View
164
Download
3
Category
Preview:
DESCRIPTION
เรียนรู้อุณหพลศาสตร์เคมีตั้งแต่พื้นฐานศึกษาความสัมพันธ์ระหว่างปฎิกิริยา ความร้อน และพลังงาน ไปกับอิโอะจังและเนรุจัง
Citation preview
225.-
... KISO KARA MANABU KAGAKUNETSU RIKIGAKU
By Katsuhiro Saito
. .
:
5-7 29 10110
. 0-2258-0320 (6 ), 0-2259-9160 (10 )
www.tpa.or.th/publisher/new
www.tpabookcentre.com
()
1858/87-90 19 -
10260
. 0-2739-8000, 0-2739-8222 0-2739-8356-9
www.se-ed.com
: (Chemical thermodynamics)
By... Katsuhiro Saito
... . .
Saito, Katsuhiro .
: .-- : (-
), 2555.
232 .
1. . 2. . I. , . II. .
500
ISBN 978-974-443-491-3
1 2555
. 0-2258-0320 1560, 1570
225
KISO KARA MANABU KAGAKUNETSU RIKIGAKU by Katsuhiro Saito
Copyright 2010 Katsuhiro Saito
All right reserved.
Originally published in Japan by SOFTBANK Creative Corp., Tokyo
Thai translation rights arranged with SOFTBANK Creative Corp.
through THE SAKAI AGENCY.
(-)
....................................................................................................... (1)1 ? ................................................................. 1 1-1 ? ........................................................................ 2 1-2 ? ................................................................. 4 1-3 .................................................... 6 1-4 ..................................................... 8 1-5 ..................................................................... 10 1-6 ..................................................................... 12 1-7 ........................................................ 14 1-8 ............................... 161 ........................................................................................ 18
2 .............................................. 19 2-1 ........................................................................ 20 2-2 ................................................... 22 2-3 ........................................... 24 2-4 .............................................. 26 2-5 .................................................................. 28 2-6 ............................................ 30 2-7 .......................................................... 322 ........................................................................................ 34
3 .............................................................. 35 3-1 .................................................. 36 3-2 ...................................................... 38 3-3 .................................................................. 40 3-4 ............................................................. 42
3-5 ................................................................ 44 3-6 ........................... 46 3-7 ............................. 48 3-8 ................................................................. 50 3-9 .................................................. 52 3-10 ..................................................................... 543 ........................................................................................ 56
4 ............................................................ 57 4-1 ................................................ 58 4-2 ............................................................................... 60 4-3 ................................. 62 4-4 ....................................... 64 4-5 ........................................................ 66 4-6 ......................................... 68 4-7 ............................................. 70 4-8 .......................................... 72 4-9 ................................................... 74 4-10 ................................................................. 76 4-11 .................................................. 78 4-12 ............................................................... 804 ........................................................................................ 82
5 ................................................................... 83 5-1 ............................................................... 84 5-2 ............................................................................. 86 5-3 ................................................... 88
5-4 ............................................ 90 5-5 ............................................ 92 5-6 ................................................. 94 5-7 ....................................................................... 96 5-8 .................................................... 98 5-9 .................................................................... 100 5-10 .................................................. 102 5-11 ................................................................ 1045 ........................................................................................ 106 6 .............. 107 6-1 ............................................................. 108 6-2 ............................................................................ 110 6-3 ............................................ 112 6-4 .................................................................... 114 6-5 .............................................................. 116 6-6 .................................................. 118 6-7 ............................................... 120 6-8 ............................. 122 6-9 .......................................... 1246 ........................................................................................ 126
7 ............................................................. 127 7-1 ................................. 128 7-2 1 ..................................................... 130 7-3 ......................................... 132 7-4 ....................................................... 134
7-5 ................................................ 136 7-6 .................................................................. 138 7-7 ......................................................................................... 140 7-8 .............................................................. 142 7-9 .......................................................................... 144 7-10 .................................................... 146 7-11 .......................................................... 1487 ........................................................................................ 150
8 .................................................................................... 151 8-1 ...................................... 152 8-2 ....................................................... 154 8-3 23 ......................................... 156 8-4 ........................................... 158 8-5 ..................................................... 160 8-6 ..................................................................... 162 8-7 .................................................................. 164 8-8 ........................ 1668 ........................................................................................ 168 9 ........................................................................... 169 9-1 .................................................. 170 9-2 .......................................................... 172 9-3 ........................................... 174 9-4 ........................................................... 176 9-5 ......................................................... 178
9-6 ....................................................... 180 9-7 ...................................... 1829 ........................................................................................ 184 10 ......................................... 185 10-1 ....................................................... 186 10-2 ....................................................................... 188 10-3 ............................................ 190 10-4 ............................................................................. 192 10-5 .................................................................... 194 10-6 .................................................................................. 196 10-7 .............................................. 198 10-8 ............... 200 10-9 ............................................................ 202 10-10 ............................................................... 20410 ...................................................................................... 206
1-3 ................................................................................................ 207 4-6 ................................................................................................ 208 7-9 ................................................................................................ 209 10 ................................................................................................. 210 ............................................................................................... 211 .............................................................................................................. 212
2 :
?
1 ?
E W Q
energy
2 1
(Chemical thermodynamics) 4 1
?1-1
1 ?
3
(system)
(isolatedsystem)
E m 1 -
1-
E = mc2E : m : c :
10
:
1-5
1
2
()
(exothermic reaction)
1 ?
11
(endothermicreaction)
EEE
12
:
1-6
(enthalpy)H
1
(transf iguration)
( 1)
2
U1 U2
Q Q = U2 - U1 = U
1 ?
13
W P V W = PV U
1 U2
W ()
H H = U1 (U2 W) = U + W = U +
PV (2)
1
2
V
H = U + PV
P
U1 U2
14
:
1
2-3
( 1)
(2)
2 2
(entropy) S S
S S (1)
1-7
1 ?
15
S
2
1
2
S S
() ()
S
16
:
1-8
A B A B B A
1 A B
(irreversiblereaction)
A B
(reversiblereaction)
A B
?
2 2
(12)
(free
energy)
1 ?
17
1 2
E0
...
!
S>0
E
Recommended