007

G = A + BT-0.02242331 153.9565130.00013452 0.044907830.99953239 0.0112543427788.0016 133.51963536 0.00164658

logK = A + B(1/T)-8054.09555 1.170272162.32409801 0.007020550.99999892 0.0017682112009493.1 1337.5485616 4.0645E-005

G = A + BT0.02208524 -218.8981080.00014478 0.048335250.99944163 0.0121132923269.0159 13

3.414304 0.00190751

logK = A + B(1/T)11451.7881 -1.15234812.51344333 0.007592510.99999937 0.0019122720759094.5 1375.9112867 4.7538E-005

Eth(25C)OXIDACION Zn = Zn(+2a) + 2 e- 0.76REDUCCIONCu(+2a) + 2e- = Cu 0.34TOTAL Cu(+2a)+Zn = Cu + Zn(+2a) 1.10

Eth(95C) pE(95C) DeltaG(25C)DeltaG(95C)logk(25C)0.76 12.920142 10.351909 -147.25192 -145.6814 25.8402840.34 5.706765 4.6234801 -65.040469 -65.065782 11.41353

1.10 18.62690714.975389 -212.2924 -210.7472 37.253814

pE(25C)

logk(95C)20.7038189.246960229.950778

HSCCALCULOS