金属有机化学国家重点实验室学科带头人现状与需求

现有人员 目前学科方向陆熙炎院士 过渡金属有机化学戴立信院士 不对称催化麻生明院士 过渡金属有机化学侯雪龙研究员 不对称催化

施敏研究员 过渡金属有机化学丁奎玲研究员 不对称催化唐勇研究员 主族金属有机化学，高分子化学刘元红研究员 钛、锆金属有机化学，过渡金属催化陈耀峰研究员 稀土金属有机化学

游书力研究员 过渡金属有机化学，不对称催化

刘国生研究员 过渡金属有机化学邓亮研究员 廉价金属有机化学李玉学研究员 计算金属有机化学黄正研究员 金属有机化学和催化

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段伟良副研究员 过渡金属催化余金权研究员 碳氢键活化反应

发展学科方向 需求计划人数金属催化的小分子活化 1

金属络合物及反应化学 1

后过渡金属有机化学 1

前过渡金属有机化学 1

主族元素金属有机化学 1

金属有机计算化学 1

一、科研工作与成果按照国家科技部最新要求和规定，2012年实验室自主研究课题共计资助

660.5万元，包括自由探索课题 14项，资助 140万，重点课题 5项，资助 520.5

万元。今年实验室主持的国家和省部委的重大重点项目有： (1)科技部 973项目 1

项，科技支撑项目 1项；(2) 国家基金委创新群体项目 1项、重大研究计划重点支撑项目 1项、重点项目 2项、国际合作项目 1项；(3)中科院知识创新方向性重大项目 1项、海外团队项目 1项；(4)上海市资助项目 6项。作为课题骨干参加的国家和省部委的重大重点项目有：(1) 973项目 5项；(2)国家基金委重点项目 1

项；另外实验室还承担了(1)国家基金委其他项目 22项；(2)其他省部委及中科

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院项目 13项；横向项目 8项。实验室 2012年共发表了 282篇论文（含客座人员发表论文），其中 J. Am.

Chem. Soc. 12篇，Angew. Chem. Int. Ed. 26篇。其中金属室固定成员发表了 122

篇论文，包括 J. Am. Chem. Soc. 5篇，Angew. Chem. Int. Ed. 12篇，Chem. Soc.

Rev. 3篇，Acc. Chem. Res. 1篇，Chem. Sci. 1篇，Adv. Synth. Catal. 10篇，Chem.

Commun. 10 篇， Chem. Eur. J. 5 篇，Org. Lett. 18 篇， J. Org. Chem. 3 篇，Organometallics 7篇等。实验室今年在金属有机配合物合成、结构及反应化学、不对称催化、过渡金

属催化的新反应等方面取得了一些突出的成果：1. 在金属有机配合物合成、结构及反应化学的研究方面，成功地合成了第一

例稀土金属末端氮卡宾化合物-钪末端氮卡宾化合物，研究了其反应性能和反应模式 (Chem. Commun. 2012, 48, 3403)；以 2-三丁基锡基呋喃作为金属转移试剂，实现了金催化的 1,6-二炔-4-烯-3-醇环化/金属转移反应，并通过呋喃锡与阳离子型金络合物的当量实验分离得到的二金物种直接证明了金属转移反应的发生，同时也揭示了金催化的反应体系中可能广泛存在二金中间体(Angew. Chem. Int.

Ed. 2012, 51, 6181)；深入研究了 In-TOX/Ni(II)催化下的不对称合成反应，通过三噁唑啉配体 In-TOX’与高氯酸镍的配合物单晶，研究了边臂上单噁唑啉在催化体系中的重要作用，发现边臂上的手性基团对反应的活性以及对映选择性控制有着重要的影响 (J. Am. Chem. Soc. 2012, 134, 9066)。

2. 在不对称催化的研究方面，通过 SpinPhox/Iridium(I)络合物催化 α, α’-二

(2-羟基亚芳基)酮的不对称催化氢化-缩酮化，首次实现了芳香螺缩酮化合物的

催化不对称合成，该反应在温和的条件下，能够以高的收率、优秀的非对映和对

映选择性得到目标化合物，工作发表在 Angew. Chem. Int. Ed. 2012, 51, 936上，

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并先后被 SYNFACTS和 Angew. Chem. Int. Ed.积极评价；进一步研究了过渡金属

铱催化的去芳构化反应，将铱催化的不对称烯丙基去芳构化反应成功地运用到

了取代吡咯中(Chem. Sci. 2012, 3, 205)，并通过铱催化的吲哚体系分子内烯丙基

去芳构化实现了具有 5元螺环结构骨架的 Spiroindolenine衍生物的不对称合成

(Angew. Chem. Int. Ed. 2012, 51, 1680)。3. 在过渡金属催化的新反应方面，研究了两价钯催化的通过芳烃 C-H活化

启动的串联环化反应或碳-碳偶联反应；研究了 CuBr催化和 ZnI2促进的轴手性

联烯的不对称合成，筛选了一系列仲胺，发现当使用吡咯烷时，通过简单的过

滤操作后再加入 ZnI2即可成功实现从炔丙基胺到联烯的转化；深入研究了金催

化下的羟甲基亚甲基环丙烷的分子内环化反应和亚乙烯基环丙烷的开环反应，

并对张力分子在金催化下的 C-C键的断裂模式 (Chem. Soc. Rev. 2012, 41, 3318)

和亚甲基环丙烷张力分子的反应新模式(Acc. Chem. Res. 2012, 45, 641)进行了总

结；研究了钯催化的活性烯烃氧化芳三氟甲基化反应，以活性烯烃为底物，

TMSCF3 为三氟甲基源，在室温条件下以较高收率得到芳三氟甲基化产物，从

而构建含三氟甲基的氧化吲哚骨架并进行了初步的机理研究(J. Am. Chem. Soc.,

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2012, 134, 878)。今年实验室的重大研究成果有：

1. “基于边臂策略的立体化学控制与催化反应研究”项目获国家自然科学二等

奖现代合成反应要求经济、高效、环境友好的化学。发展新型催化剂(试剂)以实

现选择性控制与提高催化效率成为现代有机合成化学研究中最重要和最具挑战

性的领域之一。“基于边臂策略的立体化学控制与催化反应研究”围绕叶立德反

应和不对称催化中选择性控制与催化问题，在科技部“973”、国家基金委重点项

目、杰出青年基金和创新研究群体、中科院“百人计划”等项目资助下开展了系

统的创新性研究。项目运用“边臂策略”设计新的催化剂(试剂)，成功应用于高

选择性的有机合成反应和功能分子的合成中，发展了一些调控有机合成反应选

择性和提高催化效率的新策略、新方法及新反应，为新型催化剂（试剂）的设计

和反应选择性控制提供了新思路和途径： （1） 采用“边臂策略”首次设计合成了假C3-对称性手性噁唑啉配体(TOX),

发现TOX/ 金属体系在傅-克反应、Kinugasa 反应、环加成与环丙烷化反应等多个

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重要的不对称催化反应中表现出对映选择性提高、配体加速、杂质容忍性好和催

化剂用量低等优异性能，阐明了“边臂”的作用；首次实现了Cu(II) 催化的不

对称Kinugasa 反应；首次通过反应条件的改变实现了吲哚和硝酮对亚烷基丙二

酸酯的不对称傅-克反应和环加成反应立体选择性的调控。该策略和配体多次被

国际同行应用于不对称催化反应

中。（2） 高效催化和高选择性控制

是叶立德化学面临的挑战性课题。

利用“边臂策略”设计了PEG-

Te 催化剂，将叶立德烯基化反

应的催化剂用量降至最低 0.5

mol ％，是迄今为止叶立德反应

催化剂效率最高的例子；利用

“羟基”或“锂离子”边臂经叶立德途径实现了乙烯基环丙烷化合物的多样性

和高选择性的直接合成，发展了调控该类反应立体化学的新方法和新策略，并6

实现了催化的不对称叶立德环丙烷化反应；发现了一些叶立德启动的新的串联

环化反应，为合成杂、并环化合物提供了新途径。这些方法被成功地应用于一些

生物活性分子的全（表观）合成中。 （3） 利用"边臂策略"设计的新型吡咯烷-脲双功能催化剂实现了高效催化的

环酮对硝基烯的Michael 加成反应（最高达dr > 99/1 和98% ee）。该催化剂被国

际同行成功应用于(+)-trachyspic acid 的全合成中。 研究成果在多种国际重要化学期刊发表，包括Acc. Chem. Res.1 篇, J. Am.

Chem. Soc. 7 篇，Angew. Chem. Int. Ed. 2 篇，影响因子> 9.0 的12 篇，所发展的

催化剂和手性配体被国际同行成功应用于有机合成反应和功能分子的合成。20

篇核心论文的总影响因子202.9 （以2010 年计)，篇均影响因子10.1；SCI 他引

1070 次，篇均他引53.5 次，单篇最高他引183 次。培养了15 名博士，其中1 人获

中国科学院院长特别奖和全国百篇优秀论文，1 人获中国科学院50 篇优秀论文

和全国百篇优秀论文提名奖。这15 名博士中，目前1 人入选中国科学院百人计划

5 名已成为985 高校教授或副教授（其中1 名入选青年千人）。项目负责人应邀

在包括IUPAC 国际金属有机等系列会议上作邀请或大会报告11 次，在双边会议7

上做邀请报告5 次，2002 年获国家杰出青年基金，2004 年获Thieme Journal

Award，2006 年获第九届中国青年科技奖。本研究丰富和发展了有机合成化学中

选择性调控和催化的方法和途径，在一定程度上推动了有机合成化学的发展，

项目主要成果处于国际领先水平。

2. “手性膦氮配体的设计合成及在不对称催化中的应用” 项目获上海市自然科

学一等奖手性化合物在生命和材料等领域的地位举足轻重，不对称催化则为获得手

性物质的最理想方法之一。金属催化不对称反应中配体的作用至关重要。 该项目从手性配体作用的认识和不对称催化过程的理解着手，设计合成和改造了一系

列手性膦氮配体，围绕不对称催化一些反应中的挑战，重要不对称催化新反应的实现以及反应选择性调控、配体中多手性因素的相互关系等开展研究，取得了如下重要成果：（ 1）设计了新型膦氮配体

SIOCPhox，对类型广泛的单取代烯丙基底物实现了高区域、高对映选择性，为国际最好结果；实现了开链酮、酰胺等羰基 α-碳负离子等“硬”碳负离子的高对映选择性烯丙基烷基化反应，成果具国际领先；实现了钯催化高选择性不对称环丙烷化反应，为该领域一个重大突破；实现了对碳亲核试剂的动力学拆分，

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提供了简便获得各种光学活性化合物的新途径。（2）首次实现了铜催化硝基

烯烃与甲亚胺叶立德的不对称 1,3-

偶极环加成反应和铱催化 α,β-不饱和酮碳碳双键不对称氢化。实现了铜催化不对称 1,3-偶极环加成及Mannich反应的非对映选择性调控

和钯催化不对称 Heck反应中产物构型调控，解决了 Mannich反应中难以实现anti-选择性的难题。（ 3）阐明了二茂铁配

体中平面手性对于不对称诱导的作用及其作用方式。相关成果已在重要国际

刊物上发表。20篇重要论文被他引 1154 次，单篇最高他引 210次。编著专著一部 。5项发明专利获授权。在重要国际会议做大会报告、邀请报告 10余次。所获成果对有机化学特别是不对称催化领域的发展起到了重要推动作用。

二、 队伍建设与人才培养实验室的学术骨干队伍以中国科学院院士、杰出青年基金获得者和中科院百

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人计划入选者为主体。现有在职人员 81人，副高级以上研究人员 38人，这其中

包括研究员 15名(含院士 3名)，国家杰出青年基金获得者 8名，科学院“百人

计划”入选者 8名，“青年千人计划”入选者 1名，“千人计划(创新人才短期

项目)” 入选者 1名。2012年实验室固定人员中余金权研究员获 “千人计划（创新人才短期项

目）”；刘国生研究员获 “国家杰出青年基金”；邓亮研究员获 “优秀青年科学基金”；丁奎岭研究员获 “上海市优秀院所长奖上海市优秀院所长奖”； 唐勇研究员获“黄耀曾金属有机化学奖”；游书力研究员获 “Asian Core Program

Lectureship Award (Japan, Singapore)”、“AstraZeneca Excellence in Chemistry

Award ”、 “中国科学院优秀导师奖”、 “中国科学院研究生院 BHP Billiton奖学金导师科研奖”。

2012年实验室在读硕士研究生 34名，博士研究生 72名，在站博士后 3名；毕业硕士 4名，博士 23名。

三、对外开放与学术交流今年实验室面向所外单位设立的开放课题有 4项，资助总额 130.6万元，均

按照预定的研究目标顺利执行，由开放基金资助完成的优秀成果如下：优秀成果（一）：首次报道了以炔丙基叠氮和酸为底物，通过直接的氧化脱氢偶联简洁高效

的形成炔丙基三级碳的碳氧键的方法，该方法条件温和，避免了卤代物的使用，10

具有很高的原子经济性，且通过控制实验证明，叠氮在这一偶联中可能是一种

重要辅基。得到的含有炔，叠氮和酯的多官能团产物是一种重要的合成中间体，

它可以进一步转化成三氮唑，苯并三氮唑和烯基醛等可能具有生物活性小分子

(Angew. Chem. Int. Ed. 2012, 51, 10823)。优秀成果（二）：在 C-O活化的研究方面，首次实现了苄醇 sp3 C-O的在 Fe，Co，Ni等催化

下与格式试剂的偶联反应，并通过机理研究进一步实现了从醇到格式试剂的转

化(J. Am. Chem. Soc. 2012, 134, 14638）。优秀成果（三）：利用双锂试剂的“协同效应”，建立了高效合成氮杂半瞬烯分子的2种方法，

首次测定了该类分子的活化能和单晶结构，发现了该类分子的多种化学反应类

型，该项研究结果表明该类分子存在中性同芳香性，为进一步的实验研究奠定

了基础，该工作被选为JACS Spotlights。学术交流对于提高重点实验室的研究水平具有重要意义。实验室今年分别接

待了美国、日本、德国、英国、加拿大、西班牙、瑞典等国以及包括中国香港、台湾

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在内的的 41位科学家来室访问进行了学术交流。同时，实验室学术带头人积极

参加国际国内的重要学术会议，应邀在国内外学术会议上作邀请及大会报告 39

人次。2012年 10月 9-12日，由金属有机化学国家重点实验室主办的第五届国际

均相催化论坛（The Fifth International Forum on Homogeneous Catalysis）在中科

院上海有机所君谋楼一楼报告厅成功召开，麻生明院士和唐勇研究员共同担任

大会主席。国家自然科学基金委员会化学科学部主任林国强院士，中科院上海有

机所丁奎岭所长出席了开幕式。来自上海有机所、华东师范大学、华东理工大学、

复旦大学、上海交通大学、厦门大学、中国科技大学等科研院所和高校的两百多

名专家、科研工作者以及学生参加了本次论坛。丁奎岭所长及林国强院士先后在开幕式上致辞，表达了对与会专家、学者

的热烈欢迎和诚挚感谢。本次会议共邀请了来自美国、加拿大、德国、西班牙、日

本以及中国的 19名著名专家作了精彩的学术报告，主要围绕金属有机试剂参与

的有机合成、金属参与或催化的有机化学反应、不对称合成与催化等前沿及交叉

科学领域进行交流与探讨，突出均相催化领域的最新发展和未来态势。整个会议12

反响热烈，很多听讲的学生和科研人员都表示有这样的机会了解学科前沿的相

关知识受益匪浅，同时结合自己在科研工作过程中遇到的问题与专家进行了积

极的沟通和交流。国际均相催化论坛是由麻生明院士发起，金属有机化学国家重点实验室主

办的每两年一次的系列国际研讨会，自 2004年以来，已在杭州、苏州、上海、昆

明等地成功举办了四届。该系列会议旨在为来自世界各地的均相催化领域的中外

科学家搭建桥梁，提供交流化学新思想、新成果的机会，共同商讨均相催化领域

的进一步发展计划，促进学术交流，探讨及建立合作。

四、实验室学术委员会工作金属有机化学国家重点实验室第三届学术委员会第三次会议于 2012年 10

月 23-24日在北京召开。国家自然科学基金委化学部常务副主任梁文平研究员、

杜灿屏研究员、郑企雨处长以及中国科学院高技术研究与发展局化工处唐清研究

员应邀参加了此次会议。在会议上，实验室主任唐勇研究员汇报了重点实验室 2012年度工作进展，

四川大学的冯小明教授作了题为“手性氮氧金属络合物催化不对称反应研究”13

的专家报告，北京大学的焦宁教授作了题为“ Aerobic Oxidation and

Oxygenation”的学术动态介绍，刘磊教授、王春江教授、施敏研究员、肖文精教授、

唐勇研究员分别汇报了各自的课题组工作进展及研究计划，此外，游书力研究

员、段伟良副研究员、陈耀峰研究员以及施章杰教授分别进行了有关 International

Conference "Catalysis in Organic Synthesis"、 12th International Symposium for

Chinese Organic Chemists & 9th International Symposium for Chinese Inorganic

Chemists 、 XXV International Conference on Organometallic Chemistry 以 及

Innovation on Organic Synthesis: The 1st Symposium in Direct C-H Activation的国

际会议介绍。10月 24日上午，与会的领导、专家、学术委员以及老师等进行了热烈的讨

论和充分的交流。大家充分肯定了金属有机化学国家重点实验室近年来取得的成

绩，实验室在保持金属有机化学学科的优势和特色基础上，在面向国家重大需

求的研究方向如聚烯烃、氢甲酰化制丁醛等领域的新型催化剂研制方面也取得了

很好的成绩。同时，大家也对实验室的发展提出了建设性的建议和意见。希望实

验室能在保持特色和优势的基础上，更上一个台阶，进一步完善和壮大科研队

14

伍，在人才引进方面根据实验室的发展规划，结合国家需求，从目前活跃在金

属有机化学研究领域第一线的国外研究小组引进年轻有为的研究人才。

五、2012年度研究生获奖情况表序号 获奖名称 获奖人员 指导教师

1 2012年度国家奖学金 王鹏 唐勇2 2012年度国家奖学金 章迪翰 施敏3 2012年度国家奖学金 林渭龙 麻生明4 2012年度国家奖学金 孙宁 刘元红5 布劳恩奖学金 王晓明 丁奎岭6 布劳恩奖学金 楚甲祥 陈耀峰7 布劳恩奖学金 章迪翰 施敏8 布劳恩奖学金 李军 唐勇9 上海市高校优秀毕业生 陈宜峰 刘元红10 中国科学院院长优秀奖 陈宜峰 刘元红11 中科院研究生院三好学生标兵 王鹏 唐勇12 中国科学院研究生院优秀毕业生 蔡泉 游书力13 中国科学院研究生院院长特别奖 蔡泉 游书力14 博士研究生学术新人奖 武庆锋 游书力15 SciFinder Future Leaders in Chemistry 武庆锋 游书力

15

16 中国科学院研究生院 BHP Billiton奖学金 武庆锋 游书力17 刘铸晋优秀博士生奖学金 叶克印 游书力18 中国科学院研究生院优秀学生干部 叶俊涛 麻生明19 中国科学院研究生院优秀学生干部 李德尧 施敏20 中国科学院研究生院优秀学生干部 刘家旺 丁奎岭21 中国科学院研究生院优秀学生干部 袁浙梁 刘国生22 中科院研究生院三好学生 王飞 刘国生23 中科院研究生院三好学生 林渭龙 麻生明24 中科院研究生院三好学生 孙宁 刘元红25 中科院研究生院三好学生 张攀科 丁奎岭26 中科院研究生院三好学生 陈波 麻生明27 中科院研究生院三好学生 楚甲祥 陈耀峰28 中科院研究生院三好学生 范国钦 刘元红29 中科院研究生院三好学生 李小惠 侯雪龙30 中科院研究生院三好学生 慕欣 刘国生31 中科院研究生院三好学生 沈坤 陆熙炎32 中科院研究生院三好学生 杨晓菲 戴立信33 中科院研究生院三好学生 袁渭 施敏34 中科院研究生院三好学生 章迪翰 施敏35 中科院研究生院三好学生 卓春祥 游书力36 中科院研究生院三好学生 莫贞波 邓亮

16

17

2012年自由探索课题（2012-2013年）序 号 姓 名 题 目2012-01 陆熙炎 芳基钯物种对碳－杂原子重键的加成反应研究2012-02 麻生明 基于末端炔烃联烯的合成化学研究2012-03 侯雪龙 钯催化“硬”碳亲核试剂的分子内烯丙基取代反应及应用研究2012-04 施 敏 金催化的高张力分子的反应性能研究2012-05 丁奎岭 环状碳酸酯均相催化氢化合成甲醇和乙二醇的研究2012-06 唐 勇 基于双噁唑啉配体的新型双功能催化剂及其在不对称合成中的应用2012-07 刘元红 具有可互变异构结构的金属杂环化合物的形成及反应性能研究2012-08 陈耀峰 新型稀土硼杂苯化合物的合成、反应和催化性能研究2012-09 游书力 过渡金属催化的烯丙基芳基化与去芳构化反应研究2012-10 刘国生 过渡金属催化氟化反应研究2012-11 李玉学 有机小分子催化的 CO2还原官能团化机理的理论研究2012-12 邓 亮 活性铁络合物促进的碳-碳、碳-氮键构筑反应研究2012-13 段伟良 过渡金属催化不对称碳氢键官能团化合成手性膦化合物方法的研究2012-14 黄 正 发展新型的烷烃转化体系：烷烃二聚和烷烃齐聚反应

18

19

2012年实验室团队重点研究课题（2012-2016年）

项目一：基于金属有机化学的反应设计与控制课题负责人：侯雪龙研究队伍：戴立信，侯雪龙，丁奎岭，王正，丁昌华

经费总额: 400万

项目二：金属配合物的合成及其促进的高选择性合成反应课题负责人：刘元红

研究队伍：刘元红，邓亮，李玉学，孙杰

经费总额: 300万

项目三：金属催化的不饱和烃的合成和反应研究项目负责人：麻生明研究队伍：陆熙炎，麻生明，韩秀玲，张雪，余世超经费总额: 400万

项目四：新型烯烃聚合催化剂的研究

20

项目负责人：唐勇研究队伍：唐勇，陈耀锋，黄正，孙秀丽，李军方经费总额: 350万

项目五：惰性化学键及体系的活化与官能团化中的金属有机化学

课题负责人：游书力研究队伍：游书力，施敏，刘国生，段伟良，张玮经费总额: 300万

21

2012年实验室开放课题（2012-2014年）项目一：碳－碳(杂)键形成的过渡金属有机化学项目负责人：吴劼研究队伍：吴劼，王佰全，陈忠宁，王磊，郎建平，施章杰，张兆国经费总额: 81万

项目二：过渡金属参与的有机合成反应项目负责人：王剑波研究队伍：王剑波，张俊良，余正坤，雷爱文，焦宁，刘磊，许斌，王春江经费总额: 87万

项目三：主族金属有机化合物的反应化学项目负责人：席振峰研究队伍：席振峰，周永贵，甘良兵，曹卫国，金国新，肖文精经费总额: 63万

22

项目四：稀土金属有机物的合成、结构与反应化学项目负责人：王绍武研究队伍：王绍武，周锡庚， 苏成勇，朱成建经费总额: 42万

23

2012年申请专利编号 专利名称 申请号 发明人1 高支化油状烷烃聚合物及其制法和应用 201210098399.2

唐勇、陶闻杰、孙秀丽、李军方、王峥

2 一类由烯烃制备高支化烷烃的催化体系 PCT/

CN2012/074545

唐勇、陶闻杰、孙秀丽、李军方、王峥

3吲哚并八元环双烯化合物的合成方法及其应用于伊普吲哚的合成 201210165288.9

麻生明、朱灿、练雄东

4 氟代异喹啉类化合物及其制备方法 201210194986.1 刘国生、徐涛5 氟代异喹啉[a]吡咯类化合物及其制备方法 201210195020.x 刘国生、徐涛6 光学活性轴手性 α-联烯醇、合成方法和用途 201210193176.4 麻生明、叶俊涛7

螺缩酮骨架的双齿亚磷酰胺配体及其制备方法和应用 201210243736.2

丁奎岭、王正、贾肖飞

8手性芳香螺缩酮骨架双膦配体及其制备方法和应用 201210253896.5

丁奎岭、王晓明、韩召斌、王正

9手性芳香螺缩酮类化合物及其制备方法和应用 201210253476.7

丁奎岭、王晓明、韩召斌、王正

10一种手性 α亚甲基 β内酰胺类化合物及其制备方法和应用 201210253862.6

丁奎岭、王晓明、孟繁烨、王正

11一种依泽替米贝的合成方法及该方法中所用的中间体 201210253879.1

丁奎岭、王晓明、王正

12 并四苯及并五苯类化合物的合成方法 201210359027.0刘元红、陈铭、陈宜峰

13 新型钌络合物及制备甲醇和二醇的方法 201210403332.5 丁奎岭、韩召斌14

一种平面手性二茂铁化合物、合成方法及用途 201210489246.0

游书力、顾庆、高得伟、石延超、赵正乐

15新型铱络合物以及利用伯醇 α-烷基化酰胺的方法和应用 201210533272.9 黄正、郭乐

24

2012年授权专利编号 专利名称 专利号 发明人1 一种内酯类化合物 ZL 201010195202.8 蒋敏、施敏2 乙烯齐聚催化剂、合成方法及其用途 ZL 200510025276.6

唐勇、郭阳辉、孙秀丽

3含锆物质在催化水杨酸类化合物的清洁硝化方法中的应用 ZL 200610026933.3

高骏、郭英文、施敏

4 1-氧杂苯并杂环类化合物、合成方法和用途 ZL 201010217729.6 游书力、贺虎5

β-萘甲基取代的螺环双噁唑啉配体、合成方法及其应用 ZL 200910196167.9 舒伟、麻生明

6α-萘甲基取代的螺环双噁唑啉配体、合成及其在合成吡咯烷衍生物中的应用 ZL 200910051785.4 麻生明、舒伟

7 一种(S)-3-氟-2-(4-异丁基苯)丙酸的医药用途 ZL 201110032035.x苏红，谢雨礼，游书力，刘文博

8 一种丙烯氢甲酰化催化体系和方法 ZL 200610147735.2

丁奎岭、侯雪龙、李欣、朱霞珍、吴良泉、蒋文、赖春波、陈建伟

9螺环骨架膦噁唑啉配体、合成方法及其在不对称氢化反应中的应用 ZL 200910051314.3

丁奎岭、韩召斌、王正

10四氢喹晽和吲哚啉衍生的磷氮配体、合成方法和应用 ZL 200910048438.6 游书力、刘文博

11一类具有单活性中心性质的齐格勒-纳塔烯烃聚合催化剂 ZL 201010108695.7

唐勇、卫兵、李军方、孙秀丽

12 新型三齿氮配体及其稀土金属配合物 ZL 200910047182.7陈耀峰、陆而立、甘伟

13 单茚基稀土配合物、合成方法以及应用 ZL 200810032938.6 陈耀峰、徐信14 桥链双希夫碱-钴络合物及其合成方法和用途 ZL 201010288969.5

丁奎玲（丁奎岭），张志鹏，张如周，王正

15Catalyst for Polymerization or Copolymerization

of Olefins,Preparation and Use of the same EP1426385B1

孙秀丽、胡 蔚秋、王聪、唐勇、张玉良、夏春安

16 一种合成氟代含氮杂环化合物的方法 ZL 200910197231.5 刘国生、吴涛25

17 一种有效的吡咯胺类衍生物的合成方法 ZL 200810204867.3 唐翔鹰、施敏

26

2012年金属有机化学国家重点实验室来访人员报告编号 题目 报告人 单位 主持人 时间1 低碳发展－分离科学

和工程面临的新挑战 费维扬 院士 清华大学 丁奎岭 2012-01-0910:00

2Palladium-Catalyzed Carbonylation Reactions

Dr. Xiaofeng Wu University Rostock 刘国生 2012-02-0910:00

3

Sythesis of Natural Products with Conformational Chirality

Prof. Christopher Beaudry

Oregon State University 刘国生 2012-03-

0115:00

4Supramolecular Photochirogenesis

Dr. Yang Cheng Osaka University 施敏 2012-03-1215:00

5Uranium in Non-Conventional Ligand Enviroments

Prof. Stephen T. LiddleUniversity of Nottingham 陈耀峰 2012-03-

1613:30

6New Strategies in Organocatalysis

Prof. Wei WangUniversity of New Mexico 游书力 2012-03-

2015:00

7C-H Activation Reactions at sp2- and sp3-Carbon Centers

Prof. Thorsten BachTechnische Universität München

唐勇 2012-03-2615:00

8

手性氮氧作为有机催化剂和手性配体在不对称催化反应中的应用

冯小明 教授 四川大学 唐勇 2012-03-2815:00

9The Development of Monovalent Phosphorus Chemistry

Prof. Francois MatheyNanyang Technological University

丁奎岭 2012-04-0110:00

10

Tunneling by Carbon. Telling Experimentalists Where to Look and What to Look for

Prof. Wes BordenUniversity of North Texas 麻生明 2012-04-

0913:30

11

Ru2-Alkynyl Molecular Wires and Attenuation of Electronic Coupling

Dr. Bin Xi Harvard University 邓亮 2012-04-0914:00

12

Multifunctional Radical Quenchers as Mitochondrial Therapeutic Agents

Prof. Sidney HechtAssociate Editor, JACS 丁奎岭 2012-04-

1608:30

13 Development of Prof. William R. Roush Associate Editor, 丁奎岭 2012-04-

27

Bifunctional Allylboron Reagents via allene Hydroboration Reactions and Applications to the Synthesis of Natural Products

JACS 1608:30

14

Recent Advances in the Design, Synthesis and Testing of Artificial Molecular Machines

Prof. Miguel Garcia- Garibay

Associate Editor, JACS 丁奎岭 2012-04-

1608:30

15

Synthetic and Mechanistic Aspects of Gold(I) p-Activation Catalysis

Prof. Ross A. Widenhoefer

Duke University 施敏 2012-05-0910:00

16

Stereocontrol in the Synthesis of Natural Products: New Methods toward Solanoeclepin, Gibberellin, Prostaglandin, Malyngamide, etc.

Prof. Minoru Isobe National Tsing Hua University 丁奎岭 2012-05-

1110:00

17

Precise Synthesis of Hydrocarbon Polymers with Coordination Polymerization Catalysis

Prof. Takeshi ShionoHiroshima University 唐勇 2012-05-

1410:00

18

About the Ssymmetric Functionalisation of Carbonyls after the Advent of Cinchona-based Primary Amine Catalysis

Prof. Paolo MelchiorreInstitute of Chemical Research of Catalonia

游书力 2012-05-1715:00

19

The Quest for New Asymmetric Methodologies: Searching for Untrodden Path in Organocatalysis Territory

Dr. Ramon Rios TorresUniversity of Barcelona 游书力 2012-05-

1810:00

28

20

Enantioselective Organocatalytic Reactions: Dual Activation Concenpt Using Hydrogen Bonding Catalysts

Prof. Vinod Kumar Singh

IISER 张玮 2012-05-2215:00

21

Organic Photovoltaics Research Guided by New Reactions and New Molecules

Eiichi NakamuraThe University of Tokyo 丁奎岭 2012-05-

2410:00

22

Step-Economical Organic Syntheses through C-H Bond Functionalizations

Prof. Lutz AckermannGeorg-August-Universitat of Gottingen

顾庆 2012-05-259:00

23

Novel Enantioselective Reactions Promoted by Bifunctional Organocatalysts

Prof. Hiroaki Sasai Osaka University 顾庆 2012-05-259:00

24

Synthesis of Natural Products, Drugs, Agrochemicals and Materials by Multiple Pd-Catalyzed Transformations

Prof. Lutz F. TietzeGeorg-August-University of Gottingen

丁奎岭 2012-05-2510:00

25

Diamination of Alkenes: Palladium Catalysis and Iodine(III) Reagents

Prof. Kilian MunizInstitute of Chemical Research of Catalonia

刘国生 2012-05-2810:00

26Gold-catalyzed Oxidative Cyclizations of Alkynes

Prof. R.-S. LiuNational Tsing-Hua University 施敏 2012-05-

3010:00

27

Minor Enantiomer Recycling–a Strategy for Improving Enantioselectivity

Prof. Christina MobergOrganic Chemistry Royal Institute of Technology Sweden

游书力 2012-05-3015:00

28Photocatalysis with Visible Light

Prof. Tehshik YoonUniversity of Wisconsin at Madison

游书力 2012-06-1510:00

29Science Publishing at Nature Publishing Group

Dr. Matthew SalterMacmillan Scientific Communications 游书力 2012-06-

2019:00

30 Well-Defined Base Metal Catalysts for

Prof. Xile Hu Institute of Chemical Sciences

游书力 2012-06-2810:00

29

Cross Coupling of Alkyl Halides and Direct Alkylation

and Engineering, Switzerland

31

Advances in the Synthetic Chemistry of Tetrapyrroles —the Pigments of Life

Prof. Jonathan S. Lindsey

North Carolina State University 游书力 2012-06-

2910:00

32Chemical Process R&D: Chemistry and Beyond

Dr. Jianguang Zhou Suzhou Novartis 游书力 2012-07-1114:00

33Taming of Superacids: A Fascinating Journey

Prof. Thomas MathewUniversity of Southern California 丁奎岭 2012-07-

1610:00

34 探讨纳米科技发展的思路 何丹农 教授 纳米技术及应用国

家工程研究中心 丁奎岭 2012-07-1915:30

35

Chiral Counterion Pair Catalysis: From Concepts to Applications

Prof. Dr. Magnus Rueping

Institute of Organic Chemistry, RWTH Aachen, Germany

游书力 2012-08-0810:00

36

From Selectivity Profiling technology to New Drug Discovery---A Focused Scaffold Approach to Develop Kinase inhibitors as Potential Anti-cancer Theraies

刘青松 研究员 中科院合肥物质科学研究院 游书力 2012-08-

1510:00

37

Designing Non-Cp Ancillary Ligands to Support Thermally Stable Rare Earth Dialkyl Complexes

Prof. Paul G. HayesUniversity of Lethbridge 陈耀峰 2012-08-

1710:00

38

Merck Catalysis Needs for Drug Discovery, Development and Commercialization

Dr. Yongkui SunMerck Sharp & Dohme 丁奎岭 2012-08-

2809:30

39Synthesizing Electronic Properties

Prof. Klaus MüllenMax-Planck-

Institute for Polymer Research Germany

丁奎岭 2012-09-2810:00

40

Advantages of Ruthenium Catalysts in C-H Bond Activation

Prof. Pierre DixneufThe University of Rennes 唐勇 2012-10-

1610:00

41 New Chemistry and Prof. Ming Xian Washington State 游书力 2012-12-

30

Chemical Tools for Sulfur Related Biological Problems

University 1310:00

31

2012年会议报告1. 陈耀峰，新型稀土金属配合物的合成、结构和反应性能研究 (邀请报告)，中

国化学会第 28届学术年会，中国成都，2012年 4月。2. 陈 耀 峰 ， Scandium Terminal Imido Complexes: Synthesis, Structure and

Reactivities (Invited Lecture), Münster-上海 -香港 三边金属有机化学会议 ,

Shanghai, China, May. 2012.

3. 邓 亮 ， Iron and Cobalt Complexes with Monodentate N-Heterocyclic

CarbeneLigation: Synthesis, Structure, and Reactivity Study (Invited Lecture),

XXV International Conference on Organometallic Chemisty, Lisboa, Portugal,

Sep. 2012.

4. 丁奎岭，Chiral Catalyst Evolution: Rational Design and Serendipity (Invited

Lecture), 4th Dalton Transactions International Symposium: Organometallic

Chemistry and Catalysis, Shanghai, China, Nov. 2012.

5. 丁奎岭，Chiral Catalyst Evolution: Rational Design and Serendipity (大会报告)，

中国化学会第十七届全国金属有机化学学术讨论会，中国北京，2012年 10

月。6. 丁奎岭，Chiral Catalyst Evolution: Rational Design and Serendipity (Invited

Lecture), The 5th International Forum on Homogeneous Catalysis, Shanghai,

China, Oct. 2012.

32

7. 丁奎岭，Chiral Catalyst Evolution: Rational Design and Serendipity (Invited

Lecture), 1st International Symposium on the Natural Product Synthesis and

Process Methods for Drug Manufacture, Chongqing, China, Sep. 2012.

8. 丁奎岭，Chiral Catalyst Evolution: Rational Design and Serendipity (Invited

Lecture), The 6th Takeda Science Foundation Symposium on PharmaSciences,

Osaka, Japan, Sep. 2012.

9. 丁奎岭，Chiral Catalyst Evolution: Rational Design and Serendipity (Plenary

Lecture), 12th International Symposium for Chinese Organic Chemists (ISCOC-

12), Lanzhou, China, Aug. 2012.

10.丁奎岭，Chiral Catalyst Evolution: Rational Design and Serendipity (Invited

Lecture), Chiral China 2012 Symposium, Lanzhou, China, Aug. 2012.

11.丁奎岭，Chiral Catalyst Evolution: Rational Design and Serendipity (大会报告)，

中国化学会第十届全国有机合成化学学术讨论会，中国长春，2012年 8月。12.丁奎岭，Chiral Catalyst Evolution: Rational Design and Serendipity (邀请报告)，

河南大学百年校庆“有机功能材料专题研讨会，中国开封，2012年 4月。13.丁奎岭，Chiral Catalyst Evolution: Rational Design and Serendipity (Invited

Lecture), 19th International Conference on Phosphorus Chemistry (ICPC 2012),

Rotterdam, The Netherlands, Jul. 2012.

14.丁奎岭，Chiral Catalyst Evolution: Rational Design and Serendipity (Invited

Lecture), 3th International Symposium on Organic Synthesis and Drug

Development (ISOSDD’2012), Changzhou, China, May 2012.

33

15.侯雪龙，Pd-Catalyzed Asymmetric Allylic Alkylation with “Hard” Carbonanions

(Invited Lecture), Tarragona, Spain, July 2012.

16.侯雪龙， Some Advances in Pd-Catalyzed Asymmetric Allylic Substitution(Invited

Lecture)，Chiral China 2012 Symposium, Lanzhou, China, Aug. 2012.

17.刘国生，过渡金属催化的氟化反应研究 (邀请报告)，第 28届全国化学会年

会，中国成都，2012年 4月。18.刘国生，金属银催化的氟化反应研究 (邀请报告)，第 7届中美有机化学家会

议，中国昆明，2012年 7月。19.刘国生，过渡金属催化 (邀请报告)，第 9届有机化学合成会议，中国长春，

2012年 8月。20.刘国生，Pd-catalyzed C-H Activation: Oxidative Functionalization of Alkenes

(Invited Lecture), The 1st International Symposium on C-H Activation, Beijing,

China, Oct. 2012.

21.刘国生，过渡金属催化氟化 (邀请报告)，第 11届全国氟化学会议，中国南

昌，2012年 10月。22.刘国生，过渡金属催化氟化 (邀请报告)，第 17届全国金属有机化学会议，

中国北京，2012年 10月。23.刘国生， Transition Metal -catalyzed Fluorination (Invited Lecture), The 7th

34

International Conference on Cutting-Edge Organic Chemistry in Asia (ICCEOCA-

6), Asian Core Program (ACP), Singapore, Dec. 2012.

24.麻生明，Nucleophilic Additions of 2,3-Allenoates with Organometallic Reagents

(Invited Lecture), The First International Conference on Organometallics and

Catalysis (OM&Cat), Beijing, China, Oct. 2012.

25.唐勇， Bystander as a Remote Control of Enantioselectivity in Bisoxazoline-

based Asymmetric Catalysis (Invited Lecture)，OBC 2012, 上海，2012年 4月。26.唐 勇 ， Sidearm-Performance Control of Titanium Imino-enolates in Olefin

Polymerization (Invited Lecture)，第五届高分子化学国际学术研讨会 (PC

2012)，中国长春，2012年 6月。27.唐勇，Sidearm Approach to Olefin Polymerization Catalysts Based on Titanium

Imino-Enolates (Plenary Lecture), The International European Cooperation in

Science and Technology Workshop, Regensburg, Germany, Aug. 2012.

28.唐勇，A New Approach to Catalysis-Sidearm Effects and Applications (Keynote

Lecture), XXV International Conference on Organometallic Chemisty, Lisboa,

Portugal, Sep. 2012.

29.唐勇，边臂调控-手性催化剂设计的策略与应用 (大会报告)，第 17届全国金属有机化学会议，中国北京，2012年 10月。

30.游书力，Selective C-H Bond Direct Funcationalization (Invited Lecture), 2011

AstraZeneca Excellence in Chemistry Award Symposium, Bangalore, India, Jan.

2012.

31.游书力，Catalytic Asymmetric Dearomatization Reaction (Invited Lecture), 2011

AstraZeneca Excellence in Chemistry Award Symposium, Bangalore, India, Feb.

2012.

32.游书力，Catalytic Asymmetric Dearomatization Reaction (Invited Lecture), The

First Nagoya Symposium on Green Synthesis & Catalysis (NSGSC-1), Nagoya,

35

Japan, Mar. 2012.

33.游书力，Exploring Dearomatization Reactions in Asymmetric Catalysis (Invited

Lecture), Catalysis and Sensing for our Environment 2012 (CASE12), Shanghai,

China, Apr. 2012.

34.游书力，Catalytic Asymmetric Dearomatization Reaction (Invited Lecture), The

3rd International Symposium on Organic Synthesis and Drug Development (3rd

ISOSDD), Changzhou, China, May 2012.

35.游书力，Catalytic Asymmetric Dearomatization Reaction (Invited Lecture), The

2nd Hong Kong-Münster-Shanghai Joint Trilateral Symposium on Organometallic

Chemistry, Shanghai, China, May 2012.

36.游书力，Asymmetric Allylic Dearomatization Reactions (Invited Lecture), The

8th Sino-US Chemistry Professors Conference, Kunming, China, Jul. 2012.

37.游书力，Asymmetric Allylic Dearomatization Reactions (Invited Lecture), 2nd

International Conference on Molecular & Functional Catalysis (ICMFC-2),

Singapore, Jul. 2012.

38.游书力， Ir-Catalyzed Asymmetric Allylic Dearomatization Reactions (Invited

Lecture), Chiral China 2012, Lanzhou, China, Aug. 2012.

39.游书力， Ir-Catalyzed Asymmetric Allylic Dearomatization Reactions (Invited

Lecture), International Conference “Catalysis in Organic Synthesis”, (ICCOS-

2012), Moscow, Sep. 2012.

36

2012年发表专著(章节)

专著(章节)题目 作者 专著名称 出版社Organic Chemistry-

Breakthroughs and

Perspectives

Kuiling Ding,

Lixin Dai

Organic Chemistry-

Breakthroughs and

Perspectives

Wiley-VCH

DFT Studies on Zirconium-

Mediated ReactionsYuxue Li

Computational

Organometallic Chemistry

Springer-Verlag

Berlin

Heidelberg

Chemical Transformation

of

Vinylidenecyclopropanes

Lixiong Shao,

Jianmei Lu,

Min Shi

Spring Briefs in

Molecular

Science

BenzylidenecyclopropaneZhen Zhang,

Min ShiEROSMS

Iridium-Catalyzed

Asymmetric Allylic

Substitutions

Wenbo Liu,

Jibao Xia,

Shuli You

Top. Organomet. Chem.

Springer-Verlag

Berlin

Heidelberg

37

Reduction: Asymmetric

Transfer Hydrogenation

with Hantzsch Esters

Chao Zheng,

Shuli YouComprehensive Chirality Elsevier

38

2012年论文目录一、 固定人员论文目录（按通讯作者姓氏首字母排序）1. Reactivity of Scandium Terminal Imido Complexes towards Metal Halides. Erli

Lu, Qinghai Zhou, Yuxue Li, Jiaxiang Chu, Yaofeng Chen*, Xuebing Leng, Jie

Sun Chem. Commun. 2012, 48, 3403-3405.

2. C−P or C−H Bond Cleavage of Phosphine Oxides Mediated by an Yttrium

Hydride. Erli Lu, Yaofeng Chen*, Jiliang Zhou, Xuebing Leng Organometallics

2012, 31, 4574-4578.

3. Synthesis, Structure, and Reactivity Study of Iron(II) Complexes with Bulky

Bis(anilido)thioether Ligation. Jie Xiao, Liang Deng* Organometallics 2012, 31,

428-434.

4. Dinuclear Iron Complex-Catalyzed Cross-Coupling of Primary Alkyl Fluorides

with Aryl Grignard Reagents. Zhenbo Mo, Qiang Zhang, Liang Deng*

Organometallics 2012, 31, 6518-6521.

5. Dinuclear Iron-Imido Complexes with N-Heterocyclic Carbene Ligation:

Synthesis, Structure, and Redox Reactivity. Qiang Zhang, Li Xiang, Liang

Deng* Organometallics 2012, 31, 4537-4543.

6. C-H Bond Amination by Iron-imido/nitrene Species. Long Zhang, Liang Deng*

Chin. Sci. Bull. 2012, 57, 2352-2360.

7. Intramolecular C(sp3)–H Bond Activation Reactions of Low-Valent Cobalt

Complexes with Coordination Unsaturation. Zhenbo Mo, Dake Chen, Xuebing

Leng, Liang Deng* Organometallics 2012, 31, 7040-7043.

8. Rh(I)-Catalyzed Enantioselective Hydrogenation of α-Substituted

Ethenylphosphonic Acids. Kaiwu Dong, Zheng Wang, Kuiling Ding* J. Am.

Chem. Soc. 2012, 134, 12474-12477.

9. Catalytic Asymmetric Synthesis of Aromatic Spiroketals by SpinPhox/Iridium(I)-

Catalyzed Hydrogenation and Spiroketalization of a,a’-Bis(2-hydroxyarylidene)

Ketones. Xiaoming Wang, Zhaobin Han, Zheng Wang*, Kuiling Ding* Angew.

Chem. Int. Ed. 2012, 51, 936-940.

39

10. Aromatic Spiroketal Bisphosphine Ligands: Palladium-Catalyzed Asymmetric

Allylic Amination of Racemic Morita–Baylis–Hillman Adducts. XiaomingWang,

Fanye Meng, YanWang, Zhaobin Han, Yong-Jun Chen, Li Liu*, ZhengWang*,

Kuiling Ding* Angew. Chem. Int. Ed. 2012, 51, 9276-9282.

11. Asymmetric Hydrogenation of α- or β-acyloxy α, β-unsaturated Phosphonates

Catalyzed by a Rh(I) Complex of Mmonodentate Phosphoramidite. Jinzhu Zhang,

Kaiwu Dong, Zheng Wang, Kuiling Ding* Org. Biomol. Chem. 2012, 10, 1598-

1601.

12. Access to Both Enantiomers of α-Chloro-β-keto Esters with a Single Chiral

Ligand: Highly Efficient Enantioselective Chlorination of Cyclic β-Keto Esters

Catalyzed by Chiral Copper(II) and Zinc(II) Complexes of a Spiro-2,2’-

bischroman-Based Bisoxazoline Ligand. Jie Li, Wei Pan, Zheng Wang, Xumu

Zhang, Kuiling Ding* Adv. Synth. Catal. 2012, 354, 1980-1986.

13. Highly Enantioselective Asymmetric Hydrogenation of (E)-β, β-disubstituted α,

β-unsaturated Weinreb Amides Catalyzed by Ir(I) Complexes of Spin Phox

Ligands. Jian Shang, Zhaobin Han, Yang Li, Zheng Wang, Kuiling Ding* Chem.

Commun. 2012, 48, 5172-5174.

14. Rh(I)/DpenPhos Catalyzed Asymmetric Hydrogenation of Enol Esters and

Potassium (E)-3-Cyano-5-methylhex-3-enoate. Yan Liu, Zheng Wang, Kuiling

Ding* Tetrahedron 2012, 68, 7581-7585.

15. DpenPhos/Rh(I)催化的 β-脱氢氨基酸酯的不对称氢化反应. 刘龑, 王正, 丁奎岭* 化学学报 2012, 70(13), 1464-1470.

16. Catalytic Hydrogenation of Cyclic Carbonates: A Practical Approach from CO2

and Epoxides to Methanol and Diols. Zhaobin Han, Liangce Rong, Jiang Wu,

Zheng Wang, Kuiling Ding* Angew Chem. Int. Ed. 2012, 51, 13041-13045.(VIP)

17. Palladium-Catalyzed Asymmetric 1,4-Addition of Diarylphosphines to

Nitroalkenes for the Synthesis of Chiral P,N-Compounds. Jianjun Feng; Miao

Huang, Ziqi Lin, Weiliang Duan* Adv. Synth. Catal. 2012, 354, 3122-3126.

18. Palladium-catalyzed Asymmetric Addition of Diarylphosphines to N-tosylimines.

Miao Huang, Chun Li, Jian Huang, Weiliang Duan*, Sheng Xu Chem. Commun.

2012, 48, 11148-11150.

19. Diastereo- and Enantioselective Synthesis of Fluorinated Proline Derivatives via

Copper-Catalyzed Asymmetric 1,3-Dipolar Cycloaddition. Qing Li, Chag Hua

40

Ding, Xiao Hui Li, Walter Weissensteiner, Xuelong Hou* Synthesis 2012, 265-

271.

20. Regio- and Enantioselective Palladium-Catalyzed Allylic Alkylation of

Nitromethane with Monosubstituted Allyl Substrates: Synthesis of (R)-Rolipram

and (R)-Baclofen. Xiaofei Yang, Changhua Ding, Xiaohui Li, Jianqiang Huang,

Xuelong Hou*, Lixin Dai, Pinjie Wang J. Org. Chem. 2012, 77, 8980-8985.

21. Palladacycle-Catalyzed Reaction of Bicyclic Alkenes with Terminal Ynones:

Regiospecific Synthesis of Polysubstituted Furans. Guangcun Ge, Dongliang Mo,

Changhua Ding, Lixin Dai, Xuelong Hou* Org. Lett. 2012, 14, 5756-5759.

22. Multi-carbazole Derivatives: New Dyes for Highly Efficient Dye-sensitized Solar

Cells. Hua Lai, Jia Hong, Ping Liu, Chao Yuan, Yuxue Li*, Qiang Fang* RSC

Advances 2012, 2, 2427-2432.

23. Palladium-Catalyzed Oxidative Aryltrifluoromethylation of Activated Alkenes at

Room Temperature. Xin Mu, Tao Wu, Haoyang Wang, Yinlong Guo, Guosheng

Liu* J. Am. Chem. Soc. 2012, 134 (2), 878-881.

24. Highly Selective Palladium-Catalyzed Intramolecular Chloroamination of

Unactivated Alkenes by Using Hydrogen Peroxide as an Oxidant. Guoyin Yin,

Tao Wu, Guosheng Liu* Chem. Eur. J. 2012, 18, 451-455.

25. Transition Metal-catalyzed Fluorination of Multi Carbon–carbon Bonds: New

Strategies for Fluorinated Heterocycles. Guosheng Liu* Org. Biomol. Chem.

2012, 10, 6243-6248.

26. Palladium-Catalyzed Oxidative Arylalkylation of Unactivated Alkenes: Dual C–H

Bond Cleavage of Anilines and Acetonitrile. Hao Zhang, Pinhong Chen,

Guosheng Liu* Synlett. 2012, 23, 2749-2752.

27. Organocatalyzed Arylalkylation of Activated Alkenes via Decarboxylation of

PhI(O2CR)2: Efficient Synthesis of Oxindoles. Tao Wu, Hao Zhang, Guosheng

Liu* Tetrahedron 2012, 68, 5229-5233.

28. Silver-catalyzed Fluorination Reactions. Tao Xu, Guosheng Liu* SynLett. 2012,

23, 955-958.

29. Ag(I)-Catalyzed Aminofluorination of Alkynes: Efficient Synthesis of 4-

Fluoroisoquinolines and 4-Fluoropyrrolo[α]isoquinolines. Tao Xu, Guosheng

Liu* Org. Lett. 2012, 14, 5416-5419.

41

30. Gold-Catalyzed Cyclization of 1,6-Diyne-4-en-3-ols: Stannyl Transfer from 2-

Tributylstannylfuran Through Au/Sn Transmetalation. Yifeng Chen, Ming Chen,

Yuanhong Liu* Angew. Chem. Int. Ed. 2012, 51, 6181-6186.

31. Gold-Catalyzed Cascade Cyclizations of 1,6-Diynyl Carbonates to

Benzo[b]fluorenes Involving Arylation of Oxocarbenium Ion Intermediates and

Decarboxylative Etherification. Yifeng Chen, Ming Chen, Yuanhong Liu*

Angew. Chem. Int. Ed. 2012, 51, 6493-6497.

32. Nucleophilic Addition of Grignard Reagents to 3-Acylindoles: Stereoselective

Synthesis of Highly Substituted Indoline Scaffolds. Lu Wang, Yushang Shao,

Yuanhong Liu* Org. Lett. 2012, 14, 3978-3981.

33. Highly Efficient Synthesis of cis-[3]Cumulenic Diols via Zirconocene-Mediated

Coupling of 1,3-Butadiynes with Aldehydes. Xiaoping Fu, Shasha Yu, Guoqin

Fan, Yuanhong Liu*, Yuxue Li* Organometallics2012, 31, 531-534.

34. Gold-Catalyzed Furan/Yne Cyclizations for the Regiodefined Assembly of

Multisubstituted Protected 1-Naphthols. Chengyu Wang, Yifeng Chen, Xin Xie,

Jun Liu, Yuanhong Liu* J. Org. Chem. 2012, 77, 1915-1921.

35. Titanium-Mediated Cross-Coupling Reactions of Imines with Ketones or

Aldehydes: An Efficient Route for the Synthesis of 1,2-Amino Alcohols. Guoqin

Fan, Yuanhong Liu* Tetrahedron Lett. 2012, 53, 5084-5087. 

36. Gold-Catalyzed Cyclizations of (o-Alkynyl)phenoxyacrylates with External

Nucleophiles: Regio- and Stereoselective Synthesis of Functionalized

Benzo[b]oxepines. Jun Liu, Yuanhong Liu* Org. Lett. 2012, 14, 4742-4745.

37. Unexpected Zirconium-Mediated Multicomponent Reactions of Conjugated 1,3-

Butadiynes and Monoynes with Acyl Cyanide Derivatives. Shasha Yu, Xu, You,

Yuanhong Liu* Chem. Eur. J. 2012, 18, 13936-13940.

38. Palladium-catalyzed Highly Efficient Synthesis of Tetracenes and Pentacenes.

Ming Chen, Yifeng Chen, Yuanhong Liu* Chem. Commun. 2012, 48, 12189-

12191.

39. Facile Synthesis of Fully Substituted Dihydro-β-carbolines via Brønsted Acid

Promoted Cascade Reactions of α-Indolyl Propargylic Alcohols with Nitrones. Lu

Wang, Xin Xie, Yuanhong Liu* Org. Lett. 2012, 14, 5848-5851.

42

40. Cationic Pd(II)-Catalyzed Highly Enantioselective Arylative Cyclization of

Alkyne-tethered Enals or Enones Initiated by Carbopalladation of Alkynes with

Arylboronic Acid. Kun Shen, Xiuling Han*, Xiyan Lu* Org. Lett. 2012, 14,

1756-1759.

41. Palladium(II)-Catalyzed Cyclization Reaction of 2-(Alk-2’-ynyloxy)benzonitriles

or 2-(Alk-2’-ynylamino)benzonitriles: A Facile Way to 2H-Chromene and 1,2-

Dihydroquinoline Derivatives. Guoqin Xia, Xiuling Han*, Xiyan Lu*Adv. Synth.

Catal. 2012, 354, 2701-2705.

42. Allenes in Catalytic Asymmetric Synthesis and Natural Product Syntheses.

Shichao Yu, Shengming Ma*Angew. Chem. Int. Ed. 2012, 51, 3074-3112.

43. One-Pot Approach to Installing Eight-Membered Rings onto Indoles. Can Zhu,

Xue Zhang, Xiongdong Lian, Shengming Ma*Angew. Chem. Int. Ed. 2012, 51,

7817- 7820.

44. Palladium-Catalyzed Cyclization Reactions of 2,3-Allenyl Amines with

Propargylic Carbonates. Juntao Ye, Suhua Li, Shengming Ma* Org. Lett. 2012,

14, 2312-2315.

45. Palladium-Catalyzed Decarboxylation of Allenyl 3-Oxoalkanoates: An Efficient

Synthesis of 3,4-Allenyl Ketones. Baoqiang Wan, Guochen Jia*, Shengming

Ma* Org. Lett. 2012, 14, 46-49.

46. Catalytic Asymmetric Synthesis of Optically Active Allenes from Terminal

Alkynes. Juntao Ye, Suhua Li, Bo Chen,Wu Fan, Jinqiang Kuang, Jinxian Liu,

Yu Liu, Bukeyan Miao, Baoqiang Wan, Yuli Wang, Xi Xie, Qiong Yu, Weiming

Yuan, Shengming Ma* Org. Lett. 2012, 14, 1346-1349.

47. Tuning of Regioselectivity in Inorganic Iodide-Catalyzed Alkylation of 2-

Methoxyfurans via Electronic and Steric Effects. Jie Chen, Shengjun Ni,

Shengming Ma* Adv. Synth. Catal. 2012, 354, 1114-1128.

48. Electronic Effect-Directed Au(I)-Catalyzed Cyclic C2-H Bond Functionalization

of 3-Allenyl Indoles Involving Dearomatization. Bo Chen, Wu Fan, Guobi Chai,

Shengming Ma* Org. Lett. 2012, 14, 3616-3619.

49. CO2-Activation for γ-Butyrolactones and Its Application in the Total Synthesis of

(±)-Heteroplexisolide E. Suhua Li, Shengming Ma* Chem. Asian J. 2012, 7,

2411-2418.

43

50. Quadri-Synergtic Effect for Highly Effective Carbon Dioxide Fixation and Its

Application to Indoloquinolinone. Suhua Li, Shengming Ma* Adv. Synth. Catal.

2012, 354, 2387-2394.

51. Electrophilic Cyclization of 2-(2’,3’-Allenyl)acetylacetates with Iodine Using

Calcium Hydride as the Base. Baoqiang Wan, Xuefeng Jiang, Guochen Jia*,

Shengming Ma* Eur. J. Org. Chem. 2012, 4373-4379.

52. Efficient Synthesis of N-(buta-2,3-dienyl) amides from Terminal N-propargyl

Amides and Their Synthetic Potential towards Oxazoline Derivatives. Bo Chen,

Nan Wang, Wu Fan, Shengming Ma* Org. Biomol. Chem. 2012, 10, 8465-8470.

53. FeCl3-catalyzed Cyclization of α-sulfonamido-allenes with Aldehydes—the

Substituent Effect. Jiajia Cheng, Xinjun Tang, Yihua Yu, Shengming Ma*

Chem. Commun. 2012, 48, 12074-12076.

54. PPh2Me-Mediated Tandem Reaction of 2-Alkyl-2,3-butadienoates with

Isothiocyanates: Formation of 2-Aminothiophenes. Xiaoyang Guan, Min Shi*

ACS Catalysis 2011, 1, 1154-1157.

55. Preparation of Chiral Multifunctional Thiourea–Phosphanes and Synthesis of

Chiral Allylic Phosphites and Phosphane Oxides through Asymmetric Allylic

Substitution Reactions of Morita–Baylis–Hillman Carbonates. Hongping Deng,

Min Shi* Eur. J. Org. Chem. 2012, 183-187.

56. Rhodium(I)-Catalyzed [3+2] Intramolecular Cycloaddition of

Alkylidenecyclopropane-propargylic Esters. Dihan Zhang, Min Shi* Tetrahedron

Lett. 2012, 53, 487-490.

57. Nitrogen- and Phosphorus-Containing Lewis Bases Catalyzed [4+2] and [3+2]

Annulations of Isatins with But-3-yn-2-one. Zhong Lian, Min Shi* Eur. J. Org.

Chem. 2012, 581-586.

58. LDA-Mediated Cascade Carbolithiation Reactions of Vinylidenecyclopropanes

with Enones and N-Sulfonated Imines as Well as Nitroalkene and

Phenylmethylidenemalononitrile. Beili Lu, Jianmei Lu, Min Shi* Eur. J. Org.

Chem. 2012, 587-695.

59. Reactions of Vinylidenecyclopropanes with Diphenyl Diselenide in the Presence

of AIBN and Thermal-induced Further Transformation. Wei Yuan, Yin Wei, Min

44

Shi*, Yuxue Li* Chem. Eur. J. 2012, 18, 1280-1285.

60. HOTf Mediated Cascade Reactions of 1-Arenoylcyclopropanecarboxylic Acids

with Arenes. Genqiang Chen, Xiangying Tang, Min Shi* Chem. Commun. 2012,

48, 2340-2342.

61. Phosphorus-Containing Lewis Base Catalyzed Highly Regioselective Cyclization

of Isatin Derived Electron Deficient Alkenes with But-3-yn-2-one. Zhong Lian,

Yin Wei, Min Shi* Tetrahedron 2012, 68, 2401-2408.

62. Asymmetric Catalytic Mannich-type Reaction of Hydrazones with

Difluoroenoxysilanes by using Imidazoline-anchored phosphine Ligand-Zinc(II)

Complexes. Zhiliang Yuan, Liangyong Mei, Yin Wei, Min Shi*, Padmanabha V.

Kattamuri, Patrick McDowell, Guigen Li Org. Biomol. Chem. 2012, 10, 2509-

2513.

63. Enantioselective Synthesis of Highly Functionalized Trifluoromethyl-Bearing

Cyclopentenes: Asymmetric [3+2] Annulation of Morita-Baylis-Hillman

Carbonates with Trifluoroethylidene Malonates Catalyzed by Multifunctional

Thiourea-Phosphines. Hongping Deng, Yin Wei, Min Shi* Adv. Synth. & Catal.

2012, 354, 783-789.

64. Strained Small Rings in Gold-Catalyzed Rapid Chemical Transformations. Beili

Lu, Lunzhi Dai, Min Shi* Chem. Soc. Rev. 2012, 41, 3318-3339.

65. Reduction of Activated Carbonyl Groups Using Alkyl Phosphines as Reducing

Agents: A Mechanistic Study. Yin Wei, Xuguang Liu, Min Shi* Eur. J. Org.

Chem. 2012, 2386-2393.

66. Gold(I)-Catalyzed Intramolecular Hydroamination and Ring-Opening of

Sulfonamide-Substituted 2-(Arylmethylene)cyclopropylcarbinols. Dihan Zhang,

Kang Du, Min Shi* Org. Biomol. Chem. 2012, 10, 3763-3766.

67. Rapid Generation of Molecular Complexity in the Lewis or Brønsted Acid-

mediated Reactions of Methylenecyclopropanes. Min Shi*, Jianmei Lu, Yin Wei,

Lixiong Shao* Acc. Chem. Res. 2012, 45, 641-652.

68. A Three-component Condensation to Construct Spiro[indoline-3,3'-piperidin]-2-

one Skeleton. Haibin Yang, Xiaoyang Guan, Yin Wei, Min Shi* Eur. J. Org.

45

Chem. 2012, 2792-2800.

69. Gold(I)-Catalyzed Cycloisomerization of Nitrogen and Oxygen-Tethered

Alkylidenecyclopropanes to Tricyclic Compounds. Dihan Zhang, Yin Wei*, Min

Shi* Chem. Eur. J. 2012, 18, 7026-7029.

70. DABCO-mediated [4+2] Annunation of But-3-yn-2-one and Activated Ketones:

Facile Preparation of 2,3-Dihydropyran-4-one. Zhong Lian, Qianyi Zhao, Yin

Wei, Min Shi* Eur. J. Org. Chem. 2012, 3338-3341.

71. Rh(I)-catalyzed Pauson-Khand-type [3+2+1] Cycloaddition Reaction of Ene-

vinylidenecyclopropanes and CO: A Highly Regio- and Stereoselective Synthetic

Approach for the Preparation of Aza- or Oxa-bicyclic Compounds. Beili Lu, Yin

Wei, Min Shi* Organometallics 2012, 31, 4601-4609.

72. Chiral Multifunctional Thiourea-Phosphine-Catalyzed Asymmetric [3+2]

Annulation of Morita-Baylis-Hillman Carbonates with Maleimides. Hongping

Deng, De Wang, Yin Wei, Min Shi* Beils. J. Org. Chem. 2012, 8, 1098-1104.

73. An Efficient Method for the Synthesis of Alkylidenecyclobutanones via Gold-

Catalyzed Oxidative Ring Enlargement of Vinylidenecyclopropanes. Wei Yuan,

Xiang Dong, Min Shi* Chem. Eur. J. 2012, 18, 10501-10505.

74. Transition Metal-catalyzed Carbocyclization of Nitrogen and Oxygen-tethered

1,n-enynes and Diynes: Synthesis of Five or Six-membered Heterocyclic

Compounds. Dihan Zhang, Zhen Zhang, Min Shi* Chem. Commun. 2012, 48,

10271-10279.

75. Asymmetric [3+2] Annulation of N-protected Isatins with But-3-yn-2-one

Catalyzed by DIOP: Facile Creation of Enantioenriched Spiro[furan-2,3'-

indoline]-2',4(5H)-dione. Zhong Lian, Min Shi* Org. Biomol. Chem. 2012, 10,

8048-8050.

76. Yb(NTf2)3-Catalyzed [3+3] Cycloaddition between Isatin Ketonitrones and

Cyclopropanes to Construct Novel Spiro[tetrahydro-1,2-oxazine]oxindoles.

Haibin Yang, Min Shi* Org. Biomol. Chem. 2012, 10, 8236-8243.

77. Rh(I)-catalyzed Pauson-Khand-type Cycloaddition Reaction of Ene-

vinylidenecyclopropanes with Carbon Monoxide (CO). Wei Yuan, Xiang Dong,

46

Min Shi*, Patrick McDowell, Guigen Li* Org. Lett. 2012, 14, 5582-5585.

78. A Chiral Cage-like Copper(I) Catalyst for the Highly Enantioselective Synthesis

of 1,1-Cyclopropane Diesters. Chao Deng, Lijia Wang, Jun Zhu, Yong Tang*

Angew. Chem. Int. Ed. 2012, 51, 11620-11623.

79. Side-Arm-Promoted Highly Enantioselective Ring-Opening Reactions and

Kinetic Resolution of Donor-Acceptor Cyclopropanes with Amines. Youyun

Zhou, Lijia Wang, Jun Li, Xiuli Sun*, Yong Tang* J. Am. Chem. Soc. 2012, 134,

9066-9069.

80. Tridentate Ligands and Beyond in Group IV Metal α-olefin Homo-/co-

polymerization Catalysis. Carl Redshaw*, Yong Tang* Chem. Soc. Rev. 2012,

41, 4484-4510.

81. Highly Diastereo- and Enantioselective Cyclopropanation of 1,2-Disubstituted

Alkenes. Jun Li, Saihu Liao, Hu Xiong, Youyun Zhou, Xiuli Sun*, Yue Zhang,

Xiaoguang Zhou, Yong Tang* Angew. Chem. Int. Ed. 2012, 51, 8838-8841.

82. 有机化学中新兴领域的积极开拓者——黄耀曾先生。唐勇*， 戴立信* 化学

进展 2012， 24，1623-1631.

83. Highly Efficient and Practical Catalytic Wittig Olefination. Peng Wang,

Chunrong Liu, Xiuli Sun, Shuaishuai Chen, Junfang Li, Zuowei Xie, Yong Tang*

Chem. Commun. 2012, 48, 290-292.

84. Highly Diastereoselective Construction of Fused Carbocycles from

Cyclopropane-1,1-dicarboxylates and Cyclic Enol Silyl Ethers: Scope,

Mechanism, and Origin of Diastereoselectivity. Jianping Qu, Yong Liang, Hao

Xu, Xiuli Sun, Zhixiang Yu*, Yong Tang* Chem. Eur. J. 2012, 18, 2196-2201.

85. Diastereoselective and Enantioselective Desymmetrization of α-Substituted

Cyclohexadienones via Intramolecular Stetter Reaction. Minqiang Jia, Chuan Liu,

Shuli You*J. Org. Chem. 2012, 77, 10996-11001.

86. Ring-Closing Metathesis/Isomerization/Pictet-Spengler Cascade via Ruthenium/

Chiral Phosphoric Acid Sequential Catalysis. Quan Cai, Xiaowei Liang, Shouguo

47

Wang, Junwei Zhang, Xiao Zhang, Shuli You* Org. Lett. 2012, 14, 5022-5025.

87. Enantioselective Construction of Pyrroloindolines via Chiral Phosphoric Acid

Catalyzed Cascade Michael Addition Cyclization of Tryptamines. Quan Cai,

Chuan Liu, Xiaowei Liang, Shuli You* Org. Lett. 2012, 14, 4588-4590.

88. One-Pot Synthesis of Pyrrolo[1,2-a]indoles by Chiral N-Triflyl Phosphoramide

Catalyzed Friedel-Crafts Alkylation of 4,7-Dihydroindole with β,γ-Unsaturated α-

Keto Esters (invited paper for Special Issue “Asymmetric Catalysis” Guest

Editor: Shuli You). Mi Zeng, Wei Zhang*, Shuli You* Chin. J. Chem. 2012, 30,

2615-2623.

89. Catalytic Asymmetric Dearomatization Reactions. Chunxiang Zhuo, Wei Zhang*,

Shuli You* Angew. Chem. Int. Ed. 2012, 51, 12662-12686.

90. Copper(I)-Catalyzed Cascade Dearomatization of 2-Substituted Tryptophols with

Arylidonium Salts. Chuan Liu, Wei Zhang, Lixin Dai, Shuli You* Org. Lett.

2012, 14, 4525-4527.

91. Palladium(0)-Catalyzed Dearomative Arylation of Indoles: Convenient Access to

Spiroindolenine Derivatives. Kejia Wu, Lixin Dai, Shuli You* Org. Lett. 2012,

14, 3772-3775.

92. Cascade Dearomatization of N-Subsituted Tryptophols via Lewis Acid-Catalyzed

Michael Reaction. Chuan Liu, Wei Zhang, Lixin Dai, Shuli You* Org. Biomol.

Chem. 2012, 10, 7177-7183.

93. Intramolecular Alkene Electrophilic Bromination Initiated ipso-Bromocyclization

for the Synthesis of Functionalized Azaspirocyclohexadienones. Qin Yin, Shuli

You* Org. Lett. 2012, 14, 3526-3529.

94. Organocatalyzed Enantioselective Formal [4+2] Cycloaddition of 2,3-

Disubstituted Indole and Methyl Vinyl Ketone. Quan Cai, Shuli You* Org. Lett.

2012, 14, 3040-3043.

95. Desymmetrization of Cyclohexadienones via D-Camphor-derived Triazolium

Salts Catalyzed Intramolecular Stetter Reaction. Minqiang Jia, Shuli You* Chem.

Commun. 2012, 48, 6363-6365.

48

96. Enantioselective Synthesis of Tetrahydroisoquinolines via Iridium-Catalyzed

Intramolecular Friedel-Crafts-Type Allylic Alkylation of Phenols. Qinglong Xu,

Lixin Dai, Shuli You* Org. Lett. 2012, 14, 2579-2581.

97. Iridium-Catalyzed Enantioselective Allylic Alkylation of Methyl 2-(4-

nitrophenylsulfonyl)acetate and Subsequent Transformations. Qinglong Xu, Lixin

Dai, Shuli You* Adv. Synth. Catal. 2012, 354, 2275-2282.

98. Asymmetric N-Allylation of Indoles via Ir-Catalyzed Allylic Alkylation of

Indolines and Oxidation Strategy. Wenbo Liu, Xiao Zhang, Lixin Dai, Shuli

You* Angew. Chem. Int. Ed. 2012, 51, 5183-5187.

99. Enantioselective Synthesis of 2,5-Dihydrobenzo[b]azepine Derivatives via

Iridium-Catalyzed Asymmetric Allylic Amination with 2-Allylanilines and Ring-

Closing-Metathesis Reaction. Keyin Ye, Lixin Dai, Shuli You* Org. Biomol.

Chem. 2012, 10, 5932-5939.

100. Enantioselective Synthesis of Fluorene Derivatives by Chiral N-Triflyl

Phosphoramide Catalyzed Double Friedel-Crafts Alkylation Reaction. Shouguo

Wang, Long Han, Mi Zeng, Fenglai Sun, Wei Zhang, Shuli You* Org. Biomol.

Chem. 2012, 10, 3202-3209.

101. Ir-Catalyzed Allylic Alkylation Reaction with N-Aryl Phosphoramidite

Ligands: Scope and Mechanistic Studies. Wenbo Liu, Chao Zheng, Chunxiang

Zhuo, Lixin Dai, Shuli You* J. Am. Chem. Soc. 2012, 134, 4812-4821.

102. Iridium-Catalyzed Asymmetric Allylic Etherification and Ring-Closing-

Metathesis Reaction for Enantioselective Synthesis of Chromene and 2,5-

Dihydrobenzo[b]oxepine Derivatives. Hu He, Keyin Ye, Qingfeng Wu, Lixin

Dai, Shuli You* Adv. Synth. Catal. 2012, 354, 1084-1094.

103. Transfer Hydrogenation with Hantzsch Esters and Related Organic Hydride

Donors. Chao Zheng, Shuli You* Chem. Soc. Rev. 2012, 41, 2498-2518.

104. Enantioselective Syntheses of Spiro Cyclopentane-1,3'-indoles and 2,3,4,9-

Tetrahydro-1H-carbazoles via Ir-Catalyzed Allylic Dearomatization and

Stereospecific Migration. Qingfeng Wu, Chao Zheng, Shuli You* Angew. Chem.

Int. Ed. 2012, 51, 1680-1683.

49

105. Asymmetric Dearomatization of Pyrroles via Ir-Catalyzed Allylic

Substitution Reaction: Enantioselective Synthesis of Spiro-2H-pyrroles.

Chunxiang Zhuo, Wenbo Liu, Qingfeng Wu, Shuli You* Chem. Sci. 2012, 3,

205-208.

以下论文重点实验室为作者第二单位：1. Synthesis and Catalytic Activity of Heterogeneous Rare-earth Metal Catalysts

Coordinated with Multitopic Schiff-base Ligands. Yilin Sun, Guangming Wu,

Dinghai Cen, Yaofeng Chen*, Limin Wang* Dalton Trans. 2012, 41, 9682-9688.

2. Spiroketal-Based Phosphorus Ligands for Highly Regioselective

Hydroformylation of Terminal and Internal Olefins. Xiaofei Jia, Zheng Wang,

Chungu Xia*, Kuiling Ding* Chem. Eur. J. 2012, 18, 15288-15295.

3. Pd-Catalyzed Diastereo- and Enantio-selective [3+2] Cycloaddition Reaction of

Vinyl Epoxide with Nitroalkenes. Wenqiong Wu, Changhua Ding, Xuelong Hou*

Synlett. 2012, 1035-1038.

4. Tempering the Reactivities of Postulated α-Oxo Gold Carbenes Using Bidentate

Ligands: Implication of Tricoordinated Gold Intermediates and the Development

of an Expedient Bimolecular Assembly of 2,4-Disubstituted Oxazoles. Yingdong

Luo, Kegong Ji, Yuxue Li, Liming Zhang* J. Am. Chem. Soc. 2012, 134, 17412-

17415.

5. Highly Selective Activation of Vinyl C–S Bonds Over Aryl C–S Bonds in the Pd-

Catalyzed Coupling of (E)-(β-Trifluoromethyl)vinyldiphenylsulfonium Salts:

Preparation of Trifluoromethylated Alkenes and Dienes. Hao Lin, Xicheng Dong,

Yuxue Li*, Qilong Shen,* Long Lu* Eur. J. Org. Chem. 2012, 4675-4679.

6. Benzofurans or Isochromenes via the Ring-Opening Cyclization of Cyclopropene

Derivatives with Organolithiums. Yu Liu, Shengming Ma* Org. Lett. 2012, 14,

720-723.

7. Copper (I) Iodide-Catalyzed One-Step Preparation of Functionalized Allenes

from Terminal Alkynes: Amine Effect. Jinqiang Kuang, Hongwen Luo,

Shengming Ma* Adv. Synth. Catal. 2012, 354, 933-944.

8. Aerobic Oxidation of Propargylic Alcohols to α,β-Unsaturated Alkynals or

Alkynones Catalyzed by Fe(NO3)39H2O, TEMPO and Sodium Chloride in

Toluene. Jinxian Liu, Xi Xie, Shengming Ma* Synthesis 2012, 44, 1569-1576.

50

9. CuCl-Catalyzed Aerobic Oxidation of Allylic and Propargylic Alcohols to

Aldehydes or Ketones with 1 1 Combination of Phenanthroline and Bipyridine as∶

the Ligands. Yu Liu, Shengming Ma* Chin. J. Chem. 2012, 30, 29-34.

10. CuCl–K2CO3-Catalyzed Highly Selective Borylcupration of Internal Alkynes–

Ligand Effect. Weiming Yuan, Shengming Ma* Org. Biomol. Chem. 2012, 10,

7266-7268.

11. Efficient Synthesis of 4-Halo-2,5-dihydro-1,2-oxaphosphole 2-Oxides from 1,2-

Allenylphosphonates and CuX2 and Subsequent Suzuki Cross-Coupling of the C–

Cl Bonds. Ning Xin, Shengming Ma* Eur. J. Org. Chem. 2012, 3806-3817.

12. Ligand Controlled Highly Selective Copper-Catalyzed Borylcuprations of

Allenes with Bis(pinacolato)diboron. Weiming Yuan, Shengming Ma* Adv.

Synth. Catal. 2012, 354, 1867-1872.

13. Lewis Acid-catalyzed Unexpected Selective C–C Bond Cleavage: An Efficient

and Mild Construction of Cyclopentenes. Qiong Yu, Shengming Ma* Chem.

Commun. 2012, 48, 11784-11786.

14. Synthesis, Structure, and Ethylene Polymerization Behavior of Nickel Complexes

Based on Benzoylmethylenetri(2-alkoxylphenyl)phosphorane. Dawei Wan,

Yanshan Gao, Junfang Li, Qi Shen, Xiuli Sun*, Yong Tang Dalton Transactions

2012, 41, 4552-4557.

15. Tris(oxazoline)/copper-catalyzed Coupling of Alkynes with Nitrones: A Highly

Enantioselective Access to Beta-lactams. Jianghua Chen, Saihu Liao, Xiuli Sun,

Qi Shen*, Yong Tang* Tetrahedron 2012, 68, 5042-5045.

16. Synthesis, Characterization, and Highly Selective Ethylene Dimerization to 1-

Butene of [O-NX]Ni(II) Complexes, Chongjie Xu, Qi Shen, Xiuli Sun*, Yong

Tang, Chin. J. Chem. 2012, 30, 1105-1113.

17. Chiral Counteranion-Directed Silver-Catalyzed Asymmetric Synthesis of 1,2-

Dihydroisoquinolines by Friedel-Crafts Alkylation Reactions. Junwei Zhang, Zhe

Xu, Qing Gu, Xiaoxin Shi, Xuebing Leng, Shuli You* Tetrahedron 2012, 68,

5263-5268.

51

二、 客座人员论文目录（按通讯作者姓氏首字母排序）1. Scope and Regioselectivity of the 1,3-Dipolar Cycloaddition of Azides with

Methyl 2-Perfluoroalkynoates for An Easy, Metal-free Route to

Perfluoroalkylated 1,2,3-Triazoles. Jiamei Wei, Jie Chen, Jiechao Xu, Long Cao,

Hongmei Deng, Weihua Sheng, Hui Zhang*, Weiguo Cao* J. Fluorine Chem.

2012, 133, 146-154.

2. An Efficient and Highly Stereoselective Synthesis of Novel Trifluoromethylated

trans-Dihydrofuro[2,3-c]pyrazoles Using Arsonium Ylides. Jiaping Zhang,

Shuxin Yang, Kai Zhang, Jie Chen, Hongmei Deng, Min Shao, Hui Zhang*,

Weiguo Cao* Tetrahedron 2012, 68, 2121-2127.

3. Preparation of (E)-4-Aryl-1,1,1-trifluoro-3-tosylbut-3-en-2-ones as Fluorinated

Building Blocks and Their Application in Ready and Highly Stereoselective

Routes to trans-2,3-Dihydrofurans Substituted with Trifluoromethyl and Sulfonyl

Groups. Haigang Yu, Jing Han, Jie Chen, Hongmei Deng, Min Shao, Hui

Zhang*, Weiguo Cao* Eur. J. Org. Chem. 2012, 16, 3142-3150.

4. Redox-Modulated Stepwise Photochromism in a Ruthenium Complex with Dual

Dithienylethene-Acetylides. Bin Li, Jinyun Wang, Huimin Wen, Linxi Shi,

Zhongning Chen* J. Am. Chem. Soc. 2012, 134, 16059-16067.

5. Gold(I)-Coordination Triggered Multistep and Multiple Photochromic Reactions

in Multi-Dithienylethene (DTE) Systems. Bin Li, Yuhui Wu, Huimin Wen, Linxi

Shi, Zhongning Chen* Inorg. Chem. 2012, 51, 1933-1942.

6. Vapochromic and Mechanochromic Phosphorescence Materials Based on a

Platinum(II) Complex with 4-Trifluoromethylphenylacetylide. Xu Zhang, Jinyun

Wang, Jun Ni, Liyi Zhang, Zhongning Chen* Inorg. Chem. 2012, 51, 5569-

5579.

7. Head-to-Tail and Back-to-Back Dimerization of an Open-Cage Fullerene

Derivative through π-π Interaction-Based Self-Assembly. Shuming Liu, Qianyan

Zhang, Yuming Yu, Liangbing Gan* Org. Lett. 2012, 14, 4002-4005.

52

8. Fullerene Doping: Preparation of Azafullerene C59NH and Oxafulleroids C59O3

and C60O4. Nana Xin, Huan Huang, Jianxin Zhang, Zhifei Dai, Liangbing Gan*

Angew. Chem. Int. Ed. 2012, 51, 6163-6166.

9. Facile Preparation of Fullerenyl Boronic Esters. Zhifei Da, Zhongping Jiang,

Gang Zhang, Nana Xin, Liangbing Gan* Tetrahedron, 2012, 68, 5193-5196.

10. Selective Synthesis of Fullerenol Derivatives with Terminal Alkyne and Crown

Ether Addends. Huan Huang, Gang Zhang, Sisi Liang, Nana Xin, Liangbing

Gan* J. Org. Chem., 2012, 77, 2456-2462.

11. Synthesis of Decahydropyrrolo[2,1,5-cd]indolizine Derivatives through

RuCl3/AgOTf induced Alkene–alkene and Alkene–arene Double

Cycloisomerizations. Peipei Cui, Liang Xu, Hao Cheng, Liangbing Gan*

Tetrahedron, 2012, 68, 152-158.

12. Copper-catalyzed C-H Azidation of Anilines under Mild Conditions. Conghui

Tang, Ning Jiao* J. Am. Chem. Soc. 2012, 134, 18924-18927. (Highlighted by

Synform)

13. Cu-mediated Aerobic Oxidative Dehydrogenative Annulation and Oxygenation of

Aldehydes and Amines for Oxazoles via C-H Functionalization and Dioxygen

Activation. Xejun Xu,† Chun Zhang,† (†These two authors contributed equally to

this work), Ning Jiao* Angew. Chem. Int. Ed. 2012, 51, 11367–11370 (Hot

Paper).

14. Iron-Facilitated Oxidative Dehydrogenative C-O Bond Formation via Propargyl

Csp3–H Functionalization. Teng Wang, Wang Zhou, Hang Yin, Jun-An Ma, Ning

Jiao* Angew. Chem. Int. Ed. 2012, 51, 10823-10826.

15. Metal-Free, NHPI Catalyzed Oxidative Cleavage of C-C Double Bond Using

Molecular Oxygen as Oxidant. Riyuan Lin, Feng Chen, Ning Jiao* Org. Lett.

2012, 14, 4158-4161.

16. Chemoselective Synthesis of Naphthylamides & Isoquinolinones via Rh-

catalyzed Oxidative Dehydrogenative Annulation of Benzamides with Alkynes.

Zhuangzhi Shi,† Conghui Tang,† (†These two authors contributed equally to this

work), Ning Jiao* Adv. Synth. Cat. 2012, 354, 2695-2700.

53

17. FeCl2-promoted Unactivated C-C Bond Cleavage of Alkylarenes and Polystyrene:

Direct Synthesis of Versatile Arylamines. Chong Qin, Tao Shen, Conghui Tang,

Ning Jiao*Angew. Chem. Int. Ed. 2012, 51, 6971-6975 (Hot Paper).

18. N,N-Dimethylformamide: A Multipurpose Building Block. Shengtao Ding, Ning

Jiao* Angew. Chem. Int. Ed. 2012, 51, 9226-9237(review, invited contribution).

19. N-Heterocyclic Carbene-Catalyzed Homoenolate Additions with N-Aryl

Ketimines as Electrophiles: Efficient Synthesis of Spirocyclic γ-Lactam

Oxindoles. Bo Zhang, Peng Feng, Lihui Sun, Yuxin Cui, Song Ye*, Ning Jiao*

Chem. Eur. J. 2012, 18, 9198-9203.

20. Mn-promoted Aerobic Oxidative C-C Bond Cleavage of Aldehydes with

Dioxygen Activation: A Simple Synthetic Approach to Formamides. Chun Zhang,

Zejun Xu, Tao Shen, Guolin Wu, Liangren Zhang, Ning Jiao* Org. Lett. 2012,

14, 2362-2365.

21. Multiple Oxidative Dehydrogenative Functionalization of Aryl Acetaldehydes

Using Molecular Oxygen as Oxidant Leading to 2-Oxo-acetamidines. Chun

Zhang, Liangren Zhang, Ning Jiao* Adv. Synth. Cat. 2012, 354, 1293-1300.

22. Recent Advances in Transition-metal Catalyzed Reactions Using Molecular

Oxygen as the Oxidant. Zhuangzhi Shi, Chun Zhang, Chonghui Tang, Ning Jiao*

Chem. Soc. Rev. 2012, 41, 3381-3430.

23. Zwitterionic Half-sandwich Rh and Ir Complexes Containing a Diphosphine

Nido-carborane Ligand: Synthesis, Structure Transformation and Application in

H2 Activation. Zijian Yao, Xiankuan Huo, Guoxin Jin* Chem. Commun. 2012,

48, 6714–6716.

24. Efficient Route to Organometallic Cage Formation via C-H Activation-Directed

Muticomponent Assembly Accompanying Aromatic Guest Encapsulation.

Yingfeng Han, Yuejian Lin, T. S. Andy Hor, Guoxin Jin* Organometallics 2012,

31, 995-1000.

25. Synthesis, Reactivity, and Structural Transformation of Mono- and Binuclear

Carboranylamidinate-Based 3d Metal Complexes and Metallacarborane

Derivatives. Zijian Yao, Guoxin Jin* Organometallics 2012, 31, 1767-1774.

26. Self-Assembled Hexanuclear Organometallic Cages: Synthesis, Characterization,

54

and Host-Guest Properties. Yingfeng Han, Hao Li, Zhifang Zheng, Guoxin Jin*

Chem. Asian J. 2012, 7, 1243- 1250.

27. Oxidative Polymerization of 2,6-Dimethylphenol to Form Poly(2,6-dimethyl-1,4-

phenylene Oxide) in Water Through One Water-Soluble Copper(II) Complex of a

Zwitterionic Calix[4]arene. Limin Wan, Hongxi Li, Wei Zhao, Hongye Ding,

Yangyang Fang, Peihong Ni, Jianping Lang* J. Polym. Sci. Part A: Polym.

Chem. 2012, 50, 4864-4870.

28. Formation of N-heterocyclic Diphosphine Ligands from Ag(I)-assisted Mannich

Condensation Reactions between Bdppeda and HCHO and Their Sandwich-like

Silver(I) Complexes. Sha Sun, Zhigang Ren, Juhua Yang, Rentian He, Fan Wang,

Xinyi Wu, Weijie Gong, Hongxi Li, Jianping Lang* Dalton Trans. 2012, 41,

8447-8454.

29. Activation and Amplification of the Third-order NLO and Luminescent

Responses of a Cluster Precursor by a Supramolecular Approach. Xi Chen,

Hongxi Li, Zhiyuan Zhang, Wei Zhao, Jianping Lang*, Brendan F. Abrahams

Chem. Commun. 2012, 48, 4480-4482.

30. Reactions of the Cationic Zinc Thiolate Model Complex [Zn(Tab)4](PF6)2 with N-

Donor Ligands and Cobalt Dichloride. Aixia Zheng, Jing Si, Xiaoyan Tang, Lili

Miao, Miao Yu, Kaipeng Hou, Fan Wang, Hongxi Li, Jianping Lang* Inorg.

Chem. 2012, 51, 10262-10273.

31. Group 12 Metal Zwitterionic Thiolate Compounds: Preparation and Structural

Characterization. Xiaoyang Tang, Rongxin Yuan, Jinxiang Chen, Wei Zhao, Aixia

Zheng, Miao Yu, Hongxi Li, Zhigang Ren, Jianping Lang* Dalton Trans. 2012,

41, 6162-6172.

32. Assembly of Two Cluster-based Coordination Polymers with Good NLO

Performances from One NLO-inactive Precursor Cluster [Et4N][Tp*W(μ3-

S)3(CuCl)3]. Xi Chen, Hongxi Li, Zhiyuan Zhang, Cheng Xu, Kaipeng Hou,

Likuan Zhou, Jianping Lang*, Zhenrong Sun CrystEngComm. 2012, 14, 4027-

4033.

33. Substituted Groups-directed Assembly of Cd(II) Coordination Polymers Based on

55

5-R-1,3-benzenedicarboxylate and 4,4′-bis(1-imidazolyl)bibenzene: Syntheses,

Structures and Photoluminescent Properties. Hongjian Cheng, Hongxi Li,

Zhigang Ren, Chunning Lü, Jing Shi, Jianping Lang* CrystEngComm. 2012, 14,

6064-6071.

34. Zinc(II) Coordination Polymers of Tetrakis(4-pyridyl)cyclobutane and Various

Dicarboxylates: Syntheses, Structures and Luminescent Properties, Min Dai,

Wenyan Yan, Zhigang Ren, Huifang Wang, Weijie Gong, Feilong Li, Xin Zhao,

Hongxi Li, Jianping Lang* CrystEngComm. 2012, 14, 6230-6240.

35. Spectroscopic Observation of Iodosylarene Metalloporphyrin Adducts and

Manganese(V)-oxo Porphyrin Species in a Cytochrome P450 Analogue. Mian

Guo, Hang Dong, Jie Li, Ben Cheng, Yunqing Huang, Yuqi Feng, Aiwen Lei*

Nat. Commun. 2012, 3, 1190-1198.

36. Insights into the Elementary Steps in Negishi Coupling through Kinetic

Investigations. Liqun Jin, Aiwen Lei* Org. Biomol. Chem. 2012, 10, 6817-6825.

37. Alkylboronic Esters from Palladium- and Nickel-Catalyzed Borylation of

Primary and Secondary Alkyl Bromides. Jun Yi, Jinhui Liu, Jun Liang, Jianjun

Dai, Chuting Yang, Yao Fu, Lei Liu* Adv. Synth. Catal. 2012, 354, 1685-1691.

38. Rh-Catalyzed C-C Cleavage of Benzyl/Allylic Alcohols to ProduceBenzyl/

Allylic Amines or other Alcohols by Nucleophilic Addition of Intermediate

Rhodacycles to Aldehydes and Imines. Xisha Zhang, Yang Li, Hu Li, Kang

Chen, Zhiquan Lei, Zhangjie Shi* Chem. Eur. J. 2012, 18, 16214-16225.

39. From C(sp2)–H to C(sp3)–H: Systematic Studies on Transition Metal-catalyzed

Oxidative C–C Formation. Bijie Li, Zhangjie Shi* Chem. Soc. Rev. 2012, 41,

5588-5598.

40. Synthesis of Fluorenone Derivatives through Pd-Catalyzed Dehydrogenative

Cyclization. Hu Li, Ruyi Zhu, Wenjuan Shi, Kehan He, Zhangjie Shi* Org. Lett.

2012, 14, 4850-4853.

41. Reductive Cleavage of the Csp2-Csp3 Bond of Secondary Benzyl Alcohols:

Rhodium Catalysis Directed by N-Containing Groups. Kang Chen, Hu Li,

Zhiquan Lei, Yang Li, Wenhe Ye, Lisheng Zhang, Jian Sun, Zhangjie Shi*

56

Angew. Chem. Int. Ed. 2012, 51, 9851-9855.

42. Direct Arylation/Alkylation/Magnesiation of Benzyl Alcohols in the Presence of

Grignard Reagents via Ni-, Fe-, or Co-Catalyzed sp3 C–O Bond Activation.

Dagang Yu, Xin Wang, Ruyi Zhu, Shuang Luo, Xiaobo Zhang, Biqin Wang,

Zhangjie Shi* J. Am. Chem. Soc. 2012, 134, 14638-14641.

43. Olefinic C–H Bond Addition to Aryl Aldehyde and Its N-Sulfonylimine via Rh

Catalysis. Yang Li, Xisha Zhang, Qilei Zhu, Zhangjie Shi* Org. Lett. 2012, 14,

4498-4501.

44. Challenges in C–C Bond Formation through Direct Transformations of sp2 C–H

Bonds. Dagang Yu, Bijie Li, Zhangjie Shi* Tetrahedron 2012, 68, 5130-5136.

45. Mechanistic Insight into the Regioselective Palladation of Indole Derivatives:

Tetranuclear Indolyl Palladacycles with High C2–Pd or C3–Pd Bond Selectivity.

Yang Li, Wenhua Wang, Kehan He, Zhangjie Shi* Organometallics 2012, 31,

4397-4400.

46. Straightforward Synthesis of Phenanthrenes from Styrenes and Arenes. Hu Li,

Kehan He, J. Liu, Biqin Wang, Keqing Zhao, Zhangjie Shi* Chem. Commun.

2012, 48, 7028-7030.

47. Rhodium/Copper-Catalyzed Annulation of Benzimides with Internal Alkynes:

Indenone Synthesis through Sequential C-H and C-N Cleavage. Bijie Li,

Haoyuan Wang, Qilei Zhu, Zhangjie Shi* Angew. Chem. Int. Ed. 2012, 51,

3948-3952.

48. Direct Oxidative Arylation via Rhodium-Catalyzed C-C Bond Cleavage of

Secondary Alcohols with Arylsilanes. Kang Chen, Hu Li, Yang Li, Xisha Zhang,

Zhiquan Lei, Zhangjie Shi* Chem. Sci. 2012, 3, 1645-1649.

49. Mechanistic Understanding on Rh-Catalyzed N-Sulfonylaldimines Insertion to

Aryl C-H Bonds.Yang Li, Xisha Zhang, Hu Li, Wenhua Wang, Kang Chen, Bijie

Li, Zhangjie Shi* Chem. Sci. 2012, 3, 1634-1639.

50. Extrusion of CO from Aryl Ketones: Rhodium(I)-Catalyzed C-C Bond Cleavage

Directed by a Pyridine Group. Zhiquan Lei, Hu Li, Yang Li, Xisha Zhang, Kang

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51. N-Directing Group Assisted Rhodium-Catalyzed Aryl C–H Addition to Aryl

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52. Two ZnII Metal-Organic Frameworks with Coordinatively Unsaturated Metal

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53. Dual-Emission from a Single-Phase Eu−Ag Metal−Organic Framework: An

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54. Anion effect on the structural diversity of three 1D coordination polymers based

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55. Rhodium-catalyzed Cascade Oxidative Annulation Leading to Substituted

Naphtho[1,8-bc]pyrans by Sequential Cleavage of C(sp2)H/C(sp3)H and

C(sp2)H/OH Bonds. Xing Tan, Bingxian Liu, Xiangyu Li, Bin Li, Shansheng

Xu, Haibin Song, Baiquan Wang* J. Am. Chem. Soc. 2012, 134, 16163-16166.

56. Ruthenium-catalyzed Oxidative Coupling/cyclization of Isoquinolones with

Alkynes through C-H/N-H Activation: Mechanism Study and Synthesis of

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Wang, Jianfeng Ma, Haibin Song, Shansheng Xu, Baiquan Wang* Chem. Eur. J.

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57. Ruthenium-catalyzed Oxidative C-H Bond Olefination of N-methoxybenzamides

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Huiliang Feng, Shansheng Xu, Baiquan Wang* Org. Lett. 2012, 14, 736-739.

58. Synthesis, Structures, and Norbornene ROMP Behavior of o-aryloxide-N-

heterocyclic Carbene p-cymene Ruthenium Complexes, Yong Kong, Shansheng

Xu, Haibin Song, Baiquan Wang* Organometallics 2012, 31, 5527-5532.

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59. Stereoselective Construction of Spiro-[Butyrolactone-Pyrrolidines] via Highly

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60. A Facile Access to Fluorinated Pyrrolidines via Catalytic Asymmetric 1,3-Dipolar

Cycloaddition of Azomethine Ylides with Methyl α-Fluoroacrylate. Dingce Yan,

Qinghua Li, Chunjiang Wang* Chin. J. Chem. 2012, 30, 2714-2720.

61. C(sp)-C(sp3) Bond Formation through Cu-Catalyzed Cross-Coupling of N-

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Huan Li, Yan Zhang, Jianbo Wang* J. Am. Chem. Soc. 2012, 134, 5742-5745.

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62. Transition Metal-Free Synthesis of Pinacol Alkylboronates from

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63. Rh(II)-Catalyzed Cyclization of Bis-N-tosylhydrazones: An Efficient Approach

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Peiyuan Qu, Rui Ge, Yan Zhang, Jianbo Wang* Angew. Chem. Int. Ed. 2012,

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64. Direct Carbo-Acylation Reactions of 2-Arylpyridines with α-Diketones via Pd-

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Hongji Li, Lei Wang* Org. Lett. 2012, 14, 4594-4597.

65. Iron-Promoted Tandem Reaction of Anilines with Styrene Oxides via C–C

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66. An Efficient Synthesis of 2-Bromo(chloro)-3-selenyl(sulfenyl)indoles via

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67. Et3N-Promoted Tandem Ring-Opening Reaction of N-Tosylaziridines with

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Ling-Guo Meng, Lei Wang* Chem. Commun. 2012, 48, 3242-3244.

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69. TBHP/I2-Promoted Oxidative Coupling of Acetophenones with Amines at Room

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70. Magnetic Nanoparticles Supported Palladium: A Highly Efficient and Reusable

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71. The Facile Synthesis of 2-Bromoindoles via Cs2CO3-Promoted Intramolecular

Tandem Cyclization of 2-(gem-Dibromovinyl)anilines under Transition-metal-

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72. Synthesis and Characterization of Dinuclear NHC–Palladium Complexes and

Their Applications in the Hiyama Reactions of Aryltrialkyoxysilanes with Aryl

Chlorides. Jin Yang, Lei Wang* Dalton Trans. 2012, 41, 12031-12037.

73. A Highly Efficient One-Pot Reaction of 2-(gem-

Dibromovinyl)phenols(thiophenols) with K4Fe(CN)6 to 2-

Cyanobenzofurans(thiophenes). Wei Zhou, Wei Chen, Lei Wang* Org. Biomol.

Chem. 2012, 10, 4172-4178.

74. Synthesis of (Z)-3-Aryloxy-acrylonitriles, (E)-3-Aryloxy-acrylonitriles and 3-

Cyanobenzofurans through the Sequential Reactions of Phenols with

Propiolonitriles. Wei Zhou, Yicheng Zhang, Pinhua Li, Lei Wang* Org. Biomol.

Chem. 2012, 10, 7184-7196.

75. Fe3O4 Nanoparticle-Supported Copper(I): Magnetically Recoverable and

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Pyrimidinones. Lin Yu, Min Wang, Pinhua Li, Lei Wang* Appl. Organometal.

Chem. 2012, 26, 576-582.

76. Recyclable Magnetic Nanoparticles Supported Palladium Catalyst for the

Hiyama Reaction of Aryltrialkyoxysilanes with Aryl Halides. Lei Zhang,

Pinhua Li, Hongji Li,* Lei Wang* Catal. Sci. Technol. 2012, 2, 1859-1864.

77. Postsynthetic Modification of Metal-Organic Framework as a Highly Efficient

and Recyclable Catalyst for Three-Component (Aldehyde–Alkyne–Amine)

Coupling Reaction. Jin Yang, Pinhua Li, Lei Wang* Catal. Commun. 2012, 27,

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78. An Efficient Palladium-Catalyzed Desulfitative Arylation of Azoles with

Sodium Arylsulfinates. Min Wang, Dengke Li, Wei Zhou, Lei Wang*

Tetrahedron 2012, 68, 1926-1930.

79. SiO2-NHC-CuI Catalyzed N-Arylation of Imidazoles with Arylboronic Acids

under Base-Free Reaction Conditions. Ping Liu, Pinhua Li, Lei Wang* Synth.

Commun. 2012, 42, 2595-2605.

80. Pd-NHC-Catalyzed Direct Arylation of 1,4-Disubstituted 1,2,3-Triazoles with

Aryl Halides. Tao He, Min Wang, Pinhua Li, Lei Wang* Chin. J. Chem. 2012,

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81. Rare-earth Metal Complexes Having an Unusual Indolyl-1,2-dianion through C–

H Activation with a Novel η1:(μ2–η1: η1) Bonding with Metals. Xiancui Zhu,

Shuangliu Zhou, Shaowu Wang*, Yun Wei, Lijun Zhang, Fenhua Wang,

Shaoyin Wang, Zhijun Feng Chem. Commun. 2012, 48, 12020-12022.

82. Highly Efficient Hydrophosphonylation of Aldehydes and Unactivated Ketones

Catalyzed by Methylene-Linked Pyrrolyl Rare Earth Metal Amido Complexes.

Shuangliu Zhou, Zhangshuan Wu, Jiewei Rong, Shaowu Wang*, Gaosheng

Yang, Xiancui Zhu, Lijun Zhang Chem. Eur. J. 2012, 18, 2653-2659.

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83. Synthesis, Structure of Zinc Complexes Containing Sulfonylated Binaphtholate

Ligands and Their Catalytic Activities towards Ring-Opening Polymerization of

Lactide and ε-Caprolactone. Shuangliu Zhou *, Yongyao Jiang, Tao Xie,

Zhanshuan Wu, Linmin Zhou, Wenjing Xu, Lijun Zhang, Shaowu Wang*,

Chin. J. Chem. 2012, 30, 2176-2182.

84. Lanthanide Amido Complexes Incorporating Amino-Coordinate-Lithium Bridged

Bis(indolyl) Ligands: Synthesis, Characterization, and Catalysis for

hydrophosphonylation of Aldehydes and Aldimines. Xiancui Zhu, Shaowu

Wang*, Shuangliu Zhou, Yun Wei, Lijun Zhang, Fenhua Wang, Zhijun Feng,

Liping Guo, Xiaolong Mu Inorg. Chem. 2012, 51, 7134-7143.

85. Synthesis and Characterization of Organolanthanide Complexes with a Calix[4]-

pyrrolyl Ligand and Their Catalytic Activities toward Hydrophosphonylation of

Aldehydes and Unactivated Ketones. Shuangliu Zhou, Hengyu Wang, Jian Ping,

Shaowu Wang*, Lijun Zhang*, Xiancui Zhu, Yun Wei, Fenhua Wang, Zhijun

Feng, Xiaoxia Gu, Song Yang, Hui Miao Organometallics 2012, 31, 1696-1702.

86. Synthesis of 2-(polyfluoroaryl)benzofurans via a Copper(I)-catalyzed Tandem

Reaction of 2-(2,2-dibromovinyl)phenol with Polyfluoroarene. Shengqing Ye,

Gang Liu, Shouzhi Pu, Jie Wu* Org. Lett. 2012, 14, 70-73.

87. Generation of Indeno[1,2-c]pyrroles via a Pd-catalyzed Reaction of 2-

Alkynylbromobenzene with Propargylic Sulfonamide. Yong Luo, Jie Wu* Org.

Lett. 2012, 14, 1592-1595.

88. An Unexpected Silver Triflate-catalyzed Reaction of 2-Alkynylbenzaldehyde

with 2-Isocyanoacetate. Danqing Zheng, Shaoyu Li, Jie Wu* Org. Lett. 2012, 14,

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89. A Silver(I)-catalyzed Tandem Reaction of 2-Alkynylbenzaldoxime with

Alkylidenecyclopropane. Qian Xiao, Shengqing Ye, Jie Wu* Org. Lett. 2012, 14,

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90. A Palladium-catalyzed Three-component Reaction for the Preparation of

Quinazolin-4(3H)-imines. Guanyinsheng Qiu, Gang Liu, Shouzhi Pu, Jie Wu*

Chem. Commun. 2012, 48, 2903-2905.

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91. Generation of 4-Polyfluoroaryl Pyrrolo[1,2-a]quinolines via C-H Bond

Activation. Shengqing Ye, Jianping Liu, Jie Wu* Chem. Commun. 2012, 48,

5028-5030.

92. Generation of Cyclopenta[c]chromenes via a Palladium-catalyzed Reaction of 2-

Alkynylphenol with 2-Alkynylvinyl Bromide. Huanhuan Wang, Yong Luo, Biao

Zhu, Jie Wu* Chem. Commun. 2012, 48, 5581-5583.

93. Generation of Benzoimidazo[1,5-a]imidazoles via a Copper-catalyzed Tandem

Reaction of Carbodiimide and Isocyanoacetate. Guanyinsheng Qiu, Jie Wu*

Chem. Commun. 2012, 48, 6046-6048.

94. An Unexpected Silver Triflate-catalyzed Tandem Reaction of N'-(2-

alkynylbenzylidene)hydrazide with Ketene. Gang Liu, Hongliang Liu,

Guanyinsheng Qiu, Shouzhi Pu, Jie Wu* Chem. Commun. 2012, 48, 7049-7051.

95. A Palladium-catalyzed Three-component Coupling of Arylboronic Acids, Sulfur

Dioxide, and Hydrazines. Shengqing Ye, Jie Wu* Chem. Commun. 2012, 48,

7753-7755.

96. Generation of 3-(1H-pyrrol-3-yl)-1H-inden-1-ones via a Reaction of 1-(2-

alkynylphenyl)-2-enone, 2-Isocyanoacetate, with Water. Danqing Zheng, Shaoyu

Li, Jie Wu* Chem. Commun. 2012, 48, 8568-8570.

97. A Copper(I)-catalyzed Three-component Reaction of 2-(2-ethynylphenyl)oxirane,

Sulfonylazide, with 2-Isocyanoacetate. Shaoyu Li, Jie Wu* Chem. Commun.

2012, 48, 8973-8975.

98. A Palladium-catalyzed Reaction of Aryl Halides, Potassium Metabisulfite, and

Hydrazines. Shengqing Ye, Jie Wu* Chem. Commun. 2012, 48, 10037-10039.

99. A Novel Route to Benzo[a]fluorenes via a Palladium-catalyzed Reaction of 2-

Alkynylbromobenzene with 2-(2-Alkynylphenyl)malonate. Yong Luo, Xiaolin

Pan, Jie Wu* Adv. Synth. Catal. 2012, 354, 3071-3077.

100. Synthesis of Benzoindolines via a Copper-catalyzed Reaction of 1-

Bromoethynyl-2-(cyclopropylidenemethyl)arene with N-allyl Sulfonamide.

Shaoyu Li, Zhiming Li, Jie Wu* Adv. Synth. Catal. 2012, 354, 3087-3094.

101. A Novel and Efficient Approach for the Construction of Benzazepine and

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Benzoxepine Derivatives. Shaoyu Li, Shaowu Zou, Jie Wu* Chem. Asian J.

2012, 7, 2882-2887.

102. Reaction of N'-(2-alkynylbenzylidene)hydrazide with Tertiary Amine: A

Concise Synthesis of H-pyrazolo[5,1-a]isoquinolines. Chao Ye, Xingxin Yu,

Guanyinsheng Qiu, Jie Wu*, RSC Adv. 2012, 2, 5961-5963.

103. Facile Assembly of Indeno[1,2-c]chromenes via a Palladium-catalyzed

Reaction of 2-Alkynylhalobenzene. Xiaolin Pan, Hongming Nie, Yong Luo,

Yueqiu Gao, and Jie Wu*, Org. Biomol. Chem. 2012, 10, 8244-8250.

104. 2,6-Diazasemibullvalenes: Synthesis, Structural Characterization, Reaction

Chemistry and Theoretical Analysis. Shaoguang Zhang, Junnian Wei, Ming Zhan,

Qian Luo, Chao Wang, Wenxiong Zhang, Zhenfeng Xi* J. Am. Chem. Soc. 2012,

134, 11964-11967. (JACS Spotlight)

105. Palladium-Catalyzed Intermolecular Coupling of 2-Silylaryl Bromides with

Alkynes: Synthesis of Benzosiloles and Heteroarene-Fused Siloles by Catalytic

Cleavage of the C(sp3)-Si Bond. Yun Liang, Weizhi Geng, Junnian Wei,

Zhenfeng Xi* Angew. Chem. Int. Ed. 2012, 51, 1934 -1937.

106. 1,3-Butadienylzinctrimer Formed via Transmetallation from 1,4-Dilithio-1,3-

butadienes: Synthesis, Structural Characterization and Application in Negishi

Cross-coupling. Yi Zhou, Wenxiong Zhang, Zhenfeng Xi* Organometallics

2012, 31, 5546-5550.

107. Reactivity of Seven-membered Azazirconacycloallenes and Four-membered

Zirconacycles towards Diphenylacetonitrile. Jing Zhao, Shaoguang Zhang,

Wenxiong Zhang*, Zhenfeng Xi* Organometallics 2012, 31, 8370-8374.

108. Carbonylation of 1-Lithiobutadiene with Carbon Monoxide Followed by

Intramolecular Acyllithiation of C=C Double Bond and Intermolecular Acylation

with Acid Chloride: Scope, Applications, and Mechanistic Aspects. Heng Li,

Lantao Liu, Fei Zhao, Congyang Wang, Chao Wang, Qiuling Song, Wenxiong

Zhang, Zhenfeng Xi* J. Org. Chem. 2012, 77, 4793-4800.

109. Synthesis of gem-Dihaloenynes and Butatrienes from gem-Dihalovinyl

64

Derivatives. Tianhao Meng, Huijun Zhang, Zhenfeng Xi* Tetrahedron Lett.

2012, 53, 4555-4557.

110.Synthesis of Benzothieno[2,3-b]thiophenes, [2,3-b:3',2'-d]- dithienothiophenes

and Their Selenium Derivatives via Electrophilic Cyclization and McMurry

Cyclization. Weizhi Geng, Hanliu Wang, Zitao Wang, Shaoguang Zhang,

Wenxiong Zhang, Zhenfeng Xi* Tetrahedron 2012, 68, 5283-5289.

111.Palladium-catalyzed Silyl C(sp3)-H Bond Activation. Yun Liang, Weizhi Geng,

Junnian Wei, Zhenfeng Xi* Org. Biomol. Chem. 2012, 10, 1537-1542.

112. Highly Efficient Aerobic Oxidative Hydroxylation of Arylboronic Acids:

Photoredox Catalysis Using Visible Light. Youquan Zou, Jiarong Chen,

Xiaopeng Liu, Liangqiu Lu, Rebecca L. Davis, Karl Anker Jørgensen*, Wenjing

Xiao* Angew. Chem. Int. Ed. 2012, 51, 784-788.

113. Synthesis of Indolo [1,2-a]Quinoxalines via a Pd-Catalyzed Regioselective

C-H Olefination/Cyclization Sequence. Liang Wang, Wei Guo, Xiaoxiao Zhang,

Xudong Xia, Wenjing Xiao* Org. Lett. 2012, 14, 740-743.

114.Visible Light Induced Intermolecular [2+2]-cycloaddition Reactions of 3-

Ylidene-oxindoles through Energy Transfer Pathway. Youquan Zou, Shuwen

Duan, Xianggao Meng, Xiaoqiang Hu, Shuang Gao, Jiarong Chen, Wenjing

Xiao* Tetrahedron 2012, 68, 6914-6919.

115.Rhodium-Catalyzed Oxidative Annulation of Sulfonylhydrazones with Alkenes.

Guifei Li, Zhengwei Ding, Bin Xu* Org. Lett. 2012, 14, 5338-5341.

116.Palladium-Assisted Regioselective C–H Cyanation of Heteroarenes Using

Isonitrile as Cyanide Source. Shuguang Xu, Xiaomei Huang, Xiaohu Hong, Bin

Xu* Org. Lett. 2012, 14, 4614-4617.

117.Palladium-Catalyzed Tandem Allenyl and Aryl C–N Bond Formation: Efficient

Access to N-Functionalized Multi-substituted Indoles. Bingxin Liu, Xiaohu

Hong, Dong Yan, Shuguang Xu, Xiaomei Huang, Bin Xu* Org. Lett. 2012, 14,

4398-4401.

118.Synthesis of N–Alkyl Substituted 4-Quinolones via Tandem Alkenyl and Aryl C-

N Bond Formation. Jun Shao, Xiaomei Huang, Xiaohu Hong, Bingxin Liu, Bin

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Xu* Synthesis 2012, 44, 1798-1808.(invited contribution).

119.A Straightforward Synthesis of N-Monosubstituted α-Keto Amides via Aerobic

Benzylic Oxidation of Amides. Jun Shao, Xiaomei Huang, Siyuan Wang, Bingxin

Liu, Bin Xu* Tetrahedron 2012, 68, 573-579.

120. Ruthenium(II) Pyrazolyl-Pyridyl-Oxazolinyl Complex Catalysts for

Asymmetric Transfer Hydrogenation of Ketones. Wenjing Ye, Miao Zhao,

Zhengkun Yu* Chem. Eur. J. 2012, 18, 10843-10846.

121. A Versatile Ruthenium(II) NNC Complex Catalyst for Transfer

Hydrogenation of Ketones and Oppenauer-Type Oxidation of Alcohols.

Wangming Du, Liandi Wang, Ping Wu, Zhengkun Yu* Chem. Eur. J. 2012, 18,

11550-11554.

122. A Highly Active Ruthenium(II) Pyrazolyl-Pyridyl-Pyrazole Complex

Catalyst for Transfer Hydrogenation of Ketones. Weiwei Jin, Liandi Wang,

Zhengkun Yu* Organometallics 2012, 31, 5664-5667.

123. Brnsted Acid Activation Strategy in Transition Metal-Catalyzed

Asymmetric Hydrogenation of Unprotected N-H Imines, Enamines and N-

Heteroaromatics. Zhengkun Yu*, Weiwei Jin, Quanbin Jiang Angew. Chem. Int.

Ed. 2012, 51, 6060-6072.

124. FeCl3.6H2O-Catalyzed Alkenylation of Indoles with Aldehydes. Qin Yang,

Liandi Wang, Tenglong Guo, Zhengkun Yu* J. Org. Chem. 2012, 77, 8355-8361.

125. Cationic Rhodium(I)-Catalyzed Regioselective Tandem

Hetero-cyclization/[3+2] Cycloaddition of 2-(1-Alkynyl)-2-alken-1-ones with

Alkynes. Hongyin Gao, Junliang Zhang* Chem. Eur. J. 2012, 18, 2777-2782.

126. A Base-Promoted Tandem Cycloaddition/Air Oxidation Reaction of

Electron-Deficient Conjugated Enynes and Hydrazines: Synthesis of Highly

Substituted Pyrazoles. Xiuzhao Yu, Junliang Zhang* Chem. Eur. J. 2012, 18,

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127. Ni(ClO4)2-Catalysed Regio- and Diastereoselctive [3+2]

Cycloadditon of Indoles and Aryl Oxiranyl-Dicarboxylates/Diketones: A Facile

Access to Furo[3,4-b]indoles. Jieming Zhang, Zuliang Chen, Hai-Hong Wu,

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Junliang Zhang* Chem. Commun. 2012, 48, 1817-1819.

128. Efficient Synthesis of Isochromanones and Isoquinolines via Yb(OTf)3-

Catalyzed Tandem Oxirane/Aziridine Ring Opening/ Friedel-Crafts Cyclization.

Lai Wei, Junliang Zhang* Chem. Commun. 2012, 48, 2636-2638.

129. Gold(I)-catalyzed Cyclization of 2-(1-alkynyl)-alk-2-en-1-one Oximes: A

Facile Access to Highly Substituted N-alkoxypyrroles. Mei Zhang, Junliang

Zhang* Chem. Commun. 2012, 48, 6399-6401.

130. Kinetic Resolution of 1-(1-alkynyl)cyclopropyl ketones by Gold(I)-catalyzed

Asymmetric [4+3]cycloaddition with Nitrones: Scope, Mechanism and

Applications. Yanqing Zhang, Junliang Zhang* Chem. Commun. 2012, 48,

4710-4712.

131. DBU-catalyzed Tandem Additions of Electron-deficient 1,3-conjugated

Enynes with 2-aminomalonates: A Facile Access to Highly Substituted 2-

pyrrolines. Xiuzhao Yu, Guanghua Zhou, Junliang Zhang* Chem. Commun.

2012, 48, 4002-4004.

132. Catalytic Oxidation/C–H Functionalization of N-arylpropiolamides by Means

of Gold Carbenoids: Concise Route to 3-acyloxindoles. Deyun Qiana, Junliang

Zhang* Chem. Commun., 2012, 48, 7082-7084.

133. Palladium(II)-Catalyzed Stereospecific Three-Component Domino Reactions

of Diyne-enones, Nucleophiles, and Vinyl Ketones. Renrong Liu, Junliang

Zhang* Chem. Asian. J. 2012. 7, 294-297.

134. Highly Substituted Pyrroles by Gold(I)-Catalyzed Tandem Reaction of 1-(1-

Alkynyl)cyclopropyl Oxime Ethers with Nucleophiles. Yanqing Zhang, Junliang

Zhang* Synlett, 2012, 23, 1389-1393.

135. Y(OTf)3-Catalyzed Diastereoselective [3+2]Cycloaddition of N-

Tosylaziridines and Imines; Efficient Synthesis of Multisubstituted

Imidazolidines. Xingxing Wu, Junliang Zhang* Synthesis 2012, 44, 2147-2154.

136. Gold(I)-Catalyzed Regio- and Stereoselective 1,3-Dipolar Cycloaddition

Reactions of 1-(1-Alkynyl)cyclopropyl Oximes with Nitrones: A Modular Entry

to Highly Substituted Pyrrolo[3,4-d][1,2]oxazepines. Yanqing Zhang, Junliang

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Zhang* Adv. Synth. Catal. 2012, 354, 2556-2560.

137. Direct aza-Darzens Aziridination of N-Tosyl Imines with 2-Bromomalonates

for Efficient Synthesis of Highly Functionalized Donor-acceptor Aziridines.

Xingxing Wu, Lei Li, Junliang Zhang* Adv. Synth. Catal. 354, 3485-3489.

138. Ru-catalyzed Hydrogenation of 3,5-diketo Amides: Simultaneous Control of

Chemo- and Enantioselectivity. Wanfang Li, Weizheng Fan, Xin Ma, Xiaoming

Tao, Xiaoming Li, Xiaomin Xie, Zhaoguo Zhang* Chem. Commun. 2012, 48,

8976.

139. Ru-Catalyzed Asymmetric Hydrogenation of 3-Oxoglutaric Acids

Derivatives: A Study on the Unconventional Solvent and Substituent Effects.

Wanfang Li, Xiaoming Tao, Xin Ma, Weizheng Fan, Xiaoming Li, Mengmeng

Zhao, Xiaomin Xie, Zhaoguo Zhang* Chem. Eur. J. 2012, 18, 16531-16539.

140. 多官能团羰基化合物的高选择性不对称氢化。马欣，李万方，范为正，

陶晓明，李晓明，姚莹，诸吕锋，陈厚和，谢小敏，张兆国* 有机化学， 2012, 32, 1353-1358.

141. Enantioselective Hydrogenation of β-Ketophosphonates with Chiral Ru(II)

Catalysts. Xiaoming Tao, Wanfang Li, Xin Ma, Xiaoming Li, Weizheng Fan,

Lvfeng Zhu, Xiaomin Xie, Zhaoguo Zhang* J. Org. Chem. 2012, 77, 8401-

8409.

142. Regioselective Synthesis of Substituted Naphthalenes and Phenanthrenes by

Iron-promoted Annulation of Aryl and Naphthyl Acetaldehydes with Alkynes.

Xiuli Bu, Longcheng Hong, Ruiting Liu, Jianquan Hong, Zhengxing Zhang,

Xigeng Zhou* Tetrahedron, 2012, 68, 7960-7965.

143. MeSi Bond Cleavage of Anionic Bis(trimethylsilyl)amide in Scorpionate-

Anchored Rare Earth Metal Complexes. Weiyin Yi, Jie Zhang*, Zhenxia Chen,

Xigeng Zhou* Inorg. Chem. 2012, 51, 10631-10638.

144. Reactivity of Scorpionate-Anchored Yttrium Alkyl Complex toward Organic

Nitriles. Weiyin Yi, Jie Zhang*, Zhenxia Chen, Xigeng Zhou* Organometallics

2012, 31, 7213-7221.

68

145. Facile Synthesis of Sulfenyl-substituted Isocoumarins, Heterocycle-fused

Pyrones and 3-(inden-1-ylidene)iso-benzofuranones by FeCl3-promoted

Regioselective Annulation of o-(1-alkynyl)benzoates and o-(1-

alkynyl)heterocyclic Carboxylates with Disulfides. Zhen Li, Jianquan Hong,

Linhong Weng, Xigeng Zhou* Tetrahedron, 2012, 68, 1552-1559.

146. Dihydrophenanthridine: A New and Easily Regenerable NAD(P)H Model for

Biomimetic Asymmetric Hydrogenation. Qingan Chen, Kai Gao, Ying Duan,

Zhishi Ye, Lei Shi, Yan Yang, Yonggui Zhou* J. Am. Chem. Soc. 2012, 134,

2442-2448.

147. Iridium-Catalyzed Asymmetric Hydrogenation of 3-Substituted -2H-1,4-

Benzoxazines. Kai Gao, Changbin Yu, Duosheng Wang, Yonggui Zhou* Adv.

Synth. Catal. 2012, 354, 483-488.

148. Enantioselective Pd-Catalyzed Hydrogenation of Tetrasubstituted Olefins of

Cyclic β-(Aryl-sulfonamido)acrylates. Changbin Yu, Kai Gao, Qingan Chen,

Muwang Chen, Yonggui Zhou* Tetrahedron Lett. 2012, 53, 2560-2563.

149. A Highly Efficient Gold-Catalyzed Oxidative C-C Coupling from C-H

Bonds Using Air as Oxidant. Jin Xie, Huamin Li, Jiecong Zhou, Yixiang Cheng,

Chengjian Zhu* Angew. Chem. Int. Ed. 2012, 51, 1252-1255.

150. Metal-free, Organocatalytic Cascade Formation of C–N and C–O Bonds

through Dual sp3 C–H Activation: Oxidative Synthesis of Oxazole Derivatives.

Jin Xie, Honglai Jiang, Yixiang Cheng, Chengjian Zhu* Chem. Commun. 2012,

48, 979-981.

151. A Scalable, Efficient Gold-catalyzed Oxidative Phosphonation of sp3 C-H

Bonds Using Air as Sustainable Oxidant. Jin Xie, Huamin Li, Qicai Xue, Yixiang

Cheng, Chengjian Zhu* Adv. Synth. Catal. 2012, 354, 1646-1650.

152. Coumarin-based Chiral Fluorescence Sensor Incorporating a Thiourea Unit

for Highly Enantioselective Recognition of N-Boc-protected Proline. Zhitao

Xing, Yong Fu, Jiecong Zhou, Chengjian Zhu*, Yixiang Cheng Org. Biomol.

Chem. 2012, 10, 4024-4028.

153. A Highly Selective Ratiometric Fluorescent Chemosensor for Zn2+ ion Based

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on a Polyimine Macrocycle. Kang Shen, Xia Yang, Yixiang Cheng, Chengjian

Zhu* Tetrahedron, 2012, 68, 5719-5723.

154. Metal-free n-Bu4NI-catalyzed direct Synthesis of Amides from Alcohols and

N,N-disubstituted Formamides. Huamin Li, Jin Xie, Qicai Xue, Yixiang Cheng,

Chengjian Zhu* Tetrahedron Lett. 2012, 53, 6479-6482.

155. Metal-free, One-pot Highly Selective Synthesis of (E)-vinyl Sulfones and

Sulfoxides via Addition–oxidation of Thiols with Alkynes. Qicai Xue, Zhijie

Mao, Yan Shi, Haibin Mao, Yixiang Cheng, Chengjian Zhu* Tetrahedron Lett.

2012, 53, 1851-1854.

156. A Novel Calixsalen Macrocycle: Metal Sensing Behavior for Zn2+ and

Intracellular Imaging Application. Yong Fu, Zhitao Xing, Chengcheng Zhu,

Hongwei Yang, Weijiang He, Chengjian Zhu*, Yixiang Cheng Tetrahedron

Lett. 2012, 53, 804-807.

157. Efficient Synthesis of β-Enaminones and β-Enaminoesters Catalyzed by

Gold (I)/Silver (I) under Solvent-Free Conditions. Ming Zhang, Ablimit

Abdukader, Yong Fu, Chengjian Zhu* Molecules, 2012, 17, 2812-2822.

158. Oxidation and Amination of Benzylic sp3 C–H Bond Catalyzed by

Rhenium(V) Complexes. Hao Peng, Aijun Lin, Yan Zhang, Honglai Jiang,

Jiecong Zhou, Yixiang Cheng, Chengjian Zhu*, Hongwen Hu ACS Catal. 2012,

2, 163-167.

159. The Au(III)-catalyzed Coupling Reactions between Alcohols and N-

heterocycles via C–H Bond Activation. Honglai Jiang, Jin Xie, Aijun Lin,

Yixiang Cheng, Chengjian Zhu* RSC Adv. 2012, 2, 10496-10498.

160. Crystal structures of chiral mono- and dinuclear salan–Cu(II) complexes and

the application to catalytic asymmetric Henry reaction. Yan Shi, Zhijie Mao,

Qicai Xue, Chengjian Zhu*, Hongwen Hu, Yixiang Cheng Inorg. Chem.

Commun. 2012, 20, 259-262.

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固定人员代表性论文复印件目录（按通讯作者姓氏首字母排序）

1. Rh(I)-Catalyzed Enantioselective Hydrogenation of α-Substituted

Ethenylphosphonic Acids. Kaiwu Dong, Zheng Wang, Kuiling Ding* J. Am.

Chem. Soc. 2012, 134, 12474-12477.

2. Catalytic Asymmetric Synthesis of Aromatic Spiroketals by SpinPhox/Iridium(I)-

Catalyzed Hydrogenation and Spiroketalization of a,a’-Bis(2-hydroxyarylidene)

Ketones. Xiaoming Wang, Zhaobin Han, Zheng Wang*, Kuiling Ding* Angew.

Chem. Int. Ed. 2012, 51, 936-940.

3. Aromatic Spiroketal Bisphosphine Ligands: Palladium-Catalyzed Asymmetric

Allylic Amination of Racemic Morita–Baylis–Hillman Adducts. XiaomingWang,

Fanye Meng, YanWang, Zhaobin Han, Yong-Jun Chen, Li Liu*, ZhengWang*,

Kuiling Ding* Angew. Chem. Int. Ed. 2012, 51, 9276-9282.

4. Catalytic Hydrogenation of Cyclic Carbonates: A Practical Approach from CO2

and Epoxides to Methanol and Diols. Zhaobin Han, Liangce Rong, Jiang Wu,

Zheng Wang, Kuiling Ding* Angew Chem. Int. Ed. 2012, 51, 13041-13045.(VIP)

5. Palladium-Catalyzed Oxidative Aryltrifluoromethylation of Activated Alkenes at

Room Temperature. Xin Mu, Tao Wu, Haoyang Wang, Yinlong Guo, Guosheng

Liu* J. Am. Chem. Soc. 2012, 134 (2), 878-881.

6. Gold-Catalyzed Cyclization of 1,6-Diyne-4-en-3-ols: Stannyl Transfer from 2-

Tributylstannylfuran Through Au/Sn Transmetalation. Yifeng Chen, Ming Chen,

Yuanhong Liu* Angew. Chem. Int. Ed. 2012, 51, 6181-6186.

7. Gold-Catalyzed Cascade Cyclizations of 1,6-Diynyl Carbonates to

Benzo[b]fluorenes Involving Arylation of Oxocarbenium Ion Intermediates and

Decarboxylative Etherification. Yifeng Chen, Ming Chen, Yuanhong Liu*

Angew. Chem. Int. Ed. 2012, 51, 6493-6497.

8. Allenes in Catalytic Asymmetric Synthesis and Natural Product Syntheses.

Shichao Yu, Shengming Ma*Angew. Chem. Int. Ed. 2012, 51, 3074-3112.

9. One-Pot Approach to Installing Eight-Membered Rings onto Indoles. Can Zhu,

Xue Zhang, Xiongdong Lian, Shengming Ma*Angew. Chem. Int. Ed. 2012, 51,

7817- 7820.

10. Strained Small Rings in Gold-Catalyzed Rapid Chemical Transformations. Beili

Lu, Lunzhi Dai, Min Shi* Chem. Soc. Rev. 2012, 41, 3318-3339.

11. Rapid Generation of Molecular Complexity in the Lewis or Brønsted Acid-

71

mediated Reactions of Methylenecyclopropanes. Min Shi*, Jianmei Lu, Yin Wei,

Lixiong Shao* Acc. Chem. Res. 2012, 45, 641-652.

12. A Chiral Cage-like Copper(I) Catalyst for the Highly Enantioselective Synthesis

of 1,1-Cyclopropane Diesters. Chao Deng, Lijia Wang, Jun Zhu, Yong Tang*

Angew. Chem. Int. Ed. 2012, 51, 11620-11623.

13. Side-Arm-Promoted Highly Enantioselective Ring-Opening Reactions and

Kinetic Resolution of Donor-Acceptor Cyclopropanes with Amines. Youyun

Zhou, Lijia Wang, Jun Li, Xiuli Sun*, Yong Tang* J. Am. Chem. Soc. 2012, 134,

9066-9069.

14. Tridentate Ligands and Beyond in Group IV Metal α-olefin Homo-/co-

polymerization Catalysis. Carl Redshaw*, Yong Tang* Chem. Soc. Rev. 2012,

41, 4484-4510.

15. Highly Diastereo- and Enantioselective Cyclopropanation of 1,2-Disubstituted

Alkenes. Jun Li, Saihu Liao, Hu Xiong, Youyun Zhou, Xiuli Sun*, Yue Zhang,

Xiaoguang Zhou, Yong Tang* Angew. Chem. Int. Ed. 2012, 51, 8838-8841.

16. Catalytic Asymmetric Dearomatization Reactions. Chunxiang Zhuo, Wei Zhang*,

Shuli You* Angew. Chem. Int. Ed. 2012, 51, 12662-12686.

17. Asymmetric N-Allylation of Indoles via Ir-Catalyzed Allylic Alkylation of

Indolines and Oxidation Strategy. Wenbo Liu, Xiao Zhang, Lixin Dai, Shuli

You* Angew. Chem. Int. Ed. 2012, 51, 5183-5187.

18. Ir-Catalyzed Allylic Alkylation Reaction with N-Aryl Phosphoramidite Ligands:

Scope and Mechanistic Studies. Wenbo Liu, Chao Zheng, Chunxiang Zhuo, Lixin

Dai, Shuli You* J. Am. Chem. Soc. 2012, 134, 4812-4821.

19. Transfer Hydrogenation with Hantzsch Esters and Related Organic Hydride

Donors. Chao Zheng, Shuli You* Chem. Soc. Rev. 2012, 41, 2498-2518.

20. Enantioselective Syntheses of Spiro Cyclopentane-1,3'-indoles and 2,3,4,9-

Tetrahydro-1H-carbazoles via Ir-Catalyzed Allylic Dearomatization and

Stereospecific Migration. Qingfeng Wu, Chao Zheng, Shuli You* Angew. Chem.

Int. Ed. 2012, 51, 1680-1683.

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